JP5897803B2 - Creamy skin cleanser - Google Patents
Creamy skin cleanser Download PDFInfo
- Publication number
- JP5897803B2 JP5897803B2 JP2011027326A JP2011027326A JP5897803B2 JP 5897803 B2 JP5897803 B2 JP 5897803B2 JP 2011027326 A JP2011027326 A JP 2011027326A JP 2011027326 A JP2011027326 A JP 2011027326A JP 5897803 B2 JP5897803 B2 JP 5897803B2
- Authority
- JP
- Japan
- Prior art keywords
- glyceryl
- acid
- skin cleanser
- creamy
- creamy skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 235000014113 dietary fatty acids Nutrition 0.000 claims description 24
- 239000000194 fatty acid Substances 0.000 claims description 24
- 229930195729 fatty acid Natural products 0.000 claims description 24
- -1 fatty acid salt Chemical class 0.000 claims description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 8
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 8
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical group CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 8
- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 229940075529 glyceryl stearate Drugs 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- LDDUCKDUDZVHLN-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C LDDUCKDUDZVHLN-UHFFFAOYSA-N 0.000 claims description 5
- KJYGRYJZFWOECQ-UHFFFAOYSA-N [2-hydroxy-3-[2-hydroxy-3-[2-hydroxy-3-(16-methylheptadecanoyloxy)propoxy]propoxy]propyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)COCC(O)COC(=O)CCCCCCCCCCCCCCC(C)C KJYGRYJZFWOECQ-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- QHZLMUACJMDIAE-UHFFFAOYSA-N 1-monopalmitoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 claims description 4
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- 238000002156 mixing Methods 0.000 claims 2
- 239000002537 cosmetic Substances 0.000 description 20
- 230000000694 effects Effects 0.000 description 16
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- 239000006260 foam Substances 0.000 description 12
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- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
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- 230000000052 comparative effect Effects 0.000 description 4
- 230000001815 facial effect Effects 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
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- 239000003205 fragrance Substances 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 229940074052 glyceryl isostearate Drugs 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
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- 239000011538 cleaning material Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
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- 239000000049 pigment Substances 0.000 description 3
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 2
- OVRNDRQMDRJTHS-UHFFFAOYSA-N N-acelyl-D-glucosamine Natural products CC(=O)NC1C(O)OC(CO)C(O)C1O OVRNDRQMDRJTHS-UHFFFAOYSA-N 0.000 description 2
- OVRNDRQMDRJTHS-FMDGEEDCSA-N N-acetyl-beta-D-glucosamine Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O OVRNDRQMDRJTHS-FMDGEEDCSA-N 0.000 description 2
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- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
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- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 229940124274 edetate disodium Drugs 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- OYHQOLUKZRVURQ-AVQMFFATSA-N linoelaidic acid Chemical compound CCCCC\C=C\C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-AVQMFFATSA-N 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Description
本発明はクリーム状皮膚洗浄料に関し、更に詳しくは、泡立ち、泡質に優れ、メイクアップ化粧料に対するクレンジング効果、洗浄後の使用感に優れたクリーム状皮膚洗浄料に関するものである。 The present invention relates to a creamy skin cleanser, and more particularly to a creamy skin cleanser with excellent foaming and foam quality, a cleansing effect for makeup cosmetics, and an excellent feeling after use.
メイクアップ化粧料は、顔料や色素などの光学的散乱効果を用いて、美しい肌色を演出し、色素沈着などの皮膚トラブルなどを目立たせなくする目的で使用されている。その為、皮脂や汗などによる化粧崩れにより光学的な効果が損なわれないようにワックスや耐水性・耐油性油脂等が使用されている。しかしながら、この様なワックスや油脂類の使用は、これらメイクアップ化粧料を取り去る際に大きな障害となり、メイクアップ化粧料を落とす場合には、予め油脂成分を多く含有する油性クレンジング化粧料でワックスや油脂類を相溶させて除去した後に、水性洗顔料で残りの成分やクレンジング化粧料を洗い落とす2度洗いによる洗顔方法が長い間行われてきた。 Makeup cosmetics are used for the purpose of producing a beautiful skin color and making skin troubles such as pigmentation inconspicuous by using optical scattering effects such as pigments and pigments. For this reason, wax, water-resistant / oil-resistant oils and the like are used so that optical effects are not impaired by makeup collapse due to sebum or sweat. However, the use of such waxes and fats and oils is a major obstacle when removing these makeup cosmetics, and when removing the makeup cosmetics, wax or oily cleansing cosmetics that contain a large amount of fat components in advance. After washing and removing fats and oils, a face washing method by washing twice in which the remaining components and cleansing cosmetics are washed away with an aqueous facial cleanser has been performed for a long time.
