WO2020085861A1 - Acier austénitique cryogénique à haute teneur en manganèse ayant une excellente forme, et procédé de fabrication associé - Google Patents

Acier austénitique cryogénique à haute teneur en manganèse ayant une excellente forme, et procédé de fabrication associé Download PDF

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Publication number
WO2020085861A1
WO2020085861A1 PCT/KR2019/014193 KR2019014193W WO2020085861A1 WO 2020085861 A1 WO2020085861 A1 WO 2020085861A1 KR 2019014193 W KR2019014193 W KR 2019014193W WO 2020085861 A1 WO2020085861 A1 WO 2020085861A1
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WO
WIPO (PCT)
Prior art keywords
less
austenite
present
rolling
tnr
Prior art date
Application number
PCT/KR2019/014193
Other languages
English (en)
Korean (ko)
Inventor
이운해
김보성
석정훈
이동호
김성규
강상덕
Original Assignee
주식회사 포스코
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020190118925A external-priority patent/KR102255826B1/ko
Application filed by 주식회사 포스코 filed Critical 주식회사 포스코
Priority to EP19876795.6A priority Critical patent/EP3872216A4/fr
Priority to CN201980069717.2A priority patent/CN112930415A/zh
Publication of WO2020085861A1 publication Critical patent/WO2020085861A1/fr

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20Ferrous alloys, e.g. steel alloys containing chromium with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese

Definitions

  • high-manganese steel has a high deformation resistance at high temperatures, and in particular, in the case of thin materials, it is difficult to secure a uniform shape in the longitudinal direction according to a rolling pass, a rolling reduction, and the like.
  • shape of the hot rolled material is inferior, cooling safety is lowered, and there is a possibility of causing equipment damage in a process such as transfer.
  • longitudinal shape of the hot rolled material is inferior, it is not preferable in terms of economical efficiency and productivity since subsequent work such as shape correction work must be performed.
  • Figure 1 (a) is a view for helping to understand the bone and floor formed in the steel material in the present invention
  • Figure 1 (b) is a picture of a steel material according to an example of the present invention.
  • the austenite-based high-manganese steel for excellent cryogenic shape has a difference in height between the floor and the valley formed in the steel in the region within 2 m for the rolling direction even if a separate calibration operation is not performed after the steel is manufactured. Since it is within a maximum of 10 mm, excellent shape uniformity can be secured.
  • Figure 1 (a) is a view for helping to understand the bone and floor formed in the steel material in the present invention
  • Figure 1 (b) is a picture of a steel material according to an example of the present invention.
  • composition of the slab provided in the manufacturing method of the present invention corresponds to the steel composition of the austenitic high-manganese steel described above
  • description of the steel composition of the slab is described for the steel composition of the austenitic high-manganese steel described above. Instead.
  • the slab provided with the above-described steel composition may be primary heated in a temperature range of 1050 to 1300 ° C.
  • the primary heating temperature is less than a predetermined range, a problem that excessive rolling load may occur during primary hot rolling or a problem that an alloy component is not sufficiently dissolved may occur, and the present invention provides a lower limit of the primary heating temperature range. It can be limited to 1050 °C.
  • the primary heating temperature exceeds a certain range, there is a fear that the grains are excessively grown and the strength is lowered or the hot rollability of the steel material is deteriorated by heating the steel above the solidus temperature of the steel material.
  • the upper limit of the silver slab primary heating temperature range may be limited to 1300 ° C.
  • the secondary hot rolling process includes a rough rolling process and a finish rolling process, and the secondary reheated intermediate material may be provided as an intermediate material by secondary hot rolling.
  • the finish rolling is preferably performed in a temperature range of (Tnr-120) to Tnr ° C.
  • Tnr can be derived by Equation 1 below.
  • the present invention can limit the finish rolling temperature of the secondary hot rolling to the range of (Tnr-120) to Tnr ° C.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

