WO2020104026A1 - Use of 1,2-alkane diols - Google Patents

Abstract

Suggested is the use of at least one 1,2-alkane diol as an anti-foaming agent in cosmetic compositions.

Description

USE OF 1,2-ALKANE DIOLS

FIELD OF INVENTION

[0001] The present invention refers to the area of cosmetics and to the use of 1,2-alkane diols as an anti-foaming agent. Further it refers to cosmetic compositions comprising 1,2-alkane diols and their specific applications.

BACKGROUND OF THE INVENTION

[0002] Cosmetic compositions often contain substances, which, for example when applied to the skin, have a strong foaming effect. The foaming in general occurs during the spreading of the cosmetic composition on the skin or hair. This may of course be beneficial in some applications, such as for example in shower gels or shampoos. However, in applications such as, for example, in a cream, lotion or aqueous solution, foaming behavior is not desirable.

[0003] There a known substances, for example silicones + ethanol, which can reduce the foaming behavior of cosmetic compositions during distribution on the skin. However, the application of silicones in cosmetics is still under considerable debate. Silicones in general replace high-quality vegetable oils, making them a cost-effective alternative for the industry. However, another critical issue is the environmental impact of silicones. As synthetic products, they are difficult to break down in nature. With cosmetics, however, tons of silicones are flushed into the sewage and thus into the environment.

[0004] Another issue is that especially in natural formulas, silicones are not allowed to use, because of their synthetic origin. Since years, the cosmetic industry is looking for other substances, which can act as anti-foaming agents and replace silicones in cosmetic compositions.

[0005] Therefore it was an object of the present invention to provide an anti-foaming agent, which can be used in natural formulas and which can replace silicones in cosmetic compositions.

DESCRIPTION OF THE INVENTION

[0006] A first object of the present invention refers to the use of at least one 1,2-alkane diol as an anti-foaming agent in cosmetic compositions.

[0007] The inventors have surprisingly found that 1,2-alkane diols show a great anti-foaming effect when used in cosmetic compositions. In a preferred embodiment according to the invention, the at least one 1,2-alkane diol has a chain length of from 5 to 12 carbon atoms.

1.2-alkanediols according to the present invention encompass particularly 1,2-pentanediol,

1.2-hexanediol, 1,2-octanediol, 1,2-decanediol, 1,2-dodecanediol and their mixtures. In a further preferred embodiment according to the invention, the 1,2-alkane diol is selected from 1,2-pentanediol glycol or 1,2-hexanediol.

[0008] According to the invention, an "anti-foaming agent", as previously explained above, is a substance which can reduce the foaming behavior of cosmetic compositions during distribution on the skin. The terms "foaming" and "soaping" can be used synonymously in the context of the invention.

[0009] In one embodiment according to the invention the at least one 1,2-alkane diol is used in an amount of from 0.1 to 10 % per weight, calculated on the cosmetic composition. In a preferred embodiment according to the invention the at least one 1,2-alkane diol is used in an amount of from 0.2 to 8% per weight, calculated on the cosmetic composition. In a further preferred embodiment according to the invention the at least one 1,2-alkane diol is used in an amount of from 0,5 to 5% per weight, calculated on the cosmetic composition.

[0010] In one embodiment according to the invention the cosmetic composition is selected from the group consisting of an emulsion, a mousse, a spray or a lotion. In an especially preferred embodiment according to the invention the cosmetic composition is a sunscreen lotion or color cosmetics. Color cosmetics in the sense of the present invention is to be understood as cosmetic with some color pigments, for example face make-up, as foundation, blushers, illuminators, face bronzing lotions, creams and powders, loose and pressed powders, mineral powders; Eye make-up, as eye shadows, eyeliners, eyebrow pencils, kohl and mascara, mineral powders; Lip make-up, as lipstick, lip glosses, lip pencils, lip plumpers, pots and palettes; Nail make-up, as nail varnishes and polishes, hardeners and strengtheners, base and top coat.

[0011 ] In a further embodiment the formulation of this invention is an aqueous solution e.g. a toner, facial water, body freshener or an eau de toilette/eau de parfume with low or no content of ethanol. In these formulation types solubilizers are used for incorporating/presolving lipophilic ingredients to achieve a clear solution. The solubilizers lead to a foaming behavior during application if no or low contents (0-5%) of ethanol are included due to ethanol acts as foaming inhibitor. Therefore it's a challenge to formulate low foaming formulations without or low content of ethanol. The addition of 1,2 alkanediols, especially 1,2-pentanediol, 1,2-hexanediol can reduce or avoid the foaming behaviour.

[0012] COSMETIC COMPOSITION

[0013] Another object of the present invention encompasses a cosmetic composition, comprising

(a) at least one 1,2-alkane diol;

(b) inorganics;

(c) water; and optionally

(d) emulsifier; (e) essential oils; and

(f) thickener,

wherein the cosmetic composition is free of silicones (polysiloxane).

[0014] In one embodiment according to the invention, the cosmetic composition is an aqueous solution. In another embodiment according to the invention the cosmetic composition is an emulsion.

[0015] In a preferred embodiment according to the invention the cosmetic composition comprises

(a) at least one 1,2-alkane diol;

(b) inorganics;

(c) water;

(d) emulsifier; and optionally

(e) essential oils; and

(f) thickener,

wherein the cosmetic composition is free of silicones (polysiloxane).

[0016] Silicones

Silicones, more precisely siloxanes, or more precisely, organo-substituted polysiloxanes, are linear or cyclic polymers of monomeric silicon/oxygen monomers.

The polymeric backbone is made up of alternating silicon and oxygen atoms. The silicon atoms may carry a wide variety of substituents which can be the same or different. The chemically least reactive substituents are the methyl or phenyl groups:

Dim ethic one CCyclotr (siloxane)

Phony! Trimethicone

[0017] The cosmetic composition according to the invention may additionally contain for example abrasives, anti-acne agents, preservatives, agents against ageing of the skin, anti cellulitis agents, antidandruff agents, anti-inflammatory agents, irritation-preventing agents, irritation-inhibiting agents, antioxidants, astringents, deodorant agents, perspiration- inhibiting agents, antiseptic agents, anti-statics, binders, buffers, carrier materials, chelating agents, cell stimulants, cleansing agents, care agents, depilatory agents, surface-active substances, deodorizing agents, antiperspirants, softeners, enzymes, essential oils, fibres, film-forming agents, fixatives, foam-forming agents, foam stabilizers, substances for preventing foaming, foam boosters, gelling agents, gel-forming agents, hair care agents, hair setting agents, hair-straightening agents, moisture-donating agents, moisturizing substances, moisture-retaining substances, bleaching agents, strengthening agents, stain-removing agents, optically brightening agents, impregnating agents, dirt-repellent agents, friction- reducing agents, lubricants, moisturizing creams, ointments, opacifying agents, plasticizing agents, covering agents, polish, gloss agents, polymers, powders, proteins, re-oiling agents, abrading agents, silicones, skin-soothing agents, skin-cleansing agents, skin care agents, skin healing agents, skin-lightening agents, skin-protecting agents, skin-softening agents, hair promotion agents, cooling agents, skin-cooling agents, warming agents, skin-warming agents, stabilizers, UV-absorbing agents, UV filters, detergents, fabric conditioning agents, suspending agents, skin-tanning agents, thickeners, vitamins, oils, waxes, a-hydroxy acids, liquefiers, dyestuffs, colour-protecting agents, pigments, anti-corrosives, aromas, flavouring substances, odoriferous substances, polyols, surfactants, electrolytes, organic solvents and the like as additional auxiliaries and additives. [0018] INORGANICS

[0019] This group includes mined materials, various inorganic gases, liquids, or solids, some elemental substances, and inorganic oxides. Excluded are all substances which are classified as Inorganic Salts, Inorganic Acids or Inorganic Bases. In the sense of the present invention, inorganics are chemically inert under conditions of cosmetic use. Some of them are used as pigments (e.g., Titanium Dioxide, Ultramarines, and Iron Oxides), while others are fillers, abrasives and smoothing agents (e.g., Kaolin, Talc, and Silica). The gaseous materials are used as propellants (e.g., Nitrogen). The clay-type materials (e.g., Magnesium Aluminum Silicate, Hectorite, and Montmorillonite) are used to increase the viscosity of aqueous suspensions. Hydrogen Peroxide is an important oxidizing agent which is used in cosmetics for hair bleaching and as a neutralizer in hair waving products, and to a lesser extent in oral care products. For example the following substances can be used as inorganics:

[0020] Activated Clay, Alexandrite Powder, Alluvial Mud, Alumina, Aluminum, Aluminum/Calcium/Manganese Oxide, Aluminum Calcium Sodium Silicate, Aluminum/Dysprosium/Europium/Strontium Oxide, Aluminum Hydroxide, Aluminum Hydroxide Oxide, Aluminum Iron Calcium Magnesium Germanium Silicates, Aluminum Iron Calcium Magnesium Zirconium Silicates, Aluminum Iron Silicates, Aluminum/Magnesium Azelate Hydroxide, Aluminum Magnesium Oxide, Aluminum Powder, Aluminum Zinc Carbonate Hydroxide, Aluminum Zinc Oxide, Amethyst Extract, Amethyst Powder, Ammonia, Ammonium Silver Zeolite, Ammonium Silver Zinc Aluminum Silicate, Andesite Extract, Anthracite Extract, Aqua, Aquamarine Extract, Aquamarine Powder, Attapulgite, Azurite, Azurite Extract, Bakuhan, Barium/Calcium/Silicon/Titanium Oxide, Barium Hexaferrite, Bentonite, Benzalkonium Montmorillonite, Benzalkonium Sepiolite, Benzoyl Peroxide, Biotite, Bronze Powder, Bronzite Powder, Calamine, Calcite, Calcite Powder, Calcium Aluminum Borosilicate, Calcium Carbonate/Calcium Hydroxide/Calcium