しかしながら、時間的に余裕が無くなってきている現代社会においては、この様な洗顔方法は好まれず、より簡便な方法でメイク落としを行える方法が望まれ、例えば、水性洗顔料の機能の一部を犠牲にして、簡便性に対応した商品が開発されてきた。その犠牲とされた機能としては、起泡性や洗い上がりのさっぱり感などである。一般に水性洗顔料は石鹸を主成分としているが、油脂類を配合することにより、メイクアップ化粧料により顔部に付着したワックスや油性成分を除去するメカニズムで油脂類が配合されてきた。しかしながら、水性洗顔料に配合した油脂類が洗浄成分の界面活性能力を著しく損なわれるため、起泡性と洗い上がりのさっぱり感において不十分な機能となっている。そのため水溶性洗顔料においては、従来の基本機能を犠牲することなく簡便にメイク落ちが実現でき、使用感触においても優れた洗浄技術の開発が望まれていた。 However, in the modern society where time is running out, such a face washing method is not preferred, and a method that can remove makeup by a simpler method is desired. For example, part of the function of an aqueous facial cleanser At the expense of products, products that are easy to use have been developed. The sacrificial functions include foaming and freshness after washing. In general, aqueous facial cleansers are mainly composed of soap, but by incorporating oils and fats, oils and fats have been incorporated by a mechanism that removes wax and oily components adhering to the face by makeup cosmetics. However, since the fats and oils blended in the water-based face wash significantly impairs the surface-active ability of the cleaning component, it has an insufficient function in terms of foaming properties and a refreshing feeling after washing. Therefore, in water-soluble facial cleansers, it has been desired to develop a cleaning technique that can easily remove makeup without sacrificing conventional basic functions and that is excellent in use feeling.
そこでこれらの課題を解決する方法として、水性洗浄成分と吸油性粉体とを含有することを特徴とするメーク落とし(例えば、特許文献1参照。)が提案されている。しかしながら、特許文献1に記載されるメーク落としは、無水ケイ酸等の吸油性粉体を10%以上配合するために硬いクリーム状となり、延びが悪く皮膚へ塗布しにくく、また洗い上がりはさっぱり感あるものの皮膚にゴワつきを生じ、仕上がり感触が好ましくないという欠点があり、また皮膚を傷つけ、使用時に刺激感や痛みを感じ、過度の脱脂により肌荒れが生じるなどといった問題を有していた。またN−アシル化アミノ酸塩で被覆したヒドロキシアパタイトと、カオリン、タルク、マイカ、ベントナイト、モンモリロナイト、サポナイト、ヘクトライト選ばれる1種以上の粘土鉱物を含有してなる皮膚洗浄用化粧料(例えば、特許文献2参照。)が提案されている。特許文献2に記載される皮膚洗浄用化粧料は、上記の皮膚に対する刺激は緩和されているものの、原料コストが高いこと、またメイク落ち効果を高めるためには多量の粘土鉱物を配合する必要があり、洗い上がりはさっぱり感あるものの皮膚にゴワつきを生じ、仕上がり感触が好ましくないという欠点があり、これらの発明は十分満足すべきレベルに至っていなかった。 Therefore, as a method for solving these problems, make-up removal (see, for example, Patent Document 1) characterized by containing an aqueous cleaning component and an oil-absorbing powder has been proposed. However, the make-up remover described in Patent Document 1 becomes a hard cream because it contains 10% or more of an oil-absorbing powder such as silicic acid anhydride, and does not spread easily and is difficult to apply to the skin. However, some skins are irritated, resulting in an unfavorable finish, and there are problems such as hurting the skin, feeling irritation and pain during use, and rough skin due to excessive degreasing. A skin cleansing cosmetic comprising hydroxyapatite coated with an N-acylated amino acid salt and one or more clay minerals selected from kaolin, talc, mica, bentonite, montmorillonite, saponite, hectorite (for example, patents) Reference 2) has been proposed. Although the skin cleansing cosmetic described in Patent Document 2 has alleviated irritation to the above skin, the raw material cost is high, and a large amount of clay mineral needs to be blended in order to enhance the makeup removal effect. However, although the skin feels refreshing, the skin is irritated and the finish feel is unfavorable, and these inventions have not reached a satisfactory level.
本発明は上記実情に鑑みてなされたものであり、皮膚洗浄料としての泡立ちや泡質を損なわず、メイクアップ化粧料に対するクレンジング効果を両立し、かつ洗浄後に肌がつっぱらず、さっぱりとした使用感を有するクリーム状皮膚洗浄料を提供することを技術的課題とするものである。 The present invention has been made in view of the above circumstances, does not impair foaming and foam quality as a skin cleanser, has both a cleansing effect for makeup cosmetics, and does not have a tight skin after washing, and is used refreshingly It is an object of the present invention to provide a creamy skin cleanser having a feeling.
