WO2020074174A1 - A polymer composite - Google Patents
A polymer composite Download PDFInfo
- Publication number
- WO2020074174A1 WO2020074174A1 PCT/EP2019/073038 EP2019073038W WO2020074174A1 WO 2020074174 A1 WO2020074174 A1 WO 2020074174A1 EP 2019073038 W EP2019073038 W EP 2019073038W WO 2020074174 A1 WO2020074174 A1 WO 2020074174A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polypropylene
- vip
- polymer composite
- vacuum insulation
- matrix
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 31
- 229920000642 polymer Polymers 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000004743 Polypropylene Substances 0.000 claims description 27
- 229920001155 polypropylene Polymers 0.000 claims description 27
- 238000009413 insulation Methods 0.000 claims description 24
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 claims description 19
- 239000011159 matrix material Substances 0.000 claims description 15
- 239000002699 waste material Substances 0.000 claims description 15
- -1 polypropylene Polymers 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 230000004888 barrier function Effects 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 239000008240 homogeneous mixture Substances 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 238000010412 laundry washing Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000000654 additive Substances 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000012774 insulation material Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
- E04B1/803—Heat insulating elements slab-shaped with vacuum spaces included in the slab
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/242—Slab shaped vacuum insulation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/10—Insulation, e.g. vacuum or aerogel insulation
Definitions
- the present invention relates to a polymer composite, to the production method thereof and the use thereof in white goods.
- Vacuum Insulation Panels which are used as insulation material cannot be recycled.
- the vacuum insulation panels cause serious problems such as clogging in recycling machines, which prevents the same from being recycled. This material which is now waste seriously harms the environment and causes serious problems in terms of costs.
- thermoplastic polymer by using materials containing silicone such as silica, talk, fumed silica, etc. as additive to cross-link thermoplastic polymers.
- German Patent Application No. DE 199915311 A relates to a seven-layer vacuum insulation panel with improved insulation properties.
- the aim of the present invention is the realization of white goods comprising polymeric composites obtained by recycling the Vacuum Insulation Panels (VIP) used as insulation materials and adding the resulting material into the polypropylene matrix.
- VIP Vacuum Insulation Panels
- the polymeric composite realized in order to attain the aim of the present invention, explicated in the first claim and the respective claims thereof comprises a polypropylene (PP) matrix, powdered waste vacuum insulation panel (VIP) and maleic anhydride-grafted polypropylene (MA-g-PP).
- PP polypropylene
- VIP powdered waste vacuum insulation panel
- MA-g-PP maleic anhydride-grafted polypropylene
- mineral additives such as calcite, talk, etc.
- fiber additives such as glassfiber and carbon fiber can be added.
- the polymeric composite of the present invention is used in white goods such as washing machine, dishwasher, laundry dryer, oven, air conditioner, small appliances, etc., in particular in refrigerators.
- the polymeric composite of the present invention comprises a polypropylene (PP) matrix and maleic anhydride-grafted polypropylene (MA-g-PP).
- MA-g-PP interacts with the silica, glassfiber and silicon carbide present in both polypropylene matrix and the vacuum insulation panel (VIP) filler, thus making the filler and the polymer matrix compatible.
- VIP vacuum insulation panel
- the polymeric composite of the present invention comprises powdered waste vacuum insulation panel (VIP).
- VIP powdered waste vacuum insulation panel
- Waste vacuum insulation panels which cannot be recycled are used as filler in the polymeric composite, thus significantly improving the mechanical properties of raw materials. While in the PP matrix with the silica-based vacuum insulation panel (VIP) filler and MA-g-PP additive, the existing flexibility and lightness of the PP material can be partially retained, the silica, glassfiber and silicon carbide therein significantly improve tensile and yield strength, Young modulus, E modulus and bend strength.
- VIP vacuum insulation panel
- the polymeric composite comprises 50-94% polypropylene (PP) matrix, 5-40% powdered waste vacuum insulation panel (VIP) and 3% maleic anhydride-grafted polypropylene (MA-g-PP).