Oxide/Clay/lllite/Orthoclase/Oyster Shell Powder/Quartz Powder/Vermiculite/Zeolite Extract, Calcium Cerium Oxide, Calcium Cerium Phosphate, Calcium Ferrite, Calcium Hydroxyapatite, Calcium/Magnesium/Zinc Hydroxyapatite, Calcium Oxide, Calcium Peroxide, Calcium Sodium Borosilicate, Calcium Sodium Fluorophosphosilicate, Calcium Sodium Phosphosilicate, Calcium Titanium Borosilicate, Camellia Sinensis Leaf/Iron Hydroxide Powder, Canadian Colloidal Clay, Carbonado Extract, Carbon Dioxide, Ceria/Silica, Ceria/Silica Talc, Cerium Oxide, Chalk, Charcoal Extract, Chlorine Dioxide, Chromium Hydroxide Green, Chromium Oxide Greens, Chrysocolla, Cl 77000 (Aluminum Powder), Cl 77002 (Aluminum Hydroxide), Cl 77004 (Bentonite), Cl 77007 (Pigment Blue 29), Cl 77015 (Aluminum Silicate & Iron Oxide), Cl 77120 (Barium Sulfate), Cl 77163 (Bismuth Chloride Oxide), Cl 77220 (Calcium Carbonate), Cl 77231 (Calcium Sulfate), Cl 77266 (Carbon Black), Cl 77267 (Bone Charcoal), Cl 77268:1 (Carbo Medicinalis Vegetalis), Cl 77288 (Chromic Oxide), Cl 77289 (Chromium Hydroxide Green ), Cl 77346 (Cobalt Aluminum Oxide), Cl 77400 (Copper Powder), Cl 77480 (Gold), Cl 77491 (Ferric Oxide), Cl 77492 (Iron Hydroxide Oxide ), Cl 77499 (Black Iron Oxide), Cl 77510 (Ferric Ferrocyanide), Cl 77713 (Magnesium Carbonate), Cl 77742 (Ammonium Manganese Pyrophosphate), Cl 77745 (Manganese Orthophosphate), Cl 77820 (Silver), Cl 77891 (Titanium Dioxide), Cl 77947 (Zinc Oxide), Citrine, Citrine Extract, Clay, Clay Extract, Clay Mineral Oxides, Clay Minerals, Cobalt Aluminum Oxide, Cobalt Titanium Oxide, Colloidal Diamond, Colloidal Diamond/Gold, Colloidal Gold, Colloidal Palladium, Colloidal Platinum, Colloidal Silver, Colloidal Sulfur, Copper Powder, Copper Tripeptide-1, Copper Tripeptide-34, Copper Tripeptide-34 HCI, Cryolite Extract, Cuprous Iodide, Cuprous Oxide, Diamond Powder, Diatomaceous Earth, Dihydrogenated Tallow Benzylmonium Hectorite, Dolomite, Dolomite Powder, Elguea Clay, Emerald, Erbium Chloride, Europium Chloride, Feldspar Powder, Ferric Hexapeptide-35, Fuller's Earth, Garnet Powder, Germanium Dioxide, Glass, Glass Beads, Gold, Gold Zeolite, Halloysite, Hectorite, Heilmoor Clay, Hematite, Hematite Extract, Hematite Powder, Hokkaido Akan Clay, Holmium Oxide, Hydrated Silica, Hydrogen, Hydrogen Peroxide, Hydroxyapatite, lllite, I Mite Extract, Indium Silver Zinc Diethyldithiocarbamate Nitrate, Iron Hydroxide, Iron Oxides, Iron Titanium Oxide, Kaolin, Lapis Lazuli, Lapis Lazuli Extract, Lava Extract, Lava Powder, Lignite Extract, Lithium Cobalt Titanate, Lithium Magnesium Silicate, Lithium Magnesium Sodium Silicate, Lithium/Potassium/Iron/Titanium Oxides, Lithium/Potassium/Titanium Oxides, Loess, Loess Extract, Lutetium Chloride, Magnesium/Aluminum/Hydroxide/Carbonate,

Magnesium/Aluminum/Zinc/Hydroxide/Carbonate, Magnesium Hydride,

Magnesium/Manganese/Titanium Oxide, Magnesium Nitrate, Magnesium Oxide, Magnesium Peroxide, Magnesium Potassium Fluorosilicate,

Magnesium/Potassium/Silicon/Fluoride/Hydroxide/Oxide, Magnesium/Potassium/Titanium Chloride/Oxide, Magnesium Powder, Magnesium Sodium Fluorosilicate, Malachite, Malachite Extract, Manganese Dioxide, Manganese Oxide, Manganese Tripeptide-1, Manicouagan Clay, Marble Powder, Maris Aqua, Maris Limus Extract, Maris Sal, Meteorite Extract, Meteorite Powder, Mica, Mica Extract, Montmorillonite, Moonstone Extract, Moonstone Powder, Moroccan Lava Clay, Mother of Pearl, Mudstone Powder, Nephrite Extract, Nephrite Powder, Nitrogen, Nitrous Oxide, Olivine Extract, Onsen-Sui, Opal Powder, Orthoclase, Oxygen, Ozone, Palau White Clay, Palau White Clay Extract, Pegmatite, Perfluoroalkylsilyl Mica, Perlite, Phonolite, Phosphorus Pentoxide, Pigment Blue 27, Pigment Green 50, Plant Ash, Plant Ash Extract, Porphyridium/Zinc Ferment, Potassium Oxide, Potassium Vanadyl Tungstate Antimonate, Pumice, Pumice Extract, PVP Montmorillonite, Pyrite Powder, Pyrophyllite, Quartz, Quartz Powder, Quaternium-18 Bentonite, Quaternium-18/Benzalkonium Bentonite, Quaternium-18 Hectorite, Quaternium-90 Bentonite, Quaternium-90 Montmorillonite, Quaternium-90 Sepiolite, Radium Ore Powder, Rhodochrosite, Rhodochrosite Extract, Rhyolite Extract, Rhyolite Powder, Ruby Extract, Ruby Powder, Saccharomyces/Magnesium/Potassium/Sodium/Sulfur/Zinc Ferment Lysate Filtrate, Salt Mine Mud, Sand, Sapphire Extract, Sapphire Powder, Schist, Sea Salt Extract, Sea Silt, Sea Silt Extract, Sea Water, Sea Water Extract, Sedimentary Rock Powder, Selenium/Glycine, Soja (Soybean) Sprout Extract, Sepiolite, Sepiolite Extract, Shale Extract, Silica, Silicon/Titanium/Cerium/Iron Oxides, Silicon/Titanium/Cerium/Zinc Oxides, Sillimanite, Silt, Silt Extract, Silver, Silver Borosilicate, Silver Copper Zeolite, Silver Magnesium Aluminum Phosphate, Silver Oxide, Silver/Titanium Carbide, Smithsonite, Smithsonite Extract, Sodalite Powder, Sodium Chlorite, Sodium Magnesium Fluorosilicate, Sodium Magnesium Silver Phosphate, Sodium Oxide, Sodium Phosphorus/Zinc/Calcium/Silicon/Aluminum/Silver Oxides, Sodium Silver Aluminum Silicate, Soil Minerals, Solum Diatomeae, Solum Fullonum, Stearalkonium Bentonite, Stearalkonium Hectorite, Strontium Nitrate, Strontium Peroxide, Sulfur, Sunstone Powder, Synthetic Fluorphlogopite, Synthetic Moonstone Powder, Synthetic Ruby, Synthetic Ruby Powder, Synthetic Sapphire, Talc, Tanakura Clay, Terbium Chloride, Thorium Dioxide, Tin Oxide, Titanium Dioxide, Titanium Hydroxide, Titanium Nitride, Titanium Oxynitride, Titanium/Titanium Dioxide, Titanium Zeolite, Topaz, Tourmaline, Tourmaline Extract, Tourmaline Powder, Trona, Tungsten Oxide, Turquoise Powder, Ultramarines, Umber, Vermiculite, Vermiculite Extract, Volcanic Ash, Volcanic Ash Extract, Volcanic Rock, Volcanic Rock Extract, Volcanic Rock Powder, Volcanic Sand, Volcanic Soil, Volcanic Soil Extract, Water, Wollastonite, Xenotime, Yellow Ocher, Yttrium Oxide, Zeolite, Zinc Borosilicate, Zinc Cerium Oxide, Zinc Chloride Hydroxide, Zinc Hydroxyapatite, Zinc Oxide, Zinc Peroxide, Zinc/Strontium Fluoride Hydroxyapatite, Zinc Zeolite, Zirconium Dioxide.

[0021 ] In a preferred embodiment according to the invention the inorganic is an inorganic pigment. In a further preferred embodiment according to the invention the inorganic is selected from zinc oxide or titanium dioxide.

[0022] EMULSIFIER

[0023] According to the invention suitable emulsifiers are for example:

• products of the addition of 2 to 30 mol ethylene oxide and/or 0 to 5 mol propylene oxide onto linear Cs-22 fatty alcohols, onto C12-22 fatty acids and onto alkyl phenols containing 8 to 15 carbon atoms in the alkyl group;

• C12/18 fatty acid monoesters and diesters of addition products of 1 to 30 mol ethylene oxide onto glycerol;

• glycerol mono- and diesters and sorbitan mono- and diesters of saturated and unsaturated fatty acids containing 6 to 22 carbon atoms and ethylene oxide addition products thereof;

• addition products of 15 to 60 mol ethylene oxide onto castor oil and/or hydrogenated castor oil;

• polyol esters and, in particular, polyglycerol esters such as, for example, polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimerate isostearate. Mixtures of compounds from several of these classes are also suitable;

• addition products of 2 to 15 mol ethylene oxide onto castor oil and/or hydrogenated castor oil;

• partial esters based on linear, branched, unsaturated or saturated C6/22 fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, - dipentaerythritol, sugar alcohols (for example sorbitol), alkyl glucosides (for example methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (for example cellulose); • mono-, di and trialkyl phosphates and mono-, di- and/or tri-PEG-alkyl phosphates and salts thereof;

• wool wax alcohols;

• polysiloxane/polyalkyl polyether copolymers and corresponding derivatives;

• mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol and/or mixed esters of C -22 fatty acids, methyl glucose and polyols, preferably glycerol or polyglycerol,

• polyalkylene glycols and

• glycerol carbonate.

[0024] The addition products of ethylene oxide and/or propylene oxide onto fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or onto castor oil are known commercially available products. They are homologue mixtures of which the average degree of alkoxylation corresponds to the ratio between the quantities of ethylene oxide and/or propylene oxide and substrate with which the addition reaction is carried out. Cn/is fatty acid monoesters and diesters of addition products of ethylene oxide onto glycerol are known as lipid layer enhancers for cosmetic formulations. The preferred emulsifiers are described in more detail as follows:

[0025] Partial glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride and technical mixtures thereof which may still contain small quantities of triglyceride from the production process. Addition products of 1 to 30 and preferably 5 to 10 mol ethylene oxide onto the partial glycerides mentioned are also suitable.

[0026] Sorbitan esters. Suitable sorbitan esters are sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, sorbitan monoerucate, sorbitan sesquierucate, sorbitan dierucate, sorbitan trierucate, sorbitan monoricinoleate, sorbitan sesquiricinoleate, sorbitan diricinoleate, sorbitan triricinoleate, sorbitan monohydroxystearate, sorbitan sesquihydroxystearate, sorbitan dihydroxystearate, sorbitan trihydroxystearate, sorbitan monotartrate, sorbitan sesquitartrate, sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan sesquicitrate, sorbitan dicitrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan dimaleate, sorbitan trimaleate and technical mixtures thereof. Addition products of 1 to 30 and preferably 5 to 10 mol ethylene oxide onto the sorbitan esters mentioned are also suitable.

[0027] Polyglycerol esters. Typical examples of suitable polyglycerol esters are Polyglyceryl-2 Dipolyhydroxystearate (Dehymuls^® PGPH), Polyglycerin-3-Diisostearate (Lameform^® TGI), Polyglyceryl-4 Isostearate (Isolan^® Gl 34), Polyglyceryl-3 Oleate, Diisostearoyl Polyglyceryl-3 Diisostearate (Isolan^® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care^® 450), Polyglyceryl-3 Beeswax (Cera Beilina^®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010/90), Polyglyceryl-3 Cetyl Ether (Chimexane^® NL), Polyglyceryl-3 Distearate (Cremophor^® GS 32) and Polyglyceryl Polyricinoleate (Admul^® WOL 1403), Polyglyceryl Dimerate Isostearate and mixtures thereof. Examples of other suitable polyolesters are the mono-, di- and triesters of trimethylol propane or pentaerythritol with lauric acid, cocofatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like optionally reacted with 1 to 30 mol ethylene oxide.

[0028] Anionic emulsifiers. Typical anionic emulsifiers are aliphatic C12-22 fatty acids, such as palmitic acid, stearic acid or behenic acid for example, and C12-22 dicarboxylic acids, such as azelaic acid or sebacic acid for example.

