WO2020021193A1 - Method for the production and purification of 2-chloro-1,1,1,2-tetrafluoropropane - Google Patents

Abstract

The present invention relates to a method for the purification of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) using a first composition comprising 2-chloro-1,1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene, said method comprising the steps of: (a) bringing the first composition into contact with at least one organic extraction agent in order to form a second composition; (b) extractively distilling the second composition in order to form (i) a third composition comprising the organic extraction agent and 2-chloro-3,3,3-trifluoropropene and (ii) a stream comprising 2- chloro-1,1,1,2-tetrafluoropropane; and (c) recovering and separating the third composition in order to form a stream comprising the organic extraction agent and a stream comprising 2-chloro-3,3,3-trifluoropropene.

Description

 Process for the production and purification of 2-chloro-1.1.1.2-tetrafluoropropane

Technical field of the invention

 The present invention relates to a process for the production and purification of 2-chloro-1,1,1,2-tetrafluoropropane. The present invention also relates to a process for producing 2,3,3,3-tetrafluoropropene from purified 2-chloro-1,1,1,2-tetrafluoropropane according to the present invention.

Technological background of the invention

 Halogenated hydrocarbons, in particular fluorinated hydrocarbons such as hydrofluoroolefins, are compounds which have a useful structure as functional materials, solvents, refrigerants, blowing agents and monomers for functional polymers or starting materials for such monomers. Hydrofluoroolefins such as 2,3,3,3-tetrafluoropropene (HFO-1234yf) attract attention because they offer promising behavior as refrigerants with low global warming potential.

 The processes for producing fluoroolefins are usually carried out in the presence of a starting material such as an alkane containing chlorine or an alkene containing chlorine, and in the presence of a fluorinating agent such as hydrogen fluoride. These processes can be carried out in the gas phase or in the liquid phase, with or without the catalyst.

 In particular, 2,3,3,3-tetrafluoropropene can be obtained by dehydrochlorination of 2-chloro-l, l, l, 2-tetrafluoropropane (HCFC-244bb), the latter itself being obtained by fluorination of 2- chloro-3,3,3-trifluoropropene (HCFO-1233xf). At the end of the fluorination reaction of 2-chloro-3,3,3-trifluoropropene to 2-chloro-l, l, l, 2-tetrafluoropropane, a step of separation of 2-chloro-l, l, l , 2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene is necessary to recycle in the reaction step 2-chloro-3,3,3-trifluoropropene not converted into 2-chloro-1,1,1 , 2-tetrafluoropropane and to reduce the impurity contents of 2,3,3,3- tetrafluoropropene obtained after dehydrochlorination of 2-chloro-1,1,1,2,2-tetrafluoropropane. Indeed, 2-chloro-3,3,3-trifluoropropene is a precursor of trifluoropropyne, a toxic compound which is difficult to separate from 2,3,3,3-tetrafluoropropene.

Consequently, there is a need to efficiently separate 2-chloro-1,1,1,2-tetrafluoropropane from 2-chloro-3,3,3-trifluoropropene to improve the economy of the process, and thus be able to obtain in fine 2,3,3,3-tetrafluoropropene of higher purity. However, it is known from US2009 / 0242832 that 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane form an azeotrope, even in the presence of hydrofluoric acid (W02011 / 126620). The formation of azeotropes between 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2,2-tetrafluoropropane prevents effective separation of these two compounds by conventional distillation.

 US 2010/0048961 discloses a process for the separation between 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2,2-tetrafluoropropane by solidification. Also known from WO2011 / 126620 is a separation process between 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane by azeotropic distillation via the addition of hydrofluoric acid . Also known from WO 2013/049105 and WO 2016/172413 is a process for the purification of 2-chloro-l, l, l, 2-tetrafluoropropane respectively by absorption on activated carbon and by filtration on molecular sieve with pores larger than 5Â.

 There is still a need for a simple, effective and efficient separation process between 2-chloro-3,3,3-trifluoropropene and 2-chloro-1,1,1,2,2-tetrafluoropropane.

Summary of the invention

 According to a first aspect, the present invention relates to a process for the purification of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) from a first composition comprising 2-chloro-1,1,1, 2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene, said process comprising the steps of:

 a) bringing said first composition into contact with at least one organic extracting agent to form a second composition; b) extractive distillation of said second composition to form: i) a third composition comprising said organic extractant and 2-chloro-3,3,3-trifluoropropene, ii) a stream comprising 2-chloro-1,1,1, 1,2-tetrafluoropropane;

 c) recovery and separation of said third composition to form a stream comprising said organic extractant and a stream comprising 2-chloro-3,3,3-trifluoropropene.

According to a preferred embodiment, the stream comprising the organic extraction agent separated in step c) is recycled in step a). According to a preferred embodiment, said stream comprising 2-chloro-1,1,1,2-tetrafluoropropane formed in step b) is recovered at the top of the distillation column and used optionally in a process for producing 2, 3,3,3-tetrafluoropropene.

 According to a preferred embodiment, the stream comprising 2-chloro-3,3,3-trifluoropropene formed in step c) is recovered at the top of the distillation column and optionally recycled in a process for producing 2-chloro-1 , 1,1,2-tetrafluoropropane.

 According to a preferred embodiment, said organic extractant is a solvent chosen from the group consisting of hydrocarbon, hydrohalocarbon, alcohol, ketone, amine, ester, ether, aldehyde, nitrile, carbonate, phthalate, sulfate, thioalkyl amide, sulfoxide , heterocycles, preferably said organic extractant is an amine.

 According to a preferred embodiment, said organic extraction agent has a boiling point between 30 ° C and 200 ° C.

According to a preferred embodiment, said organic extraction agent has a separation factor Si, 2 greater than or equal to 1.1, said separation factor being calculated by the formula Si _, 2 = (YI, S * P1) / (Y2, S * P2) in which

Yi _, s represents the activity coefficient of 2-chloro-1,1,1,2-tetrafluoropropane in said organic extraction agent with infinite dilution,

PI represents the saturated vapor pressure of 2-chloro-1,1,1,2,2-tetrafluoropropane, j2 _, s represents the activity coefficient of 2-chloro-3,3,3-trifluoropropene in said organic extractant with infinite dilution,

 P2 represents the saturated vapor pressure of 2-chloro-3,3,3-trifluoropropene;

advantageously, the separation factor Si, 2 is greater than or equal to 1.2, preferably greater than or equal to 1.3, more preferably greater than or equal to 1.4, in particular greater than or equal to 1.5, more particularly greater than or equal to 1.6, preferably greater than or equal to 1.7.

According to a preferred embodiment, said organic extraction agent has an absorption capacity C2 _, s greater than or equal to 0.20, said absorption capacity being calculated by the formula C2 _, s = l / (Y2 _, s ) in which j2 _, s represents the activity coefficient of 2-chloro-3,3,3-trifluoropropene in said organic extraction agent with infinite dilution; advantageously, the absorption capacity C2 _, s is greater than or equal to 0.40, preferably greater than or equal to 0.60, more preferably greater than or equal to 0.80, in particular greater than or equal to 1.0, more particularly greater than or equal to 1.2, preferably greater than or equal to 1.3, advantageously favorably greater than or equal to 1.4. According to a preferred embodiment, said organic extraction agent is chosen from the group consisting of diethylether, hexanal, diethylsulfoxide, isopropylamine, 2-amino-2-methylpropane, 3,3-dimethyl-2-butanone, 2,2- dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2-propylcyclohexanone, 3-pentanone, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, n-ethyl-morpholine, 1,1,3,3- tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4-methylbenzenemethanamine, ethylpropionate, 4-methyl-2- hexanamine, 4-methyl-2-hexanone, sec- butylacetate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, n-propylamine, 4-methoxy-4- methyl-pentan-2-one, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, 1- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 2,4- dimethylpyridine, 2,6-dimethylpyridine, l-me thoxy-2-acetoxypropane, 4-methylpyridine, cyclohexylamine, cyclohexanone, diethylamine, thiophene, ethoxyethanol, 2-allyloxyethanol, ethanolamine, 2-bromo-2-methylpropane, 3-pentanol, 2-hexanol, methyl-t-butylether, isopropyl- isobutyl-ether, tetrachloroethene, methylacetate;

 advantageously said organic extractant is chosen from the group consisting of 2,2-dimethoxypropane, butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 2- (dimethylamino) -ethanol, 4- methyl-2-pentanone, 1- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 1-methoxy- 2-acetoxypropane, diethylamine, ethoxyethanol, 3-pentanol, 2-hexanol, methyl-t-butylether, tetrachloroethene, methylacetate;

 preferably said organic extractant is chosen from the group consisting of butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 4-methyl-2-pentanone, diisopropylamine, diisopropylether, isopropylacetate, diethylamine , ethoxyethanol, methyl-t-butylether, tetrachloroethene, methylacetate;

 in particular said organic extraction agent is chosen from the group consisting of sec-butylacetate, 1,1-diethoxyethane, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t-butylether, tetrachloroethene;

 more particularly, said organic extraction agent is chosen from the group consisting of diisopropylamine, diisopropylether, diethylamine, 1,1-diethoxyethane, ethoxyethanol.

According to a second aspect, the present invention relates to a process for the production of 2-chloro-1,1,1,2-tetrafluoropropane comprising the steps of: A) bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid in the presence of a catalyst to form a stream Al comprising 2-chloro-1,1,1,1-2-tetrafluoropropane and 2 -chloro-3,3,3-trifluoropropene unreacted and unreacted hydrofluoric acid,

 B) purification of said stream Al obtained in step A to form a stream A2 comprising 2-chloro-l, 1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and a stream A3 comprising l hydrofluoric acid,

 C) purification of said stream A2 according to the present invention to form a stream A4 comprising 2-chloro-1,1,1,2-tetrafluoropropane.

 According to a third aspect, the present invention relates to a process for producing 2,3,3,3-tetrafluoropropene comprising the steps of:

 implementation of the process for producing 2-chloro-1,1,1,2-tetrafluoropropane according to the present invention,

 - Use of a dehydrochlorination reaction of 2-chloro-1,1,1,2-tetrafluoropropane contained in stream A4 under conditions effective to form 2,3,3,3-tetrafluoropropene.

According to a fourth aspect, the present invention relates to a composition comprising 2-chloro-1, 1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of diethylether, hexanal, diethylsulfoxide, isopropylamine, 2-amino-2-methylpropane, 3,3-dimethyl-2-butanone, 2,2- dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2- propylcyclohexanone, 3- pentanone, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, n- ethyl-morpholine, 1,1,3,3-tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4-methylbenzenemethanamine, ethylpropionate, 4-methyl-2-hexanamine, 4-methyl-2- hexanone, sec-butylacetate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6- dimethyl-5-heptenal, n-propylamine, 4-methoxy-4-methyl-pentan-2- one, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, l- (dimethylamino) - 2- propanol, diisopropylamine, diisopropylether, isopropylacetate, 2,4-dimethylpyridine, 2,6- dimethylpyridine, l-methoxy-2-acetoxypropane, 4-methylpyridine, cyclohexylamine, cyclohexanone, diethylamine, thiophene, ethoxyethanol, 2-allyloxyethanol, ethanol bromo-2-methylpropane, 3-pentanol, 2-hexanol, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate; advantageously said organic extracting agent is chosen from the group consisting of 2,2-dimethoxypropane, butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 2- (dimethylamino) -ethanol, 4- methyl-2-pentanone, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, l-methoxy-2-acetoxypropane, diethylamine, ethoxyethanol, 3-pentanol, 2-hexanol, methyl-t-butylether, tetrachloroethene, methylacetate;

preferably said organic extractant is chosen from the group consisting of butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 4-methyl-2-pentanone, diisopropylamine, diisopropylether, isopropylacetate, diethylamine , ethoxyethanol, methyl-t-butylether, tetrachloroethene, methylacetate;

in particular, said organic extraction agent is chosen from the group consisting of sec-butylacetate, 1,1-diethoxyethane, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t-butylether, tetrachloroethene;

more particularly said organic extraction agent is chosen from the group consisting of diisopropylamine, diisopropylether, diethylamine, 1,1-diethoxyethane, ethoxyethanol.

