WO2020013371A1 - Antibacterial, antifungal, and high-performance coating liquid composition and product using same - Google Patents

Antibacterial, antifungal, and high-performance coating liquid composition and product using same Download PDF

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Publication number
WO2020013371A1
WO2020013371A1 PCT/KR2018/008416 KR2018008416W WO2020013371A1 WO 2020013371 A1 WO2020013371 A1 WO 2020013371A1 KR 2018008416 W KR2018008416 W KR 2018008416W WO 2020013371 A1 WO2020013371 A1 WO 2020013371A1
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weight
antimicrobial
parts
antifungal
coating
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PCT/KR2018/008416
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French (fr)
Korean (ko)
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윤동신
이경훈
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(주)유니드
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80—Processes for incorporating ingredients

Definitions

  • the present invention relates to a coating liquid composition
  • a coating liquid composition comprising a material having excellent antimicrobial and anti-fungal properties in a UV curable resin composition used as a coating material for kitchen furniture and indoor interior furniture.
  • dispersing in the coating composition can be more completely mixed with the antimicrobial composition, and thus relates to an environmentally friendly antimicrobial and anti-fungal coating liquid composition and products using the same designed to give more antimicrobial function to the product produced.
  • Patent Publication No. 10-2015-0135397 “Coating Agent Composition and Antimicrobial, Antiviral Member”
  • the prior art contains cuprous oxide particles, metal oxide particles having no photocatalytic activity, a binder resin, and an organic solvent. And content of 1-80 mass parts of content of a photocatalyst particle in 100 mass parts of coating agent compositions, 0.1-5 mass parts of content of a cuprous oxide particle, 40-80 mass parts of total content of a photocatalyst particle and a metal oxide particle are included. It is presenting technology.
  • Patent No. 10-1724577 Alignment of a resin composition reinforced with antibacterial and deodorizing function and a method for producing the resin composition thereof
  • the prior art is coated with a resin composition for reinforcing antibacterial and deodorizing function, improved to clean the water quality by coating the antimicrobial composition made of a ceramic material harmless to the human body to prevent bacterial growth in the tap water on the inside and outside of the aluminum water pipe.
  • the aluminum tube and the resin composition manufacturing method are presented.
  • Patent Publication No. 10-2017-0111535 Anti-microbial sheet improved visibility and its manufacturing apparatus
  • Patent Publication No. 10-2016-0113572 Coating structure of a product with an antibacterial composite layer and Its coating method ”.
  • the conventional techniques merely suggest a coating layer including an antimicrobial composition, and the composition of the antimicrobial coating solution prepared by dispersing the metal oxide in a high gloss, excellent ring smoothness, durability, weather resistance, and environmentally friendly coating solution is not presented. There is a problem that it is very difficult to mix the antimicrobial composition in the composition.
  • the present invention relates to an antimicrobial and antifungal coating solution composition and a product using the same,
  • the antimicrobial and antifungal coating composition mainly uses inorganic oxides, and has excellent antibacterial and antifungal properties against E. coli, Staphylococcus aureus, pneumococcus, Pseudomonas aeruginosa, MRSA, high gloss, excellent smoothness, durability, weather resistance, eco-friendly antibacterial and antifungal It is an object to provide a coating composition.
  • the coating liquid composition commonly used in MDF, a polymer film, a glass substrate, a metal substrate, artificial leather in order to increase the surface strength is aimed to solve the problem that is usually not mixed with inorganic oxides.
  • inorganic oxides (metal oxides) to metals (oxides) are finely divided into nano-sizes and dispersed in a coating solution, and are completely mixed with high gloss, excellent smoothness, durability, weather resistance, environment-friendly, antibacterial properties and
  • Another object of the present invention is to provide an antifungal coating solution composition.
  • UV curable oligomer 30 to 70 wt% of UV curable oligomer, 20 to 60 wt% of UV curable monomer, 0.1 to 5 wt% of antibacterial and antifungal substances, and 0.1 to 5 wt% of photoinitiator and functional additive.
  • the present invention relates to an environment-friendly antimicrobial and antifungal coating liquid composition and a product using the same,
  • the inorganic oxides (metal oxides) to metals (oxides) are nano-sized into fine particles and dispersed in the coating solution, so that the coating liquid composition is used for the surface strength of MDF, polymer film, glass substrate, metal substrate, and artificial leather. There is an effect that mixing can be done perfectly.
  • FIG. 1 is a schematic diagram of an antimicrobial and antifungal product according to the present invention
  • Figure 2 is a photograph of the antimicrobial activity of the antimicrobial microorganisms according to the present invention
  • the same reference numerals in particular, the tens and ones digits, or the same digits, tens and ones, and the same alphabet, refer to members having the same or similar functions, and unless otherwise specified, each member in the figures The member referred to by the reference numeral may be regarded as a member conforming to these criteria.
