WO2020103395A1 - Waveguide-type photodetector and manufacturing method therefor - Google Patents

Waveguide-type photodetector and manufacturing method therefor

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Publication number
WO2020103395A1
WO2020103395A1 PCT/CN2019/083946 CN2019083946W WO2020103395A1 WO 2020103395 A1 WO2020103395 A1 WO 2020103395A1 CN 2019083946 W CN2019083946 W CN 2019083946W WO 2020103395 A1 WO2020103395 A1 WO 2020103395A1
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Prior art keywords
layer
waveguide
photoelectric conversion
silicon nitride
conversion layer
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PCT/CN2019/083946
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French (fr)
Chinese (zh)
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汪巍
方青
余明斌
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上海新微技术研发中心有限公司
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Publication of WO2020103395A1 publication Critical patent/WO2020103395A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/10Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by potential barriers, e.g. phototransistors
    • H01L31/101Devices sensitive to infrared, visible or ultraviolet radiation
    • H01L31/102Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier
    • H01L31/109Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier the potential barrier being of the PN heterojunction type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0232Optical elements or arrangements associated with the device
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0232Optical elements or arrangements associated with the device
    • H01L31/02327Optical elements or arrangements associated with the device the optical elements being integrated or being directly associated to the device, e.g. back reflectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264Inorganic materials
    • H01L31/028Inorganic materials including, apart from doping material or other impurities, only elements of Group IV of the Periodic Table
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/10Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by potential barriers, e.g. phototransistors
    • H01L31/101Devices sensitive to infrared, visible or ultraviolet radiation
    • H01L31/102Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier
    • H01L31/105Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier the potential barrier being of the PIN type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic Table
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present application relates to the field of semiconductor technology, in particular to a waveguide type photodetector and a manufacturing method thereof.
  • Silicon (Si) -based photodetectors are widely cited in the fields of optical communication, optical interconnection, and optical sensing because of their compatibility with CMOS processes and ease of integration.
  • the detector can be divided into a vertical incidence detector and a waveguide detector.
  • the waveguide detector can avoid the problem of mutual restriction between the speed and quantum efficiency of the photodetector, and can be integrated with the waveguide optical path, which is easier to achieve high speed and high responsiveness, which is to achieve high speed optical communication and optical interconnection One of the core devices of the chip.
  • Group IV germanium (Ge) detectors are small in size, easy to integrate, low cost, because of their preparation process compatible with Si-based CMOS processes Potential advantages such as high performance are widely used in the fields of optical communication and optical sensing.
  • the wavelength of Ge material is greater than 1.55 ⁇ m, the absorption coefficient drops sharply, which makes the Ge detector unable to meet the application of short-wave infrared and even mid-infrared.
  • GeSn has a large absorption coefficient from short-wave infrared to mid-infrared because its energy band gap decreases with the increase of Sn composition. It is an ideal material for preparing infrared detectors. In recent years, GeSn infrared detectors have received extensive research.
  • the inventor of the present application found that the current waveguide Ge detectors mostly use Si materials as optical waveguides, and then the light enters the Ge photoelectric conversion layer through the evanescent wave coupling mode, which is limited by the evanescent wave coupling efficiency.
  • the length of the detector needs to be greater than 10 microns, which makes it difficult to further optimize the capacitance and dark current of the detector; in order to improve the light absorption efficiency, a waveguide detector based on the coupling of the Si waveguide and the end face of the Ge photoelectric conversion layer is proposed, however, through selective epitaxy It is extremely difficult to achieve a high-quality Si / Ge interface by the process; in addition, Si waveguides have higher transmission losses in the infrared band.
  • Embodiments of the present application provide a waveguide-type photodetector and a manufacturing method thereof.
  • the waveguide is formed of SiN, and the waveguide is coupled to the end face of the photoelectric conversion layer. Since the SiN waveguide has extremely low transmission loss in the near-infrared and even mid-infrared bands, and can realize low-loss coupling with optical fibers or silicon waveguides, it can improve the light transmission efficiency; and, between the SiN waveguide and the Ge photoelectric conversion layer Can form a high-quality SiN / Ge interface, thereby improving light detection efficiency.
  • a waveguide-type photodetector including: a first insulating layer on a surface of a substrate; a lower contact layer on the surface of the first insulating layer; and a surface on the lower contact layer
  • Photoelectric conversion layer the material of the photoelectric conversion layer includes germanium (Ge); an upper contact layer on the surface of the photoelectric conversion layer; and a silicon nitride waveguide formed above the first insulating layer, the nitride A silicon waveguide extends in a lateral direction parallel to the surface of the substrate, and in the lateral direction, one end of the silicon nitride waveguide is connected to the photoelectric conversion layer, and the light transmitted by the silicon nitride waveguide It is incident on the photoelectric conversion layer, and a photocurrent is generated in the photoelectric conversion layer.
  • the waveguide-type photodetector further includes: a second insulating layer formed on the surface of the first insulating layer and surrounding the lower contact layer in the lateral direction, wherein, The silicon nitride waveguide is formed on the surface of the second insulating layer.
  • the difference between the thickness of the second insulating layer and the thickness of the lower contact layer is -10% to 10% of the thickness of the lower contact layer.
  • the difference between the thickness of the silicon nitride waveguide and the thickness of the photoelectric conversion layer is -10% to 10% of the thickness of the photoelectric conversion layer.
  • the lateral dimension of the photoelectric conversion layer is smaller than the lateral dimension of the lower contact layer.
  • the lower contact layer is a doped layer containing silicon and / or germanium
  • the photoelectric conversion layer is an undoped layer of germanium (Ge) or germanium tin (GeSn)
  • the upper contact layer is a doped layer of germanium (Ge) or a doped layer of germanium tin (GeSn).
  • a method for manufacturing a waveguide photodetector including:
  • a silicon nitride waveguide is formed on the surface of the second insulating layer, the silicon nitride waveguide extends in a lateral direction parallel to the surface of the substrate, and, in the lateral direction, one end of the silicon nitride waveguide Is connected to the photoelectric conversion layer, wherein the light transmitted by the silicon nitride waveguide is incident on the photoelectric conversion layer, and a photocurrent is generated in the photoelectric conversion layer.
  • the steps of forming the photoelectric conversion layer and the upper contact layer include:
  • the upper contact material layer and the photoelectric conversion material layer are etched to form the photoelectric conversion layer and the upper contact layer.
  • the step of forming a silicon nitride waveguide includes:
  • the silicon nitride material layer is etched to form the silicon nitride waveguide.
  • the difference between the thickness of the silicon nitride material layer and the thickness of the photoelectric conversion layer is -10% to 10% of the thickness of the photoelectric conversion layer.
  • the waveguide is formed by SiN, the light transmission efficiency can be improved; and the SiN waveguide is coupled to the end face of the photoelectric conversion layer, which can improve the light detection efficiency.
  • FIG. 1 is a schematic perspective view of a waveguide-type photodetector according to Example 1 of the present application
  • Fig. 2 is a schematic cross-sectional view viewed in the direction A-A 'of Fig. 1;
  • FIG. 3 is a schematic diagram of a method of manufacturing a waveguide-type photodetector according to Example 2 of the present application;
  • the direction parallel to the main surface of the first insulating layer of the substrate is referred to as “lateral”, and the direction perpendicular to the main surface of the first insulating layer of the substrate It is called “longitudinal”, where the “thickness" of each component refers to the size of the component in the “longitudinal”.
  • This embodiment provides a waveguide type photodetector.
  • Fig. 1 is a schematic perspective view of a waveguide-type photodetector of this embodiment
  • Fig. 2 is a schematic cross-sectional view viewed in the direction A-A 'of Fig. 1.
  • the waveguide-type photodetector 1 includes:
  • the light transmitted by the silicon nitride waveguide 16 enters the photoelectric conversion layer 14 through the end portion 161, and a photocurrent is generated in the photoelectric conversion layer 14.
