WO2020107685A1 - 一种敏化材料的制备方法及有机发光二极管 - Google Patents

一种敏化材料的制备方法及有机发光二极管 Download PDF

Info

Publication number
WO2020107685A1
WO2020107685A1 PCT/CN2019/072159 CN2019072159W WO2020107685A1 WO 2020107685 A1 WO2020107685 A1 WO 2020107685A1 CN 2019072159 W CN2019072159 W CN 2019072159W WO 2020107685 A1 WO2020107685 A1 WO 2020107685A1
Authority
WO
WIPO (PCT)
Prior art keywords
preparing
silica gel
column chromatography
gel column
sensitizing
Prior art date
Application number
PCT/CN2019/072159
Other languages
English (en)
French (fr)
Inventor
罗佳佳
Original Assignee
武汉华星光电半导体显示技术有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 武汉华星光电半导体显示技术有限公司 filed Critical 武汉华星光电半导体显示技术有限公司
Priority to US16/490,898 priority Critical patent/US11453691B2/en
Publication of WO2020107685A1 publication Critical patent/WO2020107685A1/zh

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65685—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine oxide or thioxide
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/805—Electrodes
    • H10K50/81—Anodes
    • H10K50/814—Anodes combined with auxiliary electrodes, e.g. ITO layer combined with metal lines
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/40—Organosilicon compounds, e.g. TIPS pentacene
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/654—Aromatic compounds comprising a hetero atom comprising only nitrogen as heteroatom
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6596—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having atoms other than oxygen, sulfur, selenium, tellurium, nitrogen or phosphorus as ring hetero atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1003—Carbocyclic compounds
    • C09K2211/1007—Non-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C09K2211/104—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom with other heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1096—Heterocyclic compounds characterised by ligands containing other heteroatoms
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00—Properties of the organic materials covered by group H10K85/00
    • H10K2101/20—Delayed fluorescence emission
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H10K50/12—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers comprising dopants
    • H10K50/121—OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers comprising dopants for assisting energy transfer, e.g. sensitization
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6572—Polycyclic condensed heteroaromatic hydrocarbons comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole

Definitions

  • the invention relates to the technical field of display, in particular to a preparation method of a sensitizing material and an organic light emitting diode.
  • the luminescent guest material that plays a leading role is crucial.
  • the luminescent guest materials used in early OLEDs were fluorescent materials. Since the ratio of singlet and triplet excitons in OLED is 1:3, the theoretical internal quantum efficiency (IQE) of OLED based on fluorescent materials It can reach 25%, which greatly limits the application of fluorescent electroluminescent devices.
  • TADF organic thermally activated delayed fluorescence
  • the existing TADF material has a very broad spectrum, which results in poor color gamut when applied in the blue light field, which greatly limits its development.
  • Ordinary blue fluorescence has a very narrow spectrum, but is limited to its theoretical quantum efficiency of only 25%.
  • blue phosphorescent materials have poor stability and short life, which reduces the service life of organic light-emitting diodes.
  • the purpose of the present invention is to provide a method for preparing a sensitizing material and an organic light emitting diode, which can improve the internal quantum efficiency, service life of the organic light emitting diode, and expand the color gamut.
  • the present invention provides a method for preparing a sensitized material, which includes:
  • the preset electron donor material includes 9,10-dihydro-9, At least one of 9-dimethylacridine, 9,10-dihydro-9,9-diphenylacridine, and 9,10-dihydro-9,9-diphenylsilaccridine;
  • the chemical structural formula of the sensitized material is:
  • R1 is a substituent
  • R1 includes the following chemical structural formula
  • the second silica gel column chromatography includes dichloromethane and n-hexane, and the volume ratio of the dichloromethane and the n-hexane in the second silica gel column chromatography is 1:1 to 3:1.
  • the first silica gel column chromatography includes methylene chloride and n-hexane, and the volumes of the methylene chloride and n-hexane in the first silica gel column chromatography The ratio is 3:2.
  • the weight range of the intermediate is 1.5 g-5 g, and the molar amount range is 3 mmol-7 mmol.
  • the weight range of the preset electron donor material is 0.5 g-2 g, and the molar amount range is 4 mmol-8 mmol.
  • the weight range of the palladium acetate is 20 mg-60 mg, and the molar amount range is 0.01 mmol-0.4 mmol.
  • the weight range of the tri-tert-butylphosphine tetrafluoroborate is 0.01 g-0.5 g, and the molar amount range is 0.2 mmol-0.9 mmol.
  • the weight range of the sodium tert-butoxide is 0.2 g-0.8 g, and the molar amount range is 3 mmol-9 mmol.
  • the invention provides a method for preparing a sensitized material, which includes:
  • the preset electron donor material includes 9,10-dihydro-9, At least one of 9-dimethylacridine, 9,10-dihydro-9,9-diphenylacridine, and 9,10-dihydro-9,9-diphenylsilaccridine;
  • the second reaction solution was extracted with dichloromethane and purified by second silica gel column chromatography to obtain a sensitized material.
  • the chemical structural formula of the sensitizing material is:
  • R1 is a substituent
  • R1 includes the following chemical structural formula
  • the first silica gel column chromatography includes methylene chloride and n-hexane, and the volumes of the methylene chloride and n-hexane in the first silica gel column chromatography The ratio is 3:2.
  • the second silica gel column chromatography includes methylene chloride and n-hexane, and the volume of the methylene chloride and n-hexane in the second silica gel column chromatography The ratio is 1:1 to 3:1.
  • the weight of the intermediate is in the range of 1.5 g to 5 g, and the molar amount is in the range of 3 mmol to 7 mmol.
  • the weight range of the preset electron donor material is 0.5 g-2 g, and the molar amount range is 4 mmol-8 mmol.
  • the weight range of the palladium acetate is 20 mg-60 mg, and the molar amount range is 0.01 mmol-0.4 mmol.
  • the weight range of the tri-tert-butylphosphine tetrafluoroborate is 0.01 g-0.5 g, and the molar amount range is 0.2 mmol-0.9 mmol.
  • the weight range of the sodium tert-butoxide is 0.2 g-0.8 g, and the molar amount range is 3 mmol-9 mmol.
  • the present invention also provides an organic light emitting diode, which includes an anode, a light emitting layer, and a cathode, wherein the material of the light emitting layer includes a sensitizing material, and the chemical structural formula of the sensitizing material is:
  • R1 is a substituent
  • R1 includes the following chemical structural formula
  • the material of the light emitting layer further includes DPEPD and fluorescent material.
  • the material of the cathode layer includes lithium fluoride and aluminum.
  • the material of the anode is indium tin oxide.
  • the preparation method of the sensitizing material and the organic light-emitting diode of the present invention by preparing a new sensitizing material, expand the color gamut of its application in the field of blue light, and improve the internal quantum efficiency and the service life of the organic light-emitting diode.
  • 1 is a schematic diagram of the distribution of the highest electron occupied orbit and the lowest electron unoccupied orbit of the compounds 1 to 3 of the present invention
  • FIG. 3 is a transient photoluminescence spectrum of compounds 1 to 3 of the present invention in a toluene solution
  • FIG. 4 is a schematic structural diagram of an organic light emitting diode of the present invention.
  • the preparation method of the sensitizing material of the present invention includes:
  • a 24 mL flask with a capacity of 100 mL is added with a weight of 5.24 g and a molar amount of 10 mmol of C 24 H 16 Br 2 P 2 , 60 mL of dichloromethane (DCM) and a concentration of 10 mL of A 30% aqueous solution of hydrogen peroxide (H 2 O 2 ) was then reacted at room temperature for 24 hours to obtain a first reaction liquid.
  • DCM dichloromethane
  • H 2 O 2 hydrogen peroxide
  • the first reaction solution was poured into 200 mL of ice water, and suction filtration was performed to obtain an off-white solid.
  • dichloromethane is used to dissolve the above white solid
  • the first silica gel column chromatography is used for separation and purification to obtain an intermediate
  • the intermediate is a white powder
  • the weight is 5.1 g
  • the yield of the intermediate is 92%
  • the first silica gel column chromatography includes methylene chloride and n-hexane, and the volume ratio of the methylene chloride and n-hexane is 3:2.
  • the preset electron donor material includes 9,10-dihydro-9,9-dimethylacridine, 9,10-dihydro-9,9-diphenylacridine and 9,10-dihydro At least one of -9,9-diphenylsilicoacridine.
  • the intermediate, the preset electron donor material, palladium acetate, and tri-tert-butylphosphine tetrafluoroborate are mixed in a two-necked bottle to obtain a mixed solution.
  • the weight range of the intermediate is 1.5g-5g, and the molar amount range is 3mmol-7mmol.
  • the weight range of the preset electron donor material is 0.5g-2g, and the molar amount range is 4mmol-8mmol.
  • the weight range of the palladium acetate is 20mg-60mg, and the molar amount range is 0.01mmol-0.4mmol.
  • the weight range of the tri-tert-butylphosphine tetrafluoroborate is 0.01g-0.5g, and the molar amount range is 0.2mmol-0.9mmol.
  • the two-neck flask containing the mixed solution into a glove box, in which the working gas of the glove box is argon, and the glove box is pre-filled with sodium tert-butoxide NaOt-Bu and dehydrated and deoxidized toluene,
  • the mixed solution reacts with sodium tert-butoxide NaOt-Bu and toluene in the glove box to obtain a second reaction solution.
  • the second reaction solution is subjected to multiple extractions with dichloromethane, the organic phases are combined, and purified using second silica gel column chromatography to obtain a sensitized material.
  • the sensitizing material includes at least one of C 54 H 44 N 2 O 2 P 2 , C 74 H 52 N 2 O 2 P 2 and C 72 H 52 N 2 O 2 P 2 Si 2 .
  • the second silica gel column chromatography includes methylene chloride and n-hexane, and the volume ratio of the methylene chloride and n-hexane is 1:1 to 3:1.