  • the present invention relates to a coating liquid composition comprising a material having excellent antimicrobial and antifungal properties in a UV curable resin composition used as a coating material for kitchen furniture and indoor interior furniture surfaces.
  • FIG. 1 is a product coated with the coating liquid of the present invention. As showing
  • the coating solution is UV curable oligomer 30 ⁇ 70 wt%, UV curable monomer 20 ⁇ 60 wt%, antibacterial and antifungal substances or surface treated antibacterial and antifungal substances 0.1 ⁇ 5 wt%, photoinitiator and functional additives 0.1 ⁇ 5 It comprises a wt%.
  • Metal oxide particles comprising at least one of zinc oxide, titanium oxide, tungsten oxide, zeolite, clay, metal particles or metal ion materials comprising at least one of copper, zinc, gold,
  • It contains at least one of quaternary ammonium salts, phosphonium salts, pyridine compounds, organic halogen compounds, and organic compounds including thiazolin, which is dispersed or mixed in an acrylic monomer, and is made to be finely mixed in nano units. .
  • Surface treated metal oxide particles comprising at least one of surface treated zinc oxide, titanium oxide, tungsten oxide, zeolite, clay,
  • Surface treated metal particles comprising at least one of surface treated silver, copper, zinc, and gold,
  • the surface treatment agent used in this case is 3- (Trimethoxysilyl) propyl vinyl carbonate, 3- (Trimethoxysilyl) propyl acrylate, 3- (Trimethoxysilyl) propyl methacrylate,
  • It comprises one or more of 3- (2,3-Epoxypropyloxy) propyltriethoxysilane and tetramethyl orthosilicate.
  • Such antimicrobial and antifungal substances are characterized by excellent bactericidal or mold growth inhibition against E. coli, Staphylococcus aureus, Pseudomonas aeruginosa, pneumococci, MRSA (Methicillin Resistant Staphylococcus Aureus).
  • the metal oxides have a particle size of more than 0 and 100 nm or less, and the metals have a particle size of more than 0 and 20 nm or less to improve the ease of mixing, and have a specific surface area of 40 m 2 / g or more. do.
  • the average particle size is more than 100nm, the transparency of the coating film realized by scattering by light is inferior, especially in the case of the metal nanoparticles having an average particle size of more than 0 and 20nm or less because the antibacterial activity is excellent.
  • the UV curable oligomer is a multifunctional oligomer having at least one acrylic group in one molecule
  • the UV curable monomer is composed of a 1-2 functional monomer or a polyfunctional monomer having one or more acrylic groups in one molecule to improve the antibacterial and antifungal performance.
  • the UV curable oligomer Specifically, the UV curable oligomer
  • UV-curable oligomer substituted with an acryl group at the end and middle, and having 4 or more functional groups, a UV-curable oligomer substituted at both ends with an acryl group, and a UV-curable oligomer substituted at the end and an intermediate with an acrylic group.
  • the UV curable monomer is N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl
  • UV monomer monofunctional including 2-Hydoxypropyl Acylate, 2-Hydroxyethyl Metha Acrylate,
  • Trimethylolpropane Triacrylate Pentaerythritol Triacrylate containing a trifunctional group comprising a triacrylate.
  • antimicrobial and antifungal metal oxide particles or metal particles are provided.
  • the substrate applied to the present invention is characterized in that it comprises at least one of a furniture material, a polymer film, a glass substrate, a metal substrate and artificial leather.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the antimicrobial, antifungal and high functionality coating solution prepared as described above was applied to prepare a processable board through UV curing.
  • the defoaming 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution.
  • room temperature 23 ° C ⁇ 3 ° C
  • the mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the defoaming 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution.
  • room temperature 23 ° C ⁇ 3 ° C
  • the mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the defoaming 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution.
  • room temperature 23 ° C ⁇ 3 ° C
  • the mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the defoaming 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution.
  • room temperature 23 ° C ⁇ 3 ° C
  • a mechanical stirrer and a dissolver were used to prepare an antimicrobial, antifungal and high functional coating solution by stirring at 1,000 RPM for 1 hour.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the defoaming 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution.
  • room temperature 23 ° C ⁇ 3 ° C
  • the mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the defoaming 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution.
  • room temperature 23 ° C ⁇ 3 ° C
  • the mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the defoaming 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution.
  • room temperature 23 ° C ⁇ 3 ° C
  • the mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
  • the antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
  • the average particle size of the prepared ZnO Sol was measured using a particle size analyzer (four models).
  • Pencil hardness was measured at 750 g load using a pencil hardness tester according to ASTM D3502 measurement.
  • the glossiness of the coating film according to the KS M ISO 2813 measurement method was measured using a Glossmeter (Company model). The gloss value was determined from the average value (60 o ) of the three coating layer surfaces.
  • polished black glass with a refractive index of 1.567 at a wavelength of 587.6 nm is defined as 100 in 20, 60, and 85 batches.
