KR20220005576A - hair dressing composition - Google Patents

Abstract

This invention provides the hair dressing composition by which the increase in the viscosity resulting from mixing|blending of a clay mineral was suppressed. The hair dressing composition which concerns on 1 aspect of this invention contains component A: a clay mineral, component B: polyphosphoric acid or its salt, and component C: water.

Description

hair dressing composition

This invention relates to a hair dressing composition.

Conventionally, a solid oil agent, a film-type polymer, etc. are used as a component which provides hairstyling power to a hair dressing composition. However, there has been a problem in that an unnatural glossy feel is imparted to the hair by blending such components. In order to solve this problem and make sufficient hairstyling power and matte texture compatible, the hair dressing which mix|blended the clay mineral is developed. For example, Patent Document 1 discloses a waxy hairdressing agent containing kaolin, which is a kind of clay mineral. Moreover, in patent document 2, the hair dressing which mix|blended the oil-swellable clay mineral is disclosed.

Japanese Patent Laid-Open No. 2002-114652 Japanese Patent Laid-Open No. 2003-026550

However, the clay mineral also has a function as a thickener. Therefore, when a clay mineral is mix|blended in large quantity, the viscosity of the intermediate solution in the middle of preparation, the viscosity of a formulation, etc. will become high too much. Therefore, the composition containing a clay mineral abundantly will become unsuitable for manufacture of a hair dressing composition, and practical use. That is, there was a limit to the amount of the clay mineral that can be blended into the formulation due to the thickening property of the clay mineral.

One aspect of this invention aims at providing the hair dressing composition which can provide the increase in the viscosity resulting from mixing|blending of a clay mineral, and matte texture.

In order to solve said subject, according to the hair dressing composition containing (i) a clay mineral, (ii) polyphosphoric acid or its salt, and (iii) water, as a result of the present inventors earnestly examining, a clay mineral is abundantly It has been found that even when blended, an increase in viscosity due to the clay mineral can be suppressed and a matte texture can be imparted.

That is, the hair dressing composition which concerns on one aspect of this invention is a hair dressing composition containing the following component A, component B, and component C;

Component A: clay mineral

Component B: polyphosphoric acid or a salt thereof, and

Component C: Water.

One aspect of the present invention provides a hair dressing composition in which an increase in viscosity due to mixing of a clay mineral is suppressed and can impart a matte texture.

[Form for carrying out the invention]

Hereinafter, although an example of embodiment of this invention is described in detail, this invention is not limited to these.

In this specification, unless otherwise indicated, "A to B" which shows a numerical range means "A or more and B or less." Unless otherwise indicated in this specification, mass % which shows content of a component is the value which made the mass of the whole hair dressing composition 100 mass %.

[Each ingredient]

The hair dressing composition which concerns on one Embodiment of this invention contains component A: clay mineral, component B: polyphosphoric acid or its salt, and component C: water.

Hereinafter, each component contained in the hair dressing composition which concerns on one Embodiment of this invention is demonstrated in order.

[Component A: clay mineral]

Component A is a clay mineral. In the hair dressing composition which concerns on one Embodiment of this invention, the said component A has a role which provides a matte texture. As for the component A, only 1 type may be used and may use 2 or more types together.

The clay mineral of component A may be a natural clay mineral, what refined the natural clay mineral, and a synthesized clay mineral may be sufficient as it. Although it does not specifically limit as said component A, For example, as a natural clay mineral or a natural clay mineral refined, a kaolin group clay mineral, an antigolite group clay mineral, a pyrophyllite group clay mineral, a mica group and clay minerals, smectite group clay minerals, vermiculite group clay minerals, and chlorite group clay minerals.

Examples of the kaolin group clay minerals include kaolin, nacreite, dickite and halloysite. Examples of the antigolite group clay minerals include antigolite, amethyst, and kronstedtite. Examples of the pyrophyllite group clay mineral include pyrophyllite and talc (talc). Examples of the mica group clay mineral include illite, parasite, seldonite, sericite, mica (mica), muscovite, chromium muscovite and biotite. Examples of the smectite group clay mineral include bentonite, montmorillonite, smectite, weidellite, nontronite, saponite, and hectorite. As said vermiculite group clay mineral, vermiculite etc. are mentioned. As said chlorite group clay mineral, chlorite (chlorite) etc. are mentioned.