本発明者は、上記実状に鑑み鋭意検討を重ねた結果、高級脂肪酸塩を主成分とする洗浄料において、特定のIOB値を有するトリエチルヘキサノイン、トリ(カプリル/カプリン 酸)グリセリル、ステアリン酸グリセリル、パルミチン酸グリセリル、イソステアリン酸 グリセリル、ジイソステアリン酸トリグリセリル、ジイソステアリン酸ジグリセリルから 選ばれる1種又は2種以上の油剤又は非イオン性界面活性剤と、カオリン、マイカ、タルク、結晶セルロース、炭酸カルシウムから選ばれる1種以上の吸油性粉体とを組み合わせて配合することにより、高級脂肪酸塩の泡立ちや泡質を損なわずにメイクアップ化粧料に対するクレンジング効果、洗浄後の使用感に優れたクリーム状皮膚洗浄料が得られることを見出し、本発明を完成するに至った。
As a result of intensive studies in view of the above situation, the present inventor has found that triethylhexanoin, tri (capryl / capric acid) glyceryl, glyceryl stearate having a specific IOB value in a cleaning material mainly composed of a higher fatty acid salt. , Glyceryl palmitate, glyceryl isostearate, triglyceryl diisostearate, diglyceryl diisostearate, or one or more oil agents or nonionic surfactants, and kaolin, mica, talc, crystalline cellulose, calcium carbonate By combining with one or more selected oil-absorbing powders, creamy skin with a cleansing effect on makeup cosmetics and a feeling of use after washing without impairing foaming or foam quality of higher fatty acid salts. Finding that a cleaning material can be obtained and completing the present invention Led was.
即ち、本発明は、下記成分(A)〜(C):
(A)炭素原子数8〜22の高級脂肪酸塩
(B)IOB値が0.2以上0.7未満のトリエチルヘキサノイン、トリ(カプリル/カ プリン酸)グリセリル、ステアリン酸グリセリル、パルミチン酸グリセリル、イソステア リン酸グリセリル、ジイソステアリン酸トリグリセリル、ジイソステアリン酸ジグリセリ ルから選ばれる1種又は2種以上
(C)カオリン、マイカ、タルク、結晶セルロース、炭酸カルシウムから選ばれる1種又は2種以上の吸油性粉体
を含有し、且つ成分(B)の配合量が全組成物中の3〜15質量%であることを特徴とす るクリーム状皮膚洗浄料である。
That is, the present invention includes the following components (A) to (C):
(A) Higher fatty acid salt having 8 to 22 carbon atoms
(B) IOB value of 0.2 to 0.7 less triethylhexanoin, tri (caprylic / capric acid) glyceryl, glyceryl stearate, palmitate, glyceryl isostere phosphoric acid glyceryl diisostearate triglyceryl diisostearate Jiguriseri One or more selected from the above (C) One or more oil-absorbing powders selected from kaolin, mica, talc, crystalline cellulose, calcium carbonate
It contains, and the amount of component (B) is a creamy skin cleanser you characterized in that 3 to 15% by weight of the total composition.
本発明のクリーム状皮膚洗浄料は、皮膚洗浄料としての泡立ちや泡質に優れ、メイクアップ化粧料に対するクレンジング効果、洗浄後に肌がつっぱらず、さっぱりとした使用感を有するものである。 The creamy skin cleansing material of the present invention is excellent in foaming and foam quality as a skin cleaning material, has a cleansing effect on makeup cosmetics, has a refreshed feeling of use because the skin does not become tight after washing.
以下、本発明の構成について詳述する。本発明のクリーム状皮膚洗浄料に用いられる成分(A)炭素原子数8〜22の高級脂肪酸塩において、高級脂肪酸としては炭素数原子数8〜22のものが用いられ、飽和又は不飽和、直鎖状又は分岐鎖状のいずれでも構わない。具体的には、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、アラキドン酸、ベヘン酸、イソステアリン酸、オレイン酸、2−パルミトレイン酸、ペトロセリン酸、オレイン酸、エライジン酸、リシノール酸、リノール酸、リノエライジン酸、リノレン酸、アラキドン酸や、その他にヤシ油脂肪酸、パーム核油脂肪酸、牛脂脂肪酸等の混合脂肪酸も用いることができる。 Hereinafter, the configuration of the present invention will be described in detail. In the component (A) higher fatty acid salt having 8 to 22 carbon atoms used in the creamy skin cleanser of the present invention, a higher fatty acid having 8 to 22 carbon atoms is used, saturated or unsaturated, straight Either a chain or a branched chain may be used. Specifically, lauric acid, myristic acid, palmitic acid, stearic acid, arachidonic acid, behenic acid, isostearic acid, oleic acid, 2-palmitoleic acid, petrothelic acid, oleic acid, elaidic acid, ricinoleic acid, linoleic acid, lino Elaidic acid, linolenic acid, arachidonic acid, and mixed fatty acids such as coconut oil fatty acid, palm kernel oil fatty acid, and beef tallow fatty acid can also be used.
またこれら高級脂肪酸の対イオンの塩基としては、ナトリウム、カリウム、マグネシウム等の無機塩基、アンモニウム、モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、2−アミノ−2−メチルプロパノール、2−アミノ−2−メチルプロパンジオール等のアルカノールアミン、リジン、アルギニン等の塩基性アミノ酸等が挙げられ、中でもアルカリ金属塩が特に好ましく用いられる。 In addition, as a base of a counter ion of these higher fatty acids, inorganic bases such as sodium, potassium and magnesium, ammonium, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methylpropanol, 2-amino-2-methyl Examples include alkanolamines such as propanediol, and basic amino acids such as lysine and arginine. Among them, alkali metal salts are particularly preferably used.