 According to a fifth aspect, the present invention relates to a composition comprising more than 99% by weight of 2-chloro-l, l, l, 2-tetrafluoropropane and less than 1% by weight of 2-chloro-3,3,3- trifluoropropene based on the total weight of the composition.

Brief description of the figures

 FIG. 1 schematically represents a process for the production and purification of 2-chloro-1,1,1,2-tetrafluoropropane according to a particular embodiment of the invention.

Detailed description of the invention

The term "hydrocarbon" as used herein refers to linear or branched alkane compounds C ₁ -C ₂₀ cycloalkane C ₃ -C ₂₀ alkene, C ₅ -C ₂₀ cycloalkene, C ₅ -C ₂₀ , C ₆ -C ₁₈ arena. For example, the term alkane refers to compounds of formula C _n H ₂ n ₊₂ in which n is between 1 and 20. The term C ₁ -C ₂₀ alkane includes, for example, pentane, heptane, octane, nonane , decane or isomers thereof. The term C ₅ -C ₂₀ alkene refers to hydrocarbon compounds comprising one or more carbon-carbon double bonds and comprising from 5 to 20 carbon atoms. The term C ₃ -C ₂₀ cycloalkane refers to a saturated hydrocarbon ring comprising from 3 to 20 carbon atoms. The term C ₆ -C ₁₈ aryl refers to cyclic and aromatic hydrocarbon compounds having 6 to 18 atoms of carbon. The term C5-C20 cycloalkene refers to cyclic hydrocarbon compounds comprising from 5 to 20 carbon atoms and comprising one or more carbon-carbon double bonds.

The term "alkyl" denotes a monovalent radical derived from an alkane, linear or branched, comprising from 1 to 20 carbon atoms. The term "cycloalkyl" denotes a monovalent radical derived from a cycloalkane comprising from 3 to 20 carbon atoms. The term "aryl" denotes a monovalent radical originating from an arene comprising from 6 to 18 carbon atoms. The term "alkenyl" denotes a monovalent radical of 2 to 20 carbon atoms and at least one carbon-carbon double bond. The term "alkynyl" denotes a monovalent radical of 2 to 20 carbon atoms and at least one carbon-carbon triple bond. The term "halogen" refers to a group -F, -Cl, -Br or -I. The term "cycloalkenyl" refers to a monovalent radical derived from a cycloalkene comprising from 3 to 20 carbon atoms. The alkyl substituents C ₁ -C ₂₀ alkenyl, C ₂ -C ₂₀ alkynyl, C ₂ -C ₂₀ cycloalkyl, C ₃ -C ₂₀ cycloalkenyl, C ₃ - C ₂₀ aryl, C ₆ -C ₁₈ may be substituted or not by one or more substituents -OH, halogen, -P (0) (OR ^a ) ₂ , -NR ^a C (0) R ^b , -C (0) NR ^a R ^b -CN, -N0 ₂ , -NR ^a R ^b , -OR ^a , -SR ^a , -C0 ₂ R ^a , -OC (0) OR ^a , -OC (0) R ^a , -C (0) H, -C (0) R ^a , -S (0) R ^a in which R ^a and R ^b are independently of each other hydrogen, unsubstituted C ₁ -C ₂₀ alkyl, unsubstituted C ₂ -C ₂₀ alkenyl, C alkynyl ₂ -C ₂₀ unsubstituted cycloalkyl, C ₃ -C ₂₀ substituted cycloalkenyl, C ₃ -C ₂₀ unsubstituted aryl, C ₆ -C ₁₈ unsubstituted. In the substituents -NR ^a R ^b , R ^a and R ^b can form with the nitrogen atom to which they are attached a saturated or unsaturated heterocycle, aromatic or not, comprising from 5 to 10 members.

The term "hydrohalocarbures" refers to compounds of the formula R ^a X where R ^a is selected from C ₁ -C ₂₀ alkenyl, C ₂ -C ₂₀ alkynyl, C ₂ -C ₂₀ cycloalkyl, C ₃ - C ₂₀ , C ₃ -C ₂₀ cycloalkenyl, C ₆ -C ₁₈ aryl and X represents a chlorine, fluorine, bromine or iodine atom. The alkyl substituents C ₁ -C ₂₀ alkenyl, C ₂ -C ₂₀ alkynyl, C ₂ -C ₂₀ cycloalkyl, C ₃ -C ₂₀ cycloalkenyl, C ₃ -C ₂₀ aryl, C ₆ -C ₁₈ may be substituted or not by one or more substituents -OH, halogen, -P (0) (OR ^a ) ₂ , -NR ^a C (0) R ^b , -C (0) NR ^a R ^b -CN, -NO ₂ , - NR ^a R ^b , -OR ^a , -SR ^a , -C0 ₂ R ^a , -OC (0) OR ^a , -OC (0) R ^a , -C (0) H, -C (0) R ^a , -S (0) R ^a in which R ^a and R ^b are as defined above.

The term "alcohol" refers to hydrocarbons or hydrohalocarbons as defined above in which at least one hydrogen atom is replaced by a hydroxyl group -OH. The term “ketone” refers to hydrocarbons comprising at least one or more carbonyl functional groups R ^c -C (O) -R ^d in which R ^c and R ^d are, independently of one another, C1- C20, C2-C20 alkenyl, C2-C20 alkynyl, C3-C20 cycloalkyl, C3-C20 cycloalkenyl, C6-C18 aryl and may or may not be substituted by one or more substituents -OH, halogen, -P ( 0) (OR ^a ) ₂ , -NR ^a C (0) R ^b , -C (0) NR ^a R ^b -CN, -N0 ₂ , -NR ^a R ^b , -OR ^a , -SR ^a , - C0 ₂ R ^a , -OC (0) OR ^a , -OC (0) R ^a , -C (0) H, -C (0) R ^a , -S (0) R ^a in which R ^a and R ^b are , R ^c and R ^d can be linked together to form, with the carbonyl group to which they are attached, a cyclic ketone comprising from 4 to 10 members, preferably from 4 to 7 members. The cyclic ketone can also include one or more carbon-carbon double bonds. The cyclic ketone can also be substituted or not by one or more substituents as defined above.

The term "amine" refers to hydrocarbons comprising at least one or more amine functional groups -NR ^c R ^d in which R ^c and R ^d are as defined above, R ^c and R ^d can be linked together to form with the nitrogen atom to which they are attached an aromatic or non-aromatic heterocycle comprising from 4 to 10 links.

The term “esters” refers to compounds of formula R ^c -C (0) -0-R ^d in which R ^c and R ^d are as defined above, R ^c and R ^d being able to be linked together for forming with the ester group a ring comprising from 4 to 20 carbon atoms.

The term "ether" refers to compounds of formula R ^c -0-R ^d in which R ^c and R ^d are as defined above, R ^c and R ^d can be linked together to form with the atom of oxygen to which they are attached a heterocycle comprising from 4 to 20 carbon atoms.

 The term "aldehyde" refers to compounds comprising at least one or more functional groups -C (O) -H.

 The term "nitrile" refers to compounds comprising at least one or more functional groups -CN.

The term "carbonate" refers to compounds of the formula R ^c -0-C (0) -0-R ^d wherein R ^c and R ^d are as defined above.

The term “sulfoxide” relates to compounds of formula R ^c S (0) R ^d in which R ^c and R ^d are as defined above.

The term "sulfate" relates to compounds of formula R ^c S (0) ₂ R ^d .

The term "thioalkyl" relates to compounds of formula R ^c SR ^d in which R ^c and R ^d are as defined above. The term “amide” relates to compounds of formula R ^c C (0) NR ^e R ^d in which R ^c and R ^d are as defined above, R ^e being defined by the same substituents as R ^c , R ^c and R ^d can be linked together to form, with the amide group -C (0) N- to which they are attached, a cyclic amide comprising from 4 to 10 members, preferably from 4 to 7 members. The cyclic amide may also include one or more carbon-carbon double bonds. The cyclic amide may also be substituted or not by one or more substituents as defined above.

The term “heterocycle” designates a carbon ring comprising from 4 to 10 links, at least one of the links is a heteroatom selected from the group consisting of O, S, P and N. The heterocycle can comprise one or more carbon double bond- carbon or one or more carbon-heteroatom double bond or one or more heteroatom-heteroatom double bond. Preferably, the heterocycle can comprise 1, 2, 3, 4 or 5 heteroatoms as defined above. In particular, the heterocycle can comprise 1, 2 or 3 heteroatoms selected from oxygen, nitrogen or sulfur. Preferably, the heterocycle can be a carbon ring comprising from 4 to 6 links, of which 1, 2 or 3 links are heteroatoms selected by O or N; preferably O. The heterocycle may or may not be substituted by one or more substituents chosen from -OH, halogen, -P (0) (OR ^a ) ₂ , -NR ^a C (0) R ^b , -C (0) NR ^a R ^b -CN, - N0 ₂ , -NR ^a R ^b , -OR ^a , -SR ^a , -C0 ₂ R ^a , -OC (0) OR ^a , -OC (0) R ^a , -C ( 0) H, -C (0) R ^a , -S (0) R ^a in which R ^a and R ^b are as defined above.

 According to a first aspect, the invention relates to a process for purifying 2-chloro-l, l, l, 2-tetrafluoropropane (HCFC-244bb) from a first composition comprising 2-chloro-l, l, 1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene.

 Preferably, said method comprising the steps of:

 a) bringing said first composition into contact with at least one organic extracting agent to form a second composition; b) extractive distillation of said second composition to form:

 i) a third composition comprising said organic extractant and 2-chloro-3,3,3-trifluoropropene, ii) a stream comprising 2-chloro-1,1,1,2,2-tetrafluoropropane;

c) recovery and separation of said third composition to form a stream comprising said organic extractant and a stream comprising 2-chloro-3,3,3-trifluoropropene. Said first composition may comprise from 20% to 99.99% by weight of 2-chloro-1,1,1,2-tetrafluoropropane, advantageously from 25% to 99.9% by weight, preferably from 30% to 95% by weight, in particular from 40 to 90% by weight, more particularly from 50 to 90% by weight of 2-chloro-l, l, l, 2-tetrafluoropropane based on the total weight of the first composition.

 Said first composition can comprise from 0.01 to 80% by weight of 2-chloro-3,3,3-trifluoropropene based on the total weight of the first composition, advantageously from 0.1 to 75% by weight, preferably from 5 to 70% by weight, in particular from 10 to 60% by weight, more particularly from 10 to 50% by weight of 2-chloro-3,3,3-trifluoropropene based on the total weight of the first composition.

 Alternatively, step c) can be optional.

 Preferably, the stream comprising said organic agent is recycled in step a).

Preferably, said stream comprising 2-chloro-1,1,1,2-tetrafluoropropane formed in step b) is recovered at the top of the distillation column and used optionally in a process for producing 2,3,3, 3-tetrafluoropropene.

 Preferably, said stream comprising 2-chloro-3,3,3-trifluoropropene formed in step c) is recovered at the top of the distillation column and optionally recycled in a process for producing 2-chloro-1,1,1 2-tetrafluoropropane.

 According to a particular embodiment, said organic extraction agent is a solvent chosen from the group consisting of hydrocarbon, hydrohalocarbon, alcohol, ketone, amine, ester, ether, aldehyde, nitrile, carbonate, phthalate, sulfate, amide, thioalkyl, sulfoxide and heterocycles. Preferably, said organic extraction agent is a solvent chosen from the group consisting of hydrohalocarbon, alcohol, ketone, amine, ester and ether. In particular, said organic extractant is an amine.

