WO2020098947A1 - Recyclingfreundliches verpackungslaminat mit guter barrierewirkung sowie niedriger dichte und verfahren zu dessen herstellung - Google Patents

Recyclingfreundliches verpackungslaminat mit guter barrierewirkung sowie niedriger dichte und verfahren zu dessen herstellung Download PDF

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Publication number
WO2020098947A1
WO2020098947A1 PCT/EP2018/081477 EP2018081477W WO2020098947A1 WO 2020098947 A1 WO2020098947 A1 WO 2020098947A1 EP 2018081477 W EP2018081477 W EP 2018081477W WO 2020098947 A1 WO2020098947 A1 WO 2020098947A1
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WO
WIPO (PCT)
Prior art keywords
layer
laminate
barrier
laminate layer
weight
Prior art date
Application number
PCT/EP2018/081477
Other languages
German (de)
English (en)
French (fr)
Inventor
Thami LAMTIGUI
Achim Grefenstein
Original Assignee
Constantia Pirk Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Constantia Pirk Gmbh & Co. Kg filed Critical Constantia Pirk Gmbh & Co. Kg
Priority to PCT/EP2018/081477 priority Critical patent/WO2020098947A1/de
Priority to US17/287,653 priority patent/US20210354894A1/en
Priority to JP2021526500A priority patent/JP2022507509A/ja
Priority to EP18807033.8A priority patent/EP3880473B1/de
Priority to MX2021005773A priority patent/MX2021005773A/es
Priority to ES18807033T priority patent/ES2913632T3/es
Priority to CA3119686A priority patent/CA3119686A1/en
Priority to PL18807033T priority patent/PL3880473T3/pl
Publication of WO2020098947A1 publication Critical patent/WO2020098947A1/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/144—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001—Combinations of extrusion moulding with other shaping operations
    • B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07—Flat, e.g. panels
    • B29C48/08—Flat, e.g. panels flexible, e.g. films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • B29C48/10—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels flexible, e.g. blown foils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/49—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using two or more extruders to feed one die or nozzle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
    • B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
    • B29C55/16—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial simultaneously
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B32B27/205—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents the fillers creating voids or cavities, e.g. by stretching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/325—Layered products comprising a layer of synthetic resin comprising polyolefins comprising polycycloolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/005—Shaping by stretching, e.g. drawing through a die; Apparatus therefor characterised by the choice of materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/023—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets using multilayered plates or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
    • B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
    • B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
    • B29C55/143—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively firstly parallel to the direction of feed and then transversely thereto
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04—Polymers of ethylene
    • B29K2023/06—PE, i.e. polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • B29K2995/0017—Heat stable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0065—Permeability to gases
    • B29K2995/0067—Permeability to gases non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
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    • B29K2995/0068—Permeability to liquids; Adsorption
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    • B32B2439/00—Containers; Receptacles
    • B32B2439/02—Open containers
    • B32B2439/06—Bags, sacks, sachets

Definitions

  • the subject invention relates to a packaging laminate with a first laminate layer and a second laminate layer, the first laminate layer comprising a barrier layer, and a method for producing such a packaging laminate.
  • Packaging laminates are used in the packaging industry, which should have different properties depending on the application.
  • Packaging laminates of this type are generally multilayer plastic films which are produced in the extrusion process, co-extrusion process (in both cases in the flat film and blown film process) or laminating process (connection of individual layers by means of a laminating adhesive), and also mixtures thereof. Layers not made of plastic can also be integrated in the packaging laminate, for example a layer made of aluminum or paper.
  • the packaging laminate usually also has an outer sealing layer in order to heat seal the packaging laminate to a desired packaging, such as e.g. a bag, a sack, a bag, etc. to process.
  • the packaging laminate generally contains a barrier layer made of aluminum or a suitable barrier polymer, such as, for example, ethylene-vinyl alcohol copolymer (EVOH) or polyamide (PA).
  • a barrier layer made of aluminum or a suitable barrier polymer, such as, for example, ethylene-vinyl alcohol copolymer (EVOH) or polyamide (PA).