  • the waveguide is formed of SiN, and the waveguide is coupled to the end face of the photoelectric conversion layer. Since the SiN waveguide has extremely low transmission loss in the near-infrared and even mid-infrared bands, and can realize low-loss coupling with optical fibers or silicon waveguides, it can improve the light transmission efficiency; Can form a high-quality SiN / Ge interface, thereby improving light detection efficiency.
  • the lower contact layer 13 may be a doped layer containing silicon and / or germanium, for example, a heavily doped P-type layer or a heavily doped N-type layer.
  • the first insulating layer 12 may be silicon oxide, for example, and the substrate 11 may be silicon, for example.
  • the silicon on insulator can be processed, the top silicon layer of the SOI can be processed as the lower contact layer 13, the buried oxygen layer of the SOI can be used as the first insulating layer 12, and the silicon of the SOI substrate As the substrate 11.
  • this embodiment may not be limited to this, for example, bulk silicon may be used as the substrate 11, an insulating layer may be formed on the surface of the bulk silicon as the first insulating layer 12, and methods such as deposition or bonding may be performed on the surface of the first insulating layer 12 A silicon material layer is formed, and the silicon material layer is processed to form the lower contact layer 13.
  • the waveguide-type photodetector 1 may further include: a second insulating layer 17 formed on the surface of the first insulating layer 12 and surrounding the lower contact layer 13 in the lateral direction.
  • the silicon nitride waveguide 16 is formed on the surface of the second insulating layer 17.
  • the difference between the thickness of the second insulating layer 17 and the thickness of the lower contact layer 13 is -10% to 10% of the thickness of the lower contact layer 13, thereby providing nitrogen on the surface of the second insulating layer 17
  • the lower surface of the silicon nitride waveguide 16 can be flush with the lower surface of the lower contact layer 13.
  • the difference between the thickness of the silicon nitride waveguide 16 and the thickness of the photoelectric conversion layer 14 is -10% to 10% of the thickness of the photoelectric conversion layer 14, thereby facilitating the transmission of light transmitted by the silicon nitride waveguide 16
  • the end surface 161 is coupled into the photoelectric conversion layer 14, which improves the coupling efficiency of light.
  • the lateral position of the end portion 161 of the silicon nitride waveguide 16 can be aligned with the lateral center position of the photoelectric conversion layer 14, thereby, the light coupling efficiency is further improved.
  • the lateral dimension of the photoelectric conversion layer 14 is smaller than the lateral dimension of the lower contact layer 13, and therefore, a portion of the lower contact layer 13 is not blocked by the photoelectric conversion layer 14, and the surface of the unblocked portion can be provided with The electrode that the lower contact layer 13 contacts.
  • the first electrode 18 may be located on both sides of the photoelectric conversion layer 14, and the first electrode 18 may be disposed on the surface of the lower contact layer 13 and in contact with the lower contact layer 13;
  • the electrode 19 may be in contact with the upper contact layer 15.
  • the second insulating layer 17 may also cover a part of the upper contact layer 15 and the side walls of the photoelectric conversion layer 14 and the upper contact layer 15.
  • the photoelectric conversion layer 14 may be an undoped layer of germanium (Ge) or an undoped layer of germanium tin (GeSn), that is, the photoelectric conversion layer 14 may be an intrinsic layer of germanium (Ge) or Intrinsic layer of germanium tin (GeSn).
  • the photoelectric conversion layer 14 by incorporating Sn into Ge, the absorption efficiency of the photoelectric conversion layer 14 can be increased and the detection range of the photoelectric conversion layer 14 can be widened.
  • the composition of Sn can be greater than 0 and less than 40% (mole ratio).
  • the upper contact layer 15 may be a doped layer of germanium (Ge) or a doped layer of germanium tin (GeSn).
  • the doping type of the upper contact layer 15 is opposite to that of the lower contact layer 13.
  • the upper contact layer 15 is heavily doped with P type and the lower contact layer 13 is heavily doped with N type; or, the upper contact layer 15 is heavily doped with N type and the lower contact layer 13 is heavily doped with P type.
  • Both the first insulating layer 12 and the second insulating layer 17 are, for example, silicon oxide.
  • light can enter the silicon nitride waveguide 16 through the fiber-SiN waveguide coupler or enter the silicon nitride waveguide 16 through the Si waveguide-SiN waveguide coupler and directly couple into the end through the silicon nitride waveguide 16 Photoelectric conversion layer 14.
  • the photodetector integrated with the silicon nitride waveguide 16 of this embodiment can be integrated with the waveguide optical path, and it is easier to realize the preparation of a photodetector with low dark current, low capacitance, and high response in the communication band.
  • the waveguide-type photodetector of this embodiment has the following advantages: First, compared with the conventional perpendicular-incidence germanium detector, the photodetector based on the waveguide structure can avoid the mutual restriction between the photodetector rate and quantum efficiency, and It is easy to integrate with other passive optical devices; second, compared with the evanescent wave coupling waveguide detector, the waveguide detector based on the end face coupling of this embodiment has higher absorption efficiency; third, the silicon nitride waveguide is The near-infrared and even mid-infrared bands have extremely low transmission loss and can realize low-loss coupling with optical fibers or silicon waveguides. Fourth, the end face of the silicon nitride waveguide and the end face of the photoelectric conversion layer form a good quality interface, which improves the optical Coupling efficiency.
  • Embodiment 2 provides a method for manufacturing a waveguide-type photodetector, which is used to manufacture the waveguide-type photodetector described in Embodiment 1.
  • FIG. 3 is a schematic diagram of the manufacturing method of the waveguide-type photodetector of this embodiment. As shown in FIG. 3, in this embodiment, the manufacturing method may include:
  • Step 301 forming a lower contact material layer 13a on the surface of the first insulating layer 12 on the surface of the substrate 11;
  • Step 302 Form a photoelectric conversion layer 14 on the surface of the lower contact material layer 13a, and form an upper contact layer 15 on the surface of the photoelectric conversion layer 14, wherein the material of the photoelectric conversion layer 14 includes germanium (Ge);
  • Step 303 etching the lower contact material layer 13a to form the lower contact layer 13;
  • Step 304 forming a second insulating layer 17 surrounding the lower contact layer 13 on the surface of the first insulating layer 12;
  • Step 305 forming a silicon nitride waveguide 16 on the surface of the second insulating layer 17, the silicon nitride waveguide 16 extends in a lateral direction parallel to the surface of the substrate 11, and, in the lateral direction, one end of the silicon nitride waveguide 16 161 is connected to the photoelectric conversion layer 14.
  • the light transmitted by the silicon nitride waveguide 16 is incident on the photoelectric conversion layer 14, and a photocurrent is generated in the photoelectric conversion layer 14.
  • step 302 may include:
  • Step 3021 Form a stack of the photoelectric conversion material layer 14a and the upper contact material layer 15a on the surface of the lower contact material layer 13a, wherein the photoelectric conversion material layer 14a is an undoped material layer and the upper contact material layer 15a is a doped material layer ;as well as
  • Step 3022 etching the upper contact material layer 15a and the photoelectric conversion material layer 14a to form the photoelectric conversion layer 14 and the upper contact layer 15, wherein the upper contact layer 15 and the photoelectric conversion layer 14 form a mesa.
  • the step of forming a silicon nitride waveguide in step 305 may include:
  • Step 3051 depositing a silicon nitride material layer 16a on the surface of the second insulating layer 17;
  • Step 3052 The silicon nitride material layer 16a is etched to form a silicon nitride waveguide 16.
  • the difference between the thickness of the silicon nitride material layer 16a and the thickness of the photoelectric conversion layer 14 is -10% to 10% of the thickness of the photoelectric conversion layer 14.
  • the manufacturing method of the waveguide-type photodetector includes the following steps:
  • Step 1 Perform ion implantation and high-temperature annealing on the silicon material layer of the first insulating layer 12 on the surface of the substrate 11 so that the silicon material layer becomes the lower contact material layer 13a.