  • Embodiment 1 To a two-necked bottle with a capacity of 100 mL, add an intermediate with a weight of 2.80 g and a molar amount of 5 mmol, a weight of 1.14 g and a molar amount of 9,10-dihydro-9,9-di Methylacridine, palladium acetate (Pd(OAc) 2 ) with a weight of 45 mg and a molar amount of 0.2 mmol, tritert-butylphosphine tetrafluoroborate ((t- Bu) 3 HPBF 4 ) to make them mixed; then put the above two-necked bottle into the glove box, the working gas of the glove box is argon, and the glove box is pre-added with a weight of 0.58g and a molar amount of 6mmol of tert-butanol Sodium (NaOt-Bu) was also injected with 40 mL of toluene that was previously dehydrated and de
  • the mixed solution in the two-necked bottle and the sodium tert-butoxide and toluene in the glove box were reacted at a temperature of 120°C for 48 hours Second reaction liquid.
  • the second reaction liquid was poured into 50 mL of ice water, extracted three times with dichloromethane, the organic phases were combined, spinned into silica gel, and separated and purified by column chromatography to obtain a blue-white powdery sensitive substance.
  • the chemical material, namely compound 1 has a weight of 1.5 g and a yield of 37%.
  • the volume ratio of methylene chloride and n-hexane in column chromatography is 2:1.
  • TOL is an abbreviation for toluene.
  • Second embodiment To a two-necked flask with a capacity of 100 mL, add an intermediate with a weight of 2.80 g and a molar amount of 5 mmol, a weight of 2 g and a molar amount of 9,10-dihydro-9,9-diphenyl Acridine, 45mg, palladium acetate (Pd(OAc) 2 ) with a molar amount of 0.2mmol, trit-butylphosphine tetrafluoroborate ((t-Bu) with a weight of 0.17g, a molar amount of 0.6mmol ) 3HPBF4) to make them mixed; then put the above two-necked bottle into the glove box, the working gas of the glove box is argon, and the glove box is pre-added with a weight of 0.58g and a molar amount of 6mmol sodium tert-butoxide (NaOt -Bu), also inject 40 mL of toluene
  • Embodiment 3 to a two-necked flask with a capacity of 100 mL, respectively add an intermediate with a weight of 2.80 g and a molar amount of 5 mmol and a weight of 2 g and a molar amount of 9,10-dihydro-9,9-diphenyl with a molar amount of 6 mmol Acridine based silicon, 45mg, palladium acetate (Pd(OAc) 2 ) with a molar amount of 0.2mmol, trit-butylphosphine tetrafluoroborate ((t -Bu) 3 HPBF 4 ) to make it mixed; then put the above two-necked bottle into the glove box, the working gas of the glove box is argon, and the glove box is pre-added with a weight of 0.58 g and a molar amount of 6 mmol of tert-butyl Sodium alkoxide (NaOt-Bu) was also injected with
  • a second reaction liquid is obtained. Cool the second reaction liquid to room temperature, pour the second reaction liquid into 200 mL of ice water, extract three times with dichloromethane, combine the organic phases, spin into silica gel, and separate and purify by column chromatography to obtain a light blue powder
  • the sensitized material in the form of compound 3 was 2.2 g, and the yield was 40%.
  • the volume ratio of methylene chloride and n-hexane in column chromatography is 2:1.
  • R1 is a substituent
  • R1 includes the following chemical structural formula
  • the distribution of the highest electron occupied orbit (Highest Occupied Molecular Orbital, HOMO) and lowest electron unoccupied orbit (Lowest Unoccupied Molecular Orbital, LUMO) of the above compounds 1 to 3 are given.
  • the photoluminescence spectra of compounds 1 to 3 in toluene solution at room temperature are given.
  • the abscissa represents the wavelength in nm
  • the ordinate represents the normalized intensity (dimensionless), where 101 represents the spectrum of compound 1, 102 represents the spectrum of compound 2, and 103 represents the spectrum of compound 3. It can be seen that the spectra of compounds 1 to 3 are narrow and the color gamut is good. At the same time, the spectrum is very blue and the energy level is very high.
  • the transient photoluminescence spectra of compounds 1 to 3 in toluene solution at room temperature are given.
  • 201-203 represent the transient spectra of compounds 1 to 3, respectively.
  • the transient emission spectrum affects the luminescence lifetime of the material It can be seen that the luminescence lifetime of compounds 1 to 3 is relatively low. The lower the lifetime of the luminescent material, the better the lifetime of the device prepared therefrom. Moreover, the luminescence lifetime of compounds 1 to 3 decreases in sequence, so the longer the lifetime of the fabricated device. It can be seen that the sensitizing material prepared by the present invention has TADF characteristics, and has high internal quantum efficiency and a wide color gamut.
  • TADF materials have a molecular structure that combines an electron donor and an electron acceptor.
  • the electron donor (the electron donor of the present invention includes C 15 H 15 N, C 25 H 19 N, C 25 H 19 Nsi), the ability to provide electrons is different, the configuration is different, so as to adjust the torsion angle and charge transfer between the electron donor and the electron acceptor (biphosphorus oxygen as the intermediate nuclear electron acceptor) Characteristics, to achieve the purpose of reducing the lowest single and triple energy levels of target molecules and high energy levels, so that the above-mentioned sensitizing materials have an ultra-fast reverse intersystem crossing rate.
  • the preparation method of the present invention synthesizes a series of high-level TADF sensitizing materials with high TADF ratio and PLQY (photoluminescence quantum yield), doping the above sensitizing materials in the light-emitting layer to sensitize blue Fluorescence can reduce the internal quantum efficiency of organic light-emitting diodes to 100%, and the spectrum of the device is narrow, which enables the application of a wide color gamut.
  • the present invention further provides an organic light emitting diode, which includes an anode 22, a light emitting layer 23 and a cathode 25, wherein the material of the light emitting layer 23 includes the above-mentioned sensitizing material.
  • the material of the light-emitting layer includes DPEPD (bis[2-((oxo)diphenyl transient) phenyl] ether, with a molecular formula of C 36 H 28 O 3 P 2 ), a sensitizing material, and a fluorescent material.
  • the fluorescent material is preferably a blue fluorescent material.
  • the material of the anode 22 is ITO (indium tin oxide).
  • the organic light emitting diode of the present invention may further include a glass substrate 21, a hole transport layer and an injection layer 22, and an electron transport layer 24.
  • the material of the hole transport layer includes poly 3,4-ethylenedioxythiophene or polystyrenesulfonic acid Salt; the material of the hole injection layer includes a mixture of PEDOT:PSS; the material of the electron transport layer 24 includes 1,3,5-tris(3-(3-pyridyl)phenyl)benzene/Tm3PyPB; the cathode layer 25
  • Materials include lithium fluoride and aluminum.
  • the manufacturing method of the organic light emitting diode includes: spin-coating the material of the PESOT:PSS and the light-emitting layer on the washed conductive glass (ITO), and then sequentially depositing TmPyPB, LiF and Al under high vacuum conditions.
  • Organic light-emitting diodes 1 to 3 are prepared by this method using compounds 1 to 3, hereinafter referred to as devices 1 to 3.
  • the specific structure of the above devices is as follows: the thickness of the anode and hole injection layer is 50 nm; the thickness of the light-emitting layer is 40 nm, the electron The thickness of the transport layer 24 is 40 nm, the thickness of LiF in the cathode layer is 1 nm, and the thickness of Al is 100 nm, where the thickness ratio of DPEPO:compound 1:PAA in the light-emitting layer is 8:1.5:0.5.
  • the material of the light-emitting layer in the device 1 includes DPEPO: Compound 1: PAA.
  • the material of the light emitting layer in the device 2 includes DPEPO: Compound 2: PAA.
  • the material of the light emitting layer in the device 3 includes DPEPO: Compound 3: PAA.
  • the performance data of devices 1 to 3 are shown in Table 2:
  • the current-brightness-voltage characteristics of the device are completed by the Keithley source measurement system (Keithley 2400 Sourcemeter, Keithley 2000 Currentmeter) with a corrected silicon photodiode, and the electroluminescence spectrum is measured by SPEX CCD3000 spectrometer of French JY company Yes, all measurements are done in room temperature atmosphere.
  • the preparation method of the sensitizing material and the organic light-emitting diode of the present invention by preparing a new sensitizing material, expand the color gamut of its application in the field of blue light, and improve the internal quantum efficiency and the service life of the organic light-emitting diode.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Optics & Photonics (AREA)