 Said organic extractant refers to a compound having at least one carbon atom.

 Preferably, the hydrocarbons are selected from the group consisting of 2,2-dimethylbutane, 1,2-dimethylbenzene, 1,2,4-trimethylbenzene, 1,2,4,5-tetramethylbenzene, 3-methylpentane, isopropylbenzene, ethylbenzene, styrene, 3-methylstyrene, n-propylbenzene, 1,4-dimethylbenzene, 2,4,4-trimethyl-l-pentene, 2,2,4-trimethyl-2-pentene, 2,4-dimethylpentane, 1,3- dimethylbenzene, 1,3-diethenylbenzene, 1,3,5-trimethylbenzene, methylcyclohexane, toluene, cyclohexane, octane.

Preferably, the hydrohalocarbons are selected from the group consisting of tetrachloromethane, trichloromethane, hexachloroethane, 1,1,1-trichloroethane, iodomethane, bromoethane, chlorobromomethane, iodoethane, dichloromethane, diiodomethane, tribromomethane, 2-bromopropane, dichlorobromomethane, 2-chloropropane, 2-iodopropane, 1,1-dichloroethane, 1,1-dichloroethylene, bromotrichloromethane, trichloroacethane, trichloroacethane,

2.2-difluorotetrachloroethane, l, l, 2,2-tetrachloro-l, 2-difluoro-ethane, 1,2-dibromopropane,

2-bromobutane, 2-chlorobutane, 1,2-dichloropropane, 2,3-dichloro-l-propene, 1,1,2- trichloroethane, 1,1-dichloropropane, trichloroethene, 1,1,2,2-tetrachloroethane, l-chloro-2- methylbenzene, 1,2-dichlorobenzene, 2-fluorotoluene, l-chloro-2,4-dimethylbenzene, 2- chloro-l, 4-dimethylbenzene, 1,2,3-trichloropropane, 1,2, 3-trichloropropene, l-bromo-4- methylbenzene, l-bromo-4-chlorobenzene, l-chloro-4-methylbenzene, 1,4-dichlorobenzene,

1.2-dibromoethane, 1-bromopropane, 3-bromopropene, l-bromo-2-chloroethane, 3- chloropropene, 1,2-dichloroethane, 1-iodopropane, 2-bromopentane, l-bromo-3- methylbutane, isoamylchloride, 3- chlorotoluene, bromocyclohexane, chlorobenzene, 1-chlorobutane, 1,3-dichloropropane, perfluoroheptane, 2-bromo-2-methylpropane, 2-chloro-2-methylpropane, tetrachloroethene.

 Preferably, the alcohols are selected from the group consisting of 2-propanol, 1-octanol, propylene glycol, ethanol, propanol, 1-butanol, 1-pentanol, tert-butanol, 2-methyl-2-butanol, 2.2 -dimethyl-l-propanol, l, l, l-trichloro-2-propanol, 2-methyl-2-nitro-l-propanol, 3- methyl-3-pentanol, isobutanol, 2-chloro-l-propanol, 2 -aminopropanol, 2-butanol, 2- methylphenol, 2-aminophenol, 2-bromophenol, 2-chlorophenol, 2-amino-l-butanol, 1,3- dichloro-2-propanol, 2-ethyl-l-butanol, 2 -furanmethanol, 2- (diethylamino) -ethanol, cyclohexanemethanol, 2-ethyl-l-hexanol, 2-methyl-l-pentanol, 2-chloroethanol, glycol, 2- methyl-2,4-pentanediol, l-methoxy-2 -propanol, 2- (dimethylamino) -ethanol, 4-methyl-2- pentanol, l- (dimethylamino) -2-propanol, cyclohexanol, phenol, 2-isopropoxyethanol, 2- allyloxyethanol, 3-pentanol, 2-hexanol.

 Preferably, the ketones are selected from the group consisting of propanone,

3.3-dimethyl-2-butanone, butanone, 2-propylcyclohexanone, 2,3-heptanedione, 3-pentanone, dihydroxyacetone, 4-methyl-2-hexanone, 3-octanone, 4-methoxy-4-methyl-pentan-2- one, 2- pentanone, 4-methyl-2-pentanone, cyclohexanone.

Preferably, the amines are selected from the group consisting of aniline, isopropylamine, 2-amino-2-methylpropane, 1,2-propanediamine, n, n-diethylethylenediamine, n, n, n ', n'-tetraethylmethanediamine, n, n-dipropyl-1-propanamine, n, n-di-2-propenyl-2-propen- 1-amine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4-methylbenzenemethanamine, 4-methyl-2-hexanamine, n-propylamine, 1,2-diaminoethane, diisopropylamine, 2,4-dimethylpyridine, 2,6-dimethylpyridine, 4-methylpyridine, cyclohexylamine, diethylamine, ethanolamine.

 Preferably, the esters are selected from the group consisting of methylbenzoate, bromoaceticacidmethylester, ethylpropionate, methylacetoacetate, sec-butylacetate, isopropylchloroacetate, diethylmalonate, methylhexanoate, methylheptanoate, methylformate, isopropylacetate, dimethylmalonate, ethylacetate, n-propylate.

 Preferably, the ethers are selected from the group consisting of diethylether, 1,1-dichloro-2,2-difluoroethylmethylether, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, 2-chloro-l, l-dimethoxyethane, 1,1,3,3-tetramethoxypropane, ethoxybenzene, 1,1-diethoxyethane, chloromethoxymethane, diisopropylether, l-methoxy-2-acetoxypropane, 2- methoxyethanol, dimethoxymethane, 1,2-dimethoxyethane, ethoxyethanol, di-n-propylether, 2-ethoxy-propane, l-ethoxy-2-methylpropane, methyl-t-butylether, isopropyl-isobutyl-ether.

 Preferably, the aldehydes are selected from the group consisting of hexanal, isobutanal, methylglyoxal, 2-methylbutanal, furfural, 2,6-dimethyl-5-heptenal, 3-hydroxybutanal.

 Preferably, the nitrile is propionitrile.

 Preferably, the carbonate is diethylcarbonate.

 Preferably, the phthalate is dihexylphthalate.

 Preferably, the sulfoxides are selected from the group consisting of dimethylsulfoxide and diethylsulfoxide.

 Preferably, the sulfate is dimethyl sulfate.

 Preferably, the amides are selected from the group consisting of ethanthioamide and dimethylformamide.

 Preferably, the thioalkyls are selected from the group consisting of ethanethiol, dimethylsulfide, 2-propanethiol, tert-butylthiol, 3-mercapto-l, 2-propanediol, 1-propanethiol, m-toluenethiol, thiophene.

 Preferably, the heterocycles are selected from the group consisting of n-ethylmorpholine, 1,3,5-trioxane, 1,4-dioxane, 2,6-dimethylpyrazine.

The organic extraction agent to be used can be selected according to the compounds present in said first composition. Thus, the organic extractant can be selected according to the separation factor and the absorption capacity established for a particular composition. In addition to these two criteria, the choice of organic extracting agent can optionally be based on other commercial or environmental criteria, such as for example the cost of the organic extracting agent, its availability on the market, its toxic or flammable properties.

 In addition, according to a particular embodiment, in order to optimize the operation of the distillation columns used in step b) and c) of the present process for the purification of 2-chloro 3,3,3-trifluoropropene, the point of boiling of the organic extracting agent can be from 30 ° C to 200 ° C, preferably from 30 ° C to 190 ° C, more preferably from 40 ° C to 180 ° C, in particular 50 ° C to 160 ° C, preferably from 50 ° C to 150 ° C, advantageously preferred from 50 ° C to 140 ° C, preferentially preferred from 50 ° C to 135 ° C, particularly preferred from 50 ° C at 120 ° C.

Preferably, said organic extraction agent has a separation factor Si _{, 2} greater than or equal to 1.1, said separation factor being calculated by the formula Si _{, 2} = (Y _{I, S} * P1) / (Y _{2 , S} * P2) in which

Yi _, s represents the activity coefficient of 2-chloro-1,1,1,2-tetrafluoropropane in said organic extraction agent with infinite dilution,

PI represents the saturated vapor pressure of 2-chloro-l, l, l, 2-tetrafluoropropane, j2 _{, s} represents the activity coefficient of 2-chloro-3,3,3-trifluoropropene in said organic extractant with infinite dilution,

 P2 represents the saturated vapor pressure of 2-chloro-3,3,3-trifluoropropene.

In the present application, the saturated vapor pressure is considered for a temperature of 25 ° C. Advantageously, the separation factor Si _{, 2} is greater than or equal to 1.2, preferably greater than or equal to 1.3, more preferably greater than or equal to 1.4, in particular greater than or equal to 1.5, more particularly greater than or equal to 1.6, preferably greater than or equal to 1.7.

Preferably, said organic extraction agent has an absorption capacity C _2, s greater than or equal to 0.20, said absorption capacity being calculated by the formula C _2, s = 1 / (7 _2, s) in which 7 _2, s represents the activity coefficient of 2-chloro-3,3,3-trifluoropropene in said organic extraction agent with infinite dilution. Advantageously, the absorption capacity C _2, s is greater than or equal to 0.40, preferably greater than or equal to 0.60, more preferably greater than or equal to 0.80, in particular greater than or equal to 1.0, more particularly greater than or equal to 1.2, preferably greater than or equal to 1.3, advantageously preferably greater than or equal to 1.4. Preferably, said organic extracting agent can be selected from the group consisting of 2-propanol, 1-octanol, tetrachloromethane, diethylether, aniline, ethanol, hexanal, propanone, trichloromethane, hexachloroethane, dimethylformamide, diethylsulfoxide, propanol, 1-butanol , 1-pentanol, 1,1,1-trichloroethane, iodomethane, bromoethane, chlorobromomethane, iodoethane, ethanethiol, dichloromethane, diiodomethane, dimethylsulfide, tribromomethane, 2-bromopropane, dichlorobromomethane, 2-chloropropane, 2-iodopropane, isopropyl , 1,1-dichloroethane, 1,1- dichloroethylene, bromotrichloromethane, 2-amino-2-methylpropane, tert-butanol, tert-butylthiol, 2,2-dimethylbutane, 2-methyl-2-butanol, 2,2-dimethyl -l-propanol, trichloroacetaldehyde, 3,3-dimethyl-2-butanone, l, l, l-trichloro-2-propanol, pentachloroethane, trichloroacetylchloride, 2,2-difluorotetrachloroethane, 1,1,2,2-tetrachloro- 1 , 2-difluoro-ethane, l, l-dichloro-2,2-difluoroethylmethylether, 2-met hyl-2-nitro-l-propanol, 3- methyl-3-pentanol, 2,2-dimethoxypropane, dimethylsulfate, 1,1,1-triethoxyethane, 1,2- dibromopropane, 2-bromobutane, isobutanol, isobutanal, 2- chlorobutane, 1,2- dichloropropane, 2,3-dichloro-l-propene, 2-chloro-l-propanol, 1,2-propanediamine, 2- aminopropanol, 2-butanol, butanone, methylglyoxal, 1,1,2- trichloroethane, 1,1- dichloropropane, trichloroethene, 1,1,2,2-tetrachloroethane, dihexylphthalate, methylbenzoate, 2-propylcyclohexanone, 1,2-dimethylbenzene, 2-methylphenol, l-chloro-2- methylbenzene, 1,2- dichlorobenzene, 2-fluorotoluene, 2-bromophenol, 2-chlorophenol, 1,2,4- trimethylbenzene, l-chloro-2,4-dimethylbenzene, 2-chloro-l, 4-dimethylbenzene, 1, 2,4,5- tetramethylbenzene, 2,3-heptanedione, 2-methylbutanal, 3-methylpentane, 1,2,3- trichloropropane, 1,2,3-trichloropropene, 2-amino-l-butanol, 3-pentanone, bromoaceticacidmethylester, 2-ethyl- l-butanol, 2-chloro-l, l-dimethoxyethane, furfural, 2- furanmethanol, isopropylbenzene, ethylbenzene, styrene, 2- (diethylamino) -ethanol, n, n- diethylethylenediamine, cyclohexanemethanol, n-ethyl-morpholine, 3-methylstyrene, 1, 1,3,3- tetramethoxypropane, n, n, n ', n'-tetraethylmethanediamine, n, n- dipropyl-l-propanamine, n, n- di-2-propenyl-2-propen-l-amine, n-propylbenzene, benzylmethylamine, ethoxybenzene, n, n- dimethylbenzylamine, 2-ethylhexylamine, 2-ethyl-l-hexanol, diethylaminopropylamine, 4- methylbenzenemethanamine, 2-methyl-l-pentanol, ethylpropionate, 4-methyl-2-hexanamine, 4-methyl-2-hexanone, methylacetoacetate, sec-butylacetate, isopropylchloroacetate, diethylmalonate, 1,1-diethoxyethane, diethylcarbonate, l-bromo-4-methylbenzene, 1-bromo-4-chlorobenzene, 1,4-dimethylbenzene, l-chloro-4-methylbenzene, 1,4-dichlorobenzene, 3- octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl- 5-heptenal, 1,2-dibromoethane, 1-bromopropane, 3-bromopropene, 1-propanethiol, l-bromo-2-chloroethane, 3-chloropropene, 1,2-dichloroethane, 1-iodopropane, n-propylamine, propionitrile, chloromethoxymethane, methylformate, 2,4,4- trimethyl-l-pentene, 2,2,4-trimethyl-2-pentene,

