WO2020101096A1 - Barre d'armature ayant une limite d'élasticité de classe 700 mpa et une excellent rapport de résistance à la traction/limite d'élasticité et un allongement uniforme, et son procédé de fabrication - Google Patents

Barre d'armature ayant une limite d'élasticité de classe 700 mpa et une excellent rapport de résistance à la traction/limite d'élasticité et un allongement uniforme, et son procédé de fabrication Download PDF

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Publication number
WO2020101096A1
WO2020101096A1 PCT/KR2018/014517 KR2018014517W WO2020101096A1 WO 2020101096 A1 WO2020101096 A1 WO 2020101096A1 KR 2018014517 W KR2018014517 W KR 2018014517W WO 2020101096 A1 WO2020101096 A1 WO 2020101096A1
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WO
WIPO (PCT)
Prior art keywords
rebar
cooling
mpa
yield ratio
uniform elongation
Prior art date
Application number
PCT/KR2018/014517
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English (en)
Korean (ko)
Inventor
황병철
이준호
심상철
홍태운
이상인
Original Assignee
고려대학교 산학협력단
서울과학기술대학교 산학협력단
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 고려대학교 산학협력단, 서울과학기술대학교 산학협력단 filed Critical 고려대학교 산학협력단
Priority to US16/617,559 priority Critical patent/US20200277681A1/en
Publication of WO2020101096A1 publication Critical patent/WO2020101096A1/fr

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/16Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling wire rods, bars, merchant bars, rounds wire or material of like small cross-section
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0062Heat-treating apparatus with a cooling or quenching zone
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0075Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

Definitions

  • the linear velocity of the reinforcing bar is 5 to 20 m / sec
  • the yield ratio and uniform elongation are characterized by cooling with water pressure of 10 to 20 bar and a quantity of 100 to 300 m 3 / hr by water cooling. This excellent yield strength provides 700 MPa class rebar.
  • Figure 2 shows a cross-sectional view of the reinforcing bars in Examples and Comparative Examples according to the present invention.
  • Figure 5 shows a graph showing the hardness by location of one embodiment and a comparative example according to the present invention.
  • Carbon (C) is an element effective for increasing strength, but if the content is low, the desired high strength is not obtained, and if the content is high, it is effective for increasing strength, but since deterioration in toughness and ductility is remarkable, it is 0.18 to 0.30 wt% to obtain high strength. It is preferred.
  • Silicon (Si) is an essential element for deoxidation of steel and is an element effective in increasing strength. If the silicon content is 0.10 wt% or less, a desired high strength is difficult to obtain, and if it exceeds a certain range, a decrease in toughness and ductility is caused. Accordingly, silicon is preferably 0.13 to 0.40 wt%.
  • the tempered martensite structure is formed on the surface part through the cooling process in the first austenite, and the tempered martensite and bainite at the boundary.
  • Low temperature metamorphic tissue such as is formed.
  • the central part is characterized in that bainite is mainly formed and the rest is ferrite.
  • cooling was performed by air cooling at a line speed of 30 m / sec.
  • the reinforcing bars of the comparative examples have a rebar performance of 600 MPa class with a yield strength developed in the prior art.
  • the reinforcing bars of Examples 1 and 2 of the present invention have excellent yield ratio characteristics of 1.25 or higher despite the yield strength being very high of 700 MPa or higher. And high uniform elongation at 5.0% or higher.
  • Comparative Example 2 only a microstructure composed of ferrite and pearlite is formed on both the surface portion and the center portion due to production by air cooling.
  • 3 and 4 show an optical microscope and a scanning electron microscope photograph of Examples and Comparative Examples according to the present invention.
  • Comparative Examples 1 and 3 due to the temper core cooling process, bainite and tempered martensite are partially formed at the boundary, and tempered martensite is formed at the surface, but a soft ferrite and pearlite structure is formed at the center. Yield strength is less than 700 MPa.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

La présente invention concerne une barre d'armature ayant une limite d'élasticité de classe 700 MPa et un excellent rapport de résistance à la traction/limite d'élasticité et un allongement uniforme, et son procédé de fabrication et, plus spécifiquement, une barre d'armature ayant une limite d'élasticité de classe 700 MPa et un excellent rapport de résistance à la traction/limite d'élasticité et un allongement uniforme, dont la partie centrale est composée de structures comprenant de la bainite et de la ferrite, la bainite représentant 20 à 80 % en volume, et son procédé de fabrication.
PCT/KR2018/014517 2018-11-16 2018-11-23 Barre d'armature ayant une limite d'élasticité de classe 700 mpa et une excellent rapport de résistance à la traction/limite d'élasticité et un allongement uniforme, et son procédé de fabrication WO2020101096A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US16/617,559 US20200277681A1 (en) 2018-11-16 2018-11-23 700MPa CLASS STEEL BAR HAVING EXCELLENT YIELD RATIO AND UNIFORM ELONGATION PROPERTY, AND METHOD FOR MANUFACTURING THE SAME

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2018-0141344 2018-11-16
KR1020180141344A KR102173920B1 (ko) 2018-11-16 2018-11-16 항복비와 균일연신율이 우수한 항복강도 700 MPa급 철근 및 그 제조 방법

Publications (1)

Publication Number Publication Date
WO2020101096A1 true WO2020101096A1 (fr) 2020-05-22

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PCT/KR2018/014517 WO2020101096A1 (fr) 2018-11-16 2018-11-23 Barre d'armature ayant une limite d'élasticité de classe 700 mpa et une excellent rapport de résistance à la traction/limite d'élasticité et un allongement uniforme, et son procédé de fabrication

Country Status (3)

Country Link
US (1) US20200277681A1 (fr)
KR (1) KR102173920B1 (fr)
WO (1) WO2020101096A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114000051A (zh) * 2021-09-29 2022-02-01 武钢集团昆明钢铁股份有限公司 一种超细晶hrb400e盘条抗震钢筋及其制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112410677A (zh) * 2020-11-30 2021-02-26 武汉钢铁有限公司 一种500MPa级热轧盘螺及其生产方法

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KR20090132796A (ko) * 2008-06-23 2009-12-31 동국제강주식회사 고강도 저항복비 철근의 제조방법
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KR20110072787A (ko) * 2009-12-23 2011-06-29 주식회사 포스코 항복강도 및 신장 플랜지성이 우수한 강판 및 그 제조방법
JP2012241266A (ja) * 2011-05-24 2012-12-10 Jfe Steel Corp 高圧縮強度耐サワーラインパイプ用鋼管及びその製造方法
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114000051A (zh) * 2021-09-29 2022-02-01 武钢集团昆明钢铁股份有限公司 一种超细晶hrb400e盘条抗震钢筋及其制备方法
CN114000051B (zh) * 2021-09-29 2022-05-10 武钢集团昆明钢铁股份有限公司 一种超细晶hrb400e盘条抗震钢筋及其制备方法

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KR20200057247A (ko) 2020-05-26
KR102173920B1 (ko) 2020-11-04
US20200277681A1 (en) 2020-09-03

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