  • the lower contact material layer 13a is heavily doped P-type;
  • a germanium (Ge) or germanium tin (GeSn) material layer is epitaxially grown on the surface of the lower contact material layer 13a, and ion implantation and high temperature annealing are performed on the upper part of the germanium (Ge) or germanium tin germanium (GeSn) material layer to remove
  • the upper part of the germanium (Ge) or germanium tin (GeSn) material layer is prepared as an N-type heavily doped layer, whereby the lower part (ie, intrinsic part) of the germanium (Ge) or germanium tin (GeSn) material layer As the photoelectric conversion material layer 14a, the upper part (ie, the heavily doped portion) of the
  • Step 2 Perform photolithography and dry etching on the upper contact material layer 15a and the photoelectric conversion material layer 14a to form the photoelectric conversion layer 14 and the upper contact layer 15, wherein the upper contact layer 15 and the photoelectric conversion layer 14 form a mesa; and , Performing photolithography and dry etching on the exposed lower contact material layer 13a to form the lower contact layer 13. See (b) of Figure 4.
  • Step 3 Deposit SiO 2 as the second insulating layer 17; deposit a silicon nitride material layer 16a on the surface of the second insulating layer 17 whose thickness is equivalent to the thickness of the photoelectric conversion layer 14; then, light the silicon nitride material layer 16a
  • the silicon nitride waveguide 16 is prepared by etching and etching, and the silicon nitride waveguide 16 is directly connected to the Ge photoelectric conversion layer 14. See (c) of Figure 4.
  • Step 4 Perform photolithography and etching on the second insulating layer 17 to define a metal contact area, and then deposit a metal electrode, and form the first electrode and the second electrode by photolithography and etching, thereby completing device preparation. See (d) of FIG. 4.
  • the waveguide is formed of SiN, and the waveguide is coupled to the end face of the photoelectric conversion layer. Since the silicon nitride waveguide has extremely low transmission loss in the near-infrared and even mid-infrared bands, and can realize low-loss coupling with the optical fiber or the silicon waveguide, it can improve the light transmission efficiency; and, the silicon nitride waveguide and the Ge photoelectricity A high-quality SiN / Ge interface can be formed between the conversion layers, thereby improving light detection efficiency.

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Abstract

A waveguide-type photodetector (1) and a manufacturing method therefor, the waveguide-type photodetector (1) comprising: a first insulating layer (12) located on a surface of a substrate (11); a lower contact layer (13) located on a surface of the first insulating layer (12); a photo-electric conversion layer (14) located on a surface of the lower contact layer (13), the material of the photo-electric conversion layer (14) comprising Ge; an upper contact layer (15) located on a surface of the photo-electric conversion layer (14); and a silicon nitride waveguide (16) formed above the first insulating layer (12), the silicon nitride waveguide (16) extending in the lateral direction parallel to the surface of the substrate (11), and one end part (161) of the silicon nitride waveguide (16) being connected in the lateral direction to the photo-electric conversion layer (14), wherein light transferred by the silicon nitride waveguide (16) enters the photo-electric conversion layer (14), and a photo-electric current is generated in the photo-electric conversion layer (14). SiN is used to form the waveguide (16), and therefore light transmission efficiency may be improved; moreover, the SiN waveguide (16) is coupled to an end surface of the photo-electric conversion layer (14), which may improve light detection efficiency.

Description

一种波导型光电探测器及其制造方法Waveguide photoelectric detector and manufacturing method thereof
本申请要求2018年11月19日向中国国家知识产权局提交的专利申请号为201811379149.X,发明名称为“一种波导型光电探测器及其制造方法”的在先申请的优先权。在先申请的全文通过引用的方式结合于本申请中。This application requires the priority of the prior application for the patent application number 201811379149.X submitted to the State Intellectual Property Office of China on November 19, 2018, and the invention titled "a waveguide photodetector and its manufacturing method". The entire text of the prior application is incorporated into this application by reference.
技术领域Technical field
本申请涉及半导体技术领域,尤其涉及一种波导型光电探测器及其制造方法。The present application relates to the field of semiconductor technology, in particular to a waveguide type photodetector and a manufacturing method thereof.
背景技术Background technique
硅(Si)基光电探测器尤其是硅基锗光电探测器,因其与CMOS工艺兼容,且便于集成,在光通信、光互联和光传感等领域有着广泛的引用。根据光进入的方向,探测器可以分为垂直入射型探测器和波导型探测器。相较于垂直入射型探测器,波导型探测器能避免光探测器速率和量子效率间相互制约的问题,且可以与波导光路集成,更容易实现高速高响应度,是实现高速光通信和光互联芯片的核心器件之一。Silicon (Si) -based photodetectors, especially silicon-based germanium photodetectors, are widely cited in the fields of optical communication, optical interconnection, and optical sensing because of their compatibility with CMOS processes and ease of integration. According to the direction of light entry, the detector can be divided into a vertical incidence detector and a waveguide detector. Compared with the vertical incidence detector, the waveguide detector can avoid the problem of mutual restriction between the speed and quantum efficiency of the photodetector, and can be integrated with the waveguide optical path, which is easier to achieve high speed and high responsiveness, which is to achieve high speed optical communication and optical interconnection One of the core devices of the chip.
相较于传统的III-V族和II-V族红外光电探测器,IV族的锗(Ge)探测器,因其制备工艺与Si基CMOS工艺兼容,具有体积小、易集成、低成本、高性能等潜在优势,在光通讯及光传感领域受到了广泛的应用。然而,Ge材料在波长大于1.55μm时,吸收系数急剧下降,这使得Ge探测器无法满足短波红外乃至中红外的应用。GeSn作为一种新型IV族材料,因其能带带隙随着Sn组分增加而减小,在短波红外到中红外有着大的吸收系数,是制备红外探测器的理想材料。近年来,GeSn红外探测器受到了广泛的研究。Compared with traditional III-V and II-V infrared photodetectors, Group IV germanium (Ge) detectors are small in size, easy to integrate, low cost, because of their preparation process compatible with Si-based CMOS processes Potential advantages such as high performance are widely used in the fields of optical communication and optical sensing. However, when the wavelength of Ge material is greater than 1.55μm, the absorption coefficient drops sharply, which makes the Ge detector unable to meet the application of short-wave infrared and even mid-infrared. As a new type IV material, GeSn has a large absorption coefficient from short-wave infrared to mid-infrared because its energy band gap decreases with the increase of Sn composition. It is an ideal material for preparing infrared detectors. In recent years, GeSn infrared detectors have received extensive research.
应该注意,上面对技术背景的介绍只是为了方便对本申请的技术方案进行清楚、完整的说明,并方便本领域技术人员的理解而阐述的。不能仅仅因为这些方案在本申请的背景技术部分进行了阐述而认为上述技术方案为本领域技术人员所公知。It should be noted that the above introduction to the technical background is set forth only to facilitate a clear and complete description of the technical solutions of the present application and to facilitate understanding by those skilled in the art. It cannot be considered that the above technical solutions are known to those skilled in the art just because these solutions are described in the background part of the present application.
发明内容Summary of the invention
本申请的发明人发现:目前的波导型Ge探测器多采用Si材料作为光波导,进而光通过消逝波耦合方式进入Ge光电转换层,受限于消逝波耦合效率,为了实现高的响应度,探测器长度需要大于10微米,这使得探测器的电容和暗电流难以进一步优化;为了提高光吸收效率,基于Si波导与Ge光电转换层端面耦合的波导探测器被提出,然而,通过选择性外延工艺实现高质量Si/Ge界面极其困难;此外,Si波导对红外波段的传输损耗较高。The inventor of the present application found that the current waveguide Ge detectors mostly use Si materials as optical waveguides, and then the light enters the Ge photoelectric conversion layer through the evanescent wave coupling mode, which is limited by the evanescent wave coupling efficiency. In order to achieve high responsivity, The length of the detector needs to be greater than 10 microns, which makes it difficult to further optimize the capacitance and dark current of the detector; in order to improve the light absorption efficiency, a waveguide detector based on the coupling of the Si waveguide and the end face of the Ge photoelectric conversion layer is proposed, however, through selective epitaxy It is extremely difficult to achieve a high-quality Si / Ge interface by the process; in addition, Si waveguides have higher transmission losses in the infrared band.