  • EVOH ethylene-vinyl alcohol copolymer
  • PA polyamide
  • further layers can be included in order to impart the desired properties to the packaging laminate, such as toughness, rigidity, shrinkability, tear resistance, etc.
  • a sealing layer is typically made of a polyolefin, usually polypropylene (PP) or polyethylene (PE) in the different densities of LLDPE, LDPE, MDPE or HDPE.
  • the packaging laminate In order to be able to process the packaging laminate easily, the packaging laminate must of course not be thrown or rolled up (so-called curling), which is why symmetrical layer structures are usually used.
  • orientation can take place through the extrusion process, for example in a multiple bubble process, or only after the extrusion process by stretching the packaging laminate in the machine direction (in the longitudinal direction of the packaging laminate) and / or in the transverse direction (normal on the longitudinal direction).
  • the orientation of the packaging laminate can above all improve the rigidity, tensile strength and toughness.
  • the orientation can change the crystallization of the packaging laminate, that even rather cloudy materials, such as HDPE, become more transparent after stretching.
  • WO 2013/032932 A1 describes such a packaging laminate, for example with the structure HDPE / connecting layer / EVOH / connecting layer / sealing layer, as a shrink film.
  • the packaging laminate as a whole is stretched biaxially to produce the shrinkage property.
  • stretching can only be carried out after the individual layers of the packaging laminate have reached sufficient bond strength.
  • WO 2009/017588 A1 shows something similar.
  • WO 2013/032932 A1 and WO 2009/017588 A1 primarily aim at a suitable material for the connecting layer.
  • Films made of so-called cavitated polyolefins, in particular polypropylene, are also known.
  • a cavitating agent is added to the polyolefin used before extrusion. After extrusion, the film is stretched (in the machine direction and / or transverse direction), as a result of which the microcavities in the film are formed by the embedded cavitation medium.
  • Cavitated PP-based films have good rigidity and low water permeability (a high barrier against water / water vapor), but poor oxygen and aroma permeability (low oxygen barrier and aroma barrier).
  • US 2012/0135256 A1 describes a packaging laminate consisting of a first laminate layer made of ethylene-vinyl alcohol copolymer (EVOH) and a second laminate layer made of a cavitated PP or a mixture of cavitated PP and HDPE (high density polyethylene).
  • EVOH ethylene-vinyl alcohol copolymer
  • a second laminate layer made of a cavitated PP or a mixture of cavitated PP and HDPE (high density polyethylene).
  • the two laminate layers are co-extruded and are stretched in the machine and cross directions after extrusion.
  • This object is achieved by co-extrusion of a first laminate layer consisting of a substrate layer with 5-30% by weight cavitating agent and with a PE content of at least 60% by weight, a connecting layer and a barrier layer made of a barrier polymer, preferably made of polyamide or ethylene -Vinyl alcohol copolymer, with a thickness of at most 20% of the total thickness of the first laminate layer, the connecting layer being arranged between the substrate layer and the barrier layer, the subsequent stretching of the co-extruded first laminate layer, and the subsequent connection of those stretched in this way first laminate layer with a second laminate layer with a polyethylene content of at least 80% by weight, the second laminate layer with the barrier layer Re slaughter the first laminate layer is connected.
  • the packaging laminate according to the invention comprises a first laminate layer and a second laminate layer, the first laminate layer being a co-extruded and stretched composite of a cavitated substrate layer with 5-30% by weight cavitating agent and with a PE content of at least 60% by weight, a connecting layer and a barrier layer of a barrier polymer, preferably of polyamide or ethylene-vinyl alcohol copolymer, with a thickness of at most 20% of the total thickness of the first laminate layer, the connecting layer being arranged between the substrate layer and the barrier layer and the first laminate layer on whose barrier layer is connected to the second laminate layer.
  • a barrier polymer preferably of polyamide or ethylene-vinyl alcohol copolymer
  • the barrier effect of the first laminate layer is significantly increased by stretching the first laminate layer before laminating with the second laminate layer.
  • the simple, asymmetrical structure of the first laminate layer simplifies production considerably compared to conventional symmetrical structures, which also significantly reduces manufacturing costs.
  • the density of the cavitated layer can be reduced by the cavitation agent, as a result of which the basis weight of the packaging laminate can be reduced. In this way, very light and thin-walled packaging can be produced without having to compromise on the barrier properties.