2-methyl-2,4-pentanediol, 4-methoxy-4-methyl-pentan-2-one, 2-bromopentane, l-bromo-3- methylbutane, isoamylchloride, 2-pentanone, 3-hydroxy-butanal, l- methoxy-2-propanol, 2- (dimethylamino) -ethanol, 2,4-dimethylpentane, 4-methyl-2-pentanone, 4-methyl-2-pentanol, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 1,3-dimethylbenzene, m-toluenethiol, 3-chlorotoluene, 2,4-dimethylpyridine, 2,6-dimethylpyridine, 2,6-dimethylpyrazine, dimethylmalonate, 1,3-diethenylbenzene, l-methoxy-2-acetoxypropane, 1,3,5-trimethylbenzene, bromocyclohexane, methylcyclohexane, toluene, 4-methylpyridine, chlorobenzene, cyclohexylamine, cyclohexanol, cyclohexanone, phenol, 2-isopropoxyethanol,

1-chlorobutane, 2-methoxyethanol, dimethoxymethane, diethylamine, thiophene, n-propylformate, 1,2-dimethoxyethane, ethoxyethanol, cyclohexane, 1,3,5-trioxane, di-n-propylether, 2-allyloxyethanol, octane, 1, 4-dioxane, ethanolamine, perfluoroheptane, 2-bromo-

2-methylpropane, 2-chloro-2-methylpropane, 3-pentanol, 2-ethoxy-propane, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, ethylacetate, methyl acetate.

According to a preferred embodiment, the second composition can comprise 2-chloro-1,1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and said organic extractant. To separate the first composition comprising 2-chloro-1,1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene, an organic extracting agent having a separation factor Si greater than or equal to 1, 1 and an absorption capacity C _, s greater than or equal to 0.2 can be used; said organic extraction agent can be selected from the group consisting of 2-propanol, 1-octanol, tetrachloromethane, diethylether, aniline, ethanol, hexanal, propanone, trichloromethane, hexachloroethane, dimethylformamide, diethylsulfoxide, propanol, 1-butanol, 1- pentanol, 1,1,1-trichloroethane, iodomethane, bromoethane, chlorobromomethane, iodoethane, ethanethiol, dichloromethane, diiodomethane, dimethylsulfide, tribromomethane, 2-bromopropane, dichlorobromomethane, 2-chloropropane, 2-iodopropane, isopropylamine 1-dichloroethane, 1,1- dichloroethylene, bromotrichloromethane, 2-amino-2-methylpropane, tert-butanol, tert-butylthiol, 2,2-dimethylbutane, 2-methyl-2-butanol, 2,2-dimethyl-l- propanol, trichloroacetaldehyde, 3,3-dimethyl-2-butanone, l, l, l-trichloro-2-propanol, pentachloroethane, trichloroacetylchloride, 2,2-difluorotetrachloroethane, 1,1,2,2-tetrachloro- 1,2-difluoro-ethane, l, l-dichloro-2,2-difluoroethylmethylether, 2-methyl-2-nitro-l-propanol, 3- methyl-3-pentanol, 2,2-dimethoxypropane, dimethylsulfate, 1, 1,1-triethoxyethane, 1,2- dibromopropane, 2-bromobutane, isobutanol, isobutanal, 2-chlorobutane, 1,2- dichloropropane, 2,3-dichloro-l-propene, 2-chloro-l-propanol, 1, 2-propanediamine, 2- aminopropanol, 2-butanol, butanone, methylglyoxal, 1,1,2-trichloroethane, 1,1- dichloropropane, trichloroethene, 1,1,2,2-tetrachloroethane, dihexylphthalate, methylbenzoate, 2-propylcyclohexanone, 1,2-dimethylbenzene, 2-methylphenol, l-chloro-2- methylbenzene, 1,2-dichlorobenzene, 2-fluorotoluene, 2-bromophenol, 2-chlorophenol, 1,2,4- trimethylbenzene, l-chloro-2, 4-dimethylbenzene, 2-chloro-l, 4-dimethylbenzene, 1, 2,4,5- tetramethylbenzene, 2,3-heptanedione, 2-methylbutanal, 3-methylpentane, 1,2,3- trichloropropane, 1,2, 3-trichloropropene, 2-amino-l-butanol, 3-pentanone, bromoaceticacidmethylester, 2-ethyl-l-butanol, 2-chloro-l, l-dimethoxyethane, fu rfural, 2- furanmethanol, isopropylbenzene, ethylbenzene, styrene, 2- (diethylamino) -ethanol, n, n- diethylethylenediamine, cyclohexanemethanol, n-ethyl-morpholine, 3-methylstyrene, 1, 1,3,3- tetramethoxypropane, n, n, n ', n'-tetraethylmethanediamine, n, n-dipropyl-l-propanamine, n, n- di-2-propenyl-2-propen-l-amine, n-propylbenzene, benzylmethylamine, ethoxybenzene, n, n- dimethylbenzylamine, 2-ethylhexylamine, 2-ethyl-l-hexanol, diethylaminopropylamine, 4- methylbenzenemethanamine, 2-methyl-l-pentanol, ethylpropionate, 4-methyl-2-hexanamine, 4-methyl-2-hexanone, methylacetoacetate, sec- butylacetate, isopropylchloroacetate, diethylmalonate, 1,1-diethoxyethane, diethylcarbonate, l-bromo-4-methylbenzene, 1-bromo-4-chlorobenzene, 1,4-dimethylbenzene, l-chloro-4-methylbenzene, 1,4-dichlorobenzene, 3- octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, 1,2-dibromoethane,

1-bromopropane, 3-bromopropene, 1-propanethiol, l-bromo-2-chloroethane, 3-chloropropene, 1,2-dichloroethane, 1-iodopropane, n-propylamine, propionitrile, chloromethoxymethane, methylformate, 2,4,4- trimethyl-l-pentene, 2,2,4-trimethyl-2-pentene,

2-methyl-2,4-pentanediol, 4-methoxy-4-methyl-pentan-2-one, 2-bromopentane, l-bromo-3- methylbutane, isoamylchloride, 2-pentanone, 3-hydroxy-butanal, l- methoxy-2-propanol, 2- (dimethylamino) -ethanol, 2,4-dimethylpentane, 4-methyl-2-pentanone, 4-methyl-2-pentanol, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 1,3-dimethylbenzene, m-toluenethiol, 3-chlorotoluene, 2,4-dimethylpyridine, 2,6-dimethylpyridine, 2,6-dimethylpyrazine, dimethylmalonate, 1,3-diethenylbenzene, l-methoxy-2-acetoxypropane, 1,3,5-trimethylbenzene, bromocyclohexane, methylcyclohexane, toluene, 4-methylpyridine, chlorobenzene, cyclohexylamine, cyclohexanol, cyclohexanone, phenol, 2-isopropoxyethanol, 1-chlorobutane, 2-methoxyethanol, dimethoxymethane, diethylamine, thiophene, n-propylformate, 1,2-dimethoxyethane, ethoxyethanol, cyclohexane, 1,3,5-trioxane, di-n-propylether, 2-allyloxyethanol, octane, 1, 4-dioxane, ethanolamine, perfluoroheptane, 2-bromo-

2-methylpropane, 2-chloro-2-methylpropane, 3-pentanol, 2-ethoxy-propane, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, ethylacetate, methyl acetate.

Advantageously, said organic extraction agent can have a separation factor Si greater than or equal to 1.2 and an absorption capacity C _, s greater than or equal to 0.4; and be selected from the group consisting of 2-propanol, 1-octanol, tetrachloromethane, diethylether, hexanal, propanone, trichloromethane, hexachloroethane, dimethylformamide, diethylsulfoxide, propanol, 1-butanol, 1-pentanol, 1,1,1-trichloroethane, iodomethane, bromoethane, chlorobromomethane, iodoethane, ethanethiol, dichloromethane, dimethylsulfide, 2-bromopropane, dichlorobromomethane, 2-chloropropane, 2-iodopropane, isopropylamine, 2-propanethiol, 1,1-dichloroethane, 1,1- dichloroethylene, motor amino-2-methylpropane, tert-butanol, tert-butylthiol, 2-methyl-2-butanol, 2,2-dimethyl-l-propanol, trichloroacetaldehyde, 3,3-dimethyl-

2-butanone, l, l, l-trichloro-2-propanol, pentachloroethane, trichloroacetylchloride, 3-methyl-

3-pentanol, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, 1,2-dibromopropane, 2-bromobutane, isobutanol, isobutanal, 2-chlorobutane, 1,2-dichloropropane, 2,3-dichloro-l- propene, 1,2-propanediamine, 2-butanol, butanone, methylglyoxal, 1,1,2-trichloroethane, 1,1- dichloropropane, trichloroethene, 1,1,2,2-tetrachloroethane, dihexylphthalate, methylbenzoate, 2-propylcyclohexanone, 1,2-dimethylbenzene, 2-methylphenol, l-chloro-2- methylbenzene, 1,2-dichlorobenzene, 2-bromophenol, 2-chlorophenol, 1,2,4- trimethylbenzene, l-chloro-2,4-dimethylbenzene, 2-chloro-1,4-dimethylbenzene, 1, 2,4,5- tetramethylbenzene, 2,3-heptanedione, 2-methylbutanal, 3-methylpentane, 1,2,3- trichloropropene, 3-pentanone, 2-ethyl- l-butanol, 2-chloro-l, l-dimethoxyethane, isopropylbenzene, ethylbenzene, styrene, 2- (diethylamino) -ethanol, n, n- diethylethylenediamine, cyclohexanemethanol, n-ethyl-morpholine, 3-methylstyrene, 1, 1, 3,3- tetramethoxypropane, n, n, n ', n'-tetraethylmethanediamine, n, n-dipropyl-l-propanamine, n, n- di-2-propenyl-2-propen-l-amine, n-propylbenzene, benzylmethylamine, ethoxybenzene, n, n- dimethylbenzylamine, 2-ethylhexylamine, 2-ethyl-l-hexanol, diethylaminopropylamine, 4-methylbenzenemethanamine, 2-methyl-l-pentanol, ethylpropionate, 4-methyl-2-hexanamine,