Moreover, synthetic silicate and derivatives of synthetic silicate are mentioned as a synthetic|combined clay mineral. The above synthetic silicates and derivatives of synthetic silicates are not silicate minerals (not a little impurity) containing natural magnesium silicate or silicic acid (sodium/magnesium) as a main component, but silicates obtained by synthesis and derivatives of silicates say that

The synthetic silicate and derivatives of the synthetic silicate include, for example, synthetic silicic acid (sodium/magnesium) (INCI name “SODIUM MAGNESIUM SILICATE”: International Cosmetic Ingredient Dictionary and Handbook, 14th Edition, Vol. 2, CTFA, 2012) , p.3076), magnesium fluorosilicate (INCI name "MAGNESIUM FLUOROSILICATE": International Cosmetic Ingredient Dictionary and Handbook, 14th ed., vol. 2, CTFA, 2012, p.1793), fluorosilicate (sodium/magnesium). ) (INCI name 「SODIUM MAGNESIUM FLUOROSILICATE」: International Cosmetic Ingredient Dictionary and Handbook, 14th ed., vol. 2, CTFA, 2012, p.3076), fluorosilicic acid (magnesium/potassium) (INCI name 「MAGNESIUM POTASSIUM FLUOROSILICATE」 ”: International Cosmetic Ingredient Dictionary and Handbook, 14th ed., Vol. 2, CTFA, 2012, p.1799), Fluorosilicate (magnesium/sodium) (INCI name “MAGNESIUM SODIUM FLUOROSILICATE”: International Cosmetic Ingredient Dictionary and Handbook , 14th ed., vol. 2, CTFA, 2012, p.1800), synthetic aluminum silicate (INCI name 「ALUMINUM SILICATE」: International Cosmetic Ingredient Dictionary and Handbook, 14th ed., vol. 1, CTFA, 2012, p.156) and the like.

As a commercial item of the said synthetic silicate and the derivative of a synthetic silicate, the Lockwood company make, brand name "Laponite XLG", a brand name "Laponite XL21", etc. are mentioned, for example.

In one embodiment of the present invention, the component A is preferably at least one type of clay mineral selected from the group consisting of a smectite group clay mineral, a synthetic silicate, and a derivative of a synthetic silicate. This is because the smectite group clay mineral, synthetic silicate, and derivatives of synthetic silicate have a property of swelling in water to form a colloidal form, and when applied to hair, the powder is unlikely to float (a state in which a white powder appears). On the other hand, other clay minerals (for example, kaolin blended in the hairdressing agent described in Patent Document 1) tend to be relatively easy to float when applied to hair.

1.0 mass % or more is preferable with respect to 100 mass % of hair dressing composition which concerns on one Embodiment of this invention, as for the lower limit of content of the said component A, 2.0 mass % or more is more preferable, 3.0 mass % or more is still more preferable do. 20.0 mass % or less is preferable with respect to 100 mass % of hair dressing composition which concerns on one Embodiment of this invention, as for the upper limit of content of the said component A, 12.0 mass % or less is more preferable, 8.0 mass % or less is still more preferable do. A matte texture can be more fully provided as the said content is 1.0 mass % or more. Moreover, when the said content is 20.0 mass % or less, the viscosity of a formulation will become a more suitable range, and stability of a formulation will increase.

[Component B: polyphosphoric acid or its salt]

Component B is polyphosphoric acid or its salt. Polyphosphoric acid is a compound formed by condensing two or more phosphoric acids. The hair dressing composition which concerns on one Embodiment of this invention WHEREIN: Component B has a role which suppresses the increase of the viscosity by a clay mineral. As for the component B, only 1 type may be used and may use 2 or more types together.