  • the gloss value is affected by the surface properties (eg roughness, texture, structure) of the sample.
  • the degree of peeled part after tape adhesion test in 25 2 X 2 mm scales was classified and evaluated as follows.
  • Class 0 Cutting surface is smooth. There is no stripped rectangular grid.
  • Class 2 (3B): The coating is peeled into small pieces along the cut plane and / or at the cut line intersection. Stripped crosscut area is 5% to 15%
  • Classification 3 (2B): The coating is peeled off in small ribbons, in part or in whole, along the cutting plane and / or in other parts of the rectangle in the form of large ribbons. Exfoliated crosscut area is 15% to 35%
  • Classification 4 (1B): The coating is peeled off into small pieces along the cut surface in the form of a large ribbon and / or part or all of the rectangle is peeled off. Exfoliated crosscut area is 35% to 65%
  • Class 5 (0B): Flaking not applicable to Class 4
  • Grade 3 Medium change in gloss and / or color
  • Grade 2 Significant change in gloss and / or color

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
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Abstract

The present invention relates to a coating liquid composition comprising a UV-curable resin composition for use as a painting material for surfaces of kitchen furniture and interior furniture; and a material having excellent antibacterial and antifungal activity. Inorganic oxides and metals are atomized into nano sizes and dispersed in a coating liquid whereby the coating liquid composition can be more completely mixed with an antibacterial and antifungal composition. Thus, the present invention relates to an eco-friendly, antibacterial coating liquid composition designed to impart antibacterial and antifungal activity to the product applied therewith.

Description

항균성, 항곰팡이성 및 고기능성 코팅액 조성물 및 이를 이용한 제품Antimicrobial, antifungal and high functional coating liquid composition and products using the same
본 발명은 주방 가구 및 실내 인테리어 가구 표면의 도장재로 사용되는 UV 경화형 수지 조성물에 항균성 및 항 곰팡이성이 우수한 물질을 포함하는 코팅액 조성물에 관한 것으로서, 무기산화물 내지 금속물을 나노 크기로 미립자화시켜 코팅액에 분산 처리함에 따라 코팅액 조성물에 항균성 조성물을 보다 완벽하게 혼합할 수 있으며, 이에 따라 제조되는 제품에 보다 항균성 기능을 부여할 수 있도록 고안된 친환경 항균성 및 항곰팡이성 코팅액 조성물 및 이를 이용한 제품에 관한 것이다.The present invention relates to a coating liquid composition comprising a material having excellent antimicrobial and anti-fungal properties in a UV curable resin composition used as a coating material for kitchen furniture and indoor interior furniture. By dispersing in the coating composition can be more completely mixed with the antimicrobial composition, and thus relates to an environmentally friendly antimicrobial and anti-fungal coating liquid composition and products using the same designed to give more antimicrobial function to the product produced.
항균성 코팅 조성물과 관련된 종래기술로는 공개특허 제10-2015-0135397호 “코팅제 조성물 및 항균, 항바이러스성 부재”가 있는데,Prior arts related to antimicrobial coating compositions include Patent Publication No. 10-2015-0135397 "Coating Agent Composition and Antimicrobial, Antiviral Member,"
상기 종래기술은 아산화구리 입자와, 광촉매 활성을 갖지 않는 금속 산화물 입자와, 바인더 수지와, 유기용제를 함유한다. 그리고, 코팅제 조성물 100질량부 중에 있어서의, 광촉매 입자의 함유량이 1~80질량부, 아산화구리 입자의 함유량이 0.1~5질량부, 광촉매 입자와 금속 산화물 입자의 합계 함유량이 40~80질량부를 포함하는 기술을 제시하고 있다.The prior art contains cuprous oxide particles, metal oxide particles having no photocatalytic activity, a binder resin, and an organic solvent. And content of 1-80 mass parts of content of a photocatalyst particle in 100 mass parts of coating agent compositions, 0.1-5 mass parts of content of a cuprous oxide particle, 40-80 mass parts of total content of a photocatalyst particle and a metal oxide particle are included. It is presenting technology.
또 다른 종래기술로는 등록특허 제10-1724577호 “항균 및 탈취 기능이 보강된 수지조성물이 코팅된 알루미늄판 및 그 수지조성물 제조방법”이 있는데,Another conventional technology is Patent No. 10-1724577 "Aluminum plate coated with a resin composition reinforced with antibacterial and deodorizing function and a method for producing the resin composition thereof,"
상기 종래기술은 수돗물에서의 세균증식을 방지하기 위하여 인체에 무해한 세라믹 물질로 이루어진 항균성 조성물을 알루미늄 수도관의 내, 외부에 코팅하여 수질을 정화하도록 개선된, 항균 및 탈취 기능이 보강용 수지 조성물이 코팅된 알루미늄관 및 그 수지조성물 제조방법을 제시하고 있다.The prior art is coated with a resin composition for reinforcing antibacterial and deodorizing function, improved to clean the water quality by coating the antimicrobial composition made of a ceramic material harmless to the human body to prevent bacterial growth in the tap water on the inside and outside of the aluminum water pipe. The aluminum tube and the resin composition manufacturing method are presented.