Abstract

提供一种敏化材料的制备方法及有机发光二极管，该方法包括：将C24H16Br2P2、二氯甲烷加入过氧化氢水中反应，将反应物溶解于二氯甲烷中，并用第一硅胶柱层析提纯；将提纯物、预设电子给体材料、醋酸钯以及三叔丁基膦四氟硼酸盐放入叔丁醇钠和甲苯中反应；用二氯甲烷进行萃取，并用第二硅胶柱层析提纯。

Description

一种敏化材料的制备方法及有机发光二极管 【技术领域】
本发明涉及显示技术领域，特别是涉及一种敏化材料的制备方法及有机发光二极管。
【背景技术】
在OLED中，起主导作用的发光客体材料至关重要。早期的OLED使用的发光客体材料为荧光材料，由于在OLED中单重态和三重态的激子比例为1:3，因此基于荧光材料的OLED的理论内量子效率(Internal Quantum Efficiency,IQE)只能达到25％，极大的限制了荧光电致发光器件的应用。
纯有机热活化延迟荧光(delayed fluorescence，TADF)材料，通过巧妙的分子设计，使得分子具有较小的最低单三重能级差(ΔEST)，这样三重态激子可以通过反向系间窜越(RISC)回到单重态，再通过辐射跃迁至基态而发光，从而能够同时利用单、三重态激子，也可以实现100％的IQE。
但是现有的TADF材料，由于其较强的电荷转移特性，其光谱非常宽，导致其在蓝光领域应用时色域差，极大的 限制了其发展。普通蓝光荧光具有很窄的光谱，但是受限于其理论内量子效率仅达到25％，同时蓝光磷光材料稳定性差、寿命短，降低了有机发光二极管的使用寿命。
因此，有必要提供一种敏化材料的制备方法及有机发光二极管，以解决现有技术所存在的问题。
【发明内容】
本发明的目的在于提供一种敏化材料的制备方法及有机发光二极管，能够提高有机发光二极管的内量子效率、使用寿命以及扩大了色域。
为解决上述技术问题，本发明提供一种敏化材料的制备方法，其包括：
将C 24H 16Br 2P 2、二氯甲烷加入过氧化氢水溶液中反应，得到第一反应液，并过滤得到固体；
将所述固体溶解于二氯甲烷中，并用第一硅胶柱层析提纯，得到中间体；
将所述中间体、预设电子给体材料、醋酸钯以及三叔丁基膦四氟硼酸盐混合，得到混合液；所述预设电子给体材料包括9,10-二氢-9,9-二甲基吖啶、9,10-二氢-9,9-二苯基吖啶以及9,10-二氢-9,9-二苯基硅代吖啶中的至少一种；
将所述混合液放入加入有叔丁醇钠和甲苯的手套箱 中反应，得到第二反应液；以及
将所述第二反应液用二氯甲烷进行萃取，并用第二硅胶柱层析提纯，得到敏化材料；
其中所述敏化材料的化学结构式为：
Figure PCTCN2019072159-appb-000001
其中R1为取代基，R1包括以下化学结构式
Figure PCTCN2019072159-appb-000002
以及
Figure PCTCN2019072159-appb-000003
中的至少一种；
所述第二硅胶柱层析包括二氯甲烷和正己烷，所述第二硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为1:1至3:1。
在本发明的敏化材料的制备方法中，所述第一硅胶柱层析包括二氯甲烷和正己烷，所述第一硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为3:2。
在本发明的敏化材料的制备方法中，所述中间体的重量范围为1.5g—5g，摩尔量范围为3mmol—7mmol。
在本发明的敏化材料的制备方法中，所述预设电子给体材料的重量范围为0.5g—2g，摩尔量范围为4mmol—8mmol。
在本发明的敏化材料的制备方法中，所述醋酸钯的重量范围为20mg—60mg，摩尔量范围为0.01mmol—0.4mmol。
在本发明的敏化材料的制备方法中，所述三叔丁基膦四氟硼酸盐的重量范围为0.01g—0.5g，摩尔量范围为0.2mmol—0.9mmol。
在本发明的敏化材料的制备方法中，所述叔丁醇钠的重量范围为0.2g—0.8g，摩尔量范围为3mmol—9mmol。
本发明提供一种敏化材料的制备方法，其包括：
将C 24H 16Br 2P 2、二氯甲烷加入过氧化氢水溶液中反应，得到第一反应液，并过滤得到固体；
将所述固体溶解于二氯甲烷中，并用第一硅胶柱层析提纯，得到中间体；
将所述中间体、预设电子给体材料、醋酸钯以及三叔丁基膦四氟硼酸盐混合，得到混合液；所述预设电子给体材料包括9,10-二氢-9,9-二甲基吖啶、9,10-二氢-9,9-二苯基吖啶以及9,10-二氢-9,9-二苯基硅代吖啶中的至少一种；
将所述混合液放入加入有叔丁醇钠和甲苯的手套箱 中反应，得到第二反应液；
将所述第二反应液用二氯甲烷进行萃取，并用第二硅胶柱层析提纯，得到敏化材料。
在本发明的敏化材料的制备方法中，所述敏化材料的化学结构式为：
Figure PCTCN2019072159-appb-000004
其中R1为取代基，R1包括以下化学结构式
Figure PCTCN2019072159-appb-000005
以及
Figure PCTCN2019072159-appb-000006
中的至少一种。
在本发明的敏化材料的制备方法中，所述第一硅胶柱层析包括二氯甲烷和正己烷，所述第一硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为3:2。
在本发明的敏化材料的制备方法中，所述第二硅胶柱层析包括二氯甲烷和正己烷，所述第二硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为1:1至3:1。
在本发明的敏化材料的制备方法中，所述中间体的重 量范围为1.5g—5g，摩尔量范围为3mmol—7mmol。
在本发明的敏化材料的制备方法中，所述预设电子给体材料的重量范围为0.5g—2g，摩尔量范围为4mmol—8mmol。
在本发明的敏化材料的制备方法中，所述醋酸钯的重量范围为20mg—60mg，摩尔量范围为0.01mmol—0.4mmol。
在本发明的敏化材料的制备方法中，所述三叔丁基膦四氟硼酸盐的重量范围为0.01g—0.5g，摩尔量范围为0.2mmol—0.9mmol。
在本发明的敏化材料的制备方法中，所述叔丁醇钠的重量范围为0.2g—0.8g，摩尔量范围为3mmol—9mmol。
本发明还提供一种有机发光二极管，其包括：阳极、发光层以及阴极，其中所述发光层的材料包括敏化材料，所述敏化材料的化学结构式为：
Figure PCTCN2019072159-appb-000007
其中R1为取代基，R1包括以下化学结构式
Figure PCTCN2019072159-appb-000008
以及
Figure PCTCN2019072159-appb-000009
中的至少一种。
在本发明的有机发光二极管中，所述发光层的材料还包括DPEPD和荧光材料。
在本发明的有机发光二极管中，所述阴极层的材料包括氟化锂和铝。
