WO2020235603A1 - Engine valve and method for manufacturing same - Google Patents

Engine valve and method for manufacturing same Download PDF

Info

Publication number
WO2020235603A1
WO2020235603A1 PCT/JP2020/019982 JP2020019982W WO2020235603A1 WO 2020235603 A1 WO2020235603 A1 WO 2020235603A1 JP 2020019982 W JP2020019982 W JP 2020019982W WO 2020235603 A1 WO2020235603 A1 WO 2020235603A1
Authority
WO
WIPO (PCT)
Prior art keywords
engine valve
diffusion
joint surface
metal
joint
Prior art date
Application number
PCT/JP2020/019982
Other languages
French (fr)
Japanese (ja)
Inventor
水野芳伸
伊藤誠
Original Assignee
Eco-A株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eco-A株式会社 filed Critical Eco-A株式会社
Priority to CN202080037290.0A priority Critical patent/CN113891774A/en
Priority to JP2021520823A priority patent/JPWO2020235603A1/ja
Publication of WO2020235603A1 publication Critical patent/WO2020235603A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01LCYCLICALLY OPERATING VALVES FOR MACHINES OR ENGINES
    • F01L3/00Lift-valve, i.e. cut-off apparatus with closure members having at least a component of their opening and closing motion perpendicular to the closing faces; Parts or accessories thereof
    • F01L3/02Selecting particular materials for valve-members or valve-seats; Valve-members or valve-seats composed of two or more materials