이 밖에 또 다른 종래기술로는 공개특허 제10-2017-0111535호 “시인성이 향상된 항균시트 및 그 제조장치”, 공개특허 제10-2016-0113572호 “항균복합층이 구비된 제품의 코팅구조 및 그의 코팅방법”을 들 수 있다.In addition, the prior art Patent Publication No. 10-2017-0111535 "Anti-microbial sheet improved visibility and its manufacturing apparatus", Patent Publication No. 10-2016-0113572 "Coating structure of a product with an antibacterial composite layer and Its coating method ”.
그러나 상기 종래기술들은 단순히 항균성 조성물을 포함한 코팅층을 제시하는 것으로서, 고광택, 우수환 평활도, 내구성, 내후성, 친환경적인 코팅액에 금속산화물을 분산 처리하여 제조한 항균성 코팅액의 조성물은 제시되지 않고 있으며, 이에 따라 코팅액 조성물에 항균성 조성물을 혼합하기가 매우 어렵다는 문제점이 있다.However, the conventional techniques merely suggest a coating layer including an antimicrobial composition, and the composition of the antimicrobial coating solution prepared by dispersing the metal oxide in a high gloss, excellent ring smoothness, durability, weather resistance, and environmentally friendly coating solution is not presented. There is a problem that it is very difficult to mix the antimicrobial composition in the composition.
본 발명은 항균성 및 항곰팡이성 코팅액 조성물 및 이를 이용한 제품에 관한 것으로서,The present invention relates to an antimicrobial and antifungal coating solution composition and a product using the same,
항균성 및 항곰팡이성 코팅액 조성물은 무기산화물을 주로 사용하며, 대장균, 황색포도상구균, 폐렴균, 녹농균, MRSA에 대한 우수한 항균력 및 우수한 항곰팡이성, 고광택, 우수한 평활도, 내구성, 내후성, 친환경 항균성 및 항곰팡이성 코팅액 조성물을 제공함을 목적으로 한다.The antimicrobial and antifungal coating composition mainly uses inorganic oxides, and has excellent antibacterial and antifungal properties against E. coli, Staphylococcus aureus, pneumococcus, Pseudomonas aeruginosa, MRSA, high gloss, excellent smoothness, durability, weather resistance, eco-friendly antibacterial and antifungal It is an object to provide a coating composition.
또한 표면강도를 증가하기 위하여 MDF, 고분자필름, 유리기판, 금속기판, 인조가죽에 공통적으로 사용하는 코팅액 조성물은 통상적으로 무기 산화물과 혼합이 되지 않는 다는 문제점을 해결하는 것을 목적으로 한다.In addition, the coating liquid composition commonly used in MDF, a polymer film, a glass substrate, a metal substrate, artificial leather in order to increase the surface strength is aimed to solve the problem that is usually not mixed with inorganic oxides.
특히, 상기와 같은 문제점을 해결하기 위하여 무기 산화물(금속산화물) 내지 금속물(산화물)을 나노 사이즈로 미립자화시켜 코팅액에 분산 처리하여 완전히 혼합한 고광택, 우수한 평활도, 내구성, 내후성, 친환경, 항균성 및 항곰팡이성 코팅액 조성물을 제공함을 또 하나의 목적으로 한다.In particular, in order to solve the above problems, inorganic oxides (metal oxides) to metals (oxides) are finely divided into nano-sizes and dispersed in a coating solution, and are completely mixed with high gloss, excellent smoothness, durability, weather resistance, environment-friendly, antibacterial properties and Another object of the present invention is to provide an antifungal coating solution composition.
본 발명에 따른 항균성 및 항곰팡이성 코팅액 조성물은The antimicrobial and antifungal coating solution composition according to the present invention
UV 경화형 올리고머 30~70 wt%, UV 경화형 모노머 20~60 wt%, 항균 및 항곰팡이성 물질 0.1~5 wt%, 광개시제 및 기능성 첨가제 0.1~5 wt%를 포함하여 이루어지는 것을 특징으로 한다.30 to 70 wt% of UV curable oligomer, 20 to 60 wt% of UV curable monomer, 0.1 to 5 wt% of antibacterial and antifungal substances, and 0.1 to 5 wt% of photoinitiator and functional additive.
본 발명은 친환경 항균성 및 항곰팡이성 코팅액 조성물 및 이를 이용한 제품에 관한 것으로서,The present invention relates to an environment-friendly antimicrobial and antifungal coating liquid composition and a product using the same,
무가산화물을 주로 사용하며, 항균성 및 항곰팡이성 제품 기준을 향상시켜 고광택, 우수한 평활도, 내구성, 내후성, 친환경적이라는 효과가 있다.It mainly uses non-oxides and improves antibacterial and anti-fungal product standards. It has high gloss, excellent smoothness, durability, weather resistance, and eco-friendliness.