[0029] Amphoteric emulsifiers. Other suitable emulsifiers are amphboteric or zwitterionic surfactants. Zwitterionic surfactants are surface-active compounds which contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule. Particularly suitable zwitterionic surfactants are the so-called betaines, such as the N-alkyl-N,N-dimethyl ammonium glycinates, for example cocoalkyl dimethyl ammonium glycinate, N-acylaminopropyl-N,N-dimethyl ammonium glycinates, for example coco- acylaminopropyl dimethyl ammonium glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl imidazolines containing 8 to 18 carbon atoms in the alkyl or acyl group and cocoacyl- aminoethyl hydroxyethyl carboxymethyl glycinate. The fatty acid amide derivative known under the CTFA name of Cocamidopropyl Betaine is particularly preferred. Ampholytic surfactants are also suitable emulsifiers. Ampholytic surfactants are surface-active compounds which, in addition to a Cs/is alkyl or acyl group, contain at least one free amino group and at least one -COOH- or -SO3H- group in the molecule and which are capable of forming inner salts. Examples of suitable ampholytic surfactants are N-alkyl glycines, N-alkyl propionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N- alkylamidopropyl glycines, N-alkyl taurines, N-alkyl sarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids containing around 8 to 18 carbon atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethyl aminopropionate and Ci2/i8 acyl sarcosine.

In a preferred embodiment according to the invention the emulsifiers / co-emulsifiers are selected from the group consisting of Ceteraryl alcool, cetearyl glucoside, glyceryl caprylate, cera alba, glyceryl undecylenate, lecithin, Glyceryl stearate (and other carbon chains), cocoglycerides, glyceryl stearate citrate, glyceryl oleate, stearic acid + palmitic acid, , cetyl alcohol, stearyl alcohol, Potassium Cetyl Phosphate (and other carbon chains), Hydrogenated Palm Glycerides, Sorbitan Laurate (and other carbon chains), Polyglyceryl-3 Caprylate (and other carbon chain) and polyglyceryl-x (different numbers) + carbon chains, Sodium Stearoyl glutamate, Glyceryl Stearate SE, Hydrogenated Vegetable Oil, Polyglyceryl-3 Ricinoleate, Hydrogenated Lecithin, beeswax, Lecithin, Sucrose Laurate (+ other carbon chain), Cetearyl Wheat Bran , Glucosides [0030] In a preferred embodiment according to the invention the emulsifier is selected from potassium cetyl phosphate and hydrogenated palm glycerides.

[0031 ] OIL BODIES

[0032] Suitable oil bodies, which form constituents of the O/W emulsions, are, for example, Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of linear C₆-C₂₂-fatty acids with linear or branched C₆-C₂₂-fatty alcohols or esters of branched C₆-C ₁₃-carboxylic acids with linear or branched C₆-C ₂₂-fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, stearyl isostearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. Also suitable are esters of linear C₆-C₂₂-fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of C₁₈-C₃₈- alkylhydroxy carboxylic acids with linear or branched C₆-C ₂₂-fatty alcohols, in particular Dioctyl Malate, esters of linear and/or branched fatty acids with polyhydric alcohols (such as, for example, propylene glycol, dimerdiol or trimertriol) and/or Guerbet alcohols, triglycerides based on C₆ -Cio-fatty acids, liquid mono-/di-/triglyceride mixtures based on C₆-Cis-fatty acids, esters of C₆- C₂₂-fatty alcohols and/or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, esters of C₂- Ci₂-dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C₆-C₂₂-fatty alcohol carbonates, such as, for example, Dicaprylyl Carbonate (Cetiol^® CC), Guerbet carbonates, based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of benzoic acid with linear and/or branched C₆-C₂₂-alcohols (e.g. Finsolv^® TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as, for example, dicaprylyl ether (Cetiol^® OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclomethicones, silicone methicone grades, etc.) and/or aliphatic or naphthenic hydrocarbons, such as, for example, squalane, squalene or dialkylcyclohexanes.

[0033] SUPERFATTING AGENTS AND CONSISTENCY FACTORS

[0034] Superfatting agents may be selected from such substances as, for example, lanolin and lecithin and also polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, the fatty acid alkanolamides also serving as foam stabilizers. [0035] The consistency factors mainly used are fatty alcohols or hydroxyfatty alcohols containing 12 to 22 and preferably 16 to 18 carbon atoms and also partial glycerides, fatty acids or hydroxyfatty acids. A combination of these substances with alkyl oligoglucosides and/or fatty acid N-methyl glucamides of the same chain length and/or polyglycerol poly-12- hydroxystea rates is preferably used.

[0036] THICKENING AGENTS AND RHEOLOGY ADDITIVES

[0037] Suitable thickeners are polymeric thickeners, such as Aerosil^® types (hydrophilic silicas), polysaccharides, more especially xanthan gum, guar-guar, agar-agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, also relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (for example Carbopols^® [Goodrich] or Synthalens^® [Sigma]), polyacrylamides, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, esters of fatty acids with polyols, for example pentaerythritol or trimethylol propane, narrow- range fatty alcohol ethoxylates and electrolytes, such as sodium chloride and ammonium chloride.

[0033] In a preferred embodiment according to the invention the thickener is a thickener of natural origin and is selected from the group consisting of Xanthan gum, Acacia Gum, cellulose gum, cellulose, Sclerotium gum, Algin, Microcrystalline cellulose, Carrageenan, Pectin, Carboxymethylcellulose, Gellan gum. In a most preferred embodiment according to the invention the thickener is pectin.

[0039] FRAGRANCES

[0040] The cosmetic composition can further contain fragrances. Fragrance Ingredients, according to the International Fragrance Association and in the sense of the present invention, are "any basic substance used in the manufacture of fragrance materials for its odorous, odor enhancing or blending properties. Fragrance ingredients may be obtained by chemical synthesis from synthetic, fossil, or natural raw materials, or by physical operations from natural sources. For example, the fragrance ingredient can also be botanical extracts. The function comprises also aroma chemicals, essential oils, natural extracts like botanical extracts, distillates and isolates, oleoresins, etc." Additionally, for purposes of labeling under "Fragrance" or "Parfum", the term Fragrance Ingredient signifies "any natural or synthetic substance or substances used solely to impart an odor to a cosmetic product".