  • the barrier effect can additionally be increased by metallizing or coating with aluminum oxide or silicon oxide and / or additional barrier lacquers on the barrier layer before further lamination.
  • the first laminate layer on the substrate layer is connected to a further single or multi-layer laminate layer.
  • the first laminate layer can be printed, metallized or coated on the barrier layer and / or on the substrate layer.
  • at least one layer of the further laminate layer can be printed, metallized or coated.
  • the first laminate layer is connected to the substrate layer with a unidirectionally (in the machine direction) or bidirectionally oriented fourth laminate layer, which has a substrate layer with a PE content of at least 60% by weight, a barrier layer made of a Has barrier polymer and a connection layer arranged between them.
  • a packaging laminate has particularly good barrier properties.
  • the second laminate layer is a co-extruded, machine direction or bidirectionally stretched laminate from a cavitated substrate layer with a PE content of at least 60% by weight, preferably at least 70% by weight and very particularly preferably at least 80% by weight.
  • a connecting layer a barrier layer made of a barrier polymer, preferably made of polyamide or ethylene Vinyl alcohol copolymer, with a maximum thickness of 20% of the total thickness of the second laminate layer and a sealing layer
  • the connecting layer of the second laminate layer is arranged between the substrate layer and the barrier layer of the second laminate layer and the sealing layer is arranged on the substrate layer and the barrier layer of the second laminate layer is connected to the barrier layer of the first laminate layer.
  • a packaging laminate also has particularly good barrier properties.
  • this advantageously integrates the sealing layer into the co-extruded second laminate layer, which means that no further manufacturing steps for the packaging laminate are required.
  • the stretched second laminate layer preferably also has a polyethylene layer with a cavitating agent, as a result of which the basis weight of the packaging laminate can be reduced even further. It is particularly advantageous here if the second laminate layer has a polyethylene layer with a cavitation agent, which is connected on one or the sides to a polyethylene layer without a cavitation agent.
  • FIG. 1 shows a first embodiment of a packaging laminate according to the invention
  • FIG. 3 shows a third advantageous embodiment of a packaging laminate according to the invention.
  • FIG. 4 shows a fourth advantageous embodiment of a packaging laminate according to the invention.
  • FIG. 1 shows a packaging laminate 1 according to the invention with a first laminate layer 2 and a second laminate layer 3 connected thereto.
  • the first laminate layer 2 in the packaging laminate 1 is stretched in the machine direction (MDO) and / or in the transverse direction (TDO), that is to say unidirectionally (in MDO) or bidirectionally, and has an asymmetrical layer structure with a substrate layer 4 and a barrier layer 6, which is formed by a Connection layer 5 are interconnected.
  • the thickness of the first laminate layer 2 is preferably 10 to 40 pm.
  • the substrate layer 4 is a polyethylene (PE), whereby different types of polyethylene can be used, such as HDPE (high density polyethylene with a density between 0.94-0.97 g / cm 3 ), MDPE (medium density polyethylene), LDPE (Low density polyethylene with a density between 0.915-0.935 g / cm 3 ), LLDPE (linear low density polyethylene with a density between 0.87-0.94 g / cm 3 ) or mLLDPE (linear metallocene polyethylene low density). HDPE or MDPE are preferred. Conventional additives (such as slip additives, antiblock additives, fillers, etc.) can be added to the substrate layer 4.
  • PE polyethylene
  • Conventional additives such as slip additives, antiblock additives, fillers, etc.
  • the substrate layer 4 can comprise a compatible polyolefin material.
  • any type of polyethylene can be used as a compatible polyolefin material, in particular also ethylene copolymers, such as, for example, ethylene-vinyl acetate copolymer (EVA), methacrylic acid ethyl ester (EMA), ethylene / acrylic acid copolymer (EAA) or ethylene-butyl acrylate copolymer (EBA).
  • EVA ethylene-vinyl acetate copolymer
  • EMA methacrylic acid ethyl ester
  • EAA ethylene / acrylic acid copolymer
  • EBA ethylene-butyl acrylate copolymer
  • polypropylene (PP) or a cycloolefin copolymer (COC) can be used in a dimension of up to 20% by weight.