- PP polypropylene
- VIP powdered waste vacuum insulation panel
- MA-g-PP maleic anhydride-grafted polypropylene
- 77% PP, 20% VIP and 3% MA-g-PP by weight are used.
- the VIP filler increases the strength of the material while decreasing the elongation at yield value. Therefore, the elongation at yield value obtained by using 5-40%, preferably 20% VIP by weight is suitable for white goods applications.
- the polymer composite production method of the present invention comprises the steps of
- vacuum insulation panels used as insulation material in white goods are recycled, thus minimizing the harm against the environment and decreasing raw material costs.
- the recycled material is repeatedly used in white goods, a full recycling is ensured.
- the amount of raw material used is minimized, the waste and toxic vacuum insulation panel components are made use of in the product, and environmentally-friendly polymeric composites with improved mechanical properties are obtained.
- the polymer composite of the present invention is used in white goods.
- the polymer composite of the present invention is used in a refrigerator.
- the polymer composite of the present invention is used in a laundry washing machine.
- the polymer composite of the present invention is used in a dishwasher.
Abstract
The present invention relates to a polymer composite produced to be used in white goods and to the production method thereof.
Description
The present invention relates to a polymer composite, to the production method thereof and the use thereof in white goods.
Vacuum Insulation Panels (VIP) which are used as insulation material cannot be recycled. The vacuum insulation panels cause serious problems such as clogging in recycling machines, which prevents the same from being recycled. This material which is now waste seriously harms the environment and causes serious problems in terms of costs.
In the state of the art American Patent Application No. US 4,446,090, a method is disclosed, for obtaining a thermoplastic polymer by using materials containing silicone such as silica, talk, fumed silica, etc. as additive to cross-link thermoplastic polymers.
The state of the art German Patent Application No. DE 199915311 A relates to a seven-layer vacuum insulation panel with improved insulation properties.
The aim of the present invention is the realization of white goods comprising polymeric composites obtained by recycling the Vacuum Insulation Panels (VIP) used as insulation materials and adding the resulting material into the polypropylene matrix.
The polymeric composite realized in order to attain the aim of the present invention, explicated in the first claim and the respective claims thereof comprises a polypropylene (PP) matrix, powdered waste vacuum insulation panel (VIP) and maleic anhydride-grafted polypropylene (MA-g-PP). Optionally, mineral additives such as calcite, talk, etc. and fiber additives such as glassfiber and carbon fiber can be added.
The polymeric composite of the present invention is used in white goods such as washing machine, dishwasher, laundry dryer, oven, air conditioner, small appliances, etc., in particular in refrigerators.
The polymeric composite of the present invention comprises a polypropylene (PP) matrix and maleic anhydride-grafted polypropylene (MA-g-PP). MA-g-PP interacts with the silica, glassfiber and silicon carbide present in both polypropylene matrix and the vacuum insulation panel (VIP) filler, thus making the filler and the polymer matrix compatible. Thus, the physical and mechanical properties thereof given below are improved.
The polymeric composite of the present invention comprises powdered waste vacuum insulation panel (VIP).
Waste vacuum insulation panels which cannot be recycled are used as filler in the polymeric composite, thus significantly improving the mechanical properties of raw materials. While in the PP matrix with the silica-based vacuum insulation panel (VIP) filler and MA-g-PP additive, the existing flexibility and lightness of the PP material can be partially retained, the silica, glassfiber and silicon carbide therein significantly improve tensile and yield strength, Young modulus, E modulus and bend strength. By using the waste vacuum insulation panel material in the PP matrix, cost advantage is provided in raw material costs, and the waste vacuum insulation panel contents are prevented from harming the environment.