これらの炭素原子数8〜22の高級脂肪酸塩は、脂肪酸塩として配合しても、また脂肪酸と塩基とを独立に配合して処方系の中で脂肪酸塩を形成させてもよい。またこれらの高級脂肪酸塩は、一種単独又は二種以上を混合して用いてもよい。 These higher fatty acid salts having 8 to 22 carbon atoms may be blended as fatty acid salts, or fatty acids and bases may be blended independently to form fatty acid salts in the formulation system. These higher fatty acid salts may be used alone or in combination of two or more.
本発明のクリーム状皮膚洗浄料における成分(A)炭素原子数8〜22の高級脂肪酸塩の含有量は、クリーム状皮膚洗浄料の総量を基準として、好ましくは15〜60質量%であり、更に好ましくは20〜50質量%である。これは当該含有量の範囲において、優れた起泡力と洗浄作用を発揮し、クリーム状の性状を形成できるからである。 The content of the component (A) higher fatty acid salt having 8 to 22 carbon atoms in the creamy skin cleanser of the present invention is preferably 15 to 60% by mass based on the total amount of the creamy skin cleanser, and Preferably it is 20-50 mass%. This is because, within the range of the content, excellent foaming power and cleaning action can be exhibited, and cream-like properties can be formed.
本発明のクリーム状皮膚洗浄料に用いられる成分(B)は、IOB値が0.2以上0.7 未満であるトリエチルヘキサノイン、トリ(カプリル/カプリン酸)グリセリル、ステア リン酸グリセリル、パルミチン酸グリセリル、イソステアリン酸グリセリル、ジイソステ アリン酸トリグリセリル、ジイソステアリン酸ジグリセリルから選択される。ここでいうIOB値(Inorganic Organic Balance)とは、藤田穆の有機概念図によるもので、無機性及び有機性の値の比である。有機化合物の極性の指標であり、この数値が高いほど極性が高くなる。これら成分(B)のIOB値が0.2未満の場合は、洗浄剤により乳化されて起泡力や泡質が悪くなり好ましくなく、IOB値が0.7以上の場合は、皮膚に残留しているメイクアップ化粧料の油性成分等を溶解することができず、除去効果が悪いため良好なクレンジング効果が得られないため好ましくない。
Creamy skin cleanser to the ingredients used in the present invention (B) is Toriechiruhekisanoin IOB value is 0.2 or more and less than 0.7, tri (caprylic / capric acid) glyceryl, monostearate, palmitate glyceryl isostearate, Jiisosute Allyn triglyceryl, chosen from diglyceryl diisostearate. Here, the IOB value (Inorganic Organic Balance) is based on the organic conceptual diagram of Satoshi Fujita, and is the ratio of the inorganic and organic values. It is an index of the polarity of an organic compound, and the higher this value, the higher the polarity. When the IOB value of these components (B) is less than 0.2, it is not preferable because they are emulsified by a cleaning agent and the foaming power and foam quality deteriorate, and when the IOB value is 0.7 or more, they remain on the skin. It is not preferable because the oily component of the makeup cosmetics that are used cannot be dissolved and the removal effect is poor, and a good cleansing effect cannot be obtained.
本発明に用いられる成分(B)のIOB値を以下に示す。The IOB value of component (B) used in the present invention is shown below.
トリエチルヘキサノイン(IOB値0.35)Triethylhexanoin (IOB value 0.35)
トリ(カプリル/カプリン酸)グリセリル(IOB値0.33)Tri (capryl / capric acid) glyceryl (IOB value 0.33)
ステアリン酸グリセリル(IOB値0.47)Glyceryl stearate (IOB value 0.47)
パルミチン酸グリセリル(IOB値0.53)Glyceryl palmitate (IOB value 0.53)
イソステアリン酸グリセリル(IOB値0.63)Glyceryl isostearate (IOB value 0.63)
ジイソステアリン酸トリグリセリル(IOB値0.52)Triglyceryl diisostearate (IOB value 0.52)
ジイソステアリン酸ジグリセリル(IOB値0.42)Diglyceryl diisostearate (IOB value 0.42)
これらの中でも、常温(25℃)において液状の性状を示すトリエチルヘキサノイン、トAmong these, triethylhexanoin, which exhibits liquid properties at room temperature (25 ° C),
リ(カプリル/カプリン酸)グリセリル、イソステアリン酸グリセリルがメイクアップ化Li (capryl / capric acid) glyceryl and glyceryl isostearate make up
粧料の油性成分等を除去するクレンジング効果、洗浄後の皮膚感触やクリーム状皮膚洗浄Cleansing effect for removing oily components of cosmetics, skin feel after washing and creamy skin washing
料の保存安定性の点から好ましい。From the viewpoint of storage stability of the material.