在本发明的有机发光二极管中，所述阳极的材料为氧化铟锡。
本发明的敏化材料的制备方法及有机发光二极管，通过制备新的敏化材料，扩大了其在蓝光领域应用时的色域，且提高了内量子效率和有机发光二极管的使用寿命。
【附图说明】
图1为本发明化合物1至3的最高电子占据轨道与最低电子未占据轨道分布示意图；
图2为本发明化合物1至3在甲苯溶液中的光致发光光谱；
图3为本发明化合物1至3在甲苯溶液中的瞬态光致发光光谱；
图4为本发明的有机发光二极管的结构示意图。
【具体实施方式】
以下各实施例的说明是参考附加的图式，用以例示本发明可用以实施的特定实施例。本发明所提到的方向用语，例如「上」、「下」、「前」、「后」、「左」、「右」、「内」、「外」、「侧面」等，仅是参考附加图式的方向。因此，使用的方向用语是用以说明及理解本发明，而非用以限制本发明。在图中，结构相似的单元是以相同标号表示。
本发明的敏化材料的制备方法包括：
S101、将C 24H 16Br 2P 2、二氯甲烷加入过氧化氢水溶液中反应，得到第一反应液，并过滤得到固体；
例如，在一实施方式中，向容量为100mL的二口瓶中加入重量为5.24g，摩尔量为10mmol的C 24H 16Br 2P 2，60mL的二氯甲烷(DCM)以及10mL的浓度为30％的过氧化氢(H 2O 2)水溶液，然后在在室温下反应24小时，得到第一反应液。
之后，将第一反应液倒入200mL的冰水中，抽滤得灰白色固体。
S102、将所述固体溶解于二氯甲烷中，并用第一硅胶柱层析提纯，得到中间体；
例如，在一实施方式中，用二氯甲烷溶解上述白色固体，用第一硅胶柱层析分离纯化，得到中间体，中间体为 白色粉末，重量为5.1g，中间体的产率为92％。其中所述第一硅胶柱层析包括二氯甲烷和正己烷，该二氯甲烷和该正己烷的体积比为3:2。
上述S101、S102的简化化学方程式如下：
Figure PCTCN2019072159-appb-000010
其中R.T.代表室温，C 24H 16Br 2P 2的化学结构式为：
Figure PCTCN2019072159-appb-000011
其中中间体的化学式为C 24H 16Br 2O 2P 2，化学结构式为：
Figure PCTCN2019072159-appb-000012
S103、将所述中间体、预设电子给体材料、醋酸钯以及三叔丁基膦四氟硼酸盐混合，得到混合液；
其中所述预设电子给体材料包括9,10-二氢-9,9-二甲 基吖啶、9,10-二氢-9,9-二苯基吖啶以及9,10-二氢-9,9-二苯基硅代吖啶中的至少一种。
例如，将所述中间体、预设电子给体材料、醋酸钯以及三叔丁基膦四氟硼酸盐放入二口瓶中混合，得到混合液。
其中，所述中间体的重量范围为1.5g—5g，摩尔量范围为3mmol—7mmol。
其中，所述预设电子给体材料的重量范围为0.5g—2g，摩尔量范围为4mmol—8mmol。
其中，所述醋酸钯的重量范围为20mg—60mg，摩尔量范围为0.01mmol—0.4mmol。
其中，所述三叔丁基膦四氟硼酸盐的重量范围为0.01g—0.5g，摩尔量范围为0.2mmol—0.9mmol。
S104、并将所述混合液放入加入有叔丁醇钠和甲苯的手套箱中反应，得到第二反应液；
例如，将所述装有混合液的二口瓶放入手套箱中，其中手套箱的工作气体为氩气，手套箱预先加入有叔丁醇钠NaOt-Bu和除水除氧的甲苯，使所述混合液与手套箱中的叔丁醇钠NaOt-Bu和甲苯反应，得到第二反应液。
S105、将所述第二反应液用二氯甲烷进行萃取，并用第二硅胶柱层析提纯，得到敏化材料。
例如，将所述第二反应液用二氯甲烷进行多次萃取， 合并有机相，并用第二硅胶柱层析提纯，得到敏化材料。其中所述敏化材料包括C 54H 44N 2O 2P 2、C 74H 52N 2O 2P 2以及C 72H 52N 2O 2P 2Si 2中的至少一种。其中所述第二硅胶柱层析包括二氯甲烷和正己烷，该二氯甲烷和该正己烷的体积比为1:1至3:1。
上述步骤S103-S105的包括以下具体实施方式：
实施方式一、向容量为100mL的二口瓶中分别加入重量为2.80g，摩尔量为5mmol的中间体、重量为1.14g，摩尔量为6mmol的9,10-二氢-9,9-二甲基吖啶、重量为45mg，摩尔量为0.2mmol的醋酸钯(Pd(OAc) 2)、重量为0.17g，摩尔量为0.6mmol的三叔丁基膦四氟硼酸盐((t-Bu) 3HPBF 4)，使其混合；然后将上述二口瓶放入手套箱中，手套箱的工作气体为氩气，手套箱中预先加入重量为0.58g，摩尔量为6mmol的叔丁醇钠(NaOt-Bu)，还注入40mL事先除水除氧的甲苯，使上述二口瓶中的混合液和手套箱中的叔丁醇钠以及甲苯，在120℃的温度下反应48小时，得到第二反应液。将第二反应液冷却至室温，之后将第二反应液倒入50mL的冰水中，用二氯甲烷萃取三次，合并有机相，旋成硅胶，柱层析分离纯化，得到蓝白色粉末状的敏化材料，也即化合物1，该化合物1的重量为1.5g，产率37％。其中柱层析中二氯甲烷和正己烷的体积比为2:1。
其中实施方式一的具体化学方程式如下：
Figure PCTCN2019072159-appb-000013
其中上述化合物1的分子式为C 54H 44N 2O 2P 2，其化学结构式为：
Figure PCTCN2019072159-appb-000014
其中9,10-二氢-9,9-二甲基吖啶的化学式为C 15H 15N，其化学结构式为：
Figure PCTCN2019072159-appb-000015
TOL为甲苯(toluene)的缩写。
实施方式二，向容量为100mL的二口瓶中分别加入重量为2.80g，摩尔量为5mmol的中间体、重量为2g，摩尔量为6mmol的9,10-二氢-9,9-二苯基吖啶、重量为45mg，摩尔量为0.2mmol的醋酸钯(Pd(OAc) 2)、重量为0.17g，摩尔量为0.6mmol的三叔丁基膦四氟硼酸盐 ((t-Bu)3HPBF4)，使其混合；然后将上述二口瓶放入手套箱中，手套箱的工作气体为氩气，手套箱中预先加入重量为0.58g，摩尔量为6mmol的叔丁醇钠(NaOt-Bu)，还注入40mL事先除水除氧的甲苯，使上述二口瓶中的混合液和手套箱中的叔丁醇钠以及甲苯，在110℃的温度下反应24小时，得到第二反应液。将该第二反应液冷却至室温，并将该第二反应液倒入200mL的冰水中，用二氯甲烷萃取三次，合并有机相，旋成硅胶，柱层析分离纯化，得到淡蓝色粉末状的敏化材料，也即化合物2，该化合物2的重量为2.3g，产率43％。其中柱层析中二氯甲烷和正己烷的体积比为1:1。
其中实施方式二的具体化学方程式如下：
Figure PCTCN2019072159-appb-000016
其中上述化合物2的分子式为C 74H 52N 2O 2P 2，其化学结构式为：
Figure PCTCN2019072159-appb-000017
其中9,10-二氢-9,9-二苯基吖啶的化学式为C 25H 19N，其化学结构式为：