The present inventors have found, surprisingly, that polyphosphoric acid or a salt thereof suppresses an increase in viscosity due to a clay mineral. This mechanism has not been elucidated in detail. However, it is estimated that the effect is not merely due to the function as a chelating agent (refer to Comparative Examples 2 and 3 to be described later).

The polymerization degree of polyphosphoric acid should just be 2 or more, for example, it is 2 or more and 10 or less. As polyphosphoric acid, tripolyphosphoric acid, hexametaphosphoric acid, pyrophosphoric acid, trimetaphosphoric acid, tetrametaphosphoric acid, cyclopolyphosphoric acid etc. are mentioned, for example. As these salts, alkali metal salts, such as a sodium salt and potassium salt, etc. are mentioned.

0.01 mass % or more is preferable with respect to 100 mass % of hair dressing composition which concerns on one Embodiment of this invention, as for the lower limit of content of the said component B, 0.02 mass % or more is more preferable, 0.1 mass % or more is still more preferable do. 3.0 mass % or less is preferable with respect to 100 mass % of hair dressing composition which concerns on one Embodiment of this invention, as for the upper limit of content of the said component B, 2.0 mass % or less is more preferable, 1.5 mass % or less is still more preferable and 1.0 mass % or less is still more preferable. When the content is 0.01 mass% or more, it is possible to more sufficiently suppress an increase in the viscosity due to the clay mineral. It is preferable from a safety viewpoint that the said content is 3.0 mass % or less. Moreover, when the said content exceeds 3.0 mass %, it is hard to raise the inhibitory effect of the viscosity increase resulting from a clay mineral.

[Component C: Water]

Component C is water. Although component C is not specifically limited, Purified water is preferable. 20.0 mass % or more is preferable with respect to 100 mass % of hair dressing composition which concerns on one Embodiment of this invention, as for the lower limit of content of the component C, 25.0 mass % or more is more preferable, 30.0 mass % or more is still more preferable . 95.0 mass % or less is preferable with respect to 100 mass % of hair dressing composition which concerns on one Embodiment of this invention, as for the upper limit of content of component C, 90.0 mass % or less is more preferable, 85.0 mass % or less is still more preferable .

[Optional Ingredients]

The hair dressing composition which concerns on one Embodiment of this invention may contain components (other components) other than components A-C according to a dosage form etc. within the range which does not impair the effect of this invention. It does not specifically limit as said other component, For example, the component etc. normally used for cosmetics and quasi-drugs are mentioned. Specifically, For example, Lower alcohols, such as ethanol; oily components such as polyhydric alcohols, higher alcohols, silicone oils, ester oils, lead (wax), vegetable oils, hydrocarbon waxes, hydrocarbon oils, oils and fats, and higher fatty acids; thickeners such as carboxyvinyl polymer, acrylic acid, and alkyl methacrylate copolymer; Surfactants; Spices; UV absorbers; antioxidants; sequestering agents; film-forming high molecular compounds such as polyvinylpyrrolidone; powders such as kaolin, silica and talc; pigment; pigment; dyes; vitamins; amino acids; astringent; whitening agent; animal and plant extracts; Mountain; alkali and the like.

[Formulation and manufacturing method]

The dosage form of the hair dressing composition which concerns on one Embodiment of this invention is not specifically limited. As an example, the formulation of the composition is a gel, wax or aqueous pomade.

[Gel]

A gel is, for example, a high-viscosity water-based hair dressing agent in which a gel skeleton by a thickener is formed, and hair is fixed and hair-set with a film-forming polymer or the like. When the hair dressing composition which concerns on one Embodiment of this invention is a gel, it is preferable to add a film formation polymer, polyhydric alcohol, a thickener, alcohol, and a pH adjuster in addition to components A-C. Moreover, the said hair dressing composition may contain surfactant, a fragrance|flavor, and the preservative.

