WO2020019430A1 - 包含hppd抑制剂类除草剂的三元除草组合物及其应用 - Google Patents

包含hppd抑制剂类除草剂的三元除草组合物及其应用 Download PDF

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WO2020019430A1
WO2020019430A1 PCT/CN2018/105273 CN2018105273W WO2020019430A1 WO 2020019430 A1 WO2020019430 A1 WO 2020019430A1 CN 2018105273 W CN2018105273 W CN 2018105273W WO 2020019430 A1 WO2020019430 A1 WO 2020019430A1
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polyoxyethylene ether
ciclopirox
methyl
fatty alcohol
suspension
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PCT/CN2018/105273
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English (en)
French (fr)
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彭学岗
赵德
金涛
刘娜
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青岛清原化合物有限公司
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Publication of WO2020019430A1 publication Critical patent/WO2020019430A1/zh

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

Definitions

  • the invention belongs to the field of pesticides, and particularly relates to a ternary herbicidal composition containing an HPPD inhibitor herbicide and its application.
  • Chemical weed control is the most economical and effective method for controlling weeds in farmland.
  • long-term continuous high-dose use of a single variety or single action chemical herbicide can easily cause problems such as resistance and evolution of weeds.
  • oxadiazone is a newly developed HPPD inhibitor herbicide for the treatment of stems and leaves of wheat field seedlings. It has excellent biological activity and can effectively control a variety of malignant weeds in wheat fields.
  • the chemical structural formula of ciclopirox is It belongs to the HPPD inhibitor.
  • HPPD enzyme By inhibiting the activity of the HPPD enzyme, the process of converting p-hydroxypyruvate to uromelic acid is blocked, resulting in the inability to synthesize tocopherols and plastid quinones, affecting the carotenoid synthesis in the target, and causing the leaves to turn white Affect the normal progress of photosynthesis in plants, and eventually die completely.
  • Reasonable compounding or mixing of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of weed resistance and resistance, and is one of the most effective methods to solve the above problems. Therefore, there is an urgent need to develop a variety of herbicidal compositions with high safety, broad herbicidal spectrum, which can produce synergistic effects and solve the problem of resistant weeds.
  • the present invention provides a ternary herbicidal composition containing an HPPD inhibitor herbicide and its application.
  • the composition can effectively prevent weeds such as broken rice mash, stellate, amaranth, ox stellate, pig sedge, watching Mai Niang, Japanese watching Mai Niang, Yarrow in crop fields, etc. Dosage, safety to crops, synergistic effects, and resistance to weeds.
  • a ternary herbicidal composition comprising an HPPD inhibitor herbicide, comprising an herbicidally effective amount of active ingredient A, active ingredient B, and active ingredient C, wherein,
  • the active ingredient A is selected from one or more of the following HPPD inhibitor-type herbicide compounds: diazoxynone (CAS number: 1622908-18-2), ciclopirox (CAS number: 1855929-45-1 ) And / or its derivatives
  • Active ingredient B is selected from one or more of the following compounds: oxaflutole (CAS number: 210631-68-8), mesotrione (CAS number: 104206-82-8), sulfazone (CAS No. 335104-84-2), isoxaflutole (CAS number: 141112-29-0), bicyclosulfone (CAS number: 156963-66-5), trisotrione (CAS number: 1911613) -97-2), flubendicarb (CAS number: 1992017-55-6) and / or derivatives thereof;
  • the active ingredient C is selected from one or more of the following compounds: (1) a VLCFA inhibitor: prachlor (CAS number: 51218-49-6), butachlor (CAS number: 23184-66-9), Mefenazol (CAS number: 73250-68-7), salarphos (CAS number: 64249-01-0); (2) Microtubule assembly inhibitor: bupropion (CAS number: 33629-47- 9); (3) PPO inhibitors: oxadiazon (CAS number: 19666-30-9), bisoxacillin (CAS number: 158353-15-2), ethoxyfluorfen (CAS number: 42874- 03-3); (4) PSII inhibitor: isoprolong (CAS number: 34123-59-6), xicaojing (CAS number: 1014-70-6); (5) DOXP inhibitor: clomazone Pine (CAS number: 81777-89-1); (5) hormones: 2 methyl 4 chloride (CAS number: 94-74-6), dichloroquinolinic acid (CAS number: 84087-01
  • the common name of the active compound all conventional derivatives, such as esters and salts, as well as isomers, especially optical isomers, in particular One or more commercially available forms. If the common name indicates an ester or salt, all other conventional derivatives are also included in each case, such as other esters and salts, free acids and neutral compounds, and isomers, especially optical isomers, especially It is one or more commercially available forms.
  • the given chemical name of a compound represents at least one compound that is covered by a common name, and is generally a preferred compound.
  • salts also include salts formed by the exchange of a cation with a hydrogen atom in a sulfonamide group.
  • the 2 methyl 4 chloride derivative includes, but is not limited to, 2 methyl 4 chloride sodium salt, potassium salt, dimethyl ammonium salt, isopropylamine salt, and the like, and 2 methyl 4chloromethyl, ethyl, isooctyl, and ethylsulfide. Esters, etc.
  • the salt of the compound is preferably in the form of a respective alkali metal salt, alkaline earth metal salt or ammonium salt, preferably in the form of a respective alkali metal salt, more preferably in the form of a respective sodium or potassium salt, Most preferred is the form of the respective sodium salt.
  • the weight ratios of A, B and C are 1 to 500: 0.1 to 100: 1 to 5000 and 5 to 300: 0.5 to 80: 5 to 4000; preferably 10 to 250: 0.7 to 50: 10 to 3000 and 20 to 200. : 1 to 30: 30 to 2000; more preferably 30 to 150: 3 to 20: 50 to 1000 and 40 to 120: 5 to 15: 100 to 800; even more preferably 50 to 100: 7 to 12: 200 to 600 And 60 ⁇ 80: 8 ⁇ 10: 300 ⁇ 500.
  • the mass percentage of A, B, and C in the herbicidal composition accounts for 1-95% of the total, preferably 10-80%.
  • the herbicidal composition further includes a conventional auxiliary agent, and the conventional auxiliary agent includes a carrier and a surfactant.
  • carrier herein means an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier is generally inert and must be agriculturally acceptable, especially by the treated plant.
  • the carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, etc .; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or wax hydrocarbons, chlorine Hydrocarbon replacement, liquefied gas, etc.
  • the surfactant may include an emulsifier, a dispersant, or a wetting agent, and it may be ionic or non-ionic.
  • examples which may be mentioned are salts of polyacrylic acid, lignin sulfonates, phenol sulfonic acids or naphthalene sulfonic acids, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols (particularly Is an alkylphenol or an arylphenol) polymer, a sulfosuccinate, a taurine derivative (especially an taurine alkyl ester), and a phosphate of an alcohol or a polyhydroxyethylated phenol, Alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated cetyl-, hepta-
  • composition may also contain various other components such as protective colloids, adhesives, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
  • the ternary composition of the present invention can be mixed with the following active substances, for example, "World Encyclopedia of New Pesticide Technology", China Agricultural Science and Technology Press, 2010.9, and known substances in the literature cited here.
  • the herbicide active substances mentioned below (note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, with a code when appropriate): acetochlor, butachlor, Alachlor, Promethachlor, Metolachlor, Prometachlor, Promechlor, Toxachlor, Chlortochlor, Naproxyl, R-Lonaphal , Fenoxadi, fenoxyfen, fenflufen, chlorfenapyr, flubutyramide, bromobutyramide, methacetamide, high-efficiency methacetamide, ethoxylate Acetochlor, fluoxadi, methachlor, imazapyr, clomazone, high-performance dicamba,
  • the herbicidal composition further includes at least one safener selected from:
  • Dichlorophenylpyrazoline-3-carboxylic acid (S1) compounds and preferred compounds are, for example, 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl Ethyl-2-pyrazoline-3-carboxylic acid ethyl ester (S1-1, mefenpyr-diethyl, PM, pages 594-595), as well as described in, for example, WO91 / 07874 and PM (page 594-595).
  • Dichlorophenylpyrazolecarboxylic acid derivatives are, for example, 1- (2,4-dichlorophenyl) -5-methylpyrazole-3-carboxylic acid ethyl ester (S1-2), 1- (2,4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1- (2,4-dichlorophenyl) -5- (1 1,1-Dimethyl-ethyl) pyrazole-3-carboxylic acid ethyl ester (S1-4), 1- (2,4-dichlorophenyl) -5-phenylpyrazole-3-carboxylic acid ethyl Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
  • Triazolecarboxylic acid (S1) compounds and preferred compounds are, for example, fenchlorazole, that is, 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1H) -1 , 2,4-triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
  • 5-benzyl- or 5-phenyl-2-isooxazoline-3-carboxylic acids or 5,5-diphenyl-2-isooxazoline-3-carboxylic acids preferably
  • the compound is, for example, 5- (2,4-dichlorobenzyl) -2-isoxazoline-3-carboxylic acid ethyl ester (S1-7) or 5-phenyl-2-isooxazoline-3-carboxylic acid Ethyl Ester (S1-8) and related compounds described in WO91 / 08202, or 5,5-diphenyl-2-isooxazoline- described in patent application (WO-A-95 / 07897) Ethyl 3-carboxylate (S1-9, isoxadifen-ethyl) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid n-propyl ester (S1-10) Or 5- (4-fluorophenyl) -5-phenyl
  • S2 8-quinolinoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolinoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (p.195-196), (1,3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy Methyl) acetate (S2-4), (5-chloro-8-quinolinyloxy) ethyl acetate (S2-5), (5-chloro-8-quinolinyloxy) acetic acid methyl ester (S2- 6), (5-chloro-8-quinolinoxy) allyl acetate (S2-7), 2- (2-propyleneiminooxy) -1-eth
  • 5-chloro-8-quinolinyloxy) malonic acid compounds and preferred compounds are, for example, (5-chloro-8-quinolinyloxy) malonic acid diethyl ester, (5-chloro-8 -Quinolinoxy) diallyl malonate, (5-chloro-8-quinolinoxy) -methyl malonate and related compounds described in EP-A-0582198.
  • phenoxyacetic acid phenoxypropionic acid or aromatic carboxylic acid active compounds, such as 2,4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and esters) (dicamba) .
  • Corn seed dressings are called safeners to prevent damage from thiourethane herbicides
  • the safener is preferably dibenzoxazolic acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyrazolidin (CAS: 135590-91-9), and detoxification quinone (CAS) : 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
  • composition of the present invention can be diluted or used directly by the user before use.
  • the formulation can be prepared by ordinary processing methods, that is, after mixing the active substance with a liquid solvent or a solid carrier, and then adding one or more of a surfactant such as a dispersant, a stabilizer, a wetting agent, a binder, and an antifoaming agent Species.
  • a surfactant such as a dispersant, a stabilizer, a wetting agent, a binder, and an antifoaming agent Species.
  • the specific preparation of the herbicidal composition is a dispersible oil suspension, an aqueous suspension, a suspoemulsion, a wettable powder, an emulsifiable concentrate, a water-dispersible granule (dry suspension), an aqueous emulsion, and a microemulsion.
  • compositions of the present invention can be mixed with solid and liquid additives conventionally used in formulations of the prior art.
  • the invention also provides an application of the ternary herbicidal composition for controlling weeds in crops; and a method for controlling unwanted plant growth, which comprises applying the ternary herbicidal composition to plants, Plant parts, plant seeds or areas where plants grow, preferably for selective control of weeds in crops.
  • composition of the present invention can be applied to the leaves of the plant to be treated by spraying, that is, to the weeds, especially to the surface of weeds that are harmful to crop growth or easily affected by the weeds.
  • composition of the present invention is environment-friendly and easily degrades in the environment, and is suitable for various crop fields.
  • the herbicidal composition of the present invention has low cost and convenient use, and its promotion and application has huge economic and social benefits.
  • Ciclofurone 3% Ciclosulone, 24% Sec-Butyl, 5% Calcium Dodecylbenzene Sulfonate, 5% Fatty Alcohol Polyoxyethylene Ether, 6% Castor Oil Oxyethylene Ether, 2.5% Organic bentonite + 2.5% fumed silica + 20% 100 # solvent oil + methyl oleate
  • the above-mentioned water suspending agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned water suspending agent processing process Put all the materials into the mixing tank, mix and pass the colloid mill, and then enter the three-stage sand mill of the sand mill, and finally cut evenly in the shearing machine. After passing the test, transfer to the storage. Can filling.
  • dispersable oil suspending agent processing equipment mixing kettle, colloid mill, sand mill, shearing machine, etc.
  • the above-mentioned dispersible oil suspending agent processing process Put all the materials into the mixing tank, mix and pass the colloid mill, then enter the sand mill three-stage sand mill, and finally cut it uniformly in the shearing machine. Fill to the tank.
  • the above suspension emulsion processing equipment mixing kettle, colloid mill, sand mill, shearing machine, shearing kettle.
  • the above suspension emulsion processing process Put some materials into the mixing tank, stir and mix and then pass the colloid mill, and then enter the sand mill three-stage sand mill. After passing the test, enter the shear tank for backup, and use it as the water phase material. The medicine and solvent are put into the mixing kettle, stirred to dissolve until completely transparent, and then an emulsifier is added, and the oil phase is evenly stirred. Then, the shearing machine is turned on, and the oil phase is slowly drawn into the shearing kettle under the shearing state. After all the materials are pumped in, continue to cut for 1 hour. After passing the test, transfer to the storage tank for filling.
  • the aforementioned water-dispersed granule processing equipment jet mill, coulter mixer, basket granulator, drying box, sieving machine, etc.
  • the above-mentioned water-dispersed granule processing process the above materials are mixed uniformly and pulverized by air flow, water is added into the kneaded granulation, then dried, and finally sieved to obtain a finished product.
  • Cardamine hirsuta L. and Stellaria media were collected from Xinghua, Jiangsu.
  • the above-mentioned weeds are cultivated by a pot method.
  • a 180 ⁇ 140mm plastic nutrition bowl is placed in an enamel plate, and the surface soil (4/5 places) collected from the farmland is air-dried and sieved.
  • the initial humidity of the soil is controlled at 20%.
  • Weed seeds with full and uniform grains are selected. Soak in warm water at 25 ° C for 6 hours, germinate in a 28 ° C biochemical incubator (dark), place the freshly weed seeds evenly on the soil surface, and then cover the soil with 0.7cm. After the medicine treatment, it is cultivated in a controlled sunlight greenhouse, and a certain amount of water is regularly added to the enamel plate to keep the soil moist.
  • 3WP-2000 walking spray tower Nanjing Agricultural Machinery Research Institute, Ministry of Agriculture. GA110 type ten thousandth electronic balance (Germany); ZDR2000 intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory).
  • Each treatment was repeated 4 times, each treatment was 3 pots, and 20 weed seeds were sown in each pot, for a total of 60 plants per treatment.
  • the trial used the drug once, 24 hours after sowing.
  • the cultivated test material was evenly placed on a platform with an area of 0.5 m 2 , and the soil surface layer of the 3WP-2000 walking spray tower was used to spray the liquid amount at 450 kg / ha.
  • Spray pressure is 0.3MPa. After spraying all the chemicals, close the gas valve. After 30 seconds, open the spray tower door and remove the nutrition bowl. Then open the air valve, spray 50mL of clean water, and clean the spray tube.
  • Absolute number survey method was used to cut the surviving weed seedlings along the soil surface with a blade, and the fresh weeds were weighed with an analytical balance. For dead weeds, the fresh weight is zero.
  • the Colby method was used to evaluate the combined effect of any two and three on weeds.
  • E (%) (fresh weed weight in the treatment area / fresh weed weight in the control area) ⁇ 100
  • X represents the weed survival rate of A when the amount is P
  • Y is the weed survival rate of B when the amount is Q
  • E0 is the theoretical weed survival rate of A + B when the amount is (P + Q)
  • E represents Actual weed survival rates for each treatment.
  • E0 (%) X ⁇ Y ⁇ Z ⁇ ... ⁇ N / 100 (n-1) (mixed with ternary and above)
  • X, Y, Z, and N respectively represent the actual survival rates of n single agents, and n is the number of compound herbicides.
  • E0-E> 10% it means that synergism occurs; when E0-E ⁇ -10%, it means that there is an antagonistic effect; when E0-E is between ⁇ 10%, it means that an additive effect occurs.
  • test material is broken rice mash; when A is ciclopira In the case of humulone, the test material is Stellariae.