4-methyl-2-hexanone, sec-butylacetate, isopropylchloroacetate, diethylmalonate, 1,1- diethoxyethane, diethylcarbonate, l-bromo-4-methylbenzene, l-bromo-4-chlorobenzene, 1,4- dimethylbenzene, l-chloro-4-methylbenzene, 1,4-dichlorobenzene, 3-octanone, methylhexanoate, methylheptanoate, 2, 6-dimethyl-5-heptenal, 1-bromopropane, 3- bromopropene, 1-propanethiol, 3-chloropropene, 1-iodopropane, n-propylamine, methylformate, 2,2,4-trimethyl-2-pentene, 2-methyl- 2,4-pentanediol, 4-methoxy-4-methyl-pentan-2-one, 2-bromopentane, l-bromo-3-methylbutane, isoamylchloride, 2-pentanone, 1- methoxy-2-propanol, 2- (dimethylamino ) -ethanol, 2,4-dimethylpentane, 4-methyl-2-pentanone, 4-methyl-2-pentanol, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 1,3-dimethylbenzene, m- toluenethiol, 3-chlorotoluene, 2,4-dimethylpyridine, 2,6-dimethylpyridine, 2,6-dimethylpyrazine, 1,3-diethenylbenzene, l-methoxy-2- acetoxypropane, 1,3,5-trimethylbenzene, bromocyclohexane, methylcyclohexane, toluene, 4- methylpyridine, chlorobenzene, cyclohexylamine, cyclohexanol, cyc lohexanone, 2- isopropoxyethanol, 1-chlorobutane, 2-methoxyethanol, dimethoxymethane, diethylamine, thiophene, n-propylformate, 1,2-dimethoxyethane, ethoxyethanol, cyclohexane, 1,3,5-trioxane, 2-allyloxyethanol, octane, 1, 4-dioxane, ethanolamine, perfluoroheptane, 2-bromo-2- methylpropane, 2-chloro-2-methylpropane, 3-pentanol, 2-ethoxy-propane, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t- butylether, isopropyl-isobutyl-ether, tetrachloroethene, ethylacetate, methylacetate.

Preferably, said organic extraction agent may have a separation factor Si greater than or equal to 1.4 and an absorption capacity C _, s greater than or equal to 0.4; and be selected from the group consisting of 2-propanol, 1-octanol, diethylether, hexanal, propanone, dimethylformamide, diethylsulfoxide, propanol, 1-butanol, 1-pentanol, isopropylamine, 2-amino-2-methylpropane, tert-butanol, 2-methyl-2-butanol, 3,3-dimethyl-2- butanone, 3-methyl-3-pentanol, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, isobutanol, 1,2-propanediamine, 2- butanol, butanone, dihexylphthalate, 2-propylcyclohexanone, 3-pentanone, 2-ethyl-l-butanol, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, cyclohexanemethanol, n-ethyl-morpholine, 1,1,3, 3-tetramethoxypropane, n, n-dipropyl-l- propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, 2-ethyl-l- hexanol, diethylaminopropylamine, 4-methylbenzenemethanamine, 2-methyl-l-pentanol, ethylpropionate, 4-methyl-2-hexanamine, 4-methyl-2-hexanone, sec-butylacetate, diethylmalonate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, n-propylamine, 2-methyl-2,4 -pentanediol, 4-methoxy-4-methyl-pentan-2- one, 2-pentanone, l-methoxy-2-propanol, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, 4-methyl-2-pentanol, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 2,4-dimethylpyridine, 2,6-dimethylpyridine, l-methoxy-2-acetoxypropane, 4- methylpyridine, cyclohexylamine, cyclohexanol, cyclohexanone, 2-isopropoxyethanol, 2- methoxyethanol, diethylamine, thiophene, ethoxyethanol, cyclohexane, 2-allyloxyethanol, octane, ethanolamine, 2-bromo-2-methylpropane, 3-pentanol, 2-ethoxy-propane, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate.

In particular, said organic extraction agent can have a separation factor Si greater than or equal to 1.4 and an absorption capacity C _, s greater than or equal to 0.6; and be selected from the group consisting of 1-octanol, diethylether, hexanal, propanone, dimethylformamide, diethylsulfoxide, isopropylamine, 2-amino-2-methylpropane, 3,3-dimethyl-2-butanone, 3-methyl-3-pentanol, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2-propylcyclohexanone, 3-pentanone, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, n-ethyl-morpholine, 1,1, 3,3-tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4-methylbenzenemethanamine, ethylpropionate, 4-methyl-2- hexanamine, 4-methyl-2- hexanone, sec-butylacetate, diethylmalonate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, n-propylamine, 2- methyl-2,4-pentanediol, 4-methoxy- 4-methyl-pentan-2-one, 2-pentanone, l-methoxy-2- propanol, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isop ropylacetate, 2,4-dimethylpyridine, 2,6- dimethylpyridine, l-methoxy-2-acetoxypropane, 4-methylpyridine, cyclohexylamine, cyclohexanone, 2-isopropoxyethanol, diethylamine, thiophene, ethoxyethanol, cyclohexane, 2- allyloxyethanol, octane, etane 2-bromo-2-methylpropane, 3-pentanol, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate.

In particular, said organic extraction agent can have a separation factor Si greater than or equal to 1.4 and an absorption capacity C _, s greater than or equal to 0.8; and be selected from the group consisting of diethylether, hexanal, diethylsulfoxide, isopropylamine, 2-amino-2-methylpropane, 3,3-dimethyl-2-butanone, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2-propylcyclohexanone, 3-pentanone, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, n-ethyl-morpholine, 1,1,3,3- tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n- dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4- methylbenzenemethanamine, ethylpropionate, 4-methyl-2-hexanamine, 4-methyl-2-hexanone, sec-butylacetate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2, 6- dimethyl-5-heptenal, n-propylamine, 4-methoxy-4-methyl-pentan-2-one, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, l- (dimethylamino ) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 2,4-dimethylpyridine, 2,6- dimethylpyridine, l-methoxy-2-acetoxypropane, 4-methylpyridine, cyclohexylamine, cyclohexanone, diethylamine, thiophene, ethoxyethanol, 2-allyloxyethanol ethanolamine, 2- bromo-2-methylpropane, 3-pentanol, 2-hexanol, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate.

More particularly, said organic extracting agent can have a separation factor Si, 2 greater than or equal to 1.4, an absorption capacity C2 _, s greater than or equal to 0.8 and a boiling temperature of 50 °. C at 150 ° C; and be selected from the group consisting of 2,2-dimethoxypropane, butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, l-methoxy-2-acetoxypropane, diethylamine, ethoxyethanol, 3-pentanol, 2-hexanol, methyl-t-butylether, tetrachloroethene and methylacetate.

Preferably, said organic extracting agent can have a separation factor Si, 2 greater than or equal to 1.4, an absorption capacity C2 _, s greater than or equal to 0.8 and a boiling point of 50 ° C to 150 ° C; and be selected from the group consisting of butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 4-methyl-2-pentanone, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t- butylether, tetrachloroethene and methylacetate.

Advantageously, said organic extraction agent can have a separation factor Si, 2 greater than or equal to 1.4, an absorption capacity C2 _, s greater than or equal to 1.2 and a boiling temperature of 50 ° C to 150 ° C; and be selected from the group consisting of sec-butylacetate, 1,1-diethoxyethane, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t-butylether, tetrachloroethene.

Preferably, said organic extraction agent can have a separation factor Si, 2 greater than or equal to 1.4, an absorption capacity C2 _, s greater than or equal to 0.8 and a boiling temperature of 50 ° C to 150 ° C; and be selected from the group consisting of diisopropylamine, diisopropylether, diethylamine, 1,1-diethoxyethane and ethoxyethanol.

In a particularly preferred manner, said organic extraction agent can have a separation factor Si greater than or equal to 1.4, an absorption capacity C _, s greater than or equal to 1.2 and a boiling temperature of 50 °. C at 150 ° C; and be selected from the group consisting of diisopropylamine, diisopropylether, diethylamine, 1,1-diethoxyethane and ethoxyethanol.

 Said first composition may be an azeotropic or quasi-azeotropic composition comprising 2-chloro-1,1,1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene. Thus, the second composition can comprise 2-chloro-1,1,1,1-2 tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and the organic extractant.

 According to a preferred embodiment, said third composition can be subjected to a distillation in order to separate on the one hand the organic extracting agent and on the other hand 2-chloro-3,3,3-trifluoropropene.

 According to a particular embodiment, the stream comprising 2-chloro-1,1,1,2-tetrafluoropropane separated in step b) of the present process is recovered at the top of the distillation column and used in a process for producing the 2,3,3,3-tetrafluoropropene. Traces of organic extractant may be present in the stream comprising 2-chloro-1,1,1,2-tetrafluoropropane. The mass content of organic extractant in said stream comprising 2-chloro-1,1,1,2-tetrafluoropropane is less than 500 ppm, advantageously less than 100 ppm, preferably less than 50 ppm, more preferably less than 10 ppm, in particular less than 5 ppm, more particularly less than 1 ppm, preferably less than 500 ppb.

 The present process therefore makes it possible to purify 2-chloro-1,1,1,1,2-tetrafluoropropane. Advantageously, the content of 2-chloro-3,3,3-trifluoropropene in the stream comprising 2-chloro-1,1,1,2-tetrafluoropropane, obtained in step b) of the present purification process is less than the content thereof or thereof in said first composition. For example, the content of 2-chloro-3,3,3-trifluoropropene can be reduced by 50%, advantageously by 75%, preferably by 90%, in particular by 95%, more particularly by 98%.

In a second aspect, a process for the production of 2-chloro-1,1,1,2-tetrafluoropropane is provided. Preferably, said method comprises the steps of: A) bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid to form a stream Al comprising 2-chloro-l, l, l, 2-tetrafluoropropane and 2-chloro-3,3 , 3- unreacted trifluoropropene and unreacted hydrofluoric acid,

 B) purification of said stream A1 obtained in step A) to form a stream A2 comprising 2-chloro-l, l, l, 2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and a stream A3 comprising l hydrofluoric acid,

 C) purification of said stream A2 according to the present process for the purification of 2-chloro-1,1,1,2-tetrafluoropropane to form a stream A4 comprising 2-chloro-1,1,1,2-tetrafluoropropane.

 Preferably, step A) is carried out in the presence of a catalyst. Preferably, step A) is carried out in the liquid phase.

When a catalyst is used, it can be a metal halide such as antimony halides, tin halides, tantalum halides, niobium halides, titanium halides or iron halides or the combination of these. For example, the catalyst can be SbCI ₅ , SbCU, SbF ₅ , SbCl _x F _y (x + y = 5), TaCI ₅ , NbCI ₅ , SnCI ₄ , TiCI ₄ , FeCU or a combination thereof. Ionic liquids can also be used. Reference may be made in particular to the catalysts described in application WO 2012/056263. Alternatively, the catalyst can be triflic or trifluoroacetic acid as mentioned in document US Pat. No. 6,166,274. Step A) can be carried out at a temperature of 30 ° C to 200 ° C, advantageously from 40 ° C to 170 ° C, preferably from 50 ° C to 150 ° C. Step A) can be carried out at a pressure greater than 2 bara, advantageously from 4 to 50 bara, preferably from 5 to 15 bara. Step A) can be carried out with a HF / HCFO-1233xf molar ratio of 1: 1 to 80: 1, advantageously from 1.5: 1 to 40: 1, preferably from 2: 1 to 20: 1 .