또한 무기 산화물(금속산화물) 내지 금속물(산화물)을 나노 사이즈로 미립자화시켜 코팅액에 분산 처리함에 따라 MDF, 고분자필름, 유리기판, 금속기판, 인조가죽의 표면강도를 위해 사용되는 코팅액 조성물과의 혼합이 완벽하게 이루질 수 있는 효과가 있다.In addition, the inorganic oxides (metal oxides) to metals (oxides) are nano-sized into fine particles and dispersed in the coating solution, so that the coating liquid composition is used for the surface strength of MDF, polymer film, glass substrate, metal substrate, and artificial leather. There is an effect that mixing can be done perfectly.
도 1은 본 발명에 따른 항균성 및 항곰팡이성 제품의 개략도1 is a schematic diagram of an antimicrobial and antifungal product according to the present invention
도 2는 본 발명에 따른 항균성 미생물의 항균력 시험 사진도Figure 2 is a photograph of the antimicrobial activity of the antimicrobial microorganisms according to the present invention
이하 첨부된 도면을 참고하여 본 발명을 상세히 설명하도록 한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
본 발명은 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있는 바, 구현예(態樣, aspect)(또는 실시예)들을 본문에 상세하게 설명하고자 한다. 그러나 이는 본 발명을 특정한 개시 형태에 대해 한정하려는 것이 아니며, 본 발명의 사상 및 기술범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다. Since the present invention may be modified in various ways and have various forms, embodiments (or embodiments) will be described in detail in the text. However, this is not intended to limit the present invention to the specific form disclosed, it should be understood to include all modifications, equivalents, and substitutes included in the spirit and scope of the present invention.
각 도면에서 동일한 참조부호, 특히 십의 자리 및 일의 자리 수, 또는 십의 자리, 일의 자리 및 알파벳이 동일한 참조부호는 동일 또는 유사한 기능을 갖는 부재를 나타내고, 특별한 언급이 없을 경우 도면의 각 참조부호가 지칭하는 부재는 이러한 기준에 준하는 부재로 파악하면 된다.In each of the drawings, the same reference numerals, in particular, the tens and ones digits, or the same digits, tens and ones, and the same alphabet, refer to members having the same or similar functions, and unless otherwise specified, each member in the figures The member referred to by the reference numeral may be regarded as a member conforming to these criteria.
또 각 도면에서 구성요소들은 이해의 편의 등을 고려하여 크기나 두께를 과장되게 크거나(또는 두껍게) 작게(또는 얇게) 표현하거나, 단순화하여 표현하고 있으나 이에 의하여 본 발명의 보호범위가 제한적으로 해석되어서는 안 된다.In addition, in the drawings, the components are exaggerated in size (or thick) in size (or thick) in size (or thin) or simplified in consideration of the convenience of understanding and the like, thereby limiting the scope of protection of the present invention. It should not be.
본 명세서에서 사용한 용어는 단지 특정한 구현예(태양, 態樣, aspect)(또는 실시예)를 설명하기 위해 사용된 것으로, 본 발명을 한정하려는 의도가 아니다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. 본 출원에서, ~포함하다~ 또는 ~이루어진다~ 등의 용어는 명세서 상에 기재된 특징, 숫자, 단계, 동작, 구성요소, 부분품 또는 이들을 조합한 것이 존재함을 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 동작, 구성요소, 부분품 또는 이들을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다.The terminology used herein is for the purpose of describing particular embodiments (suns, aspects, and embodiments) (or embodiments) only and is not intended to be limiting of the invention. Singular expressions include plural expressions unless the context clearly indicates otherwise. In this application, the terms “comprises” or “consists” are intended to indicate that there is a feature, number, step, operation, component, part, or combination thereof described on the specification, but one or more other features. It is to be understood that the present invention does not exclude the possibility of the presence or the addition of numbers, steps, operations, components, parts, or combinations thereof.
다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가지고 있다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥 상 가지는 의미와 일치하는 의미를 가지는 것으로 해석되어야 하며, 본 출원에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art. Terms such as those defined in the commonly used dictionaries should be construed as having meanings consistent with the meanings in the context of the related art and shall not be construed in ideal or excessively formal meanings unless expressly defined in this application. Do not.