本発明のクリーム状皮膚洗浄料における成分(B)の含有量は、クリーム状皮膚洗浄料のThe content of component (B) in the creamy skin cleanser of the present invention is the same as that of the creamy skin cleanser. 総量を基準として、3〜15質量%である。3質量%未満では、十分なクレンジング効果3 to 15% by mass based on the total amount. If it is less than 3% by mass, sufficient cleansing effect が得られない場合があり、15質量%を超えると、製剤ののびの悪さ、洗浄後のべたつきMay not be obtained, and if it exceeds 15% by mass, the formulation will not spread easily and will become sticky after washing. や保存安定性が悪くなる場合がある。And storage stability may deteriorate.
本発明のクリーム状皮膚洗浄料に用いられる成分(C)吸油性粉体は化粧料などに使用される粉体であって、吸油量が自重の10重量%以上である粉体を指し、カオリン、マイカ、タルク、結晶セルロース、炭酸カルシウムから選ばれる1種又は2種以上である。 The component (C) oil-absorbing powder used in the creamy skin cleanser of the present invention is a powder used in cosmetics and the like, and refers to a powder having an oil absorption of 10% by weight or more of its own weight. , Mica, talc, crystalline cellulose, or one or more selected from calcium carbonate.
本発明のクリーム状皮膚洗浄料における成分(C)吸油性粉体の含有量は、クリーム状皮膚洗浄料の総量を基準として、好ましくは0.1〜10質量%であり、更に好ましくは0.5〜5質量%である。0.1質量%未満では、十分なメイクアップ化粧料の除去効果が得られない場合があり、10質量%を超えると、使用時ののびの悪さ、洗浄後に皮膚への残留、保存安定性が悪くなる場合がある。 The content of the component (C) oil-absorbing powder in the creamy skin cleanser of the present invention is preferably 0.1 to 10% by mass, more preferably 0.8%, based on the total amount of the creamy skin cleanser. 5 to 5% by mass. If it is less than 0.1% by mass, a sufficient makeup cosmetic removal effect may not be obtained. If it exceeds 10% by mass, it will not spread well when used, remains on the skin after washing, and has storage stability. It may get worse.
本発明のクリーム状皮膚洗浄料に用いられる成分(D)多価アルコールは、脂肪酸石鹸の結晶状態の安定化効果を目的として配合され、また成分(B)の分散安定化を付与する目的で配合される。多価アルコールの具体例を例示すると、グリセリン、エチレングリコール、ポリエチレングリコール(平均分子量が10,000以下)、プロピレングリコール、ポリプロピレングリコール、イソプレングリコール、プロパンジオール、1,3−ブチレングリコール、ジプレピレングリコール、ジグリセリン、ポリグリセリン、トレハロース、グルコシルトレハロース、キシリトール、フルクトース、ラクトース、トリメチルグリシン、ソルビトール、マルチトール等が挙げられる。これら多価アルコールの中でもグリセリン、ポリエチレングリコール(平均分子量が10,000以下)、グルコシルトレハロース、ソルビトール、マルチトールが好ましい。これら多価アルコールは1種又は2種以上を組み合わせて使用しても良い。 The component (D) polyhydric alcohol used in the creamy skin cleanser of the present invention is blended for the purpose of stabilizing the crystalline state of the fatty acid soap, and blended for the purpose of providing dispersion stabilization of the component (B). Is done. Specific examples of polyhydric alcohols include glycerin, ethylene glycol, polyethylene glycol (average molecular weight of 10,000 or less), propylene glycol, polypropylene glycol, isoprene glycol, propanediol, 1,3-butylene glycol, and dipropylene glycol. , Diglycerin, polyglycerin, trehalose, glucosyl trehalose, xylitol, fructose, lactose, trimethylglycine, sorbitol, maltitol and the like. Among these polyhydric alcohols, glycerin, polyethylene glycol (average molecular weight is 10,000 or less), glucosyl trehalose, sorbitol, and maltitol are preferable. These polyhydric alcohols may be used alone or in combination of two or more.
本発明のクリーム状皮膚洗浄料における成分(D)多価アルコールの含有量は、クリーム状皮膚洗浄料の総量を基準として、好ましくは10〜50質量%、更に好ましくは15〜40質量%である。10質量%未満では、脂肪酸石鹸の結晶状態の安定化効果が十分に発揮されず、50質量%を超える場合は、逆に脂肪酸石鹸の溶解度が向上して不安定となり好ましくない。 The content of component (D) polyhydric alcohol in the creamy skin cleanser of the present invention is preferably 10 to 50% by weight, more preferably 15 to 40% by weight, based on the total amount of the creamy skin cleanser. . If it is less than 10% by mass, the effect of stabilizing the crystalline state of the fatty acid soap is not sufficiently exerted, and if it exceeds 50% by mass, the solubility of the fatty acid soap is improved and becomes unstable, which is not preferable.
本発明のクリーム状皮膚洗浄料の剤型は特に限定されるものではないが、使用時の塗布のしやすさ、製剤の保存安定性の観点からクリーム状あるいはペースト状などが好ましい。 The dosage form of the creamy skin cleanser of the present invention is not particularly limited, but a creamy or pastey form is preferred from the viewpoint of ease of application during use and storage stability of the preparation.
