JP5473238B2 - Non-aqueous warm skin cleansing composition - Google Patents

Description

  The present invention relates to a non-aqueous warm skin cleansing composition.

  Conventionally, as one of attempts to soften the skin and remove sebum dirt clogged in pores, means for imparting a thermal effect by mixing with water and improving the cleansing effect has been used. As those that impart such a thermal effect, the heat of hydration of alcohols and polyhydric alcohols is mainly used from the viewpoint of safety to the skin and mildness of heat generation.

  Specifically, non-aqueous cosmetics containing alcohol and sorbite ether (see, for example, Patent Document 1), gel-type thermal massage materials containing glycerin or diglycerin, an anionic polymer compound, and water (eg, patents) Means such as massage cosmetics (see, for example, Patent Document 3) containing a specific polyhydric alcohol, a scrub agent, and a water-soluble polymer compound have been proposed.

  However, when the heat of hydration of alcohols and polyhydric alcohols is used, there is a mild expression of warmth, and the heat generation time is short because it is easily mixed with water, making it difficult to obtain the desired warmth. There is. Moreover, in order to obtain an appropriate thermal feeling, it must be blended in a large amount, and there is a problem that it is inferior in use feeling such as a sticky feeling. In addition, there is also a problem that the adhesion to the skin during application is inferior.

  In addition, as compared with alcohols and polyhydric alcohols, an attempt has been made to use an inorganic salt that instantly exhibits a thermal effect when mixed with water. Specifically, cleansing pack cosmetics containing magnesium sulfate (see, for example, Patent Document 4), skin cosmetics containing exothermic agents and warming agents (see, for example, Patent Document 5), specific oils, and Means such as a non-aqueous cosmetic containing an inorganic salt and an activator (see, for example, Patent Document 6) have been proposed.

  However, when the heat of hydration of these inorganic salts is used, an excellent thermal effect can be obtained, but due to the nature, the dosage form must be a non-aqueous, so-called oil-based dosage form, resulting in a feeling of stickiness and the like. There is a problem of being inferior. There are also problems such as poor formulation stability during storage due to the separation of the oil and poor adhesion to the skin during application.

  On the other hand, as an effect required for a skin cleansing cosmetic, there is a feeling of use that can sufficiently realize the effect of removing sebum dirt, that is, a so-called refreshing refreshing feeling. Usually, in order to give such a feeling of use, a refreshing agent is mix | blended. However, there is a problem that even when a refreshing agent is added to the cosmetics having a thermal feeling due to the alcohols and polyhydric alcohols described above, the refreshing feeling exceeds the thermal feeling and a sufficient thermal feeling cannot be obtained. Moreover, even if it mix | blends with the cosmetics which have the thermal feeling by an inorganic salt, there exists a problem that a sticky feeling exceeds a refreshing feeling and is inferior to the actual feeling of the refreshing refreshing feeling after rinsing.

JP-A-6-80534 Japanese Patent Laid-Open No. 11-12126 JP 2000-247860 A Japanese Patent Laid-Open No. 7-173033 Japanese Patent Laid-Open No. 11-60460 JP-A-11-228332

  The present invention has been made in view of the prior art, and has excellent formulation stability, and has a non-heat-based warm skin that has both a warm feeling during washing and a refreshing refreshing feeling after rinsing. It is an object to provide a cleaning composition. It is another object of the present invention to provide a non-aqueous warm skin-cleaning composition that has good adhesion to the skin, exhibits an excellent sebum dirt removing effect, and improves the skin condition after use.

