WO2020046409A2 - Wear resistant concrete formulations and methods for their preparation - Google Patents
Wear resistant concrete formulations and methods for their preparation Download PDFInfo
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- WO2020046409A2 WO2020046409A2 PCT/US2019/000043 US2019000043W WO2020046409A2 WO 2020046409 A2 WO2020046409 A2 WO 2020046409A2 US 2019000043 W US2019000043 W US 2019000043W WO 2020046409 A2 WO2020046409 A2 WO 2020046409A2
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0032—Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
- C04B14/062—Microsilica, e.g. colloïdal silica
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/002—Water
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00068—Mortar or concrete mixtures with an unusual water/cement ratio
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
Definitions
- silica such as, for example silica fume
- a general problem with silica is that it can raise the water demand of a concrete formulation such that the likelihood of capillaries and void formation during curing is increased due to the higher likelihood of significant bleedwater. In order to reduce bleed water, water is commonly minimized, even when relatively large amounts of silica fume are used (often 5 to 10 percent by weight of cementitious materials).
- Water is often carefully rationed to be present in relative amounts below a water: cementitious materials ratio of about 0.5. (Design and Control of Concrete Mixtures, Sixteenth Edition, Second Printing (revised); Kosmatka, Steven H.; page 156). Such low amounts of water are generally below what is recommended by the cement manufacturer, and can significantly impair the rheology of the concrete mix, causing it to be difficult to pour or work. Materials such as superplasticizers can be necessary at such low water content.
- a concrete and method of preparation which comprises small-particle-size, high-surface-area amorphous silica, used in much smaller proportions to the cement than generally used in the industry for structural purposes: only about 0.1 to about 4 ounces per hundred weight of cementitious materials.
- the improved concretes are prepared by a process-specific addition of the silica. These improved concretes can be prepared using the standard amount of water recommended by the cement manufacturer, or even water in excess of the recommended amount, without significantly compromising compressive strength. Such a result is truly surprising.
- the low-silica concretes described above have improved compressive strength and abrasion resistance, among other improved characteristics.
- An improvement in compressive strength is surprising, considering the small amounts of silica employed, while known methods use much larger amounts to achieve gains which are, in some cases, significantly less.
- significant improvement in concrete abrasion resistance has generally not been observed with the use of silicas such as, for example, silica fume, even in the larger amounts usually used (id, page 159).
- the low-silica concretes, described in the foregoing application (US Provisional Application 62/761,064), give profound improvement in abrasion resistance as measured by test ASTM C944.
- Standard concretes i.e., not comprising the high-surface-area amorphous silica taught infra
- the low-silica concretes taught herein can have an ASTM C944 value is as low as 1.1 grams of loss or less.
- the concrete of the present invention generally exhibits a greatly reduced absorption of water-both during and after curing.
- the absorption of water during curing and/or after curing can be eliminated completely.
- the admixture comprises a compound commonly used to re-emulsify concrete.
- the concrete cutter has been used in the concrete industry to dissolve hardened (i.e., cured) concrete deposits from equipment used to prepare and work concrete, such as Readymixes, power trowels, and the like.
- a re-emulsifier which has the ability to destroy the structure (C-S-H matrix) of cured concrete, could be expected to thin the concrete mix, preventing curing, or negatively affecting the cured structure of the concrete by permitting the migration of water during curing.
- the concrete when used in conjunction with the silica as described infra, the concrete not only cures, but little or no bleed water is generally observed during curing of concrete of the present invention.
- the cured concrete has a better abrasion resistance than even the concrete prepared with the silica admixture alone, let alone traditional concretes.
- the high degree of water impermeability can be obtained without subjecting the concrete to a finishing step (See Example 2, for example, which describes the preparation of a footing which shows density and impermeability).
- the concrete of the present invention is particularly appropriate for outdoor concrete applications.
- concrete for outside use such as, for example, sidewalks, curbs, and parking lots, does not require extensive finishing, although some degree of floating may be performed.
- the small imperfections in the surface are generally allowed to remain, and eventually the surface weathers and renders the issue of imperfections moot.
- water damage during the life of the concrete is a problem with outside concrete.
- One countermeasure taken is the application of a cure and seal agent. The protection given by these agents is generally short-lived.
- Another countermeasure is the use of air-entrained concrete such that the damage done by absorbed water during freezing is minimized.
- neither measure is a long-term solution to the problem of freeze damage.
- cured concrete of the present invention generally has a negligible or no water absorption. No further finishing or sealant application is necessary. Furthermore, the concrete thus generally does not require the entrainment of air in order to resist freeze-thaw damage.
- the normal water absorption of outdoor cement according to the Rilum test is about 1 .5 to 3 ml in 20 minutes.
- the surfaces of the concrete of the present invention absorbed essentially no water, despite the lack of a finishing step.
- the Rilum test is expected to give an absorption in 20 minutes of from about 0 to about 1 .0 ml in 20 minutes.
- concretes of the present invention may not develop the surface imperfections and capillaries which are an issue with other concretes, or the inventive concretes may develop them to a greatly reduced degree.
- the surface which develops can be plastic-like (the extent of which can be controlled by details of the finishing process, as discussed infra) having a greatly reduced amount of friction with respect to the finishing blades, when compared to the finishing of standard concrete.
- Increased finishing speeds with respect to standard concrete finishing speeds generally further the achievement of a glossy surface having a plastic-like consistency.
- finishing concrete prepared by existing methods and formulations improves the smoothness and planarity of the surface, with longer finishing times giving greater improvement, to a point.
- Such concrete can be finished by hand or with a ride-on power trowel, with ride on power trowel generally giving a faster, more even, higher quality finish than a hand trowel.
- the concretes of the present invention generally finish faster (i.e., take a shorter time to reach a given degree of glossiness) and have a higher glossiness potential (as measured, for example, with a glossiness meter) with regard to the finishing process.
- the use of higher-than-conventional speeds can be expected to result in gains in glossiness beyond that possible with existing concretes.
- Such high finishing speeds are generally easier to use with the concretes of the present invention due to reduced friction.
- the admixture as indicated herein generally gives a concrete which requires less finishing effort to achieve a finished surface.
- the finisher can generally feel a difference in that the friction between the trowel or finishing blades, and the floor surface is generally significantly less than it would be without the admixture use of the present invention.
- the amount of time needed to finish a floor surface with a finishing machine to a given degree of glossiness is reduced for a given finishing machine speed (rpm).
- finishing speeds from about 190-210 rpm
- the surface can generally be finished to a higher gloss than traditional concrete surfaces.
- higher finishing speeds are not necessary, and thus, newer finishing machines are capable of lesser top speeds (180 rpm or 190 rpm) than older machines (200 rpm or 210 rpm).
- the heat of curing promotes a reaction between the high surface area amorphous silica and the components of the“re-emulsifier” admixture to form a plastic-like component throughout the concrete. Finishing at high speeds promotes this reaction at the surface, where heat dissipation may prevent the reaction from taking place to the degree in the concrete bulk.
- the formation of the plastic-like substance promoted by the heat generated by finishing at high finishing speeds (i.e., generally 200 rpm and above), gives the surface having an improved gloss with respect to that possible with traditional concretes.
- finishing of concrete surfaces can have an effect upon the water-impermeability of the slab.
- “Closing the slab,” i.e., finishing a slab using a technique involving the repetitive, directional application of finishing machinery, well-known in the art, is a method of finishing which can give a decrease in water permeability.