[0041 ] For example, the following fragrances can be used in the cosmetic composition according to the present invention: 1-Acetonaphthone, 2,3-Butanediol, 2,4-Dimethyl-3- Cyclohexene Carboxaldehyde, 2,6-Dimethyl-7-Octen-2-ol, 2-Acetonaphthone, 2- Benzylheptanol, 2-Cyclohexylethyl Acetate, 2-Heptylcyclopentanone, 2-Methyl 5- Phenylpentanol, 2-Naphthol, 2-t-Butylcyclohexyl Acetate, 2-t-Butylcyclohexyloxybutanol, 3- Benzylidene Camphor, 3-Decenol, 3-Hexenol, 4-Ethoxybenzaldehyde, 4-Hydroxybenzoic Acid, 4-Methylbenzaldehyde, 4-t-Butyl Benzaldehyde, 4-t-Butylbenzoic Acid, 4-t-Butylcyclohexanol, 4-Terpineol, 6-Methyl Coumarin, Abies Alba Leaf Oil, Abies Balsamea (Balsam Canada) Bark Oil, Abies Balsamea (Balsam Canada) Needle Oil, Abies Balsamea (Balsam Canada) Resin, Abies Concolor Branch/Leaf/Wood Oil, Abies Grandis Oil, Abies Koreana Leaf Powder, Abies Pectinata Oil, Abies Sachalinensis Branch/Leaf Water, Abies Sachalinensis Leaf Oil, Abies Sibirica Oil, Abies Spectabilis Branch/Leaf Oil, Acacia Catechu Gum, Acacia Decurrens Flower Extract, Acacia Farnesiana Flower Extract, Acacia Senegal Gum, Acetaldehyde, Acetanilid, Acetyl Hexamethyl Indan, Acetyl Hexamethyl Tetralin, Acetyl Tributyl Citrate, Acetyl Triethyl Citrate, Acetylbenzofuran, Achillea Millefolium Extract, Achillea Millefolium Flower Water, Achillea Millefolium Oil, Achyrocline Satureioides Flower Oil, Actinidia Chinensis (Kiwi) Fruit Water, Adenium Obesum Leaf Cell Extract, Adesmia Boronioides Flower/Leaf/Stem Oil, Aegle Marmelos Leaf Oil, Aeollanthus Suaveolens Leaf Oil, Aesculus Hippocastanum (Horse Chestnut) Flower Water, Aetoxylon Sympetalum Wood Oil, Aframomum Angustifolium Leaf Oil, Agonis Fragrans Branch/Leaf Oil, Agropyron Repens Root Extract, Albizia Julibrissin Bark Extract, Aloe Barbadensis Leaf, Aloe Barbadensis Leaf Water, Alpha-Damascone, Alpha- Isomethyl lonone, Alpinia Formosana Leaf Oil, Alpinia Uraiensis Leaf Oil, Alpinia Uraiensis Leaf Water, Alpinia Zerumbet Leaf Oil, Amburana Cearensis Seed Oil, Amelanchier Alnifolia Flower Extract, Aminomethyl Propanediol, Ammonium Glycyrrhizate, Ampelopsis Japonica Root Powder, Amyl Acetate, Amyl Benzoate, Amyl Cinnamal, Amyl Salicylate, Amylcinnamyl Alcohol, Amyris Balsamifera Bark Oil, Anethole, Anethum Graveolens Seed Oil, Angelica Acutiloba Root Water, Angelica Archangelica Root Extract, Angelica Archangelica Root Oil, Angelica Archangelica Seed Oil, Angelica Dahurica Root Powder, Aniba Ferrea Wood Oil, Aniba Rosodora (Rosewood) Wood Extract, Aniba Rosodora (Rosewood) Wood Oil, Anisaldehyde, Anise Alcohol, Antennaria Microphylla Flower Extract, Anthemis Nobilis Flower Extract, Anthemis Nobilis Flower Oil, Anthemis Nobilis Flower Water, Anthemis Nobilis Flower/Leaf/Stem Oil, Anthoxanthum Odoratum Leaf/Stem Extract, Anthriscus Cerefolium Leaf Oil, Apium Graveolens (Celery) Root/Seed Extract, Aquilaria Agallocha Wood Oil, Aquilaria Malaccensis Wood Oil, Arnica Montana Flower Extract, Artemisia Afra Leaf/Stem Oil, Artemisia Annua Extract, Artemisia Capillaris Flower/Leaf/Stem Water, Artemisia Caruifolia Powder, Artemisia Dracunculus (Tarragon) Leaf/Stem Extract, Artemisia Herba-Alba Leaf Oil, Artemisia Herba-Alba Oil, Artemisia Pallens Flower Oil, Artemisia Pallens Flower/Leaf/Stem Oil, Artemisia Princeps Leaf Water, Artemisia Tridentata Leaf/Stem Oil, Asarum Canadense Root Oil, Asarum Sieboldii Root Water, Ascorbyl Palmitate, Astragalus Gummifer Gum, Astragalus Membranaceus Root Powder, Atractylodes Macrocephala Root/Stalk Powder, Azadirachta Indica Leaf Oil, Backhousia Citriodora Leaf Oil, Backhousia Citriodora Leaf/Twig Water, Barleria Prionitis Root Extract, Barleria Prionitis Stem Extract, Barosma Betulina Leaf Oil, Benzaldehyde, Benzyl Alcohol, Benzyl Benzoate, Benzyl Benzoyloxybenzoate, Benzyl Cinnamate, Benzyl Laurate, Benzyl Salicylate, Betula Alba Bark Extract, Betula Alba Bark/Leaf Extract, Betula Alba Leaf Extract, Betula Alba Oil, Betula Lenta Bark Oil, Bisabolol, Bixa Orellana Pulp Extract, Bixa Orellana Seed Extract, Bletilla Striata Root Water, Bletilla Striata Root/Stalk Powder, Boesenbergia Pandurata Root Oil, Borneol, Bornyl Acetate, Boronia Megastigma Flower Oil, Boswellia Carterii Gum Water, Boswellia Carterii Oil, Boswellia Carterii Resin Extract, Boswellia Frereana Resin Oil, Boswellia Neglecta Resin Oil, Boswellia Papyrifera Resin Oil, Boswellia Sacra Resin Oil, Boswellia Sacra Resin Water, Boswellia Serrata Gum, Boswellia Serrata Leaf Cell Extract, Boswellia Serrata Oil, Bourbon Extract, Brachychiton Acerifolius Leaf Extract, Bulnesia Sarmientoi Wood Oil, Bursera Bipinnata Resin Extract, Bursera Graveolens Fruit Oil, Bursera Graveolens Wood Oil, Butyl Acetate, Butyl Benzoate, Butyl Lactate, Butyl Methacrylate, Butylphenyl Methylpropional, Butyric Acid, Butyrolactone, Calendula Officinalis Flower Extract, Calendula Officinalis Flower Oil, Calendula Officinalis Flower Water, Callitris Columellaris Leaf/Twig Oil, Callitris Intratropica Wood Oil, Callitris Quadrivalvis Gum, Calluna Vulgaris Flower Water, Calocedrus Decurrens Leaf/Stem Oil, Calochortus Tolmiei Flower Extract, Camellia Japonica Seed Water, Camellia Oleifera Leaf, Camellia Sinensis Leaf Extract, Camellia Sinensis Leaf Water, Camphene, Camphor, Camphylcyclohexanol, Cananga Odorata Flower Oil, Cananga Odorata Flower Wax, Cananga Odorata Leaf Oil, Canarium Commune Gum Oil, Canarium Luzonicum Gum Nonvolatiles, Caprylic Acid, Caprylyl Butyrate, Carthamus Tinctorius (Safflower) Flower, Carthamus Tinctorius (Safflower) Seed Oil, Carum Carvi (Caraway) Fruit Oil, Carum Carvi (Caraway) Seed Extract, Carum Carvi (Caraway) Seed Oil, Carum Copticum Fruit Extract, Carum Petroselinum (Parsley) Seed Oil, Carvacrol, Carvone, Cedrol, Cedrus Atlantica Bark Oil, Cedrus Atlantica Wood Oil, Cedrus Deodara Wood Oil, Ceratonia Siliqua (Carob) Fruit Extract, Ceratonia Siliqua (Carob) Gum, Cestrum Nocturnum Branch/Flower/Leaf Water, Chaenomeles Speciosa Flower Extract, Chamaecyparis Lawsoniana Wood Oil, Chamaecyparis Obtusa Oil, Chamaecyparis Obtusa Water, Chamaecyparis Obtusa Wood Oil, Chamomilla Recutita (Matricaria) Flower Extract, Chamomilla Recutita (Matricaria) Flower Oil, Chamomilla Recutita (Matricaria) Flower Water, Chamomilla Recutita (Matricaria) Flower/Leaf/Stem Water, Chamomilla Recutita (Matricaria) Leaf Extract, Chamomilla Recutita (Matricaria) Oil, Chrysanthemum Indicum Flower/Leaf/Stem Oil, Chrysanthemum Indicum Leaf Oil, Chrysanthemum Parthenium (Feverfew) Flower/Leaf/Stem Water, Chrysanthemum Zawadskii Water, Cichorium Intybus (Chicory) Leaf Extract, Cichorium Intybus (Chicory) Root Extract, Cinnamal, Cinnamomum Camphora (Camphor) Bark Oil, Cinnamomum Camphora (Camphor) Branch/Stem Oil, Cinnamomum Camphora (Camphor) Branch/Stem Water, Cinnamomum Camphora (Camphor) Leaf Extract, Cinnamomum Camphora (Camphor) Leaf Oil, Cinnamomum Camphora (Camphor) Oil, Cinnamomum Camphora (Camphor) Wood Oil, Cinnamomum Camphora Linaloolifera Leaf Oil, Cinnamomum Cassia Bark Oil, Cinnamomum Cassia Bark/Myristica Fragrans (Nutmeg) Shell/Piper Nigrum (Pepper) Seed/Syzygium Aromaticum Flower Oil, Cinnamomum Cassia Leaf Oil, Cinnamomum Cassia Oil, Cinnamomum Japonicum Leaf Oil, Cinnamomum Tamala Leaf Oil, Cinnamomum Zeylanicum Bark Oil, Cinnamomum Zeylanicum Leaf Oil, Cinnamyl Acetate, Cinnamyl Alcohol, Cistus Ladaniferus Leaf/Stem Extract, Cistus Ladaniferus Oil, Cistus Ladaniferus Resin, Cistus Monspeliensis Extract, Citral, Citric Acid, Citronellal, Citronellic Acid, Citronellol, Citronellyl Acetate, Citronellyl Methylcrotonate, Citrus Aurantifolia (Lime) Fruit Oil, Citrus Aurantifolia (Lime) Leaf Oil, Citrus Aurantifolia (Lime) Oil, Citrus Aurantifolia (Lime) Peel Oil, Citrus Aurantifolia (Lime) Peel Water, Citrus Aurantifolia (Lime) Seed Oil, Citrus Aurantium Amara (Bitter Orange) Flower Oil, Citrus Aurantium Amara (Bitter Orange) Flower Water, Citrus Aurantium Amara (Bitter Orange) Leaf/Twig Oil, Citrus Aurantium Amara (Bitter Orange) Peel Extract, Citrus Aurantium Amara (Bitter Orange) Peel Oil, Citrus Aurantium Bergamia (Bergamot) Fruit Oil, Citrus Aurantium Bergamia (Bergamot) Peel Oil, Citrus Aurantium Currassuviensis Peel Oil, Citrus Aurantium Dulcis (Orange) Flower Oil, Citrus Aurantium Dulcis (Orange) Fruit Extract, Citrus Aurantium Dulcis (Orange) Fruit Water, Citrus Aurantium Dulcis (Orange) Oil, Citrus Aurantium Dulcis (Orange) Peel Oil, Citrus Aurantium Dulcis (Orange) Seed Oil, Citrus Clementina Peel Oil, Citrus Grandis (Grapefruit) Peel Oil, Citrus Grandis/Paradisi Fruit Water, Citrus Hystrix Fruit/Sucrose Ferment Filtrate, Citrus Hystrix Leaf Oil, Citrus Hystrix Leaf Water, Citrus Hystrix Peel Oil, Citrus Jabara Peel Oil, Citrus Jabara Peel Powder, Citrus Jabara Peel Water, Citrus Junos Flower Oil, Citrus Junos Fruit Oil, Citrus Junos Fruit Water, Citrus Junos Peel Powder, Citrus Keraji Fruit Water, Citrus Limon (Lemon) Flower/Leaf/Stem Extract, Citrus Limon (Lemon) Flower/Leaf/Stem Oil, Citrus Limon (Lemon) Fruit Extract, Citrus Limon (Lemon) Fruit Water, Citrus Limon (Lemon) Leaf Oil, Citrus Limon (Lemon) Peel, Citrus Limon (Lemon) Peel Oil, Citrus Limon (Lemon) Seed Oil, Citrus Medica Vulgaris Peel