Step A) can also be carried out in the gas phase, preferably in the presence of a catalyst. The catalyst can be FeC 4 / C, SbF ₅ / C, SnCI ₄ / C, TiCI ₄ / C or activated carbon or a combination thereof. The catalyst can be an alkali metal halide or an alkaline earth metal halide, supported or not supported on activated carbon, washed or not. The catalyst can be composed of oxides, halides, oxyhalides and / or mineral salts of nickel, cobalt, zinc and chromium, optionally deposited on a support. In the gas phase, step A) can be carried out at a temperature of 30 ° C to 350 ° C, advantageously from 40 ° C to 300 ° C, preferably from 50 ° C to 250 ° C. Step A) can be carried out at a pressure of 1 to 15 bara, advantageously from 1 to 10 bara. Step A) can be implemented with a HF / HCFO-1233xf molar ratio of 1: 1 to 80: 1, advantageously from 1.5: 1 to 40: 1, preferably from 2: 1 to 20: 1.

 The stream Al is preferably purified to remove all or part of the hydrofluoric acid (HF) which it contains. Step B) of purification of said stream Al is carried out by absorption of HF in sulfuric acid, by absorption of HF in water, by condensation of stream Al followed by decantation at cold, by azeotropic distillation or a combination thereof. The absorption of HF in water can be carried out under conditions effective for manufacturing a concentrated solution of HF followed by distillation to obtain a stream comprising anhydrous HF and a stream comprising an azeotropic composition or quasi-azeotropic comprising hydrofluoric acid and water. Alternatively, the absorption of HF in water can be carried out under effective conditions to obtain a solution with a low concentration of hydrofluoric acid, ie a solution having a concentration of HF lower than the concentration of the azeotrope HF- water. When step B) is carried out by condensation of the stream Al followed by cold settling, the cold settling is carried out under conditions effective to obtain a phase rich in hydrofluoric acid, ie stream A3, and a phase rich in 2-chloro-1,1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene, ie current A2.

 Step B) can combine several purification techniques. For example, the condensation of stream Al followed by cold decantation, itself followed by absorption of the HF possibly contained in stream A2 in sulfuric acid or in water or followed by distillation azeotropic of current A2.

 When step B) implements the absorption of HF in water, a drying step, for example on a molecular sieve, is carried out before step C).

 Thus the stream A2 can comprise 2-chloro-1,1,1,1-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and less than 1% of HF, advantageously less than 0.5% of HF, preferably less than 0.1% HF, more preferably less than 0.05% HF, in particular less than 0.01% HF.

 Thus, the present process for producing 2-chloro-1,1,1,2-tetrafluoropropane can comprise the steps of:

A) bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid to form a stream Al comprising 2-chloro-l, 1,1,2-tetrafluoropropane and 2-chloro-3,3 , 3- unreacted trifluoropropene and unreacted hydrofluoric acid, B) purification of said stream A1 obtained in step A) to form a stream A2 comprising 2-chloro-l, l, l, 2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and a stream A3 comprising l hydrofluoric acid; Optionally drying said stream A2;

 C) purification of said stream A2 according to the following steps:

 a) bringing said stream A2 into contact with at least one organic extraction agent to form a second composition;

 b) extractive distillation of said second composition to form: i) a third composition comprising said organic extractant and 2-chloro-3,3,3-trifluoropropene, ii) a stream A4 comprising 2-chloro-l, l , 1,2-tetrafluoropropane; c) recovery and separation of said third composition to form a stream comprising said organic extractant and a stream comprising 2-chloro-3,3,3-trifluoropropene.

FIG. 1 schematically represents a process for the purification of 2-chloro-1,1,1,2-tetrafluoropropane according to a particular embodiment of the present invention. A stream 1 comprising 2-chloro-1,1,1,1-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and HF is introduced into an HF 2 recovery unit. This can be by a unit for absorbing HF in sulfuric acid or absorbing HF in water or a unit for condensing stream 1 and decanting it cold, or a unit for azeotropic distillation of stream 1 or a combination thereof. The HF recovery unit makes it possible to recover a stream 3 comprising HF which can be recycled. A stream 4 comprising 2-chloro-1,1,1,1-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene, equivalent to said stream A2 or to the first composition described above, is conveyed to a first distillation column 5. The organic extractant 13 is mixed with 2-chloro-1, 1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene in said first column distillation 5. A stream comprising 2-chloro-1,1,1,2-tetrafluoropropane is recovered at the head of distillation column 5 to be conveyed via line 6 to a device for producing 2,3,3 , 3-tetrafluoropropene 7. A stream comprising 2-chloro-3,3,3-trifluoropropene and the organic extraction agent is recovered at the bottom of distillation column 5 and conveyed via line 8 to a second distillation column 9 The second distillation column 9 makes it possible to separate the 2-chloro-3,3,3-trifluoropropene from the extraction agent o rganique. The 2-chloro-3,3,3-trifluoropropene is recovered at the top of the distillation column 9 to be conveyed, for example to a device for the production of 2-chloro-1,1,1,2-tetrafluoropropane 11 via line 10. The organic extraction agent is recovered at the bottom of distillation column 9 to be recycled to the first distillation column 5 per l line 12.

 According to a third aspect, the present invention also provides a process for the production of 2,3,3,3-tetrafluoropropene. The process includes the steps of:

 implementation of the process for producing 2-chloro-1,1,1,2-tetrafluoropropane according to the present invention;

 implementation of a dehydrochlorination reaction of 2-chloro-1,1,1,2-tetrafluoropropane contained in stream A4 under conditions effective to form 2,3,3,3-tetrafluoropropene.

 Thus, said process for producing 2,3,3,3-tetrafluoropropene comprises the steps of:

 A) bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid to form a stream Al comprising 2-chloro-l, 1,1,2-tetrafluoropropane and 2-chloro-3,3 , 3- unreacted trifluoropropene and unreacted hydrofluoric acid,

 B) purification of said stream A1 obtained in step A) to form a stream A2 comprising 2-chloro-l, 1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and a stream A3 comprising l hydrofluoric acid; Optionally drying said stream A2;

 C) purification of said stream A2 according to the following steps:

 a) bringing said stream A2 into contact with at least one organic extraction agent to form a second composition;

 b) extractive distillation of said second composition to form: i) a third composition comprising said organic extractant and 2-chloro-3,3,3-trifluoropropene, ii) an A4 stream comprising 2-chloro-1,1 , 1,2-tetrafluoropropane; c) recovering and separating said third composition to form a stream comprising said organic extractant and a stream comprising 2-chloro-3,3,3-trifluoropropene;

 D) implementation of a dehydrochlorination reaction of the 2-chloro-1,1,1,2-tetrafluoropropane contained in stream A4 under conditions effective to form 2,3,3,3-tetrafluoropropene.

Steps A) to C) are described above in connection with the first or second aspect of the present invention. Preferably, step D) is carried out in the gas phase. Of preferably, step D) is implemented at a contact time of 1 to 100 s, preferably from 2 to 75 s, in particular from 3 to 50 s. Preferably, step D) is implemented at a pressure of 1 to 20 bara, preferably from 2 to 18 bara, more preferably from 3 to 15 bara. Preferably, step D) is carried out at a temperature (of the catalytic bed) from 150 ° C to 500 ° C, preferably from 180 ° C to 450 ° C, more preferably from 200 ° C to 400 ° C . Step D) can be carried out in the presence of a catalyst, such as metal oxides, metal halides, metal oxyhalides, neutral metals or activated, bulk or supported carbon. Examples of catalysts can be found in applications US 2009/0182179, US 2009/0240090, US 2009/0312585 and US 2010/0036179, incorporated by reference.

 According to a fourth aspect of the present invention, a composition is provided. Said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extractant. Advantageously, said composition comprises 2-chloro-

1.1.1.2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of 2-propanol, 1-octanol, tetrachloromethane, diethylether, aniline, ethanol, hexanal, propanone, trichloromethane, hexachloroethane, dimethylformamide, diethylsulfoxide, propanol, 1-butanol, 1-pentanol, 1,1,1-trichloroethane, iodomethane, bromoethane, chlorobromomethane, iodoethane, ethanethiol, dichloromethane, diiodomethane, dimethylsulfide, triethyl bromide, triethyl bromide 2-chloropropane, 2-iodopropane, isopropylamine, 2-propanethiol, 1,1-dichloroethane, 1,1-dichloroethylene, bromotrichloromethane, 2-amino-2-methylpropane, tert-butanol, tert-butylthiol, 2,2-dimethylbutane, 2-methyl-2-butanol, 2,2-dimethyl-l-propanol, trichloroacetaldehyde, 3,3-dimethyl-2-butanone, l, l, l-trichloro-2-propanol, pentachloroethane, trichloroacetylchloride, 2,2- difluorotetrachloroethane, 1,1,2,2-tetrachloro-

1.2-difluoro-ethane, l, l-dichloro-2,2-difluoroethylmethylether, 2-methyl-2-nitro-l-propanol, 3- methyl-3-pentanol, 2,2-dimethoxypropane, dimethylsulfate, 1,1, 1-triethoxyethane, 1,2- dibromopropane, 2-bromobutane, isobutanol, isobutanal, 2-chlorobutane, 1,2- dichloropropane, 2,3-dichloro-l-propene, 2-chloro-l-propanol, 1,2- propanediamine, 2- aminopropanol, 2-butanol, butanone, methylglyoxal, 1,1,2-trichloroethane, 1,1- dichloropropane, trichloroethene, 1,1,2,2-tetrachloroethane, dihexylphthalate, methylbenzoate, 2-propylcyclohexanone, 1, 2-dimethylbenzene, 2-methylphenol, l-chloro-2- methylbenzene, 1,2-dichlorobenzene, 2-fluorotoluene, 2-bromophenol, 2-chlorophenol, 1,2,4- trimethylbenzene, l-chloro-2,4- dimethylbenzene, 2-chloro-l, 4-dimethylbenzene, 1,2,4, 5- tetramethylbenzene, 2,3-heptanedione, 2-methylbutanal, 3-methylpentane, 1,2,3- trichloropropane, 1,2,3-trichloropropene, 2-amino-l-butanol, 3-pentanone, bromoaceticacidmethylester, 2-ethyl- l-butanol, 2-chloro-l, l-dimethoxyethane, furfural, 2- furanmethanol, isopropylbenzene, ethylbenzene, styrene, 2- (diethylamino) -ethanol, n, n- diethylethylenediamine, cyclohexanemethanol, n-ethyl-morpholine, 3- methylstyrene, 1, 1,3,3- tetramethoxypropane, n, n, n ', n'-tetraethylmethanediamine, n, n-dipropyl-l-propanamine, n, n- di-2-propenyl-2-propen-l- amine, n-propylbenzene, benzylmethylamine, ethoxybenzene, n, n- dimethylbenzylamine, 2-ethylhexylamine, 2-ethyl-l-hexanol, diethylaminopropylamine, 4- methylbenzenemethanamine, 2-methyl-l-pentanol, ethylpropionate, 4-methyl-2- hexanamine, 4-methyl-2-hexanone, methylacetoacetate, sec-butylacetate, isopropylchloroacetate, diethylmalonate, 1,1-diethoxyethane, diethylcarbonate, l-bromo-4-methylbenzene, 1-bromo-4-chlorobenzene, 1,4-dimethylbenzene, l-chloro-4-methylphenyl lbenzene, 1,4-dichlorobenzene, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, 1,2-dibromoethane,

1-bromopropane, 3-bromopropene, 1-propanethiol, l-bromo-2-chloroethane, 3-chloropropene, 1,2-dichloroethane, 1-iodopropane, n-propylamine, propionitrile, chloromethoxymethane, methylformate, 2,4,4- trimethyl-l-pentene, 2,2,4-trimethyl-2-pentene,

2-methyl-2,4-pentanediol, 4-methoxy-4-methyl-pentan-2-one, 2-bromopentane, l-bromo-3- methylbutane, isoamylchloride, 2-pentanone, 3-hydroxy-butanal, l- methoxy-2-propanol, 2- (dimethylamino) -ethanol, 2,4-dimethylpentane, 4-methyl-2-pentanone, 4-methyl-2-pentanol, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 1,3-dimethylbenzene, m-toluenethiol, 3-chlorotoluene, 2,4-dimethylpyridine, 2,6-dimethylpyridine, 2,6-dimethylpyrazine, dimethylmalonate, 1,3-diethenylbenzene, l-methoxy-2-acetoxypropane, 1,3,5-trimethylbenzene, bromocyclohexane, methylcyclohexane, toluene, 4-methylpyridine, chlorobenzene, cyclohexylamine, cyclohexanol, cyclohexanone, phenol, 2-isopropoxyethanol,

1-chlorobutane, 2-methoxyethanol, dimethoxymethane, diethylamine, thiophene, n-propylformate, 1,2-dimethoxyethane, ethoxyethanol, cyclohexane, 1,3,5-trioxane, di-n-propylether, 2-allyloxyethanol, octane, 1, 4-dioxane, ethanolamine, perfluoroheptane, 2-bromo-

2-methylpropane, 2-chloro-2-methylpropane, 3-pentanol, 2-ethoxy-propane, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, ethylacetate, methyl acetate.