- Such methods can be applied to concretes of the present invention, however, the concretes of the present invention exhibit surprisingly high water impermeability, or even complete water impermeability even without a finishing step.
- the surfaces of the concrete of the present invention are generally harder than concrete of traditional methods and formulations.
- most concretes increase in hardness with curing times. For example, at about 28 days post-pour, most concretes prepared according to existing methods have a hardness in the range of from about 4 to about 5 with respect to the Mohs hardness scratch test. It is not unusual for the concretes of the present invention to achieve such a hardness after time lengths in the range of from about 3 to about 8 days (about 72 to about 192 hours) post-pour. After about 28 days, it is not unusual for concretes of the present invention to have a hardness in the range of from about 6 to about 9, or in many cases, to have a hardness in the range of from about 7 to about 8.
- the methods of the present invention are preferably used as admixture with the concrete formulations comprising amorphous silica (such concrete formulations prepared as described in the section below entitled“Novel Compositions for Improved Concrete Performance”).
- amorphous silica such concrete formulations prepared as described in the section below entitled“Novel Compositions for Improved Concrete Performance”.
- the admixture use with the composition of the aforementioned section is described herein, its manner of use in these formulations thoroughly described.
- the use of silica which is not described herein, such as having larger particle sizes than described herein, may give some limited benefits of the invention, but will likely be more difficult to pour, work and finish than concretes prepared with low-particle size, high-surface-area amorphous silica.
- Fig. 1 depicts a concrete slab containing 4 oz per hundred weight E5 Internal Cure, with E5 Finish used topically as a finish at rates of 1000 square feet per gallon. The burnishing process was initiated directly after the conclusion of the finishing step. Fig. 1 shows the undamaged surface, despite the 27-inch burnisher being run at 2500 rpm. While the photo is of the topically applied E5 Finish, the same result is obtained for admixture applications of E5 Finish, as indicated.
- Fig. 2 shows the conversion of the surface from approximately Grade 1 to approximately Grade 2. While the photo is of the topically applied E5 Finish, the same result is obtained for admixture applications of E5 Finish, as indicated.
- the admixture formulations which can be used in the present invention. While the invention disclosed in this provisional application refers to Korkay Concrete Dissolver (“Korkay”) of the formulation available for sale on March 20, 2017, from Tate’s Soaps and Surfactants, one of skill in the art will recognize that Korkay, and water dilutions thereof, are chemical formulations, and such chemical formulations can be prepared by various different sources and/or methods and be suitable for use in the present invention, in order to obtain the benefits of the present invention.
- the admixture composition comprises or consists essentially of a water dilution of Korkay.
- formulations comprising the same chemical components of Korkay or water dilutions thereof, but in which the concentrations of one or more components, not including water, deviate from the concentration with respect to Korkay or a water dilution thereof, respectively, by less than 50, 40, 30, 20, 10 or 5 % by weight, with respect to the weight of Korkay or its water dilutions, respectively, can be useful in the present invention.
- concentrations of one or more components, not including water deviate from the concentration with respect to Korkay or a water dilution thereof, respectively, by less than 50, 40, 30, 20, 10 or 5 % by weight, with respect to the weight of Korkay or its water dilutions, respectively, can be useful in the present invention.
- Such chemical compositions can be used in the recommended amounts and rates above.
- the admixture comprises or consists essentially of water; an alpha-hydroxy acid, a glycol alkyl ether, and a polyethylene glycol with an average molecular weight in the range of from about 500 to about 1500 mw.
- the alpha- hydroxy acid contains in the range of from about 5 to about 1 carbons, with glycolic acid preferred. Glycolic acid is available from Chemsolv.
- the glycol alkyl ether is preferably a polypropylene methyl ether, with dipropylene glycol methyl ether preferred. Dipropylene glycol methyl ether is available from many sources, for example, Dow Chemical, Lyondell Bassell, and Shell.
- the polyethylene glycol having an average molecular weight in the range of from about 500 to about 1500 molecular weight is preferably polyethylene glycol having an average molecular weight in the range of from about 750 to about 1250 molecular weight, and even more preferably in the range of from about 950 to about 1050 molecular weight.
- a suitable polyethylene glycol is PEG(1000).
- the alpha-hydroxy acid is preferably present in the admixture in the range of from about 5 to about 20 weight percent, with a weight percent in the range of from about 10 to about 15 weight percent more preferred.
- the weight percent of glycol alkyl ether is preferably in the range of from about 5 to about 20 weight percent, with a range of about 10 to about 15 weight percent more preferred.
- the weight percent of polyethylene glycol is preferably in the range of from about 1 to about 15 weight percent, with a ration in the range of from about 1 to about 9 weight percent more preferred.
- Water is present in the range of from about 70 to about 80 weight percent, with a range of about 71 to about 77 weight percent more preferred.
- the admixture comprises, consists or consists essentially of a water dilution of the following four part mixture:
- the dilution is preferably comprises, consists, or consists essentially of one part mixture to between about 4 and about 20 parts of water, with a more preferred dilution of between about 5 and about 12 parts water, with an even more preferred dilution being from about 6 to about 8 parts of water, with a range of from about 6.5 to about 7.5, or even from about 6.8 to about 7.2 being particularly suitable.
- the admixture to be added to the concrete mix comprises, consists or consists essentially of one part by weight Korkay to between about 4 and about 20 parts by weight of water, with a more preferred dilution of between about 5 and about 12 parts by weight water, with an even more preferred dilution being from about 6 to about 8 parts by weight of water.
- the E5 Finish formulation can be formed by creating a mixture which comprises about 7 parts water to about 1 part Korkay).
- the admixture comprises the E5 Finish formulation.
- the admixture comprises a water dilution or water-removed concentration of the E5 finish or a chemically identical preparation of the foregoing. In other embodiments, the admixture comprises or consists essentially of the E5 Finish. In further embodiments, the foregoing admixture is added to the Readymix in amounts in the range of from about 0.5 to about 8 oz per 100 lbs cement, with from about 2 to about 5 oz per 100 lbs cement preferred, and from about 2.5 to about 3.5 oz per 100 lbs cement even more preferred, with from about 2.8 to about 3.2 oz per 100 lbs cement being most preferred.
- E5 Finish greater than about 5 ounces of E5 Finish per 100 wt cementitious materials, or for amounts of amorphous silica greater than about 5 ounces per 100 wt cementitious materials, the observed benefits of the invention may begin to diminish in that increased brittleness and decreased compressive strength may, in some cases, be observed.
- amorphous silica or E5 Internal Cure
- Korkay or E5 Finish
- a change in the amount of amorphous silica away from about 4 ounces per hundredweight or in the amount of E5 Finish away from about 3 ounces per hundredweight gives some reduction in abrasion resistance, water impermeability and compressive strength.
- the formulations are generally employed as an admixture, and thus they are prepared in the prescribed proportions and added to a bulk concrete mixture, such as adding to a ReadyMix which contains a concrete mixture which comprises the small particle-size amorphous silica, such as the concrete mixtures described infra.
- a ReadyMix which contains a concrete mixture which comprises the small particle-size amorphous silica, such as the concrete mixtures described infra.
- Such admixture addition is most preferred.
- the separate addition of the components of the admixture may be permissible. For example, it may be permissible to add some or all of one or more of the water, glycolic acid, dipropylene glycol methyl ether or polyethylene glycol components to the concrete mixture, particularly after the mixture is fully mixed, before adding the balance of the admixture.