Definitions

  • the present invention relates to an engine valve and a method for manufacturing the same.
  • engine parts that operate under harsh conditions such as engine valves that reciprocate at high speed while being exposed to high temperatures, have excellent shapes such as weight reduction, heat capacity reduction, heat dissipation and heat resistance improvement. Structure is needed.
  • various engine valves are provided, such as making them hollow, or enclosing metallic sodium in a hollow shaft to reduce the heat load.
  • each member such as the valve head, valve face, valve stem, and valve stem end that make up the engine valve is manufactured individually according to each purpose such as weight reduction, reduction of heat capacity, improvement of heat dissipation and heat resistance.
  • an engine valve as a finished product is manufactured by joining each member to each other (for example, Patent Document 1).
  • an object of the present invention is to provide an engine valve which does not require deburring, has high strength of the joint portion 14, and has little deterioration of the metal structure other than the joint portion, and a method for manufacturing the engine valve.
  • the engine valve of the present invention has a first member and a second member joined to each other, and the first member and the second member are interposed via a diffusion layer within 5 ⁇ m. It is characterized by being joined together.
  • it may have a hollow portion that communicates the first member and the second member.
  • the shape of the diffusion layer is preferably formed in a convex shape on at least one of the first member and the second member, and is preferably one of the first member and the second member. It is better to have one formed in a convex shape on the side with higher electrical resistance.
  • the first member is made of a first metal
  • the second member can be made of a second metal made of a material different from that of the first member.
  • the method for manufacturing an engine valve of the present invention is a method for manufacturing an engine valve composed of a first member and a second member joined to each other, and the joint surface of the first member and the second member are subjected to current diffusion joining. It is characterized in that the joint surfaces of the above are joined.
  • At least one of the first member and the second member has a convex joint surface, and preferably, the first member and the second member having the lower electric resistance are joined. It is better to make the surface convex.
  • the energization diffusion joint energizes the joint surface between the first member and the second member by controlling the output of the power supply with an upslope.
  • the time for energizing the first member and the second member is preferably 90 seconds or less, preferably 30 seconds or less.
  • first member may be made of a first metal
  • second member may be made of a second metal whose material is different from that of the first member
  • the diffusion bonding may be one in which the bonding surface between the first metal and the second metal is energized and diffusion bonding is performed in a solid phase by the resistance heat generation thereof, or diffusion bonding is performed in a liquid phase. There may be.
  • the joint portion 14 is joined by current diffusion joint, there is little deterioration of the metal structure other than the joint portion 14. Moreover, the strength of the joint portion 14 is very high.
  • the engine valve 1 of the present invention has at least a first member 11 and a second member 12 joined to each other.
  • the first member 11 and the second member 12 may be any combination as long as they are members constituting the engine valve 1 and are joined to each other.
  • the first member 11 is a valve face and the second member 12 is a valve stem.
  • FIG. 1B the first member 11 is a valve stem and the second member 12 is a valve stem end.
  • the engine valve 1 may have three or more joined members.
  • the first member 11 and the second member 12 are joined via a diffusion layer 13 within 5 ⁇ m.
  • the diffusion layer 13 should be 5 ⁇ m or less, preferably 3 ⁇ m or less, and more preferably 1 ⁇ m or less.
  • the joining method may be any method as long as the thickness of the diffusion layer 13 can be 5 ⁇ m or less, and for example, an energization diffusion joining described later can be used.
  • the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining is made convex, and first contact with a point or a line, and when an electric current is applied, a diffusion layer is gradually formed.
  • a shape in which 13 is spread and joined is preferable.
  • the other joint surface preferably has a smooth shape such as a flat surface or a mirror surface so that at least no voids are formed during diffusion bonding.
  • the shape of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining one is formed in a convex shape and the other is formed in a flat shape.
  • the diffusion layer 13 gradually and neatly spreads from the apex of the convex portion in contact with the plane, so that a uniform diffusion layer 13 can be formed. Therefore, the breaking strength of the joint portion 14 can be increased.
  • a member having a high electric resistance is more likely to generate heat, it is easier to form a uniform diffusion layer by making the joint surface of the first member 11 and the second member 12 having a lower electric resistance convex. ..
  • the convex shape of the joint surface means that the tip of the joint surface is point-shaped or linear, and for example, the joint surface may be conical or spherical, or the cross section of the joint surface may be triangular or arch-shaped. be able to. Further, only one convex portion may be formed on the joint surface, or a plurality of convex portions may be formed. When a plurality of convex portions are formed on the joint surface, conventionally known methods such as sand blast treatment, shot blast treatment, etching treatment, and laser treatment can be used.
  • the shape of the diffusion layer 13 is either the first member 11 or the second member 12 at the joint portion 14, as shown in FIG. It will have a convexly formed portion on one side. More preferably, as described above, the first member 11 and the second member 12 having a convex joint surface having a lower electric resistance and a flat joint surface having a higher electric resistance are joined. It is a shape formed in the case, and specifically, it is preferable that the shape of the diffusion layer 13 is formed to be convex toward the higher electrical resistance of the first member 11 and the second member 12. The number of convex portions formed on the diffusion layer 13 may be plural.
  • first member 11 and the second member may have any shape as long as they can exert the functions of the respective members, and a conventionally known general shape can be adopted.
  • first member 11 and the second member 12 may have a hollow portion 15 that communicates with each other.
  • the hollow portion 15 is a portion whose inside is hollow for the purpose of reducing the weight of the engine valve 1 and reducing the heat capacity.
  • the material of the first member 11 is made of metal (first metal).
  • the first member 11 may be any metal as long as it can exhibit the function of the member, and for example, steel materials such as austenitic stainless steel and martensitic stainless steel, nickel alloys, titanium and titanium alloys may be used. it can. Specific examples include SUH3 as a material for the valve face (first member 11).
  • the material of the second member 12 is made of a metal (second metal) whose material is different from that of the first member 11.
  • a metal second metal
  • steel materials such as austenitic stainless steel and martensitic stainless steel, nickel alloys, titanium and titanium alloys can be used.
  • the metals having different materials include not only metals having different components but also metals having the same components but different properties such as metals formed by different quenching.
  • the first member 11 and the second member 12 are made of the same type of metal, there is an advantage that the bonding interface is hardly seen and the fracture strength is superior to that of the conventional friction welding.
  • SUH3 is used as the material of the valve face (first member 11)
  • SUH35 can be used as the valve stem (second member 12).
  • the method for manufacturing the engine valve 1 of the present invention is to join the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 described above by current diffusion joining.
  • the energization diffusion bonding is a method in which the bonding surface of the first member 11 and the second member 12 is energized and diffusion bonding is performed in a solid phase or a liquid phase by the heat generation of the resistance.
  • the current diffusion bonding has an advantage that the deformation of the bonding portion 14 between the first member 11 and the second member 12 is small and precise bonding is possible. It also has the advantage that there is almost no alteration of the metal structure other than the joint portion 14.
  • the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining is made convex, and first contact with a point or a line, and when an electric current is applied, a diffusion layer is gradually formed.
  • a shape in which 13 is spread and joined is preferable.
  • the other joint surface preferably has a smooth shape such as a flat surface or a mirror surface so that at least no voids are formed during diffusion bonding.
  • the shape of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining one is formed in a convex shape and the other is formed in a flat shape.
  • the diffusion layer 13 gradually and neatly spreads from the apex of the convex portion in contact with the plane, so that an even and uniform diffusion layer 13 can be formed. Therefore, the breaking strength of the joint portion 14 can be increased.
  • a member having a high electric resistance is more likely to generate heat, it is easier to form a uniform diffusion layer by making the joint surface of the first member 11 and the second member 12 having a lower electric resistance convex. ..
  • the convex shape of the joint surface means that the tip of the joint surface is point-shaped or linear, and for example, the joint surface may be conical or spherical, or the cross section of the joint surface may be triangular or arch-shaped. be able to. Further, only one convex portion may be formed on the joint surface, or a plurality of convex portions may be formed. When a plurality of convex portions are formed on the joint surface, conventionally known methods such as sand blast treatment, shot blast treatment, etching treatment, and laser treatment can be used.
  • the shape of the diffusion layer 13 is either the first member 11 or the second member 12 at the joint portion 14, as shown in FIG. It will have a convexly formed portion on one side. More preferably, as described above, the joint surface of the first member 11 and the second member 12 having the lower electric resistance is convex and the joint surface having the higher electric resistance is flat. It is a shape formed in the case, and specifically, it is preferable that the shape of the diffusion layer 13 is formed to be convex toward the higher electrical resistance of the first member 11 and the second member 12. The number of convex portions formed on the diffusion layer 13 may be plural.
  • the energization diffusion joining device is for performing diffusion bonding by energizing the first member 11 and the second member 12 with which the joint surfaces are abutted, and is an electrode, a power source, a temperature information providing unit, and an output control unit. And a pressurizing part.
  • the electrodes are for conducting electricity output from the power supply to the first member 11 and the second member 12.
  • the energization diffusion joining device may be provided with at least two electrodes for conducting electricity to the first member 11 and the second member 12, for example, sandwiching the joining surface between the first member 11 and the second member 12. It is provided in the opposite part with.
  • three or more electrodes may be provided depending on the material and shape of the first member 11 and the second member 12.
  • the electrode may be made of any material as long as electricity can be conducted through the first member 11 and the second member 12, and for example, copper, molybdenum, tungsten, or the like can be used.
  • the electrodes are connected to the power supply via a cable.
  • the power supply is for outputting power to multiple electrodes.
  • the power supply may be any power supply as long as the outputs applied to the plurality of electrodes can be continuously changed, and for example, a known inverter power supply can be used.
  • the temperature information providing unit is for providing the output control unit with temperature information of the first member 11 and the second member 12 or the electrodes.
  • the temperature information means information on the temperature of the first member 11 and the second member 12 or the electrode, and may be the information as it is, or is calculated from the temperature such as the voltage value that determines the voltage of the power supply. It may be the information converted by.
  • a temperature sensor that detects the temperature of the first member 11, the second member 12, or the electrode can be used.
  • the temperature sensor may be any one as long as it can detect the temperature of the joint 14 material or the electrode.
  • a non-contact sensor that detects the temperature in a non-contact manner such as an infrared radiation thermometer, or a first member 11
  • a contact type sensor such as a thermocouple that detects the temperature by contacting the second member 12 or the electrode may be used. It is also possible to use both a non-contact type and a contact type.
  • the energization diffusion joint energizes the joint surface of the first member 11 and the second member 12 by controlling the output of the power supply with an upslope. Therefore, it is preferable that the output control unit controls the output of the power supply with an upslope based on the temperature information from the temperature information providing unit.
  • a constant current is energized for a certain period of time, or a constant current is energized by ON / OFF control, so that the temperature of the place where the current is concentrated may rise sharply.
  • the bonding state of the bonding surface becomes non-uniform, such as the bonding state of the relevant portion becoming a liquid phase bond, which leads to variations in the bonding state.
  • the upslope control since the current is gradually increased, sudden current concentration can be suppressed and the temperature of the joint surface can be made uniform. Therefore, it is possible to grow a uniform diffusion layer 13 on the joint surface, and it is possible to achieve uniform strength.
  • one of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining is formed to be convex and the other is flat. This is because the concentration of electric current can be suppressed and a more uniform diffusion layer 13 can be grown.
  • the output control unit can continuously control the output of the power supply in real time with an upslope based on the temperature information detected by the temperature sensor, enabling precise temperature control of the first member 11 and the second member 12. it can. Therefore, the joining strength of the 14 joining portions on the joining surface is high, and it is possible to perform joining with little variation. Further, such continuous control can maintain a constant thermal expansion as compared with ON / OFF control, so that the influence of pressure fluctuation due to thermal expansion can be reduced.
  • the output control unit may be any as long as the output of the power supply can be controlled by an upslope based on the temperature information from the temperature information providing unit. For example, from the CPU, ROM, RAM, I / O, etc. It is possible to use the one which is configured and the operation unit and the display unit are electrically connected. Specifically, a known PID temperature controller such as a high-speed sampling temperature controller can be used.
  • the operation unit is composed of various operation switches such as a start switch and a start switch, an input panel including a touch panel, and the like. The information input from the operation unit is transmitted to the output control unit. Further, the display unit receives information based on the input to the output control unit or the calculation result in the output control unit from the output control unit, and displays the information.
  • the display unit is composed of a digital display panel, a lamp, and the like.
  • the temperature of the first member 11 and the second member 12 or the electrode is acquired in real time by using the temperature sensor, and the output control unit of the first member 11 and the second member 12 or the electrode
  • the case of providing temperature information has been described.
  • the relationship between the elapsed time and the temperature of the first member 11 and the second member 12 or the electrode is the same. The result is. Therefore, if the temperature information indicating the relationship between the elapsed time and the temperature of the first member 11 and the second member 12 or the electrode is acquired in advance, the temperature information can be provided without using the temperature sensor. ..
  • the temperature information providing unit is a temperature information storage unit that stores temperature information indicating the relationship between the elapsed time of the first member 11 and the second member 12 or the electrode and the temperature of the first member 11 and the second member 12 or the electrode. It may be.
  • the output control unit can control the output of the power supply based on the temperature information stored in the temperature information storage unit.
  • the temperature information storage unit may be any as long as it can store the temperature information for determining the relationship between the elapsed time and the output of the power supply, and for example, a known memory or the like may be used.
  • the pressurizing portion is for applying pressure to the joint surface between the first member 11 and the second member 12.
  • the structure of the pressurizing portion may be any as long as pressure can be applied to the joint surface between the first member 11 and the second member 12, but for example, the pressurizing member to which the electrodes are fixed and the pressurizing member are driven. It may be composed of a drive source for the purpose and a ball screw mechanism that transmits the driving force of the drive source and moves the pressurizing member up and down.
  • the pressurizing member may be formed according to the shapes of the first member 11 and the second member 12, or an intermediate member matching the shapes of the first member 11 and the second member 12 may be sandwiched between them.
  • the material of the pressure member may be any material as long as it has rigidity against pressure, and for example, a metal such as stainless steel, copper, molybdenum, or tungsten may be used.
  • the pressurizing member may have a cooling means for cooling the first member 11 and the second member 12.
  • the cooling means may be any one as long as the first member 11 and the second member 12 can be cooled, and for example, a cooling fluid such as tap water may be circulated in the flow path. ..
  • the flow path may be provided on the pressurizing member itself, or a cooling block on which the flow path is formed may be arranged in close contact with the pressurizing member.
  • a servomotor with a speed reducer can be used as the drive source.
  • An encoder is attached to the servomotor and is arranged on a gantry.
  • the ball screw mechanism consists of a screw shaft extending in the vertical direction and having a thread groove formed on the outer peripheral surface, a nut having a thread groove formed on the inner peripheral surface, and a plurality of balls accommodated between these thread grooves.
  • the nut is fixed to the upper part of the pressurizing member via an insulator made of bakelite or the like and a pressure sensor.
  • the screw shaft is connected to the rotating shaft of the servomotor via a speed reducer.
  • the servomotor When the servomotor is rotationally driven, the screw shaft rotates, and the nut, and thus the pressurizing member, moves up and down relative to the screw shaft. Further, when the driving of the servomotor is stopped, the position of the pressurizing member is maintained. At this time, the pressurizing portion regulates the displacement of the first member 11 and the second member 12 to apply pressure to the joint surface.
  • the pressurizing unit may have a pressure sensor that detects the pressure on the joint surface.
  • the pressure sensor is, for example, a uniaxial load cell that measures the pressure in the vertical direction, but a multi-axis pressure sensor may be used.
  • the pressure sensor can indirectly detect the pressure applied to the joint surface between the first member 11 and the second member 12.
  • the pressurizing portion may further include an elastic force urging means for urging the joint surface between the first member 11 and the second member 12.
  • an elastic force urging means is arranged between the base member on which the pressurizing member is arranged and the base of the current diffusion joining device.
  • the elastic force urging means is composed of, for example, a spring and a block body for restricting the spring to a preset length shorter than the free length between the spring and the base member.
  • the pressure acting on the first member 11 and the second member 12 from the base member pushed up by the elastic force urging means can be changed by exchanging the spring. With this configuration, even if thermal expansion or contraction occurs in the first member 11 and the second member 12, a sudden change in pressure acting on the joint surface can be alleviated.
  • the pressurizing portion may have any other configuration as long as it is for pressing the first member 11 and the second member 12 with each other at the joint surface.
  • the energization heating joining device may further have a pressure control unit for controlling the pressure applied to the joining surface.
  • the pressure control unit is composed of, for example, a CPU, ROM, RAM, I / O, etc., and the operation unit and the display unit are electrically connected to each other.
  • the operation unit is composed of various operation switches such as a start switch and a start switch, an input panel including a touch panel, and the like.
  • the information input from the operation unit is transmitted to the pressure control unit.
  • the display unit receives information from the pressure control unit based on the input to the pressure control unit or the calculation result in the pressure control unit, and displays the information.
  • the display unit is composed of a digital display panel, a lamp, and the like. It is also possible to use the same pressure control unit as the output control unit described above.
  • detection signals are input to the pressure control unit from the encoder, the pressure sensor and the temperature sensor.
  • the pressure control unit is based on these detection signals, information input from the operation unit, and control information such as set pressure Ps, lower limit set pressure Ps1, set temperature Ts, and set holding time Hs stored in the storage unit. Outputs a control signal to the servo motor.
  • the bonding surface 11a of the first member 11 and the bonding surface 12a of the second member 12 are brought into contact with each other, and the first member 11 and the second member 12 are energized. Heat.
  • the diffusion layer 13 can be grown and joined to the joint surface between the first member 11 and the second member 12.
  • the energization time is preferably 90 seconds or less, and more preferably 30 seconds or less.
  • the thickness of the diffusion layer 13 of the first member 11 and the second member 12 can be reduced to 5 ⁇ m or less.
  • Engine valve 11 First member 11a: Joint surface 12: Second member 12a: Joint surface 13: Diffusion layer 14: Joint 15: Hollow part