Table 1. Vacuum insulation panel components.
| Vacuum Insulation Panel Components. | By mass % |
| Silicon (SiO 2 ) | 75 |
| Glassfiber | 15 |
| Silicon carbide (SiC) | 15 |
In an embodiment of the present invention, the polymeric composite comprises 50-94% polypropylene (PP) matrix, 5-40% powdered waste vacuum insulation panel (VIP) and 3% maleic anhydride-grafted polypropylene (MA-g-PP). In a preferred embodiment of the present invention, 77% PP, 20% VIP and 3% MA-g-PP by weight are used.
The VIP filler increases the strength of the material while decreasing the elongation at yield value. Therefore, the elongation at yield value obtained by using 5-40%, preferably 20% VIP by weight is suitable for white goods applications.
Table 2. Mechanical properties of polymer composite samples.
| Material Properties | PP |
Formulation 1
(17% VIP) |
| Density, g/cm 3 | 0.9 | 1.1 |
|
Tensile strength at yield
(MPa) |
32 | 37 |
|
Elongation at yield
(%) |
9.6 | 4 |
|
Young modulus
(MPa) |
1326 | 2377 |
| Izod Impact Strength (kJ/m 2 ) | 3.4 | 3.4 |
| Bend Strength (MPa) | 38 | 54 |
|
E Modulus
(MPa) |
1178 | 2077 |
The polymer composite production method of the present invention comprises the steps of
- removing the barrier films of the waste vacuum insulation panel (VIP),
- pulverizing the filler material in the mixer,
- adjusting the temperature of the extruder according to the melting temperature of the polypropylene (PP) matrix,
- melting in the extruder the polypropylene (PP) matrix and the maleic anhydride-grafted polypropylene (MA-g-PP) by mixing the same homogeneously,
- adding the powdered waste vacuum insulation panel (VIP) filler from the side feeder of the extruder into the material,
- obtaining a homogeneous mixture in the extruder by means of screws,
- instantaneously cooling down the polymeric composite melt in a water bath, then granulating the same by means of crusher knives,
- forming the obtained polymer composite granules by means of injection molding method.
By means of the polymer composite of the present invention, vacuum insulation panels used as insulation material in white goods are recycled, thus minimizing the harm against the environment and decreasing raw material costs. As the recycled material is repeatedly used in white goods, a full recycling is ensured. Thus, the amount of raw material used is minimized, the waste and toxic vacuum insulation panel components are made use of in the product, and environmentally-friendly polymeric composites with improved mechanical properties are obtained.
In an embodiment of the present invention, the polymer composite of the present invention is used in white goods.
In an embodiment of the present invention, the polymer composite of the present invention is used in a refrigerator.
In an embodiment of the present invention, the polymer composite of the present invention is used in a laundry washing machine.
In an embodiment of the present invention, the polymer composite of the present invention is used in a dishwasher.
Claims (8)
- A polymeric composite comprising a polypropylene (PP) matrix and maleic anhydride-grafted polypropylene (MA-g-PP), characterized by comprising powdered waste vacuum insulation panel (VIP).
- A polymeric composite as in Claim 1, characterized by comprising 50-94% polypropylene (PP) matrix, 5-40% powdered waste vacuum insulation panel (VIP) and 3% maleic anhydride-grafted polypropylene (MA-g-PP).
- A polymeric composite as in Claim 2, characterized by comprising 77% polypropylene (PP) matrix, 20% powdered waste vacuum insulation panel (VIP) and 3% maleic anhydride-grafted polypropylene (MA-g-PP).
- A polymer composite production method characterized by comprising the steps of- removing the barrier films of the waste vacuum insulation panel (VIP),- pulverizing the filler material in the mixer,- adjusting the temperature of the extruder according to the melting temperature of the polypropylene (PP) matrix,- melting in the extruder the polypropylene (PP) matrix and the maleic anhydride-grafted polypropylene (MA-g-PP) by mixing the same homogeneously,- adding the powdered waste vacuum insulation panel (VIP) filler from the side feeder of the extruder into the material,- obtaining a homogeneous mixture in the extruder by means of screws,- instantaneously cooling down the polymeric composite melt in a water bath, then granulating the same by means of crusher knives,- forming the obtained polymer composite granules by means of injection molding method.
