WO2020091287A1 - 윤기 지속형 화장료 조성물 - Google Patents
윤기 지속형 화장료 조성물 Download PDFInfo
- Publication number
- WO2020091287A1 WO2020091287A1 PCT/KR2019/013904 KR2019013904W WO2020091287A1 WO 2020091287 A1 WO2020091287 A1 WO 2020091287A1 KR 2019013904 W KR2019013904 W KR 2019013904W WO 2020091287 A1 WO2020091287 A1 WO 2020091287A1
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- WIPO (PCT)
- Prior art keywords
- oil
- water
- cosmetic composition
- refractive
- polyol
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
Definitions
- the present invention relates to a cosmetic composition capable of improving the durability of skin gloss.
- emulsions used in cosmetics, medicines, and foods are largely classified into two types.
- One is an oil-in-water emulsion in which oil is dispersed in water
- the other is an oil-in-water emulsion in which water is dispersed in oil.
- Water-in-oil formulations can deliver moisture and skin-active substances to the skin for a long time continuously by suppressing evaporation of moisture from the skin compared to oil-in-water formulations, and their application ranges such as sunscreen products, skin cover products, and hand creams are very wide.
- the water-in-oil cosmetic composition has many advantages in terms of water resistance, longevity, and skin protection effect because the external wound is oil, but has a heavy feeling of use and a thick cosmetic layer, resulting in poor skin permeability.
- an oily polymer in a composition mainly composed of such a high refractive oil may prevent makeup from collapsing, but there is a limit to the application of an oily polymer for reasons such as cosmetic film thickness, feeling of use, or cosmetic effect.
- the problem to be solved by the present invention is to provide a cosmetic composition that includes a high-refractive oil and improves the frustrating feeling of use while improving the durability of skin gloss.
- the water-in-oil cosmetic composition comprising a high-refractive oil and a high-refractive polyol on the inner surface, the polyol of the inner layer forms a moisturizing film even after the cremation film collapses over time It was found that the persistence was significantly increased.
- the present inventors have completed the present invention by surprisingly discovering that when the water-in-oil formulation further includes an oily polymer, not only high initial glossiness is realized, but gloss persistence is significantly increased even after a long time. .
- the present invention includes a high-refractive oil and a high-refractive polyol, and the high-refractive polyol provides a water-in-oil cosmetic composition included in an inner box.
- the composition may further include an oily polymer.
- the high refractive oil is an oil having a refractive index (Refractive index, RI) of 1.39 or more, preferably 1.39 to 1.6, more preferably 1.4 to 1.58, most preferably 1.41 to 1, as measured according to standard test method ASTM D1218. It may be 1.56.
- RI refractive index
- the high refractive oil has a relatively high refractive index value and can be used without limitation as long as it is commonly used in cosmetics.
- an oil having a refractive index higher than the refractive index (1.39) of silicone oil mainly used in water-in-oil cosmetics may be included to increase initial gloss and gloss persistence of the cosmetic composition.
- the high refractive oil is phenyl trimethicone (1.46), diphenylsiloxyphenyl trimethicone (1.50), triethylhexanoin (1.44), dipentaerythryl hexa C5-9 acid ester (1.52) ), Diisostearyl malate (1.46), and polyglyceryl-2 triisostearate (1.466), but may include any one or more selected from the group consisting of, but is not limited thereto.
- the high refractive oil may preferably include a silicone oil, for example, phenyltrimethicone, diphenylsiloxyphenyltrimethicone, or a combination thereof, in which case the initial gloss of the cosmetic composition and The gloss persistence is remarkably excellent.
- a silicone oil for example, phenyltrimethicone, diphenylsiloxyphenyltrimethicone, or a combination thereof, in which case the initial gloss of the cosmetic composition and The gloss persistence is remarkably excellent.
- the high-refractive oil may be included in an amount of 20% by weight or less based on the total weight of the composition, for example, 1-20% by weight, preferably 1.5-18% by weight, and more preferably 2-15% by weight. If the high-refractive oil is less than 1% by weight based on the total weight of the composition, initial gloss or gloss persistence may be deteriorated, and if it is more than 20% by weight, a frustrating feeling of use or cremation of the cosmetic film may occur. In terms of improving the stuffiness of use due to the high refractive oil, the high refractive oil is 1-12% by weight, preferably 2-10% by weight, more preferably 3-8% by weight, more preferably 5 ⁇ It may be blended at 8% by weight.
- the oily polymer is an oily component that can increase the initial glossiness and gloss persistence of the cosmetic composition, and a function that can function as a coating and can make the cosmetic film smooth can be used.