That is, the present invention
[1] containing (A) nonpolar oil, (B) exothermic agent, (C) clay mineral, (D) nonionic surfactant and (E) refreshing agent, (B) component is calcium chloride, At least one member selected from the group consisting of magnesium chloride, calcium sulfate and magnesium sulfate, and the component (C) is kaolin, talc, mica, dimethyl distearyl ammonium hectorite, benzyl dimethyl stearyl ammonium hectorite and dimethyl distearyl ammonium bentonite The content of the component (A) is 15 to 60% by weight, the content of the component (B) is 5 to 45% by weight, and the content of the component (C) Is 0.5 to 40% by weight, the content of component (D) is 3 to 13% by weight, and the content of component (E) is 0.3 to 1% by weight. Ri, nonaqueous warming skin cleansing composition characterized in that it is a paste,
[2] The non-aqueous warm skin cleansing composition according to [1], wherein the component (A) is liquid paraffin and / or decamethylcyclopentasiloxane ,
[3] In addition, contains (F) scrubbing agent, (F) content of the component for a non-aqueous warming skin cleansing according to the Ru 0.1 to 15 wt% der [1] or [2] Composition,
[ 4 ] The non-aqueous warm skin cleansing composition according to [ 3 ] above, wherein the component (F) is spherical polyethylene and / or crystalline cellulose, and [ 5 ] any one of [1] to [ 4 ] above It relates to a non-aqueous warm face cleanser comprising the non-aqueous warm skin cleansing composition described in 1.

  The non-aqueous warm skin cleansing composition of the present invention has excellent formulation stability and excellent adhesion to the skin. Moreover, at the time of washing | cleaning, while having a moderate thermal feeling, there exists an effect excellent in the sebum dirt removal effect. In addition, after rinsing, there is an effect of providing a smooth skin state and imparting a refreshing refreshing feeling.

  The non-aqueous warm skin cleansing composition of the present invention contains (A) nonpolar oil, (B) exothermic agent, (C) clay mineral, (D) nonionic surfactant and (E) refreshing agent. Do it.

  (A) As a nonpolar oil of a component, hydrocarbon oil, volatile silicone, etc. are mentioned, for example. Specific examples of the hydrocarbon oil include ozokerite, light isoparaffin, light liquid isoparaffin, synthetic squalane, vegetable squalane, squalane, ceresin, paraffin, liquid paraffin, liquid isoparaffin, petrolatum and the like. Specific examples of volatile silicones include cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylcyclopolysiloxane; octamethyltrisiloxane, tetradecamethylhexasiloxane, low Examples thereof include chain silicones such as viscosity methylpolysiloxane. These components may be used alone or in combination of two or more. The preferred component (A) is preferably light isoparaffin, liquid paraffin, low-viscosity methylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane from the viewpoint of usability and formulation stability. Among them, liquid paraffin, More preferably, decamethylcyclopentasiloxane is used.

  The content of the component (A) is not particularly limited as long as the desired effect is sufficiently imparted, but usually 10% by weight or more is preferable in the composition from the viewpoint of non-aqueous, more preferably 15 % By weight or more. Moreover, from a viewpoint of a usability | use_condition and formulation stability, 60 weight% or less is preferable, More preferably, it is 50 weight% or less. From these viewpoints, the content of the component (A) is preferably 10 to 60% by weight, more preferably 15 to 50% by weight.

  (B) The exothermic agent of component (B) is not particularly limited as long as it generates heat when mixed with water and exhibits an appropriate thermal feeling. For example, calcium chloride, magnesium chloride, aluminum chloride, ferric chloride, chloride Examples thereof include inorganic salts such as zinc, calcium sulfate, magnesium sulfate, zinc sulfate, aluminum sulfate, ferrous sulfate, calcium carbonate and sodium carbonate. These components may be used alone or in combination of two or more. Among these (B) components, it is preferable to use calcium chloride, magnesium chloride, calcium sulfate, and magnesium sulfate from the viewpoint of generating heat quickly after mixing with water and producing an appropriate thermal feeling.

  In addition, a commercial item can also be used for (B) component as it is. Examples of commercially available calcium chloride include calcium chloride H (trade name, manufactured by Tomita Pharmaceutical Co., Ltd.). Examples of commercially available products of magnesium chloride include magnesium chloride (trade name, manufactured by Tomita Pharmaceutical Co., Ltd.), and commercially available products of calcium sulfate. Examples thereof include calcium sulfate (trade name, manufactured by Maui Kasei Kogyo Co., Ltd.) and examples of commercially available magnesium sulfate include anhydrous magnesium sulfate O-TS (trade name, manufactured by Tomita Pharmaceutical Co., Ltd.). it can.