Un aspect de la présente invention concerne un acier austénitique cryogénique à haute teneur en manganèse ayant une excellente forme, qui comprend 0,2 à 0,5 % en poids de C, 23 à 28 % en poids de Mn, 0,05 à 0,5 % en poids de Si, 1 % en poids ou moins (mais pas 0 % en poids) en poids de Cu, 0,03 % en poids ou moins de P, 0,005 % en poids ou moins de S, 0,5 % en poids ou moins d'Al, 2,5 à 4,5 % en poids de Cr, et 0,0005 à 0,01 % en poids de B, le reste étant constitué de Fe et d'autres impuretés inévitables, et comprend également au moins 95 % en poids d'austénite en tant que microstructure, la ténacité au choc Charpy à -196 °C étant d'au moins 30 J (sur la base d'une épaisseur de 5 mm), et la différence maximale de hauteur entre une crête et un creux formé dans une zone de 2 m le long de la direction de laminage peut être d'au plus 10 mm
PCT/KR2019/014193 2018-10-25 2019-10-25 Acier austénitique cryogénique à haute teneur en manganèse ayant une excellente forme, et procédé de fabrication associé WO2020085861A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP19876795.6A EP3872216A4 (fr) 2018-10-25 2019-10-25 Acier austénitique cryogénique à haute teneur en manganèse ayant une excellente forme, et procédé de fabrication associé
CN201980069717.2A CN112930415A (zh) 2018-10-25 2019-10-25 形状优良的超低温用奥氏体高锰钢材及其制造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20180128504 2018-10-25
KR10-2018-0128504 2018-10-25
KR1020190118925A KR102255826B1 (ko) 2018-10-25 2019-09-26 형상이 우수한 극저온용 오스테나이트계 고망간 강재 및 그 제조방법
KR10-2019-0118925 2019-09-26

Publications (1)

Publication Number Publication Date
WO2020085861A1 true WO2020085861A1 (fr) 2020-04-30

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Country Status (1)

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WO (1) WO2020085861A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116426836B (zh) * 2023-05-16 2024-01-05 燕山大学 一种Fe-Mn-Al-C-Nb-V奥氏体轻质钢及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR940002370A (ko) 1992-07-24 1994-02-17 정명식 성형성, 강도 및 용접성이 우수한 오스테나이트계 고 망간강과 그 제조방법
JP2007126715A (ja) * 2005-11-04 2007-05-24 Sumitomo Metal Ind Ltd 高Mn鋼材及びその製造方法
KR20130088331A (ko) * 2012-01-31 2013-08-08 현대제철 주식회사 고강도 강판 및 그 제조 방법
CN107620010A (zh) * 2017-10-18 2018-01-23 舞阳钢铁有限责任公司 一种低屈强比高韧性高锰钢板及其生产方法
KR20180072967A (ko) * 2016-12-22 2018-07-02 주식회사 포스코 저온인성 및 항복강도가 우수한 고 망간 강 및 제조 방법
KR20180074450A (ko) * 2016-12-23 2018-07-03 주식회사 포스코 극저온용 오스테나이트계 고 망간 강 및 제조방법

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR940002370A (ko) 1992-07-24 1994-02-17 정명식 성형성, 강도 및 용접성이 우수한 오스테나이트계 고 망간강과 그 제조방법
JP2007126715A (ja) * 2005-11-04 2007-05-24 Sumitomo Metal Ind Ltd 高Mn鋼材及びその製造方法
KR20130088331A (ko) * 2012-01-31 2013-08-08 현대제철 주식회사 고강도 강판 및 그 제조 방법
KR20180072967A (ko) * 2016-12-22 2018-07-02 주식회사 포스코 저온인성 및 항복강도가 우수한 고 망간 강 및 제조 방법
KR20180074450A (ko) * 2016-12-23 2018-07-03 주식회사 포스코 극저온용 오스테나이트계 고 망간 강 및 제조방법
CN107620010A (zh) * 2017-10-18 2018-01-23 舞阳钢铁有限责任公司 一种低屈强比高韧性高锰钢板及其生产方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116426836B (zh) * 2023-05-16 2024-01-05 燕山大学 一种Fe-Mn-Al-C-Nb-V奥氏体轻质钢及其制备方法

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