本申请实施例提供一种波导型光电探测器及其制造方法,由SiN形成波导,并且波导与光电转换层端面耦合。由于SiN波导在近红外乃至中红外波段具有极低的传输损耗,并能实现与光纤或硅波导的低损耗耦合,因此,能提高光的传输效率;并且,SiN波导与Ge光电转换层之间能形成高质量的SiN/Ge界面,从而提高光探测效率。Embodiments of the present application provide a waveguide-type photodetector and a manufacturing method thereof. The waveguide is formed of SiN, and the waveguide is coupled to the end face of the photoelectric conversion layer. Since the SiN waveguide has extremely low transmission loss in the near-infrared and even mid-infrared bands, and can realize low-loss coupling with optical fibers or silicon waveguides, it can improve the light transmission efficiency; and, between the SiN waveguide and the Ge photoelectric conversion layer Can form a high-quality SiN / Ge interface, thereby improving light detection efficiency.
根据本申请实施例的一个方面,提供一种波导型光电探测器,包括:位于衬底表面的第一绝缘层;位于所述第一绝缘层表面的下接触层;位于所述下接触层表面的光电转换层,所述光电转换层的材料包含锗(Ge);位于所述光电转换层表面的上接触层;以及形成于所述第一绝缘层上方的氮化硅波导,所述氮化硅波导在平行于所述衬底表面的横向上延伸,并且,在所述横向上,所述氮化硅波导的一个端部与所述光电转换层连接,所述氮化硅波导传递的光入射到所述光电转换层,并在所述光电转换层中生成光电流。According to an aspect of an embodiment of the present application, there is provided a waveguide-type photodetector, including: a first insulating layer on a surface of a substrate; a lower contact layer on the surface of the first insulating layer; and a surface on the lower contact layer Photoelectric conversion layer, the material of the photoelectric conversion layer includes germanium (Ge); an upper contact layer on the surface of the photoelectric conversion layer; and a silicon nitride waveguide formed above the first insulating layer, the nitride A silicon waveguide extends in a lateral direction parallel to the surface of the substrate, and in the lateral direction, one end of the silicon nitride waveguide is connected to the photoelectric conversion layer, and the light transmitted by the silicon nitride waveguide It is incident on the photoelectric conversion layer, and a photocurrent is generated in the photoelectric conversion layer.
根据本申请实施例的另一个方面,其中,所述波导型光电探测器还包括:形成于所述第一绝缘层表面,且在横向上围绕所述下接触层的第二绝缘层,其中,所述氮化硅波导形成于所述第二绝缘层表面。According to another aspect of the embodiments of the present application, wherein the waveguide-type photodetector further includes: a second insulating layer formed on the surface of the first insulating layer and surrounding the lower contact layer in the lateral direction, wherein, The silicon nitride waveguide is formed on the surface of the second insulating layer.
根据本申请实施例的另一个方面,其中,所述第二绝缘层的厚度与所述下接触层的厚度之差为所述下接触层的厚度的-10%~10%。According to another aspect of the embodiments of the present application, wherein the difference between the thickness of the second insulating layer and the thickness of the lower contact layer is -10% to 10% of the thickness of the lower contact layer.
根据本申请实施例的另一个方面,其中,所述氮化硅波导的厚度与所述光电转换层的厚度之差为所述光电转换层的厚度的-10%~10%。According to another aspect of the embodiments of the present application, wherein the difference between the thickness of the silicon nitride waveguide and the thickness of the photoelectric conversion layer is -10% to 10% of the thickness of the photoelectric conversion layer.
根据本申请实施例的另一个方面,其中,所述光电转换层的横向尺寸小于所述下接触层的横向尺寸。According to another aspect of the embodiments of the present application, wherein the lateral dimension of the photoelectric conversion layer is smaller than the lateral dimension of the lower contact layer.
根据本申请实施例的另一个方面,其中,所述下接触层是包含硅和/或锗的掺杂层,所述光电转换层是锗(Ge)的非掺杂层或锗锡(GeSn)的非掺杂层,所述上接触层是锗(Ge)的掺杂层或锗锡(GeSn)的掺杂层。According to another aspect of the embodiments of the present application, wherein the lower contact layer is a doped layer containing silicon and / or germanium, and the photoelectric conversion layer is an undoped layer of germanium (Ge) or germanium tin (GeSn) The upper contact layer is a doped layer of germanium (Ge) or a doped layer of germanium tin (GeSn).
根据本申请实施例的另一个方面,提供一种波导型光电探测器的制造方法,包括:According to another aspect of the embodiments of the present application, there is provided a method for manufacturing a waveguide photodetector, including:
在衬底表面的第一绝缘层表面形成下接触材料层;Forming a lower contact material layer on the surface of the first insulating layer on the substrate surface;
在所述下接触材料层表面形成光电转换层,并在所述光电转换层表面形成上接触层,所述光电转换层的材料包含锗(Ge);Forming a photoelectric conversion layer on the surface of the lower contact material layer, and forming an upper contact layer on the surface of the photoelectric conversion layer, the material of the photoelectric conversion layer containing germanium (Ge);
刻蚀所述下接触材料层,以形成下接触层;Etching the lower contact material layer to form a lower contact layer;
在所述第一绝缘层表面形成围绕所述下接触层的第二绝缘层;以及Forming a second insulating layer surrounding the lower contact layer on the surface of the first insulating layer; and
在所述第二绝缘层表面形成氮化硅波导,所述氮化硅波导在平行于所述衬底表面的横向上延伸,并且,在所述横向上,所述氮化硅波导的一个端部与所述光电转换层连接,其中,所述氮化硅波导传递的光入射到所述光电转换层,并在所述光电转换层中生成光电流。A silicon nitride waveguide is formed on the surface of the second insulating layer, the silicon nitride waveguide extends in a lateral direction parallel to the surface of the substrate, and, in the lateral direction, one end of the silicon nitride waveguide Is connected to the photoelectric conversion layer, wherein the light transmitted by the silicon nitride waveguide is incident on the photoelectric conversion layer, and a photocurrent is generated in the photoelectric conversion layer.
根据本申请实施例的另一个方面,其中,形成光电转换层和上接触 层的步骤包括:According to another aspect of the embodiments of the present application, wherein the steps of forming the photoelectric conversion layer and the upper contact layer include:
在所述下接触材料层表面形成光电转换材料层和上接触材料层的叠层;以及Forming a stack of the photoelectric conversion material layer and the upper contact material layer on the surface of the lower contact material layer; and
刻蚀所述上接触材料层和所述光电转换材料层,形成所述光电转换层和所述上接触层。The upper contact material layer and the photoelectric conversion material layer are etched to form the photoelectric conversion layer and the upper contact layer.
根据本申请实施例的另一个方面,其中,形成氮化硅波导的步骤包括:According to another aspect of the embodiments of the present application, wherein the step of forming a silicon nitride waveguide includes:
在所述第二绝缘层表面沉积氮化硅材料层;以及Depositing a silicon nitride material layer on the surface of the second insulating layer; and
刻蚀所述氮化硅材料层,形成所述氮化硅波导。The silicon nitride material layer is etched to form the silicon nitride waveguide.
根据本申请实施例的另一个方面,其中,所述氮化硅材料层的厚度与所述光电转换层的厚度之差为所述光电转换层的厚度的-10%~10%。According to another aspect of the embodiments of the present application, wherein the difference between the thickness of the silicon nitride material layer and the thickness of the photoelectric conversion layer is -10% to 10% of the thickness of the photoelectric conversion layer.
本申请的有益效果在于:The beneficial effects of this application are:
由SiN形成波导,因此,能提高光的传输效率;并且,SiN波导与光电转换层端面耦合,能提高光探测效率。Since the waveguide is formed by SiN, the light transmission efficiency can be improved; and the SiN waveguide is coupled to the end face of the photoelectric conversion layer, which can improve the light detection efficiency.