[wax]

A wax agent is, for example, O/W emulsification of a solid oily component (lead (wax), hydrocarbon, etc.) with a surfactant, and a creamy emulsification in which hair is fixed and hair-set by the adhesive force derived from the solid oily component. It's a hair straightener When the hair dressing composition which concerns on one Embodiment of this invention is a wax agent, in addition to components A-C, it is preferable to contain an oily component and surfactant. Moreover, the said hair dressing composition may contain the higher fatty acid, higher alcohol, polyhydric alcohol, alcohol, and the thickener.

[Water-Based Pomade]

The water-based pomade agent is, for example, a gel-like water-based hair dressing agent in which a gel skeleton by a highly blended surfactant is formed, and hair is fixed and hair-set by the adhesive force derived from the surfactant. When the hair dressing composition which concerns on one Embodiment of this invention is an aqueous pomade agent, in addition to components A-C, it is preferable to contain surfactant and polyhydric alcohol. Moreover, the said hair dressing composition may contain the film formation polymer, the oil component, the pH adjuster, alcohol, and the fragrance|flavor.

The hair dressing composition which concerns on one Embodiment of this invention can be manufactured according to a conventional method.

[Usage]

Although the use of the hair dressing composition of this invention is not specifically limited, For example, in addition to fixing and setting hair, you may use in order to improve the touch, texture, etc. of hair.

Moreover, use as a hair dressing composition of the following component A, component B, and component C is also contained in one Embodiment of this invention;

Component A: clay mineral

Component B: polyphosphoric acid or a salt thereof, and

Component C: Water.

Moreover, the manufacturing method which manufactures the hair dressing composition containing the following component A, component B, and component C which has a process of mixing the following component A, component B, and component C is also included in one Embodiment of this invention;

Component A: clay mineral

Component B: polyphosphoric acid or a salt thereof, and

Component C: Water.

In addition, for "use" and "manufacturing method" which concerns on one Embodiment of this invention, each description of the above-mentioned [form for carrying out the invention] can be used suitably.

The contents described in each of the above items can be appropriately referred to in other items as well. The present invention is not limited to each of the above-described embodiments, and various modifications are possible within the scope shown in the claims. Accordingly, embodiments obtained by appropriately combining technical means disclosed in other embodiments are also included in the technical scope of the present invention.

All of the academic documents and patent documents described in this specification are incorporated as a reference in this specification.

The hair dressing composition which concerns on one aspect of this invention includes the following inventions.

(1) Hair dressing composition containing the following component A, component B, and component C;

Component A: clay mineral

Component B: polyphosphoric acid or a salt thereof, and

Component C: Water.

(2) Content of the said component A is 1.0 mass % - 20.0 mass % with respect to 100 mass % of the said hair dressing composition,

The hair dressing composition as described in (1) whose content of the said component B is 0.01 mass % - 3.0 mass % with respect to 100 mass % of the said hair dressing composition.

(3) The hair dressing composition according to (1) or (2), wherein the component A is at least one type of clay mineral selected from the group consisting of a smectite group clay mineral, a synthetic silicate, and a derivative of a synthetic silicate.

Example

Hereinafter, the present invention will be described in more detail by way of Examples, but the present invention is not limited to the following Examples only. In addition, the compounding quantity and content in a following Example and a comparative example are the quantity (mass %) converted into the pure part.

[Evaluation items]

(Joseon's right or wrong)

The following reference|standard evaluated the right or wrong of preparation when the hair dressing composition which concerns on Tables 1-4 was prepared by the usual method.

A: The hair dressing composition was able to be prepared without a problem.

Impossibility: It thickened too much and the hair dressing composition could not be prepared, or the formulation became non-uniform|heterogenous at the time of combining each component and could not be prepared.

(matte feeling)

After taking 1.5 g of the obtained hair dressing composition on the palm and spreading it on the palm, it apply|coated to the cut wig (the Yukari Japan company make, brand name "A-386"), and hairdressed it. The hair of the wig immediately after hair-setting was visually observed, and the following reference|standard evaluated "matte feeling". In addition, evaluation of the matte feeling was not performed about the thing which the evaluation result of the said "preparation is impossible" was impossible.

<evaluation standard of a feeling of mat>

++: Almost no gloss is produced on the hair, and a sufficient matte feeling is provided.