Preferably, said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extractant chosen from the group consisting of 2-propanol, 1- octanol, tetrachloromethane, diethylether, hexanal, propanone, trichloromethane, hexachloroethane, dimethylformamide, diethylsulfoxide, propanol, 1- butanol, 1-pentanol, 1,1,1-trichloroethane, iodomethane, bromoethane, chlorobromomethane, iodoethane, ethanethiol, dichloromethane, dimethylsulfide, 2-bromopropane, 2-bromopropane, 2-iodopropane, isopropylamine, 2-propanethiol, 1,1-dichloroethane, 1,1-dichloroethylene, bromotrichloromethane, 2-amino-2- methylpropane, tert-butanol, tert-butylthiol, 2-methyl-2-butanol, 2, 2-dimethyl-l-propanol, trichloroacetaldehyde, 3,3-dimethyl-2-butanone, l, l, l-trichloro-2-propanol, pentachloroethane, trichloroacetylchloride, 3-methyl-3-pentanol, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, 1,2-dibromopropane, 2-bromobutane, isobutanol, isobutanal, 2-chlorobutane, 1,2-dichloropropane, 2,3-dichloro-l-propene, 1,2-propanediamine, 2- butanol, butanone, methylglyoxal, 1,1,2-trichloroethane, 1,1-dichloropropane, trichloroethene, 1, 1,2,2- tetrachloroethane, dihexylphthalate, methylbenzoate, 2-propy lcyclohexanone, 1,2- dimethylbenzene, 2-methylphenol, l-chloro-2-methylbenzene, 1,2-dichlorobenzene, 2-bromophenol, 2-chlorophenol, 1,2,4-trimethylbenzene, l-chloro2,4-dimethylbenzene, 2- chloro-l, 4-dimethylbenzene, 1,2,4,5-tetramethylbenzene, 2,3-heptanedione, 2-methylbutanal,

3-methylpentane, 1,2,3-trichloropropene, 3-pentanone, 2-ethyl-l-butanol, 2-chloro-l, l- dimethoxyethane, isopropylbenzene, ethylbenzene, styrene, 2- (diethylamino) -ethanol, n, n- diethylethylenediamine, cyclohexanemethanol, n-ethyl-morpholine, 3-methylstyrene, 1, 1,3,3- tetramethoxypropane, n, n, n ', n'-tetraethylmethanediamine, n, n-dipropyl-l-propanamine, n, n-di-2-propenyl-2-propen-l-amine, n-propylbenzene, benzylmethylamine, ethoxybenzene, n, n- dimethylbenzylamine, 2-ethylhexylamine, 2-ethyl-l-hexanol, diethylaminopropylamine, 4- methylbenzenemethanamine, 2- methyl-l-pentanol, ethylpropionate, 4-methyl-2-hexanamine,

4-methyl-2-hexanone, sec-butylacetate, isopropylchloroacetate, diethylmalonate, 1,1- diethoxyethane, diethylcarbonate, l-bromo-4-methylbenzene, l-bromo-4-chlorobenzene, 1,4-dimethylbenzene, l-chloro- 4-methylbenzene, 1,4-dichlorobenzene, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, 1-bromopropane, 3- bromopropene, 1-propanethiol, 3-chloropropene, 1-iodopropane, n- propylamine, methylformate, 2,2,4-trimethyl-2-pentene, 2-methyl-2,4-pentanediol, 4-methoxy-4-methyl- pentan-2-one, 2-bromopentane, l-bromo-3- methylbutane, isoamylchloride, 2-pentanone, 1- methoxy-2-propanol, 2- (dimethylamino) -ethanol, 2,4-dimethylpentane, 4-methyl-2-pentanone, 4-methyl-2-pentanol, l- (dimethylamino ) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 1,3-dimethylbenzene, m-toluenethiol, 3-chlorotoluene, 2,4-dimethylpyridine, 2,6-dimethylpyridine, 2,6-dimethylpyrazine, 1,3-diethenylbenzene, l-methoxy-2- acetoxypropane, 1,3,5-trimethylbenzene, bromocyclohexane, methylcyclohexane, toluene, 4- methylpyridine, chlorobenzene, cyclohexylamine, cyclohexanol, cyclohexanone, 2- isopropoxyethanol, 1-chlorobutane, 2-methoxyethanol, dimethoxymethane, ethylene 1,2-dimethoxyethane, ethoxyethanol, cyclohexane, 1,3,5-trioxane, 2-allyloxyethanol, octane, 1,4-dioxane, ethanolamine, perfluoroheptane, 2-bromo-2- methylpropane, 2-chloro-2-methylpropane, 3-pentanol, 2-ethoxy-propane, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, ethylacetate, methylacetate.

 More preferably, said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of 2-propanol, 1- octanol, diethylether, hexanal, propanone, dimethylformamide, diethylsulfoxide, propanol, 1-butanol, 1-pentanol, isopropylamine, 2- amino-2-methylpropane, tert-butanol, 2-methyl-2-butanol, 3,3-dimethyl- 2-butanone, 3- methyl-3-pentanol, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, isobutanol, 1,2- propanediamine, 2-butanol, butanone, dihexylphthalate, 2-propylcyclohexanone, 3-pentanone, 2-ethyl-l-butanol, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, cyclohexanemethanol, n-ethyl-morpholine, 1,1,3,3-tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, 2-ethyl-l- hexanol, diethylaminopropylamine, 4-methylbenzenemethanamine, 2-methyl-l-pentanol, ethylpropionate, 4-methyl-2-hexanamine, 4-methyl-2- hexanone, dry-drunk tylacetate, diethylmalonate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6- dimethyl-5-heptenal, n-propylamine, 2-methyl-2,4-pentanediol, 4-methoxy-4-methyl- pentan-2- one, 2-pentanone, l-methoxy-2-propanol, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, 4-methyl-2-pentanol, l- (dimethylamino) -2- propanol, diisopropylamine, diisopropylether, isopropylacetate, 2,4-dimethylpyridine, 2,6-dimethylpyridine, l-methoxy-2-acetoxypropane, 4- methylpyridine, cyclohexylamine, cyclohexanol, cyclohexanone, 2-isopropoxyethanol, 2- methoxyethanol, diethylamine ethoxyethanol, cyclohexane, 2-allyloxyethanol, octane, ethanolamine, 2-bromo-2-methylpropane, 3-pentanol, 2-ethoxy-propane, 2-hexanol, 1- ethoxy-2-methylpropane, methyl-t-butylether, isopropyl- isobutyl-ether, tetrachloroethene, methylacetate.

In particular, said composition comprises 2-chloro-1,1,1,1-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of 1-octanol, diethylether, hexanal, propanone, dimethylformamide, diethylsulfoxide, isopropylamine, 2-amino-2-methylpropane, 3,3-dimethyl-2-butanone, 3- methyl-3-pentanol, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2- propylcyclohexanone, 3-pentanone, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, n-ethyl-morpholine, 1,1,3,3-tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4-methylbenzenemethanamine, ethylpropionate, 4-methyl-2-hexanamine, 4-methyl-2- hexanone, sec-butylacetate, diethylmalonate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, n-propylamine, 2-methyl-2,4-pentanediol, 4-methoxy-4-methyl-pentan-2-one, 2-pentanone, l-methoxy-2- propanol, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, 2,4-dimethylpyridine, 2,6- dimethylpyridine, l-methoxy- 2-acetoxypropane, 4-methylpyridine, cyclohexylamin e, cyclohexanone, 2-isopropoxyethanol, diethylamine, thiophene, ethoxyethanol, cyclohexane, 2- allyloxyethanol, octane, ethanolamine, 2-bromo-2-methylpropane, 3-pentanol, 2-hexanol, 1- ethoxy-2-methylpropane, methyl- t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate.

More particularly, said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of diethylether, hexanal, diethylsulfoxide, isopropylamine, 2-amino- 2-methylpropane, 3,3-dimethyl-2-butanone, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2-propylcyclohexanone, 3-pentanone, 2- (diethylamino ) -ethanol, n, n-diethylethylenediamine, n-ethyl-morpholine, 1,1,3,3-tetramethoxypropane, n, n-dipropyl-l- propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4-methylbenzenemethanamine, ethylpropionate, 4-methyl-2- hexanamine, 4-methyl-2-hexanone, sec-butylacetate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, n-propylamine, 4-methoxy-4- methyl-pentan-2-one, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, 1- (dimethylamino) -2-propanol, diisopropylamine, diisop ropylether, isopropylacetate, 2,4-dimethylpyridine, 2,6-dimethylpyridine, l-methoxy-2-acetoxypropane, 4-methylpyridine, cyclohexylamine, cyclohexanone, diethylamine, thiophene, ethoxyethanol, 2-allyloxyethanol, ethanolamine, 2-bromo-2- methylpropane, 3-pentanol, 2-hexanol, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate. Preferably, said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of 2,2-dimethoxypropane , butanone, 3-pentanone, sec- butylacetate, 1,1-diethoxyethane, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2- pentanone, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether , isopropylacetate, l-methoxy-2-acetoxypropane, diethylamine, ethoxyethanol, 3-pentanol, 2-hexanol, methyl-t-butylether, tetrachloroethene, methylacetate.

 Advantageously, said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of butanone, 3- pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 4-methyl-2-pentanone, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t-butylether, tetrachloroethene, methylacetate.

 Preferably, said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of sec-butylacetate, 1,1-diethoxyethane, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t-butylether, tetrachloroethene.

 In a particularly preferred manner, said composition comprises 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3-trifluoropropene and an organic extraction agent chosen from the group consisting of diisopropylamine, diisopropylether, diethylamine, 1,1- diethoxyethane, ethoxyethanol.

 According to a fifth aspect of the present invention, a composition is provided. Said composition comprises more than 99% by weight of 2-chloro-1,1,1,2-tetrafluoropropane, advantageously more than 99.2% by weight, preferably more than 99.4% by weight, more preferably more than 99 , 6% by weight, in particular more than 99.8% by weight, more particularly more than 99.9% by weight of 2-chloro-1,1,1,2-tetrafluoropropane based on the total weight of the composition.

According to a preferred embodiment, said composition comprises less than 1% by weight of 2-chloro-3,3,3-trifluoropropene, advantageously less than 0.8% by weight, preferably less than 0.6% by weight, more preferably less than 0.4% by weight, in particular less than 0.2% by weight, more particularly less than 0.1% by weight of 2-chloro 3,3,3-trifluoropropene based on the total weight of the composition. Thus, said composition may comprise more than 99% by weight of 2-chloro-1,1,1,2-tetrafluoropropane, advantageously more than 99.2% by weight, preferably more than 99.4% by weight, more preferably more than 99.6% by weight, in particular more than 99.8% by weight, more particularly more than 99.9% by weight of 2-chloro-1,1,1,2-tetrafluoropropane; and less than 1% by weight of 2-chloro-3,3,3-trifluoropropene, advantageously less than 0.8% by weight, preferably less than 0.6% by weight, more preferably less than 0.4% by weight weight, in particular less than 0.2% by weight, more particularly less than 0.1% by weight of 2-chloro 3,3,3-trifluoropropene based on the total weight of the composition.