Oil, Citrus Natsudaidai Flower Oil, Citrus Natsudaidai Flower Water, Citrus Natsudaidai Peel Water, Citrus Nobilis (Mandarin Orange) Fruit Extract, Citrus Nobilis (Mandarin Orange) Oil, Citrus Nobilis (Mandarin Orange) Peel Extract, Citrus Nobilis (Mandarin Orange) Peel Oil, Citrus Paradisi (Grapefruit) Fruit Water, Citrus Paradisi (Grapefruit) Peel Oil, Citrus Reticulata (Tangerine) Fruit Water, Citrus Reticulata (Tangerine) Leaf Oil, Citrus Reticulata (Tangerine) Peel Oil, Citrus Sinensis (Orange) Fruit Water, Citrus Tangerina (Tangerine) Peel Oil, Citrus Tankan Peel Oil, Citrus Unshiu Flower Water, Citrus Unshiu Fruit Powder, Citrus Unshiu Peel Powder, Citrus Unshiu/Citrus Reticulata/Citrus lyo Fruit Water, Cnidium Monnieri Seed Powder, Cnidium Officinale Root Water, Cochlearia Armoracia (Horseradish) Root Extract, Cocos Nucifera (Coconut) Liquid Endosperm, Cocos Nucifera (Coconut) Oil, Cod Liver Oil, Codonopsis Pilosula Root Powder, Coffea Arabica (Coffee) Seed Oil, Coffea Canephora Flower Extract, Coix Lacryma-Jobi (Job's Tears) Seed Water, Coix Lacryma-Jobi Ma-yuen Seed Water, Commiphora Myrrha Oil, Commiphora Myrrha Resin, Commiphora Myrrha Resin Water, Commiphora Wildii Oil, Conobea Scoparioides Leaf Oil, Copaifera Coriacea Resin Oil, Copaifera Coriacea/Langsdorffii/Officinalis/Reticulata Resin Oil, Copaifera Langsdorffii Resin Oil, Copaifera Officinalis (Balsam Copaiba) Resin, Copaifera Officinalis (Balsam Copaiba) Resin Oil, Copaifera Reticulata Resin Oil, Coptis Chinensis Root/Stalk Powder, Cordia Curassavica Leaf Oil, Coriandrum Sativum (Coriander) Fruit Extract, Coriandrum Sativum (Coriander) Fruit Oil, Coriandrum Sativum (Coriander) Fruit/Leaf Extract, Coriandrum Sativum (Coriander) Leaf/Stem Oil, Corylus Avellana (Hazelnut) Leaf Water, Corylus Avellana (Hazelnut) Seed Oil, Cotinus Coggygria Branch/Leaf Oil, Coumarin, Crataegus Oxyacantha Flower Water, Crocus Sativus Flower Extract, Croton Glabellus Bark Oil, Cryptocarya Crassinervia Bark Oil, Cryptocarya Massoy Bark Extract, Cryptolepis Buchanani Flower/Leaf Extract, Cryptomeria Japonica Branch/Leaf Oil, Cryptomeria Japonica Leaf Oil, Cryptomeria Japonica Leaf Water, Cryptomeria Japonica Stem Oil, Cryptomeria Japonica Stem Water, Cuminum Cyminum (Cumin) Seed Extract, Cuminum Cyminum (Cumin) Seed Oil, Cunila Galioides Flower/Leaf Oil, Cupressus Lusitanica Branch/Leaf Oil, Cupressus Nootkatensis Wood Oil, Cupressus Sempervirens Branch/Leaf Oil, Cupressus Sempervirens Leaf Oil, Cupressus Sempervirens Leaf/Nut/Stem Oil, Cupressus Sempervirens Oil, Curcuma Longa (Turmeric) Root Extract, Curcuma Longa (Turmeric) Root Water, Curcuma Zedoaria Root Water, Cyamopsis Tetragonoloba (Guar) Gum, Cyclamen Aldehyde, Cyclized Eucalyptus Citriodora Leaf/Twig Oil, Cymbopogon Citratus Flower Water, Cymbopogon Citratus Leaf, Cymbopogon Citratus Leaf Oil, Cymbopogon Citratus Leaf/Stem Oil, Cymbopogon Flexuosus Leaf Oil, Cymbopogon Flexuosus Leaf/Stem Oil, Cymbopogon Flexuosus Oil, Cymbopogon Martini Oil, Cymbopogon Nardus (Citronella) Oil, Cymbopogon Schoenanthus Leaf, Cymbopogon Schoenanthus Oil, Cymbopogon Schoenanthus Water, Cymbopogon Winterianus Leaf Oil, Cyperus Articulatus Root Oil, Cyperus Esculentus Root Oil, Cystine, Cytisus Scoparius Flower Extract, Dalea Spinosa Seed Oil, Daucus Carota Sativa (Carrot) Root Water, Daucus Carota Sativa (Carrot) Seed Oil, Daucus Carota Sativa (Carrot) Water, Delta-Damascone, Delta-Decalactone, Denatonium Benzoate, Dianthus Caryophyllus Flower Oil, Dianthus Caryophyllus Flower Water, Dicentra Formosa Flower Extract, Dihydro Pentamethylindanone, Dihydrocitronellol, Dihydrocoumarin, Diisobutyl Adipate, Diisopropyl Adipate, Dimethyl Brassylate, Dimethyl Carbonate, Dimethyl Decadienal, Dimethyl Hexahydronaphthyl Dihydroxymethyl Acetal, Dimethyl Phenethyl Butyrate, Dimethyl Phenylbutanol, Dimethyl Phenylpropanol, Dimethyl Phthalate, Dimethyl Succinate, Dimethylcyclohexylethoxy Isobutylpropanoate, Dimethylhydroxy Furanone, Dimethylisobutyl Methylcyclohexanone, Dimethyloctahydro-2- Naphthaldehyde, Diphenyl Ether, Diphenyl Methane, Dipterocarpus Turbinatus Wood Oil, Dipteryx Odorata Bean Extract, Dipteryx Odorata Seed Extract, Dipteryx Odorata Seed Oil, Dipteryx Odorata Seed Water, Disodium Phosphate, Disodium Succinate, Dodecene, Eicosane, Elaeagnus Latifolia Leaf Cell Extract, Elettaria Cardamomum Seed Extract, Elettaria Cardamomum Seed Oil, Ephedra Sinica Water, Eremophila Mitchellii Wood Oil, Eriocephalus Punctulatus Oil, Erythorbic Acid, Erythrina Variegata Flower Water, Estratetraenol, Ethoxydiglycol, Ethyl 2,2-Dimethylhydrocinnamal, Ethyl Acetate, Ethyl Acetoacetate, Ethyl Benzoate, Ethyl Butyl Valerolactone, Ethyl Cinnamate, Ethyl Cyclohexyl Propionate, Ethyl Ether, Ethyl Hexanediol, Ethyl Hydroxypyrone, Ethyl Lactate, Ethyl Laurate, Ethyl Linalool, Ethyl Linoleate, Ethyl Linolenate, Ethyl Menthane Carboxamide, Ethyl Methylbutyl Ketoxime, Ethyl Methylphenylglycidate, Ethyl Myristate, Ethyl Nicotinate, Ethyl Oleate, Ethyl Palmitate, Ethyl Pelargonate, Ethyl Phenethyl Acetal, Ethyl Phenylacetate, Ethyl Pyruvate, Ethyl Ricinoleate, Ethyl Stearate, Ethyl Thioglycolate, Ethyl Trimethylcyclopentene Butenol, Ethyl Vanillin, Ethylene Brassylate, Ethylene Dodecanedioate, Ethylhexyl Ethylhexanoate, Ethylhexyl Palmitate, Ethylhexyl Salicylate, Eucalyptol, Eucalyptus Acmenoides Leaf Extract, Eucalyptus Cinerea Leaf Oil, Eucalyptus Cinerea Leaf Water, Eucalyptus Citriodora Oil, Eucalyptus Dives Leaf/Twig Oil, Eucalyptus Dunnii Leaf Extract, Eucalyptus Globulus Leaf Oil, Eucalyptus Globulus Leaf Water, Eucalyptus Globulus Leaf/Twig Oil, Eucalyptus Parvula Leaf Oil, Eucalyptus Pulverulenta Leaf Water, Eucalyptus Radiata Flower/Leaf/Stem Extract, Eucalyptus Radiata Flower/Leaf/Stem Oil, Eucalyptus Radiata Leaf Oil, Eucalyptus Radiata Leaf/Stem Oil, Eucalyptus Staigeriana Branch/Leaf Oil, Eugenia Caryophyllus (Clove) Bud Oil, Eugenia Caryophyllus (Clove) Flower Extract, Eugenia Caryophyllus (Clove) Flower Oil, Eugenia Caryophyllus (Clove) Leaf Oil, Eugenia Caryophyllus (Clove) Stem Oil, Eugenol, Eugenyl Acetate, Euphorbia Cerifera (Candelilla) Wax, Euphrasia Officinalis Flower/Leaf/Stem Water, Euterpe Precatoria Fruit Extract, Evernia Furfuracea (Treemoss) Extract, Evernia Prunastri (Oakmoss) Extract, Fabiana Imbricata Oil, Fagraea Berteroana Flower Water, Farnesene, Farnesol, Farnesyl Acetate, Ferula Assa Foetida Gum Extract, Ferula Galbaniflua (Galbanum) Resin Oil, Ficus Carica (Fig) Fruit Water, Ficus Sycomorus Leaf Cell Extract, Foeniculum Vulgare (Fennel) Fruit Extract, Foeniculum Vulgare (Fennel) Fruit Powder, Foeniculum Vulgare (Fennel) Oil, Foeniculum Vulgare (Fennel) Water, Formic Acid, Fortunella Japonica Peel Oil, Fragaria Ananassa (Strawberry) Fruit Juice, Fragaria Ananassa (Strawberry) Fruit Water, Fragrance, Fucus Vesiculosus Extract, Fumaric Acid, Furfural, Fusanus Spicatus Wood Oil, Galactoarabinan, Gamma-Caprolactone, Gamma-Decalactone, Gamma-Nonalactone, Gamma-Undecalactone, Garcinia Humilis Peel Extract, Gardenia Florida Oil, Gaultheria Fragrantissima Leaf Oil, Gaultheria Procumbens (Wintergreen) Flower/Leaf/Stem Oil, Gaultheria Procumbens (Wintergreen) Leaf Extract, Gaultheria Procumbens (Wintergreen) Leaf Oil, Gaultheria Yunnanensis Branch/Leaf Oil, Genipa Americana Fruit Juice, Gentiana Lutea Root Extract, Geranic Acid, Geraniol, Geranium Macrorrhizum Flower/Leaf/Stem Oil, Geranium Maculatum Oil, Geranyl Acetate, Ginkgo Biloba Leaf Water, Gluconic Acid, Glucose Pentaacetate, Glutaral, Glutaric Acid, Glutathione, Glycerin, Glyceryl Rosinate, Glycyrrhiza Glabra (Licorice) Rhizome/Root, Glycyrrhizic Acid, Gnaphalium Leontopodium Flower/Leaf/Stem Water, Gossypium Arboreum (Cotton) Leaf Cell Extract, Gossypium Herbaceum (Cotton) Fruit Water, Guaiacum Officinale Wood Oil, Guaiazulene, Hakka Yu, Hamamelis Virginiana (Witch Hazel) Flower Water, Hay Water, Helichrysum Angustifolium Flower Oil, Helichrysum Italicum Flower Oil, Helichrysum Stoechas Extract, Heliotropine, Heptamethyl Decahydroindenofuran, Heterotheca Inuloides Flower Extract, Hexadecanolactone, Hexamethylindanopyran, Hexanal, Hexenyl Acetate, Hexyl Acetate, Hexyl Alcohol, Hexyl Cinnamal, Hexyl Salicylate, Hexylene Glycol, Hibiscus Abelmoschus Extract, Hibiscus Abelmoschus Flower/Seed Water, Hibiscus Abelmoschus Seed Extract, Hibiscus Abelmoschus Seed Oil, Hinokitiol, Hippophae Rhamnoides Water, Hippuric Acid, Houttuynia Cordata Flower/Leaf/Stem Water, Houttuynia Cordata Water, Humulus Lupulus (Hops) Extract, Humulus Lupulus (Hops) Oil, Hydrogenated Rosin, Hydroxybenzaldehyde, Hydroxycitronellal, Hydroxyisohexyl 3-Cyclohexene Carboxaldehyde, Hydroxymethoxybenzyl Pelargonamide, Hyptis Suaveolens Seed Oil, Hyssopus Officinalis Extract, Hyssopus Officinalis Flower/Leaf/Stem Oil, Hyssopus Officinalis Leaf Oil, lllicium Verum (Anise) Fruit Water, lllicium Verum (Anise) Fruit/Seed Oil, lllicium Verum (Anise) Leaf Oil, Imidazolidinone, Ipomoea Hederacea Seed Powder, Iris Florentina Flower Water, Iris Florentina Root Extract, Isatis Tinctoria Root Powder, Isoamyl Acetate, Isoamyl Alcohol, Isoamyl Allylglycolate, Isoamyl Cinnamate, Isoamyl Laurate, Isobornyl