参照后文的说明和附图,详细公开了本申请的特定实施方式,指明了本申请的原理可以被采用的方式。应该理解,本申请的实施方式在范围上并不因而受到限制。在所附权利要求的精神和条款的范围内,本申请的实施方式包括许多改变、修改和等同。With reference to the following description and drawings, specific embodiments of the present application are disclosed in detail, and the manner in which the principles of the present application can be adopted is indicated. It should be understood that the embodiments of the present application are not thus limited in scope. Within the scope of the spirit and terms of the appended claims, the embodiments of the present application include many changes, modifications, and equivalents.
针对一种实施方式描述和/或示出的特征可以以相同或类似的方式在一个或更多个其它实施方式中使用,与其它实施方式中的特征相组合,或替代其它实施方式中的特征。Features described and / or illustrated for one embodiment may be used in one or more other embodiments in the same or similar manner, combined with features in other embodiments, or substituted for features in other embodiments .
应该强调,术语“包括/包含”在本文使用时指特征、整件、步骤或组件的存在,但并不排除一个或更多个其它特征、整件、步骤或组件的存在或附加。It should be emphasized that the term "comprising / comprising" as used herein refers to the presence of features, whole pieces, steps or components, but does not exclude the presence or addition of one or more other features, whole pieces, steps or components.
附图说明BRIEF DESCRIPTION
所包括的附图用来提供对本申请实施例的进一步的理解,其构成了说明书的一部分,用于例示本申请的实施方式,并与文字描述一起来阐释本申请的原理。显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。在附图中:The included drawings are used to provide a further understanding of the embodiments of the present application, which form a part of the specification, are used to exemplify the embodiments of the present application, and explain the principle of the present application together with the text description. Obviously, the drawings in the following description are only some embodiments of the present application. For those of ordinary skill in the art, without paying any creative labor, other drawings can be obtained based on these drawings. In the drawings:
图1是本申请实施例1的波导型光电探测器的一个立体示意图;FIG. 1 is a schematic perspective view of a waveguide-type photodetector according to Example 1 of the present application;
图2是图1的A-A’方向观察的一个截面示意图;Fig. 2 is a schematic cross-sectional view viewed in the direction A-A 'of Fig. 1;
图3是本申请实施例2的波导型光电探测器的制造方法的一个示意图;3 is a schematic diagram of a method of manufacturing a waveguide-type photodetector according to Example 2 of the present application;
图4是本申请实施例2中各步骤对应的器件截面图。4 is a cross-sectional view of the device corresponding to each step in Embodiment 2 of the present application.
具体实施方式detailed description
参照附图,通过下面的说明书,本申请的前述以及其它特征将变得明显。在说明书和附图中,具体公开了本申请的特定实施方式,其表明了其中可以采用本申请的原则的部分实施方式,应了解的是,本申请不限于所描述的实施方式,相反,本申请包括落入所附权利要求的范围内的全部修改、变型以及等同物。The foregoing and other features of the present application will become apparent from the following description with reference to the drawings. In the specification and the drawings, specific implementations of the present application are disclosed in detail, which shows some implementations in which the principles of the present application can be adopted. It should be understood that the present application is not limited to the described implementations. The application includes all modifications, variations, and equivalents falling within the scope of the appended claims.
在本申请各实施例的说明中,为描述方便,将平行于衬底的第一绝缘层的主表面的方向称为“横向”,将垂直于衬底的第一绝缘层的主表面的方向称为“纵向”,其中,各部件的“厚度”是指该部件在“纵向”的尺寸。In the description of the embodiments of the present application, for the convenience of description, the direction parallel to the main surface of the first insulating layer of the substrate is referred to as “lateral”, and the direction perpendicular to the main surface of the first insulating layer of the substrate It is called "longitudinal", where the "thickness" of each component refers to the size of the component in the "longitudinal".
实施例1Example 1
本实施例提供一种波导型光电探测器。This embodiment provides a waveguide type photodetector.
图1是本实施例的波导型光电探测器的一个立体示意图,图2是图1的 A-A’方向观察的一个截面示意图。Fig. 1 is a schematic perspective view of a waveguide-type photodetector of this embodiment, and Fig. 2 is a schematic cross-sectional view viewed in the direction A-A 'of Fig. 1.
如图1和图2所示,该波导型光电探测器1包括:As shown in FIGS. 1 and 2, the waveguide-type photodetector 1 includes:
位于衬底11表面的第一绝缘层12;位于第一绝缘层12表面的下接触层13;位于下接触层13表面的光电转换层14,光电转换层14的材料包含锗(Ge);位于光电转换层14表面的上接触层15;形成于第一绝缘层12上方的氮化硅波导16,氮化硅(SiN)波导16在平行于衬底11表面的横向上延伸,并且,在该横向上,氮化硅波导16的一个端部161与光电转换层14连接。A first insulating layer 12 on the surface of the substrate 11; a lower contact layer 13 on the surface of the first insulating layer 12; a photoelectric conversion layer 14 on the surface of the lower contact layer 13, the material of the photoelectric conversion layer 14 includes germanium (Ge); The upper contact layer 15 on the surface of the photoelectric conversion layer 14; a silicon nitride waveguide 16 formed above the first insulating layer 12, the silicon nitride (SiN) waveguide 16 extends in a lateral direction parallel to the surface of the substrate 11, and, in this In the lateral direction, one end 161 of the silicon nitride waveguide 16 is connected to the photoelectric conversion layer 14.
在本实施例中,氮化硅波导16传递的光通过该端部161入射到光电转换层14,并在光电转换层14中生成光电流。In this embodiment, the light transmitted by the silicon nitride waveguide 16 enters the photoelectric conversion layer 14 through the end portion 161, and a photocurrent is generated in the photoelectric conversion layer 14.
根据本实施例,由SiN形成波导,并且波导与光电转换层端面耦合。由于SiN波导在近红外乃至中红外波段具有极低的传输损耗,并能实现与光纤或硅波导的低损耗耦合,因此,能提高光的传输效率;并且,SiN波导与Ge光电转换层之间能形成高质量的SiN/Ge界面,从而提高光探测效率。According to this embodiment, the waveguide is formed of SiN, and the waveguide is coupled to the end face of the photoelectric conversion layer. Since the SiN waveguide has extremely low transmission loss in the near-infrared and even mid-infrared bands, and can realize low-loss coupling with optical fibers or silicon waveguides, it can improve the light transmission efficiency; Can form a high-quality SiN / Ge interface, thereby improving light detection efficiency.
在本实施例中,下接触层13可以是包含硅和/或锗的掺杂层,例如,为重掺杂的P型层或重掺杂的N型层。In this embodiment, the lower contact layer 13 may be a doped layer containing silicon and / or germanium, for example, a heavily doped P-type layer or a heavily doped N-type layer.
在本实施例中,第一绝缘层12例如可以是氧化硅,衬底11例如可以是硅。In this embodiment, the first insulating layer 12 may be silicon oxide, for example, and the substrate 11 may be silicon, for example.
在本实施例中,可以对绝缘体上的硅(SOI)进行加工,将SOI的顶层硅加工为下接触层13,将SOI的埋氧层作为第一绝缘层12,并将SOI的衬底硅作为衬底11。此外,本实施例也可以不限于此,例如,可以将体硅作为衬底11,在体硅表面形成绝缘层作为第一绝缘层12,在第一绝缘层12表面通过沉积或键合等方法形成硅材料层,对该硅材料层进行加工以形成下接触层13。In this embodiment, the silicon on insulator (SOI) can be processed, the top silicon layer of the SOI can be processed as the lower contact layer 13, the buried oxygen layer of the SOI can be used as the first insulating layer 12, and the silicon of the SOI substrate As the substrate 11. In addition, this embodiment may not be limited to this, for example, bulk silicon may be used as the substrate 11, an insulating layer may be formed on the surface of the bulk silicon as the first insulating layer 12, and methods such as deposition or bonding may be performed on the surface of the first insulating layer 12 A silicon material layer is formed, and the silicon material layer is processed to form the lower contact layer 13.