  • PP polypropylene
  • COC cycloolefin copolymer
  • a polypropylene copolymer with ethylene or a polypropylene homopolymer using linear PE types, such as mLLDPE , LLDPE or HDPE is sufficiently compatible, used to achieve at least a limited recyclability.
  • the proportion of polyethylene (PE) in the substrate layer is preferably at least 60% by weight, preferably at least 70% by weight and very particularly preferably at least 80% by weight, in order to improve the recyclability.
  • the PE and the compatible polyolefin material can be present in the substrate layer 4 as a mixture.
  • the substrate layer 4 can also be constructed in multiple layers (extruded or co-extruded) with one (or also more) PE layer (s) and one (or also more) layer (s) made of the compatible polyolefin material.
  • the thickness of the substrate layer 4 is preferably 5 to 35 pm.
  • a cavitation agent is added to the PE of the substrate layer 4, the cavitation agent being added to the substrate layer 4 in an amount of 5-30% by weight, preferably 15-25% by weight.
  • a cavitating agent is a polymer incompatible with PE (i.e. a polymer that remains isolated in the PE matrix), for example polyamides (PA), polyesters (e.g. PET or PBT), polylactides (PLA).
  • PA polyamides
  • PET or PBT polylactides
  • a mineral cavitation agent such as calcium carbonate or mica can also be used.
  • the cavitation agent is usually available as a fine powder, which is embedded as a masterbatch in a PE matrix before extrusion and mixed with the PE granulate.
  • the substrate layer 4 can also have a multilayer structure.
  • the cavitated PE layer is surrounded on one or both sides by a non-cavitated PE layer.
  • a conceivable structure of the substrate layer 4 of the first laminate layer 3 would be, for example, a cavitated PE layer which is connected on one side to a non-cavitated PE layer (for example, coextruded), the cavitated PE layer in the packaging laminate 1 of the second laminate layer 3 is facing.
  • Another preferred The structure of the substrate layer 4 would be, for example, a cavitated PE layer which is connected on both sides to a non-cavitated PE layer (for example coextruded).
  • Such a structure of the substrate layer 4 can also improve the sealing properties of the packaging laminate 1.
  • the sum of polyethylene, cavitation agent, any additives and possible compatible polyolefin materials in the substrate layer 4 can of course only add up to 100% by weight.
  • the decisive factor here is the proportion of polyethylene to which the other proportions must be directed.
  • the barrier layer 6 consists of a barrier polymer, that is to say a polymer with a sufficient barrier property, in particular against oxygen, water and / or aroma.
  • the barrier polymer is preferably a polyamide (PA) or an ethylene-vinyl alcohol copolymer (EVOH). EVOH is preferred as the barrier polymer.
  • the barrier layer 6 has a maximum thickness of 20%, preferably 5 to 10%, the total thickness of the first laminate layer 2, that is to say a maximum of 2 to 8 pm. The low thickness of the barrier layer 6 does not impair the ease of recycling.
  • connection layer 5 serves to connect the barrier layer 6 and the substrate layer 4. Sufficient bond adhesion is to be achieved here, in particular in order to reliably prevent undesired delamination of the first laminate layer 2.
  • Suitable connecting layers 5 preferably consist of polymers with increased polarity, for example based on maleic anhydride-modified polyolefins (such as PE or PP), ethylene-vinyl acetate copolymer (EVA), ethylene / acrylic acid copolymer (EAA), ethylene-butyl acrylate copolymer (EBA), or similar polyolefin copolymers.
  • the thickness of a connecting layer 5 is at most 10% of the total thickness of the first laminate layer 2, typically 1 to 5 pm.
  • the second laminate layer 3 consists predominantly of a PE, the PE portion of the total amount of polymer in the second laminate layer 3, without any mineral or other fillers added, being at least 80% by weight.
  • PE i.e. LDPE, LLDPE, MDPE, HDPE
  • the thickness of the second laminate layer 3 is typically between 20 to 200 ⁇ m and preferably forms a sealing layer in the packaging laminate 1.