本発明のクリーム状皮膚洗浄料には、前記の必須成分に加えて必要に応じて本発明の効果を損なわない範囲で通常化粧料、医薬品等の皮膚外用剤に用いられている任意の成分を使用することが出来る。これらの成分としては、アニオン性界面活性剤、カチオン性界面活性剤、非イオン性界面活性剤、油分、高級アルコール、紫外線吸収剤、防腐剤、保湿剤、ポリマー類、パール光沢剤、アミノ酸誘導体、糖誘導体、香料、水、アルコール、増粘剤、色剤、金属イオン封鎖剤、酸化防止剤、薬剤、香料、各種ビタミン等の薬剤が挙げられる。 The creamy skin cleanser of the present invention contains, in addition to the essential components described above, optional components that are usually used in skin external preparations such as cosmetics and pharmaceuticals as long as the effects of the present invention are not impaired. Can be used. These components include anionic surfactants, cationic surfactants, nonionic surfactants, oils, higher alcohols, UV absorbers, preservatives, humectants, polymers, pearl brighteners, amino acid derivatives, Examples include sugar derivatives, fragrances, water, alcohol, thickeners, colorants, sequestering agents, antioxidants, drugs, fragrances, and various vitamins.
次に本発明を実施例に基づいて詳細に説明するが、これらに限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。なお、以下の処方の含有量において%と示したものは全て質量%のことである。 EXAMPLES Next, although this invention is demonstrated in detail based on an Example, it is not limited to these. Prior to the examples, test methods and evaluation methods employed in each example will be described. In addition, what was shown as% in content of the following prescriptions is mass%.
泡立ち、泡質、洗浄後の使用感
(評価方法)
専門パネラー10名により、実施例、比較例で調製した組成物を使用したときの泡立ちの良さ、泡質(泡のクリーミィーさ)の良さ、洗浄後の使用感(さっぱり感)について1点から5点の5段階の官能評価を行い、その平均点を求め、以下の基準で判定した。
(評価基準)
◎ :平均点が4.5以上
〇 :平均点が3.5以上、4.5未満
△ :平均点が2.5以上、3.5未満
× :平均点が1.5以上、2.5未満
××:平均点が1.5未満
Foaming, foam quality, feeling after washing (evaluation method)
By 10 expert panelists, 1 to 5 in terms of good foaming, good foam quality (foam creaminess) when using the compositions prepared in Examples and Comparative Examples, and feeling after use (freshness) The sensory evaluation of 5 steps | paragraphs of a point was performed, the average score was calculated | required, and the following references | standards determined.
(Evaluation criteria)
◎: Average score is 4.5 or more 〇: Average score is 3.5 or more and less than 4.5 △: Average score is 2.5 or more and less than 3.5 ×: Average score is 1.5 or more, 2.5 Less than xx: Average score is less than 1.5
メイクアップ化粧料に対するクレンジング効果
(評価方法)
下記に示す処方のリップカラーを上腕内側部に3cm×3cmの範囲に塗布し、10分間放置後、実施例、比較例で調製した組成物を少量の水と混合して泡立たせてから塗布し、良くなじませて擦過して流水で濯いだ。色彩色差計を用いてリップカラー塗布前の明度(E0)、リップカラー塗布後の明度(E1)、洗浄後の明度(E2)を計測し、下記式より洗浄率を算出した。
洗浄率(%)=100×(E0−E2)/(E0−E1)
Cleansing effect for makeup cosmetics (evaluation method)
Apply the lip color of the formula shown below to the inner side of the upper arm in the range of 3cm x 3cm, leave it for 10 minutes, mix the foamed composition prepared in Examples and Comparative Examples with a small amount of water, and apply. It was thoroughly rubbed and rubbed and rinsed with running water. Using a color difference meter, the brightness before applying the lip color (E 0 ), the brightness after applying the lip color (E 1 ), and the brightness after cleaning (E 2 ) were measured, and the cleaning rate was calculated from the following formula.
Washing rate (%) = 100 × (E 0 −E 2 ) / (E 0 −E 1 )
(リップカラー処方)
(1)ポリエチレン粉末 5%
(2)マイクロクリスタリンワックス 15%
(3)カルナウバワックス 10%
(4)モクロウ 5%
(5)固形パラフィン 5%
(6)重質流動パラフィン 5%
(7)グリセリルトリイソステアレート 5%
(8)ひまし油 20%
(9)ネオペンチルグリコールジイソオクタネート 20%
(10)顔料 10%
(Lip color prescription)
(1) Polyethylene powder 5%
(2) Microcrystalline wax 15%
(3) Carnauba wax 10%
(4) 5% Owl
(5) Solid paraffin 5%
(6) Heavy liquid paraffin 5%
(7) Glyceryl triisostearate 5%
(8) Castor oil 20%
(9) Neopentyl glycol diisooctanoate 20%
(10) 10% pigment
実施例1〜12、比較例1〜5
表1に示した処方のクリーム状皮膚洗浄料を調整し、前記各試験を実施した。その結果を表1に併せて示す。
Examples 1-12, Comparative Examples 1-5
The creamy skin cleanser having the formulation shown in Table 1 was prepared and the above tests were performed. The results are also shown in Table 1.