Figure PCTCN2019072159-appb-000018
实施方式三，向容量为100mL的二口瓶中分别加入重量为2.80g，摩尔量为5mmol的中间体、重量为2g，摩尔量为6mmol的9,10-二氢-9,9-二苯基硅代吖啶、重量为45mg，摩尔量为0.2mmol的醋酸钯(Pd(OAc) 2)、重量为0.17g，摩尔量为0.6mmol的三叔丁基膦四氟硼酸盐((t-Bu) 3HPBF 4)，使其混合；然后将上述二口瓶放入手套箱中，手套箱的工作气体为氩气，手套箱中预先加入重量为0.58g，摩尔量为6mmol的叔丁醇钠(NaOt-Bu)，还注入40mL事先除水除氧的甲苯，使上述二口瓶中的混合液和手套箱中的叔丁醇钠以及甲苯，在110℃的温度下反应24小时，得到第二反应液。将该第二反应液冷却至室温，并将该第二反应液倒入200mL的冰水中，用二氯甲烷萃取三次，合并有机相，旋成硅胶，柱层析分离纯化，得到淡蓝色粉末状的敏化材料，也即化合物3，该化合物3的重量为2.2g，产率40％。其中柱层析中二氯甲烷和正己烷的体积比为2:1。
其中实施方式三的具体化学方程式如下：
Figure PCTCN2019072159-appb-000019
其中上述化合物3的分子式为C 72H 52N 2O 2P 2Si 2，其化学结构式为：
Figure PCTCN2019072159-appb-000020
其中9,10-二氢-9,9-二苯基硅代吖啶的化学式为C 25H 19NSi，其化学结构式为：
Figure PCTCN2019072159-appb-000021
综上，上述敏化材料的化学结构式为：
Figure PCTCN2019072159-appb-000022
其中R1为取代基，R1包括以下化学结构式
Figure PCTCN2019072159-appb-000023
以及
Figure PCTCN2019072159-appb-000024
中的至少一种。
如图1所示，给出上述化合物1至3的最高电子占据轨道(Highest Occupied Molecular Orbital，HOMO)与最低电子未占据轨道(Lowest Unoccupied Molecular Orbital，LUMO)分布，图中第一行的结构分别代表化合物1至3的HOMO，图中第二行的结构分别代表化合物1至3的LUMO，不难看出上述化合物1至3的HOMO与LUMO轨道较密集，轨道越密集，轨道中心距离越远，因而电荷转移特性越强。
化合物1至3的最低单重态(S1)和最低三重态能级(T1)以及电化学能级，如表1所示：
表1
  PL Peak(nm) S 1(eV) T 1(eV) ΔE ST(eV) HOMO(eV) LUMO(eV)
化合物1 447 2.77 2.73 0.04 -5.49 -1.73
化合物2 420 2.95 2.90 0.05 -5.37 -1.72
化合物3 417 2.98 2.91 0.07 -5.39 -1.71
如图2所示，给出化合物1至3在室温下，甲苯溶液中的光致发光光谱，图2中横坐标代表波长，单位为nm，纵坐标表示归一化强度(无量纲)，其中101表示化合物1的光谱，102表示化合物2的光谱，103表示化合物3 的光谱，可以看出化合物1至3的光谱较窄，色域好，与此同时，光谱很蓝，能级很高。
如图3所示，给出化合物1至3在室温下，甲苯溶液中的瞬态光致发光光谱，201-203分别表示化合物1至3的瞬态光谱，瞬态发光光谱影响材料的发光寿命，可以看出化合物1至3的发光寿命都比较低，发光材料的寿命越低，其制备的器件的寿命会越好。且化合物1至3的发光寿命依次降低，因此制备的器件的寿命越好。由此可见，本发明制备的敏化材料具备TADF特性，且内量子效率较高，色域广。
通常TADF材料具有电子给体和电子受体相结合的分子结构，本发明通过筛选不同的电子给体单元，通过电子给体(本发明的电子给体包括C 15H 15N、C 25H 19N、C 25H 19Nsi)的不同，其提供电子的能力不同，构型不同，从而调节电子给体与电子受体(双磷氧作为中间核电子受体)之间的扭转角以及电荷转移特性，达到减小目标分子最低单三重能级差以及高能级的目的，从而使得上述敏化材料具有超快的反向系间窜越速率。
此外，本发明的制备方法，合成一系列具有高的TADF比例和PLQY(光致发光量子产率)的高能级TADF敏化材料，将上述敏化材料掺杂在发光层中，敏化蓝色荧光，可以将有机发光二极管的内量子效率到100％，同时器件 的光谱较窄，实现了广色域的应用。
如图4所示，本发明还提供一种有机发光二极管，其包括：阳极22、发光层23以及阴极25，其中所述发光层23的材料包括上述敏化材料。发光层的材料包括DPEPD(二[2-((氧代)二苯基瞬基)苯基]醚，分子式为C 36H 28O 3P 2)、敏化材料以及荧光材料。该荧光材料优选为蓝色荧光材料。阳极22的材料为ITO(氧化铟锡)。
本发明的有机发光二极管还可包括玻璃基板21、空穴传输层和注入层22、电子传输层24，空穴传输层的材料包括聚3，4-乙撑二氧噻吩或聚苯乙烯磺酸盐；空穴注入层的材料包括PEDOT:PSS的混合液；电子传输层24的材料包括1,3,5-三(3-(3-吡啶基)苯基)苯/Tm3PyPB；阴极层25的材料包括氟化锂和铝。
有机发光二极管的制作方法包括：在经过清洗的导电玻璃(ITO)上依次旋涂PESOT:PSS、发光层的材料，然后在高真空条件下依次蒸镀TmPyPB、LiF和Al。
通过该方法用化合物1至3制得有机发光二极管1至3，以下简称器件1至3，上述器件的具体结构如下：阳极、空穴注入层的厚度为50nm；发光层的厚度为40nm，电子传输层24的厚度为40nm，阴极层中的LiF的厚度为1nm，Al的厚度为100nm，其中发光层中DPEPO:化合物1:PAA的厚度比为8:1.5:0.5。
其中，器件1中发光层的材料包括DPEPO:化合物1:PAA。器件2中发光层的材料包括DPEPO:化合物2:PAA。器件3中发光层的材料包括DPEPO:化合物3:PAA。器件1至3的性能数据如表2所示：
表2
Figure PCTCN2019072159-appb-000025
可见，将上述敏化材料掺杂到发光层的材料中制备了一系列高性能的深蓝光荧光OLED。
其中，器件的电流-亮度-电压特性是由带有校正过的硅光电二极管的Keithley源测量系统(Keithley 2400 Sourcemeter、Keithley 2000 Currentmeter)完成的，电致发光光谱是由法国JY公司SPEX CCD3000光谱仪测量的，所有测量均在室温大气中完成。
本发明的敏化材料的制备方法及有机发光二极管，通过制备新的敏化材料，扩大了其在蓝光领域应用时的色域，且提高了内量子效率和有机发光二极管的使用寿命。
综上所述，虽然本发明已以优选实施例揭露如上，但上述优选实施例并非用以限制本发明，本领域的普通技术 人员，在不脱离本发明的精神和范围内，均可作各种更动与润饰，因此本发明的保护范围以权利要求界定的范围为准。