  The content of the component (B) is not particularly limited as long as the desired effect is sufficiently imparted, but usually 5% by weight or more is preferable in the composition from the viewpoint of imparting a thermal feeling, and more preferably. 10% by weight or more. Moreover, from a viewpoint of setting a moderate warm feeling, 50 weight% or less is preferable, More preferably, it is 45 weight% or less. From these viewpoints, the content of the component (B) is preferably 5 to 50% by weight, more preferably 10 to 45% by weight.

  Specific examples of the clay mineral as component (C) are not particularly limited as long as they are natural products, purified products from natural products, or synthetic materials. For example, kaolins such as kaolin, nacrite, dickite, and halosite are used. Group clay minerals; antigolite group clay minerals such as antigolite, amesite and chronsteadite; pyrophyllite group clay minerals such as pyrophyllite and talc; illite, sea green stone, ceradonite and sericite , Mica, muscovite, chrome muscovite, biotite, etc .; smectite clay minerals such as bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite, lucentite; vermiculite clay such as vermiculite Minerals: Chlorite-type clays such as chlorite Minerals: organically modified clay minerals obtained by treating smectite group or vermiculite group clay minerals with quaternary ammonium salt type cationic surfactants such as alkyltrimethylammonium chloride, dialkyldimethylammonium chloride and benzalkonium chloride it can. These components may be used alone or in combination of two or more.

  In the present invention, from the viewpoint of formulation stability and removal of sebum dirt, kaolin, talc, mica, sericite, bentonite, saponite, hectorite, dimethyl distearyl ammonium hectorite, benzyl dimethyl stearyl ammonium hectorite, Dimethyl distearyl ammonium bentonite is preferably used, and kaolin, talc, mica, dimethyl distearyl ammonium hectorite, benzyl dimethyl stearyl ammonium hectorite, and dimethyl distearyl ammonium bentonite are more preferable.

  In addition, a commercial item can also be used for (C) component as it is. As a commercial product of kaolin, for example, kaolin (trade name, manufactured by Ina Trading Co., Ltd.); As a commercial product of talc, for example, TALK PP (trade name, manufactured by Matsumura Sangyo Co., Ltd.); Kashmir (trade name, manufactured by Catalyst Kasei Co., Ltd.); As a commercial product of dimethyl distearyl ammonium hectorite, for example, Benton 38V (trade name, manufactured by Elementis Japan); As a commercial product of benzyl dimethyl stearyl ammonium hectorite, For example, as a commercial product of Benton 27V (trade name, manufactured by Elementis Japan); dimethyl distearyl ammonium bentonite, for example, Benton 34 (trade name, manufactured by Elementis Japan) can be exemplified.

  The content of the component (C) is not particularly limited as long as a desired effect is imparted, but usually in the composition from the viewpoint of improving formulation stability, sebum stain removal, and adhesion during application. 0.5% by weight or more is preferable, and more preferably 1% by weight or more. Moreover, from a viewpoint of reducing the irritation at the time of use, 40 weight% or less is preferable, More preferably, it is 35 weight% or less. From these viewpoints, the content of component (C) is preferably 0.5 to 40% by weight, more preferably 1 to 30% by weight.

  Examples of the component (D) nonionic surfactant include sorbitan monostearate, sorbitan palmitate, sorbitan tristearate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan tristearate, sorbitan monooleate Sorbitan fatty acid esters such as sorbitan sesquioleate, sorbitan coconut oil fatty acid sorbitan, sorbitan sesquistearate; sorbitol fatty acid esters such as polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol tetrastearate, polyoxyethylene sorbitol tetraoleate; mono Glycerin fatty acid esters such as glyceryl stearate, glyceryl monocaprylate, glyceryl monooleate; hexaglyceryl monolaurate , Polyglycerin fatty acid esters such as hexaglyceryl monomyristate, decaglyceryl monostearate, decaglyceryl monolinoleate, decaglyceryl monooleate; polyoxy such as polyoxyethylene glyceryl monostearate, polyoxyethylene glyceryl monooleate Ethylene glycerin fatty acid ester; polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene behenyl ether, polyoxyethylene octyldodecyl ether, polyoxyethylene lauryl ether, polyoxyethylene oleyl ether, polyoxyethylene octyldodecyl ether, etc. Polyoxyethylene alkyl ether; Polyethylene glycol monooleate, Poly monostearate Polyalkylene glycol fatty acid esters such as ethylene glycol, polyethylene glycol monolaurate, propylene glycol monostearate, propylene glycol monolaurate, propylene glycol monooleate; polyoxyethylene castor oil; polyoxyethylene lanolin; polyoxyethylene hydrogenated castor oil Can be illustrated. These components may be used alone or in combination of two or more. As a suitable component (D), it is preferable to use polyoxyethylene alkyl ether and sorbite fatty acid ester from the viewpoint of formulation stability. Among them, polyoxyethylene octyldodecyl ether and polyoxyethylene sorbite tetraoleate are preferably used. Is preferred.