  • Table 1 A is diazatol, B is oxaflutole, and C is prazachlor
  • Table 2 A is diazatol, B is oxaflutole, and C is butachlor
  • Table 3 A is diflufenazone, B is oxaflutole, and C is fenflufenazone
  • Table 4 A is diazatofen, B is oxaflutole, and C is salazaphos
  • Table 5 A is diazatol, B is oxaflutole, and C is bupropion
  • Table 6 A is diazatofen, B is oxadiazon, C is oxadiazon
  • Table 7 A is dimetrione, B is oxafludione, and C is isoprolong
  • Table 8 A is oxaflutole
  • B is oxaflutole
  • C is oxaflutole
  • Table 9 A is diflufenazone, B is oxaflutole, and C is ethoxyfluorfen
  • Table 12 A is diazatol, B is oxaflutole, and C is oxacillin
  • Table 14 A is diflufenazone, B is oxaflutole, and C is penoxsulam
  • Table 16 A is diazoxynone, B is oxafludione, and C is grass herb
  • Table 17 A is diflufenazone, B is oxaflutole, and C is grass grass.
  • Table 18 A is dimetridione, B is mesotrione, and C is pretilachlor
  • Table 19 A is dimetrione, B is mesotrione, and C is butachlor
  • Table 20 A is dimetrione, B is mesotrione, and C is fenpropifen.
  • A is diazoxynone
  • B is mesotrione
  • C is salazaphos
  • Table 22 A is dimetrione, B is mesotrione, and C is bupropion.
  • Table 24 A is dimetrione, B is mesotrione, and C is isoprolong
  • Table 31 A is dimetrione, B is mesotrione, and C is penoxsulam
  • Table 33 A is diazatridone, B is mesotrione, and C is grass herb.
  • Table 34 A is diazatridone, B is mesotrione, and C is grass grass.
  • A is diazoxynone
  • B is sulfazone
  • C is fenflufenazone
  • Table 39 A is diflufenone, B is sulfazone, and C is bupropion.
  • Table 40 A is diazolidin, B is sulfazone, and C is clomazone
  • A is diflufenazone
  • B is sulfazone
  • C is ethoxyflutole
  • Table 45 A is dimetrione, B is sulfazone, and C is 2 methyl 4 chloride
  • Table 48 A is diflufenazone, B is sulfazone, and C is penoxsulam
  • Table 50 A is dimetrione, B is sulfazone, and C is grass herb
  • Table 51 A is diazolidin, B is sulfazone, and C is grass grass.
  • Table 54 A is diflubenzolone, B is isoxaflutole, and C is fenflufenazone
  • Table 56 A is diazoxynone, B is isoxazone, and C is bupropion.
  • Table 61 A is diazoxynone, B is isoxazone, and C is clomazone
  • Table 67 A is diazoxynone, B is isoxazone, and C is grass herb
  • Table 68 A is diazoxynone, B is isoxazone, C is grass grass
  • Table 70 A is diflufenazone, B is dicyclotrione, and C is butachlor
  • A is diflufenazone
  • B is dicyclotrione
  • C is fenflufenazone
  • Table 72 A is diazatridone, B is dicyclotrione, and C is salazaphos
  • Table 73 A is diazatridone, B is dicyclotrione, and C is bupropion.
  • Table 74 A is diazatridone, B is dicyclotrione, and C is clomazone
  • Table 75 A is diazatridone, B is dicyclotrione, and C is isoprolong
  • Table 76 A is diflufenazone, B is dicyclotrione, and C is diflufenacil.
  • A is diflufenazone
  • B is dicyclotrione
  • C is ethoxyflutole
  • Table 78 A is diazatridone, B is dicyclotrione, and C is clomazone
  • Table 80 A is diazatridone, B is dicyclotrione, and C is oxacillin.
  • Table 81 A is diazoxynone, B is disulfatrione, and C is dicloquinac
  • Table 82 A is diazatridone, B is dicyclotrione, and C is penoxsulam.
  • Table 84 A is diazatridone, B is dicyclotrione, and C is gramine.
  • Table 85 A is diazatridone, B is dicyclotrione, and C is grass grass
  • Table 87 A is dimetrione, B is triazosulone, and C is butachlor
  • A is diflufenazone
  • B is triazosulone
  • C is fenflufenazone
  • A is diazatridone
  • B is triazosulone
  • C is saprofen
  • Table 90 A is diazatridone, B is triazosulone, and C is bupropion.
  • A is diflufenazone
  • B is triazosulone
  • C is diflufenacil.
  • Table 96 A is dimetrione, B is triazosulone, C is 2 methyl 4 chloride
  • A is diflufenazone
  • B is triazolam
  • C is penoxsulam
  • Table 101 A is diazatridone, B is triazosulone, and C is grass herb
  • Table 102 A is diazatridone, B is triazosulone, and C is grass grass.
  • A is diflufenazone
  • B is flufenazone
  • C is propachlor
  • Table 104 A is diflufenazone, B is flufenazone, and C is butachlor
  • A is diflufenazone
  • B is flufenazone
  • C is fenflufenazone
  • A is diflufenazone
  • B is flufenazone
  • C is salazaphos
  • Table 107 A is diflufenazone, B is flufenazone, and C is bupropion.
  • A is diflufenazone
  • B is flubendione
  • C is clomazone
  • Table 109 A is diflufenazone, B is flufenazone, and C is isoprolong
  • Table 110 A is diflufenazone, B is flufenazone, and C is diflufenazone
  • A is diflufenazone
  • B is flufenazone
  • C is ethoxyflutole
  • A is diflufenazone
  • B is flufenazone
  • C is clomazone
  • A is diflufenazone
  • B is flufenazone
  • C is 2 methyl 4 chloride
  • Table 114 A is diflufenazone, B is flufenazone, and C is oxacillin
  • Table 116 A is diflufenazone, B is flufenazone, and C is penoxsulam
  • A is diflufenazone
  • B is flufenazone
  • C is clofludinate
  • Table 118 A is diflufenazone, B is flufenazone, and C is grass herb
  • A is diflufenazone
  • B is flufenazone
  • C grass grass
  • Table 120 A is ciclopirox, B is oxaflutole, and C is propachlor
  • Table 121 A is ciclopirox, B is oxaflutole, and C is butachlor
  • Table 122 A is ciclopirox, B is oxaflutole, and C is fenflufenazone
  • Table 123 A is ciclopirox, B is oxaflutole, and C is salazaphos
  • Table 124 A is ciclopirox, B is oxaflutole, and C is bupropion.
  • Table 125 A is ciclopirox, B is oxaflutole, and C is clomazone
  • Table 126 A is ciclopirox, B is oxaflutole, and C is isoprolong
  • Table 127 A is ciclopirox, B is oxaflutole, and C is diflufenacil
  • Table 128 A is ciclopirox, B is oxaflutole, and C is ethoxyflutomat
  • Table 129 A is ciclopirox, B is oxaflutole, and C is clomazone
  • Table 130 A is ciclopirox, B is oxaflutole, and C is 2 methyl chloride
  • A is ciclopirox
  • B is oxaflutole
  • C is oxacillin
  • Table 132 A is ciclopirox, B is oxaflutole, and C is dicloquinac
  • A is cimiflubenone
  • B is flufenazone
  • C is penoxsulam
  • Table 135 A is ciclopirox, B is oxaflutole, and C is grass herb
  • Table 136 A is ciclopirox, B is oxaflutole, and C is grass grass.
  • Table 137 A is cimiflubenone, B is mesotrione, and C is prochlorfen
  • Table 138 A is ciclopirox, B is mesotrione, and C is butachlor
  • Table 139 A is ciclopirox, B is mesotrione, and C is fenflufenazone
  • A is cimifloxazone
  • B is mesotrione
  • C is salazaphos
  • Table 141 A is cimifloxazone, B is mesotrione, and C is bupropion.
  • Table 142 A is ciclopirox, B is mesotrione, and C is clomazone
  • Table 143 A is ciclopirox, B is mesotrione, and C is isoprolong
  • Table 144 A is ciclopirox, B is mesotrione, and C is diflufenacil.
  • A is cimifloxazone
  • B is mesotrione
  • C is ethoxyfluorfen
  • Table 146 A is cimifloxazone, B is mesotrione, and C is clomazone
  • Table 148 A is cimifloxazone, B is mesotrione, and C is oxacillin
  • Table 149 A is ciclopirox, B is mesotrione, and C is dicloquinac
  • A is cimifloxazone
  • B is mesotrione
  • C is penoxsulam
  • Table 151 A is ciclopirox, B is mesotrione, and C is chlorofluridin
  • Table 152 A is cimifloxazone, B is mesotrione, and C is grass herb.
  • Table 153 A is ciclopirox, B is mesotrione, and C is grass grass.
  • Table 154 A is ciclopirox, B is ciclosulone, and C is prochlorfen
  • Table 155 A is ciclopirox, B is ciclosulone, and C is butachlor
  • Table 156 A is ciclopirox, B is ciclosulone, and C is fenflufenazone
  • Table 157 A is ciclopirox, B is cisulone, and C is salazaphos
  • Table 158 A is ciclopirox, B is cisulone, and C is bupropion.
  • Table 159 A is ciclopirox, B is cisulone, and C is clomazone
  • Table 160 A is ciclopirox, B is cisulone, and C is isoprolong
  • A is ciclopirox
  • B is ciclosulone
  • C is diazoxyn
  • A is cimifloxazone
  • B is cisulone
  • C is ethoxyflutole
  • A is cimifloxazone
  • B is cisulone
  • C is clomazone
  • Table 164 A is ciclopirox, B is cisulone, and C is 2 methyl 4 chloride
  • Table 165 A is ciclopirox, B is cisulone, and C is ciprofloxacin
  • Table 166 A is ciclopirox, B is ciclosulone, and C is dichloroquinolinic acid
  • A is cimifloxazone
  • B is ciclosulone
  • C is penoxsulam
  • Table 168 A is ciclopirox, B is ciclosulone, and C is chlorofluridin
  • Table 169 A is ciclopirox, B is cisulone, and C is grass.
  • Table 170 A is ciclopirox, B is cisulone, and C is grass grass.
  • Table 172 A is ciclopirox, B is isoxaflutole, and C is butachlor
  • Table 173 A is ciclopirox, B isoxazosin, and C is fenflufenazone
  • A is cimiflufenone
  • B is isoxaflutole
  • C is salazaphos
  • Table 175 A is ciclopirox, B is isoxaflutole, and C is bupropion
  • Table 176 A is ciclopirox, B is isoxaflutole, and C is clomazone
  • Table 177 A is ciclopirox, B is isoxaflutole, and C is isoprolong
  • Table 178 A is ciclopirox, B is isoxaflutole, and C is diazatol
  • Table 180 A is ciclopirox, B is isoxaflutole, and C is clomazone
  • Table 182 A is ciclopirox, B is isoxaflutole, and C is oxacillin
  • Table 185 A is ciclopirox, B isoxazosin, and C is chlorofluridin
  • Table 186 A is ciclopirox, B is isoxaflutole, and C is grass herb
  • Table 187 A is ciclopirox, B is isoxaflutole, and C is grass grass
  • Table 188 A is cimiflufenone, B is dicyclosulfenone, and C is pretilachlor
  • Table 190 A is ciclopirox, B is bicyclosulfazone, and C is fenflufenazone
  • A is ciclopirox
  • B is dicyclosulfazone
  • C is salazaphos
  • Table 192 A is ciclopirofen, B is dicyclosulfenone, and C is bupropion.
  • A is ciclopirox
  • B is dicyclosulfenone
  • C is clomazone
  • Table 195 A is ciclopirox, B is dicyclosulfazone, and C is diflufenacil
  • Table 196 A is cimifloxazone, B is dicyclosulfone, and C is ethoxyflutole
  • A is cimiflufenone
  • B is dicyclosulfone
  • C is clomazone
  • A is ciclopirox
  • B is dicyclosulfazone
  • C is oxacillin
  • Table 200 A is ciclopirox, B is dicyclosulfenone, and C is dichloroquinolinic acid

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Abstract

本发明属于农药领域，具体涉及一种包含HPPD抑制剂类除草剂的三元除草组合物及其应用。所述三元除草组合物，包括除草有效量的活性成分A、B和C，其中，A选自以下HPPD抑制剂类除草剂化合物中的一种或多种：双唑草酮，环吡氟草酮和/或其盐/酯等衍生物；B选自以下化合物中的一种或多种：苯唑草酮，硝磺草酮，环磺酮等和/或其盐/酯等衍生物；C选自以下化合物中的一种或多种：丙草胺，丁草胺，苯噻酰草胺，莎稗磷等和/或其盐/酯等衍生物。该组合物能有效防除作物田中的碎米荠、繁缕、荠菜、牛繁缕、猪殃殃、看麦娘、日本看麦娘、菵草等杂草问题，具有扩大杀草谱、减少施用量、对作物安全、能够产生增效作用并解决抗性杂草等特点。

Description

包含HPPD抑制剂类除草剂的三元除草组合物及其应用 技术领域
本发明属于农药领域，具体涉及一种包含HPPD抑制剂类除草剂的三元除草组合物及其应用。