表1より明らかなように本発明の成分を用いた実施例のクリーム状皮膚洗浄料はいずれも優れた性能を有していた。一方、必須成分のいずれかを欠いた比較例では、泡立ちの良さ、泡質(泡のクリーミィーさ)の良さ、洗浄後の使用感(さっぱり感)、メイクアップ化粧料に対するクレンジング効果のいずれかの面で劣っており、本発明の目的を達成できなかった。 As is clear from Table 1, all of the creamy skin cleansing agents of Examples using the components of the present invention had excellent performance. On the other hand, in the comparative example lacking any of the essential ingredients, one of good foaming, good foam quality (foam creaminess), feeling after use (freshness), cleansing effect on makeup cosmetics It was inferior in the aspect, and the object of the present invention could not be achieved.
以下、本発明のクリーム状皮膚洗浄料のその他の処方例を実施例として挙げる。なお、これらの実施例のクリーム状皮膚洗浄料についても、上記の泡立ちの良さ、泡質(泡のクリーミィーさ)の良さ、洗浄後の使用感(さっぱり感)、メイクアップ化粧料に対するクレンジング効果について各項目を検討したところ、いずれの実施例においても、優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the creamy skin cleanser of the present invention will be given as examples. In addition, about the creamy skin cleansing agents of these examples, the above-mentioned good foaming, good foam quality (foam creaminess), feeling after use (freshness), cleansing effect on makeup cosmetics When each item was examined, all the examples had excellent characteristics and were good.
実施例13(クリーム状皮膚洗浄料)
(1)ミリスチン酸 28.0%
(2)ステアリン酸 5.0%
(3)水酸化カリウム 6.5%
(4)トリエチルヘキサノイン(IOB値0.35) 1.0%
(5)ステアリン酸グリセリル(IOB値0.47) 4.0%
(6)カオリン 3.0%
(7)マイカ 1.0%
(8)グリセリン 20.0%
(9)ヒマシ油 1.0%
(10)ヤシ油脂肪酸N−メチルエタノールアミン 1.0%
(11)エデト酸四ナトリウム 0.2%
(12)リン酸二水素ナトリウム 0.5%
(13)N−アセチルグルコサミン 0.1%
(14)ヤシ油脂肪酸メチルタウリンナトリウム 5.0%
(15)グリチルリチン酸ジカリウム 0.2%
(16)グルコシルトレハロース 1.0%
(17)緑茶抽出エキス 0.5%
(18)イソプロピルメチルフェノール 0.1%
(19)香料 0.3%
(20)精製水 残 部
Example 13 (Cream skin cleanser)
(1) Myristic acid 28.0%
(2) Stearic acid 5.0%
(3) Potassium hydroxide 6.5%
(4) Triethylhexanoin (IOB value 0.35) 1.0%
(5) Glyceryl stearate (IOB value 0.47) 4.0%
(6) Kaolin 3.0%
(7) Mica 1.0%
(8) Glycerin 20.0%
(9) Castor oil 1.0%
(10) Coconut oil fatty acid N-methylethanolamine 1.0%
(11) Edetate tetrasodium 0.2%
(12) Sodium dihydrogen phosphate 0.5%
(13) N-acetylglucosamine 0.1%
(14) Palm oil fatty acid methyl taurine sodium 5.0%
(15) Dipotassium glycyrrhizinate 0.2%
(16) Glucosyl trehalose 1.0%
(17) Green tea extract 0.5%
(18) Isopropyl methylphenol 0.1%
(19) Fragrance 0.3%
(20) Balance of purified water
(製法)
(1)、(2)、(20)の一部を80℃に加温し、(3)を加えて90℃で1時間中和反応を行う。冷却を開始し、70℃で(4),(5),(8)〜(14),(20)の残部を添加し、50℃で(6),(7),(15)〜(19)を加え、ホモミキサーにて分散する。次いで30℃まで冷却してクリーム状皮膚洗浄料調整した。
(Manufacturing method)
A part of (1), (2), and (20) is heated to 80 ° C., (3) is added, and a neutralization reaction is performed at 90 ° C. for 1 hour. Cooling was started, the remainder of (4), (5), (8) to (14), (20) was added at 70 ° C., and (6), (7), (15) to (19) were added at 50 ° C. ) And disperse with a homomixer. Next, it was cooled to 30 ° C. to prepare a creamy skin cleanser.