  The content of the component (D) is not particularly limited as long as the desired effect is sufficiently imparted, but usually 1% by weight or more is preferable in the composition from the viewpoint of formulation stability, more preferably 3 % By weight or more. Moreover, from a viewpoint of a usability | use_condition, 15 weight% or less is preferable, More preferably, it is 13 weight% or less. From these viewpoints, the content of the component (D) is preferably 1 to 15% by weight, more preferably 3 to 13% by weight.

  (E) As a refreshing agent of component, for example, 1-menthol, menthyl glyceryl ether, menthyl lactate, 1-menthyl-3-hydroxybutyrate, dl-camphor, eugenol, menthone, mint, menthyl salicylate, eucalyptus oil, etc. It can be illustrated. These components may be used alone or in combination of two or more. As a suitable (E) component, it is preferable to use 1-menthol and menthyl glyceryl ether, and it is more preferable to use 1-menthol from a viewpoint which is excellent in the refreshing feeling after rinsing.

  The content of the component (E) is not particularly limited as long as the desired effect is sufficiently imparted, but usually, 0.1% by weight or more is preferable in the composition from the viewpoint of refreshing feeling, more preferably. 0.3% by weight or more. Moreover, from a viewpoint of suppressing the fall of the thermal feeling by a refreshing feeling, 1.5 weight% or less is preferable, More preferably, it is 1 weight% or less. From these viewpoints, the content of the component (E) is preferably 0.1 to 1.5% by weight, more preferably 0.3 to 1% by weight.

  In addition, when using a refreshing agent such as l-menthol that does not dissolve in the non-polar oil of the component (A) of the present invention, it is preferable to dissolve and blend in the fatty acid ester oil from the viewpoint of solubility in non-aqueous preparations. . The fatty acid ester oil to be used is not particularly limited as long as it can be dissolved, but it is preferable to use a fatty acid ester oil having low lipophilicity from the viewpoint of reducing the feeling of stickiness on the skin and making it feel light. Specifically, for example, isononyl isononanoate, isotridecyl isononanoate, 2-ethylhexyl palmitate, neopentyl glycol dicaprate, isopropyl myristate, 2-ethylhexyl stearate, 2-octyldodecyl myristate, tri (capryl capric acid) ) Glyceryl, 2-ethylhexanoate isostearyl, 2-octyldodecyl neopentanoate, myristyl myristate, cetyl palmitate, trimethylolpropane tri-2-ethylhexanoate, isopropyl isostearate, cetyl 2-ethylhexanoate, isomyristate myristate Examples include stearyl and glyceryl tri-2-ethylhexanoate. These components may be used alone or in combination of two or more.

  The content of the fatty acid ester oil is not particularly limited, but is preferably 0.5 to 6% by weight, more preferably 1 to 5% by weight in the composition from the viewpoint of light use feeling. If it is less than 0.5% by weight, the solubility of the refreshing agent is poor, which is not preferable. Moreover, when it contains exceeding 6 weight%, since it is inferior to the refreshing feeling after rinsing, it is unpreferable.

  In addition, the non-aqueous warm skin cleansing composition of the present invention can contain (F) a scrub agent. By containing the component (F), old keratin scattered on the skin surface can be removed, and the skin state after rinsing can be made better. It also has the effect of floating sebum dirt clogged in pores, etc., and assisting clay mineral sebum adsorption. Furthermore, the oil film feeling at the time of washing | cleaning can be reduced and the thermal feeling of a heat generating agent can be improved more. Specific examples of the component (F) include spherical polyethylene, spherical nylon, spherical polyester, crystalline cellulose, and silica. These components may be used alone or in combination of two or more. As a suitable component (F), spherical polyethylene and crystalline cellulose are preferably used from the above viewpoint.