背景技术
化学除草是农田杂草防除中最为经济、有效的手段，但长期连续高剂量地使用单一品种或单一作用方式的化学除草剂，容易造成杂草耐药和抗性演化等问题。
双唑草酮化学结构式为
Figure PCTCN2018105273-appb-000001
是新研发的小麦田苗后茎叶处理的HPPD抑制剂类除草剂，具有优异的生物活性，可以有效防除小麦田多种恶性杂草。
环吡氟草酮化学结构式为
Figure PCTCN2018105273-appb-000002
属于HPPD抑制剂，通过抑制HPPD酶的活性，使对羟基丙酮酸转化为尿黑酸过程受阻，从而导致生育酚及质体醌无法正常合成，影响靶标体内类胡萝卜素合成，导致叶片发白，影响植物体内光合作用的正常进行，最终彻底死亡。
除草剂化合物的合理复配或混配具有扩大杂草谱、提高防除效果、延缓杂草耐药性和抗药性的发生与发展等优点，是解决上述问题的最为有效的方法之一。因此生产上亟需开发安全性高、杀草谱广、能够产生增效作用并解决抗性杂草问题的除草组合物品种。
发明内容
为解决现有技术中存在的上述问题，本发明提供一种包含HPPD抑制剂类除草剂的三元除草组合物及其应用。该组合物能有效防除作物田中的碎米荠、繁缕、荠菜、牛繁缕、猪殃殃、看麦娘、日本看麦娘、菵草等杂草问题，具有扩大杀草谱、减少施用量、对作物安全、能够产生增效作用并解决抗性杂草等特点。
一种包含HPPD抑制剂类除草剂的三元除草组合物，包括除草有效量的活性成分A、活性成分B和活性成分C，其中，
活性成分A选自以下HPPD抑制剂类除草剂化合物中的一种或多种：双唑草酮(CAS号： 1622908-18-2)，环吡氟草酮(CAS号：1855929-45-1)和/或其盐/酯等衍生物；
活性成分B选自以下化合物中的一种或多种：苯唑草酮(CAS号：210631-68-8)，硝磺草酮(CAS号：104206-82-8)，环磺酮(CAS号：335104-84-2)，异噁唑草酮(CAS号：141112-29-0)，双环磺草酮(CAS号：156963-66-5)，三唑磺草酮(CAS号：1911613-97-2)，苯唑氟草酮(CAS号：1992017-55-6)和/或其盐/酯等衍生物；
活性成分C选自以下化合物中的一种或多种：(1)VLCFA抑制剂：丙草胺(CAS号：51218-49-6)，丁草胺(CAS号：23184-66-9)，苯噻酰草胺(CAS号：73250-68-7)，莎稗磷(CAS号：64249-01-0)；(2)微管组装抑制剂：仲丁灵(CAS号：33629-47-9)；(3)PPO抑制剂：噁草酮(CAS号：19666-30-9)，双唑草腈(CAS号：158353-15-2)，乙氧氟草醚(CAS号：42874-03-3)；(4)PSII抑制剂：异丙隆(CAS号：34123-59-6)，西草净(CAS号：1014-70-6)；(5)DOXP抑制剂：异噁草松(CAS号：81777-89-1)；(5)激素类：2甲4氯(CAS号：94-74-6)，二氯喹啉酸(CAS号：84087-01-4)，氯氟吡啶酯(CAS号：1390661-72-9)；(6)ALS抑制剂：五氟磺草胺(CAS号：219714-96-2)；(7)脂质合成(非ACC)抑制剂：禾草敌(CAS号：2212-67-1)，禾草丹(CAS号：28249-77-6)和/或其盐/酯等衍生物。
在本说明书的上下文中，如果使用活性化合物的通用名称的缩写形式，则在每种情况下包括所有的常规衍生物，例如酯和盐，以及异构体，特别是光学异构体，特别是一种或多种市售形式。如果通用名称表示酯或盐，则在每种情况下还包括所有其他的常规衍生物，例如其他的酯和盐、游离酸和中性化合物，以及异构体，特别是光学异构体，特别是一种或多种市售形式。给出的化合物的化学名称表示至少一种被通用名称涵盖的化合物，通常是优选的化合物。在磺酰胺如磺酰脲的情况下，盐还包括通过阳离子与磺酰胺基团中的氢原子交换而形成的盐。例如，2甲4氯衍生物包含但不限于：2甲4氯钠盐、钾盐、二甲铵盐、异丙胺盐等，以及2甲4氯甲酯、乙酯、异辛酯、乙硫酯等。
在本发明的上下文中，化合物的盐优选为各自的碱金属盐、碱土金属盐或铵盐的形式，优选为各自的碱金属盐的形式，更优选为各自的钠盐或钾盐的形式，最优选为各自的钠盐的形式。
A、B和C的重量比为1～500:0.1～100:1～5000和5～300:0.5～80:5～4000；优选为10～250:0.7～50:10～3000和20～200:1～30:30～2000；更优选为30～150:3～20:50～1000和40～120:5～15:100～800；进一步优选为50～100:7～12:200～600和60～80:8～10:300～500。
所述除草组合物中A、B和C的质量百分含量占总量的1-95％，优选10-80％。
所述除草组合物中还包含常规助剂，所述常规助剂包括载体、表面活性剂。
本文中的术语“载体”表示一种有机或无机、天然或合成的物质。它们有助于活性成分的 施用，该载体一般是惰性的且必须是农业上可接受的，特别是被处理的植物所接受。载体可以是固体的，如陶土、天然或合成的硅酸盐、二氧化硅、树脂、蜡、固体肥料等；或者液体的，如水、醇类、酮类、石油馏分、芳烃或蜡烃、氯代烃、液化气等。
表面活性剂可包括乳化剂、分散剂或润湿剂，它可以是离子型或非离子型的。可提及的实例是聚丙烯酸的盐、木质素磺酸盐、苯酚磺酸或萘磺酸的盐、环氧乙烷与脂肪族醇或与脂族酸或与脂肪族胺与取代苯酚(特别是烷基苯酚或芳基苯酚)的聚合物、磺基琥珀酸盐、牛磺酸衍生物(特别是牛磺酸烷脂)及醇的磷酸酯或多羟乙基化的苯酚的磷酸酯、烷基磺酸盐、烷基芳基磺酸盐、烷基硫酸盐、月桂基醚硫酸盐、脂肪醇硫酸盐，以及硫酸化十六-、十七-和十八烷醇以及硫酸化脂肪醇乙二醇醚，此外还有萘或萘磺酸与苯酚和甲醛的缩合物、聚氧乙烯辛基苯基醚、乙氧基化异辛基酚、辛基酚或壬基酚、烷基苯基聚乙二醇醚、三丁基苯基聚乙二醇醚、三硬脂基苯基聚乙二醇醚、烷基芳基聚醚醇、醇和脂肪醇/氧化乙烯缩合物、乙氧基化蓖麻油、聚氧乙烯烷基醚、乙氧基化聚氧丙烯、月桂醇聚乙二醇醚缩醛、山梨醇酯、木素亚硫酸盐废液，以及蛋白质、变性蛋白、多糖(例如甲基纤维素)、疏水改性淀粉、聚乙烯醇、聚羧酸盐、聚烷氧基化物、聚乙烯胺、聚乙烯吡咯烷酮及其共聚物。至少需要一种表面活性剂存在，以有利于活性成分在水中的分散并有利于使它们能正确地施用于植物。
上述组合物也可含有各种其他的组分，如保护胶体、粘合剂、增稠剂、触变剂、渗透剂、稳定剂、螯合剂、染料、着色剂和聚合物。
另外，本发明的三元组合物可以与以下活性物质混合，例如《世界农药新品种技术大全》，中国农业科学技术出版社，2010.9和这里引用的文献中的已知物质。例如以下提到的除草剂活性物质，(备注:化合物的名称，或者为根据国际标准化组织(ISO)的普通名称，或者为化学名称，适当的时候有代号):乙草胺、丁草胺、甲草胺、异丙草胺、异丙甲草胺、精异丙甲草胺、丙草胺、毒草胺、克草胺、萘丙酰草胺、R-左旋萘丙酰草胺、敌稗、苯噻酰草胺、双苯酰草胺、吡氟酰草胺、杀草胺、氟丁酰草胺、溴丁酰草胺、二甲噻草胺、高效二甲噻草胺、乙氧苯草胺、氟噻草胺、甲氧噻草胺、吡草胺、异恶草胺、高效麦草伏甲酯、高效麦草伏丙酯、二丙烯草胺、烯草胺、丁酰草胺、环丙草胺、氟磺酰草胺、庚酰草胺、异丁草胺、丙炔草胺、特丁草胺、二甲苯草胺、二甲草胺、落草胺、三甲环草胺、氯甲酰草胺、炔苯酰草胺、戊酰苯草胺、卡草胺、新燕灵、三环赛草胺、丁烯草胺、牧草胺、苄草胺、醌萍胺、苯氟磺胺、萘丙胺、乙酰甲草胺、萘草胺、噻草胺、吡氰草胺、苯草多克死、草克乐、氯酞亚胺、丁脒胺、氟吡草胺、莠去津、西玛津、扑草净、氰草净、西草净、莠灭净、扑灭津、异丙净、氟草净、特丁净、特丁津、三嗪氟草胺、环丙津、甘扑津、草达津、扑灭通、西玛通、叠氮净、敌草净、异戊乙净、环丙青津、灭莠津、另丁津、仲丁通、特丁通、甲氧丙净、 氰草净、抑草津、可乐津、莠去通、灭草通、甘草津、三聚氰酸、Indaziflam、绿磺隆、甲磺隆、苄嘧磺隆、氯嘧黄隆、苯磺隆、噻磺隆、吡嘧黄隆、甲基二磺隆、甲基碘磺隆钠盐、甲酰氨基嘧磺隆、醚磺隆、醚苯磺隆、甲嘧磺隆、烟嘧磺隆、胺苯磺隆、酰嘧磺隆、乙氧嘧磺隆、环丙嘧磺隆、砜嘧磺隆、四唑嘧磺隆、啶嘧黄隆、单嘧磺隆、单嘧磺酯、氟唑磺隆、氟啶嘧磺隆、氟吡嘧磺隆、环氧嘧磺隆、唑吡嘧磺隆、氟嘧磺隆、丙苯磺隆、三氟丙磺隆、磺酰磺隆、三氟啶磺隆、氟胺磺隆、三氟甲磺隆、甲磺隆钠盐、氟吡磺隆、甲硫嘧磺隆、嘧苯胺磺隆、Propyrisulfuron(丙嗪嘧磺隆)、嗪吡嘧磺隆、三氟羧草醚、氟磺胺草醚、乳氟禾草灵、乙羧氟草醚、乙氧氟草醚、草枯醚、苯草醚、氯氟草醚乙酯、甲羧除草醚、三氟甲草醚、甲氧除草醚、三氟硝草醚、氟化除草醚、氟呋草醚、除草醚、甲草醚、二甲草醚、氟酯肟草醚、氟草醚酯、Halosafen、绿麦隆、异丙隆、利谷隆、敌草隆、莎扑隆、氟草隆、苯噻隆、甲基苯噻隆、苄草隆、磺噻隆、异恶隆、特丁噻草隆、炔草隆、氯溴隆、甲基杀草隆、酰草隆、甲氧杀草隆、溴谷隆、甲氧隆、绿谷隆、灭草隆、环草隆、非草隆、氟硫隆、草不隆、枯草隆、草完隆、异草完隆、环莠隆、噻氟隆、丁噻隆、枯莠隆、对氟隆、甲胺噻唑隆、隆草特、三甲异脲、恶唑隆、Monisouron、Anisuron、Methiuron、Chloreturon、四氟隆、甜菜宁、甜菜宁-乙酯、甜菜安、磺草灵、特草灵、燕麦灵、苯胺灵、氯苯胺灵、二氯苄草酯、灭草灵、氯炔灵、Carboxazole、Chlorprocarb、Fenasulam、BCPC、CPPC、Carbasulam、丁草特、禾草丹、灭草猛、禾草特、野麦畏、哌草丹、禾草畏、稗草丹、环草敌、燕麦敌、菌达灭、乙硫草特、坪草丹、克草猛、苄草丹、仲草丹、硫烯草丹、草灭散、Isopolinate、Methiobencarb、2,4-D异辛酯丁酯、2甲4氯钠、2,4-D异辛酯异辛酯、2甲4氯异辛酯、2,4-D异辛酯钠盐、2,4-D异辛酯二甲胺盐、2甲4氯乙硫酯、2甲4氯、2,4-D异辛酯丙酸、高2,4-D异辛酯丙酸盐、2,4-D异辛酯丁酸、2甲4氯丙酸、2甲4氯丙酸盐、2甲4氯丁酸、2,4,5-涕、2,4,5-涕丙酸、2,4,5-涕丁酸、2甲4氯胺盐、麦草畏、抑草蓬、伐草克、赛松、三氯苯酸、氨二氯苯酸、甲氧三氯苯酸、禾草灵、吡氟禾草灵、精吡氟禾草灵、氟吡甲禾灵、高效吡氟氯禾灵、喹禾灵、精喹禾灵、恶唑禾草灵、精恶唑禾草灵、喔草酯、氰氟草酯、恶唑酰草胺、炔草酯、噻唑禾草灵、炔禾灵、羟戊禾灵、三氟禾草肟、异恶草醚、百草枯、敌草快、安磺灵、乙丁烯氟灵、异丙乐灵、甲磺乐灵、环丙氟灵、氨基丙氟灵、乙丁氟灵、氯乙氟灵、氨基乙氟灵、地乐灵、氯乙地乐灵、Methalpropalin、丙硝酚、草甘膦、莎稗膦、草铵膦、甲基胺草磷、草硫膦、哌草膦、双丙氨膦、地散磷、抑草磷、蔓草磷、伐垅磷、双甲胺草磷、草特磷、咪唑烟酸、咪唑乙烟酸、咪唑喹啉酸、甲氧咪草烟、甲氧咪草烟铵盐、甲咪唑烟酸、咪草酯、氯氟吡氧乙酸、氯氟吡氧乙酸异辛酯、二氯吡啶酸、氨氯吡啶酸、三氯吡氧乙酸、氟硫草定、卤草定、三氯吡啶酚、噻草啶、氟啶草酮、氯氨吡啶酸、氟吡草腙、三氯吡氧乙酸丁氧基乙 酯、Cliodinate、稀禾啶、烯草酮、噻草酮、禾草灭、环苯草酮、丁苯草酮、肟草酮、吡喃草酮、Buthidazole、嗪草酮、环嗪酮、苯嗪草酮、乙嗪草酮、Ametridione、Amibuzin、溴苯腈、辛酰溴苯腈、辛酰碘苯腈、碘苯腈、敌草腈、二苯乙腈、双唑草腈、羟敌草腈、Iodobonil、唑嘧磺草胺、双氟磺草胺、五氟磺草胺、磺草唑胺、氯酯磺草胺、双氯磺草胺、啶磺草胺、氟草黄、双草醚、嘧啶肟草醚、环酯草醚、嘧草醚、嘧硫草醚、双环磺草酮、硝磺草酮、磺草酮、Tembotrione、Tefuryltrione、Bicyclopyrone、Ketodpiradox、异恶唑草酮、异恶氯草酮、Fenoxasulfone、Methiozolin、异丙吡草酯、吡草醚、吡唑特、野燕枯、苄草唑、吡草酮、吡氯草胺、Pyrasulfotole、苯唑草酮、Pyroxasulfone、唑草胺、氟胺草唑、杀草强、氨唑草酮、唑啶草酮、氟唑草酮、甲磺草胺、Bencarbazone、双苯嘧草酮、氟丙嘧草酯、除草定、异草定、环草啶、特草定、Flupropacil、吲哚酮草酯、氟烯草酸、丙炔氟草胺、炔草胺、酞苄醚、Flumezin、五氯酚(钠)、地乐酚、特乐酚、特乐酯、戊硝酚、二硝酚、氯硝酚、地乐施、地乐特、丙炔恶草酮、恶草酮、环戊恶草酮、氟唑草胺、嗪草酸甲酯、四唑酰草胺、氟哒嗪草酯、杀草敏、溴莠敏、二甲达草伏、哒草醚、草哒酮、草哒松、哒草伏、Pyridafol、二氯喹啉酸、氯甲喹啉酸、苯达松、哒草特、恶嗪草酮、草除灵、异恶草酮、环庚草醚、异丙酯草醚、丙酯草醚、茚草酮、氯酸钠、茅草枯、三氯醋酸、一氯醋酸、六氯丙酮、四氟丙酸、牧草快、溴酚肟、三唑磺、灭杀唑、呋草酮、呋草磺、乙呋草磺、嘧草胺、氯酞酸、氟咯草酮、稗草稀、丙烯醛、苯草灭、灭草环、燕麦酯、噻二唑草胺、棉胺宁、羟草酮、甲氧苯酮、苯嘧磺草胺、氯酰草膦、三氯丙酸、Alorac、Diethamquat、Etnipromid、Iprymidam、Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、Tripropindan、Sulglycapin、甲硫磺乐灵、Cambendichlor、环丙嘧啶酸、硫氰苯胺、解草酮、解草啶、解草安、解草唑、解草喹、解草腈、解草烷、解草胺腈、解草烯、吡唑解草酯、呋喃解草唑、肟草安、双苯噁唑酸、二氯丙烯胺、氟氯吡啶酯、DOW氯氟吡啶酯、UBH-509、D489，LS 82-556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、KIH-6127和KIH-2023。
所述除草组合物进一步包括至少一种安全剂，其选自：
a)二氯苯基吡唑啉-3-羧酸(S1)类化合物，优选的化合物为例如1-(2,4-二氯苯基)-5-(乙氧基羰基)-5-甲基-2-吡唑啉-3-羧酸乙酯(S1-1，吡唑解草酯(mefenpyr-diethyl)，PM，第594-595页)，以及记载于例如WO91/07874和PM(第594-595页)中的相关化合物。
b)二氯苯基吡唑羧酸衍生物，优选的化合物为例如1-(2,4-二氯苯基)-5-甲基吡唑-3-羧酸乙酯(S1-2)、1-(2,4-二氯苯基)-5-异丙基吡唑-3-羧酸乙酯(S1-3)、1-(2,4-二氯苯基)-5-(1,1-二甲基-乙基)吡唑-3-羧酸乙酯(S1-4)、1-(2,4-二氯苯基)-5-苯基吡唑-3-羧酸乙酯(S1-5)，以及记载于 EP-A-333131和EP-A-269806中的相关化合物。
c)三唑羧酸(S1)类化合物，优选的化合物为例如解草唑(fenchlorazole)，即1-(2,4-二氯苯基)-5-三氯甲基-(1H)-1,2,4-三唑-3-羧酸乙酯(S1-6)及相关化合物(参见EP-A-174562和EP-A-346620)。
d)5-苄基-或5-苯基-2-异噁唑啉-3-羧酸类或5,5-二苯基-2-异噁唑啉-3-羧酸类化合物，优选的化合物为例如5-(2,4-二氯苄基)-2-异噁唑啉-3-羧酸乙酯(S1-7)或5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-8)及记载于WO91/08202中的相关化合物，或记载于专利申请(WO-A-95/07897)中的5,5-二苯基-2-异噁唑啉-3-羧酸乙酯(S1-9，双苯噁唑酸(isoxadifen-ethyl))或5,5-二苯基-2-异噁唑啉-3-羧酸正丙酯(S1-10)或5-(4-氟苯基)-5-苯基-2-异噁唑啉-3-羧酸乙酯(S1-11)。
e)8-喹啉氧基乙酸(S2)类化合物，优选1-甲基己-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-1，解毒喹(cloquintocet-mexyl)，如PM(第195-196页)，(1,3-二甲基丁-1-基)(5-氯-8-喹啉氧基)乙酸酯(S2-2)，4-烯丙基氧基丁基(5-氯-8-喹啉氧基)乙酸酯(S2-3)，1-烯丙基氧基丙-2-基(5-氯-8-喹啉氧基)乙酸酯(S2-4)，(5-氯-8-喹啉氧基)乙酸乙酯(S2-5)，(5-氯-8-喹啉氧基)乙酸甲酯(S2-6)，(5-氯-8-喹啉氧基)乙酸烯丙酯(S2-7)，2-(2-亚丙基亚氨基氧基)-1-乙基(5-氯-8-喹啉氧基)乙酸酯(S2-8)，2-氧代丙-1-基(5-氯-8-喹啉氧基)乙酸酯(S2-9)，以及记载于EP-A-86750、EP-A-94349和EP-A-191736或EP-A-0492366中的相关化合物。
f)(5-氯-8-喹啉氧基)丙二酸类化合物，优选的化合物为例如(5-氯-8-喹啉氧基)丙二酸二乙酯、(5-氯-8-喹啉氧基)丙二酸二烯丙酯、(5-氯-8-喹啉氧基)-丙二酸甲基乙酯和记载于EP-A-0582198中的相关化合物。
g)苯氧基乙酸、苯氧基丙酸或芳族羧酸类活性化合物，例如2,4-二氯苯氧基乙酸(和酯)(2,4-D)、4-氯-2-甲基苯氧基丙酸酯(2-甲-4-氯丙酸(mecoprop))、MCPA或3,6-二氯-2-甲氧基苯甲酸(和酯)(麦草畏(dicamba))。
h)嘧啶类活性化合物，例如“解草啶(fenclorim)”(PM，第386-387页)(＝4,6-二氯-2-苯基嘧啶)，
i)二氯乙酰胺类活性化合物，其常用作苗前安全剂(作用于土壤的安全剂)，例如“二氯丙烯胺(dichloromid)”(PM，第270-271页)(＝N,N-二烯丙基-2,2-二氯乙酰胺)，“AR-29148”(＝3-二氯乙酰基-2,2,5-三甲基-1,3-噁唑烷酮，购自Stauffer)，“解草嗪(benoxacor)”(PM，第74-75页)(＝4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并噁嗪)，“APPG-1292”(＝N-烯丙基-N[(1,3-二氧戊环-2-基)-甲基]二氯乙酰胺，购自PPG Industries)，“ADK-24”(＝N-烯丙基-N-[(烯丙基氨基羰基)-甲基]-二氯乙酰胺，购自Sagro-Chem)，“AAD-67”或“AMON4660”(＝3-二氯乙酰基-1-氧杂-3-氮杂-螺[4,5]癸烷，购自Nitrokemia或Monsanto)，“diclonon”或“ABAS145138” 或“ALAB145138”(＝(＝3-二氯乙酰基-2,5,5-三甲基-1,3-二氮杂双环[4.3.0]壬烷，购自BASF)，和“furilazol”或“AMON13900”(参见PM，482-483)(＝(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基噁唑烷酮)，
j)二氯丙酮衍生物类活性化合物，例如，“AMG191”(CAS登记号96420-72-3)(＝2-二氯甲基-2-甲基-1,3-二氧戊环，购自Nitrokemia)，
k)氧基亚氨基化合物类活性化合物，其被称为拌种材料，例如，“解草腈(oxabetrinil)”(PM，第689页)(＝(Z)-1,3-二氧戊环-2-基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，“氟草肟(fluxofenim)”(PM，第467-468页)(＝1-(4-氯苯基)-2,2,2-三氟-1-乙酮O-(1,3-二氧戊环-2-基甲基)-肟，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，和“解草胺腈(cyometrinil)”或“A-CGA-43089”(PM，第983页)(＝(Z)-氰基甲氧基亚氨基(苯基)乙腈)，其在拌种中称为安全剂，以防止异丙甲草胺(metolachlor)的损害，
l)噻唑羧酸酯类活性化合物，其被称为拌种材料，例如“解草安(flurazol)”(PM，第450-451页)(＝2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯)，其在拌种中被称为安全剂，以防止甲草胺(alachlor)和异丙甲草胺的损害，
m)萘二羧酸衍生物类活性化合物，其被称为拌种剂，例如“萘二甲酸酐”(PM，第1009-1010页)(＝1,8-萘二甲酸酐)，其在玉米拌种中称为安全剂，以防止硫代氨基甲酸酯除草剂的损害，
n)色满乙酸(chromaneaceticacid)衍生物类活性化合物，例如，“ACL304415”(CAS登记号31541-57-8)(＝2-84-羧基色满-4-基)乙酸，购自AmericanCyanamid)，
o)除了对有害植物具有除草作用外还对作物植物具有安全剂作用的活性化合物，例如，“哌草丹(dimepiperate)”或“AMY-93”(PM，第302-303页)(＝S-1-甲基-1-苯基乙基哌啶-1-硫代羧酸酯)，“杀草隆(daimuron)”或“ASK23”(PM，第247页)(＝1-(1-甲基-1-苯基乙基)-3-对甲苯基脲)，“苄草隆(cumyluron)”＝“AJC-940”(＝3-(2-氯苯基甲基)-1-(1-甲基-1-苯基-乙基)脲，参见JP-A-60087254)，“苯甲酮(methoxyphenon)”或“ANK049”(＝3,3'-二甲基-4-甲氧基-二苯甲酮)，“CSB”(＝1-溴-4-(氯甲基磺酰基)苯)(CAS登记号54091-06-4，购自Kumiai)。
所述安全剂优选双苯噁唑酸(CAS：163520-33-0)、cyprosulfamide(CAS：221667-31-8)、吡唑解草酯(CAS：135590-91-9)、解毒喹(CAS：99607-70-2)、赤霉酸(CAS：7-06-5)、furilazole(CAS：121776-33-8)、metcamifen(CAS：129531-12-0)中的一种或多种。
本发明的组合物可以由使用者在使用前经稀释或直接使用。其配制可由通常的加工方法制备，即将活性物质与液体溶剂或固体载体混合后，再加入表面活性剂如分散剂、稳定剂、湿润剂、粘合剂、消泡剂等中的一种或几种。
所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂(干悬浮剂)、水乳剂、微乳剂。
简而言之，本发明的组合物可以和现有技术的配方中常规使用的固体和液体添加剂混合。
本发明还提供一种所述三元除草组合物在防治作物中杂草上的应用；以及提供一种防治不想要的植物生长的方法，其包括将所述三元除草组合物施用于植物、植物部位、植物种子或植物生长的区域，优选用于选择性防治作物中的杂草。
另外，本发明的组合物可通过喷雾的方法被施用于待处理植物叶片上，即施用于杂草，特别是对作物生长有害的杂草侵扰或易侵扰影响的表面上。
当施用本发明的除草组合物时，获得了预料不到的增效效果，并且除草活性比使用单个除草剂的活性预期总和，以及单个或其中任两个除草剂组合的活性更为显著。增效效果表现为施用量减少、更宽的杂草控制谱、除草作用更快、更持久，这些特性是杂草控制实践过程中所需要的。就所描述的特性来说，这些新组合物明显地优越于现有的除草剂，达到减量使用，对环境更友好。
本发明的增效除草组合物还具有下述优点:
(1)本发明的组合物为环境友好型，在环境中均易于降解，适用于多种作物田。
(2)本发明的除草组合物成本低、使用方便，其推广应用有巨大的经济效益和社会效益。
具体实施方式
下列实施例并非限制本发明，而只是用来说明本发明是如何实现的。对于某些杂草，这些实施例显示出特别显著的有效性。举例如下:
A)实施例
1.双唑草酮+苯唑草酮+丙草胺(4+3+30)悬乳剂
4％双唑草酮+3％苯唑草酮+30％丙草胺+3％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+4％蓖麻油聚氧乙烯醚+2％丁醇嵌段聚醚+0.12％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
2.双唑草酮+苯唑草酮+丁草胺(2+1.5+30)可分散油悬浮剂
2％双唑草酮+1.5％苯唑草酮+30％丁草胺+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
3.双唑草酮+苯唑草酮+苯噻酰草胺(4+3+30)水悬浮剂
4％双唑草酮+3％苯唑草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.3％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