- the oily polymer is a silicone resin such as trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone cross polymer, dimethicone / vinyltrimethylsiloxysilicate cross polymer, polyphenylsil Sesquioxane, polypropylsilsesquioxane, and dimethicone / silsesquioxane copolymers;
- acrylate-based polymers such as acrylate / stearyl acrylate / dimethicone methacrylate copolymer, acrylate copolymer, acrylate / methacrylate copolymer, acrylate / acrylamide copolymer, acrylate / Dim
- the oily polymer may preferably include trimethylsiloxysilicate, acrylate / stearylacrylate / dimethiconemethacrylate copolymer, or mixtures thereof, in which case initial gloss of the cosmetic composition The durability and luster persistence are remarkably excellent.
- the oily polymer may be included in 1 to 15% by weight, preferably 2 to 12% by weight, more preferably 3 to 10% by weight based on the total weight of the composition.
- the oily polymer is less than 1% by weight based on the total weight of the composition, the effect of forming the cosmetic film may be insufficient and the gloss effect may be reduced, and when it is more than 15% by weight, stability of the formulation may be impaired.
- the high-refractive polyol contained in the inside of the water-in-oil cosmetic composition can form a moisturizing film when the cosmetic film is broken on the skin, thereby increasing the gloss lasting effect.
- the high refractive polyol has a refractive index (Refractive index, RI) of 1.39 or more, preferably 1.39 to 1.6, more preferably 1.4 to 1.58, and most preferably 1.41 to 1.56 when measured according to standard test method ASTM D1218. It can be a polyol.
- the high refractive polyol is glycerin (1.47), butylene glycol (1.44), dipropylene glycol (1.44), polyethylene glycol (1.46-1.47), 1,3-propanediol (1.44), 1,2- Hexanediol (1.44), and may include any one or more selected from the group consisting of pentylene glycol (1.43), but is not limited thereto.
- the high-refractive polyol may preferably include any one or more selected from the group consisting of glycerin, butylene glycol, and dipropylene glycol, in which case the gloss persisting effect due to the formation of a moisturizing film when the cosmetic film is collapsed It is remarkably excellent.
- the high-refractive polyol may be included in 10 to 20% by weight, preferably 10 to 18% by weight, more preferably 10 to 16% by weight based on the total weight of the composition.
- the cosmetic composition includes a high-refractive polyol in the above-mentioned weight range, so even if a small amount of high-refractive oil is included, the gloss persistence is remarkably excellent, so that the problem of frustrating use due to the use of a large amount of high-refractive oil can be solved.
- gloss persistence may be reduced, and when it is more than 20% by weight, stability of the water-in-oil formulation may be impaired.
- the cosmetic composition of the present invention can reduce the blending amount of the high-refractive oil and increase the content of the high-refractive polyol to give a similar level of gloss persistence and improve the frustrating feeling of use due to the high-refractive-oil blending.
- the water-in-oil cosmetic composition is an ester oil as an oil component of trauma, for example, isodecyl neopentanoate, isostearyl isostearate, ethylhexyl benzoate, phenethyl benzoate, PPG-3 Benzyl ether myristate, caprylic / capric triglyceride, isopropyl palmitate, isopropyl isostearate, isopropyl myristate, and isostearyl isostearate, and the like; Hydrocarbon oils such as hydrogenated polydecene, mineral oil, liquid paraffin, squalene, isododecane, and isohexadecane; Silicone oils such as cyclopentasiloxane, cyclohexasiloxane, trimethylpentaphenyltrisiloxane, and diphenyldimethicone; Natural plant oils, such as olive oil,
- the cosmetic composition according to the present invention may further include various components that are commonly used in the art as a water phase component.
- a water phase component For example, water, a moisturizing agent, a metal ion blocker, an antioxidant, a water-soluble agent, a neutralizing agent, a water-soluble sunscreen, a pigment, a preservative, or a fragrance may be included, but is not limited thereto.
- the cosmetic composition according to the present invention in addition to the components described above, within a range that does not impair the effects of the present invention, can be prepared according to a conventional method by mixing an appropriate amount of the ingredients commonly blended in the water-in-oil cosmetic composition.
- the cosmetic composition according to the present invention is a foundation, solution, external ointment, cream, foam, nutrient longevity, softening longevity, pack, makeup base, essence, sunscreen cream, sun oil, suspension, emulsion, paste, gel, lotion , Oil, or spray, and the like, but is not limited thereto.
- the water-in-oil-type cosmetic composition according to the present invention may be prepared according to various methods known in the art, for example, it may be prepared by the following method, but is not limited thereto.
- the method for preparing a water-in-oil cosmetic composition according to the present invention comprises the steps of: (S1) stirring and dispersing an oil phase component comprising a high refractive oil and a water phase component containing a high refractive polyol, respectively; (S2) mixing and stirring the colorant to the oil component; And (S3) adding and emulsifying the aqueous phase component to the oil phase component.