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

The purpose of the present invention is to provide an engine valve and a method for manufacturing the same, the engine valve in which: deburring and the like are unnecessary; the strength of a joining part is high; and deterioration of a metal structure other than the joining part is low. This method for manufacturing an engine valve formed of a first member 11 and a second member 12 joined with each other involves joining a joining surface of the first member 11 and a joining surface of the second member 12 through electric diffusion joining. Accordingly, it is possible to provide an engine valve in which the first member 11 and the second member 12 are joined with each other with 5 μm or less of a diffusion layer 13 therebetween.

Description

エンジンバルブおよびその製造方法Engine valve and its manufacturing method
 本発明は、エンジンバルブおよびその製造方法に関するものである。 The present invention relates to an engine valve and a method for manufacturing the same.
 近年、地球環境問題や省エネルギー化の観点から内燃機関、特に自動車用エンジンを軽量化するとともに、より高い燃焼温度で効率よくエンジンを稼働することが、今まで以上に求められている。 In recent years, from the viewpoint of global environmental issues and energy saving, it has been required more than ever to reduce the weight of internal combustion engines, especially automobile engines, and to operate the engines efficiently at higher combustion temperatures.
 エンジンをより高い燃焼温度で効率よく稼働させるためには、耐熱性構造材でエンジン用部品を構成し、さらに、熱が過剰に蓄積せず、かつ軽量な部品形状ないし構造を用いる必要がある。 In order to operate the engine efficiently at a higher combustion temperature, it is necessary to construct the engine parts with heat-resistant structural materials, and to use a lightweight part shape or structure that does not accumulate excessive heat.
 特に、過酷な条件下で稼働するエンジン用部品、例えば、高温に曝されながら高速で往復運動するエンジンバルブには、軽量化や熱容量の低減、放熱性および耐熱性の向上等に優れた形状ないし構造が必要である。 In particular, engine parts that operate under harsh conditions, such as engine valves that reciprocate at high speed while being exposed to high temperatures, have excellent shapes such as weight reduction, heat capacity reduction, heat dissipation and heat resistance improvement. Structure is needed.
 そのために、エンジンバルブでは、中空としたり、熱負荷を軽減させるために中空とした軸部内に金属ナトリウムを封入したりするなど、様々なものが提供されている。 For that reason, various engine valves are provided, such as making them hollow, or enclosing metallic sodium in a hollow shaft to reduce the heat load.
 また、エンジンバルブを構成するバルブヘッド、バルブフェース、バルブステム、バルブステムエンド等の各部材は、軽量化や熱容量の低減、放熱性および耐熱性の向上等それぞれの目的に応じて個別に製造され、その後、各部材同士を接合することにより、完成品としてのエンジンバルブを製造している(例えば、特許文献1)。 In addition, each member such as the valve head, valve face, valve stem, and valve stem end that make up the engine valve is manufactured individually according to each purpose such as weight reduction, reduction of heat capacity, improvement of heat dissipation and heat resistance. After that, an engine valve as a finished product is manufactured by joining each member to each other (for example, Patent Document 1).
特開2004-25198JP-A-2004-25198
 従来は、これらの部材同士の接合には摩擦圧接接合等が用いられてきた。しかし、摩擦圧接接合では、図4に示すように、接合部1413に無視できないバリが生じるため、後加工でバリ取り工程が必要不可欠であった。また、中空部材の場合には、内部にバリが残ることになる。しかし、バリは一種の欠陥であり、エンジンバルブの耐疲労強度を低下させる等の問題がある。また、目視できない部分にバリが残ることは、機械特性上好ましいことではない。そこで、拡散接合による接合も行われている。しかし、従来の拡散接合では、真空炉内の雰囲気温度で拡散接合するため、部品全体が拡散温度に達し、部品全体の金属組織が変質するおそれがある。 Conventionally, friction welding or the like has been used for joining these members. However, in friction welding, as shown in FIG. 4, burrs that cannot be ignored occur in the joint portion 1413, so a deburring step is indispensable in post-processing. Further, in the case of a hollow member, burrs will remain inside. However, burrs are a kind of defect and have problems such as lowering the fatigue resistance of the engine valve. Further, it is not preferable in terms of mechanical characteristics that burrs remain in the invisible portion. Therefore, joining by diffusion joining is also performed. However, in the conventional diffusion bonding, since the diffusion bonding is performed at the ambient temperature in the vacuum furnace, the entire component may reach the diffusion temperature and the metal structure of the entire component may be deteriorated.
 そこで、本発明では、バリ取りなどが不要で、接合部14の強度が高く、接合部以外の金属組織の変質が少ないエンジンバルブおよびその製造方法を提供することを目的とする。 Therefore, an object of the present invention is to provide an engine valve which does not require deburring, has high strength of the joint portion 14, and has little deterioration of the metal structure other than the joint portion, and a method for manufacturing the engine valve.
 上記目的を達成するために、本発明のエンジンバルブは、互いに接合された第1部材と第2部材を有するものであって、前記第1部材と前記第2部材は5μm以内の拡散層を介して接合されていることを特徴とする。 In order to achieve the above object, the engine valve of the present invention has a first member and a second member joined to each other, and the first member and the second member are interposed via a diffusion layer within 5 μm. It is characterized by being joined together.
 この場合、前記第1部材と前記第2部材を連通する中空部を有していてもよい。 In this case, it may have a hollow portion that communicates the first member and the second member.
 また、前記拡散層の形状は、前記第1部材と前記第2部材の少なくともいずれか一方に凸状に形成されたものある方がよく、好ましくは、前記第1部材と前記第2部材のうち電気抵抗の高い方に凸状に形成されたものある方がよい。 Further, the shape of the diffusion layer is preferably formed in a convex shape on at least one of the first member and the second member, and is preferably one of the first member and the second member. It is better to have one formed in a convex shape on the side with higher electrical resistance.
 前記第1部材は第1金属からなり、前記第2部材は前記第1部材とは異なる材質の第2金属からなるものを用いることができる。 The first member is made of a first metal, and the second member can be made of a second metal made of a material different from that of the first member.
 また、本発明のエンジンバルブの製造方法は、互いに接合された第1部材と第2部材からなるエンジンバルブの製造方法であって、通電拡散接合によって前記第1部材の接合面と前記第2部材の接合面を接合することを特徴とする。 Further, the method for manufacturing an engine valve of the present invention is a method for manufacturing an engine valve composed of a first member and a second member joined to each other, and the joint surface of the first member and the second member are subjected to current diffusion joining. It is characterized in that the joint surfaces of the above are joined.
 この場合、前記第1部材と前記第2部材の少なくともいずれか一方の接合面を凸状とする方がよく、好ましくは、前記第1部材と前記第2部材のうち電気抵抗が低い方の接合面を凸状とする方がよい。 In this case, it is preferable that at least one of the first member and the second member has a convex joint surface, and preferably, the first member and the second member having the lower electric resistance are joined. It is better to make the surface convex.
 また、前記通電拡散接合は、前記第1部材と前記第2部材の接合面に電源の出力をアップスロープで制御して通電するものである方が好ましい。 Further, it is preferable that the energization diffusion joint energizes the joint surface between the first member and the second member by controlling the output of the power supply with an upslope.
 また、前記通電拡散接合において、前記第1部材と前記第2部材に通電する時間は90秒以下、好ましくは、30秒以下である方が好ましい。 Further, in the energization diffusion joining, the time for energizing the first member and the second member is preferably 90 seconds or less, preferably 30 seconds or less.
 また、前記第1部材は第1金属からなり、前記第2部材は前記第1部材とは材質の異なる第2金属からなるものを用いることができる。 Further, the first member may be made of a first metal, and the second member may be made of a second metal whose material is different from that of the first member.
 また、前記拡散接合は、前記第1金属と前記第2金属の接合面に通電して、その抵抗発熱により固相で拡散接合するものであってもよいし、液相で拡散接合するものであってもよい。 Further, the diffusion bonding may be one in which the bonding surface between the first metal and the second metal is energized and diffusion bonding is performed in a solid phase by the resistance heat generation thereof, or diffusion bonding is performed in a liquid phase. There may be.
 本発明のエンジンバルブによれば、接合部14が通電拡散接合により接合されるため、接合部14以外の金属組織の変質が少ない。また、接合部14の強度が非常に高い。 According to the engine valve of the present invention, since the joint portion 14 is joined by current diffusion joint, there is little deterioration of the metal structure other than the joint portion 14. Moreover, the strength of the joint portion 14 is very high.
本発明のエンジンバルブを示す側面図である。It is a side view which shows the engine valve of this invention. 本発明のエンジンバルブの接合前の状態を示す側面図と一部拡大図である。It is a side view and a partially enlarged view which shows the state before joining of the engine valve of this invention. 本発明のエンジンバルブを示す側面図と一部拡大図である。It is a side view and a partially enlarged view which shows the engine valve of this invention. 摩擦圧接接合で接合したエンジンバルブを示す側面図である。It is a side view which shows the engine valve which joined by friction welding welding.
 本発明のエンジンバルブ1について図1~図3を用いて説明する。本発明のエンジンバルブ1は、図1に示すように、少なくとも互いに接合された第1部材11と第2部材12を有するものである。ここで、第1部材11と第2部材12は、エンジンバルブ1を構成する部材であって、互いに接合されるものであればどのような組み合わせでもよい。例えば、バルブヘッドとバルブフェース、バルブフェースとバルブステム、バルブステムとバルブステムエンド等の組み合わせがある。図1(a)は、第1部材11をバルブフェース、第2部材12をバルブステムとしたものである。また、図1(b)は、第1部材11をバルブステム、第2部材12をバルブステムエンドとしたものである。また、エンジンバルブ1は、接合された部材を3以上有していてもよい。 The engine valve 1 of the present invention will be described with reference to FIGS. 1 to 3. As shown in FIG. 1, the engine valve 1 of the present invention has at least a first member 11 and a second member 12 joined to each other. Here, the first member 11 and the second member 12 may be any combination as long as they are members constituting the engine valve 1 and are joined to each other. For example, there are combinations of a valve head and a valve face, a valve face and a valve stem, a valve stem and a valve stem end, and the like. In FIG. 1A, the first member 11 is a valve face and the second member 12 is a valve stem. Further, in FIG. 1B, the first member 11 is a valve stem and the second member 12 is a valve stem end. Further, the engine valve 1 may have three or more joined members.
 第1部材11と第2部材12は5μm以内の拡散層13を介して接合される。拡散層13を5μm以内にすることで、接合部14以外の金属組織の変質が少なく、各部材の機能を保持したまま接合部14の強度の高いエンジンバルブを提供することができる。当該接合は、拡散層13の厚みを5μm以下、好ましくは3μm以下、さらに好ましくは1μm以下にする方がよい。なお、当該接合方法は、拡散層13の厚みを5μm以下にできればどのようなものでもよいが、例えば、後述する通電拡散接合を用いることができる。 The first member 11 and the second member 12 are joined via a diffusion layer 13 within 5 μm. By setting the diffusion layer 13 within 5 μm, it is possible to provide an engine valve having a high strength of the joint portion 14 while maintaining the function of each member with less deterioration of the metal structure other than the joint portion 14. In the bonding, the thickness of the diffusion layer 13 should be 5 μm or less, preferably 3 μm or less, and more preferably 1 μm or less. The joining method may be any method as long as the thickness of the diffusion layer 13 can be 5 μm or less, and for example, an energization diffusion joining described later can be used.