  • a particularly advantageous embodiment of the invention consists in the use of a PE layer, preferably 20 to 40 ⁇ m thin, coextruded, and stretched, and likewise at least in one layer cavitated as a second laminate layer 3.
  • a conceivable structure of the second laminate layer 3 would be, for example a cavitated PE layer attached to is connected on one side to a non-cavitated PE layer (eg coextruded), the cavitated PE layer facing the first laminate layer 2 in the packaging laminate.
  • Another preferred structure of the second laminate layer would be, for example, a cavitated PE layer, which is connected on both sides to a non-cavitated PE layer (eg coextruded).
  • the remaining remainder will of course consist of PE or a compatible polyolefin material, as described above, for the desired ease of recycling.
  • a particularly recycling-friendly laminate can be produced, which can be easily and inexpensively recycled using common methods in mechanical recycling, and which has a very low density.
  • the first laminate layer 2 is produced by co-extrusion because this enables particularly simple, inexpensive production.
  • the known blown film or flat film extrusion process is preferably used.
  • the first laminate layer 2 is unidirectionally or bidirectionally, ie in the machine direction (generally the longitudinal or extrusion direction) and / or in the transverse direction (rotated 90 ° to the machine direction) after the co-extrusion.
  • the degree of stretching in the machine direction and in the transverse direction need not be the same.
  • the degree of stretching in the machine direction is preferably at least 4: 1 to 8: 1.
  • the degree of stretching in the transverse direction is preferably at least 5: 1 to 10: 1.
  • the stretching can take place in-line (ie immediately after the co-extrusion) or off-line (ie at a later time after the co-extrusion).
  • the stretching typically takes place at approx. 10 ° C to 30 ° C, typically approx. 20 ° C, below the lowest melting temperature (approx. 128 ° C to 130 ° C for HDPE) in the first laminate layer 2.
  • the extrusion gap for the blown film 1.5 to 2.5 mm or the gap of the extrusion die is significantly larger than the final thickness of the extruded film (typically between 10 to 200 pm) .
  • the extruded melt is stretched at temperatures well above the melting point of the extruded polymer, which gives it the final thickness.
  • the melt is typically stretched, for example, typically in the transverse direction by a factor of 2 to 3 (the so-called inflation ratio) and in the longitudinal direction by a factor of 1:10 to 1: 100 (the so-called withdrawal ratio).
  • This stretching during extrusion cannot, however, be compared to the stretching of a plastic film, since the stretching usually takes place at temperatures just below the melting point of the polymer in order to avoid the disordered poly and align the semi-crystalline areas by stretching them in the stretching direction.
  • the unidirectional or bidirectional stretching produces microcavities in a known manner due to the cavitating agent in the PE of the substrate layer 4 of the first laminate layer 2. Since it was found that the density of the substrate layer 4 could be significantly reduced by the microcavities, to values between 0.4-0.85 g / cm 3 . The first laminate layer 2 is thus lighter. The same naturally also applies analogously to the second laminate layer 3 if it contains a cavitated polyethylene.
  • An asymmetrical structure of the stretched first laminate layer 2 made primarily of polyethylene (in particular PE, EVOH) is atypical and has previously been avoided in practice, in particular in the case of blow molding, since it was assumed that such a structure, in particular due to water absorption of the polar barrier layer 6, which is on the outside in the first laminate layer 2, curls, which would make further processing difficult or impossible.
  • the curling in the concrete design of the structure happens to an acceptable extent, which is not a hindrance to further processing.
  • the advantage of the atypical asymmetrical structure of the first laminate layer 2 lies primarily in the fact that only a single expensive and less rigid connection layer 5 is required. The costs for the first laminate layer 2 can thus be reduced and a more rigid first laminate layer 2 can be achieved. The higher rigidity is particularly advantageous when using the packaging laminate 1 to produce a bag.
  • barrier layer 6 Due to the stretching of the barrier layer 6, approximately three to four times higher barrier values are achieved compared to the unstretched, similar barrier polymer, as a result of which less expensive barrier polymer can be used with the same barrier effect. As a result, the costs of the first laminate layer 2 can be significantly reduced. Apart from this, less barrier polymer is required for the same barrier effect, which additionally improves the recyclability.