如图1和图2所示,该波导型光电探测器1还可以包括:形成于第一绝缘层12表面,且在横向上围绕下接触层13的第二绝缘层17。其中,氮化硅波导16形成于第二绝缘层17表面。As shown in FIGS. 1 and 2, the waveguide-type photodetector 1 may further include: a second insulating layer 17 formed on the surface of the first insulating layer 12 and surrounding the lower contact layer 13 in the lateral direction. The silicon nitride waveguide 16 is formed on the surface of the second insulating layer 17.
在本实施例中,第二绝缘层17的厚度与下接触层13的厚度之差为下接触层13的厚度的-10%~10%,由此,在第二绝缘层17的表面设置氮化硅波导16时,能够使氮化硅波导16的下表面与下接触层13的下表面齐平。In this embodiment, the difference between the thickness of the second insulating layer 17 and the thickness of the lower contact layer 13 is -10% to 10% of the thickness of the lower contact layer 13, thereby providing nitrogen on the surface of the second insulating layer 17 When the silicon waveguide 16 is made, the lower surface of the silicon nitride waveguide 16 can be flush with the lower surface of the lower contact layer 13.
在本实施例中,氮化硅波导16的厚度与光电转换层14的厚度之差为光电转换层14的厚度的-10%~10%,由此,便于氮化硅波导16传输的光通过端面161耦合进入光电转换层14,提高了光的耦合效率。此外,氮化硅波导16的端部161的横向位置可以与光电转换层14的横向的中心位置对齐,由此,进一步提高光的耦合效率。In this embodiment, the difference between the thickness of the silicon nitride waveguide 16 and the thickness of the photoelectric conversion layer 14 is -10% to 10% of the thickness of the photoelectric conversion layer 14, thereby facilitating the transmission of light transmitted by the silicon nitride waveguide 16 The end surface 161 is coupled into the photoelectric conversion layer 14, which improves the coupling efficiency of light. In addition, the lateral position of the end portion 161 of the silicon nitride waveguide 16 can be aligned with the lateral center position of the photoelectric conversion layer 14, thereby, the light coupling efficiency is further improved.
在本实施例中,光电转换层14的横向尺寸小于下接触层13的横向尺寸,由此,下接触层13有部分不被光电转换层14遮挡,该不被遮挡的部分的表面可以设置与下接触层13接触的电极。In this embodiment, the lateral dimension of the photoelectric conversion layer 14 is smaller than the lateral dimension of the lower contact layer 13, and therefore, a portion of the lower contact layer 13 is not blocked by the photoelectric conversion layer 14, and the surface of the unblocked portion can be provided with The electrode that the lower contact layer 13 contacts.
例如,如图1和图2所示,第一电极18可以位于光电转换层14两侧,并且,第一电极18可以被设置在下接触层13的表面,并与下接触层13接触;第二电极19可以与上接触层15接触。For example, as shown in FIGS. 1 and 2, the first electrode 18 may be located on both sides of the photoelectric conversion layer 14, and the first electrode 18 may be disposed on the surface of the lower contact layer 13 and in contact with the lower contact layer 13; The electrode 19 may be in contact with the upper contact layer 15.
此外,如图2所示,第二绝缘层17还可以覆盖上接触层15的一部分,以及光电转换层14和上接触层15的侧壁。In addition, as shown in FIG. 2, the second insulating layer 17 may also cover a part of the upper contact layer 15 and the side walls of the photoelectric conversion layer 14 and the upper contact layer 15.
在本实施例中,光电转换层14可以是锗(Ge)的非掺杂层或锗锡(GeSn)的非掺杂层,即,光电转换层14可以是锗(Ge)的本征层或锗锡(GeSn)的本征层。对于光电转换层14,通过在Ge中掺入Sn,能够增大光电转换层14的吸收效率并拓宽光电转换层14的探测范围,例如,Sn的组分可以是大于0且小于40%(摩尔比)。In this embodiment, the photoelectric conversion layer 14 may be an undoped layer of germanium (Ge) or an undoped layer of germanium tin (GeSn), that is, the photoelectric conversion layer 14 may be an intrinsic layer of germanium (Ge) or Intrinsic layer of germanium tin (GeSn). For the photoelectric conversion layer 14, by incorporating Sn into Ge, the absorption efficiency of the photoelectric conversion layer 14 can be increased and the detection range of the photoelectric conversion layer 14 can be widened. For example, the composition of Sn can be greater than 0 and less than 40% (mole ratio).
在本实施例中,上接触层15可以是锗(Ge)的掺杂层或锗锡(GeSn) 的掺杂层。上接触层15的掺杂类型与下接触层13的掺杂类型相反。例如,上接触层15为P型重掺杂,下接触层13为N型重掺杂;或者,上接触层15为N型重掺杂,下接触层13为P型重掺杂。In this embodiment, the upper contact layer 15 may be a doped layer of germanium (Ge) or a doped layer of germanium tin (GeSn). The doping type of the upper contact layer 15 is opposite to that of the lower contact layer 13. For example, the upper contact layer 15 is heavily doped with P type and the lower contact layer 13 is heavily doped with N type; or, the upper contact layer 15 is heavily doped with N type and the lower contact layer 13 is heavily doped with P type.
第一绝缘层12和第二绝缘层17例如都是氧化硅。Both the first insulating layer 12 and the second insulating layer 17 are, for example, silicon oxide.
在本实施例中,光可以通过光纤-SiN波导耦合器进入氮化硅波导16或者通过Si波导-SiN波导耦合器进入氮化硅波导16,并通过氮化硅波导16的端部直接耦合进入光电转换层14。本实施例的氮化硅波导16集成的光电探测器可以与波导光路集成,更易实现通信波段低暗电流,低电容和高响应度的光电探测器的制备。In this embodiment, light can enter the silicon nitride waveguide 16 through the fiber-SiN waveguide coupler or enter the silicon nitride waveguide 16 through the Si waveguide-SiN waveguide coupler and directly couple into the end through the silicon nitride waveguide 16 Photoelectric conversion layer 14. The photodetector integrated with the silicon nitride waveguide 16 of this embodiment can be integrated with the waveguide optical path, and it is easier to realize the preparation of a photodetector with low dark current, low capacitance, and high response in the communication band.
本实施例的波导型光电探测器具有如下优点:第一,与传统的垂直入射锗探测器相比,基于波导结构的光电探测器能避免光探测器速率和量子效率间相互制约的问题,且容易与其他无源光器件集成;第二,与消逝波耦合型波导探测器相比,本实施例的基于端面耦合的波导型探测器具有更高的吸收效率;第三,氮化硅波导在近红外乃至中红外波段具有极低的传输损耗,并能实现与光纤或硅波导的低损耗耦合;第四,氮化硅波导的端面与光电转换层端面形成质量良好的界面,提高了光的耦合效率。The waveguide-type photodetector of this embodiment has the following advantages: First, compared with the conventional perpendicular-incidence germanium detector, the photodetector based on the waveguide structure can avoid the mutual restriction between the photodetector rate and quantum efficiency, and It is easy to integrate with other passive optical devices; second, compared with the evanescent wave coupling waveguide detector, the waveguide detector based on the end face coupling of this embodiment has higher absorption efficiency; third, the silicon nitride waveguide is The near-infrared and even mid-infrared bands have extremely low transmission loss and can realize low-loss coupling with optical fibers or silicon waveguides. Fourth, the end face of the silicon nitride waveguide and the end face of the photoelectric conversion layer form a good quality interface, which improves the optical Coupling efficiency.
实施例2Example 2
实施例2提供一种波导型光电探测器的制造方法,用于制造实施例1所述的波导型光电探测器。Embodiment 2 provides a method for manufacturing a waveguide-type photodetector, which is used to manufacture the waveguide-type photodetector described in Embodiment 1.