Acetate, Isobornyloxyethanol, Isobutenyl Methyltetrahydropyran, Isobutyl Acetate, Isobutyl Benzoate, Isobutyl Methyl Tetrahydropyranol, Isobutyl Palmitate, Isobutyl Pelargonate, Isobutyric Acid, Isododecane, Isoeugenol, Isoeugenyl Acetate, Isolongifolene Epoxide, Isolongifolene Ketone Exo, Isopentanal, Isopentyl Cyclohexyl Acetate, Isopentylcyclohexanone, Isopropyl Acetate, Isopropylbenzyl Salicylate, Isopropylphenylbutanal, Isopulegol, Jasminum Grandiflorum (Jasmine) Flower Extract, Jasminum Officinale (Jasmine) Flower Extract, Jasminum Officinale (Jasmine) Flower Water, Jasminum Officinale (Jasmine) Flower/Leaf Extract, Jasminum Officinale (Jasmine) Oil, Jasminum Sambac (Jasmine) Flower Extract, Jasminum Sambac (Jasmine) Flower Oil, Jasminum Sambac (Jasmine) Leaf Cell Extract, Juglans Regia (Walnut) Leaf Extract, Juglans Regia (Walnut) Shell Extract, Juniperus Communis Fruit Extract, Juniperus Communis Fruit Oil, Juniperus Communis Fruit/Leaf Water, Juniperus Communis Sprout Extract, Juniperus Mexicana Oil, Juniperus Osteosperma Oil, Juniperus Oxycedrus Fruit Oil, Juniperus Oxycedrus Wood Oil, Juniperus Oxycedrus Wood Tar, Juniperus Scopulorum Leaf/Stem Oil, Juniperus Virginiana Oil, Juniperus Virginiana Wood Oil, Keihi Ekisu, Keihi Yu, Ketoglutaric Acid, Kinginka Ekisu, Kluyveromyces/Lactobacillus/Artemisia Princeps Leaf Oil Ferment Filtrate, Kochia Scoparia Fruit Powder, Krameria Triandra Root Extract, Kunzea Ambigua Branch/Leaf/Twig Oil, Kunzea Ericoides Leaf Extract, Kunzea Ericoides Leaf Oil, Lactic Acid, Laminaria Cloustoni Extract, Laminaria Digitata Extract, Laminaria Hyperborea Extract, Laminaria Japonica Extract, Laminaria Ochroleuca Extract, Laminaria Saccharina Extract, Lantana Camara Leaf Water, Lauraldehyde, Lauramine Oxide, Laurie Acid, Laurus Nobilis Flower/Leaf/Stem Water, Laurus Nobilis Leaf, Laurus Nobilis Leaf Extract, Laurus Nobilis Leaf Oil, Laurus Nobilis Oil, Lauryl Alcohol, Lauryl Lactate, Lavandula Angustifolia (Lavender) Flower, Lavandula Angustifolia (Lavender) Flower Extract, Lavandula Angustifolia (Lavender) Flower Oil, Lavandula Angustifolia (Lavender) Flower Powder, Lavandula Angustifolia (Lavender) Flower Water, Lavandula Angustifolia (Lavender) Flower/Leaf/Stem Extract, Lavandula Angustifolia (Lavender) Flower/Leaf/Stem Oil, Lavandula Angustifolia (Lavender) Flower/Leaf/Stem Water, Lavandula Angustifolia (Lavender) Leaf Cell Extract, Lavandula Angustifolia (Lavender) Oil, Lavandula Angustifolia (Lavender) Water, Lavandula Hybrida Extract, Lavandula Hybrida Flower Extract, Lavandula Hybrida Oil, Lavandula Intermedia Flower/Leaf/Stem Extract, Lavandula Intermedia Flower/Leaf/Stem Oil, Lavandula Intermedia Flower/Leaf/Stem Water, Lavandula Intermedia Oil, Lavandula Spica (Lavender) Flower Oil, Lavandula Spica (Lavender) Flower/Leaf/Stem Extract, Lavandula Stoechas Extract, Ledum Groenlandicum Oil, Lemon Ekisu, Leonurus Artemisia Powder, Leptospermum Petersonii Oil, Leptospermum Scoparium Branch/Flower/Leaf Water, Leptospermum Scoparium Branch/Leaf Oil, Levisticum Officinale Oil, Levulinic Acid, Lilium Longiflorum Flower Extract, Lilium Parvum Flower Extract, Lilium Philadelphicum Flower Extract, Lilium Speciosum Flower Oil, Limonene, Linalool, Linalyl Acetate, Linalyl Benzoate, Lindera Umbellata Leaf/Twig Oil, Lindera Umbellata Leaf/Twig Water, Lindera Umbellata Twig Oil, Linoleic Acid, Linolenic Acid, Linum Usitatissimum (Linseed) Seed Oil, Lippia Alba Leaf/Stem Oil, Lippia Citriodora Flower Water, Lippia Citriodora Flower/Leaf/Stem Oil, Lippia Citriodora Flower/Leaf/Stem Water, Lippia Citriodora Leaf Oil, Lippia Citriodora Leaf Water, Lippia Citriodora Leaf/Flower Oil, Lippia Citriodora Water, Lippia Origanoides Leaf/Flower/Stem Oil, Lippia Sidoides Leaf Oil, Liquidambar Styraciflua Oil, Litsea Cubeba Fruit Oil, Longifolene, Lotus Corniculatus Flower Water, Lotus Corniculatus Leaf Cell Extract, Luffa Cylindrica Fruit Water, Lycium Chinense Fruit Water, m-Cresol, Magnolia Denudata Bud Powder, Magnolia Glauca Flower Water, Maltol, Maltol Isobutyrate, Malus Domestica Fruit Water, Marrubium Vulgare Extract, Marrubium Vulgare Flower/Leaf/Stem Extract, Massoy Bark Oil, Medicago Sativa (Alfalfa) Extract, Melaleuca Alternifolia (Tea Tree) Flower/Leaf/Stem Oil, Melaleuca Alternifolia (Tea Tree) Leaf Oil, Melaleuca Ericifolia Leaf Oil, Melaleuca Leucadendron Cajaput Oil, Melaleuca Quinquenervia Leaf Oil, Melaleuca Teretifolia Branch/Leaf Oil, Melaleuca Viridiflora Leaf Oil, Melilotus Officinalis Extract, Melissa Officinalis Flower/Leaf/Stem Extract, Melissa Officinalis Flower/Leaf/Stem Oil, Melissa Officinalis Flower/Leaf/Stem Water, Melissa Officinalis Leaf Extract, Melissa Officinalis Leaf Oil, Mentha Aquatica Flower/Leaf/Stem Extract, Mentha Aquatica Flower/Leaf/Stem Oil, Mentha Aquatica Flower/Leaf/Stem Water, Mentha Aquatica Leaf Oil, Mentha Aquatica Water, Mentha Arvensis Flower/Leaf/Stem Extract, Mentha Arvensis Flower/Leaf/Stem Water, Mentha Arvensis Leaf Oil, Mentha Arvensis Leaf/Stem Oil, Mentha Arvensis Powder, Mentha Canadensis Leaf/Stem Oil, Mentha Haplocalix Extract, Mentha Piperita (Peppermint) Flower/Leaf/Stem Extract, Mentha Piperita (Peppermint) Flower/Leaf/Stem Water, Mentha Piperita (Peppermint) Leaf, Mentha Piperita (Peppermint) Leaf Extract, Mentha Piperita (Peppermint) Leaf Water, Mentha Piperita (Peppermint) Oil, Mentha Pulegium Oil, Mentha Spicata Flower/Leaf/Stem Extract, Mentha Spicata Flower/Leaf/Stem Oil, Mentha Viridis (Spearmint) Extract, Mentha Viridis (Spearmint) Leaf Extract, Mentha Viridis (Spearmint) Leaf Oil, Mentha Viridis (Spearmint) Leaf/Stem Water, Menthol, Menthone Glycerin Acetal, Menthoxypropanediol, Menthyl Salicylate, Methoxydiglycol, Methoxyindane, Methoxyisopropanol, Methoxytrimethylheptanol, Methyl 2-Octynoate, Methyl 3-Methylresorcylate, Methyl 4-t-Butylbenzoate, Methyl Acetate, Methyl Alcohol, Methyl Anthranilate, Methyl Benzoate, Methyl Benzodioxepinone, Methyl Caproate, Methyl Caprylate, Methyl Cyclohexylacetate, Methyl Decenol, Methyl Di-t-butyl Hydroxyhydrocinnamate, Methyl Diisopropyl Propionamide, Methyl Dimethylmethylenecyclohexane Carboxylate, Methyl Eugenol, Methyl Hexyl Cyclopentanone Carboxylate, Methyl Hexyl Ether, Methyl Hydrogenated Rosinate, Methyl lonones, Methyl Lactate, Methylal, Methylbenzyl Acetate, Methylbenzyl Alcohol, Methylcellulose, Methylcyclohexenyl Butanol, Methylcyclopentadecenone, Methyldihydrojasmonate, Methylenedioxyphenyl Methylpropanal, Methylparaben, Methylpentenol Methylthiophene, MIBK, Michelia Alba Flower Oil, Michelia Alba Leaf Oil, Michelia Champaca Flower Oil, Mimosa Pudica Flower Water, Mimosa Tenuiflora Bark Extract, Mimosa Tenuiflora Leaf Extract, Mineral Oil, Mixed Cresols, Mixed lonones, Monarda Didyma Oil, Monarda Fistulosa Extract, Morinda Citrifolia Oil, Musa Sapientum (Banana) Flower Water, Muscone, Musk Ketone, Muskrat Musk, Myrcenol, Myrcia Polyantha Leaf Oil, Myrica Gale Flower/Fruit/Leaf/Twig Extract, Myrica Gale Leaf Water, Myristic Acid, Myristica Fragrans (Nutmeg) Extract, Myristica Fragrans (Nutmeg) Kernel Oil, Myristica Fragrans (Nutmeg) Powder, Myristyl Alcohol, Myrocarpus Fastigiatus Oil, Myroxylon Balsamum (Balsam Tolu) Resin, Myroxylon Pereirae (Balsam Peru) Oil, Myroxylon Pereirae (Balsam Peru) Resin, Myrrhis Odorata Extract, Myrtus Communis Leaf Water, Myrtus Communis Oil, Narcissus Jonquilla Flower Oil, Narcissus Jonquilla Flower Water, Narcissus Poeticus Flower Extract, Narcissus Poeticus Flower Water, Narcissus Poeticus Flower Wax, Narcissus Pseudonarcissus (Daffodil) Flower Water, Nardostachys Jatamansi Root Oil, Nasturtium Officinale Extract, Nasturtium Officinale Flower/Leaf Extract, Nasturtium Officinale Flower/Leaf/Stem Extract, Nasturtium Officinale Leaf Extract, Nelumbium Speciosum Flower Water, Nelumbo Nucifera Flower Water, Nelumbo Nucifera Root Water, Neohesperidin Dihydrochalcone, Nepeta Cataria Extract, Nepeta Cataria Oil, Nerolidol, Nicotiana Tabacum (Tobacco) Leaf Extract, Nindou Ekisu, Nitrous Oxide, Nonadienal, Nonyl Acetate, Nopyl Acetate, Nymphaea Alba Leaf Cell Extract, Nymphaea Gigantea Flower Extract, o-Cresol, o-Phenylphenol, Ocimum Americanum Leaf Oil, Ocimum Americanum Leaf/Stem Oil, Ocimum Basilicum (Basil) Flower/Leaf Extract, Ocimum Basilicum (Basil) Flower/Leaf/Stem Extract, Ocimum Basilicum (Basil) Flower/Leaf/Stem Water, Ocimum Basilicum (Basil) Leaf Extract, Ocimum Basilicum (Basil) Leaf Water, Ocimum Basilicum (Basil) Oil, Octadecane, Octyldodecanol, Olax Dissitiflora Root Oil, Olea Europaea (Olive) Fruit Oil, Oleyl Alcohol, Olibanum, Opoponax Oil, Orange Yu, Orchis Maculata Flower/Leaf/Stem Water, Origanum Heracleoticum Flower Oil, Origanum Majorana Flower Oil, Origanum Majorana Flower/Leaf/Stem Oil, Origanum Majorana Leaf Extract, Origanum Majorana Leaf Oil, Origanum Vulgare Flower Extract, Origanum Vulgare Flower/Leaf/Stem Water, Origanum Vulgare Oil, Ormenis M ulticaulis Extract, Ormenis M ulticaulis Oil, Oryza Sativa (Rice) Bran Water, Osmanthus Fragrans Flower Extract, Osmanthus Fragrans Flower Oil, Oxacyclohexadecenone, Oxidized Pogostemon Cablin Leaf Oil Extract, p-Anisic Acid, p-Cresol, p-Cymene, p-Hydroxyanisole, p-Menthan-7-ol, p-Methyl