  • the first laminate layer 2 is preferably produced using the multi-stage blown film extrusion process (for example triple or double bubble process), because this results in less edge section due to production, which leads to lower costs for the packaging laminate 1, particularly in the case of the more expensive barrier polymers.
  • Blown film extrusion can also process more viscous HDPE materials with an MFI (Mass Flow Index) of less than 3 be applied.
  • Such HDPE materials have a higher molecular weight and better mechanical properties, which is favorable for use in a packaging laminate 1.
  • such a material would tear particularly easily in the longitudinal direction and even undesirable splicing occurs in the longitudinal direction. This undesirable property can be eliminated by incorporating the HDPE material with an MFI of less than 3 in a first laminate layer 2 as described, and even uniform tearing in both directions can be achieved.
  • the stretched first laminate layer 2 and the second laminate layer 3 are connected to one another, preferably by extrusion lamination, extrusion coating or adhesive lamination, the second laminate layer 3 being connected to the barrier layer 6 of the first laminate layer 2.
  • the second laminate layer 3 is extruded onto the barrier layer 6 of the first laminate layer 2, an adhesion promoter preferably also being provided in between.
  • the second laminate layer 3 is bonded to the barrier layer 6 by means of a suitable laminating adhesive, for example based on polyurethane adhesives or also polyolefin copolymers in extrusion lamination.
  • the thickness of the laminating adhesive is preferably 2 to 5 g / m 2 in the case of conventional adhesives based on polyurethane, or 5 to 20 g / m 2 in the case of extrusion lamination.
  • the barrier layer 6 can also be surface-treated, for example by a corona or flame treatment, in order to improve the adhesive properties.
  • the second laminate layer 3 preferably forms a sealing layer 7, which in a packaging made of the packaging laminate 1 is usually turned towards the packaged product.
  • the packaging is produced by cutting, folding and thermosealing the packaging laminate 1, sealing layer against sealing layer or sealing layer against another packaging part. Possible packaging is bags, pouches, sacks, etc.
  • the second laminate layer 3 can also be designed in multiple layers, for example extruded or co-extruded, as indicated in FIG. 2 and described in detail below. However, the second laminate layer 3 can also be equipped with a barrier function and can also be stretched, as indicated in FIG. 4 and described in detail below.
  • the first laminate layer 2 is connected on the side of the barrier layer 6 to the second laminate layer 3 and on the side of the substrate layer 4 to a further laminate layer 10, here a third laminate layer 8
  • the third laminate layer 8 is preferably a single-layer or multilayer polymer film, for example a film made predominantly of PE (at least 80% by weight PE), as described with reference to the second laminate layer 3.
  • the third laminate Layer 8 can again either be extrusion-coated or adhesive-laminated onto the first laminate layer 2, as explained with reference to the sealing layer 7 in FIG. 1.
  • Such a packaging laminate 1 according to FIG. 2 can be used for example for the production of tubes.
  • the thickness of the second laminate layer 3 and the third laminate layer 8 is typically in the range of 150 pm.
  • the second laminate layer 3 can be constructed in multiple layers, here for example with two layers 7a, 7b, which form the sealing layer 7, for example also with a layer of cavitated polyethylene as described above.
  • Such a structure of the second laminate layer 3 can of course also be provided in an embodiment according to FIG.
  • the barrier layer 6 can also be subjected to a pretreatment, for example a corona or flame treatment.
  • the substrate layer 4 can also be printed or coated on the side lying outside in the packaging laminate 1, if appropriate again after a surface treatment. Common printing processes can be used here, for example a gravure printing process or a flexographic printing process.
  • the third laminate layer 8 could, in addition or as an alternative to the first laminate layer 2, be printed, metallized or coated on one or both sides.
  • the barrier layer 6 of the first laminate layer 2 is metallized, preferably with aluminum, in order to increase the barrier effect.
  • the third laminate layer 8 could be printed on the outside, or in reverse printing also on the opposite side.
  • FIG. 3 shows another embodiment of a packaging laminate 1 according to the invention, which can preferably be used for the production of tubes.
  • the first laminate layer 2 is connected to the barrier layer 6 as in the example in FIG. 1 with the second laminate layer 3.