图3是本实施例的波导型光电探测器的制造方法的一个示意图,如图3所示,在本实施例中,该制造方法可以包括:FIG. 3 is a schematic diagram of the manufacturing method of the waveguide-type photodetector of this embodiment. As shown in FIG. 3, in this embodiment, the manufacturing method may include:
步骤301、在衬底11表面的第一绝缘层12表面形成下接触材料层13a; Step 301, forming a lower contact material layer 13a on the surface of the first insulating layer 12 on the surface of the substrate 11;
步骤302、在下接触材料层13a表面形成光电转换层14,并在光电转换层14表面形成上接触层15,其中,光电转换层14的材料包含锗(Ge);Step 302: Form a photoelectric conversion layer 14 on the surface of the lower contact material layer 13a, and form an upper contact layer 15 on the surface of the photoelectric conversion layer 14, wherein the material of the photoelectric conversion layer 14 includes germanium (Ge);
步骤303、刻蚀下接触材料层13a,以形成下接触层13; Step 303, etching the lower contact material layer 13a to form the lower contact layer 13;
步骤304、在第一绝缘层12表面形成围绕所述下接触层13的第二绝缘层17; Step 304, forming a second insulating layer 17 surrounding the lower contact layer 13 on the surface of the first insulating layer 12;
步骤305、在第二绝缘层17表面形成氮化硅波导16,氮化硅波导16在平行于衬底11表面的横向上延伸,并且,在该横向上,氮化硅波导16的一个端部161与光电转换层14连接。 Step 305, forming a silicon nitride waveguide 16 on the surface of the second insulating layer 17, the silicon nitride waveguide 16 extends in a lateral direction parallel to the surface of the substrate 11, and, in the lateral direction, one end of the silicon nitride waveguide 16 161 is connected to the photoelectric conversion layer 14.
在本实施例中,氮化硅波导16传递的光入射到光电转换层14,并在光电转换层14中生成光电流。In the present embodiment, the light transmitted by the silicon nitride waveguide 16 is incident on the photoelectric conversion layer 14, and a photocurrent is generated in the photoelectric conversion layer 14.
在本实施例中,步骤302可以包括:In this embodiment, step 302 may include:
步骤3021、在下接触材料层13a表面形成光电转换材料层14a和上接触材料层15a的叠层,其中,光电转换材料层14a是非掺杂的材料层,上接触材料层15a是掺杂的材料层;以及Step 3021: Form a stack of the photoelectric conversion material layer 14a and the upper contact material layer 15a on the surface of the lower contact material layer 13a, wherein the photoelectric conversion material layer 14a is an undoped material layer and the upper contact material layer 15a is a doped material layer ;as well as
步骤3022、刻蚀上接触材料层15a和光电转换材料层14a,形成光电转换层14和上接触层15,其中,上接触层15和光电转换层14形成台面。Step 3022, etching the upper contact material layer 15a and the photoelectric conversion material layer 14a to form the photoelectric conversion layer 14 and the upper contact layer 15, wherein the upper contact layer 15 and the photoelectric conversion layer 14 form a mesa.
在本实施例中,步骤305的形成氮化硅波导的步骤可以包括:In this embodiment, the step of forming a silicon nitride waveguide in step 305 may include:
步骤3051、在第二绝缘层17表面沉积氮化硅材料层16a;Step 3051, depositing a silicon nitride material layer 16a on the surface of the second insulating layer 17;
步骤3052、刻蚀氮化硅材料层16a,形成氮化硅波导16。Step 3052: The silicon nitride material layer 16a is etched to form a silicon nitride waveguide 16.
在本实施例的上述步骤3051中,氮化硅材料层16a的厚度与光电转换层14的厚度之差为光电转换层14的厚度的-10%~10%。In the above step 3051 of this embodiment, the difference between the thickness of the silicon nitride material layer 16a and the thickness of the photoelectric conversion layer 14 is -10% to 10% of the thickness of the photoelectric conversion layer 14.
下面,结合一个具体的实例来说明本申请的波导型光电探测器的制造方法。The manufacturing method of the waveguide-type photodetector of the present application will be described below with reference to a specific example.
图4是该实例中各步骤对应的器件截面图,如图4所示,在该实例中,波导型光电探测器的制造方法包括如下步骤:4 is a cross-sectional view of the device corresponding to each step in this example. As shown in FIG. 4, in this example, the manufacturing method of the waveguide-type photodetector includes the following steps:
步骤1:对衬底11表面的第一绝缘层12的硅材料层进行离子注入及高温退火,使硅材料层成为下接触材料层13a,例如,下接触材料层13a是 P型重掺杂;然后,在下接触材料层13a的表面外延生长锗(Ge)或锗锡(GeSn)材料层,并对该锗(Ge)或锗锡(GeSn)材料层的上部进行离子注入及高温退火,以将该锗(Ge)或锗锡(GeSn)材料层的上部制备成N型重掺杂层,由此,该锗(Ge)或锗锡(GeSn)材料层的下部(即,本征的部分)成为光电转换材料层14a,该锗(Ge)或锗锡(GeSn)材料层的上部(即,重掺杂的部分)成为上接触材料层15a。参见图4的(a)。Step 1: Perform ion implantation and high-temperature annealing on the silicon material layer of the first insulating layer 12 on the surface of the substrate 11 so that the silicon material layer becomes the lower contact material layer 13a. For example, the lower contact material layer 13a is heavily doped P-type; Then, a germanium (Ge) or germanium tin (GeSn) material layer is epitaxially grown on the surface of the lower contact material layer 13a, and ion implantation and high temperature annealing are performed on the upper part of the germanium (Ge) or germanium tin germanium (GeSn) material layer to remove The upper part of the germanium (Ge) or germanium tin (GeSn) material layer is prepared as an N-type heavily doped layer, whereby the lower part (ie, intrinsic part) of the germanium (Ge) or germanium tin (GeSn) material layer As the photoelectric conversion material layer 14a, the upper part (ie, the heavily doped portion) of the germanium (Ge) or germanium tin (GeSn) material layer becomes the upper contact material layer 15a. See (a) of FIG. 4.
步骤2:对上接触材料层15a和光电转换材料层14a进行光刻和干法刻蚀,形成光电转换层14和上接触层15,其中,上接触层15和光电转换层14形成台面;并且,对露出的下接触材料层13a进行光刻及干法刻蚀,以形成下接触层13。参见图4的(b)。Step 2: Perform photolithography and dry etching on the upper contact material layer 15a and the photoelectric conversion material layer 14a to form the photoelectric conversion layer 14 and the upper contact layer 15, wherein the upper contact layer 15 and the photoelectric conversion layer 14 form a mesa; and , Performing photolithography and dry etching on the exposed lower contact material layer 13a to form the lower contact layer 13. See (b) of Figure 4.
步骤3:淀积SiO 2作为第二绝缘层17;在第二绝缘层17表面沉积氮化硅材料层16a,其厚度与光电转换层14厚度相当;然后,对氮化硅材料层16a进行光刻并刻蚀从而制备氮化硅波导16,氮化硅波导16直接与Ge光电转换层14连接。参见图4的(c)。 Step 3: Deposit SiO 2 as the second insulating layer 17; deposit a silicon nitride material layer 16a on the surface of the second insulating layer 17 whose thickness is equivalent to the thickness of the photoelectric conversion layer 14; then, light the silicon nitride material layer 16a The silicon nitride waveguide 16 is prepared by etching and etching, and the silicon nitride waveguide 16 is directly connected to the Ge photoelectric conversion layer 14. See (c) of Figure 4.
步骤4:对第二绝缘层17进行光刻及刻蚀,以定义金属接触区域,然后沉积金属电极,并通过光刻和刻蚀形成第一电极和第二电极,从而完成器件制备。参见图4的(d)。Step 4: Perform photolithography and etching on the second insulating layer 17 to define a metal contact area, and then deposit a metal electrode, and form the first electrode and the second electrode by photolithography and etching, thereby completing device preparation. See (d) of FIG. 4.