実施例14(クリーム状皮膚洗浄料)
(1)ミリスチン酸 30.0%
(2)パルミチン酸 5.0%
(3)イソステアリン酸 3.0%
(4)水酸化カリウム 7.8%
(5)ジイソステアリン酸トリグリセリル(IOB値0.52) 3.0%
(6)ジイソステアリン酸ジグリセリル(IOB値0.42) 3.0%
(7)パルミチン酸グリセリル(IOB値0.53) 3.0%
(8)タルク 1.5%
(9)炭酸カルシウム 1.5%
(10)グリセリン 25.0%
(11)プロピレングリコール 5.0%
(12)オリーブ油 3.0%
(13)ヤシ油脂肪酸ジエタノールアミド 3.0%
(14)ヤシ油脂肪酸グルタミン酸ナトリウム 3.0%
(15)リン酸一水素ナトリウム 0.2%
(16)N−アセチルグルコサミン 0.1%
(17)エデト酸二ナトリウム 0.2%
(18)グルコシルトレハロース 0.5%
(19)緑茶抽出エキス 0.5%
(20)香料 0.3%
(21)精製水 残 部
Example 14 (Cream skin cleanser)
(1) Myristic acid 30.0%
(2) Palmitic acid 5.0%
(3) Isostearic acid 3.0%
(4) Potassium hydroxide 7.8%
(5) Triglyceryl diisostearate (IOB value 0.52) 3.0%
(6) Diglyceryl diisostearate (IOB value 0.42) 3.0%
(7) Glyceryl palmitate (IOB value 0.53) 3.0%
(8) Talc 1.5%
(9) Calcium carbonate 1.5%
(10) Glycerin 25.0%
(11) Propylene glycol 5.0%
(12) 3.0% olive oil
(13) Palm oil fatty acid diethanolamide 3.0%
(14) Palm oil fatty acid sodium glutamate 3.0%
(15) Sodium monohydrogen phosphate 0.2%
(16) N-acetylglucosamine 0.1%
(17) Edetate disodium 0.2%
(18) Glucosyl trehalose 0.5%
(19) Green tea extract 0.5%
(20) Fragrance 0.3%
(21) Balance of purified water
(製法)
(1)〜(3)、(21)の一部を80℃に加温し、(4)を加えて90〜95℃で1時間中和反応を行う。冷却を開始し、80℃で(5)〜(7),(10)〜(14),(2
1)の残部を添加し、50℃で(8)、(9)、(15)〜(20)を加え、ホモミキサーにて分散する。次いで30℃まで冷却してクリーム状皮膚洗浄料調整した。
(Manufacturing method)
A part of (1) to (3) and (21) is heated to 80 ° C., (4) is added, and a neutralization reaction is performed at 90 to 95 ° C. for 1 hour. Cooling was started, and at 80 ° C., (5) to (7), (10) to (14), (2
Add the remainder of 1), add (8), (9), (15) to (20) at 50 ° C., and disperse with a homomixer. Next, it was cooled to 30 ° C. to prepare a creamy skin cleanser.
Claims (2)
(A)炭素原子数8〜22の高級脂肪酸塩
(B)IOB値が0.2以上0.7未満のトリエチルヘキサノイン、トリ(カプリル/カプリン酸)グリセリル、ステアリン酸グリセリル、パルミチン酸グリセリル、イソステアリン酸グリセリル、ジイソステアリン酸トリグリセリル、ジイソステアリン酸ジグリセリルから選ばれる1種又は2種以上
(C)カオリン、マイカ、タルク、結晶セルロース、炭酸カルシウムから選ばれる1種又は2種以上の吸油性粉体 The following components (A) to (C) are contained, and the blending amount of the component (B) is 3 to 15% by mass in the total composition , and the blending amount of the component (C) is 0.5 in the total composition. A creamy skin cleanser characterized by being ˜5% by mass .
(A) Higher fatty acid salt having 8 to 22 carbon atoms (B) Triethylhexanoin having an IOB value of 0.2 or more and less than 0.7, glyceryl tri (capryl / capric acid), glyceryl stearate, glyceryl palmitate, isostearin One or more kinds selected from glyceryl acid, triglyceryl diisostearate, diglyceryl diisostearate (C) one or more oil-absorbing powders selected from kaolin, mica, talc, crystalline cellulose, calcium carbonate
The creamy skin cleanser according to claim 1, further comprising (D) a polyhydric alcohol.
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JP2000309503A (en) * | 1999-04-28 | 2000-11-07 | Asahi Chem Ind Co Ltd | Liquid or creamy cosmetic containing cellulose fine particle |
JP2001055320A (en) * | 1999-08-18 | 2001-02-27 | Shiseido Co Ltd | Skin detergent |
JP2007261947A (en) * | 2004-06-25 | 2007-10-11 | Shiseido Co Ltd | Scrubbing agent composition and skin cosmetic comprising the same |
US7879789B2 (en) * | 2006-05-26 | 2011-02-01 | Shiseido Company Ltd. | Surfactant and composition containing the same |
JP2008007437A (en) * | 2006-06-28 | 2008-01-17 | Mandom Corp | Raw material of cosmetic and cosmetic containing the raw material |
JP2008239792A (en) * | 2007-03-27 | 2008-10-09 | Shigeko Takahashi | Manufacturing method of scrub agent-containing soap composition |
JP2009062309A (en) * | 2007-09-06 | 2009-03-26 | Mandom Corp | Cosmetic for cleansing skin |
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