 通電拡散接合を用いる場合には、電流の流れを制御する必要がある。したがって、接合する前の第1部材11の接合面11aと第2部材12の接合面12aは、少なくともいずれか一方を凸状とし、はじめに点又は線で接触し、電流を流すと徐々に拡散層13が広がって接合する形状が好ましい。この場合、他方の接合面は、平面や鏡面のように、拡散接合時に少なくとも空隙ができない程度の滑らかな形状が好ましい。例えば、図2に示すように、接合する前の第1部材11の接合面11aと第2部材12の接合面12aの形状は、一方が凸状、他方が平面状に形成されたものを用いることができる。このように接合することにより、平面に接触している凸部の頂点から徐々に綺麗に拡散層13が広がるため、むらのない均一な拡散層13を形成することができる。したがって、接合部14の破壊強度を高めることができる。なお、接合面11aと接合面12aの両方を凸状とすることももちろん可能である。 When using a current diffusion junction, it is necessary to control the current flow. Therefore, at least one of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining is made convex, and first contact with a point or a line, and when an electric current is applied, a diffusion layer is gradually formed. A shape in which 13 is spread and joined is preferable. In this case, the other joint surface preferably has a smooth shape such as a flat surface or a mirror surface so that at least no voids are formed during diffusion bonding. For example, as shown in FIG. 2, as the shape of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining, one is formed in a convex shape and the other is formed in a flat shape. be able to. By joining in this way, the diffusion layer 13 gradually and neatly spreads from the apex of the convex portion in contact with the plane, so that a uniform diffusion layer 13 can be formed. Therefore, the breaking strength of the joint portion 14 can be increased. Of course, it is also possible to make both the joint surface 11a and the joint surface 12a convex.
 また、電気抵抗の高い部材の方が発熱し易いことから、第1部材11と第2部材12のうち電気抵抗が低い方の接合面を凸状とする方が均一な拡散層を形成し易い。 Further, since a member having a high electric resistance is more likely to generate heat, it is easier to form a uniform diffusion layer by making the joint surface of the first member 11 and the second member 12 having a lower electric resistance convex. ..
 なお、接合面が凸状とは、接合面の先端が点状又は線状であることを意味し、例えば、錐状や球面状としたり、接合面の断面を三角状やアーチ状としたりすることができる。また、凸状部分は接合面に1つだけ形成されるものでもよいし、複数形成されるものでもよい。接合面に凸状部分を複数形成する場合には、例えば、サンドブラスト処理や、ショットブラスト処理、エッチング処理、レーザ処理等、従来から知られている方法を用いることができる。 The convex shape of the joint surface means that the tip of the joint surface is point-shaped or linear, and for example, the joint surface may be conical or spherical, or the cross section of the joint surface may be triangular or arch-shaped. be able to. Further, only one convex portion may be formed on the joint surface, or a plurality of convex portions may be formed. When a plurality of convex portions are formed on the joint surface, conventionally known methods such as sand blast treatment, shot blast treatment, etching treatment, and laser treatment can be used.
 このように形成された第1部材11と第2部材12を接合すると、接合部14には、図3に示すように、拡散層13の形状が第1部材11と第2部材12のいずれか一方側に凸状に形成された部分を有することになる。より好ましいのは、上述したように、第1部材11と第2部材12のうち電気抵抗が低い方の接合面が凸状、電気抵抗の高い方の接合面が平面状であるものを接合した場合に形成される形状であり、具体的には、拡散層13の形状が、第1部材11と第2部材12のうち電気抵抗の高いほうに凸状に形成されるものが好ましい。なお、拡散層13に形成される凸状部分は複数であってもよい。 When the first member 11 and the second member 12 formed in this way are joined, the shape of the diffusion layer 13 is either the first member 11 or the second member 12 at the joint portion 14, as shown in FIG. It will have a convexly formed portion on one side. More preferably, as described above, the first member 11 and the second member 12 having a convex joint surface having a lower electric resistance and a flat joint surface having a higher electric resistance are joined. It is a shape formed in the case, and specifically, it is preferable that the shape of the diffusion layer 13 is formed to be convex toward the higher electrical resistance of the first member 11 and the second member 12. The number of convex portions formed on the diffusion layer 13 may be plural.
 また、第1部材11と第2部材は、各部材の機能を発揮できればどのような形状でもよく、従来から知られている一般的な形状を採用することができる。例えば、第1部材11と第2部材12は連通する中空部15を有していてもよい。中空部15とは、エンジンバルブ1の軽量化や熱容量の低減等を目的に内部を空洞にした部分である。 Further, the first member 11 and the second member may have any shape as long as they can exert the functions of the respective members, and a conventionally known general shape can be adopted. For example, the first member 11 and the second member 12 may have a hollow portion 15 that communicates with each other. The hollow portion 15 is a portion whose inside is hollow for the purpose of reducing the weight of the engine valve 1 and reducing the heat capacity.
 また、第1部材11の材料は金属(第1金属)からなる。第1部材11は、当該部材の機能を発揮できればどのような金属でもよいが、例えば、オーステナイト系ステンレス鋼やマルテンサイト系ステンレス鋼等の鋼材や、ニッケル合金、チタンおよびチタン合金等を用いることができる。具体例としては、バルブフェース(第1部材11)の材料としてSUH3などが挙げられる。 Also, the material of the first member 11 is made of metal (first metal). The first member 11 may be any metal as long as it can exhibit the function of the member, and for example, steel materials such as austenitic stainless steel and martensitic stainless steel, nickel alloys, titanium and titanium alloys may be used. it can. Specific examples include SUH3 as a material for the valve face (first member 11).
 また、第2部材12の材料は、第1部材11とは材質の異なる金属(第2金属)からなる。例えば、オーステナイト系ステンレス鋼やマルテンサイト系ステンレス鋼等の鋼材や、ニッケル合金、チタンおよびチタン合金等を用いることができる。また、材質の異なる金属とは、成分の異なる金属だけでなく、焼き入れの違いによりできた金属等、同じ成分でも性質の異なる金属も含まれる。第1部材11と第2部材12が同種の金属であると、接合界面がほとんど見られず、従来の摩擦圧接接合と比べて破壊強度が優れているという利点がある。具体例としては、バルブフェース(第1部材11)の材料としてSUH3を用いた場合には、バルブステム(第2部材12)としてSUH35を用いることができる。 Further, the material of the second member 12 is made of a metal (second metal) whose material is different from that of the first member 11. For example, steel materials such as austenitic stainless steel and martensitic stainless steel, nickel alloys, titanium and titanium alloys can be used. Further, the metals having different materials include not only metals having different components but also metals having the same components but different properties such as metals formed by different quenching. When the first member 11 and the second member 12 are made of the same type of metal, there is an advantage that the bonding interface is hardly seen and the fracture strength is superior to that of the conventional friction welding. As a specific example, when SUH3 is used as the material of the valve face (first member 11), SUH35 can be used as the valve stem (second member 12).
 次に、本発明のエンジンバルブ1の製造方法を説明する。本発明のエンジンバルブ1の製造方法は、通電拡散接合によって上述した第1部材11の接合面11aと第2部材12の接合面12aを接合するものである。 Next, the manufacturing method of the engine valve 1 of the present invention will be described. The method for manufacturing the engine valve 1 of the present invention is to join the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 described above by current diffusion joining.
 ここで、通電拡散接合とは、第1部材11と第2部材12の接合面に通電して、その抵抗発熱により固相又は液相で拡散接合するものである。通電拡散接合では、第1部材11と第2部材12の接合部14の変形が小さく、精密な接合が可能であるという利点がある。また、接合部14以外の金属組織の変質がほとんどないという利点もある。 Here, the energization diffusion bonding is a method in which the bonding surface of the first member 11 and the second member 12 is energized and diffusion bonding is performed in a solid phase or a liquid phase by the heat generation of the resistance. The current diffusion bonding has an advantage that the deformation of the bonding portion 14 between the first member 11 and the second member 12 is small and precise bonding is possible. It also has the advantage that there is almost no alteration of the metal structure other than the joint portion 14.
 通電拡散接合を用いる場合には、電流の流れを制御する必要がある。したがって、接合する前の第1部材11の接合面11aと第2部材12の接合面12aは、少なくともいずれか一方を凸状とし、はじめに点又は線で接触し、電流を流すと徐々に拡散層13が広がって接合する形状が好ましい。この場合、他方の接合面は、平面や鏡面のように、拡散接合時に少なくとも空隙ができない程度の滑らかな形状が好ましい。例えば、図2に示すように、接合する前の第1部材11の接合面11aと第2部材12の接合面12aの形状は、一方が凸状、他方が平面状に形成されたものを用いることができる。このように接合することにより、平面に接触している凸部の頂点から徐々に綺麗に拡散層13が広がるため、むらのない均一な拡散層13を形成することができる。したがって、接合部14の破壊強度を高めることができる。なお、接合面11aと接合面12aの両方を凸状とすることももちろん可能である。 When using a current diffusion junction, it is necessary to control the current flow. Therefore, at least one of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining is made convex, and first contact with a point or a line, and when an electric current is applied, a diffusion layer is gradually formed. A shape in which 13 is spread and joined is preferable. In this case, the other joint surface preferably has a smooth shape such as a flat surface or a mirror surface so that at least no voids are formed during diffusion bonding. For example, as shown in FIG. 2, as the shape of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining, one is formed in a convex shape and the other is formed in a flat shape. be able to. By joining in this way, the diffusion layer 13 gradually and neatly spreads from the apex of the convex portion in contact with the plane, so that an even and uniform diffusion layer 13 can be formed. Therefore, the breaking strength of the joint portion 14 can be increased. Of course, it is also possible to make both the joint surface 11a and the joint surface 12a convex.
 また、電気抵抗の高い部材の方が発熱し易いことから、第1部材11と第2部材12のうち電気抵抗が低い方の接合面を凸状とする方が均一な拡散層を形成し易い。 Further, since a member having a high electric resistance is more likely to generate heat, it is easier to form a uniform diffusion layer by making the joint surface of the first member 11 and the second member 12 having a lower electric resistance convex. ..
 なお、接合面が凸状とは、接合面の先端が点状又は線状であることを意味し、例えば、錐状や球面状としたり、接合面の断面を三角状やアーチ状としたりすることができる。また、凸状部分は接合面に1つだけ形成されるものでもよいし、複数形成されるものでもよい。接合面に凸状部分を複数形成する場合には、例えば、サンドブラスト処理や、ショットブラスト処理、エッチング処理、レーザ処理等、従来から知られている方法を用いることができる。 The convex shape of the joint surface means that the tip of the joint surface is point-shaped or linear, and for example, the joint surface may be conical or spherical, or the cross section of the joint surface may be triangular or arch-shaped. be able to. Further, only one convex portion may be formed on the joint surface, or a plurality of convex portions may be formed. When a plurality of convex portions are formed on the joint surface, conventionally known methods such as sand blast treatment, shot blast treatment, etching treatment, and laser treatment can be used.