- the concrete mixture could be prepared with at least some of the water allocated to the admixture. It should be understood that in such a situation, in ascertaining the amounts of water in the concrete mixture and the admixture, the total amount of water should be considered as the sum of two subquantities: one which is within the limits of the total amount of water permitted for the concrete mixture, and the second within the total amount of water permitted for the admixture. Such separate addition of components may give some effect of the present invention.
- a mixture of components the mixture comprising an alpha-hydroxy acid, a glycol alkyl ether, a polyethylene glycol and water, is added to a Readymix which contains a mixed concrete mixture comprising amorphous silica, as described infra.
- the concrete mix comprises amorphous silica, which can be added as E5 Internal cure, if desired.
- the concrete mix comprises amorphous silica having particles with an average particle size of less than about 55 nm, and in some embodiments, an average particle size of less than about 7.8 nm, or, in other embodiments, an average particle size between about 5 and about 55 nm, or between about 5 and about 7.9 nm; and having a surface area in the range of from about 430 to about 900 m 2 /g; and present in the concrete in a weight ratio in the range of from about 0.1 to about 4 ounces amorphous silica per 100 lbs of cement (i.e., not including water, aggregate, sand or other additives).
- Amorphous silica from other sources may be suitable as long as it is characterizable by the particle size parameters above.
- suitable amorphous silica include colloidal silica, precipitated silica, silica gel and fumed silica, with colloidal silica or silica gel being preferred lt is more preferred to use particles with average particle size of less than about 25 nm, with average particle size of less than about 7.9 nm is even more preferred.
- a more preferred weight proportion in the concrete is from about 0.1 to about 3 ounces of amorphous silica per 100 lbs of cement (not including water, aggregate, sand or other additives).
- An even more preferred weight proportion in the concrete is from about 0.1 to about 1 ounces of amorphous silica per 100 lbs of cement (again, not including water, aggregate, sand or other additives).
- amorphous silicas with surface areas in the range of from about 50 to about 900 m 2 /gram are preferred, with about 150 to about 900 m 2 /gram more preferred, and about 400 to about 900 m 2 /gram even more preferred.
- Amorphous silica with an alkaline pH is preferred, with a pH in the range of from 8 to 1 1 being more preferred.
- the amorphous silica is provided by the use of E5 INTERNAL CURE, an additive available commercially from Specification Products LLC.
- the weight proportion of E5 INTERNAL CURE to cement is in the range of from about 1 to about 20 ounces of E5 INTERNAL CURE to 100 lbs cement (not including water, sand, aggregate or other additives). More preferably the weight proportion of E5 INTERNAL CURE to cement is in the range of from about 1 to about 10 ounces of E5 INTERNAL CURE to about 100 lbs cement (not including water, sand, aggregate or other additives).
- E5 INTERNAL CURE to cement is in the range of from about 1 to about 5 ounces of E5 INTERNAL CURE to about 100 lbs cement (not including water, sand, aggregate, or other additives).
- An ideal value is in the range of about 3-5, or about 4 ounces per hundred weight.
- the use of more than about 20 ounces of E5 INTERNAL CURE to about 100 lbs cement (not including water sand, aggregate or other additives), or the use of more than about 5 ounces of amorphous silica to about 100 lbs cement (not including water, sand, aggregate, or other additives) can cease to be of benefit in that beneficial water or compressive strength benefits may not be observed, or may be minimally observed.
- the order of addition of the amorphous silica and the admixture is important to realizing the maximum benefit from the inventive processes, compositions, and concretes. For example, it is strongly preferred to add the amorphous silica to the cement mix prior to the addition of the cutter-containing admixture.
- the amorphous silica is preferably combined with the cement mixture according to the section below entitled“Novel Compositions for Improved Concrete Performance”.
- a concrete mix is created from components comprising quantities of a) a dry cement mix; b) water; c) amorphous silica; and d) aggregate and/or sand.
- Dry cement mixes generally have a recommended water content which gives a water/cement ratio providing a concrete mix which has a combination of desirable pouring and curing characteristics ln some cases, the recommended water content encompasses a range of water contents. As indicated infra, the initial water content of concrete mix prior to pouring can give rise to issues during curing and finishing which reduce the quality of the resulting concrete installation (slab, footing, etc.). It is common for water-reducing measures, such as the use of “water-reducers” and superplasticizers to be employed in the interests of reducing water-mediated structural flaws in the cured concrete.
- the present invention can be used to give the inventive concrete in situations in which the water included in the concrete mix is equal to or greater than the amount specified by the manufacturer of the dry cement mix. Water-reducers in the concrete mix are generally unnecessary.
- the cement mix and the water are present in the concrete mix in the following proportions:
- a manufacturer suggested water/cement ratio value wherein said suggested ratio falls in the range of from about 0.35 to about 0.65 ; and whereupon combination with the quantity of water, the water/cement ratio is greater than the value corresponding to about 10% less than the suggested value but less than the value corresponding to about 30% more than the suggested value;
- a manufacturer suggested water/cement ratio range having an upper value and a lower value, and whereupon combination with the quantity of water, the water/cement ratio is greater than the value corresponding to about 10% less than the lower value and not greater than the value corresponding to about 30% more than the upper value;
- the water/cement ratio is in the range of from about 0.35 to 0.65.
- the benefits of the invention are generally expected to be manifest with the use of commercially useful types of Portland cement.
- the cement mix is one or more of the types commonly used in construction, such as, for example, Portland cements of Types 1, 11, III, IV and V.
- the quantity of water above is added to the cement mix. This quantity is inclusive of all water which is combined with the concrete mix comprising at least the cement mix, except water introduced with the silica in the case of water-containing formulations of silica such as colloids, dispersions, emulsions, and the like; as well as water introduced with the cutter-containing admixture.
- the water can be combined with the concrete mix comprising at least the cement mix in multiple portions, such as, for example, the addition of a second portion of water (for example,“tailwater”) after a first portion of water has been combined with the concrete mix and agitated for a time.
- a second portion of water for example,“tailwater”
- water is sometimes applied to the surface of concrete after it has partially cured, to prevent the premature drying of the surface, which could result in shrinkage, as well as later difficulties in working and finishing.
- This“finishing” water is not included within the quantity of water.
- the water/cement ratio is in the range of from about 0.38 to 0.55, or, in more specific embodiments, in the range of from about 0.48 to about 0.52, or in the range of from about 0.38 to about 0.42.
- the water and cement mix are present in the concrete mix in the proportions wherein upon combination of the quantity of dry cement mix with the quantity of water, the water/cement ratio is:
- Particle size of amorphous silica is particularly important. Larger particle sizes, such as will be found in micronized silica, generally do not reduce the formation of capillaries and voids to the degree seen when amorphous silica sized as prescribed herein is used in the prescribed amounts.
- the inventive concrete mix comprises a quantity of amorphous nanosilica, which is preferably present in an amount in the range of from about 0.1 to about 7.0 ounces per hundredweight of cement (cwt) in a), and having particle sizes such that the average silica particle size is in the range of from about 1 to about 55 nanometers, and/or wherein the surface area of the silica particles is in the range of from about 300 to about 900 m 2 /g, or in other embodiments, from about 450 to about 900 m 2 /g.
- Amorphous silica from various sources is generally suitable as long as it is characterizable by the particle size and surface area parameters above.
- suitable amorphous silica include colloidal silica, precipitated silica, silica gel and fumed silica.
- colloidal amorphous silica and silica gel are preferred, and colloidal amorphous silica is most preferred.
- the silica particle size is in the range of from about 5 to about 55 nm. Preferred are particles with average particle size of less than about 25 nm, with average particle size of less than about 10 nm more preferred, and average particle size of less than about 7.9 nm even more preferred.