본 발명은 주방 가구 및 실내 인테리어 가구 표면의 도장재로 사용되는 UV 경화형 수지 조성물에 항균성 및 항곰팡이성이 우수한 물질을 포함하는 코팅액 조성물에 관한 것으로서, 도 1은 본 발명의 코팅액을 이용하여 코팅한 제품을 도시한 것으로서,The present invention relates to a coating liquid composition comprising a material having excellent antimicrobial and antifungal properties in a UV curable resin composition used as a coating material for kitchen furniture and indoor interior furniture surfaces. FIG. 1 is a product coated with the coating liquid of the present invention. As showing
상기 코팅액은 UV 경화형 올리고머 30~70 wt%, UV 경화형 모노머 20~60 wt%, 항균 및 항곰팡이성 물질 또는 표면 처리된 항균성 및 항곰팡이성 물질 0.1~5 wt%, 광개시제 및 기능성 첨가제 0.1~5 wt%를 포함하여 이루어지는 것을 특징으로 한다.The coating solution is UV curable oligomer 30 ~ 70 wt%, UV curable monomer 20 ~ 60 wt%, antibacterial and antifungal substances or surface treated antibacterial and antifungal substances 0.1 ~ 5 wt%, photoinitiator and functional additives 0.1 ~ 5 It comprises a wt%.
이 때 상기 항균성 및 항곰팡이성 물질은 At this time, the antimicrobial and antifungal substances are
산화아연, 산화티타늄, 산화텅스텐, 제올라이트, 클레이 중 하나 이상을 포함하는 금속산화물 입자 은, 구리, 아연, 금 중 하나 이상을 포함하는 금속 입자 또는 금속 이온 물질, Metal oxide particles comprising at least one of zinc oxide, titanium oxide, tungsten oxide, zeolite, clay, metal particles or metal ion materials comprising at least one of copper, zinc, gold,
4차 암모늄염, 포스포늄염, 피리딘 화합물, 유기 할로겐 화합물, 티아졸린을 포함하는 유기 화합물 중 하나 이상을 포함하며, 아크릴계 모노머에 분산 또는 혼합하여 이루어지는 것으로서, 나노단위로 미립자화 시켜 혼합할 수 있도록 한다.It contains at least one of quaternary ammonium salts, phosphonium salts, pyridine compounds, organic halogen compounds, and organic compounds including thiazolin, which is dispersed or mixed in an acrylic monomer, and is made to be finely mixed in nano units. .
또한 표면 처리된 항균성 및 항곰팡이성 물질은 In addition, surface-treated antimicrobial and antifungal substances
표면 처리된 산화아연, 산화티타늄, 산화텅스텐, 제올라이트, 클레이 중 하나 이상을 포함하는 표면 처리된 금속산화물 입자,Surface treated metal oxide particles comprising at least one of surface treated zinc oxide, titanium oxide, tungsten oxide, zeolite, clay,
표면 처리된 은, 구리, 아연, 금 중 하나 이상을 포함하는 표면 처리된 금속 입자를 포함하여 이루어지고,Surface treated metal particles comprising at least one of surface treated silver, copper, zinc, and gold,
이 때 사용되는 표면처리제는 3-(Trimethoxysilyl)propyl vinyl carbonate, 3-(Trimethoxysilyl)propyl acrylate, 3-(Trimethoxysilyl)propyl methacrylate,The surface treatment agent used in this case is 3- (Trimethoxysilyl) propyl vinyl carbonate, 3- (Trimethoxysilyl) propyl acrylate, 3- (Trimethoxysilyl) propyl methacrylate,
3-(2,3-Epoxypropyloxy) propyltriethoxysilane, Tetramethyl orthosilicate 중 하나 이상을 포함하여 이루어지게 된다.It comprises one or more of 3- (2,3-Epoxypropyloxy) propyltriethoxysilane and tetramethyl orthosilicate.
이러한 항균성 및 항곰팡이성 물질은 대장균, 황색포도상구균, 녹농균, 폐렴균, MRSA (Methicillin Resistant Staphylococcus Aureus) 등에 대한 세균감소율 또는 곰팡이 증식 억제에 우수하다는 특징이 있다.Such antimicrobial and antifungal substances are characterized by excellent bactericidal or mold growth inhibition against E. coli, Staphylococcus aureus, Pseudomonas aeruginosa, pneumococci, MRSA (Methicillin Resistant Staphylococcus Aureus).
이 때 상기 금속산화물류는 0초과 100nm 이하의 입도를 가지고, 상기 금속류는 0초과 20nm이하의 입도로 이루어져 혼합의 용이성을 향상시키도록 하며, 비표면적이 40 m2/g이상으로 이루어지는 것을 특징으로 한다.In this case, the metal oxides have a particle size of more than 0 and 100 nm or less, and the metals have a particle size of more than 0 and 20 nm or less to improve the ease of mixing, and have a specific surface area of 40 m 2 / g or more. do.
평균입도입자가 100nm 이상인 경우에는 빛에 의한 산란으로 구현된 코팅막의 투명도가 떨어지며, 특히 금속의 나노입자의 경우에는 0초과 20nm 이하의 평균입도를 가질 때 항균력이 우수하기 때문이다.If the average particle size is more than 100nm, the transparency of the coating film realized by scattering by light is inferior, especially in the case of the metal nanoparticles having an average particle size of more than 0 and 20nm or less because the antibacterial activity is excellent.