4.双唑草酮+苯唑草酮+莎稗磷(4+3+15)可分散油悬浮剂
4％双唑草酮+3％苯唑草酮+15％莎稗磷+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
5.双唑草酮+苯唑草酮+仲丁灵(2+1.5+24)可分散油悬浮剂
2％双唑草酮+1.5％苯唑草酮+24％仲丁灵+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
6.双唑草酮+苯唑草酮+噁草酮(4+3+30)水悬浮剂
4％双唑草酮+3％苯唑草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐 +0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
7.双唑草酮+苯唑草酮+异丙隆(4+3+45)水分散粒剂
4％双唑草酮+3％苯唑草酮+45％异丙隆+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
8.双唑草酮+苯唑草酮+双唑草腈(4+3+14)可分散油悬浮剂
4％双唑草酮+3％苯唑草酮+14％双唑草腈+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1.3％有机膨润土+1.2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
9.双唑草酮+苯唑草酮+乙氧氟草醚(4+3+12)可分散油悬浮剂
4％双唑草酮+3％苯唑草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1.6％有机膨润土+1.6％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
10.双唑草酮+苯唑草酮+异噁草松(4+3+16)可分散油悬浮剂
4％双唑草酮+3％苯唑草酮+16％异噁草松+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1.6％有机膨润土+1.6％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
11.双唑草酮+苯唑草酮+2甲4氯(4+3+18)可分散油悬浮剂
4％双唑草酮+3％苯唑草酮+18％2甲4氯+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
12.双唑草酮+苯唑草酮+西草净(2+1.5+30)水悬浮剂
2％双唑草酮+1.5％苯唑草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
13.双唑草酮+苯唑草酮+二氯喹啉酸(4+3+25)水悬浮剂
4％双唑草酮+3％苯唑草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
14.双唑草酮+苯唑草酮+五氟磺草胺(4+3+2)可分散油悬浮剂
4％双唑草酮+3％苯唑草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
15.双唑草酮+苯唑草酮+氯氟吡啶酯(4+3+1)可分散油悬浮剂
4％双唑草酮+3％苯唑草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+6％脂肪醇聚氧乙烯醚+5％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
16.双唑草酮+苯唑草酮+禾草敌(1+0.75+50)可分散油悬浮剂
1％双唑草酮+0.75％苯唑草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
17.双唑草酮+苯唑草酮+禾草丹(1+0.75+50)可分散油悬浮剂
1％双唑草酮+0.75％苯唑草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
18.双唑草酮+硝磺草酮+丙草胺(4+10+30)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
19.双唑草酮+硝磺草酮+丁草胺(2+5+30)可分散油悬浮剂
2％双唑草酮+5％硝磺草酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
20.双唑草酮+硝磺草酮+苯噻酰草胺(4+10+30)水悬浮剂
4％双唑草酮+10％硝磺草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
21.双唑草酮+硝磺草酮+莎稗磷(4+10+15)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
22.双唑草酮+硝磺草酮+仲丁灵(2+5+24)可分散油悬浮剂
2％双唑草酮+5％硝磺草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
23.双唑草酮+硝磺草酮+噁草酮(4+10+30)水悬浮剂
4％双唑草酮+10％硝磺草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
24.双唑草酮+硝磺草酮+异丙隆(4+10+45)水分散粒剂
4％双唑草酮+10％硝磺草酮+45％异丙隆+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
25.双唑草酮+硝磺草酮+双唑草腈(4+10+14)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.0％有机膨润土+1.0％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
26.双唑草酮+硝磺草酮+乙氧氟草醚(4+10+12)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.6％气相法白炭黑+15％100#溶剂油+油酸甲酯补足
27.双唑草酮+硝磺草酮+异噁草松(4+10+16)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+16％异噁草松+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+5％100#溶剂油+油酸甲酯补足
28.双唑草酮+硝磺草酮+2甲4氯(4+10+18)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+18％2甲4氯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+15％100#溶剂油+油酸甲酯补足
29.双唑草酮+硝磺草酮+西草净(2+5+30)水悬浮剂
2％双唑草酮+5％硝磺草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
30.双唑草酮+硝磺草酮+二氯喹啉酸(4+10+25)水悬浮剂
4％双唑草酮+10％硝磺草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
31.双唑草酮+硝磺草酮+五氟磺草胺(4+10+2)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+1.6％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
32.双唑草酮+硝磺草酮+氯氟吡啶酯(4+10+1)可分散油悬浮剂
4％双唑草酮+10％硝磺草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+1.6％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
33.双唑草酮+硝磺草酮+禾草敌(1+2.5+50)可分散油悬浮剂
1％双唑草酮+2.5％硝磺草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
34.双唑草酮+硝磺草酮+禾草丹(1+2.5+50)可分散油悬浮剂
1％双唑草酮+2.5％硝磺草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
35.双唑草酮+环磺酮+丙草胺(4+6+30)可分散油悬浮剂
4％双唑草酮+6％环磺酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
36.双唑草酮+环磺酮+丁草胺(2+3+30)可分散油悬浮剂
2％双唑草酮+3％环磺酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
37.双唑草酮+环磺酮+苯噻酰草胺(4+6+30)水悬浮剂
4％双唑草酮+6％环磺酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
38.双唑草酮+环磺酮+莎稗磷(4+6+15)可分散油悬浮剂
4％双唑草酮+6％环磺酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
39.双唑草酮+环磺酮+仲丁灵(2+3+24)可分散油悬浮剂
2％双唑草酮+3％环磺酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
40.双唑草酮+环磺酮+噁草酮(4+6+30)水悬浮剂
4％双唑草酮+6％环磺酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
41.双唑草酮+环磺酮+异丙隆(4+6+45)水分散粒剂
4％双唑草酮+6％环磺酮+45％异丙隆+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
42.双唑草酮+环磺酮+双唑草腈(4+6+14)可分散油悬浮剂
4％双唑草酮+6％环磺酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+10％100#溶剂油+油酸甲酯补足
43.双唑草酮+环磺酮+乙氧氟草醚(4+6+12)可分散油悬浮剂
4％双唑草酮+6％环磺酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
44.双唑草酮+环磺酮+异噁草松(4+6+16)可分散油悬浮剂
4％双唑草酮+6％环磺酮+16％异噁草松+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+10％100#溶剂油+油酸甲酯补足
45.双唑草酮+环磺酮+2甲4氯(4+6+18)可分散油悬浮剂
4％双唑草酮+6％环磺酮+18％2甲4氯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+10％100#溶剂油+油酸甲酯补足
46.双唑草酮+环磺酮+西草净(2+3+30)水悬浮剂
2％双唑草酮+3％环磺酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
47.双唑草酮+环磺酮+二氯喹啉酸(4+6+25)水悬浮剂
4％双唑草酮+6％环磺酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
48.双唑草酮+环磺酮+五氟磺草胺(4+6+2)可分散油悬浮剂
4％双唑草酮+6％环磺酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
49.双唑草酮+环磺酮+氯氟吡啶酯(4+6+1)可分散油悬浮剂
4％双唑草酮+6％环磺酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
50.双唑草酮+环磺酮+禾草敌(1+1.5+50)可分散油悬浮剂
1％双唑草酮+1.5％环磺酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
51.双唑草酮+环磺酮+禾草丹(1+1.5+50)可分散油悬浮剂
1％双唑草酮+1.5％环磺酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
52.双唑草酮+异噁唑草酮+丙草胺(4+6+30)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧 乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
53.双唑草酮+异噁唑草酮+丁草胺(2+3+30)可分散油悬浮剂
2％双唑草酮+3％异噁唑草酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
54.双唑草酮+异噁唑草酮+苯噻酰草胺(4+6+30)水悬浮剂
4％双唑草酮+6％异噁唑草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
55.双唑草酮+异噁唑草酮+莎稗磷(4+6+15)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
56.双唑草酮+异噁唑草酮+仲丁灵(2+3+24)可分散油悬浮剂
2％双唑草酮+3％异噁唑草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
57.双唑草酮+异噁唑草酮+噁草酮(4+6+30)水悬浮剂
4％双唑草酮+6％异噁唑草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
58.双唑草酮+异噁唑草酮+异丙隆(4+6+45)水分散粒剂
4％双唑草酮+6％异噁唑草酮+45％异丙隆+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
59.双唑草酮+异噁唑草酮+双唑草腈(4+6+14)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+10％100#溶剂油+油酸甲酯补足
60.双唑草酮+异噁唑草酮+乙氧氟草醚(4+6+12)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+15％100#溶剂油+油酸甲酯补足
61.双唑草酮+异噁唑草酮+异噁草松(4+6+16)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+16％异噁草松+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
62.双唑草酮+异噁唑草酮+2甲4氯(4+6+18)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+18％2甲4氯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.0％有机膨润土+0.8％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
63.双唑草酮+异噁唑草酮+西草净(2+3+30)水悬浮剂
2％双唑草酮+3％异噁唑草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
64.双唑草酮+异噁唑草酮+二氯喹啉酸(4+6+25)水悬浮剂
4％双唑草酮+6％异噁唑草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
65.双唑草酮+异噁唑草酮+五氟磺草胺(4+6+2)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
66.双唑草酮+异噁唑草酮+氯氟吡啶酯(4+6+1)可分散油悬浮剂
4％双唑草酮+6％异噁唑草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+5％100#溶剂油+油酸甲酯补足
67.双唑草酮+异噁唑草酮+禾草敌(1+1.5+50)可分散油悬浮剂
1％双唑草酮+1.5％异噁唑草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
68.双唑草酮+异噁唑草酮+禾草丹(1+1.5+50)可分散油悬浮剂
1％双唑草酮+1.5％异噁唑草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
69.双唑草酮+双环磺草酮+丙草胺(4+20+30)可分散油悬浮剂
4％双唑草酮+20％双环磺草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.8％气相法白炭黑+油酸甲酯补足
70.双唑草酮+双环磺草酮+丁草胺(1+5+15)可分散油悬浮剂
1％双唑草酮+5％双环磺草酮+15％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
71.双唑草酮+双环磺草酮+苯噻酰草胺(4+20+30)水分散粒剂
4％双唑草酮+20％双环磺草酮+30％苯噻酰草胺+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
72.双唑草酮+双环磺草酮+莎稗磷(4+20+15)可分散油悬浮剂
4％双唑草酮+20％双环磺草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
73.双唑草酮+双环磺草酮+仲丁灵(2+10+24)可分散油悬浮剂
2％双唑草酮+10％双环磺草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
74.双唑草酮+双环磺草酮+噁草酮(4+20+30)水分散粒剂
4％双唑草酮+20％双环磺草酮+30％噁草酮+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
75.双唑草酮+双环磺草酮+异丙隆(2+10+22.5)水悬浮剂
2％双唑草酮+10％双环磺草酮+22.5％异丙隆+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
76.双唑草酮+双环磺草酮+双唑草腈(4+20+14)水悬浮剂
4％双唑草酮+20％双环磺草酮+14％双唑草腈+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
77.双唑草酮+双环磺草酮+乙氧氟草醚(4+20+12)可分散油悬浮剂
4％双唑草酮+20％双环磺草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.6％气相法白炭黑+15％100#溶剂油+油酸甲酯补足
78.双唑草酮+双环磺草酮+异噁草松(4+20+16)水悬浮剂
4％双唑草酮+20％双环磺草酮+16％异噁草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
79.双唑草酮+双环磺草酮+2甲4氯(4+20+18)水悬浮剂
4％双唑草酮+20％双环磺草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
80.双唑草酮+双环磺草酮+西草净(1+5+15)可分散油悬浮剂
1％双唑草酮+5％双环磺草酮+15％西草净+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.6％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
81.双唑草酮+双环磺草酮+二氯喹啉酸(4+20+25)水悬浮剂
4％双唑草酮+20％双环磺草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.07％黄原胶+0.7％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
82.双唑草酮+双环磺草酮+五氟磺草胺(4+20+2)可分散油悬浮剂
4％双唑草酮+20％双环磺草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.4％有机膨润土+1.0％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
83.双唑草酮+双环磺草酮+氯氟吡啶酯(4+20+1)可分散油悬浮剂
4％双唑草酮+20％双环磺草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.4％有机膨润土+1.0％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
84.双唑草酮+双环磺草酮+禾草敌(1+5+50)可分散油悬浮剂
1％双唑草酮+5％双环磺草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
85.双唑草酮+双环磺草酮+禾草丹(1+5+50)可分散油悬浮剂
1％双唑草酮+5％双环磺草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
86.双唑草酮+三唑磺草酮+丙草胺(4+12+30)可分散油悬浮剂
4％双唑草酮+12％三唑磺草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足
87.双唑草酮+三唑磺草酮+丁草胺(2+6+30)可分散油悬浮剂
2％双唑草酮+6％三唑磺草酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
88.双唑草酮+三唑磺草酮+苯噻酰草胺(4+12+30)水悬浮剂
4％双唑草酮+12％三唑磺草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.07％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
89.双唑草酮+三唑磺草酮+莎稗磷(4+12+15)可分散油悬浮剂
4％双唑草酮+12％三唑磺草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
90.双唑草酮+三唑磺草酮+仲丁灵(2+6+24)可分散油悬浮剂
2％双唑草酮+6％三唑磺草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
91.双唑草酮+三唑磺草酮+噁草酮(4+12+30)水悬浮剂
4％双唑草酮+12％三唑磺草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.07％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
92.双唑草酮+三唑磺草酮+异丙隆(2+6+22.5)可分散油悬浮剂
2％双唑草酮+6％三唑磺草酮+22.5％异丙隆+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
93.双唑草酮+三唑磺草酮+双唑草腈(4+12+14)可分散油悬浮剂
4％双唑草酮+12％三唑磺草酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+10％100#溶剂油+油酸甲酯补足
94.双唑草酮+三唑磺草酮+乙氧氟草醚(4+12+12)可分散油悬浮剂
4％双唑草酮+12％三唑磺草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+15％100#溶剂油+油酸甲酯补足