Method of selecting the organic extractant

 The selection of the organic extraction agent is determined by the use of the Cosmo-RS model implemented in the COSMOTHERM software. For this selected binary couple, a separation factor is calculated for each of the solvents studied by the following equation:

If, 2 = (Y _{I, S} * P1) / (Y _{2, S} * P2) in which

Yi _, s represents the activity coefficient of the first compound 1 in the organic extraction agent considered at infinite dilution,

 PI represents the saturation vapor pressure of the first compound 1, j2, s represents the activity coefficient of the second compound 2 of the binary couple in the organic extraction agent considered at infinite dilution,

 P2 represents the saturation vapor pressure of the second compound.

An absorption capacity is also calculated for each of the solvents studied and for a binary couple (1,2) considered. The absorption capacity is calculated by the formula C2 _, s = l / (Y2 _, s) in which j2, s represents the activity coefficient of the second compound of the binary couple considered in said organic extraction agent studied at infinite dilution .

 The calculations are repeated for each organic extractant studied. Minimum values of separation factor and absorption capacity are identified in order to allow sufficient separation between the first compound and the second compound of the binary pair (1,2) considered. The saturated vapor pressure is considered for a temperature of 25 ° C.

Examples The separation between 2-chloro-1,1,1,2-tetrafluoropropane (244bb) and 2-chloro-3,3,3-trifluoropropene (1233xf) is considered. Based on the information obtained by the Cosmo-RS model, the solvents listed in table 1 below were tested for the extractive distillation of a mixture comprising 2-chloro-l, l, l, 2-tetrafluoropropane (244bb) and 2-chloro 3,3,3-trifluoropropene.

Table 1 - Capacity and separation factor of the organic extractant

Claims

claims

1. Process for the purification of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) from a first composition comprising 2-chloro-1,1,1,2-tetrafluoropropane and 2-chloro- 3,3,3- trifluoropropene, said process comprising the steps of:

 a) bringing said first composition into contact with at least one organic extracting agent to form a second composition; b) extractive distillation of said second composition to form: i) a third composition comprising said organic extractant and 2-chloro-3,3,3-trifluoropropene, ii) a stream comprising 2-chloro-1,1,1, 1,2-tetrafluoropropane;

 c) recovery and separation of said third composition to form a stream comprising said organic extractant and a stream comprising 2-chloro-3,3,3-trifluoropropene.

2. Method according to the preceding claim characterized in that the stream comprising the organic extraction agent separated in step c) is recycled in step a).

3. Method according to any one of the preceding claims, characterized in that said stream comprising 2-chloro-l, l, l, 2-tetrafluoropropane formed in step b) is recovered at the top of the distillation column and used optionally in a process for producing 2,3,3,3-tetrafluoropropene.

4. Method according to any one of the preceding claims, characterized in that the stream comprising 2-chloro-3,3,3-trifluoropropene formed in step c) is recovered at the top of the distillation column and optionally recycled in a process for the production of 2-chloro-1,1,1,2-tetrafluoropropane.

5. Method according to any one of the preceding claims, characterized in that the said organic extraction agent is a solvent chosen from the group consisting of hydrocarbon, hydrohalocarbon, alcohol, ketone, amine, ester, ether, aldehyde, nitrile, carbonate, phthalate, sulfate, amide, thioalkyl, sulfoxide and heterocycles, preferably said organic extractant is an amine.

6. Method according to any one of the preceding claims, characterized in that the said organic extraction agent has a boiling point of between 30 ° C and 200 ° C. 7. Method according to any one of the preceding claims, characterized in that said organic extraction agent has a separation factor Si, 2 greater than or equal to 1.1, said separation factor being calculated by the formula Si, 2 = (YL, S * P1) / (Y2, S * P2) in which

Y _{L, S} represents the activity coefficient of 2-chloro-1,1,1,2-tetrafluoropropane in said organic extraction agent with infinite dilution,

 PI represents the saturated vapor pressure of 2-chloro-l, l, l, 2-tetrafluoropropane, j2, s represents the activity coefficient of 2-chloro-3,3,3-trifluoropropene in said organic extractant with infinite dilution,

 P2 represents the saturated vapor pressure of 2-chloro-3,3,3-trifluoropropene; advantageously, the separation factor Si, 2 is greater than or equal to 1.2, preferably greater than or equal to 1.3, more preferably greater than or equal to 1.4, in particular greater than or equal to 1.5, more particularly greater than or equal to 1.6, preferably greater than or equal to 1,

7.

8. Method according to any one of the preceding claims, characterized in that said organic extraction agent has an absorption capacity C2 _, s greater than or equal to 0.20, said absorption capacity being calculated by formula C2 _, s = l / (j2, s) in which j2, s represents the activity coefficient of 2-chloro-3,3,3-trifluoropropene in said organic extraction agent with infinite dilution; advantageously, the absorption capacity C2 _, s is greater than or equal to 0.40, preferably greater than or equal to 0.60, more preferably greater than or equal to 0.80, in particular greater than or equal to 1.0, more particularly greater than or equal to 1.2, preferably greater than or equal to 1.3, advantageously favorably greater than or equal to 1.4.

9. Method according to any one of the preceding claims, characterized in that said organic extraction agent is chosen from the group consisting of diethylether, hexanal, diethylsulfoxide, isopropylamine, 2-amino-2-methylpropane, 3,3-dimethyl- 2-butanone, 2,2- dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2- propylcyclohexanone, 3-pentanone, 2- (diethylamino) -ethanol, n, n-diethylethylenediamine, n- ethyl-morpholine, 1,1,3,3-tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4-methylbenzenemethanamine, ethylpropionate, 4-methyl-2- hexanamine, 4-methyl-2- hexanone, sec-butylacetate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, n-propylamine, 4-methoxy-4-methyl- pentan-2- one, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, l- (dimethylamino) -2- propanol, diisopropylamine, diisopropylether, isopropylacetate, 2,4-dimethylpyridine, 2, 6- dimethylpyridine, l-methoxy-2-acetoxypropane, 4-methylpyridine, cyclohexylamine, cyclohexanone, diethylamine, thiophene, ethoxyethanol, 2-allyloxyethanol, ethanolamine, 2- bromo-2-methylpropane, 3-pentanol, 2-hexanol, methyl- t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate;

advantageously said organic extracting agent is chosen from the group consisting of 2,2-dimethoxypropane, butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 2- (dimethylamino) -ethanol, 4- methyl-2-pentanone, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, l-methoxy-2-acetoxypropane, diethylamine, ethoxyethanol, 3-pentanol, 2-hexanol, methyl-t-butylether, tetrachloroethene, methylacetate;

preferably said organic extractant is chosen from the group consisting of butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 4-methyl-2-pentanone, diisopropylamine, diisopropylether, isopropylacetate, diethylamine , ethoxyethanol, methyl-t-butylether, tetrachloroethene, methylacetate;

in particular, said organic extraction agent is chosen from the group consisting of sec-butylacetate, 1,1-diethoxyethane, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t-butylether, tetrachloroethene;

more particularly said organic extraction agent is chosen from the group consisting of diisopropylamine, diisopropylether, diethylamine, 1,1-diethoxyethane, ethoxyethanol.

10. A process for producing 2-chloro-1,1,1,2-tetrafluoropropane comprising the steps of: A) bringing 2-chloro-3,3,3-trifluoropropene into contact with hydrofluoric acid in the presence of a catalyst for forming a stream Al comprising 2-chloro-1,1,1,2, tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and unreacted and unreacted hydrofluoric acid, B) purification of said stream Al obtained in step A to form a stream A2 comprising 2-chloro-1,1,1,2-tetrafluoropropane and 2-chloro-3,3,3-trifluoropropene and a stream A3 comprising l hydrofluoric acid,

 C) purification of said stream A2 according to any one of claims 1 to 9 to form a stream A4 comprising 2-chloro-1,1,1,2-tetrafluoropropane.

11. Process for the production of 2,3,3,3-tetrafluoropropene comprising the steps of:

 implementation of the process for the production of 2-chloro-l, l, l, 2-tetrafluoropropane according to the preceding claim,

 - Use of a dehydrochlorination reaction of 2-chloro-1,1,1,2-tetrafluoropropane contained in stream A4 under conditions effective to form 2,3,3,3-tetrafluoropropene.

12. Composition comprising 2-chloro-1,1,1,2-tetrafluoropropane, 2-chloro-3,3,3- trifluoropropene and an organic extracting agent chosen from the group consisting of diethylether, hexanal, diethylsulfoxide, isopropylamine, 2-amino-2-methylpropane, 3,3- dimethyl-2-butanone, 2,2-dimethoxypropane, 1,1,1-triethoxyethane, butanone, dihexylphthalate, 2-propylcyclohexanone, 3-pentanone, 2- (diethylamino) - ethanol, n, n- diethylethylenediamine, n-ethyl-morpholine, 1,1,3,3-tetramethoxypropane, n, n-dipropyl-l-propanamine, benzylmethylamine, n, n-dimethylbenzylamine, 2-ethylhexylamine, diethylaminopropylamine, 4- methylbenzenemethanamine, ethylpropionate, 4-methyl-2- hexanamine, 4-methyl-2-hexanone, sec-butylacetate, 1,1-diethoxyethane, 3-octanone, methylhexanoate, methylheptanoate, 2,6-dimethyl-5-heptenal, n- propylamine, 4-methoxy-4- methyl-pentan-2-one, 2-pentanone, 2- (dimethylamino) -ethanol, 4-methyl-2-pentanone, 1- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylace tate, 2,4-dimethylpyridine, 2,6-dimethylpyridine, l-methoxy-2-acetoxypropane, 4-methylpyridine, cyclohexylamine, cyclohexanone, diethylamine, thiophene, ethoxyethanol, 2-allyloxyethanol, ethanolamine, 2-bromo-2-methylpropane, 3-pentanol, 2-hexanol, methyl-t-butylether, isopropyl-isobutyl-ether, tetrachloroethene, methylacetate;

advantageously said organic extracting agent is chosen from the group consisting of 2,2-dimethoxypropane, butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 2- (dimethylamino) -ethanol, 4- methyl-2-pentanone, l- (dimethylamino) -2-propanol, diisopropylamine, diisopropylether, isopropylacetate, l-methoxy-2-acetoxypropane, diethylamine, ethoxyethanol, 3-pentanol, 2-hexanol, methyl-t-butylether, tetrachloroethene, methylacetate;

preferably said organic extractant is chosen from the group consisting of butanone, 3-pentanone, sec-butylacetate, 1,1-diethoxyethane, 2-pentanone, 4-methyl-2-pentanone, diisopropylamine, diisopropylether, isopropylacetate, diethylamine , ethoxyethanol, methyl-t-butylether, tetrachloroethene, methylacetate;

in particular, said organic extraction agent is chosen from the group consisting of sec-butylacetate, 1,1-diethoxyethane, diisopropylamine, diisopropylether, isopropylacetate, diethylamine, ethoxyethanol, methyl-t-butylether, tetrachloroethene;

more particularly said organic extraction agent is chosen from the group consisting of diisopropylamine, diisopropylether, diethylamine, 1,1-diethoxyethane, ethoxyethanol.

13. Composition comprising more than 99% by weight of 2-chloro-l, l, l, 2-tetrafluoropropane and less than 1% by weight of 2-chloro-3,3,3-trifluoropropene based on the total weight of the composition.