- a preferred weight proportion in the concrete is from about 0.1 to about 3 ounces of amorphous silica per 100 lbs of cement (not including water, aggregate, sand or other additives).
- a more preferred weight proportion in the concrete is from about 0.1 to about 1 ounces of amorphous silica per 100 lbs of cement (again, not including water, aggregate, sand or other additives).
- Even more preferred is about 0.45 to about 0.75 ounces of amorphous silica per 100 lbs of cement (again, not including water, aggregate, sand or other additives).
- amorphous silica per 100 lbs of cement (again, not including water, aggregate, sand or other additives).
- amounts above about 1 ounce per 100 lbs cement generally give decreasing compressive strength gains with respect to the preferred range of about 0.45 to about 0.75 ounces of amorphous silica per 100 lbs cement.
- the preferred range given is the most economically feasible range, i.e., above that, the compressive strength gains are less per additional unit of silica, and cost of silica per unit increase of compressive strength may cause the cost of the concrete to become prohibitive.
- Amorphous silicas having surface areas in the range of from about 50 to about 900 m 2 /gram are preferred, with about 150 to about 900 m 2 /gram more preferred, and about 400 to about 900 m 2 /gram even more preferred, and 450 - 700 m 2 /gram or 500 - 600 m 2 /gram even more preferred.
- Amorphous silica with an alkaline pH (about pH 7 and above) is preferred, with a pH in the range of from 8 to 1 1 being more preferred.
- the amorphous silica is provided by the use of E5 INTERNAL CURE, an additive available commercially from Specification Products LLC, which contains about 15 wt% amorphous silica in about 85 wt% water.
- the silica particle characteristics are an average particle size of less than about 10 nm (measured by BET method), and a surface area of about 550 m2/g.
- the weight proportion of E5 INTERNAL CURE to cement is in the range of from about 1 to about 20 ounce of E5 INTERNAL CURE to 100 lb cement (not including water, sand, aggregate or other additives).
- the weight proportion of E5 INTERNAL CURE to cement is in the range of from about 1 to about 10 ounces of E5 INTERNAL CURE to about 100 lb cement (not including water, sand, aggregate or other additives).
- a more preferred weight proportion of E5 INTERNAL CURE to cement is in the range of from about 1 to about 5 ounces of E5 INTERNAL CURE to about 100 lb cement, with about 3 to about 5 ounces of E5 INTERNAL CURE to about 100 lb cement (not including water, sand, aggregate, or other additives) even more preferred.
- the use of more than about 20 ounces of E5 to about 100 lb cement can cease to be of benefit in that additional beneficial water or compressive strength benefits may not be observed or may be minimally observed.
- the resulting concrete mix may be difficult to pour, and any resulting concrete may be of poor quality. Note that the quality of the concrete diminishes with the distance from the preferred range of about 3 to about 5 ounces per 100 lb cement, but the compressive strength may still be improved over that in the absence of the E5 INTERNAL CURE colloidal amorphous silica.
- the colloidal silica added to the concrete mix is in the range of from about 40 to about 98 wt% silica, with 60 to 95 wt% preferred and 70 to 92 wt% more preferred, and 75 to 90 wt% even more preferred.
- Aggregate and sand can generally be used in the inventive concrete in amounts as known in the art for construction purposes.
- a quantity of aggregate and/or a quantity of sand is used such that they total an amount in the range of from about 400 to about 700 wt% bwoc
- a concrete mix is prepared with components comprising cement mix, water, and, preferably, a quantity of aggregate and sand (sometimes referred to in the art as“large aggregate” and“small aggregate,” respectively). It is permissible for the concrete mix to comprise only one of the two, such as only sand or only aggregate, but it is preferred the mix comprise at least a quantity of each.
- Sand and aggregate can contribute to the silica content of the cement mixture, and thus they can affect (i.e., raise somewhat) the water requirement of the concrete mix.
- aggregate which are appropriate for the use to which the concrete is to be put can be used. Included are larger aggregates such as coarse, crushed limestone gravel, larger grades of crushed clean stone, and the like, as well as smaller aggregates such as the smaller grades of crushed clean stone, fine limestone gravel, and the like.
- sand such as pit (coarse) sand, river sand and the like can be used.
- “coarse sand” is preferred to“soft sand,” which is known to be more appropriate for use in mortars.
- soft sand may generally be expected to have a different water requirement than coarse sand when used in concrete preparation.
- weight-bearing applications may require larger aggregate, such as coarse, crushed limestone.
- larger aggregate is preferred for poured concrete applications, particularly for use in poured building slabs are the larger aggregates, such as, for example, coarse crushed limestone gravel and larger grades of crushed clean stone, and pit sand.
- the proportion of aggregate and sand, taken together, based on weight of cement is preferably in the range of from about 2000 to about 4000 lbs per yard of dry cement mix (in the range of from about 520 to about 610 lbs per yard, or more preferably from about 560 to about 570 lbs per yard, even more preferably, about 564 lbs per yard). More preferred is a combined proportion of aggregate and sand in the range of from about 2700 to about 3300 lbs per yard of dry cement mix. More preferred is a range of from about 2900 to about 3100 lbs per yard of dry cement mix.
- the weight of aggregate and sand is between 50 and 90 wt % based upon the weight of the concrete, with a range of from about 70 to about 85 wt % preferred.
- the relative amounts of aggregate and sand are not critical, but are preferably in the range of from about 20 wt % to about 70 wt % sand based upon the combined weight of the sand and aggregate, with about 40 wt% to about 50 wt % sand preferred.
- the process of the present invention generally includes the situation in which at least a portion of the quantity of water is added prior to the addition of the quantity of amorphous nanosilica, with at least a time period of agitation between the additions to distribute the water prior to the addition of the amorphous silica. In practice, some water may be added later in the preparation process, if desired.
- the amorphous silica is added as a colloidal silica with a second portion of water.
- the colloidal silica is added after the addition of water which has been added in two portions, with agitation after the addition of each portion.
- the quantity of water can be added in its entirety or added in portions comprising an initial portion, comprising in the range of from about 20 wt% to about 95 wt% of the quantity of water, and a tail water portion, comprising the remainder; wherein the initial portion of water is combined with the quantity of cement mix and the aggregate/sand components to form a first mix; and wherein the amorphous silica is added to a mix comprising the quantity of cement mix, the aggregate/sand components and the initial portion of water to form a second mix.
- an initial portion comprising in the range 35 to about 60 wt% of the quantity of water.
- the tailwater is 1) added to the first mix; or 2) added to the second mix; or 3) co-added with the amorphous silica to the first mix, wherein the amorphous silica and the tailwater are, optionally, intercombined; and wherein 1) the first mix is agitated for a time tn prior to the addition of the tailwater, for a time ti2 after the addition of the tailwater but before the addition of the amorphous silica, and for a time ti3 after the addition of the amorphous silica but before the addition of the admixture; or 2) the second mix is agitated for a time t2i prior to the addition of the amorphous silica, for a time t22 after the addition of the amorphous silica but before the addition of the tailwater, and for a time t23 after the addition of the tailwater, but before the addition of the admixture; or 3) the second mix is
- the quantity of cement mix and the sand/aggregate components, tn is preferably in the range of from about 2 to about 8 minutes, with about 3 to about 6 minutes more preferred, and at a mixing speed (such as for example, in a Ready-mix) preferably in the range of from about 2 to about 5 rpm.