Claims (20)

  1. 一种敏化材料的制备方法，其包括：
    将C 24H 16Br 2P 2、二氯甲烷加入过氧化氢水溶液中反应，得到第一反应液，并过滤得到固体；
    将所述固体溶解于二氯甲烷中，并用第一硅胶柱层析提纯，得到中间体；
    将所述中间体、预设电子给体材料、醋酸钯以及三叔丁基膦四氟硼酸盐混合，得到混合液；所述预设电子给体材料包括9,10-二氢-9,9-二甲基吖啶、9,10-二氢-9,9-二苯基吖啶以及9,10-二氢-9,9-二苯基硅代吖啶中的至少一种；
    将所述混合液放入加入有叔丁醇钠和甲苯的手套箱中反应，得到第二反应液；以及
    将所述第二反应液用二氯甲烷进行萃取，并用第二硅胶柱层析提纯，得到敏化材料；
    其中所述敏化材料的化学结构式为：
    Figure PCTCN2019072159-appb-100001
    其中R1为取代基，R1包括以下化学结构式
    Figure PCTCN2019072159-appb-100002
    以及
    Figure PCTCN2019072159-appb-100003
    中的至少一种；
    所述第二硅胶柱层析包括二氯甲烷和正己烷，所述第二硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为1:1至3:1。
  2. 根据权利要求1所述的敏化材料的制备方法，其中
    所述第一硅胶柱层析包括二氯甲烷和正己烷，所述第一硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为3:2。
  3. 根据权利要求1所述的敏化材料的制备方法，其中
    所述中间体的重量范围为1.5g—5g，摩尔量范围为3mmol—7mmol。
  4. 根据权利要求1所述的敏化材料的制备方法，其中所述预设电子给体材料的重量范围为0.5g—2g，摩尔量范围为4mmol—8mmol。
  5. 根据权利要求1所述的敏化材料的制备方法，其中所述醋酸钯的重量范围为20mg—60mg，摩尔量范围为0.01mmol—0.4mmol。
  6. 根据权利要求1所述的敏化材料的制备方法，其中所述三叔丁基膦四氟硼酸盐的重量范围为0.01g—0.5g，摩尔量范围为0.2mmol—0.9mmol。
  7. 根据权利要求1所述的敏化材料的制备方法，其中所述叔丁醇钠的重量范围为0.2g—0.8g，摩尔量范围为3mmol—9mmol。
  8. 一种敏化材料的制备方法，其包括：
    将C 24H 16Br 2P 2、二氯甲烷加入过氧化氢水溶液中反应，得到第一反应液，并过滤得到固体；
    将所述固体溶解于二氯甲烷中，并用第一硅胶柱层析提纯，得到中间体；
    将所述中间体、预设电子给体材料、醋酸钯以及三叔丁基膦四氟硼酸盐混合，得到混合液；所述预设电子给体材料包括9,10-二氢-9,9-二甲基吖啶、9,10-二氢-9,9-二苯基吖啶以及9,10-二氢-9,9-二苯基硅代吖啶中的至少一种；
    将所述混合液放入加入有叔丁醇钠和甲苯的手套箱中反应，得到第二反应液；
    将所述第二反应液用二氯甲烷进行萃取，并用第二硅胶柱层析提纯，得到敏化材料。
  9. 根据权利要求8所述的敏化材料的制备方法，其中所述敏化材料的化学结构式为：
    Figure PCTCN2019072159-appb-100004
    其中R1为取代基，R1包括以下化学结构式
    Figure PCTCN2019072159-appb-100005
    以及
    Figure PCTCN2019072159-appb-100006
    中的至少一种。
  10. 根据权利要求8所述的敏化材料的制备方法，其中所述第一硅胶柱层析包括二氯甲烷和正己烷，所述第一硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为3:2。
  11. 根据权利要求8所述的敏化材料的制备方法，其中所述第二硅胶柱层析包括二氯甲烷和正己烷，所述第二硅胶柱层析中的所述二氯甲烷和所述正己烷的体积比为1:1至3:1。
  12. 根据权利要求8所述的敏化材料的制备方法，其中所述中间体的重量范围为1.5g—5g，摩尔量范围为3mmol—7mmol。
  13. 根据权利要求8所述的敏化材料的制备方法，其 中所述预设电子给体材料的重量范围为0.5g—2g，摩尔量范围为4mmol—8mmol。
  14. 根据权利要求8所述的敏化材料的制备方法，其中所述醋酸钯的重量范围为20mg—60mg，摩尔量范围为0.01mmol—0.4mmol。
  15. 根据权利要求8所述的敏化材料的制备方法，其中所述三叔丁基膦四氟硼酸盐的重量范围为0.01g—0.5g，摩尔量范围为0.2mmol—0.9mmol。
  16. 根据权利要求8所述的敏化材料的制备方法，其中所述叔丁醇钠的重量范围为0.2g—0.8g，摩尔量范围为3mmol—9mmol。
  17. 一种有机发光二极管，其包括：阳极、发光层以及阴极，其中所述发光层的材料包括敏化材料，所述敏化材料的化学结构式为：
    Figure PCTCN2019072159-appb-100007
    其中R1为取代基，R1包括以下化学结构式
    Figure PCTCN2019072159-appb-100008
    以及
    Figure PCTCN2019072159-appb-100009
    中的至少一种。
  18. 根据权利要求17所述的有机发光二极管，其中所述发光层的材料还包括DPEPD和荧光材料。
  19. 根据权利要求17所述的有机发光二极管，其中所述阴极层的材料包括氟化锂和铝。
  20. 根据权利要求17所述的有机发光二极管，其中所述阳极的材料为氧化铟锡。
PCT/CN2019/072159 2018-11-26 2019-01-17 一种敏化材料的制备方法及有机发光二极管 WO2020107685A1 (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US16/490,898 US11453691B2 (en) 2018-11-26 2019-01-17 Method for preparing sensitizing material and organic light emitting diode