+: The hair is slightly shiny, but a sufficient matte feeling is provided.

-: The hair is shiny and the matte feeling is not provided.

[Examples 1 to 9, Comparative Examples 1 to 3]

According to the composition of Table 1, according to the conventional method, the hair dressing composition (gel) which concerns on Examples 1-9 and Comparative Examples 1-3 was prepared.

In Table 1, the detail of each component is as follows.

・Bentonite: manufactured by Nippon Yukinendo, trade name “Bengel”

・Saponite: Manufactured by Kunimine Kogyo, trade name “Sumekuton SA”

・Silicic acid (Na/Mg): manufactured by Rockwood Additives Limited, trade name “Laponite XLG”

・Fluorosilicate (Na/Mg): manufactured by Rockwood Additives Limited, trade name “Laponite XL21”

・Na tripolyphosphate: manufactured by Yoneyama Chemical Industries, Ltd., trade name “sodium tripolyphosphate”

・Na hexametaphosphate: manufactured by Daihei Chemical Industries, trade name “Ultrapolin”

・Na pyrophosphate: manufactured by Yoneyama Chemical Industries, Ltd., trade name “sodium pyrophosphate (anhydrous)”

・Disodium edetate: manufactured by Akzo Nobel, trade name “Dissolvin NA2-S”

・Sodium erythorbate: manufactured by Fuso Chemical Industries, Ltd., trade name “Lbeat N”

-Carbomer: The LUBRIZOL company make, a brand name "CARBOPOL 980 POLYMER".

[Table 1]

[Examples 10-13, Comparative Example 4]

According to the composition of Table 2, according to the conventional method, the hair dressing composition (wax) which concerns on Examples 10-13 and the comparative example 4 was prepared.

In Table 2, the detail of each component is as follows. In addition, about the component similar to Table 1, description is abbreviate|omitted.

・Carnauba nap: manufactured by Toa Kasei, trade name "TOWAX-1F8"

・Microcrystalline wax: manufactured by Nippon Seiro, trade name “HI-MIC-1090”

・Mineral oil: manufactured by Sonneborn Inc., trade name “CARNATION”

・Cyclopentasiloxane: Momentive Performance Materials Japan Kodo Co., Ltd., trade name “TSF405”

· Seteth-20: Croda Singapore Pte Ltd. Manufacture, brand name "SP bridge C20 MBAL-PA-(SG)"

・Sodium dioleth-8 phosphate: manufactured by Nippon Surfactant Kogyo, trade name “NIKKOL DOP-8NV”

・Sorbitan stearate: manufactured by EVONIK NUTRITION & CARE GMBH, trade name “TEGO SMS”

・Ethylhexyl palmitate: manufactured by Koyo Fine Chemicals, trade name “Kyoyo POC”

- PEG-40 hydrogenated castor oil: Aoki Yushi Kogyo Co., Ltd. make, brand name "Brunon RCW-40".

(Table 2)

[Example 14]

According to the composition of Table 3, according to the conventional method, the hair dressing composition (aqueous pomade) concerning Example 14 was prepared.

In Table 3, the detail of each component is as follows. In addition, about the same component as Table 1 or 2, description is abbreviate|omitted.

- Seteth-40: Aoki Yushi company make, brand name "Brunon CH-340".

(Table 3)

[result]

In Examples 1-9 containing components A-C, the increase in the viscosity resulting from a clay mineral was suppressed, and the hair dressing composition (gel) was able to be prepared. On the other hand, although component A and C were contained, in Comparative Examples 1-3 which do not contain component B, a viscosity became high too much and the hair dressing composition (gel) was not able to be prepared.

Similarly, in Examples 10-13 and 14 containing components A-C, the increase in the viscosity resulting from a clay mineral was suppressed, and the hair dressing composition (wax and water-based pomade) was able to be prepared. On the other hand, although the component A and the component C were contained, in the comparative example 4 which does not contain the component B, the hair dressing composition (wax) was not able to be prepared.