根据本实施例,由SiN形成波导,并且波导与光电转换层端面耦合。由于氮化硅波导在近红外乃至中红外波段具有极低的传输损耗,并能实现与光纤或硅波导的低损耗耦合,因此,能提高光的传输效率;并且,氮化硅波导与Ge光电转换层之间能形成高质量的SiN/Ge界面,从而提高光探测效率。According to this embodiment, the waveguide is formed of SiN, and the waveguide is coupled to the end face of the photoelectric conversion layer. Since the silicon nitride waveguide has extremely low transmission loss in the near-infrared and even mid-infrared bands, and can realize low-loss coupling with the optical fiber or the silicon waveguide, it can improve the light transmission efficiency; and, the silicon nitride waveguide and the Ge photoelectricity A high-quality SiN / Ge interface can be formed between the conversion layers, thereby improving light detection efficiency.
以上结合具体的实施方式对本申请进行了描述,但本领域技术人员应该清楚,这些描述都是示例性的,并不是对本申请保护范围的限制。本领域技术人员可以根据本申请的精神和原理对本申请做出各种变型和 修改,这些变型和修改也在本申请的范围内。The present application has been described above in conjunction with specific implementations, but those skilled in the art should understand that these descriptions are exemplary and do not limit the protection scope of the present application. A person skilled in the art can make various variations and modifications to the present application according to the spirit and principle of the present application, and these variations and modifications are also within the scope of the present application.

Claims (10)

  1. 一种波导型光电探测器,其中,包括:A waveguide type photodetector, which includes:
    位于衬底表面的第一绝缘层;A first insulating layer on the surface of the substrate;
    位于所述第一绝缘层表面的下接触层;A lower contact layer on the surface of the first insulating layer;
    位于所述下接触层表面的光电转换层,所述光电转换层的材料包含锗(Ge);A photoelectric conversion layer on the surface of the lower contact layer, the material of the photoelectric conversion layer includes germanium (Ge);
    位于所述光电转换层表面的上接触层;以及An upper contact layer on the surface of the photoelectric conversion layer; and
    形成于所述第一绝缘层上方的氮化硅波导,所述氮化硅波导在平行于所述衬底表面的横向上延伸,并且,在所述横向上,所述氮化硅波导的一个端部与所述光电转换层连接,A silicon nitride waveguide formed above the first insulating layer, the silicon nitride waveguide extending in a lateral direction parallel to the surface of the substrate, and, in the lateral direction, one of the silicon nitride waveguides The end is connected to the photoelectric conversion layer,
    所述氮化硅波导传递的光入射到所述光电转换层,并在所述光电转换层中生成光电流。The light transmitted by the silicon nitride waveguide is incident on the photoelectric conversion layer, and a photocurrent is generated in the photoelectric conversion layer.
  2. 如权利要求1所述的波导型光电探测器,其中,所述波导型光电探测器还包括:The waveguide-type photodetector of claim 1, wherein the waveguide-type photodetector further comprises:
    形成于所述第一绝缘层表面,且在横向上围绕所述下接触层的第二绝缘层,其中,所述氮化硅波导形成于所述第二绝缘层表面。A second insulating layer formed on the surface of the first insulating layer and laterally surrounding the lower contact layer, wherein the silicon nitride waveguide is formed on the surface of the second insulating layer.
  3. 如权利要求2所述的波导型光电探测器,其中,所述第二绝缘层的厚度与所述下接触层的厚度之差为所述下接触层的厚度的-10%~10%。The waveguide type photodetector according to claim 2, wherein the difference between the thickness of the second insulating layer and the thickness of the lower contact layer is -10% to 10% of the thickness of the lower contact layer.
  4. 如权利要求1或2所述的波导型光电探测器,其中,所述氮化硅波导的厚度与所述光电转换层的厚度之差为所述光电转换层的厚度的-10%~10%。The waveguide type photodetector according to claim 1 or 2, wherein the difference between the thickness of the silicon nitride waveguide and the thickness of the photoelectric conversion layer is -10% to 10% of the thickness of the photoelectric conversion layer .
  5. 如权利要求1所述的波导型光电探测器,其中,所述光电转换层的横向尺寸小于所述下接触层的横向尺寸。The waveguide-type photodetector according to claim 1, wherein the lateral dimension of the photoelectric conversion layer is smaller than the lateral dimension of the lower contact layer.
  6. 如权利要求1所述的波导型光电探测器,其中,所述下接触层是包含硅和/或锗的掺杂层,所述光电转换层是锗(Ge)的非掺杂层或锗锡(GeSn)的非掺杂层,所述上接触层是锗(Ge)的掺杂层或锗锡(GeSn)的掺杂层。The waveguide type photodetector according to claim 1, wherein the lower contact layer is a doped layer containing silicon and / or germanium, and the photoelectric conversion layer is an undoped layer of germanium (Ge) or germanium tin (GeSn) undoped layer, the upper contact layer is a doped layer of germanium (Ge) or a doped layer of germanium tin (GeSn).
  7. 一种波导型光电探测器的制造方法,其中,包括:A method for manufacturing a waveguide photodetector, which includes:
    在衬底表面的第一绝缘层表面形成下接触材料层;Forming a lower contact material layer on the surface of the first insulating layer on the substrate surface;
    在所述下接触材料层表面形成光电转换层,并在所述光电转换层表面形成上接触层,所述光电转换层的材料包含锗(Ge);Forming a photoelectric conversion layer on the surface of the lower contact material layer, and forming an upper contact layer on the surface of the photoelectric conversion layer, the material of the photoelectric conversion layer containing germanium (Ge);
    刻蚀所述下接触材料层,以形成下接触层;Etching the lower contact material layer to form a lower contact layer;
    在所述第一绝缘层表面形成围绕所述下接触层的第二绝缘层;以及Forming a second insulating layer surrounding the lower contact layer on the surface of the first insulating layer; and
    在所述第二绝缘层表面形成氮化硅波导,所述氮化硅波导在平行于所述衬底表面的横向上延伸,并且,在所述横向上,所述氮化硅波导的一个端部与所述光电转换层连接,A silicon nitride waveguide is formed on the surface of the second insulating layer, the silicon nitride waveguide extends in a lateral direction parallel to the surface of the substrate, and, in the lateral direction, one end of the silicon nitride waveguide Is connected to the photoelectric conversion layer,
    其中,所述氮化硅波导传递的光入射到所述光电转换层,并在所述光电转换层中生成光电流。Wherein, the light transmitted by the silicon nitride waveguide is incident on the photoelectric conversion layer, and a photocurrent is generated in the photoelectric conversion layer.
  8. 如权利要求7所述的波导型光电探测器的制造方法,其中,形成光电转换层和上接触层的步骤包括:The method of manufacturing a waveguide-type photodetector according to claim 7, wherein the steps of forming the photoelectric conversion layer and the upper contact layer include:
    在所述下接触材料层表面形成光电转换材料层和上接触材料层的叠层;以及Forming a stack of the photoelectric conversion material layer and the upper contact material layer on the surface of the lower contact material layer; and
    刻蚀所述上接触材料层和所述光电转换材料层,形成所述光电转换层和所述上接触层。The upper contact material layer and the photoelectric conversion material layer are etched to form the photoelectric conversion layer and the upper contact layer.
  9. 如权利要求7所述的波导型光电探测器的制造方法,其中,形成氮化硅波导的步骤包括:The method of manufacturing a waveguide-type photodetector according to claim 7, wherein the step of forming a silicon nitride waveguide includes:
    在所述第二绝缘层表面沉积氮化硅材料层;以及Depositing a silicon nitride material layer on the surface of the second insulating layer; and
    刻蚀所述氮化硅材料层,形成所述氮化硅波导。The silicon nitride material layer is etched to form the silicon nitride waveguide.
  10. 如权利要求9所述的波导型光电探测器的制造方法,其中,所述氮化硅材料层的厚度与所述光电转换层的厚度之差为所述光电转换层的厚度的-10%~10%。The method of manufacturing a waveguide-type photodetector according to claim 9, wherein the difference between the thickness of the silicon nitride material layer and the thickness of the photoelectric conversion layer is -10% of the thickness of the photoelectric conversion layer 10%.
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