 このように形成された第1部材11と第2部材12を接合すると、接合部14には、図3に示すように、拡散層13の形状が第1部材11と第2部材12のいずれか一方側に凸状に形成された部分を有することになる。より好ましいのは、上述したように、第1部材11と第2部材12のうち電気抵抗が低い方の接合面が凸状、電気抵抗の高い方の接合面が平面状であるものを接合した場合に形成される形状であり、具体的には、拡散層13の形状が、第1部材11と第2部材12のうち電気抵抗の高いほうに凸状に形成されるものが好ましい。なお、拡散層13に形成される凸状部分は複数であってもよい。 When the first member 11 and the second member 12 formed in this way are joined, the shape of the diffusion layer 13 is either the first member 11 or the second member 12 at the joint portion 14, as shown in FIG. It will have a convexly formed portion on one side. More preferably, as described above, the joint surface of the first member 11 and the second member 12 having the lower electric resistance is convex and the joint surface having the higher electric resistance is flat. It is a shape formed in the case, and specifically, it is preferable that the shape of the diffusion layer 13 is formed to be convex toward the higher electrical resistance of the first member 11 and the second member 12. The number of convex portions formed on the diffusion layer 13 may be plural.
 通電拡散接合には、例えば、以下に示す通電拡散接合装置を用いることができる。通電拡散接合装置は、接合面を当接された第1部材11と第2部材12に通電して拡散接合を行うものであって、電極と、電源と、温度情報提供部と、出力制御部と、加圧部とで主に構成される。 For the energization diffusion bonding, for example, the following energization diffusion bonding device can be used. The energization diffusion joining device is for performing diffusion bonding by energizing the first member 11 and the second member 12 with which the joint surfaces are abutted, and is an electrode, a power source, a temperature information providing unit, and an output control unit. And a pressurizing part.
 電極は、第1部材11と第2部材12に電源から出力された電気を導通させるためのものである。通電拡散接合装置には、第1部材11と第2部材12に電気を導通させるために少なくとも2つの電極を備えていればよく、例えば、第1部材11と第2部材12の接合面を挟んで対向する部分に設けられる。もちろん、第1部材11と第2部材12の材質や形状等によっては3以上の電極を備えていてもよい。電極の材質としては、第1部材11と第2部材12に電気を導通させることができればどのような材質でも良く、例えば、銅、モリブデン、タングステン等を用いることができる。また、電極はケーブルを介して電源と接続される。 The electrodes are for conducting electricity output from the power supply to the first member 11 and the second member 12. The energization diffusion joining device may be provided with at least two electrodes for conducting electricity to the first member 11 and the second member 12, for example, sandwiching the joining surface between the first member 11 and the second member 12. It is provided in the opposite part with. Of course, three or more electrodes may be provided depending on the material and shape of the first member 11 and the second member 12. The electrode may be made of any material as long as electricity can be conducted through the first member 11 and the second member 12, and for example, copper, molybdenum, tungsten, or the like can be used. Also, the electrodes are connected to the power supply via a cable.
 電源は複数の電極に電力を出力するためのものである。当該電源としては、複数の電極に付与する出力を連続的に変更可能であればどのようなものでもよいが、例えば、公知のインバータ電源を用いることができる。 The power supply is for outputting power to multiple electrodes. The power supply may be any power supply as long as the outputs applied to the plurality of electrodes can be continuously changed, and for example, a known inverter power supply can be used.
 温度情報提供部は、出力制御部に第1部材11と第2部材12又は電極の温度情報を提供するためのものである。なお、温度情報とは、第1部材11と第2部材12又は電極の温度に関する情報を意味し、温度そのままの情報であってもよいし、例えば電源の電圧を決める電圧値等、温度から計算によって変換された情報であってもよい。温度情報提供部としては、例えば、第1部材11と第2部材12又は電極の温度を検出する温度センサを用いることができる。温度センサは、接合部14材又は電極の温度を検出できればどのようなものでもよいが、例えば、赤外線放射温度計等のように非接触で温度を検出する非接触式センサや、第1部材11と第2部材12又は電極に接触させて温度を検出する熱電対等の接触式センサを用いればよい。また、非接触式のものと接触式のものを併用することも可能である。 The temperature information providing unit is for providing the output control unit with temperature information of the first member 11 and the second member 12 or the electrodes. The temperature information means information on the temperature of the first member 11 and the second member 12 or the electrode, and may be the information as it is, or is calculated from the temperature such as the voltage value that determines the voltage of the power supply. It may be the information converted by. As the temperature information providing unit, for example, a temperature sensor that detects the temperature of the first member 11, the second member 12, or the electrode can be used. The temperature sensor may be any one as long as it can detect the temperature of the joint 14 material or the electrode. For example, a non-contact sensor that detects the temperature in a non-contact manner such as an infrared radiation thermometer, or a first member 11 A contact type sensor such as a thermocouple that detects the temperature by contacting the second member 12 or the electrode may be used. It is also possible to use both a non-contact type and a contact type.
 ここで、本発明に係る通電拡散接合は第1部材11と第2部材12の接合面に電源の出力をアップスロープで制御して通電するものである方が好ましい。したがって、出力制御部は、温度情報提供部からの温度情報に基づいて電源の出力をアップスロープで制御するものが好ましい。従来は一定の電流を一定時間通電するか、あるいは一定の電流をON/OFF制御で通電していたため、電流の集中した箇所の温度が急激に上昇することがあった。この場合、当該箇所の接合状態が液相結合になる等、接合面の接合状態が不均一になり接合状態のばらつきにつながる。これに対しアップスロープ制御では、電流を徐々に上げていくため急激な電流集中が抑制され接合面の温度を均一にすることができる。したがって、接合面に均一な拡散層13を成長させることが可能となり、強度の均一化を図ることができる。特に、上述したように、接合する前の第1部材11の接合面11aと第2部材12の接合面12aのうち一方が凸状、他方が平面状に形成されたものを接合する場合には、電流の集中を抑制し、より均一な拡散層13を成長させることができるからである。 Here, it is preferable that the energization diffusion joint according to the present invention energizes the joint surface of the first member 11 and the second member 12 by controlling the output of the power supply with an upslope. Therefore, it is preferable that the output control unit controls the output of the power supply with an upslope based on the temperature information from the temperature information providing unit. Conventionally, a constant current is energized for a certain period of time, or a constant current is energized by ON / OFF control, so that the temperature of the place where the current is concentrated may rise sharply. In this case, the bonding state of the bonding surface becomes non-uniform, such as the bonding state of the relevant portion becoming a liquid phase bond, which leads to variations in the bonding state. On the other hand, in the upslope control, since the current is gradually increased, sudden current concentration can be suppressed and the temperature of the joint surface can be made uniform. Therefore, it is possible to grow a uniform diffusion layer 13 on the joint surface, and it is possible to achieve uniform strength. In particular, as described above, when one of the joint surface 11a of the first member 11 and the joint surface 12a of the second member 12 before joining is formed to be convex and the other is flat. This is because the concentration of electric current can be suppressed and a more uniform diffusion layer 13 can be grown.
 また、出力制御部は、温度センサで検出した温度情報に基づいてリアルタイムで電源の出力をアップスロープで連続制御し、第1部材11と第2部材12の緻密な温度管理を可能とすることができる。したがって、接合部14材同士の接合面における接合強度が高く、ばらつきの小さい接合を行うことができる。更に、このような連続制御は、ON/OFF制御と比べて熱膨張を一定に維持することができるため、熱膨張による圧力変動の影響を低減することができる。 In addition, the output control unit can continuously control the output of the power supply in real time with an upslope based on the temperature information detected by the temperature sensor, enabling precise temperature control of the first member 11 and the second member 12. it can. Therefore, the joining strength of the 14 joining portions on the joining surface is high, and it is possible to perform joining with little variation. Further, such continuous control can maintain a constant thermal expansion as compared with ON / OFF control, so that the influence of pressure fluctuation due to thermal expansion can be reduced.
 出力制御部としては、温度情報提供部からの温度情報に基づいて電源の出力をアップスロープで制御することができればどのようなものでもよいが、例えば、CPU、ROM、RAM、I/O等から構成され、操作部及び表示部が電気的に接続されているものを用いることができる。具体的には、高速サンプリング温度調節計のような公知のPID温度制御装置を用いることができる。なお、操作部は、ここでは、起動スイッチ、スタートスイッチ等の各種の操作スイッチ、タッチパネル等からなる入力盤などから構成されている。操作部から入力された情報は、出力制御部に送信される。また、表示部は、出力制御部への入力、又は出力制御部での演算結果に基づく情報を出力制御部から受信し、その情報を表示する。表示部は、ここでは、デジタル表示パネル、ランプなどから構成されている。 The output control unit may be any as long as the output of the power supply can be controlled by an upslope based on the temperature information from the temperature information providing unit. For example, from the CPU, ROM, RAM, I / O, etc. It is possible to use the one which is configured and the operation unit and the display unit are electrically connected. Specifically, a known PID temperature controller such as a high-speed sampling temperature controller can be used. The operation unit is composed of various operation switches such as a start switch and a start switch, an input panel including a touch panel, and the like. The information input from the operation unit is transmitted to the output control unit. Further, the display unit receives information based on the input to the output control unit or the calculation result in the output control unit from the output control unit, and displays the information. Here, the display unit is composed of a digital display panel, a lamp, and the like.