- the oil phase component of the step (S1) may further include an oil phase polymer.
- the (S1)-(S3) steps may be performed at 80 ° C., and the (S3) step may be emulsified using a homomixer.
- the water-in-oil cosmetic composition of the present invention can apply a polyol having a high index of refraction to the inner box, thereby realizing gloss persistence through the polyol of the inner box when the cosmetic film collapses after a lapse of time.
- the water-in-oil cosmetic composition of the present invention can improve consumer satisfaction by improving limitations such as stuffiness and deterioration of gloss due to makeup collapse, which are disadvantages of conventional glossy makeup cosmetics.
- Example 5 is a graph showing the results of measuring the glossiness of Comparative Example 2 and Example 4, and Example 5 in Experimental Example 4 with a Glossmeter.
- a water-in-oil cosmetic was prepared by the following manufacturing method.
- Example 3 to which the oily polymer was applied has a higher initial gloss than Example 2 without the oily polymer.
- Example 3 was significantly superior to Example 2 over time as the reduction rate.
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Abstract
Description
구분 | 배합성분(중량%) | 비교예1 | 비교예2 | 비교예3 | 비교예4 | 비교예5 | 실시예1 | 실시예2 | 실시예3 | 실시예4 | 실시예5 |
유상성분 | 사이클로펜타실록산 | 15.6 | 5.85 | 2.60 | 15.6 | 15.6 | 15.6 | 5.85 | 2.60 | 5.85 | 9.10 |
사이클로헥사실록산 | 8.4 | 3.15 | 1.40 | 8.4 | 8.4 | 8.4 | 3.15 | 1.40 | 3.15 | 4.90 | |
페닐트리메치콘 | - | 8.00 | 13.00 | - | - | - | 8.00 | 8.00 | 5.00 | 2.00 | |
디페닐실록시페닐트리메치콘 | - | 7.00 | 7.00 | - | - | - | 7.00 | 7.00 | 3.00 | 3.00 | |
트리메칠실록시실리케이트 | - | - | - | - | - | - | - | 5.00 | 5.00 | 5.00 | |
피이지-10디메치콘 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | 3.00 | |
디스테아디모늄헥토라이트 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | 1.00 | |
향료 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | |
수상성분 | 정제수 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 | 잔량 |
글리세린 | - | - | - | 3.00 | 8.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | |
방부제 | 적량 | 적량 | 적량 | 적량 | 적량 | 적량 | 적량 | 적량 | 적량 | 적량 | |
소듐클로라이드 | 0.50 | 0.50 | 0.5 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | 0.50 | |
착색제 | 티타늄디옥사이드 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 | 10.00 |
황색산화철,적색산화철,흑색산화철 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 | 2.00 |
광택 감소율(%) | 실시예 2 | 실시예 3 |
4시간 | 4.96 | 4.43 |
8시간 | 10.12 | 1.85 |
광택 감소율(%) | 비교예1 | 비교예4 | 비교예5 | 실시예1 |
감소율(4hr) | 48.64 | 58.66 | 57.68 | 42.38 |
감소율(8hr) | 68.32 | 77.68 | 69.43 | 55.83 |
비교예 2 | 실시예 2 | |
감소율(4hr) | 10.45 | 4.96 |
감소율(8hr) | 13.61 | 10.12 |
비교예 3 | 실시예 2 | |
감소율(4hr) | 6.27 | 4.96 |
감소율(8hr) | 16.02 | 10.12 |
비교예 3 | 실시예 2 | |
지속력 | 3.0 | 3.8 |
답답함 | 2.5 | 4.0 |
비교예 2 | 실시예 4 | 실시예 5 | |
감소율(4hr) | 10.45 | 4.57 | 9.54 |
감소율(8hr) | 13.61 | 11.43 | 14.43 |
비교예 2 | 실시예 4 | 실시예 5 | |
지속력 | 3.5 | 3.9 | 3.5 |
답답함 | 3.7 | 4.5 | 4.8 |
Claims (12)
- 고굴절 오일 및 고굴절 폴리올을 포함하며,상기 고굴절 폴리올은 내상에 포함하는 유중수형 화장료 조성물.
- 제1항에 있어서, 상기 고굴절 오일은 굴절률(R.I)이 1.39 이상인 유중수형 화장료 조성물.
- 제1항에 있어서, 상기 고굴절 오일은 페닐트리메치콘, 디페닐실록시페닐트리메치콘, 트리에칠헥사노인, 디펜타에리스리틸헥사C5-9애씨드에스터, 디이소스테아릴말레이트, 및 폴리글리세릴-2트리이소스테아레이트로 이루어진 군에서 선택된 어느 하나 이상을 포함하는 유중수형 화장료 조성물.