  The particle size of the component (F) used is not particularly limited as long as the desired effect is sufficiently imparted. For example, when spherical polyethylene is used, the average particle size is preferably 10 to 800 μm, and 150 It is more preferable to use one having a thickness of ˜400 μm. Moreover, when using crystalline cellulose, a thing with an average particle diameter of 10-150 micrometers is preferable, and it is more preferable to use a 30-100 micrometers thing.

  In addition, a commercial item can also be used for (F) component as it is. Examples of commercially available spherical polyethylene products include flow beads CL5007 (trade name, manufactured by Sumitomo Seika Co., Ltd.); examples of commercially available crystalline cellulose products include Theolas PH-101 and PH-102 (trade names, both of which are Asahi Kasei Corporation). For example).

  The content of the component (F) is not particularly limited as long as the desired effect is sufficiently imparted, but usually 0.1% by weight or more is preferable in the composition from the viewpoint of improving the skin condition. More preferably, it is 1% by weight or more. Moreover, from a viewpoint of a usability | use_condition, 20 weight% or less is preferable, More preferably, it is 15 weight% or less. From these viewpoints, the content of the component (F) is preferably 0.1 to 20% by weight, more preferably 1 to 15% by weight.

  In the non-aqueous warm skin cleansing composition of the present invention, as long as it does not impair the effects of the present invention, in addition to the above-described components, components commonly used in cosmetics such as ethylene glycol, diethylene glycol, triethylene, etc. Glycol, polyethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, 1,3-butylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, Polyhydric alcohols such as 1,2-decanediol; Thickening components such as dextrin fatty acid esters and thickening polymers; Oily components such as solid waxes, fats and oils and higher fatty acids; Anionic surfactants and cationic surfactants Surfactants such as amphoteric surfactants; inorganic pigments, organic pigments, pearl face Powders and the like; antioxidants, preservatives, ultraviolet absorbers, can be appropriately mixed depending on the purpose plant extracts, perfumes and the like.

  The application site of the non-aqueous warm skin cleansing composition is not particularly limited. However, since a smooth skin state is obtained after rinsing, for example, face parts such as the forehead, nose, eyes, eyes, cheeks, mouth; elbows, It can be applied to body parts such as fingertips, knees, and heels. Among them, it is preferable to use it on the face part where there is a lot of sebum because it is excellent in the effect of removing sebum stains. Especially, it is preferably used on the part where the amount of sebum is the largest, so-called the so-called T zone. Can do.

  Although it does not specifically limit as a treatment method, For example, (1) After apply | coating this composition to dry skin, the method of washing | cleaning so that it may massage with the fingertip wet with water; (2) Wet skin (3) Taking the composition on a dry fingertip, soaking the cosmetic and the fingertip in water, and then applying it to the skin after applying to the skin and massaging with a fingertip wet with water A method of washing so as to apply and massage; (4) A method of taking the composition on a fingertip wetted with water, applying it to the skin, and washing so as to massage can be exemplified. Among these treatment methods, the superior thermal feeling of the present invention can be realized more by washing by the method (1). The amount of water used to develop an excellent thermal feeling is not particularly limited, but 0.05 to 10 parts by weight of water is preferably used with respect to 1 part by weight of the composition. When an amount exceeding 10 parts by weight is used, the composition flows down from the skin, and a thermal sensation cannot be realized.

  Although it does not specifically limit about the time which washing | cleaning requires, It is preferable to wash for 30 seconds or more from a viewpoint which feels moderate heat and fully removes sebum dirt of skin. Moreover, it is preferable to set it as 3 minutes or less from a viewpoint of the burden on skin.

  Moreover, when apply | coating to dry skin like the method of said (1), from the viewpoint of suppressing dripping from skin and improving adhesiveness, the property of the composition for non-aqueous warm skin washing is paste. It is preferable to make it into a shape. More specifically, the consistency (N) of the composition is preferably prepared in the range of 0.04 to 4, more preferably 0.1 to 1. The consistency (N) was inserted 2 cm under the conditions of measurement temperature: 25 ° C., adapter: 10φ sphere, speed: 6 cm / min using a rheometer (RHEO METER CR-500DX, manufactured by Sun Kagaku Co., Ltd.). It is the value which measured the maximum stress at the time. Further, in the present invention, “pasted” means “semi-solid property without fluidity”, and refers to “fluid cream”, “fluid viscous liquid”, and “solid”. Are different.