- A white good characterized by comprising a polymer composite as in any one of the claims 1 to 3.
- A refrigerator characterized by comprising a polymer composite as in any one of the claims 1 to 3.
- A laundry washing machine characterized by comprising a polymer composite as in any one of the claims 1 to 3.
- A dishwasher characterized by comprising a polymer composite as in any one of the claims 1 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP19762920.7A EP3864085A1 (en) | 2018-10-08 | 2019-08-29 | A polymer composite |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TR2018/14752 | 2018-10-08 | ||
| TR201814752 | 2018-10-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2020074174A1 true WO2020074174A1 (en) | 2020-04-16 |
Family
ID=67851102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2019/073038 WO2020074174A1 (en) | 2018-10-08 | 2019-08-29 | A polymer composite |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP3864085A1 (en) |
| WO (1) | WO2020074174A1 (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4446090A (en) | 1983-10-03 | 1984-05-01 | General Electric Company | High viscosity silicone blending process |
| DE4207244A1 (en) * | 1992-03-07 | 1993-09-09 | Basf Ag | Composite sheet for e.g. cars - comprises polyolefin reinforced with mat based on natural fibre with fibres wt. above 10 tex, pref. sisal |
| DE19915311A1 (en) | 1999-04-03 | 2000-10-05 | Bayer Ag | Vacuum insulating panel, especially for refrigerators, has a microporous core encased in a 7-layer plastic foil with a polyolefin sealing layer, a gas barrier, a polyolefin layer and a metallised polymer layer |
| WO2006108256A1 (en) * | 2005-04-13 | 2006-10-19 | Ford Motor Company Brasil Ltda. | Material to be injection molded, process thereof, and use therefore |
| CN101798423A (en) * | 2010-03-25 | 2010-08-11 | 从化市聚赛龙工程塑料有限公司 | Modified composite material with waste polypropylene plastic as raw material and preparation method thereof |
| CN103589058A (en) * | 2013-10-24 | 2014-02-19 | 合肥会通新材料有限公司 | Reinforced polypropylene composite material and preparation method thereof |
| CN102952335B (en) * | 2012-10-19 | 2015-07-15 | 浙江俊尔新材料股份有限公司 | Polypropylene material prepared from waste washing machine inner cylinder material and method for preparing same |
-
2019
- 2019-08-29 WO PCT/EP2019/073038 patent/WO2020074174A1/en unknown
- 2019-08-29 EP EP19762920.7A patent/EP3864085A1/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4446090A (en) | 1983-10-03 | 1984-05-01 | General Electric Company | High viscosity silicone blending process |
| DE4207244A1 (en) * | 1992-03-07 | 1993-09-09 | Basf Ag | Composite sheet for e.g. cars - comprises polyolefin reinforced with mat based on natural fibre with fibres wt. above 10 tex, pref. sisal |
| DE19915311A1 (en) | 1999-04-03 | 2000-10-05 | Bayer Ag | Vacuum insulating panel, especially for refrigerators, has a microporous core encased in a 7-layer plastic foil with a polyolefin sealing layer, a gas barrier, a polyolefin layer and a metallised polymer layer |
| WO2006108256A1 (en) * | 2005-04-13 | 2006-10-19 | Ford Motor Company Brasil Ltda. | Material to be injection molded, process thereof, and use therefore |
| CN101798423A (en) * | 2010-03-25 | 2010-08-11 | 从化市聚赛龙工程塑料有限公司 | Modified composite material with waste polypropylene plastic as raw material and preparation method thereof |
| CN102952335B (en) * | 2012-10-19 | 2015-07-15 | 浙江俊尔新材料股份有限公司 | Polypropylene material prepared from waste washing machine inner cylinder material and method for preparing same |
| CN103589058A (en) * | 2013-10-24 | 2014-02-19 | 合肥会通新材料有限公司 | Reinforced polypropylene composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3864085A1 (en) | 2021-08-18 |
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