- Time ti2 is preferably in the range of from about 0.5 to about 4 minutes, with a more preferred range of from about 1 to 2 minutes, at a mixing speed in the range of from about 2 to about 5 rpm.
- Time ti3 is preferably in the range of from about 2 to about 10 minutes, with a range of from about 5 to about 10 minutes more preferred, with a relatively high mixing speed at a rate in the range of from about 12 to about 15 rpm before the addition of the admixture.
- the rate can be lowered to a rate in the range of from about 2 to about 5 rpm for a time, such as, for example, a transit time to a pour site.
- Transit time standards are set by the American Concrete Institute. For example, the concrete must be poured within 60 minutes of the end of high-rate mixing if the temperature is 90 F or greater, and within 90 minutes if the temperature is less than 90 F.
- t2i is preferably in the range of from about 2 to about 8 minutes, with about 3 to about 6 minutes more preferred, and at a mixing speed (such as for example, in a Ready- mix) preferably in the range of from about 2 to about 5 rpm.
- Time t22 is preferably in the range of from about 0.5 to about 2 minutes, with a more preferred range of from about 0.5 to 1 minutes, at a mixing speed in the range of from about 2 to about 5 rpm.
- Time t23 the time immediately prior to the addition of the admixture, is preferably in the range of from about 2 to about 10 minutes, with a range of from about 5 to about 10 minutes more preferred, with a relatively high mixing speed at a rate in the range of from about 12 to about 15 rpm.
- the rate can be lowered to a rate in the range of from about 2 to about 5 rpm for a time, such as, for example, a transit time to a pour site.
- transit time standards are set by the American Concrete Institute.
- t3i is preferably in the range of from about 2 to about 8 minutes, with about 3 to about 6 minutes more preferred, and at a mixing speed (such as for example, in a Ready-mix) preferably in the range of from about 2 to about 5 rpm.
- Time t32 the time immediately prior to the addition of the admixture, is preferably in the range of from about 2 to about 10 minutes, with a range of from about 5 to about 10 minutes more preferred, with a relatively high mixing speed at a rate in the range of from about 12 to about 15 rpm.
- the rate can be lowered to a rate in the range of from about 2 to about 5 rpm for a time, such as, for example, a transit time to a pour site.
- a time such as, for example, a transit time to a pour site.
- transit time standards are set by the American Concrete Institute.
- the entire quantity of water is added to the quantity of cement mix and the aggregate/sand components to form a mix, whereupon said mix is agitated for a time t a prior to the addition of the amorphous silica, whereupon the concrete mix is then agitated for a time tb prior to the addition of the admixture.
- the addition of the entire quantity of water at once is useful in the case of wet batch processes.
- Time t a is preferably in the range of from about 2 to about 8 minutes, with about 3 to about 6 minutes more preferred, and at a mixing speed (such as for example, in a Ready-mix) preferably in the range of from about 2 to about 5 rpm.
- Time t b is preferably in the range of from about 2 to about 10 minutes, with a range of from about 5 to about 10 minutes more preferred, with a relatively high mixing speed at a rate in the range of from about 12 to about 15 rpm.
- the rate can be lowered to a rate in the range of from about 2 to about 5 rpm for a time, such as, for example, a transit time to a pour site.
- transit time standards are set by the American Concrete Institute. While benefits of the invention would generally be observed in the case of a single addition of water, in practice, the two-portion division of water is generally adhered to.
- the use of a second portion has the advantage of washing down into the Ready-mix remnants of insufficiently mixed cement mix from near the mouth of the barrel.
- the admixture is preferably added at a point which the mixture comprises the silica, and the silica-comprising mixture has been thoroughly mixed before the addition of the admixture.
- the silica-comprising mixture is mixed for a total time of at least 3 minutes at one or more speeds greater than about 6 RPM.
- the silica-comprising mixture is mixed for a time in the range of from about 5 to about 15 minutes, and more preferably in the range of from about 5 to about 10 minutes, at one or more speeds in the range of from about 7 RPM to about 15 RPM, and more preferably in the range of from about 12 to about 15 RPM.
- the cutter-containing admixture is added.
- the mixture which contains the cutter-containing mixture is mixed for a total time of at least 3 minutes at one or more speeds greater than about 6 RPM.
- the cutter-containing mixture is mixed for a time in the range of from about 5 to about 15 minutes, and more preferably in the range of from about 5 to about 10 minutes, at one or more speeds in the range of from about 7 RPM to about 15 RPM, and more preferably in the range of from about 12 to about 15 RPM.
- the concrete mixture can be prepared in a wet (“central mix”) or dry (“transit mix”) batch situation.
- wet batch mode the dry components are mixed with the quantity of water followed by the amorphous silica to give a concrete mix, in one of the ways indicated above.
- the mix is agitated as above or introduced into a Ready-mix and agitated therein as indicated above.
- the wet and dry batch situations are similar except that part of the procedure for a wet batch is performed outside of the Ready-mix (for example, at the plant). Dry batching (“transit mix”) is somewhat preferred.
- 40 plus or minus 20%, or, in further embodiments, plus or minus 10% of the total quantity of water to be utilized in the preparation of the concrete mix, sand and coarse aggregate used in the batch is loaded into a Ready-mix.
- the cement mix, coarse aggregate and sand are mixed together and loaded into the Ready-mix.
- the remaining water is then loaded into the Ready-mix.
- the amorphous silica is added, and the mixture is mixed for 5 to 10 minutes.
- the mixing preferably takes place at relatively high drum rotation speeds, such as, for example, a speed in the range of from about 12 to about 15 rpm. Once the higher-speed mixing has occurred, the batch can then be poured.
- a period of time between the higher-speed mixing and pouring such as transport time to the pouring site.
- a time between the high-speed mixing and the pouring of in the range of from about 1 to about 60 minutes is permissible.
- the silica it is particularly convenient to add the silica to a Ready-mix, which contains the water, cement and other dry components, once the Ready-mix has arrived at the pour site. It has further been found that after the amorphous silica has been added, the concrete/silica mixture should be mixed, prior to pouring, for a time, most preferably at least from about 5 to about 10 minutes. However, other periods of time may be permissible with respect to at least partially obtaining the benefits of the invention.
- the benefits of the invention can be expected in commercially used variants of the foregoing process, as long as the amorphous silica is added at the end, after the mixing together of the dry components and the first and second portion of water (or with the second portion of water), and the silica-added mixture is mixed for a time as specified herein prior to pouring.
- the silica is particularly convenient to add the silica to the Ready-mix, which contains the water, cement and other dry components, once the Ready-mix has arrived at the pour site. It has further been found that after the amorphous silica has been added, the concrete/silica mixture should be mixed, such as, for example, with a Ready-mix mixer, for a time, most preferably at least from about 5 to about 10 minutes, preferably at a high speed, such as, for example 12-15 rpm. However, other periods of time and other speeds may be permissible with respect to at least partially obtaining the benefits of the invention.
- the concrete mixture can be prepared in a wet or dry batch situation, as desired. For example, 40 plus or minus 15%, or, in additional embodiments, plus or minus 10%, of the water needed to fully wet the cement, sand and coarse aggregate to be used in the batch is loaded into a Ready-mix. The cement mix, coarse aggregate and sand are mixed together and loaded into the Ready-mix. The remaining water is then loaded into the Ready-mix.