It turns out that the increase in the viscosity resulting from the component A (clay mineral) is suppressed and preparation of a hair dressing composition is attained by containing the component B from the above point.

Moreover, in Comparative Examples 2 and 3, although a chelating agent was mix|blended instead of polyphosphoric acid, the increase in the viscosity of the formulation resulting from a clay mineral could not be suppressed.

(Formulation Example 1: Hair gel)

bentonite 3.0 mass% Tripolyphosphate pentasodium 0.3 mass% carboxyvinyl polymer 0.2 mass% triethanolamine appropriate amount glycerin 6.0 mass % ethanol 15.0 mass% (hydroxyethyl acrylate/methoxyethyl acrylate) copolymer 1.0 mass% Spices appropriate amount water balance Sum 100.0 mass %.

(Formulation Example 2: Hair wax)

bentonite 4.0 mass% Tripolyphosphate pentasodium 0.4 mass% mineral oil 2.0 mass% ethylhexyl palmitate 5.0 mass% wax 4.0 mass% castor oil 4.0 mass% Dioleth-8 Sodium Phosphate 4.0 mass% Seteth-20 4.0 mass% PEG-40 Hydrogenated Castor Oil 3.0 mass% glycerin 2.0 mass% stearyl alcohol 1.0 mass% ketoglutaric acid 0.2 mass% citric acid appropriate amount Phenoxyethanol appropriate amount Spices appropriate amount water balance Sum 100.0 mass %.

(Formulation Example 3: Hair Wax)

bentonite 3.0 mass% Tripolyphosphate pentasodium 0.3 mass% mineral oil 2.0 mass% dimethicone 5.0 mass% ethylhexyl palmitate 5.0 mass% microcrystalline wax 8.0 mass% carnauba nap 4.0 mass% Dioleth-8 Sodium Phosphate 4.0 mass% Seteth-20 4.0 mass% Isopentyldiol 5.0 mass% glycerin 2.0 mass% stearyl alcohol 1.0 mass% diatomaceous earth 5.0 mass% ketoglutaric acid 0.02 mass% citric acid appropriate amount sodium benzoate appropriate amount Spices appropriate amount water balance Sum 100.0 mass %.

(Formulation Example 4: Hair Wax)

bentonite 5.0 mass% Tripolyphosphate pentasodium 0.3 mass% mineral oil 10.0 mass% dimethicone 5.0 mass% ethylhexyl palmitate 5.0 mass% microcrystalline wax 8.0 mass% carnauba nap 4.0 mass% Sorbitan Stearate 3.0 mass% Seteth-20 3.0 mass% stearyl alcohol 1.5 mass% glycerin 2.0 mass% stearic acid appropriate amount triethanolamine appropriate amount carboxyvinyl polymer 0.3 mass% Spices appropriate amount water balance Sum 100.0 mass %.

(Formulation Example 5: Aqueous Pomade)

bentonite 6.0 mass % Tripolyphosphate pentasodium 0.5 mass% Seteth-40 25.0 mass% Seteth-20 5.0 mass% diglycerin 6.0 mass % sodium benzoate appropriate amount (hydroxyethyl acrylate/methoxyethyl acrylate) copolymer 4.0 mass% Spices appropriate amount citric acid appropriate amount trisodium citrate appropriate amount water balance Sum 100.0% by mass.

Industrial Applicability

This invention can be used for a hair dressing composition.

Claims (3)

Hair dressing composition containing the following component A, component B, and component C;
Component A: clay mineral
Component B: polyphosphoric acid or a salt thereof, and
Component C: Water. The method of claim 1,
Content of the said component A is 1.0 mass % - 20.0 mass % with respect to 100 mass % of the said hair dressing composition,
The hair dressing composition whose content of the said component B is 0.01 mass % - 3.0 mass % with respect to 100 mass % of the said hair dressing composition. 3. The method of claim 1 or 2,
The hair dressing composition wherein the component A is at least one type of clay mineral selected from the group consisting of a smectite group clay mineral, a synthetic silicate, and a derivative of a synthetic silicate.