Acetophenone, Paeonia Lactiflora Root Powder, Paeonia Lactiflora Root Water, Paeonia Suffruticosa Flower Water, Paeonia Suffruticosa Root Water, Palmitic Acid, Panax Ginseng Root Water, Pandanus Amaryllifolius Leaf Extract, Papaver Rhoeas Flower Water, Pelargonic Acid, Pelargonium Graveolens Extract, Pelargonium Graveolens Flower Oil, Pelargonium Graveolens Flower/Leaf/Stem Extract, Pelargonium Graveolens Flower/Leaf/Stem Water, Pelargonium Graveolens Leaf Oil, Pelargonium Graveolens Oil, Pelargonium Graveolens Water, Pelargonium Graveolens Wax, Pentadecalactone, Pentadecyl Alcohol, Pentafluoropropane, Pentamethyl Octahydroindenodioxane, Pentamethylheptenone, Perilla Frutescens Leaf Water, Perilla Ocymoides Leaf/Stem Oil, Perillaldehyde, Perillyl Alcohol, Persea Gratissima (Avocado) Fruit Water, Petroselinum Crispum (Parsley) Leaf Oil, Petroselinum Crispum (Parsley) Seed Extract, Petroselinum Crispum (Parsley) Seed Oil, Petroselinum Sativum (Parsley) Leaf Powder, Phaseolus M ungo Root Extract, Phebalium Nudum Flower/Leaf Extract, Phenethyl Acetate, Phenethyl Alcohol, Phenol, Phenoxyethanol, Phenyl Benzoate, Phenyl Salicylate, Phenylisohexanol, Phenylmethylpentanal, Phenylpropanol, Phoenix Dactylifera (Date) Leaf Cell Extract, Phosphoric Acid, Picea Abies Leaf Oil, Picea Glauca Branch/Leaf Oil, Picea Glauca Leaf Extract, Picea Mariana Branch/Leaf Oil, Picea Mariana Leaf Oil, Picea Pungens Branch/Leaf/Wood Oil, Pimenta Acris (Bay) Leaf Oil, Pimenta Officinalis (Pimento) Leaf Oil, Pimpinella Anisum (Anise) Fruit Extract, Pimpinella Anisum (Anise) Fruit Oil, Pimpinella Anisum (Anise) Seed Oil, Pinene, Pinus Cembra Leaf/Twig Oil, Pinus Halepensis Branch/Leaf Oil, Pinus Lauricio Branch/Leaf Oil, Pinus Lauricio Leaf Oil, Pinus M ugo Leaf Oil, Pinus Palustris Oil, Pinus Palustris Tar Oil, Pinus Ponderosa Branch/Leaf Oil, Pinus Pumilio Branch/Leaf Oil, Pinus Strobus Cone Extract, Pinus Strobus Twig Oil, Pinus Sylvestris Cone Extract, Pinus Sylvestris Leaf Oil, Pinus Sylvestris Oil, Pinus Sylvestris Wood Extract, Piper Betle Leaf Oil, Piper Longum Fruit Extract, Piper Malacophyllum Flower/Leaf/Stem Oil, Piper Mollicomum Flower/Leaf/Stem Oil, Piper Nigrum (Pepper) Fruit Oil, Piper Nigrum (Pepper) Seed Oil, Pistacia Lentiscus (Mastic) Gum, Pleurotus/Rosa Canina Ferment Extract, Pogostemon Cablin Leaf Oil, Pogostemon Cablin Leaf Water, Pogostemon Cablin Oil, Polianthes Tuberosa Extract, Polygonum Multiflorum Root Water, Polygonum Odoratum Oil, Poria Cocos Powder, Protium Heptaphyllum Resin, Protium Heptaphyllum Resin Extract, Protium Pallidum Extract, Prunus Amygdalus Amara (Bitter Almond) Kernel Oil, Prunus Amygdalus Dulcis (Sweet Almond) Oil, Prunus Armeniaca (Apricot) Fruit Water, Prunus Armeniaca (Apricot) Kernel Oil, Prunus Cerasus (Bitter Cherry) Seed Oil, Prunus Persica (Peach) Flower Powder, Prunus Persica (Peach) Fruit Water, Prunus Persica (Peach) Wood Extract, Prunus Serotina (Wild Cherry) Bark Extract, Prunus Serotina (Wild Cherry) Fruit Extract, Prunus Serrulata Leaf Cell Extract, Prunus Spinosa Flower Water, Pseudotsuga Menziesii (Balsam Oregon) Branch Water, Pseudotsuga Menziesii (Balsam Oregon) Branch/Leaf Oil, Psiadia Altissima Leaf Oil, Punica Granatum Bark Extract, Punica Granatum Extract, Punica Granatum Fruit Water, Pyrus Cydonia Seed Extract, Pyrus Malus (Apple) Fruit Water, Quillaja Saponaria Bark Extract, Quillaja Saponaria Root Extract, Raspberry Ketone, Raspberryketone Glucoside, Ravensara Aromatica Leaf Oil, Resorcinol, Reynoutria Sachalinensis Sprout Extract, Rhamnose, Rhododendron Chrysanthum Leaf Extract, Rhododendron Ferrugineum Extract, Ribes Nigrum (Black Currant) Fruit Water, Rosa Alba Flower Water, Rosa Borboniana Flower Water, Rosa Canina Flower, Rosa Canina Flower Oil, Rosa Centifolia Flower, Rosa Centifolia Flower Extract, Rosa Centifolia Flower Oil, Rosa Damascena Extract, Rosa Damascena Flower Extract, Rosa Damascena Flower Oil, Rosa Damascena Flower Powder, Rosa Damascena Flower Water, Rosa Damascena Flower Wax, Rosa Eglantaria Flower/Leaf/Stem Extract, Rosa Gallica Flower Oil, Rosa Gallica Flower Water, Rosa Hybrid Flower Water, Rosa Indica Flower Extract, Rosa Moschata Oil, Rosa Multiflora Fruit Extract, Rosa Rugosa Bud Powder, Rosa Rugosa Flower Oil, Rosa Rugosa Flower Water, Rose Flower Oil, Rosmarinus Officinalis (Rosemary) Flower Wax, Rosmarinus Officinalis (Rosemary) Flower/Leaf/Stem Extract, Rosmarinus Officinalis (Rosemary) Flower/Leaf/Stem Water, Rosmarinus Officinalis (Rosemary) Leaf Extract, Rosmarinus Officinalis (Rosemary) Leaf Oil, Rosmarinus Officinalis (Rosemary) Leaf Water, Rosmarinus Officinalis (Rosemary) Water, Rubus Fruticosus (Blackberry) Fruit Extract, Rubus Fruticosus (Blackberry) Fruit Water, Rubus Fruticosus (Blackberry) Leaf Extract, Rubus Idaeus (Raspberry) Fruit Water, Rubus Idaeus (Raspberry) Leaf Wax, Ruta Graveolens (Rue) Leaf Extract, Ruta Graveolens (Rue) Oil, Salix Alba (Willow) Bark Water, Salvia Lavandulifolia Leaf Oil, Salvia Officinalis (Sage) Flower/Leaf/Stem Extract, Salvia Officinalis (Sage) Flower/Leaf/Stem Water, Salvia Officinalis (Sage) Leaf Water, Salvia Officinalis (Sage) Oil, Salvia Officinalis (Sage) Water, Salvia Sclarea (Clary) Flower/Leaf/Stem Oil, Salvia Sclarea (Clary) Flower/Leaf/Stem Water, Salvia Sclarea (Clary) Oil, Salvia Triloba Leaf Oil, Sambucus Nigra Flower Water, Sambucus Nigra Oil, Sambucus Nigra Wax, Sanguisorba Officinalis Root/Stalk Powder, Santalum Album (Sandalwood) Oil, Santalum Austrocaledonicum Wood Oil, Santalum Paniculatum Wood Oil, Sapindus Emarginatus Fruit/Sucrose Ferment Filtrate, Sasa Senanensis Leaf Extract, Sasa Senanensis Leaf Powder, Sassafras Officinale Root Oil, Satureja Hortensis Extract, Satureja Hortensis Oil, Satureja Montana Oil, Schinus Molle Oil, Schinus Terebinthifolia Fruit Extract, Schinus Terebinthifolia Fruit Oil, Schisandra Chinensis Fruit Water, Sciadopitys Verticillata Branch/Leaf Oil, Sclareol, Sclareolide, Scutellaria Baicalensis Root Powder, Sesamum Indicum (Sesame) Seed Oil, Siparuna Guianensis Leaf Oil, Sisymbrium Irio Seed Oil, Smilax Lancefolia Root/Stalk Powder, Sodium Anisate, Sodium Benzoate, Sodium Cinnamate, Sodium Citrate, Sodium Citronellate, Sodium Hexametaphosphate, Solanum Lycopersicum (Tomato) Fruit Water, Solanum Xanthocarpum Root Extract, Solidago Canadensis Flower/Leaf/Stem Oil, Sophora Flavescens Root Powder, Spartium Junceum Flower Extract, Stemona Sessifolia Root Powder, Sterculia Urens Gum, Styrax Benzoin Gum, Styrax Benzoin Resin Extract, Syringa Oblata Bark/Leaf Powder, Syzygium Polyanthum Leaf Powder, Tagetes Erecta Flower Oil, Tagetes Minuta Flower Oil, Tanacetum Annuum Flower Oil, Tanacetum Annuum Flower/Leaf/Stem Oil, Tanacetum Cinerariifolium (Pyrethrum) Flower Extract, Tarchonanthus Camphoratus Oil, Terpineol, Terpineol Acetate, Tetrahydrofurfuryl Acetate, Tetrahydrofurfuryl Alcohol, Tetramethyl Acetyloctahydronaphthalenes, Tetramethyl Cyclopentene Butenol, Tetrapleura Tetraptera Fruit Extract, Thalictrum Occidentale Flower Extract, Theobroma Cacao (Cocoa) Leaf Cell Extract, Theobroma Cacao (Cocoa) Seed Butter, Theobroma Grandiflorum Fruit Juice, Thuja Occidentalis Leaf Oil, Thuja Orientalis Water, Thuja Plicata Wood Oil, Thuja Plicata Wood Water, Thujopsis Dolabrata Leaf Oil, Thujopsis Dolabrata Stem Oil, Thujopsis Dolabrata Wood Oil, Thymol, Thymus Mastichina Flower Oil, Thymus Vulgaris (Thyme) Extract, Thymus Vulgaris (Thyme) Flower/Leaf Extract, Thymus Vulgaris (Thyme) Flower/Leaf Oil, Thymus Vulgaris (Thyme) Flower/Leaf/Stem Water, Thymus Vulgaris (Thyme) Leaf, Thymus Vulgaris (Thyme) Oil, Thymus Zygis Flower Oil, Tilia Americana Flower Extract, Tilia Americana Flower Oil, Tilia Cordata Flower Water, Tilia Cordata Oil, Tilia Vulgaris Flower Water, Torreya Californica (California Nutmeg) Oil, Tribulus Terrestris Fruit Powder, Trifolium Pratense (Clover) Flower Extract, Trigonella Foenum-Graecum Seed Extract, Trimethylhexanol, Tsuga Canadensis Leaf Oil, Tsuga Canadensis Oil, Turnera Diffusa Flower/Leaf/Stem Oil, Uikyo Yu, Undecanoic Acid, Undecyl Alcohol, Undecylenal, Undecylenic Acid, Undecylenyl Alcohol, Valeriana Jatamansi Rhizome Oil, Valeriana Officinalis Rhizome/Root, Valeriana Officinalis Root Oil, Vanilla Bahiana Fruit Extract, Vanilla Planifolia Fruit, Vanilla Tahitensis Fruit, Vanillin, Vanillosmopsis Erythropappa Flower/Leaf Oil, Vanillyl Butyl Ether, Verbena Officinalis Flower/Leaf Extract, Verbena Officinalis Leaf Extract, Vetiveria Zizanoides Root Oil, Viburnum Prunifolium Extract, Vinyl Cyclohexene Carboxaldehyde, Viola Odorata Flower Extract, Viola Odorata Flower Water, Viola Odorata Flower/Leaf Extract, Viola Odorata Leaf Extract, Viola Odorata Leaf Wax, Virola Surinamensis Shell Oil, Vitex Agnus-Castus Fruit Oil, Vitex Agnus-Castus Leaf Oil, Vitis Vinifera (Grape) Flower Extract, Vitis Vinifera (Grape) Fruit Juice Ferment Lees Oil, Vitis Vinifera (Grape) Leaf Oil, Xanthorrhoea Preissii Leaf Oil, Xerochrysum Bracteatum Flower Extract, Ximenia Americana Seed Oil, Zanthoxylum Acanthopodium Fruit Oil, Zanthoxylum Alatum Fruit Oil, Zea Mays (Corn) Oil, Zingiber Officinale (Ginger) Root Oil.