- the amorphous silica is added and the mixture is mixed for a time in the range of from about 3 to about 15 minutes, and more preferably in the range of from about 5 to about 10 minutes; preferably at relatively high drum rotation speeds, such as, for example, a speed in the range of from about 8 to about 20 rpm, and more preferably about 12 to about 15 rpm. It is permissible to have a period of time between the higher-speed mixing and silica addition, such as transport time to the pouring site.
- the cement mixture containing the silica is preferably fully mixed before admixture addition. Once the higher-speed mixing has occurred, the admixture can then be added, such as to the Ready-mix. Once the silica has been added to the mix and fully combined, it is preferable to add the admixture to the batch within 30 minutes, more preferably, within 20 minutes, and even more preferably within 10 minutes.
- the admixture-containing mixture can then be mixed at speeds in the range of from about 1 to about 18 rpm, for a time in the range of from about 2 to about 20 minutes.
- the amorphous silica is added after the mixing together of the dry components and the water (regardless of whether the water is added in one portion or 2 or more portions), within about 60 minutes of the batching (i.e., complete mixing) of the water and other concrete components;
- the silica-containing mixture is mixed at relatively high drum rotation speeds (such as, for example, one or more speeds in the range of from about 8 to about 20 rpm for a time in the range of from about 3 to about 15 minutes;
- the admixture is added to the silica-containing mixture and the resulting mixture is mixed at one or more speeds in the range of above about 1 rpm, for a time in the range of from about 2 to about 20 minutes, which preferably includes a period of time of at least 1 minute, but as long as 18 minutes, or even longer, at a speed of above about 10 rpm, and more preferably in the range of from about 12 rpm to about 15 rpm; and
- the abrasion resistance of the concrete formed from the inventive compositions and methods is generally increased with respect to concrete which is formed from standard methods and compositions (i.e., prepared without added amorphous silica and the admixture).
- subjecting the inventive concrete to abrasion-resistance test ASTM C944 generally gives a smaller weight loss resultant than standard concrete prepared substantially the same way, but in the absence of the amorphous silica and the admixture.
- standard concrete has a higher abrasion loss than the concrete of the present invention.
- the standard concrete of Example 3 exhibits an abrasion loss of 1.1 grams, whereas concrete formed from the compositions and by the methods of the present invention gives a loss of 0.6 grams.
- concrete of the present invention can give abrasion losses which are reduced with respect to standard concrete by as much as fifty percent or even more.
- standard concrete it is meant concrete prepared by comparable methods, components, and component proportions, but without the addition of the disclosed amorphous silica and the disclosed admixture.
- the finishing of concrete for inside use generally involves three successive steps after a poured slab begins to cure: floating, combination and a final finishing step. Each is undertaken at specific curing stages, and the ascertainment of when to commence each step is within the skilled judgement of the practitioner. Because many or most slabs are often the first element of new construction, the outside elements, such as temperature, relative humidity and wind speed play a role in the determination.
- the use of a specific type of amorphous silica in the context of a specific process for preparing the concrete, minimizes many of the outside element effects on curing.
- the standard three-step finishing process is much easier, with each step often requiring less energy, and less risk of concrete damage during finishing.
- all three are generally required to get the standard finish on the concrete of construction slabs, which are the basis for most home and commercial construction.
- floating is generally easier than with standard concrete due to the excellent water retention properties of the concrete described infra.
- Floating can be done by methods known in the art, such as, for example, hand trowel, walk behind, power ride-on trowel, or with use of 36, 48 or 60-inch pans or float shoes.
- hand trowel walk behind
- power ride-on trowel or with use of 36, 48 or 60-inch pans or float shoes.
- the combination step is then generally performed as known in the art, such as by, for example, a ride on power trowel or walk behind trowel with combination blades. It is during this step that the plastic-like nature of the surface generally becomes more apparent and pronounced.
- the surface is generally distinctly different from the surface developed during combination by concretes which do not contain both the following; 1) the inventive amorphous silica amounts, particle sizes and surface areas as disclosed herein, and 2) the inventive admixture formulations as disclosed herein.
- the effect has been described by the inventors as“plastic-like.”
- the surface develops a smoother appearance, which generally increases, to a degree, with combination time, the surface having a reduced incidence of large pores, as well as improved flatness, when compared to widely-used concrete formulations at like stages of finishing that lack the inventive formula and process details as disclosed herein.
- plastic-like it is meant that the surface at least has the appearance of, a coating, said coating generally not of high clarity during combination, being occluded to a degree which can be decreased, to a degree, with the progress of combination and/or increasing combination blade speed. At later times during combination, it may or may not take on the glassy texture and even greater clarity as with later finishing steps.
- the use of higher combination speeds (above about 190 rpm) than used with traditional concrete may give an improved finish with respect to clarity and glossiness, but not necessarily.
- the finishing step can then be performed.
- the methods known in the art can be used, such as, for example, a ride on power trowel or walk behind trowel with finishing blades.
- Those who have worked with the inventive concretes indicate that with the finishing step, the surface increasingly takes on glassy characteristics, such as a clarity which is increased over concretes known in the art and prepared in the same fashion, although not as clear as can generally be obtained with a burnishing step.
- a clarity is a consequence of the retention of moisture in the concrete surface, attributable to the inventive inclusion of silica as disclosed herein.
- the clarity, gloss and flatness achievable after the finishing step is generally enough to qualify as a“Grade 1” finish.
- the finishing step does not necessarily give this glassiness, i.e., heightened clarity and/or glossiness, with traditional top finishing speeds of about 190 rpm.
- finishing machines are limited to a top speed of about 190 rpm, but some older machines can attain top speeds of about 220 rpm.
- One characteristic often seen with the use of either the admixture or topical use of the inventive formulations is that the use of higher finishing blade speeds (such as, for example, 200-220 rpm) than traditionally used (such as, for example, 180-200 rpm) can improve the finish over that achievable at traditional speeds, such that the surface takes on yet greater glossiness and clarity than that achievable at lower speeds.
- the surface thereby achieved is often still a“Grade 1” finish, but with an increased clarity and gloss with respect to surfaces of the invention which have not been finished at such increased speeds.
- such clarity enhancement at higher speeds is specific to concrete surfaces of the present invention.
- the time of finishing is until the surface has the desired appearance. For example, two passes may be necessary in order to observe a finish having superior clarity, glossiness and flatness. It should be noted that the finish can take on a more matte appearance during the combination step, which, if desired can be retained by not performing the final finishing step. In order to obtain a finish having a more glass-like appearance and texture, it is generally necessary to proceed to the final finishing stage.
- Finishing can be done to various grades, based upon the desired glossiness and clarity of the concrete surface. Finishing with a finishing machine, as described above and as performed in the industry, at top speeds of 190 rpm, generally results in a“Grade 1” finish, as is well-known in the art. Further elevations in the quality of the surface, i.e., heightened gloss and clarity, can generally be achieved with the use of a burnishing machine, also well-known in the art, in order to develop a“Grade 2” or“Grade 3” finish. One of skill in the art can generally ascertain the grade of a finish by visual inspection of the finished surface.
- floor burnishing machines operate at much higher speeds (rpm) than finishing machines, it has heretofore been necessary to wait for some time after completion of finishing, such as at least about three or four days, and as long as 28 days or even longer, before using a burnishing machine on a finished surface. It is known in the art that earlier use generally risks significant damage, such as scratching (can go quite deep: 2-4 mm) and exposed aggregate, to the finished surface.
- concrete which has been prepared with amorphous silica, as disclosed and described herein, as well as the admixture or topical finishing use of the formulations disclosed and described herein, can be burnished immediately after finishing, if desired, without damage to the concrete surface.