상기 UV 경화형 올리고머는 1 분자 중에 1개 이상의 아크릴기를 갖는 다관능 올리고머이고,The UV curable oligomer is a multifunctional oligomer having at least one acrylic group in one molecule,
상기 UV 경화형 모노머는 1 분자 중에 1개 이상의 아크릴기를 갖는 1~2관능 모노머, 또는 다관능 모노머로 구성함으로써 항균 및 항곰팡이 성능을 향상시키도록 한다.The UV curable monomer is composed of a 1-2 functional monomer or a polyfunctional monomer having one or more acrylic groups in one molecule to improve the antibacterial and antifungal performance.
구체적으로 상기 UV 경화형 올리고머는Specifically, the UV curable oligomer
말단과 중간에 아크릴그룹으로 치환되고, 관능기수가 4이상인 UV경화형 올리고머, 양끝 말단이 아크릴 그룹으로 치환된 UV 경화형 올리고머, 말단과 중간이 아크릴 그룹으로 치환된 UV 경화형 올리고머를 포함하여 이루어지고,It consists of a UV-curable oligomer substituted with an acryl group at the end and middle, and having 4 or more functional groups, a UV-curable oligomer substituted at both ends with an acryl group, and a UV-curable oligomer substituted at the end and an intermediate with an acrylic group.
상기 UV 경화형 모노머는The UV curable monomer is
2-Hydoxypropyl Acylate에 ZnO 분산액을 혼합한 혼합물과,A mixture of ZnO dispersions with 2-Hydoxypropyl Acylate,
2-Hydoxypropyl Acylate, 2-Hydroxyethyl Metha Acrylate를 포함하는 UV 모노머 1관능기와,UV monomer monofunctional including 2-Hydoxypropyl Acylate, 2-Hydroxyethyl Metha Acrylate,
Trimethylolpropane Triacrylate, Pentaerythritol Triacrylate를 포함하는 UV 모노머 3관능기를 포함하여 이루어지게 된다.Trimethylolpropane Triacrylate, Pentaerythritol Triacrylate containing a trifunctional group comprising a triacrylate.
또한 상기 항균성 및 항곰팡이성 금속산화물 입자 또는 금속 입자는In addition, the antimicrobial and antifungal metal oxide particles or metal particles
Sphere, Rod, Plate-like, Acicular, Hollow sphere, Porous sphere, Core-shell sphere 형상 중 어느 하나 이상의 형상으로 이루어지는 것이 바람직하다.Sphere, Rod, Plate-like, Acicular, Hollow sphere, Porous sphere, Core-shell sphere It is preferably made of any one or more of the shape.
아울러 본 발명에 적용되는 기재는 가구재, 고분자 필름, 유리 기판, 금속 기판 및 인조가죽 중 하나 이상을 포함하여 이루어지는 것을 특징으로 한다.In addition, the substrate applied to the present invention is characterized in that it comprises at least one of a furniture material, a polymer film, a glass substrate, a metal substrate and artificial leather.
이하 하기 실시예를 통하여 본 발명을 상세히 설명하도록 한다.Hereinafter, the present invention will be described in detail with reference to the following examples.
실시예 1Example 1
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 23 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ(말단과 중간에 아크릴 그룹으로 치환된 UV 경화형 올리고머)를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ(양끝 말단에 아크릴 그룹으로 치환된 UV 경화형 올리고머)를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate, 8 parts by weight of Trimethylolpropane Triacrylate, 2 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 23 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, and Acrylic Acrylate Oligomer I (UV curable oligomer substituted with acrylic group at the end and middle) to improve adhesion 18 parts by weight of Acrylic Acrylate Oligomer II (UV curable oligomer substituted at both ends with acrylic group) in the coating solution, 0.1 part by weight of the antifoaming agent for defoaming, 2, 4, 6-Trimethylbenzoyl- photoinitiator Photocuring from an external light source by adding 1 part by weight of diphenyl Phosphine and 3 parts by weight of Hydroxy dimethyl acetophenone in the coating solution In order to prevent the homogeneous mixing of the composition in a UV-blockable batch reactor, the mixture was stirred at 1,000 RPM for 1 hour at room temperature (23 ° C ± 3 ° C) using a mechanical stirrer and a dissolver. Functional coating solution was prepared.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
비교예 1Comparative Example 1
상기 실시예 1에서 사용된 ZnO Sol 코팅액 중 19 중량부를 2-Hydoxypropyl Acylate로 교체한 것을 제외하고는 동일하게 진행하였다.The same procedure was followed except that 19 parts by weight of the ZnO Sol coating solution used in Example 1 was replaced with 2-Hydoxypropyl Acylate.