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201811415628.2 2018-11-26
CN201811415628.2A CN109627265A (zh) 2018-11-26 2018-11-26 一种敏化材料的制备方法及有机发光二极管

Publications (1)

Publication Number Publication Date
WO2020107685A1 true WO2020107685A1 (zh) 2020-06-04

Family

ID=66069468

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2019/072159 WO2020107685A1 (zh) 2018-11-26 2019-01-17 一种敏化材料的制备方法及有机发光二极管

Country Status (3)

Country Link
US (1) US11453691B2 (zh)
CN (1) CN109627265A (zh)
WO (1) WO2020107685A1 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110205117A (zh) * 2019-06-11 2019-09-06 武汉华星光电半导体显示技术有限公司 苯基磷氧热活化延迟荧光材料及其合成方法、电致发光器件
US20210296586A1 (en) * 2020-03-23 2021-09-23 Wuhan China Star Optoelectronics Semiconductor Display Technology Co., Ltd. Thermally activated delayed flourescence (tadf) material, synthesizing method thereof, and electroluminescent device
CN114835752A (zh) * 2022-05-24 2022-08-02 广东工业大学 一种膦氧苯氰基类化合物及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106831874A (zh) * 2017-02-15 2017-06-13 黑龙江大学 基于膦杂芳基衍生物的热激发延迟荧光主体材料及其制备方法和应用
CN108794533A (zh) * 2017-04-27 2018-11-13 三星显示有限公司 杂环化合物和包括该杂环化合物的有机发光器件

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4066804A (en) 1969-11-26 1978-01-03 Imperial Chemical Industries Limited Metal deposition process
BE759243A (fr) * 1969-11-26 1971-05-21 Ici Ltd Procede de depot de metaux
CN107445913B (zh) * 2017-08-15 2020-04-24 武汉大学 一种含β-二酮结构的荧光材料及其制备与应用
CN107556292A (zh) * 2017-09-22 2018-01-09 苏州大学 吖啶‑咔唑给体衍生物及其制备方法以及基于其的有机电致发光器件
CN108358908A (zh) * 2018-01-11 2018-08-03 南京邮电大学 一种不对称热活化延迟荧光红光材料及其制备方法与应用
CN108658940A (zh) * 2018-07-18 2018-10-16 武汉华星光电半导体显示技术有限公司 热活化延迟荧光材料、其合成方法及oled发光器件
CN108864350A (zh) * 2018-08-20 2018-11-23 武汉华星光电半导体显示技术有限公司 热活化延迟荧光材料、合成方法、oled发光器件、显示装置

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106831874A (zh) * 2017-02-15 2017-06-13 黑龙江大学 基于膦杂芳基衍生物的热激发延迟荧光主体材料及其制备方法和应用
CN108794533A (zh) * 2017-04-27 2018-11-13 三星显示有限公司 杂环化合物和包括该杂环化合物的有机发光器件

Also Published As

Publication number Publication date
US20200181180A1 (en) 2020-06-11
CN109627265A (zh) 2019-04-16
US11453691B2 (en) 2022-09-27

Similar Documents

Publication Publication Date Title
Shi et al. Recent progress in thermally activated delayed fluorescence emitters for nondoped organic light-emitting diodes
Naveen et al. Deep blue diboron embedded multi-resonance thermally activated delayed fluorescence emitters for narrowband organic light emitting diodes
Hwang et al. Donor engineered Deep-Blue emitters for tuning luminescence mechanism in Solution-Processed OLEDs
Wu et al. Using fluorene to lock electronically active moieties in thermally activated delayed fluorescence emitters for high-performance non-doped organic light-emitting diodes with suppressed roll-off
TW201722890A (zh) 用於電子裝置之材料
US11434419B2 (en) Deep-red light thermally activated delayed fluorescent material and synthesizing method thereof, and electroluminescent device
CN110467606B (zh) 一种以氧杂蒽酮为核心的杂环化合物、制备方法及其应用
He et al. An extended π-backbone for highly efficient near-infrared thermally activated delayed fluorescence with enhanced horizontal molecular orientation
Kothavale et al. Rational design of CN substituted dibenzo [a, c] phenazine acceptor for color tuning of thermally activated delayed fluorescent emitters
WO2020107685A1 (zh) 一种敏化材料的制备方法及有机发光二极管
WO2020113789A1 (zh) 绿光热活化延迟荧光材料及其合成方法、电致发光器件
Lee et al. Achieving over 36% EQE in blue OLEDs using rigid TADF emitters based on spiro-donor and spiro-B-heterotriangulene acceptors
US20210355376A1 (en) Near-infrared thermal activated delayed fluorescent material, preparation method thereof, and display device
Guo et al. Exceptionally efficient deep blue anthracene-based luminogens: design, synthesis, photophysical, and electroluminescent mechanisms
Pan et al. Highly efficient solution-processable four-coordinate boron compound: A thermally activated delayed fluorescence emitter with short-lived phosphorescence for OLEDs with small efficiency roll-off
Chen et al. Highly efficient blue TADF emitters incorporating bulky acridine moieties and their application in solution-processed OLEDs
CN105481672A (zh) 一系列荧光oled材料
Alam et al. Acceptor interlocked molecular design for solution‐processed stable deep‐blue TADF and hyper fluorescence organic LED enabling high‐efficiency
Zhu et al. Molecular design of blue thermally activated delayed fluorescent emitters for high efficiency solution processable OLED via an intramolecular locking strategy
Li et al. Orange-red thermally activated delay fluorescence emitters based on asymmetric difluoroboron chelated enaminone: impact of donor position on luminescent properties
US11205756B2 (en) Green light thermally activated delayed fluorescence (TADF) material and application thereof
CN109943320B (zh) 热活化延迟荧光材料及其制备方法、有机发光器件
Xie et al. Constructing an efficient deep-blue TADF emitter by host-guest interactions towards solution-processed OLEDs with narrowband emission
Du et al. Spirofluorene-locked carbazole based multiple resonance thermally activated delayed fluorescence emitters for efficient solution-processed narrowband green OLEDs
Wang et al. Enhancing reverse intersystem crossing rate of red thermally activated delayed fluorescence emitters by simultaneously involving locally excited triplet states from donor and acceptor segments

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 19889184

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 19889184

Country of ref document: EP

Kind code of ref document: A1