95.双唑草酮+三唑磺草酮+异噁草松(4+12+16)水悬浮剂
4％双唑草酮+12％三唑磺草酮+16％异噁草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
96.双唑草酮+三唑磺草酮+2甲4氯(4+12+18)水悬浮剂
4％双唑草酮+12％三唑磺草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
97.双唑草酮+三唑磺草酮+西草净(2+6+30)水悬浮剂
2％双唑草酮+6％三唑磺草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16％黄原胶+1.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
98.双唑草酮+三唑磺草酮+二氯喹啉酸(4+12+25)水悬浮剂
4％双唑草酮+12％三唑磺草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙 醇胺盐+0.16％黄原胶+1.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
99.双唑草酮+三唑磺草酮+五氟磺草胺(4+12+2)可分散油悬浮剂
4％双唑草酮+12％三唑磺草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
100.双唑草酮+三唑磺草酮+氯氟吡啶酯(4+12+1)可分散油悬浮剂
4％双唑草酮+12％三唑磺草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.2％有机膨润土+2.0％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
101.双唑草酮+三唑磺草酮+禾草敌(1+3+50)可分散油悬浮剂
1％双唑草酮+3％三唑磺草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
102.双唑草酮+三唑磺草酮+禾草丹(1+3+50)可分散油悬浮剂
1％双唑草酮+3％三唑磺草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
103.双唑草酮+苯唑氟草酮+丙草胺(4+12+30)可分散油悬浮剂
4％双唑草酮+12％苯唑氟草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
104.双唑草酮+苯唑氟草酮+丁草胺(2+6+30)可分散油悬浮剂
2％双唑草酮+6％苯唑氟草酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
105.双唑草酮+苯唑氟草酮+苯噻酰草胺(4+12+30)水悬浮剂
4％双唑草酮+12％苯唑氟草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
106.双唑草酮+苯唑氟草酮+莎稗磷(4+12+15)可分散油悬浮剂
4％双唑草酮+12％苯唑氟草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
107.双唑草酮+苯唑氟草酮+仲丁灵(2+6+24)可分散油悬浮剂
2％双唑草酮+6％苯唑氟草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
108.双唑草酮+苯唑氟草酮+噁草酮(4+12+30)水悬浮剂
4％双唑草酮+12％苯唑氟草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
109.双唑草酮+苯唑氟草酮+异丙隆(2+6+22.5)可分散油悬浮剂
2％双唑草酮+6％苯唑氟草酮+22.5％异丙隆+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.5％有机膨润土+10％100#溶剂油+油酸甲酯补足
110.双唑草酮+苯唑氟草酮+双唑草腈(4+12+14)可分散油悬浮剂
4％双唑草酮+12％苯唑氟草酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+10％100#溶剂油+油酸甲酯补足
111.双唑草酮+苯唑氟草酮+乙氧氟草醚(4+12+12)可分散油悬浮剂
4％双唑草酮+12％苯唑氟草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.4％有机膨润土+1.2％气相法白炭黑+15％100#溶剂油+油酸甲酯补足
112.双唑草酮+苯唑氟草酮+异噁草松(4+12+16)水悬浮剂
4％双唑草酮+12％苯唑氟草酮+16％异噁草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16％黄原胶+1.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
113.双唑草酮+苯唑氟草酮+2甲4氯(4+12+18)水悬浮剂
4％双唑草酮+12％苯唑氟草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
114.双唑草酮+苯唑氟草酮+西草净(2+6+30)水悬浮剂
2％双唑草酮+6％苯唑氟草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.16％黄原胶+1.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
115.双唑草酮+苯唑氟草酮+二氯喹啉酸(4+12+25)水悬浮剂
4％双唑草酮+12％苯唑氟草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
116.双唑草酮+苯唑氟草酮+五氟磺草胺(4+12+2)可分散油悬浮剂
4％双唑草酮+12％苯唑氟草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.4％有机膨润土+1.2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
117.双唑草酮+苯唑氟草酮+氯氟吡啶酯(4+12+1)可分散油悬浮剂
4％双唑草酮+12％苯唑氟草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.4％有机膨润土+1.2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
118.双唑草酮+苯唑氟草酮+禾草敌(1+3+50)可分散油悬浮剂
1％双唑草酮+3％苯唑氟草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
119.双唑草酮+苯唑氟草酮+禾草丹(1+3+50)可分散油悬浮剂
1％双唑草酮+3％苯唑氟草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
120.环吡氟草酮+苯唑草酮+丙草胺(9+3+30)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
121.环吡氟草酮+苯唑草酮+丁草胺(4.5+1.5+30)可分散油悬浮剂
4.5％环吡氟草酮+1.5％苯唑草酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+油酸甲酯补足
122.环吡氟草酮+苯唑草酮+苯噻酰草胺(9+3+30)水悬浮剂
9％环吡氟草酮+3％苯唑草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
123.环吡氟草酮+苯唑草酮+莎稗磷(9+3+15)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
124.环吡氟草酮+苯唑草酮+仲丁灵(4.5+1.5+24)可分散油悬浮剂
4.5％环吡氟草酮+1.5％苯唑草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.0％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
125.环吡氟草酮+苯唑草酮+噁草酮(9+3+30)水悬浮剂
9％环吡氟草酮+3％苯唑草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
126.环吡氟草酮+苯唑草酮+异丙隆(9+3+45)水分散粒剂
9％环吡氟草酮+3％苯唑草酮+45％异丙隆+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
127.环吡氟草酮+苯唑草酮+双唑草腈(9+3+14)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
128.环吡氟草酮+苯唑草酮+乙氧氟草醚(9+3+12)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
129.环吡氟草酮+苯唑草酮+异噁草松(9+3+16)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+16％异噁草松+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.0％有机膨润土+1.0％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
130.环吡氟草酮+苯唑草酮+2甲4氯(9+3+18)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+18％2甲4氯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.0％有机膨润土+1.0％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
131.环吡氟草酮+苯唑草酮+西草净(4.5+1.5+30)水悬浮剂
4.5％环吡氟草酮+1.5％苯唑草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
132.环吡氟草酮+苯唑草酮+二氯喹啉酸(9+3+25)水悬浮剂
9％环吡氟草酮+3％苯唑草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
133.环吡氟草酮+苯唑草酮+五氟磺草胺(9+3+2)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.2％有机膨润土+1.5％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
134.环吡氟草酮+苯唑草酮+氯氟吡啶酯(9+3+1)可分散油悬浮剂
9％环吡氟草酮+3％苯唑草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.2％有机膨润土+1.5％气相法白炭黑+6％100#溶剂油+油酸甲酯补足
135.环吡氟草酮+苯唑草酮+禾草敌(2.25+0.75+50)可分散油悬浮剂
2.25％环吡氟草酮+0.75％苯唑草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
136.环吡氟草酮+苯唑草酮+禾草丹(2.25+0.75+50)可分散油悬浮剂
2.25％环吡氟草酮+0.75％苯唑草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
137.环吡氟草酮+硝磺草酮+丙草胺(9+10+30)可分散油悬浮剂
9％环吡氟草酮+10％硝磺草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足
138.环吡氟草酮+硝磺草酮+丁草胺(4.5+5+30)可分散油悬浮剂
4.5％环吡氟草酮+5％硝磺草酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足
139.环吡氟草酮+硝磺草酮+苯噻酰草胺(9+10+30)水悬浮剂
9％环吡氟草酮+10％硝磺草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.05％黄原胶+0.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
140.环吡氟草酮+硝磺草酮+莎稗磷(9+10+15)可分散油悬浮剂
9％环吡氟草酮+10％硝磺草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
141.环吡氟草酮+硝磺草酮+仲丁灵(4.5+5+24)可分散油悬浮剂
4.5％环吡氟草酮+5％硝磺草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+1.5％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
142.环吡氟草酮+硝磺草酮+噁草酮(9+10+30)水悬浮剂
9％环吡氟草酮+10％硝磺草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.05％黄原胶+0.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
143.环吡氟草酮+硝磺草酮+异丙隆(4.5+5+22.5)水悬浮剂
4.5％环吡氟草酮+5％硝磺草酮+22.5％异丙隆+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
144.环吡氟草酮+硝磺草酮+双唑草腈(9+10+14)可分散油悬浮剂
9％环吡氟草酮+10％硝磺草酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油 氧乙烯醚+0.5％有机膨润土+10％100#溶剂油+油酸甲酯补足
145.环吡氟草酮+硝磺草酮+乙氧氟草醚(9+10+12)可分散油悬浮剂
9％环吡氟草酮+10％硝磺草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
146.环吡氟草酮+硝磺草酮+异噁草松(9+10+16)水悬浮剂
9％环吡氟草酮+10％硝磺草酮+16％异噁草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
147.环吡氟草酮+硝磺草酮+2甲4氯(9+10+18)水悬浮剂
9％环吡氟草酮+10％硝磺草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
148.环吡氟草酮+硝磺草酮+西草净(4.5+5+30)水悬浮剂
4.5％环吡氟草酮+5％硝磺草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
149.环吡氟草酮+硝磺草酮+二氯喹啉酸(9+10+25)水悬浮剂
9％环吡氟草酮+10％硝磺草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+0.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
150.环吡氟草酮+硝磺草酮+五氟磺草胺(9+10+2)可分散油悬浮剂
9％环吡氟草酮+10％硝磺草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
151.环吡氟草酮+硝磺草酮+氯氟吡啶酯(9+10+1)可分散油悬浮剂
9％环吡氟草酮+10％硝磺草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
152.环吡氟草酮+硝磺草酮+禾草敌(2.25+2.5+50)可分散油悬浮剂
2.25％环吡氟草酮+2.5％硝磺草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.8％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
153.环吡氟草酮+硝磺草酮+禾草丹(2.25+2.5+50)可分散油悬浮剂
2.25％环吡氟草酮+2.5％硝磺草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.8％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
154.环吡氟草酮+环磺酮+丙草胺(9+6+30)可分散油悬浮剂
9％环吡氟草酮+6％环磺酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足
155.环吡氟草酮+环磺酮+丁草胺(4.5+3+30)可分散油悬浮剂
4.5％环吡氟草酮+3％环磺酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足
156.环吡氟草酮+环磺酮+苯噻酰草胺(9+6+30)水悬浮剂
9％环吡氟草酮+6％环磺酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
157.环吡氟草酮+环磺酮+莎稗磷(9+6+15)可分散油悬浮剂
9％环吡氟草酮+6％环磺酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
158.环吡氟草酮+环磺酮+仲丁灵(4.5+3+24)可分散油悬浮剂
4.5％环吡氟草酮+3％环磺酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
159.环吡氟草酮+环磺酮+噁草酮(9+6+30)水悬浮剂
9％环吡氟草酮+6％环磺酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
160.环吡氟草酮+环磺酮+异丙隆(4.5+3+22.5)可分散油悬浮剂
4.5％环吡氟草酮+3％环磺酮+22.5％异丙隆+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.5％有机膨润土+10％100#溶剂油+油酸甲酯补足
161.环吡氟草酮+环磺酮+双唑草腈(9+6+14)可分散油悬浮剂
9％环吡氟草酮+6％环磺酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+10％100#溶剂油+油酸甲酯补足
162.环吡氟草酮+环磺酮+乙氧氟草醚(9+6+12)可分散油悬浮剂
9％环吡氟草酮+6％环磺酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
163.环吡氟草酮+环磺酮+异噁草松(9+6+16)可分散油悬浮剂
9％环吡氟草酮+6％环磺酮+16％异噁草松+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+8％100#溶剂油+油酸甲酯补足
164.环吡氟草酮+环磺酮+2甲4氯(9+6+18)水悬浮剂
9％环吡氟草酮+6％环磺酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.15％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
165.环吡氟草酮+环磺酮+西草净(4.5+3+30)水悬浮剂
4.5％环吡氟草酮+3％环磺酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
166.环吡氟草酮+环磺酮+二氯喹啉酸(9+6+25)水悬浮剂
9％环吡氟草酮+6％环磺酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
167.环吡氟草酮+环磺酮+五氟磺草胺(9+6+2)可分散油悬浮剂
9％环吡氟草酮+6％环磺酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
168.环吡氟草酮+环磺酮+氯氟吡啶酯(9+6+1)可分散油悬浮剂
9％环吡氟草酮+6％环磺酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
169.环吡氟草酮+环磺酮+禾草敌(2.25+1.5+50)可分散油悬浮剂
2.25％环吡氟草酮+1.5％环磺酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.8％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
170.环吡氟草酮+环磺酮+禾草丹(2.25+1.5+50)可分散油悬浮剂
2.25％环吡氟草酮+1.5％环磺酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.8％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
171.环吡氟草酮+异噁唑草酮+丙草胺(9+6+30)可分散油悬浮剂
9％环吡氟草酮+6％异噁唑草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足
172.环吡氟草酮+异噁唑草酮+丁草胺(4.5+3+30)可分散油悬浮剂
4.5％环吡氟草酮+3％异噁唑草酮+30％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
173.环吡氟草酮+异噁唑草酮+苯噻酰草胺(9+6+30)水悬浮剂
9％环吡氟草酮+6％异噁唑草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
174.环吡氟草酮+异噁唑草酮+莎稗磷(9+6+15)可分散油悬浮剂
9％环吡氟草酮+6％异噁唑草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.0％有机膨润土+2.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
175.环吡氟草酮+异噁唑草酮+仲丁灵(4.5+3+24)可分散油悬浮剂
4.5％环吡氟草酮+3％异噁唑草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.0％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
176.环吡氟草酮+异噁唑草酮+噁草酮(9+6+30)水悬浮剂
9％环吡氟草酮+6％异噁唑草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
177.环吡氟草酮+异噁唑草酮+异丙隆(4.5+3+22.5)可分散油悬浮剂
4.5％环吡氟草酮+3％异噁唑草酮+22.5％异丙隆+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+10％100#溶剂油+油酸甲酯补足
178.环吡氟草酮+异噁唑草酮+双唑草腈(9+6+14)可分散油悬浮剂
9％环吡氟草酮+6％异噁唑草酮+14％双唑草腈+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+10％100#溶剂油+油酸甲酯补足
179.环吡氟草酮+异噁唑草酮+乙氧氟草醚(9+6+12)可分散油悬浮剂