 なお、上述した温度情報提供部では、温度センサを用いて第1部材11と第2部材12又は電極の温度をリアルタイムで取得し、出力制御部に第1部材11と第2部材12又は電極の温度情報を提供する場合について説明した。しかし、通電拡散接合装置を使って同じ材料の第1部材11と第2部材12を同一環境で接合する場合、経過時間と第1部材11と第2部材12又は電極の温度の関係は同様の結果となる。そのため、予め経過時間と第1部材11と第2部材12又は電極の温度の関係を示す温度情報を取得しておけば、温度センサを用いなくても当該温度情報を提供することが可能となる。したがって、温度情報提供部は、第1部材11と第2部材12又は電極の経過時間と第1部材11と第2部材12又は電極の温度の関係を示す温度情報が格納された温度情報格納部であってもよい。これにより、出力制御部は、温度情報格納部に格納された温度情報に基づいて電源の出力を制御することができる。温度情報格納部は経過時間と電源の出力の関係を決定するための温度情報が格納できればどのようなものでもよいが、例えば、公知のメモリ等を用いればよい。 In the temperature information providing unit described above, the temperature of the first member 11 and the second member 12 or the electrode is acquired in real time by using the temperature sensor, and the output control unit of the first member 11 and the second member 12 or the electrode The case of providing temperature information has been described. However, when the first member 11 and the second member 12 of the same material are joined in the same environment using the current diffusion joining device, the relationship between the elapsed time and the temperature of the first member 11 and the second member 12 or the electrode is the same. The result is. Therefore, if the temperature information indicating the relationship between the elapsed time and the temperature of the first member 11 and the second member 12 or the electrode is acquired in advance, the temperature information can be provided without using the temperature sensor. .. Therefore, the temperature information providing unit is a temperature information storage unit that stores temperature information indicating the relationship between the elapsed time of the first member 11 and the second member 12 or the electrode and the temperature of the first member 11 and the second member 12 or the electrode. It may be. As a result, the output control unit can control the output of the power supply based on the temperature information stored in the temperature information storage unit. The temperature information storage unit may be any as long as it can store the temperature information for determining the relationship between the elapsed time and the output of the power supply, and for example, a known memory or the like may be used.
 加圧部は、第1部材11と第2部材12の接合面に圧力を付与するためのものである。加圧部の構成は、第1部材11と第2部材12の接合面に圧力を付与できればどのようなものでもよいが、例えば、電極が固定された加圧部材と、加圧部材を駆動させるための駆動源と、駆動源の駆動力を伝達し、加圧部材を上下動させるボールねじ機構とで構成すればよい。 The pressurizing portion is for applying pressure to the joint surface between the first member 11 and the second member 12. The structure of the pressurizing portion may be any as long as pressure can be applied to the joint surface between the first member 11 and the second member 12, but for example, the pressurizing member to which the electrodes are fixed and the pressurizing member are driven. It may be composed of a drive source for the purpose and a ball screw mechanism that transmits the driving force of the drive source and moves the pressurizing member up and down.
加圧部材は、第1部材11と第2部材12の形状に合わせて形成すればよいし、第1部材11と第2部材12の形状に合わせた中間部材を間に挟んでもよい。加圧部材の材質としては、加圧力に対する剛性があればどのようなものでもよいが、例えば、ステンレス、銅、モリブデン、タングステンなどの金属を用いればよい。  The pressurizing member may be formed according to the shapes of the first member 11 and the second member 12, or an intermediate member matching the shapes of the first member 11 and the second member 12 may be sandwiched between them. The material of the pressure member may be any material as long as it has rigidity against pressure, and for example, a metal such as stainless steel, copper, molybdenum, or tungsten may be used.
なお、加圧部材は、第1部材11と第2部材12を冷却するための冷却手段を有していてもよい。冷却手段としては、第1部材11と第2部材12を冷却可能なものであればどのようなものでもよいが、例えば、流路に水道水等の冷却流体を循環させる構成とすることができる。当該流路は、加圧部材自体に設けてもよいし、流路が形成された冷却ブロックを加圧部材に密接して配置してもよい。  The pressurizing member may have a cooling means for cooling the first member 11 and the second member 12. The cooling means may be any one as long as the first member 11 and the second member 12 can be cooled, and for example, a cooling fluid such as tap water may be circulated in the flow path. .. The flow path may be provided on the pressurizing member itself, or a cooling block on which the flow path is formed may be arranged in close contact with the pressurizing member.
駆動源は、例えば減速機付きのサーボモータを用いることができる。サーボモータには、エンコーダが付設されており、架台に配置されている。  As the drive source, for example, a servomotor with a speed reducer can be used. An encoder is attached to the servomotor and is arranged on a gantry.
ボールねじ機構は、上下方向に延び外周面にねじ溝が形成されたねじ軸と、内周面にねじ溝が形成されたナットと、これらのねじ溝間に収容された複数のボールとから構成されている。ナットは、加圧部材の上部にベークライト等からなる絶縁体及び圧力センサを介して固定されている。ねじ軸は、サーボモータの回転軸に減速機を介して接続されている。サーボモータが回転駆動することにより、ねじ軸が回転して、ナット、ひいては加圧部材がねじ軸に対して相対的に上下移動する。また、サーボモータの駆動を停止させると、加圧部材の位置が維持される。このとき、加圧部は、第1部材11と第2部材12の変位を規制して接合面に圧力を付与することになる。  The ball screw mechanism consists of a screw shaft extending in the vertical direction and having a thread groove formed on the outer peripheral surface, a nut having a thread groove formed on the inner peripheral surface, and a plurality of balls accommodated between these thread grooves. Has been done. The nut is fixed to the upper part of the pressurizing member via an insulator made of bakelite or the like and a pressure sensor. The screw shaft is connected to the rotating shaft of the servomotor via a speed reducer. When the servomotor is rotationally driven, the screw shaft rotates, and the nut, and thus the pressurizing member, moves up and down relative to the screw shaft. Further, when the driving of the servomotor is stopped, the position of the pressurizing member is maintained. At this time, the pressurizing portion regulates the displacement of the first member 11 and the second member 12 to apply pressure to the joint surface.
また、加圧部は、接合面の圧力を検出する圧力センサを有していてもよい。圧力センサは、例えば、上下方向の圧力を測定する一軸のロードセルであるが、多軸の圧力センサを用いてもよい。圧力センサにより、第1部材11と第2部材12同士の接合面に付与される圧力を間接的に検知することができる。  Further, the pressurizing unit may have a pressure sensor that detects the pressure on the joint surface. The pressure sensor is, for example, a uniaxial load cell that measures the pressure in the vertical direction, but a multi-axis pressure sensor may be used. The pressure sensor can indirectly detect the pressure applied to the joint surface between the first member 11 and the second member 12.
また、加圧部は、第1部材11と第2部材12同士の接合面に弾性力を付勢する弾性力付勢手段を更に備えていてもよい。例えば、加圧部材が配置されるベース部材と通電拡散接合装置の基台との間に弾性力付勢手段を配置する。弾性力付勢手段としては、例えば、ばねと、ばねをベース部材との間で自由長より短い予め設定された長さに規制するためのブロック体とから構成されている。なお、弾性力付勢手段によって押し上げられるベース部材から第1部材11と第2部材12に作用する圧力は、ばねを交換することによって変更可能である。このように構成することにより、第1部材11と第2部材12に熱膨張や熱収縮が生じても、接合面に作用する圧力の急激な変化を緩和することができる。  Further, the pressurizing portion may further include an elastic force urging means for urging the joint surface between the first member 11 and the second member 12. For example, an elastic force urging means is arranged between the base member on which the pressurizing member is arranged and the base of the current diffusion joining device. The elastic force urging means is composed of, for example, a spring and a block body for restricting the spring to a preset length shorter than the free length between the spring and the base member. The pressure acting on the first member 11 and the second member 12 from the base member pushed up by the elastic force urging means can be changed by exchanging the spring. With this configuration, even if thermal expansion or contraction occurs in the first member 11 and the second member 12, a sudden change in pressure acting on the joint surface can be alleviated.
なお、加圧部として上記のような構成について説明したが、加圧部は、第1部材11と第2部材12同士を接合面で押圧するためのものであれば他の構成でも構わない。例えば、単に、第1部材11と第2部材12の上に錘を乗せて、第1部材11と第2部材12同士を押圧するものを用いることも可能である。  Although the above-described configuration has been described as the pressurizing portion, the pressurizing portion may have any other configuration as long as it is for pressing the first member 11 and the second member 12 with each other at the joint surface. For example, it is also possible to simply put a weight on the first member 11 and the second member 12 and press the first member 11 and the second member 12 against each other.
また、通電加熱接合装置は、更に接合面に付与する圧力を制御するための圧力制御部を有していてもよい。圧力制御部は、例えば、CPU、ROM、RAM、I/O等から構成されており、操作部及び表示部が電気的に接続されている。操作部は、ここでは、起動スイッチ、スタートスイッチ等の各種の操作スイッチ、タッチパネル等からなる入力盤などから構成されている。操作部から入力された情報は、圧力制御部に送信される。また、表示部は、圧力制御部への入力、又は圧力制御部での演算結果に基づく情報を圧力制御部から受信し、その情報を表示する。表示部は、ここでは、デジタル表示パネル、ランプなどから構成されている。なお、当該圧力制御部は、上述した出力制御部と共通のものを用いることも可能である。  Further, the energization heating joining device may further have a pressure control unit for controlling the pressure applied to the joining surface. The pressure control unit is composed of, for example, a CPU, ROM, RAM, I / O, etc., and the operation unit and the display unit are electrically connected to each other. Here, the operation unit is composed of various operation switches such as a start switch and a start switch, an input panel including a touch panel, and the like. The information input from the operation unit is transmitted to the pressure control unit. Further, the display unit receives information from the pressure control unit based on the input to the pressure control unit or the calculation result in the pressure control unit, and displays the information. Here, the display unit is composed of a digital display panel, a lamp, and the like. It is also possible to use the same pressure control unit as the output control unit described above.
また、圧力制御部には、エンコーダ、圧力センサ及び温度センサから検知信号が入力される。圧力制御部は、これら検知信号、操作部から入力された情報及びその記憶部に格納された設定圧力Ps、下限設定圧力Ps1、設定温度Ts、設定保持時間Hsなどの制御情報に基づき、電源及びサーボモータに制御信号を出力する。  Further, detection signals are input to the pressure control unit from the encoder, the pressure sensor and the temperature sensor. The pressure control unit is based on these detection signals, information input from the operation unit, and control information such as set pressure Ps, lower limit set pressure Ps1, set temperature Ts, and set holding time Hs stored in the storage unit. Outputs a control signal to the servo motor.
 このように、上記通電拡散接合装置を用いた拡散接合は、第1部材11の接合面11aと第2部材12の接合面12aを当接し、第1部材11と第2部材12に通電して加熱する。これにより、第1部材11と第2部材12の接合面に拡散層13を成長させて接合することができる。なお、第1部材11や第2部材12の金属の組織変化を極力防ぐためには、通電時間を90秒以下とする方が好ましく、30秒以下とする方がさらに好ましい。これにより、第1部材11と第2部材12の拡散層13の厚みを5μm以下にすることができる。 As described above, in the diffusion bonding using the current diffusion bonding device, the bonding surface 11a of the first member 11 and the bonding surface 12a of the second member 12 are brought into contact with each other, and the first member 11 and the second member 12 are energized. Heat. As a result, the diffusion layer 13 can be grown and joined to the joint surface between the first member 11 and the second member 12. In addition, in order to prevent the structural change of the metal of the first member 11 and the second member 12 as much as possible, the energization time is preferably 90 seconds or less, and more preferably 30 seconds or less. As a result, the thickness of the diffusion layer 13 of the first member 11 and the second member 12 can be reduced to 5 μm or less.
1:エンジンバルブ
11:第1部材
11a:接合面
12:第2部材
12a:接合面
13:拡散層
14:接合部
15:中空部
1: Engine valve
11: First member
11a: Joint surface
12: Second member
12a: Joint surface
13: Diffusion layer
14: Joint
15: Hollow part