  • the first laminate layer 2 is connected at its substrate layer 4 to a further laminate layer 10, here an oriented fourth laminate layer 2 ', which has the same structure as the first laminate layer 2.
  • the fourth laminate layer 2' thus again comprises a substrate layer 4 ', which is connected with a connecting layer 5 'to a barrier layer 6'.
  • the barrier layer 6 'of the fourth laminate layer 2' is connected to the substrate layer 4 of the first laminate layer 2, preferably with a suitable laminating adhesive as described above.
  • fourth laminate layer 2 ' are constructed and put together as already described above.
  • the substrate layer 4 ′ of the fourth laminate layer 2 ′ does not necessarily have to be provided with a cavitating agent.
  • the fourth laminate layer 2 ' consists primarily of PE materials with at least 80% by weight of PE. However, the thicknesses and the exact compositions or materials of the individual layers of the first laminate layer 2 and the fourth laminate layer 2 'do not have to match.
  • the fourth laminate layer 2 ′′ on the substrate layer 4 ′′ and / or on the barrier layer 6 ′′, in addition or as an alternative to the first laminate layer 2, can be printed, metallized or coated.
  • the fourth laminate layer 2 ′ is printed, preferably on its barrier layer 6 ′′, and the first laminate layer 2 is metallized, preferably on its barrier layer 6 or substrate 4.
  • the barrier effect of the packaging laminate 1 can thus be increased.
  • a coating of aluminum oxide or silicon oxide can also be provided on the barrier layer 6 or substrate layer 4 of the first laminate layer 2 to further increase the barrier effect.
  • the second laminate layer 3 again has a multi-layer design and comprises a substrate layer 4 “, barrier layer 6“ and a connecting layer 5 “, similar to the first laminate layer 2.
  • the substrate layer 4 ′′ does not necessarily have to be provided with a cavitation agent.
  • the second laminate layer 3 additionally comprises a sealing layer 7.
  • the sealing layer 7 preferably consists of a PE material, such as, for example, mLLDPE, LLDPE, or of another suitable thermoplastic, for example polypropylene (PP).
  • this second laminate layer 3 with the sealing layer 7 that it consists of at least 80% by weight PE.
  • the sealing layer 7 of the second laminate layer 3 is co-extruded with the other layers of the second laminate layer 3.
  • the second laminate layer 3 of FIG. 4 is stretched, as is the first laminate layer 2 and as described above.
  • the sealing layer 7 is thus integrated in a multilayer, stretched barrier film which is constructed similarly to the first laminate layer 2.
  • the stretched first laminate layer 2 and the stretched second laminate layer 3 are bonded to one another at the abutting barrier layers 6, 6 ′′, preferably by adhesive lamination using an adhesive layer 9.
  • a suitable adhesive is, for example, an adhesive based on polyurethane or a polyolefin copolymer.
  • the thickness of the lamination layer 9 is preferably 2 to 5 g / m 2 .
  • one (or more) of the layers of the packaging laminate 1 can be printed, metallized or coated.
  • a further laminate layer 10 (for example a third laminate layer 8 or fourth laminate layer 2 'as described above) could also be provided on the first laminate layer 2, as indicated in FIG. 4.
  • the packaging laminate 1 thus has at least one asymmetrical, stretched, first laminate layer 2 made of at least 60% by weight PE with a substrate layer 4 with cavitating agent, a barrier layer 6 and a connecting layer 5 and a second laminate layer 3 connected to it with a PE content of at least 80% %, on.
  • a further single or multi-layer laminate layer 10 for example a third laminate layer 8 or fourth laminate layer 2 '
  • This further one or more layered laminate layer 10 is thus connected to the substrate layer 4 of the first laminate layer 2.
  • the sealing layer 7 of the packaging laminate 1 advantageously faces the inside of the packaging.
  • the barrier effect of the packaging laminate 1 can also be further increased in this way.
  • a barrier lacquer for example polyvinyl alcohol (PVOH)
  • PVOH polyvinyl alcohol
  • Such lacquer layers can be applied very thinly, typically in the range from 0.5 to 2.0 g / m 2 , and thus do not impair the recyclability of the packaging laminate 1.
  • each of the above-described layers in the first laminate layer 2, second laminate layer 3 or the further laminate layer 10 itself can also be constructed in multiple layers.