9％环吡氟草酮+6％异噁唑草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.0％有机膨润土+1.0％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
180.环吡氟草酮+异噁唑草酮+异噁草松(9+6+16)可分散油悬浮剂
9％环吡氟草酮+6％异噁唑草酮+16％异噁草松+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+8％100#溶剂油+油酸甲酯补足
181.环吡氟草酮+异噁唑草酮+2甲4氯(9+6+18)水悬浮剂
9％环吡氟草酮+6％异噁唑草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
182.环吡氟草酮+异噁唑草酮+西草净(4.5+3+30)水悬浮剂
4.5％环吡氟草酮+3％异噁唑草酮+30％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
183.环吡氟草酮+异噁唑草酮+二氯喹啉酸(9+6+25)水悬浮剂
9％环吡氟草酮+6％异噁唑草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
184.环吡氟草酮+异噁唑草酮+五氟磺草胺(9+6+2)可分散油悬浮剂
9％环吡氟草酮+6％异噁唑草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
185.环吡氟草酮+异噁唑草酮+氯氟吡啶酯(9+6+1)可分散油悬浮剂
9％环吡氟草酮+6％异噁唑草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
186.环吡氟草酮+异噁唑草酮+禾草敌(2.25+1.5+50)可分散油悬浮剂
2.25％环吡氟草酮+1.5％异噁唑草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
187.环吡氟草酮+异噁唑草酮+禾草丹(2.25+1.5+50)可分散油悬浮剂
2.25％环吡氟草酮+1.5％异噁唑草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
188.环吡氟草酮+双环磺草酮+丙草胺(9+20+30)可分散油悬浮剂
9％环吡氟草酮+20％双环磺草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+油酸甲酯补足
189.环吡氟草酮+双环磺草酮+丁草胺(2.25+5+15)可分散油悬浮剂
2.25％环吡氟草酮+5％双环磺草酮+15％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
190.环吡氟草酮+双环磺草酮+苯噻酰草胺(9+20+30)水悬浮剂
9％吡氟草酮+20％双环磺草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙 醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
191.环吡氟草酮+双环磺草酮+莎稗磷(9+20+15)可分散油悬浮剂
9％环吡氟草酮+20％双环磺草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+12％100#溶剂油+油酸甲酯补足
192.环吡氟草酮+双环磺草酮+仲丁灵(4.5+10+24)可分散油悬浮剂
4.5％环吡氟草酮+10％双环磺草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
193.环吡氟草酮+双环磺草酮+噁草酮(9+20+30)水分散粒剂
9％环吡氟草酮+20％双环磺草酮+30％噁草酮+10％萘磺酸盐分散剂+2％聚羧酸盐分散剂+4％十二烷基硫酸钠+10％沉淀法白炭黑+1％聚乙烯醇+高岭土补足
194.环吡氟草酮+双环磺草酮+异丙隆(4.5+10+22.5)水悬浮剂
4.5％环吡氟草酮+10％双环磺草酮+22.5％异丙隆+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.13％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
195.环吡氟草酮+双环磺草酮+双唑草腈(9+20+14)水悬浮剂
9％环吡氟草酮+20％双环磺草酮+14％双唑草腈+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
196.环吡氟草酮+双环磺草酮+乙氧氟草醚(9+20+12)悬乳剂
9％环吡氟草酮+20％双环磺草酮+12％乙氧氟草醚+15％100#溶剂油+3％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+4％蓖麻油聚氧乙烯醚+2％丁醇嵌段聚醚+0.1％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
197.环吡氟草酮+双环磺草酮+异噁草松(9+20+16)水悬浮剂
9％环吡氟草酮+20％双环磺草酮+16％异噁草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
198.环吡氟草酮+双环磺草酮+2甲4氯(9+20+18)水悬浮剂
9％环吡氟草酮+20％双环磺草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.08％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
199.环吡氟草酮+双环磺草酮+西草净(2.25+5+15)水悬浮剂
2.25％环吡氟草酮+5％双环磺草酮+15％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.18％黄原胶+1.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
200.环吡氟草酮+双环磺草酮+二氯喹啉酸(9+20+25)水悬浮剂
9％环吡氟草酮+20％双环磺草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
201.环吡氟草酮+双环磺草酮+五氟磺草胺(9+20+2)可分散油悬浮剂
9％环吡氟草酮+20％双环磺草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+10％100#溶剂油+油酸甲酯补足
202.环吡氟草酮+双环磺草酮+氯氟吡啶酯(9+20+1)可分散油悬浮剂
9％环吡氟草酮+20％双环磺草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+10％100#溶剂油+油酸甲酯补足
203.环吡氟草酮+双环磺草酮+禾草敌(2.25+5+50)可分散油悬浮剂
2.25％环吡氟草酮+5％双环磺草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
204.环吡氟草酮+双环磺草酮+禾草丹(2.25+5+50)可分散油悬浮剂
2.25％环吡氟草酮+5％双环磺草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
205.环吡氟草酮+三唑磺草酮+丙草胺(9+12+30)可分散油悬浮剂
9％环吡氟草酮+12％三唑磺草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油 氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
206.环吡氟草酮+三唑磺草酮+丁草胺(2.25+3+15)可分散油悬浮剂
2.25％环吡氟草酮+3％三唑磺草酮+15％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
207.环吡氟草酮+三唑磺草酮+苯噻酰草胺(9+12+30)水悬浮剂
9％环吡氟草酮+12％三唑磺草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.04％黄原胶+0.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
208.环吡氟草酮+三唑磺草酮+莎稗磷(9+12+15)可分散油悬浮剂
9％环吡氟草酮+12％三唑磺草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
209.环吡氟草酮+三唑磺草酮+仲丁灵(4.5+6+24)可分散油悬浮剂
4.5％环吡氟草酮+6％三唑磺草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.6％有机膨润土+2.5％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
210.环吡氟草酮+三唑磺草酮+噁草酮(9+12+30)水悬浮剂
9％环吡氟草酮+12％三唑磺草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.04％黄原胶+0.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
211.环吡氟草酮+三唑磺草酮+异丙隆(4.5+6+22.5)水悬浮剂
4.5％环吡氟草酮+6％三唑磺草酮+22.5％异丙隆+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
212.环吡氟草酮+三唑磺草酮+双唑草腈(9+12+14)水悬浮剂
9％环吡氟草酮+12％三唑磺草酮+14％双唑草腈+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
213.环吡氟草酮+三唑磺草酮+乙氧氟草醚(9+12+12)可分散油悬浮剂
9％环吡氟草酮+12％三唑磺草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
214.环吡氟草酮+三唑磺草酮+异噁草松(9+12+16)水悬浮剂
9％环吡氟草酮+12％三唑磺草酮+16％异噁草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
215.环吡氟草酮+三唑磺草酮+2甲4氯(9+12+18)水悬浮剂
9％环吡氟草酮+12％三唑磺草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.1％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
216.环吡氟草酮+三唑磺草酮+西草净(2.25+3+15)可分散油悬浮剂
2.25％环吡氟草酮+3％三唑磺草酮+15％西草净+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+8％100#溶剂油+油酸甲酯补足
217.环吡氟草酮+三唑磺草酮+二氯喹啉酸(9+12+25)水悬浮剂
9％环吡氟草酮+12％三唑磺草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.06％黄原胶+0.6％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
218.环吡氟草酮+三唑磺草酮+五氟磺草胺(9+12+2)可分散油悬浮剂
9％环吡氟草酮+12％三唑磺草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.6％有机膨润土+10％100#溶剂油+油酸甲酯补足
219.环吡氟草酮+三唑磺草酮+氯氟吡啶酯(9+12+1)可分散油悬浮剂
9％环吡氟草酮+12％三唑磺草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.2％有机膨润土+1.2％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
220.环吡氟草酮+三唑磺草酮+禾草敌(2.25+3+50)可分散油悬浮剂
2.25％环吡氟草酮+3％三唑磺草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
221.环吡氟草酮+三唑磺草酮+禾草丹(2.25+3+50)可分散油悬浮剂
2.25％环吡氟草酮+3％三唑磺草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
222.环吡氟草酮+苯唑氟草酮+丙草胺(9+12+30)可分散油悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+30％丙草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.5％有机膨润土+1.5％气相法白炭黑+油酸甲酯补足
223.环吡氟草酮+苯唑氟草酮+丁草胺(2.25+3+15)可分散油悬浮剂
2.25％环吡氟草酮+3％苯唑氟草酮+15％丁草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
224.环吡氟草酮+苯唑氟草酮+苯噻酰草胺(9+12+30)水悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+30％苯噻酰草胺+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.09％黄原胶+1.0％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
225.环吡氟草酮+苯唑氟草酮+莎稗磷(9+12+15)可分散油悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+15％莎稗磷+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
226.环吡氟草酮+苯唑氟草酮+仲丁灵(4.5+6+24)可分散油悬浮剂
4.5％环吡氟草酮+6％苯唑氟草酮+24％仲丁灵+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+2.5％有机膨润土+1.5％气相法白炭黑+20％100#溶剂油+油酸甲酯补足
227.环吡氟草酮+苯唑氟草酮+噁草酮(9+12+30)水悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+30％噁草酮+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.04％黄原胶+0.5％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
228.环吡氟草酮+苯唑氟草酮+异丙隆(4.5+6+22.5)水悬浮剂
4.5％环吡氟草酮+6％苯唑氟草酮+22.5％异丙隆+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
229.环吡氟草酮+苯唑氟草酮+双唑草腈(9+12+14)水悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+14％双唑草腈+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
230.环吡氟草酮+苯唑氟草酮+乙氧氟草醚(9+12+12)可分散油悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+12％乙氧氟草醚+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.8％有机膨润土+1.5％气相法白炭黑+12％100#溶剂油+油酸甲酯补足
231.环吡氟草酮+苯唑氟草酮+异噁草松(9+12+16)水悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+16％异噁草松+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.14％黄原胶+1.4％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
232.环吡氟草酮+苯唑氟草酮+2甲4氯(9+12+18)水悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+18％2甲4氯+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
233.环吡氟草酮+苯唑氟草酮+西草净(2.25+3+15)水悬浮剂
2.25％环吡氟草酮+3％苯唑氟草酮+15％西草净+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.12％黄原胶+1.2％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
234.环吡氟草酮+苯唑氟草酮+二氯喹啉酸(9+12+25)水悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+25％二氯喹啉酸+5％聚羧酸盐+2％苯乙基苯酚聚氧乙烯醚磷酸酯三乙醇胺盐+0.07％黄原胶+0.8％硅酸镁铝+0.1％消泡剂+3％乙二醇+水
235.环吡氟草酮+苯唑氟草酮+五氟磺草胺(9+12+2)可分散油悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+2％五氟磺草胺+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+0.8％有机膨润土+10％100#溶剂油+油酸甲酯补足
236.环吡氟草酮+苯唑氟草酮+氯氟吡啶酯(9+12+1)可分散油悬浮剂
9％环吡氟草酮+12％苯唑氟草酮+1％氯氟吡啶酯+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+1.6％有机膨润土+1.5％气相法白炭黑+10％100#溶剂油+油酸甲酯补足
237.环吡氟草酮+苯唑氟草酮+禾草敌(2.25+3+50)可分散油悬浮剂
2.25％环吡氟草酮+3％苯唑氟草酮+50％禾草敌+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
238.环吡氟草酮+苯唑氟草酮+禾草丹(2.25+3+50)可分散油悬浮剂
2.25％环吡氟草酮+3％苯唑氟草酮+50％禾草丹+5％十二烷基苯磺酸钙+5％脂肪醇聚氧乙烯醚+6％蓖麻油氧乙烯醚+3.0％有机膨润土+2.5％气相法白炭黑+油酸甲酯补足
上述水悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。
上述水悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。
上述可分散油悬浮剂加工设备：混料釜、胶体磨、砂磨机、剪切机等。
上述可分散油悬浮剂加工过程：将所有物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，最后在剪切机中剪切均匀，化验合格后，转移至储罐灌装。
上述悬乳剂加工设备：混料釜、胶体磨、砂磨机、剪切机，剪切釜。
上述悬乳剂加工过程：将部分物料投入混料釜中，搅拌混合后过胶体磨，之后进入砂磨机三级砂磨，合格后打入剪切釜备用，为水相物料；之后将剩余原药和溶剂投入混料釜中，搅拌溶解至完全透明，之后加入乳化剂，搅拌均匀为油相，之后开启剪切机，在剪切状态下，将油相缓缓抽入剪切釜内，全部物料抽入后，继续剪切1个小时，化验合格后，转移至储罐灌装。
上述水分散粒剂加工设备：气流粉碎机，犁刀式混合机，篮式造粒机，干燥箱，筛分机等。
上述水分散粒剂加工过程：将上述物料混合均匀过气流粉碎，加水入捏合造粒，之后干燥，最后筛分得到成品。
B)药效试验
土壤封闭处理:
1)试验条件
1.1)、供试靶标
碎米荠(Cardamine hirsuta L.)、繁缕(Stellaria media)采自江苏兴化。
1.2)、培养条件
上述杂草采用盆栽法培养。用180х140mm塑料营养钵，摆放于搪瓷盘中，内装从农田采回经风干过筛的表层土壤(4/5处)，土壤湿度初期均控制在20％，挑选籽粒饱满均一的杂草种子，用25℃温水浸泡6小时，在28℃生化培养箱(黑暗)中催芽，将刚刚露白的杂草种子 均匀摆放在土壤表面，然后覆土0.7cm。药剂处理后置于可控日光温室内培养，定期在搪瓷盘中加入一定量的水，保持土壤湿润。
在可控日光温室内进行，温度18～30℃，自然光照，相对湿度57％～72％。土壤类型为壤土，有机质含量为1.63％,pH＝7.1，碱解氮84.3mg/kg，速效磷38.5mg/kg，速效钾82.1mg/kg。1.3)、仪器设备
3WP-2000型行走式喷雾塔，农业部南京农业机械研究所。GA110型万分之一电子天平(德国)；ZDR2000智能数据记录仪(杭州泽大仪器有限公司)；SPX型智能生化培养箱(宁波江南仪器厂)。
2)试验设计
2.1)、试剂
所需活性成分环吡氟草酮、双唑草酮、三唑磺草酮、苯唑氟草酮为本公司生产，其他由试剂公司购买。原药均采用丙酮作溶剂，用含量0.1％乳化剂T-80水溶液稀释，现用现稀释。2.2)、试验处理
2.2.1)、剂量设置
在确定各组分配比或含量时，应从三种药剂的作用特点及其毒力等衡量，还要考虑该配方的主要使用目的。本研究在前期预试的基础上,设单用及混合用量。以不含药剂、含相同溶剂及乳化剂的水作为空白对照。
2.2.2)、试验重复
每处理重复4次，每次每处理3盆，每盆播种杂草种子20粒，每处理共60株。
2.3)、处理方式
2.3.1)、处理时间和次数
试验共用药1次，在播种后24小时。
2.3.2)、使用器械和用药方法
将培养好的试材均匀摆放在面积0.5m 2的平台上，用3WP-2000型行走式喷雾塔土壤表层喷雾，喷液量按450公斤/公顷计。喷雾压力0.3MPa。待全部药液喷完后，关闭气阀，30秒后，打开喷雾塔门，取出营养钵。然后打开气阀，喷清水50mL，清洗喷液管。
3)试验方法
采用盆栽法。杂草培养见1.2，参照《农药室内生物测定试验准则除草剂》进行。用药方法见2.3.2，采用土壤处理法。
4)数据调查与统计分析
4.1)、调查方法
采用绝对数调查法，用刀片沿土壤表面切断存活杂草幼苗，用分析天平称量杂草鲜重。对于已经死亡的杂草，按鲜重为零计。
4.2)、调查时间和次数
处理后15天调查，共调查1次。
4.3)、数据统计分析
用Colby法检验，评价任意两者及三者混用对杂草的联合作用类型。
15d时剪取各处理地上绿色组织，采用电子天平称重，计算实际存活率：E(％)＝(处理区杂草鲜重/对照区杂草鲜重)×100
理论杂草存活率计算公式为：E0(％)＝X×Y/100(二元混用)
式中X代表用量为P时A的杂草存活率，Y代表用量为Q时B的杂草存活率，E0代表用量为(P+Q)时A+B的理论杂草存活率，E代表各处理的实际杂草存活率。
E0(％)＝X×Y×Z×…×N/100 (n-1)(三元及以上混用)
式中X、Y、Z、N分别代表n种单剂的实际存活率，n为复配除草剂品种数量。
当E0-E>10％时，说明产生增效作用；当E0-E<-10％时，说明产生拮抗作用；当E0-E介于±10％时，说明产生相加作用。
各组分混配对杂草的实际防效及联合作用评价(土壤处理)统计结果见下表1-238，当A为双唑草酮时，试材为碎米荠；当A为环吡氟草酮时，试材为繁缕。
表1 A为双唑草酮，B为苯唑草酮，C为丙草胺
Figure PCTCN2018105273-appb-000003
表2 A为双唑草酮，B为苯唑草酮，C为丁草胺
Figure PCTCN2018105273-appb-000004