Claims (14)

  1.  互いに接合された第1部材と第2部材を有するエンジンバルブであって、
     前記第1部材と前記第2部材は5μm以内の拡散層を介して接合されていることを特徴とするエンジンバルブ。
    An engine valve having a first member and a second member joined to each other.
    An engine valve characterized in that the first member and the second member are joined via a diffusion layer within 5 μm.
  2.  前記第1部材と前記第2部材を連通する中空部を有することを特徴とする請求項1記載のエンジンバルブ。 The engine valve according to claim 1, further comprising a hollow portion that communicates the first member and the second member.
  3.  前記拡散層の形状は、前記第1部材と前記第2部材の少なくともいずれか一方に凸状に形成されたものあることを特徴とする請求項1又は2記載のエンジンバルブ。 The engine valve according to claim 1 or 2, wherein the shape of the diffusion layer is formed in a convex shape on at least one of the first member and the second member.
  4.  前記拡散層の形状は、前記第1部材と前記第2部材のうち電気抵抗の高い方に凸状に形成されたものあることを特徴とする請求項3記載のエンジンバルブ。 The engine valve according to claim 3, wherein the shape of the diffusion layer is formed in a convex shape on the side of the first member and the second member having a higher electric resistance.
  5.  前記第1部材は第1金属からなり、前記第2部材は前記第1部材とは異なる材質の第2金属からなることを特徴とする請求項1ないし4のいずれかに記載のエンジンバルブ。 The engine valve according to any one of claims 1 to 4, wherein the first member is made of a first metal, and the second member is made of a second metal having a material different from that of the first member.
  6.  互いに接合された第1部材と第2部材からなるエンジンバルブの製造方法であって、
     通電拡散接合によって前記第1部材の接合面と前記第2部材の接合面を接合することを特徴とするエンジンバルブの製造方法。
    It is a method of manufacturing an engine valve composed of a first member and a second member joined to each other.
    A method for manufacturing an engine valve, which comprises joining a joint surface of the first member and a joint surface of the second member by current diffusion joining.
  7.  前記第1部材と前記第2部材の少なくともいずれか一方の接合面を凸状とすることを特徴とする請求項6記載のエンジンバルブの製造方法。 The method for manufacturing an engine valve according to claim 6, wherein the joint surface of at least one of the first member and the second member is convex.
  8.  前記第1部材と前記第2部材のうち電気抵抗が低い方の接合面を凸状とすることを特徴とする請求項7記載のエンジンバルブの製造方法。 The method for manufacturing an engine valve according to claim 7, wherein the joint surface of the first member and the second member having the lower electric resistance is convex.
  9.  前記通電拡散接合は、前記第1部材と前記第2部材の接合面に電源の出力をアップスロープで制御して通電するものであることを特徴とする請求項6ないし8のいずれかに記載のエンジンバルブの製造方法。 The method according to any one of claims 6 to 8, wherein the energization diffusion joint energizes the joint surface between the first member and the second member by controlling the output of a power source with an upslope. How to manufacture an engine valve.
  10.  前記通電拡散接合において、前記第1部材と前記第2部材に通電する時間は90秒以下であることを特徴とする請求項6ないし9のいずれかに記載のエンジンバルブの製造方法。 The method for manufacturing an engine valve according to any one of claims 6 to 9, wherein in the current-carrying diffusion joint, the time for energizing the first member and the second member is 90 seconds or less.
  11.  前記通電拡散接合において、前記第1部材と前記第2部材に通電する時間は30秒以下であることを特徴とする請求項6ないし9のいずれかに記載のエンジンバルブの製造方法。 The method for manufacturing an engine valve according to any one of claims 6 to 9, wherein in the current-carrying diffusion joint, the time for energizing the first member and the second member is 30 seconds or less.
  12.  前記第1部材は第1金属からなり、前記第2部材は前記第1部材とは材質の異なる第2金属からなることを特徴とする請求項6ないし11のいずれかに記載のエンジンバルブの製造方法。 The manufacture of an engine valve according to any one of claims 6 to 11, wherein the first member is made of a first metal, and the second member is made of a second metal whose material is different from that of the first member. Method.
  13.  前記拡散接合は、前記第1金属と前記第2金属の接合面に通電して、その抵抗発熱により固相で拡散接合するものであることを特徴とする請求項6ないし12のいずれかに記載のエンジンバルブの製造方法。 The invention according to any one of claims 6 to 12, wherein the diffusion bonding is such that the bonding surface between the first metal and the second metal is energized and diffusion bonding is performed in a solid phase by heat generation of resistance thereof. How to make an engine valve.
  14.  前記拡散接合は、前記第1金属と前記第2金属の接合面に通電して、その抵抗発熱により液相で拡散接合するものであることを特徴とする請求項6ないし12のいずれかに記載のエンジンバルブの製造方法。 The method according to any one of claims 6 to 12, wherein the diffusion bonding is such that the bonding surface between the first metal and the second metal is energized and diffusion bonding is performed in a liquid phase by heat generation of resistance thereof. How to make an engine valve.
PCT/JP2020/019982 2019-05-21 2020-05-20 Engine valve and method for manufacturing same WO2020235603A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202080037290.0A CN113891774A (en) 2019-05-21 2020-05-20 Engine valve and method for manufacturing same
JP2021520823A JPWO2020235603A1 (en) 2019-05-21 2020-05-20