  • the second laminate layer 3 of the packaging laminate 1 does not necessarily have to form the sealing layer of the packaging laminate 1.
  • the substrate layer 4 of the first laminate layer 2 or a further laminate layer 10 could form the sealing layer and the second laminate layer 3 the outside of the packaging laminate 1.
  • a possible advantageous construction of a packaging laminate 1 comprises a first stretched laminate layer 2 and a second stretched laminate layer 3.
  • the first laminate layer 2 consists of an at least three-layer substrate layer 4, the at least one central, cavitated PE layer (preferably HDPE or MDPE or a mixture thereof), on each side of at least one non-cavitated PE layer (preferably HDPE or MDPE or a mixture from it) is surrounded.
  • This substrate layer 4 is connected to the connection layer 5 with the barrier layer 6.
  • the barrier layer 6 can also be metallized (eg aluminum) or coated (eg aluminum oxide or silicon oxide).
  • the second laminate layer 3 is composed of at least three layers, with a central cavitated PE layer (preferably HDPE or MDPE or a mixture thereof), which on each side of at least one non-cavitated PE layer (preferably HDPE or MDPE or a mixture thereof) is surrounded.
  • the first laminate layer 2 and the second laminate layer 3 are connected to one another by laminating with a laminating agent. If the substrate layer 4 of the first laminate layer 2 is used as a sealing layer, then the outside of the second laminate layer 3 can be printed. If the sealing layer is formed by the second laminate layer 3, then the substrate layer 4 can be printed.

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PCT/EP2018/081477 2018-11-15 2018-11-15 Recyclingfreundliches verpackungslaminat mit guter barrierewirkung sowie niedriger dichte und verfahren zu dessen herstellung WO2020098947A1 (de)

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PCT/EP2018/081477 WO2020098947A1 (de) 2018-11-15 2018-11-15 Recyclingfreundliches verpackungslaminat mit guter barrierewirkung sowie niedriger dichte und verfahren zu dessen herstellung
US17/287,653 US20210354894A1 (en) 2018-11-15 2018-11-15 Recyclable Packaging Laminate Having A Good Barrier Effect And Low Density, And Method For The Production Thereof
JP2021526500A JP2022507509A (ja) 2018-11-15 2018-11-15 優れたバリア性と低密度を有するリサイクル可能な包装用積層体およびその製造方法
EP18807033.8A EP3880473B1 (de) 2018-11-15 2018-11-15 Recyclingfreundliches verpackungslaminat mit guter barrierewirkung sowie niedriger dichte und verfahren zu dessen herstellung
MX2021005773A MX2021005773A (es) 2018-11-15 2018-11-15 Laminado de empaque reciclable que tiene un buen efecto de barrera y baja densidad, y metodo para la produccion del mismo.
ES18807033T ES2913632T3 (es) 2018-11-15 2018-11-15 Laminado de embalaje fácil de reciclar con buen efecto de barrera, así como baja densidad y procedimiento para su fabricación
CA3119686A CA3119686A1 (en) 2018-11-15 2018-11-15 Recyclable packaging laminate having a good barrier effect and low density, and method for the production thereof
PL18807033T PL3880473T3 (pl) 2018-11-15 2018-11-15 Nadający się do recyklingu laminat opakowaniowy o dobrym działaniu barierowym oraz małej gęstości oraz sposób jego wytwarzania

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DE102022116670A1 (de) 2022-02-22 2023-08-24 Rkw Se Kaltsiegelnde Verpackung
WO2023161142A1 (de) 2022-02-22 2023-08-31 Rkw Se Maschinenlaufrichtungorientierte folienverpackung mit hohlräumen
WO2024061813A1 (en) 2022-09-20 2024-03-28 Unilever Ip Holdings B.V. Recyclable multilayered packaging laminate with barrier coating
WO2024079175A1 (en) 2022-10-12 2024-04-18 Unilever Ip Holdings B.V. Recyclable multilayered packaging laminate with barrier coating

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US20210354894A1 (en) 2021-11-18
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ES2913632T3 (es) 2022-06-03
MX2021005773A (es) 2021-07-02
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