- 제1항에 있어서, 상기 고굴절 오일은 조성물 총 중량 대비 1~20 중량%인 유중수형 화장료 조성물.
- 제1항에 있어서, 상기 조성물은 추가로 유상 폴리머를 포함하는 유중수형 화장료 조성물.
- 제5항에 있어서, 상기 유상 폴리머는 실리콘 레진, 아크릴레이트계 폴리머, 또는 이들의 혼합물인 유중수형 화장료 조성물.
- 제5항에 있어서, 상기 유상 폴리머는 조성물 총 중량 대비 1~15 중량%인 유중수형 화장료 조성물.
- 제1항에 있어서, 상기 고굴절 폴리올은 굴절률(R.I)이 1.39 이상인 유중수형 화장료 조성물.
- 제1항에 있어서, 상기 고굴절 폴리올은 글리세린, 부틸렌글리콜, 디프로필렌글리콜, 폴리에틸렌글리콜, 1,3-프로판디올, 1,2-헥산디올, 및 펜틸렌글리콜로 이루어진 군에서 선택된 어느 하나 이상을 포함하는 유중수형 화장료 조성물.
- 제1항에 있어서, 상기 고굴절 폴리올은 조성물 총 중량 대비 10~20 중량%인 유중수형 화장료 조성물.
- 조성물 총 중량 대비 고굴절 오일 1~20 중량% 및 유상 폴리머 1~15 중량%를 포함하며, 내상에 고굴절 폴리올 10~20 중량%를 포함하는 유중수형 화장료 조성물.
- (S1) 고굴절 오일을 포함하는 유상 성분, 및 고굴절 폴리올을 포함하는 수상 성분을 각각 교반하여 분산시키는 단계;(S2) 상기 유상 성분에 착색제를 혼합하고 교반시키는 단계; 및(S3) 상기 유상 성분에 상기 수상 성분을 첨가하고 유화시키는 단계를 포함하는 유중수형 화장료 조성물의 제조 방법.
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Application Number | Priority Date | Filing Date | Title |
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CN201980070505.6A CN112912061A (zh) | 2018-11-01 | 2019-10-22 | 润泽持久型化妆料组合物 |
US17/290,499 US20220000728A1 (en) | 2018-11-01 | 2019-10-22 | Cosmetic Composition For Sustaining Luster |
JP2021523949A JP7266933B2 (ja) | 2018-11-01 | 2019-10-22 | 艶持続型化粧料組成物 |
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KR20180133182 | 2018-11-01 | ||
KR10-2018-0133182 | 2018-11-01 | ||
KR1020190075951A KR102253136B1 (ko) | 2018-11-01 | 2019-06-25 | 윤기 지속형 화장료 조성물 |
KR10-2019-0075951 | 2019-06-25 |
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WO2020091287A1 true WO2020091287A1 (ko) | 2020-05-07 |
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Citations (5)
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US6379682B1 (en) * | 2000-02-07 | 2002-04-30 | Color Access, Inc. | Clear water-in-oil emulsions |
KR20150017731A (ko) * | 2012-05-14 | 2015-02-17 | 존슨 앤드 존슨 컨수머 캄파니즈, 인코포레이티드 | 광채 조성물 및 사용 방법 |
KR20150040864A (ko) * | 2012-06-21 | 2015-04-15 | 로레알 | 수분―방출 화장 조성물 |
KR20160137907A (ko) * | 2014-03-31 | 2016-12-01 | 로레알 | 광학 효과를 갖는 조성물 |
US20180028416A1 (en) * | 2016-07-29 | 2018-02-01 | L'oreal | Cosmetic compositions with sensorial and aesthetic benefits and having enhanced stability |
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2019
- 2019-10-22 WO PCT/KR2019/013904 patent/WO2020091287A1/ko active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6379682B1 (en) * | 2000-02-07 | 2002-04-30 | Color Access, Inc. | Clear water-in-oil emulsions |
KR20150017731A (ko) * | 2012-05-14 | 2015-02-17 | 존슨 앤드 존슨 컨수머 캄파니즈, 인코포레이티드 | 광채 조성물 및 사용 방법 |
KR20150040864A (ko) * | 2012-06-21 | 2015-04-15 | 로레알 | 수분―방출 화장 조성물 |
KR20160137907A (ko) * | 2014-03-31 | 2016-12-01 | 로레알 | 광학 효과를 갖는 조성물 |
US20180028416A1 (en) * | 2016-07-29 | 2018-02-01 | L'oreal | Cosmetic compositions with sensorial and aesthetic benefits and having enhanced stability |
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