  In addition, when manufacturing the composition for non-aqueous warm skin washing | cleaning, it can manufacture by mixing each said component and stirring by a well-known method, for example, a disper mill. In the present invention, “non-aqueous” means “not containing water separately” and does not exclude a small amount of water contained in each compounding component.

  The product form of the non-aqueous warm skin cleansing composition of the present invention is not particularly limited, but may be a product form filled in a jar container, a tube container or the like. Especially, it is preferable to set it as the goods form by the tube container suitable for taking out of a paste-form dosage form. Moreover, as a usage form, it can be used as a facial cleanser, a body soap, a hand soap, etc. Among these, it is possible to remove sebum stains, lead to a smooth skin state, and give a refreshing refreshing feeling, so that it can be suitably used as a facial cleanser.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to these Examples. The blending amount represents “% by weight” unless otherwise specified. Moreover, all evaluation was implemented on the constant conditions of constant temperature and humidity of 23 degreeC and 60% of humidity.

(Sample preparation)
In accordance with the compositions described in Tables 1 and 2, the non-aqueous warm skin cleansing compositions of Examples 1-7 and Comparative Examples 1-5 and the polyhydric alcohol warm skin cleansing composition of Comparative Example 6 Each was prepared according to a conventional method and subjected to the following evaluation. The results are shown in Table 1 and Table 2, respectively.

(Test Example 1: Confirmation of properties)
The properties of the samples of each Example and each Comparative Example immediately after the preparation were visually observed.

(Test Example 2: Evaluation of formulation stability)
Samples obtained in each Example and each Comparative Example were filled in a 100 mL wide-mouth container, stored in a constant temperature bath at 40 ° C. for 2 weeks, and then the state of the preparation was visually observed and evaluated according to the following evaluation criteria. .

<Evaluation criteria for formulation stability>
A: The paste-like shape is retained. O: The paste-like shape is retained, but slight separation is observed on the surface. Δ: The paste-like shape is not retained, and the liquid is clearly separated on the surface. Liquid, liquid mobilization is observed x: separated

(Test Example 3: Evaluation of adhesion to skin)
Samples obtained in each Example and each Comparative Example were applied from 20 dry panels to a site on the nose muscles by 20 specialist panels, and sensory evaluation was performed according to the following evaluation criteria for the feeling of adhesion at the time of application.

<Adhesion evaluation criteria>
A: Reply when 16 or more out of 20 people are excellent in close contact feeling ○: Reply when 11-15 out of 20 people are excellent in close contact feeling Δ: Reply when 6-10 out of 20 people are excellent in close contact feeling ×: 20 5 or less of the names responded that they had excellent adhesion

(Test Example 4: Evaluation 1 of use feeling)
After the evaluation of Test Example 3, the 20 panelists performed cleansing for 1 minute so as to massage the part to which the sample was applied by wetting the fingertips, and sensory evaluation was performed according to the following evaluation criteria for “thermal feeling” during cleansing. After rinsing, moisture was wiped off by towel drying.

<Evaluation criteria for thermal feeling>
◎: More than 16 out of 20 responded that there was a moderate warm feeling ○: 11-15 out of 20 responded that there was a moderate thermal feeling △: 6-10 out of 20 persons had a moderate thermal feeling Answer X: 5 or less of 20 respondents said that there was a moderate thermal sensation (Test Example 5: Evaluation 2 for feeling of use)
After the evaluation of Test Example 4, the panel 20 was subjected to a sensory evaluation according to the following evaluation criteria for “coolness”, “sebum stain removal”, and “skin condition”. “Sebum dirt removal” was evaluated based on whether or not sebum adheres to the fingertips after the cleaning site was stroked with the fingertips. In addition, the “skin condition” was evaluated by touching the fingertip with the fingertip of the cleaning site.