表3 A为双唑草酮，B为苯唑草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000005
表4 A为双唑草酮，B为苯唑草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000006
Figure PCTCN2018105273-appb-000007
表5 A为双唑草酮，B为苯唑草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000008
表6 A为双唑草酮，B为苯唑草酮，C为噁草酮
Figure PCTCN2018105273-appb-000009
表7 A为双唑草酮，B为苯唑草酮，C为异丙隆
Figure PCTCN2018105273-appb-000010
表8 A为双唑草酮，B为苯唑草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000011
表9 A为双唑草酮，B为苯唑草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000012
Figure PCTCN2018105273-appb-000013
表10 A为双唑草酮，B为苯唑草酮，C为异噁草松
Figure PCTCN2018105273-appb-000014
表11 A为双唑草酮，B为苯唑草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000015
表12 A为双唑草酮，B为苯唑草酮，C为西草净
Figure PCTCN2018105273-appb-000016
表13 A为双唑草酮，B为苯唑草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000017
表14 A为双唑草酮，B为苯唑草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000018
Figure PCTCN2018105273-appb-000019
表15 A为双唑草酮，B为苯唑草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000020
表16 A为双唑草酮，B为苯唑草酮，C为禾草敌
Figure PCTCN2018105273-appb-000021
表17 A为双唑草酮，B为苯唑草酮，C为禾草丹
Figure PCTCN2018105273-appb-000022
Figure PCTCN2018105273-appb-000023
表18 A为双唑草酮，B为硝磺草酮，C为丙草胺
Figure PCTCN2018105273-appb-000024
表19 A为双唑草酮，B为硝磺草酮，C为丁草胺
Figure PCTCN2018105273-appb-000025
Figure PCTCN2018105273-appb-000026
表20 A为双唑草酮，B为硝磺草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000027
表21 A为双唑草酮，B为硝磺草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000028
表22 A为双唑草酮，B为硝磺草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000029
Figure PCTCN2018105273-appb-000030
表23 A为双唑草酮，B为硝磺草酮，C为噁草酮
Figure PCTCN2018105273-appb-000031
表24 A为双唑草酮，B为硝磺草酮，C为异丙隆
Figure PCTCN2018105273-appb-000032
Figure PCTCN2018105273-appb-000033
表25 A为双唑草酮，B为硝磺草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000034
表26 A为双唑草酮，B为硝磺草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000035
表27 A为双唑草酮，B为硝磺草酮，C为异噁草松
Figure PCTCN2018105273-appb-000036
Figure PCTCN2018105273-appb-000037
表28 A为双唑草酮，B为硝磺草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000038
表29 A为双唑草酮，B为硝磺草酮，C为西草净
Figure PCTCN2018105273-appb-000039
Figure PCTCN2018105273-appb-000040
表30 A为双唑草酮，B为硝磺草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000041
表31 A为双唑草酮，B为硝磺草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000042
表32 A为双唑草酮，B为硝磺草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000043
Figure PCTCN2018105273-appb-000044
表33 A为双唑草酮，B为硝磺草酮，C为禾草敌
Figure PCTCN2018105273-appb-000045
表34 A为双唑草酮，B为硝磺草酮，C为禾草丹
Figure PCTCN2018105273-appb-000046
表35 A为双唑草酮，B为环磺酮，C为丙草胺
Figure PCTCN2018105273-appb-000047
表36 A为双唑草酮，B为环磺酮，C为丁草胺
Figure PCTCN2018105273-appb-000048
表37 A为双唑草酮，B为环磺酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000049
Figure PCTCN2018105273-appb-000050
表38 A为双唑草酮，B为环磺酮，C为莎稗磷
Figure PCTCN2018105273-appb-000051
表39 A为双唑草酮，B为环磺酮，C为仲丁灵
Figure PCTCN2018105273-appb-000052
表40 A为双唑草酮，B为环磺酮，C为噁草酮
Figure PCTCN2018105273-appb-000053
表41 A为双唑草酮，B为环磺酮，C为异丙隆
Figure PCTCN2018105273-appb-000054
表42 A为双唑草酮，B为环磺酮，C为双唑草腈
Figure PCTCN2018105273-appb-000055
Figure PCTCN2018105273-appb-000056
表43 A为双唑草酮，B为环磺酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000057
表44 A为双唑草酮，B为环磺酮，C为异噁草松
Figure PCTCN2018105273-appb-000058
表45 A为双唑草酮，B为环磺酮，C为2甲4氯
Figure PCTCN2018105273-appb-000059
表46 A为双唑草酮，B为环磺酮，C为西草净
Figure PCTCN2018105273-appb-000060
表47 A为双唑草酮，B为环磺酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000061
Figure PCTCN2018105273-appb-000062
表48 A为双唑草酮，B为环磺酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000063
表49 A为双唑草酮，B为环磺酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000064
表50 A为双唑草酮，B为环磺酮，C为禾草敌
Figure PCTCN2018105273-appb-000065
Figure PCTCN2018105273-appb-000066
表51 A为双唑草酮，B为环磺酮，C为禾草丹
Figure PCTCN2018105273-appb-000067
表52 A为双唑草酮，B为异噁唑草酮，C为丙草胺
Figure PCTCN2018105273-appb-000068
表53 A为双唑草酮，B为异噁唑草酮，C为丁草胺
Figure PCTCN2018105273-appb-000069
表54 A为双唑草酮，B为异噁唑草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000070
表55 A为双唑草酮，B为异噁唑草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000071
Figure PCTCN2018105273-appb-000072
表56 A为双唑草酮，B为异噁唑草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000073
表57 A为双唑草酮，B为异噁唑草酮，C为噁草酮
Figure PCTCN2018105273-appb-000074
表58 A为双唑草酮，B为异噁唑草酮，C为异丙隆
Figure PCTCN2018105273-appb-000075
表59 A为双唑草酮，B为异噁唑草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000076
表60 A为双唑草酮，B为异噁唑草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000077
Figure PCTCN2018105273-appb-000078
表61 A为双唑草酮，B为异噁唑草酮，C为异噁草松
Figure PCTCN2018105273-appb-000079
表62 A为双唑草酮，B为异噁唑草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000080
表63 A为双唑草酮，B为异噁唑草酮，C为西草净
Figure PCTCN2018105273-appb-000081
表64 A为双唑草酮，B为异噁唑草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000082
表65 A为双唑草酮，B为异噁唑草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000083
Figure PCTCN2018105273-appb-000084
表66 A为双唑草酮，B为异噁唑草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000085
表67 A为双唑草酮，B为异噁唑草酮，C为禾草敌
Figure PCTCN2018105273-appb-000086
表68 A为双唑草酮，B为异噁唑草酮，C为禾草丹
Figure PCTCN2018105273-appb-000087
Figure PCTCN2018105273-appb-000088
表69 A为双唑草酮，B为双环磺草酮，C为丙草胺
Figure PCTCN2018105273-appb-000089
表70 A为双唑草酮，B为双环磺草酮，C为丁草胺
Figure PCTCN2018105273-appb-000090
表71 A为双唑草酮，B为双环磺草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000091
表72 A为双唑草酮，B为双环磺草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000092
表73 A为双唑草酮，B为双环磺草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000093
Figure PCTCN2018105273-appb-000094
表74 A为双唑草酮，B为双环磺草酮，C为噁草酮
Figure PCTCN2018105273-appb-000095
表75 A为双唑草酮，B为双环磺草酮，C为异丙隆
Figure PCTCN2018105273-appb-000096
表76 A为双唑草酮，B为双环磺草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000097
表77 A为双唑草酮，B为双环磺草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000098
表78 A为双唑草酮，B为双环磺草酮，C为异噁草松
Figure PCTCN2018105273-appb-000099
Figure PCTCN2018105273-appb-000100
表79 A为双唑草酮，B为双环磺草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000101
表80 A为双唑草酮，B为双环磺草酮，C为西草净
Figure PCTCN2018105273-appb-000102
表81 A为双唑草酮，B为双环磺草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000103
表82 A为双唑草酮，B为双环磺草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000104
表83 A为双唑草酮，B为双环磺草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000105
Figure PCTCN2018105273-appb-000106
表84 A为双唑草酮，B为双环磺草酮，C为禾草敌
Figure PCTCN2018105273-appb-000107
表85 A为双唑草酮，B为双环磺草酮，C为禾草丹
Figure PCTCN2018105273-appb-000108
表86 A为双唑草酮，B为三唑磺草酮，C为丙草胺
Figure PCTCN2018105273-appb-000109
Figure PCTCN2018105273-appb-000110
表87 A为双唑草酮，B为三唑磺草酮，C为丁草胺
Figure PCTCN2018105273-appb-000111
表88 A为双唑草酮，B为三唑磺草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000112
Figure PCTCN2018105273-appb-000113
表89 A为双唑草酮，B为三唑磺草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000114
表90 A为双唑草酮，B为三唑磺草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000115
表91 A为双唑草酮，B为三唑磺草酮，C为噁草酮
Figure PCTCN2018105273-appb-000116
Figure PCTCN2018105273-appb-000117
表92 A为双唑草酮，B为三唑磺草酮，C为异丙隆
Figure PCTCN2018105273-appb-000118
表93 A为双唑草酮，B为三唑磺草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000119
Figure PCTCN2018105273-appb-000120
表94 A为双唑草酮，B为三唑磺草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000121
表95 A为双唑草酮，B为三唑磺草酮，C为异噁草松
Figure PCTCN2018105273-appb-000122
表96 A为双唑草酮，B为三唑磺草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000123
Figure PCTCN2018105273-appb-000124
表97 A为双唑草酮，B为三唑磺草酮，C为西草净
Figure PCTCN2018105273-appb-000125
表98 A为双唑草酮，B为三唑磺草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000126
Figure PCTCN2018105273-appb-000127
表99 A为双唑草酮，B为三唑磺草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000128
表100 A为双唑草酮，B为三唑磺草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000129
表101 A为双唑草酮，B为三唑磺草酮，C为禾草敌
Figure PCTCN2018105273-appb-000130
Figure PCTCN2018105273-appb-000131
表102 A为双唑草酮，B为三唑磺草酮，C为禾草丹
Figure PCTCN2018105273-appb-000132
表103 A为双唑草酮，B为苯唑氟草酮，C为丙草胺
Figure PCTCN2018105273-appb-000133
表104 A为双唑草酮，B为苯唑氟草酮，C为丁草胺
Figure PCTCN2018105273-appb-000134
表105 A为双唑草酮，B为苯唑氟草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000135
表106 A为双唑草酮，B为苯唑氟草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000136
Figure PCTCN2018105273-appb-000137
表107 A为双唑草酮，B为苯唑氟草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000138
表108 A为双唑草酮，B为苯唑氟草酮，C为噁草酮
Figure PCTCN2018105273-appb-000139
表109 A为双唑草酮，B为苯唑氟草酮，C为异丙隆
Figure PCTCN2018105273-appb-000140
表110 A为双唑草酮，B为苯唑氟草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000141
表111 A为双唑草酮，B为苯唑氟草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000142
Figure PCTCN2018105273-appb-000143
表112 A为双唑草酮，B为苯唑氟草酮，C为异噁草松
Figure PCTCN2018105273-appb-000144
表113 A为双唑草酮，B为苯唑氟草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000145
表114 A为双唑草酮，B为苯唑氟草酮，C为西草净
Figure PCTCN2018105273-appb-000146
表115 A为双唑草酮，B为苯唑氟草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000147
表116 A为双唑草酮，B为苯唑氟草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000148
Figure PCTCN2018105273-appb-000149
表117 A为双唑草酮，B为苯唑氟草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000150
表118 A为双唑草酮，B为苯唑氟草酮，C为禾草敌
Figure PCTCN2018105273-appb-000151
表119 A为双唑草酮，B为苯唑氟草酮，C为禾草丹
Figure PCTCN2018105273-appb-000152
Figure PCTCN2018105273-appb-000153
表120 A为环吡氟草酮，B为苯唑草酮，C为丙草胺
Figure PCTCN2018105273-appb-000154
表121 A为环吡氟草酮，B为苯唑草酮，C为丁草胺
Figure PCTCN2018105273-appb-000155
Figure PCTCN2018105273-appb-000156
表122 A为环吡氟草酮，B为苯唑草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000157
表123 A为环吡氟草酮，B为苯唑草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000158
表124 A为环吡氟草酮，B为苯唑草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000159
Figure PCTCN2018105273-appb-000160
表125 A为环吡氟草酮，B为苯唑草酮，C为噁草酮
Figure PCTCN2018105273-appb-000161
表126 A为环吡氟草酮，B为苯唑草酮，C为异丙隆
Figure PCTCN2018105273-appb-000162
Figure PCTCN2018105273-appb-000163
表127 A为环吡氟草酮，B为苯唑草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000164
表128 A为环吡氟草酮，B为苯唑草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000165
表129 A为环吡氟草酮，B为苯唑草酮，C为异噁草松
Figure PCTCN2018105273-appb-000166
Figure PCTCN2018105273-appb-000167
表130 A为环吡氟草酮，B为苯唑草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000168
表131 A为环吡氟草酮，B为苯唑草酮，C为西草净
Figure PCTCN2018105273-appb-000169
Figure PCTCN2018105273-appb-000170
表132 A为环吡氟草酮，B为苯唑草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000171
表133 A为环吡氟草酮，B为苯唑草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000172
表134 A为环吡氟草酮，B为苯唑草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000173
Figure PCTCN2018105273-appb-000174
表135 A为环吡氟草酮，B为苯唑草酮，C为禾草敌
Figure PCTCN2018105273-appb-000175