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2019-095574 2019-05-21
JP2019095574 2019-05-21

Publications (1)

Publication Number Publication Date
WO2020235603A1 true WO2020235603A1 (en) 2020-11-26

Family

ID=73459086

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2020/019982 WO2020235603A1 (en) 2019-05-21 2020-05-20 Engine valve and method for manufacturing same

Country Status (3)

Country Link
JP (1) JPWO2020235603A1 (en)
CN (1) CN113891774A (en)
WO (1) WO2020235603A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003334664A (en) * 2002-05-17 2003-11-25 Masao Hondo Joining method for members by pulse electrification
JP2007032465A (en) * 2005-07-28 2007-02-08 Nippon Steel Corp Lightweight engine valve superior in heat radiation
JP2008534288A (en) * 2005-04-07 2008-08-28 ダイムラー・アクチェンゲゼルシャフト Steel and metal aluminide components using friction welding methods and nickel alloy intermediate joints
WO2015145554A1 (en) * 2014-03-25 2015-10-01 本田技研工業株式会社 Bonded metal product

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4540392B2 (en) * 2003-06-02 2010-09-08 新日本製鐵株式会社 Liquid phase diffusion bonding method for metal machine parts
JP4757651B2 (en) * 2006-02-13 2011-08-24 オリジン電気株式会社 Resistance welding method for highly conductive metal materials
JP4550086B2 (en) * 2006-10-06 2010-09-22 オリジン電気株式会社 Projection welding method for highly conductive workpieces
WO2013065175A1 (en) * 2011-11-04 2013-05-10 Eco-A株式会社 Current diffusion bonding apparatus and current diffusion boding method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003334664A (en) * 2002-05-17 2003-11-25 Masao Hondo Joining method for members by pulse electrification
JP2008534288A (en) * 2005-04-07 2008-08-28 ダイムラー・アクチェンゲゼルシャフト Steel and metal aluminide components using friction welding methods and nickel alloy intermediate joints
JP2007032465A (en) * 2005-07-28 2007-02-08 Nippon Steel Corp Lightweight engine valve superior in heat radiation
WO2015145554A1 (en) * 2014-03-25 2015-10-01 本田技研工業株式会社 Bonded metal product

Also Published As

Publication number Publication date
CN113891774A (en) 2022-01-04
JPWO2020235603A1 (en) 2020-11-26

Similar Documents

Publication Publication Date Title
US9033205B2 (en) Friction stir welding with temperature control
US9669488B2 (en) Current diffusion bonding apparatus and current diffusion bonding method
JP6249019B2 (en) Friction welding method
US20070023401A1 (en) Electric joining method and electric joining apparatus
JP6231236B1 (en) Friction stir welding apparatus, friction stir welding control apparatus, and friction stir welding method
CA2818324C (en) Structural component and method of manufacture
CN106715026B (en) Method and device for joining a composite plate component to a further component
US20210194102A1 (en) Method for electrically contacting a battery block
JP4520422B2 (en) Energization joining apparatus and energization joining method
WO2020235603A1 (en) Engine valve and method for manufacturing same
JP4890633B2 (en) Current diffusion bonding apparatus and method
JP3894544B2 (en) Spot welding method
JP4890855B2 (en) Current-carrying method and apparatus
WO2020179855A1 (en) Conduction diffusion bonding device
JP5532466B1 (en) Projection bolt welding method to thin steel plate
WO2012026205A1 (en) Joining method for joining parts with high fatigue strength
JP7433663B2 (en) Dissimilar material solid phase joining method, dissimilar material solid phase joining structure, and dissimilar material solid phase joining device
US20150343548A1 (en) Method for joining wire
JP7242112B2 (en) Solid point welding method and solid point welding apparatus
WO2020235593A1 (en) Dental device and production method therefor
CN101439451A (en) Welding device and welding method
JP7187993B2 (en) Resistance welding method using resistance welding equipment
US9193632B2 (en) On the production of metal-ceramic compounds
JP2021041649A (en) Electric current heating bonding method for metal and resin bodies
US20240316689A1 (en) Solid-state joining method, solid-state joined joint, solid-state joined structure, and solid-state joining device

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20809618

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2021520823

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC - FORM 1205A (08.03.22)

122 Ep: pct application non-entry in european phase

Ref document number: 20809618

Country of ref document: EP

Kind code of ref document: A1