<Evaluation criteria for coolness>
◎: 16 or more out of 20 people answered that there was a refreshing refreshment ○: 11-15 out of 20 people felt refreshed and refreshed △: 6-10 out of 20 people felt refreshed And answer ×: Refreshing feeling with a refreshing feeling of 5 or less of 20 people

<Evaluation criteria for removing sebum dirt>
◎: More than 16 out of 20 responded that sebum did not adhere to the fingertips ○: 11-15 out of 20 responded that sebum did not adhere to the fingertips △: 6-10 out of 20 responded to sebum No answer x: 5 or less of 20 responded that sebum does not adhere to the fingertips

<Evaluation criteria for skin condition>
◎: More than 16 out of 20 responded that the skin was smooth ○: 11-15 out of 20 responded that the skin was smooth △: 6-10 out of 20 were in the skin Answer X: 5 out of 20 respondents say they have a smooth skin condition

  From the results shown in Table 1 and Table 2, the non-aqueous warm skin cleansing compositions obtained in each example were compared with the non-aqueous warm skin cleansing compositions obtained in each comparative example. It can be seen that the preparation stability, the feeling of adhesion, the feeling of heat, the feeling of coolness, the removal of sebum stains, and the skin condition after use have excellent effects. In addition, it can be seen that the polyhydric alcohol-based warm skin cleansing composition of Comparative Example 6 is inferior in adhesion to skin, thermal feel, and sebum stain removal.

  Hereinafter, formulation examples of the non-aqueous warm skin cleaning composition according to the present invention will be shown. The content is% by weight.

(Prescription Example 1)
Liquid paraffin 34.2
Ceresin 5.0
Magnesium sulfate 30.0
Sericite 8.0
Talc 10.0
POE (9) lauryl ether 8.0
l-Menthol 0.5
Cetyl 2-ethylhexanoate 3.0
Spherical polyethylene 0.5
Black iron oxide 0.1
Vitamin E 0.2
1,2-octanediol 0.5
Total 100.0

(Prescription example 2)
Decamethylcyclopentasiloxane 23.5
Octamethylcyclotetrasiloxane 10.0
Magnesium chloride 15.0
Calcium chloride 15.0
Dimethyl distearyl ammonium bentonite 3.0
Mica 15.0
POE (20) polyoxyethylene behenyl ether 8.0
l-Menthol 0.5
Isopropyl myristate 3.0
Crystalline cellulose 5.0
Spherical nylon 2.0
Total 100.0

(Prescription Example 3)
Liquid paraffin 31.5
Vaseline 2.0
Candelilla Row 2.0
Magnesium sulfate 25.0
Kaolin 20.0
Silicic anhydride 3.0
Sorbitan sesquioleate 2.0
POE (10) oleyl ether 8.0
l-Menthol 0.5
Neopentyl glycol dicaprate 4.0
Spherical polyethylene 2.0
Total 100.0

Claims (5)

Containing (A) nonpolar oil, (B) exothermic agent, (C) clay mineral, (D) nonionic surfactant and (E) refreshing agent,
(B) component is at least 1 sort (s) chosen from the group of calcium chloride, magnesium chloride, calcium sulfate, and magnesium sulfate,
(C) component is at least one selected from the group of kaolin, talc, mica, dimethyl distearyl ammonium hectorite, benzyl dimethyl stearyl ammonium hectorite and dimethyl distearyl ammonium bentonite,
The content of the component (A) is 15 to 60% by weight, the content of the component (B) is 5 to 45% by weight, the content of the component (C) is 0.5 to 40% by weight, (D) Component content is 3 to 13% by weight, (E) Component content is 0.3 to 1% by weight,
A non-aqueous warm skin cleansing composition characterized by being in a paste form.   The composition for cleansing non-aqueous warm skin according to claim 1, wherein the component (A) is liquid paraffin and / or decamethylcyclopentasiloxane. Furthermore, (F) a scrub agent is contained ,
(F) content of the component nonaqueous warming skin cleansing composition according to 0.1-15 wt% der Ru claim 1 or 2. The non-aqueous warm skin cleansing composition according to claim 3 , wherein the component (F) is spherical polyethylene and / or crystalline cellulose. Nonaqueous warming cleanser made of a non-aqueous warming skin cleansing composition according to any one of claims 1-4.