表136 A为环吡氟草酮，B为苯唑草酮，C为禾草丹
Figure PCTCN2018105273-appb-000176
表137 A为环吡氟草酮，B为硝磺草酮，C为丙草胺
Figure PCTCN2018105273-appb-000177
表138 A为环吡氟草酮，B为硝磺草酮，C为丁草胺
Figure PCTCN2018105273-appb-000178
表139 A为环吡氟草酮，B为硝磺草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000179
Figure PCTCN2018105273-appb-000180
表140 A为环吡氟草酮，B为硝磺草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000181
表141 A为环吡氟草酮，B为硝磺草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000182
表142 A为环吡氟草酮，B为硝磺草酮，C为噁草酮
Figure PCTCN2018105273-appb-000183
表143 A为环吡氟草酮，B为硝磺草酮，C为异丙隆
Figure PCTCN2018105273-appb-000184
表144 A为环吡氟草酮，B为硝磺草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000185
Figure PCTCN2018105273-appb-000186
表145 A为环吡氟草酮，B为硝磺草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000187
表146 A为环吡氟草酮，B为硝磺草酮，C为异噁草松
Figure PCTCN2018105273-appb-000188
表147 A为环吡氟草酮，B为硝磺草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000189
表148 A为环吡氟草酮，B为硝磺草酮，C为西草净
Figure PCTCN2018105273-appb-000190
表149 A为环吡氟草酮，B为硝磺草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000191
Figure PCTCN2018105273-appb-000192
表150 A为环吡氟草酮，B为硝磺草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000193
表151 A为环吡氟草酮，B为硝磺草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000194
表152 A为环吡氟草酮，B为硝磺草酮，C为禾草敌
Figure PCTCN2018105273-appb-000195
表153 A为环吡氟草酮，B为硝磺草酮，C为禾草丹
Figure PCTCN2018105273-appb-000196
表154 A为环吡氟草酮，B为环磺酮，C为丙草胺
Figure PCTCN2018105273-appb-000197
Figure PCTCN2018105273-appb-000198
表155 A为环吡氟草酮，B为环磺酮，C为丁草胺
Figure PCTCN2018105273-appb-000199
表156 A为环吡氟草酮，B为环磺酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000200
表157 A为环吡氟草酮，B为环磺酮，C为莎稗磷
Figure PCTCN2018105273-appb-000201
表158 A为环吡氟草酮，B为环磺酮，C为仲丁灵
Figure PCTCN2018105273-appb-000202
表159 A为环吡氟草酮，B为环磺酮，C为噁草酮
Figure PCTCN2018105273-appb-000203
Figure PCTCN2018105273-appb-000204
表160 A为环吡氟草酮，B为环磺酮，C为异丙隆
Figure PCTCN2018105273-appb-000205
表161 A为环吡氟草酮，B为环磺酮，C为双唑草腈
Figure PCTCN2018105273-appb-000206
表162 A为环吡氟草酮，B为环磺酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000207
表163 A为环吡氟草酮，B为环磺酮，C为异噁草松
Figure PCTCN2018105273-appb-000208
表164 A为环吡氟草酮，B为环磺酮，C为2甲4氯
Figure PCTCN2018105273-appb-000209
Figure PCTCN2018105273-appb-000210
表165 A为环吡氟草酮，B为环磺酮，C为西草净
Figure PCTCN2018105273-appb-000211
表166 A为环吡氟草酮，B为环磺酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000212
表167 A为环吡氟草酮，B为环磺酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000213
表168 A为环吡氟草酮，B为环磺酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000214
表169 A为环吡氟草酮，B为环磺酮，C为禾草敌
Figure PCTCN2018105273-appb-000215
Figure PCTCN2018105273-appb-000216
表170 A为环吡氟草酮，B为环磺酮，C为禾草丹
Figure PCTCN2018105273-appb-000217
表171 A为环吡氟草酮，B为异噁唑草酮，C为丙草胺
Figure PCTCN2018105273-appb-000218
表172 A为环吡氟草酮，B为异噁唑草酮，C为丁草胺
Figure PCTCN2018105273-appb-000219
表173 A为环吡氟草酮，B为异噁唑草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000220
表174 A为环吡氟草酮，B为异噁唑草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000221
Figure PCTCN2018105273-appb-000222
表175 A为环吡氟草酮，B为异噁唑草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000223
表176 A为环吡氟草酮，B为异噁唑草酮，C为噁草酮
Figure PCTCN2018105273-appb-000224
表177 A为环吡氟草酮，B为异噁唑草酮，C为异丙隆
Figure PCTCN2018105273-appb-000225
表178 A为环吡氟草酮，B为异噁唑草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000226
表179 A为环吡氟草酮，B为异噁唑草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000227
Figure PCTCN2018105273-appb-000228
表180 A为环吡氟草酮，B为异噁唑草酮，C为异噁草松
Figure PCTCN2018105273-appb-000229
表181 A为环吡氟草酮，B为异噁唑草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000230
表182 A为环吡氟草酮，B为异噁唑草酮，C为西草净
Figure PCTCN2018105273-appb-000231
表183 A为环吡氟草酮，B为异噁唑草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000232
表184 A为环吡氟草酮，B为异噁唑草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000233
Figure PCTCN2018105273-appb-000234
表185 A为环吡氟草酮，B为异噁唑草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000235
表186 A为环吡氟草酮，B为异噁唑草酮，C为禾草敌
Figure PCTCN2018105273-appb-000236
表187 A为环吡氟草酮，B为异噁唑草酮，C为禾草丹
Figure PCTCN2018105273-appb-000237
Figure PCTCN2018105273-appb-000238
表188 A为环吡氟草酮，B为双环磺草酮，C为丙草胺
Figure PCTCN2018105273-appb-000239
表189 A为环吡氟草酮，B为双环磺草酮，C为丁草胺
Figure PCTCN2018105273-appb-000240
Figure PCTCN2018105273-appb-000241
表190 A为环吡氟草酮，B为双环磺草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000242
表191 A为环吡氟草酮，B为双环磺草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000243
表192 A为环吡氟草酮，B为双环磺草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000244
Figure PCTCN2018105273-appb-000245
表193 A为环吡氟草酮，B为双环磺草酮，C为噁草酮
Figure PCTCN2018105273-appb-000246
表194 A为环吡氟草酮，B为双环磺草酮，C为异丙隆
Figure PCTCN2018105273-appb-000247
Figure PCTCN2018105273-appb-000248
表195 A为环吡氟草酮，B为双环磺草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000249
表196 A为环吡氟草酮，B为双环磺草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000250
表197 A为环吡氟草酮，B为双环磺草酮，C为异噁草松
Figure PCTCN2018105273-appb-000251
Figure PCTCN2018105273-appb-000252
表198 A为环吡氟草酮，B为双环磺草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000253
表199 A为环吡氟草酮，B为双环磺草酮，C为西草净
Figure PCTCN2018105273-appb-000254
Figure PCTCN2018105273-appb-000255
表200 A为环吡氟草酮，B为双环磺草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000256
表201 A为环吡氟草酮，B为双环磺草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000257
表202 A为环吡氟草酮，B为双环磺草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000258
Figure PCTCN2018105273-appb-000259
表203 A为环吡氟草酮，B为双环磺草酮，C为禾草敌
Figure PCTCN2018105273-appb-000260
表204 A为环吡氟草酮，B为双环磺草酮，C为禾草丹
Figure PCTCN2018105273-appb-000261
Figure PCTCN2018105273-appb-000262
表205 A为环吡氟草酮，B为三唑磺草酮，C为丙草胺
Figure PCTCN2018105273-appb-000263
表206 A为环吡氟草酮，B为三唑磺草酮，C为丁草胺
Figure PCTCN2018105273-appb-000264
表207 A为环吡氟草酮，B为三唑磺草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000265
Figure PCTCN2018105273-appb-000266
表208 A为环吡氟草酮，B为三唑磺草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000267
表209 A为环吡氟草酮，B为三唑磺草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000268
表210 A为环吡氟草酮，B为三唑磺草酮，C为噁草酮
Figure PCTCN2018105273-appb-000269
表211 A为环吡氟草酮，B为三唑磺草酮，C为异丙隆
Figure PCTCN2018105273-appb-000270
表212 A为环吡氟草酮，B为三唑磺草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000271
Figure PCTCN2018105273-appb-000272
表213 A为环吡氟草酮，B为三唑磺草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000273
表214 A为环吡氟草酮，B为三唑磺草酮，C为异噁草松
Figure PCTCN2018105273-appb-000274
表215 A为环吡氟草酮，B为三唑磺草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000275
表216 A为环吡氟草酮，B为三唑磺草酮，C为西草净
Figure PCTCN2018105273-appb-000276
表217 A为环吡氟草酮，B为三唑磺草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000277
Figure PCTCN2018105273-appb-000278
表218 A为环吡氟草酮，B为三唑磺草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000279
表219 A为环吡氟草酮，B为三唑磺草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000280
表220 A为环吡氟草酮，B为三唑磺草酮，C为禾草敌
Figure PCTCN2018105273-appb-000281
表221 A为环吡氟草酮，B为三唑磺草酮，C为禾草丹
Figure PCTCN2018105273-appb-000282
表222 A为环吡氟草酮，B为苯唑氟草酮，C为丙草胺
Figure PCTCN2018105273-appb-000283
Figure PCTCN2018105273-appb-000284
表223 A为环吡氟草酮，B为苯唑氟草酮，C为丁草胺
Figure PCTCN2018105273-appb-000285
表224 A为环吡氟草酮，B为苯唑氟草酮，C为苯噻酰草胺
Figure PCTCN2018105273-appb-000286
表225 A为环吡氟草酮，B为苯唑氟草酮，C为莎稗磷
Figure PCTCN2018105273-appb-000287
表226 A为环吡氟草酮，B为苯唑氟草酮，C为仲丁灵
Figure PCTCN2018105273-appb-000288
表227 A为环吡氟草酮，B为苯唑氟草酮，C为噁草酮
Figure PCTCN2018105273-appb-000289
Figure PCTCN2018105273-appb-000290
表228 A为环吡氟草酮，B为苯唑氟草酮，C为异丙隆
Figure PCTCN2018105273-appb-000291
表229 A为环吡氟草酮，B为苯唑氟草酮，C为双唑草腈
Figure PCTCN2018105273-appb-000292
表230 A为环吡氟草酮，B为苯唑氟草酮，C为乙氧氟草醚
Figure PCTCN2018105273-appb-000293
表231 A为环吡氟草酮，B为苯唑氟草酮，C为异噁草松
Figure PCTCN2018105273-appb-000294
表232 A为环吡氟草酮，B为苯唑氟草酮，C为2甲4氯
Figure PCTCN2018105273-appb-000295
Figure PCTCN2018105273-appb-000296
表233 A为环吡氟草酮，B为苯唑氟草酮，C为西草净
Figure PCTCN2018105273-appb-000297
表234 A为环吡氟草酮，B为苯唑氟草酮，C为二氯喹啉酸
Figure PCTCN2018105273-appb-000298
表235 A为环吡氟草酮，B为苯唑氟草酮，C为五氟磺草胺
Figure PCTCN2018105273-appb-000299
表236 A为环吡氟草酮，B为苯唑氟草酮，C为氯氟吡啶酯
Figure PCTCN2018105273-appb-000300
表237 A为环吡氟草酮，B为苯唑氟草酮，C为禾草敌
Figure PCTCN2018105273-appb-000301
Figure PCTCN2018105273-appb-000302
表238 A为环吡氟草酮，B为苯唑氟草酮，C为禾草丹
Figure PCTCN2018105273-appb-000303
注：E(A)：在给定剂量下，组分A处理的实测鲜重存活率
E(B)：在给定剂量下，组分B处理的实测鲜重存活率
E(C)：在给定剂量下，组分C处理的实测鲜重存活率
E(A+B)：在给定剂量下，组分A和组分B二元混用的实测鲜重存活率
E(A+C)：在给定剂量下，组分A和组分C二元混用的实测鲜重存活率
E(B+C)：在给定剂量下，组分B和组分C二元混用的实测鲜重存活率
E(A+B+C)：在给定剂量下，组分A、B、C三元混用的实测鲜重存活率
E 0(A+B+C)：在给定剂量下，组分A、B、C三元混用的理论鲜重存活率
E 0((A+B)+C)：在给定剂量下，组分A、B作为一个整体与组分C二元混用的理论鲜重存活率
E 0((A+C)+B)：在给定剂量下，组分A、C作为一个整体与组分B二元混用的理论鲜重存活率
E 0(A+(B+C))：在给定剂量下，组分B、C作为一个整体与组分A二元混用的理论鲜重存活率C)大田示范
利用实施例1)-238)制得的除草剂组合物进行田间杂草效果试验。
2017年在安徽天长试验点进行示范性推广试验。田间发生的杂草主要有：荠菜、牛繁缕、 猪殃殃、看麦娘、日本看麦娘、菵草等。
试验方法(土壤处理)：于杂草发芽前，手动喷雾器，兑水量45公斤/667m 2，采用土壤表面均匀喷雾。具体试验药剂及剂量详见表239，小区面积50平方米，每处理重复4次。施药后45天调查防除效果见表239。
Figure PCTCN2018105273-appb-000304
表239所述复配组合物的大田示范效果情况
Figure PCTCN2018105273-appb-000305
Figure PCTCN2018105273-appb-000306
Figure PCTCN2018105273-appb-000307
Figure PCTCN2018105273-appb-000308
Figure PCTCN2018105273-appb-000309
Figure PCTCN2018105273-appb-000310
Figure PCTCN2018105273-appb-000311
Figure PCTCN2018105273-appb-000312
Figure PCTCN2018105273-appb-000313
Figure PCTCN2018105273-appb-000314
Figure PCTCN2018105273-appb-000315
经过大量试验和探索，本发明意外地发现，所述组合物用于防除荠菜、牛繁缕、猪殃殃、看麦娘、日本看麦娘、菵草等杂草具有令人惊讶的、意想不到的增效作用，这种增效作用在低剂量下表现更为显著，可降低用药量，降低对环境的污染，且合理复配降低了农用成本，对ALS、ACCase抑制剂抗性杂草高效，具有很好的应用前景。同时经过测试在对常规品种及基因编辑品种的小麦田、玉米田、水稻田、花生、甘蔗、高粱、谷子、马铃薯、油菜、大豆、棉花、蔬菜、早熟禾、高羊茅、结缕草等草坪和作物显示良好的选择性和优异的增效作用，可以开发成广泛市场价值的除草剂混剂。

Claims (10)

  1. 一种包含HPPD抑制剂类除草剂的三元除草组合物，其特征在于，包括除草有效量的活性成分A、活性成分B和活性成分C，其中，
    活性成分A选自以下HPPD抑制剂类除草剂化合物中的一种或多种：双唑草酮，环吡氟草酮和/或其盐/酯等衍生物；
    活性成分B选自以下化合物中的一种或多种：苯唑草酮，硝磺草酮，环磺酮，异噁唑草酮，双环磺草酮，三唑磺草酮，苯唑氟草酮和/或其盐/酯等衍生物；
    活性成分C选自以下化合物中的一种或多种：丙草胺，丁草胺，苯噻酰草胺，莎稗磷，仲丁灵，噁草酮，异丙隆，双唑草腈，乙氧氟草醚，异噁草松，2甲4氯，西草净，二氯喹啉酸，五氟磺草胺，氯氟吡啶酯，禾草敌，禾草丹和/或其盐/酯等衍生物。
  2. 根据权利要求1所述的一种包含HPPD抑制剂类除草剂的三元除草组合物，其特征在于，A、B和C的重量比为1～500:0.1～100:1～5000和5～300:0.5～80:5～4000；优选为10～250:0.7～50:10～3000和20～200:1～30:30～2000；更优选为30～150:3～20:50～1000和40～120:5～15:100～800；进一步优选为50～100:7～12:200～600和60～80:8～10:300～500。
  3. 根据权利要求1或2所述的一种包含HPPD抑制剂类除草剂的三元除草组合物，其特征在于，所述除草组合物中A、B和C的质量百分含量占总量的1-95％，优选10-80％。
  4. 根据权利要求1至3任意一项所述的一种包含HPPD抑制剂类除草剂的三元除草组合物，其特征在于，所述除草组合物中还包括常规助剂。
  5. 根据权利要求4所述的一种包含HPPD抑制剂类除草剂的三元除草组合物，其特征在于，所述常规助剂包括载体、表面活性剂。
  6. 根据权利要求1至5任意一项所述的一种包含HPPD抑制剂类除草剂的三元除草组合物，其特征在于，所述除草组合物进一步包括至少一种安全剂。
  7. 根据权利要求1至6任意一项所述的一种包含HPPD抑制剂类除草剂的三元除草组合物，其特征在于，所述除草组合物的具体制剂为可分散油悬浮剂、水悬浮剂、悬乳剂、可湿性粉剂、乳油、水分散粒剂、水乳剂或微乳剂。
  8. 如权利要求1至7任意一项所述包含HPPD抑制剂类除草剂的三元除草组合物在防治作物中杂草上的应用。
  9. 一种防治不想要的植物生长的方法，其包括将权利要求1至7任意一项所述包含HPPD抑制剂类除草剂的三元除草组合物施用于植物、植物部位、植物种子或植物生长的区域。
  10. 根据权利要求9所述的方法，其特征在于，用于选择性防治作物中的杂草。
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