[0042] WETTING AGENTS

[0043] The cosmetic composition according to the invention can further comprise wetting agents. Wetting agents in general have multifunctional properties which are connected to their amphiphilic molecular structure, consisting of a polar, hydrophilic and a non-polar, hydrophobic part. This structure allows the wetting agents to gravitate towards the interphase of a bi-phase system and there to lower the interfacial tension.

[0044] Suitable wetting agents are for example, glyceryl caprylate, glyceryl caprate, caprylyl glycol or sodium lauroyl lactylate.

[0045] In a preferred embodiment according to the invention the at least one 1,2-alkane diol, which is part of the cosmetic composition, is selected from 1,2-pentylene glycol or 1,2- hexanediol.

[0046] In a further preferred embodiment according to the invention the at least one 1,2- alkane diol is added in an amount of from 0.1 to 10 % per weight, calculated on the cosmetic composition.

[0047] In a further preferred embodiment according to the invention, the cosmetic composition is an emulsion or a sunscreen lotion or color cosmetics.

[0048] In a further preferred embodiment according to the invention said emulsions exhibit an average particle size, where • 10 Vol.-% show a diameter of less than 2 miti (preferably less than 0.5 pm) (DIO value),

• 50 Vol.-% show a diameter of less than 10 pm (preferably less than 5 pm) (D50 value) and

• 90 Vol.-% show a diameter of less than 15 pm (preferably less than 12 pm) (D90 value).

[0049] The particle size of emulsions can be determined using a Mastersizer Micro MAF 500 (Malvern), for example and using the principle of laser diffraction. For example, the D10 value in the sense of the present invention means that in a preferred embodiment according to the invention 10 % of the particles show a particle size less than 2 pm. The D50 value in the sense of the present invention means that in a preferred embodiment according to the invention 50 % of the particles show a particle size less than 10 pm. The D90 value in the sense of the present invention means that in a preferred embodiment according to the invention 90 % of the particles show a particle size less than 15 pm.

[0050] Of course also other compounds which are suitable for cosmetic compositions and which are not mentioned expressly, can be part of the cosmetic composition according to the present invention.

[0051] METHOD

[0052] Another object of the present invention is a method for reducing the foaming of a cosmetic composition, wherein at least one 1,2-alkane diol is used as an anti-foaming agent.

[0053] In a preferred embodiment according to the method of the invention, the at least one 1,2-alkane diol has a chain length of from 5 to 12 carbon atoms. In a further preferred embodiment according to the invention, the 1,2-alkane diol is selected from 1,2-pentanediol or 1,2-hexanediol.

[0054] In one embodiment according to the invention the at least one 1,2-alkane diol is used in an amount of from 0.1 to 10 % per weight, calculated on the cosmetic composition. In a preferred embodiment according to the invention the at least one 1,2-alkane diol is used in an amount of from 0.2 to 8% per weight, calculated on the cosmetic composition. In a further preferred embodiment according to the invention the at least one 1,2-alkane diol is used in an amount of from 0,5 to 5% per weight, calculated on the cosmetic composition.

[0055] In one embodiment according to the invention the cosmetic composition is selected from the group consisting of an emulsion, a mousse, a spray or a lotion. In an especially preferred embodiment according to the invention the cosmetic composition is a sunscreen lotion or color cosmetics.

[0056] In a preferred embodiment according to the method of the present invention, the cosmetic composition is free of silicones.

[0057] It goes without saying that all the substances, compounds or preferred embodiments mentioned above can also be part of the method according to the present invention. PAGE LEFT BLANK INTENTIONALLY

EXAMPLES

[0058] Production method of the cosmetic composition according to the invention

[0059] Pre-disperse Zinc Oxide and 1,2-pentanediol or 1,2-hexanediol in all liquid ingredients of phase A(Liquid ingredients of phase A: Ethylhexyl Salicylate, Octocrylene, Homosalate) and homogenize for 1 min by using an Ultra Turrax Stirrer (6000 rpm). Add the remaining ingredients of phase A and heat up to approx 85°C. (without Xanthan Gum). Add Xanthan Gum and homogenize for 1 min (6000rpm/min). Heat phase B up to approx. 80°C.

[0060] Add phase B to A and homogenize by using an ultra turrx stirrer for 2 min at 6000 rpm. Cool down while stirring with a vane stirrer to 40°C (50 RPM /15 min). The pH value of the finished product should be approx. 5, 8-6,0 and has to be checked.

[0061] Table 1 shows cosmetic compositions according to the invention (B and C). Composition A is placebo and D and E are for comparison.

Tab. 1: Composition, o/w sun protection formula, SPF approx. 30

[0062] As mentioned above, a pre-dispersion of Zinc Oxide was produced before emulsification step: Therefore the ingredients as listed by weight in Table 2 were weighed in. Each blend was homogenized for 1 min by using an ulktra turrax stirrer (6000 rpm).

[0063] Table 2 shows the ingredienst of the pre-dispersion. Composition B1 and Cl are according to the invention, composition A1 is placebo and composition D1 and El are for comparison.

Tab. 2: Ingredients of pre-dispersion

[0064] Soaping/foaming effect of emulsions according to compositions of table 1 (A-D)

[0065] lg of emulsion A-D was distributed onto the skin of the forearm in a circular motion for 30 seconds. Images were taken directly after distribution.

[0066] Fig. 1 shows on the left forearm composition B, containing 3% per weight 1,2 pentylene glycol. For comparison, the right forearm was distributed with composition A, containing no 1,2-alkane diol. It can be clearly seen that the left forearm shows less foaming effect in comparison to placebo.

[0067] Fig. 2 shows on the left forearm composition C, containing 1% per weight 1,2 hexanediol. For comparison, the right forearm was distributed with composition A, containing no 1,2-alkane diol. It can be clearly seen that the left forearm shows less foaming effect in comparison to placebo.

[0068] Fig. 3 shows on the left forearm composition D, containing 3% per weight propylene glycol. The right forearm was distributed with composition A, either containing no 1,2-alkane diol. It can be clearly seen that both forearms show a strong foaming effect.

[0069] Fig. 4 shows on the left forearm composition E, containing 3% per weight glycerin. The right forearm was distributed with composition A, either containing no 1,2-alkane diol. It can be clearly seen that both forearms show a strong foaming effect. [0070] Soaping/foaming effect of further emulsions

[0071 ] Furthermore, the soaping effect of two emulsions were compared: A formula without 1,2-pentanediol (placebo) versus a formula containing 5% per weight of 1,2 -pentanediol. The study was done by consumer evaluation with a naive panel and the results were obtained by a statistic method.

[0072] Table 3 shows the formulas

Tab. 3: Formulas

[0073] Results

[0074] The naive panel (50 persons) have been asked to determine a mark between 0 and 10 for each product concerning the foaming effect (0 = no foaming). 10 = strong foaming) and to conclude which formula is the most foaming.

[0075] One pressure (airless packaging) per formula was applied on the different forearms and 10 rotations have been made by the same applier. Table 4 and Fig. 5 and 6 show the results of the evaluation. "ARP" is the emulsion with 1,2-pentanediol and "OJL" is the placebo. All marks by the 50 persons have been considered and the mean was taken. It can be seen that there is a significant difference between the placebo and the formula containing 1,2- pentanediol related to the foaming effect. This means that the placebo formula is much more foaming, whereas 1,2-pentanediol shows clearly its potential as an anti-foaming agent.

Tab. 4: Results

[0076] Conclusion

[0077] There is a huge difference according to the evaluation by a naive panel between formulas with and without 1,2-alkane diols, thus an improvement can be observed for the foaming effect (less foaming of the compositions) with regard to the use of 1,2-alkane diols in cosmetic compositions, especially the use of 1,2 pentanediol and 1,2 hexane diol.

[0078] The following formulation types are aqueous based (aqueous solution) without ethanol or low content of ethanol. 1,2-pentanediol and 1,2-hexanediol act as an anti foaming agent.

1: Cooling Hair & Skin Moisturizer

2: Moisturizing Body Mist

3: Toner against Oily Skin

4. Calming & Renewing Essence Tab. 5: Aqueous based formulations

Claims

1. Use of at least one 1,2-alkane diol as an anti-foaming agent in cosmetic compositions.

2. The use according to claim 1, wherein the at least one 1,2-alkane diol is used in an amount of from 0.1 to 10 % per weight, calculated on the cosmetic composition.

3. The use according to claim 2, wherein the at least one 1,2-alkane diol is used in an amount of from 0.2 to 8% per weight, calculated on the cosmetic composition.

4. The use according to claim 2, wherein the at least one 1,2-alkane diol is used in an amount of from 0.5 to 5% per weight, calculated on the cosmetic composition.

5. The use according to at least one of the preceding claims, wherein the at least one 1,2- alkane diol has a chain length of from 5 to 12 carbon atoms.

6. The use according to at least one of the preceding claims, wherein the at least one 1,2- alkane diol is selected from 1,2-pentanediol or 1,2-hexanediol.

7. The use according to at least one of the preceding claims, wherein the cosmetic composition is selected from the group consisting of an emulsion, a cream, a mousse, a spray or a lotion or an aqueous solution.

8. The use according to claim 7, wherein the cosmetic composition is a sunscreen lotion or color cosmetics.

9. A cosmetic composition, comprising

(a) at least one 1,2-alkane diol;

(b) inorganics;

(c) water; and optionally

(d) emulsifier;

(e) essential oils; and

(f) thickener,

wherein the cosmetic composition is free of silicones.

10. The cosmetic composition according to claim 9, wherein the at least one 1,2-alkane diol is selected from 1,2-pentanediol or 1,2-hexanediol.

11. The cosmetic composition according to claim 9 and/or 10, wherein the at least one 1,2- alkane diol is added in an amount of from 0.1 to 10 % per weight, calculated on the cosmetic composition.

12. The cosmetic composition according to at least one of claims 9 to 11, being an emulsion.

13. The cosmetic composition according to at least one of claims 9 to 12, wherein the inorganics is an inorganic pigment and selected from zinc oxide or titanium dioxide.

14. The cosmetic composition according to at least one of claims 9 to 13, wherein the thickener is a mandatory ingredient and is selected from the group consisting of Xanthan gum, Acacia Gum, cellulose gum, cellulose, Sclerotium gum, Algin, Microcrystalline cellulose, Carrageenan, Pectin, Carboxymethylcellulose, Gellan gum.

15. The cosmetic composition according to at least one of claims 9 to 14, wherein the emulsifier is a mandatory ingredient and is selected from potassium cetyl phosphate and hydrogenated palm glycerides.