- concrete which has been prepared with the amorphous silica as described herein or in US Provisional Application 62/761,064 (incorporated by reference and included herein), and additionally having been prepared with the admixture use of the Korkay- or E5 Finish-containing formulations described herein, can be burnished immediately after the finishing step without damaging the surface of the concrete.
- Fig. 1 depicts a concrete slab containing 4 oz per hundred weight E5 Internal Cure, with E5 Finish used topically as a finish at rates of 1000 square feet per gallon. The burnishing process was initiated directly after the conclusion of the finishing step.
- Fig. 1 shows the undamaged surface, despite the fact that the 27-inch burnisher is being run at 2500 rpm.
- Fig. 2 shows the conversion of the surface from approximately Grade 1 to approximately Grade 2 While both Figures correspond to a topical use of the cutter, the effect is visually indistinguishable from that seen in the case of admixture use of the cutter.
- Burnishing machines generally come in three sizes (17, 20- and 27-inch diameter) with the larger diameter machines reaching speeds as high as 2500 rpm. Generally, the higher speeds give better clarity and gloss.
- One remarkable feature of the present invention is that concretes prepared by traditional methods generally require the application of a guard or sealer prior to burnishing in order to attain the Grade 2 or Grade 3 quality of glossiness, with a wait as long as 28 days often required before burnishing can be commenced. Concretes of the present invention can be burnished immediately following finishing without the application of guards or sealers, without damaging the concrete surface.
- finishing and burnishing steps cause the amorphous silica to react with the topical or admixture formulation to create a glassy substance or phase, with a more complete reaction associated with higher finishing machine and burnishing machine rpms. It has also been observed that, as with the finishing step, less friction is present between the machine and the floor, giving lower RA (Roughness Average) numbers and increased burnishing pad lifetimes.
- the number of burnishing passes utilized is generally simply what is required to achieve the clarity and glossiness.
- the number of passes required to transform a Grade 1 finish to a Grade 2 finish could be as low as 3-4 or as high as 4-20.
- approximately 20 minutes of high-speed burnishing may be required to transform a Grade 1 to a Grade 2. It has been noticed that if the floor does not develop a gloss during finishing, it is unlikely to burnish.
- waiting some time after finishing, such as, for example, from 1-24 hours, or more, to commence burnishing may, in some circumstances, give better clarity upon burnishing.
- the concrete mix is formed and agitated in the context of an industrial scale pour, such as the preparation of footings or slabs.
- the concrete mix is created with and within equipment which holds the mix as it is being created, and which also has the capacity to agitate the mix, such as, for example, a Ready- mix.
- An advantage of the present inventive process is that water in concrete formation, such as for example, a slab, formulated according to the present invention, appears to be immobilized in the formation rather than lost to evaporation. The likely fate of much of this water is to participate in hydration at extended periods of time rather than form capillaries and voids. Thus, it is expected that, regardless of thickness, concrete slabs, walls and other formations will display a reduction or lack of voids and capillaries, and a correlative gain in compressive strength. Concrete formation having improved structure and compressive strength with thicknesses up to about 20 feet can be formed with the concrete of the present invention.
- An advantage of the present inventive process is that poured concrete are less damaged by drying caused by environmental conditions, such as temperature, relative humidity and air motion such as wind.
- concrete of good quality can be produced at wind speeds as high as 50 mph, temperatures as high as l20°F and as low as l0°F, and relative humidities as low as 5% and as high as 85% or even higher.
- the compressive strength of the concrete formed by the method of the present invention is generally increased with respect to concrete formed by methods which are similar or, preferably, the same save for the addition of silica after the mixing of the water, cement mix and filler materials (aggregate, sand and the like).
- Similar or“the same” applies to environmental conditions such as wind speed, relative humidity and temperature profile, as well as other environmental factors, such as shading or heat radiating surroundings with respect to the assessment of increase in compressive strength. Factors within the pourer’s control, such as mixing times and parameters, pouring parameters (i.e., slab dimensions) are more easily accounted for.
- An increase in compressive strength is preferably assessed from pours which are identical except for the addition of the amorphous silica. In a preferred embodiment, the assessment is made from pours which are prepared from identical amounts of identical ingredients, simultaneously but in separate Ready- mixes, poured side-by-side, at the same time, but using separate Ready-mixes. Such pours are “substantially identical.”
- the increase in compressive strength can be in the range of from about 5 to about 40% or even more, based upon the compressive strength of the non-silica-containing pour of a pair of substantially identical pours. In more commonly observed embodiments, the compressive strength increase as assessed through substantially identical pours is in the range of from about 10 to about 30%.
- the concrete of the present invention can generally be used in applications which require poured concrete, such as, for example, slabs, footings, and the like.
- An advantage of the present invention is that the concrete prepared therefrom is generally of increased resistance to water penetration, and can thus be used in poured applications which are particularly prone to moisture exposure and the associated damage, such as footings.
- the present invention includes the discovery that nanosilica, when added to a concrete mix, preferably as a colloidal silica, after the addition of at least a portion of water, gives a cement having an improved compressive strength among other improved properties, such as abrasion resistance and water permeability.
- the additive concrete components such as sand and aggregates of sizes which are used in the art can generally be used in the concrete of the present invention without destroying the benefits provided by the present invention.
- a concrete comprising of ample water for hydration, pouring and working, in the preparation of concrete which generally lacks the deficiencies otherwise associated with concrete from concrete having high amounts of water of transport.
- the inventive compositions result in concrete which retains water such that exposed surfaces are less likely to dry prematurely than concrete which have not had amorphous silica added.
- the relative water retention effect is observed even in ambient conditions under which the surface would ordinarily be predisposed to desiccate. Concrete can thus be poured under a broader range of environmental conditions than standard concrete. Surfaces can thus be finished with reduced amounts of surface water, or even, in some cases, without adding surface water.
- Shrinkage is generally reduced with respect to concrete containing comparable amounts of water. More remarkably, the compressive strength is increased. This result is generally obtained even though the concrete contains amounts of water of transport that would risk capillary and void formation in absence of amorphous silica.
- the amorphous silica may immobilize the water during curing such that the water is prevented from migrating, retarding evaporation as well as capillary and void formation. Surprisingly, the immobilization does not prevent the water from participating in long term, extended hydration, which gives the unexpected increase in compressive strength.
- An overarching benefit of the present invention is the ability not to use excess water in the curing reaction (hydration) due to generally losing the water to evaporation. Such a benefit can be obtained even in the case of concrete which are poured having water levels which are less than theoretically required for full hydration of the concrete, as well as at water levels which are in excess of that theoretically required for hydration.
- a problem with existing concrete preparation and pour processes is the risk taken when a pour is done in less than optimum conditions. As indicated infra, relative humidity, wind speed and temperature, among other environmental factors, routinely compromise standard pours because of their effect on the water levels at various locations on and within the concrete.
- the present invention enables the operation at the cement manufacturer’s suggested water contents with a reduced risk of water-related issues. These suggested values generally correspond to the amount of water which would be required to enable the hydration reaction to proceed to an acceptable degree, or in some cases, to completion. In the practice of this invention, use of water in the amounts specified by the cement manufacturer is preferred. However, the present invention also reduces the risk of water issues with respect to other processes even when the water content deviates from that specified by the manufacturer.
- the water content is within the range of from about -30% of the lowest value specified by the manufacturer specifications and +30% of the greatest value specified by the manufacturer specifications, based upon the weight of the water added to the cement before the addition of the colloidal amorphous or other silica described herein.
- Yet another benefit of the present invention follows from the ability of formulations thereof to retain Tvater for the benefit of extended hydration without the formation of capillaries and void reservoirs.
- aggregate, sand and other commonly included bulking and strengthening materials to cement to form concrete generally require additional water to accommodate them in the concrete and can actually promote the formation of capillaries and, especially, void reservoirs.
- Such reservoirs are associated with and located in relation to the surfaces of the included materials.
- the most preferred aggregates and materials are of a quality such that they associate closely with the concrete over their surface areas such that during hydration, reservoir formation is minimized, as is the associated loss of compressive strength.
- high-quality included materials are generally uneconomical.
- amorphous silica particles can reduce or prevent the formation of void reservoirs and capillaries.
- the reduction of such imperfections, particularly void reservoirs, and the associated increase in compressive strength tends to indicate that the high surface area amorphous silica particles are participating in a direct association with the included material, regardless of material suboptimal quality. This association may exclude water and strengthen the attachment of the concrete to the included material.
- concrete formulations prepared thereof can be pourable and/or workable without the use of so-called“superplasticizers”.
- superplasticizers include ligninsulfonate, sulfonated naphthalene formaldehyde polycondensates, sulfonated melamine formaldehyde polycondensates, polycarboxylate ethers and other superplasticizer components whether they are emulsions, dispersions, powders or other chemical forms.
- the concrete formulations of the present invention are pourable without the inclusion of superplasticizers and are superplasticizer-free or essentially superplasticizer-free.
- “essentially superplasticizer-free” it is meant that the superplasticizer content is in trace amounts of less than about 0.1% based upon the weight of the cement.
- the concrete mixture of the present invention can be free of any or all of the below additives, or of other additives.
- the list below is ordered as per ASTM C 494 categories. Included are admixtures that are certified and not certified by ASTM C-494.
- Admixtures can be added as a powder or liquid.
- Nominal dosage range 0.25 - 5 GAL / YD • MVRA (Moisture vapor-reducing admixtures)
- Nominal dosage range 0.1 - 20 LB/ YD
- the pour was started at approximately 7:00 am, and the finishing was completed at 1 :00 pm.
- the mixture was mixed (in a concrete drum that has a high speed of 12-15 RPM for mixing of the concrete) for an additional time of 5-10 Minutes.
- the driver was ready to transport the concrete to the job location, he then slowed the concrete barrel to 3-5 RPM.
- 6-A concrete walk behind trowel machine was used to perform the panning (floating) process.
- the pan speed of the floating process was 80-130 revolutions per minute. The process is performed for an hour and a half, at which time, the surface texture of the slab indicated that it was ready for the next power ride on trowel.
- the finisher extremely experienced in concrete pouring and finishing, noted the low friction, commenting that“it felt like I was finishing on a ball bearing surface, with practically no resistance on the machine.” As known in the art, and ascertainable by one of skill in the art, a dull haze which would be identifiable to one of skill in the art. indicated that the surface was ready for the finishing step.
- Footings are a common use of poured concrete in the construction industry.
- the poured concrete is generally subject to constant moisture exposure due to soil contact while curing. Such constant contact can also provide a source of moisture in the case of the cured concrete.
- a footing was poured to observe the characteristics of concrete poured under such conditions. The intent was to observe the density of the resulting concrete (i.e., lack of capillaries and voids) in the footing and to determine if concrete strength was affected.
- the mixture was then mixed at a high speed of 12-15 RPM for an additional tipie of 5-10 Minutes.
- the driver then slowed the concrete barrel to 3-5 RJPM and drove 5-10 minutes to the test pour site.
- the E5 Finish was then added to the ready-mix truck at a rate of 3 oz per hundred weight of cement.
- the drum speed is increased to about 12-15 RPM for about 5-10 minutes, and the mixture is poured.
- ASTM C39 ⁇ Cl23 l cylinder compression break results indicated that the compression strength met or exceeded 30,000 psi at 28 days, with 25% or more of that obtained by 7 days.
- the start time of the pour was 07:30AM with a starting temperature of approximately 60°F.
- the ambient temperature peaked in the high 80s during the day.
- the relative humidity ranged from 18% to 67%.
- the wind speed range was from 3 to 18 mph.
- the mixture was mixed (in a concrete drum at 12 - 15 RPM for an additional time of 5 - 10 Minutes.
- the driver was ready to transport the concrete to the job location, he then slowed the concrete barrel to 3 -5 RPM’s.
- the time of transport to the pour site was about 5-10 min.
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
Abstract
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JP2021537026A JP2021536390A (en) | 2018-09-01 | 2019-09-03 | Abrasion resistant concrete formulations and their preparation methods |
BR112021003754-3A BR112021003754A2 (en) | 2018-09-01 | 2019-09-03 | wear-resistant concrete formulations and methods for their preparation |
EP19853955.3A EP3844122A4 (en) | 2018-09-01 | 2019-09-03 | Wear resistant concrete formulations and methods for their preparation |
KR1020217009125A KR20220004004A (en) | 2018-09-01 | 2019-09-03 | Wear-resistant concrete formulations and methods of making them |
AU2019330229A AU2019330229A1 (en) | 2018-09-01 | 2019-09-03 | Wear resistant concrete formulations and methods for their preparation |
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JP (1) | JP2021536390A (en) |
KR (1) | KR20220004004A (en) |
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EP0269015A3 (en) * | 1986-11-21 | 1989-03-01 | HENKEL CORPORATION (a Delaware corp.) | Sag resistant dry set mortar composition |
SE9603418D0 (en) * | 1996-09-19 | 1996-09-19 | Eka Chemicals Ab | A method of preparation of a hardening composition |
TW527332B (en) * | 2000-05-19 | 2003-04-11 | Akzo Nobel Nv | Composition and method to prepare a concrete composition |
FR2880015B1 (en) * | 2004-12-27 | 2007-02-23 | Francais Ciments | CEMENTITIOUS COMPOSITION COMPRISING A LOCK-UP AGENT AND ITS USE IN PARTICULAR FOR THE MANUFACTURE OF LIQUID CAPS |
FR2901268B1 (en) * | 2006-05-17 | 2008-07-18 | Lafarge Sa | CONCRETE WITH LOW CEMENT CONTENT |
NL2008605C2 (en) * | 2012-04-05 | 2013-10-09 | Cdem Minerals Group B V | Concrete and mortar pre-mixture. |
US20160107939A1 (en) * | 2014-04-09 | 2016-04-21 | Carboncure Technologies Inc. | Methods and compositions for concrete production |
EP3094460A4 (en) * | 2014-01-17 | 2017-10-04 | Multiquip, Inc. | Addition of colloidal silica to concrete |
US10494300B2 (en) * | 2015-01-16 | 2019-12-03 | New Technology Solutions, Llc | Concrete compositions and method for making same |
ES2610511B2 (en) * | 2015-09-25 | 2017-10-09 | Consejo Superior De Investigaciones Científicas (Csic) | PROCEDURE TO PREPARE A MICRO-NANOESTRUCTURED COMPOSITE CEMENTICEO, MORTARS AND CONCRETE LONG-TERM CONCRETE, UNDERSTANDING THAT COMPOSITE |
EP3762345A4 (en) * | 2018-03-09 | 2022-01-26 | Dustin A. Hartman | Novel compositions for improved concrete performance |
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KR20220004004A (en) | 2022-01-11 |
BR112021003754A2 (en) | 2021-05-25 |
EP3844122A4 (en) | 2022-09-28 |
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