실시예 2Example 2
ZnO Sol을 코팅액 중 25 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 17 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.25 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate, 8 parts by weight of Trimethylolpropane Triacrylate, 2 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 17 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for improving adhesion, and 19 parts by weight of Acrylic Acrylate Oligomer II for coating For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.On the LPM board used as a base board to form an antimicrobial, antifungal and high functional processability board, the antimicrobial, antifungal and high functionality coating solution prepared as described above was applied to prepare a processable board through UV curing.
비교예 2Comparative Example 2
실시예 2에서 사용된 ZnO Sol 코팅액을 제외하고 2-Hydoxypropyl Acylate를 코팅액 중 10 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 20 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 30 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 21 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다. 가공성 보드 제조는 동일하게 진행하였다.Except for the ZnO Sol coating solution used in Example 2, 10 parts by weight of 2-Hydoxypropyl Acylate in coating solution, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate in coating solution, 8 parts by weight of Trimethylolpropane Triacrylate in coating solution, and 2 parts in coating solution in Pentaerythritol Triacrylate. 2 parts by weight of Phosphate methacrylate, an adhesion promoter, 20 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 30 parts by weight of Acrylic Acrylate Oligomer I for coating, and 30 parts by weight of Acrylic Acrylate Oligomer Ⅱ for coating 21 parts by weight of the antifoaming agent, 0.1 parts by weight of the coating solution for defoaming, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine as a photoinitiator, 1 part by weight of the coating solution and 3 parts by weight of Hydroxy dimethyl acetophenone were added from the external light source. For homogeneous mixing of the composition in a batch reactor capable of blocking UV rays to prevent photocuring, 23 ° C ± 3 ° C) using a mechanical stirrer and a dissolver was stirred for 1 hour at 1,000 RPM to prepare an antimicrobial, anti-fungal and high functional coating solution. Workability board manufacture proceeded similarly.
실시예 3Example 3
ZnO Sol을 코팅액 중 15 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 27 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.15 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate, 8 parts by weight of Trimethylolpropane Triacrylate, 2 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 27 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for coating, and 18 parts by weight of Acrylic Acrylate Oligomer II for coating. For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
비교예 3Comparative Example 3
실시예 3에서 사용된 ZnO Sol 코팅액을 제외하고 2-Hydoxypropyl Acylate를 코팅액 중 10 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 25 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 25 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 21 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다. 가공성 보드 제조는 동일하게 진행하였다.Except for the ZnO Sol coating solution used in Example 3, 10 parts by weight of 2-Hydoxypropyl Acylate in coating solution, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate in coating solution, 8 parts by weight of Trimethylolpropane Triacrylate in coating solution, and 2 parts in coating solution in Pentaerythritol Triacrylate. By weight, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 25 parts by weight of Acrylate Oligomer with at least 6 functional groups for improving hardness, 25 parts by weight of Acrylic Acrylate Oligomer I for improving adhesion, and 25 parts by weight of Acrylic Acrylate Oligomer II in coating 21 parts by weight of the antifoaming agent, 0.1 parts by weight of the coating solution for defoaming, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine as a photoinitiator, 1 part by weight of the coating solution and 3 parts by weight of Hydroxy dimethyl acetophenone were added from the external light source. For homogeneous mixing of the composition in a batch reactor capable of blocking UV rays to prevent photocuring, 23 ° C ± 3 ° C) using a mechanical stirrer and a dissolver was stirred for 1 hour at 1,000 RPM to prepare an antimicrobial, anti-fungal and high functional coating solution. Workability board manufacture proceeded similarly.
실시예 4Example 4
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 18 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 23 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate, 8 parts by weight of Trimethylolpropane Triacrylate, 2 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 18 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 23 parts by weight of Acrylic Acrylate Oligomer I for improving adhesion, and 19 parts by weight of Acrylic Acrylate Oligomer Ⅱ in coating For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
비교예 4Comparative Example 4
실시예 4에서 사용된 ZnO Sol 코팅액을 제외하고 2-Hydoxypropyl Acylate를 코팅액 중 6 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 30 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 25 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 20 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다. 가공성 보드 제조는 동일하게 진행하였다.Except for the ZnO Sol coating solution used in Example 4, 6 parts by weight of 2-Hydoxypropyl Acylate, 2 parts by weight of 2-Hydroxyethyl Metha Acrylate, 3 parts by weight of Trimethylolpropane Triacrylate, 8 parts by weight of Coating, Pentaerythritol Triacrylate 2 2 parts by weight of Phosphate methacrylate, an adhesion promoter, 30 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 25 parts by weight of Acrylic Acrylate Oligomer I for improving adhesion, and 25 parts by weight of Acrylic Acrylate Oligomer II 20 parts by weight of the antifoaming agent, 0.1 parts by weight of the coating solution for defoaming, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution and 3 parts by weight of Hydroxy dimethyl acetophenone were added from the external light source. Room temperature (2) for homogeneous mixing of the composition in a batch reactor capable of blocking UV rays to prevent photocuring. 3 ° C ± 3 ° C) using a mechanical stirrer and a dissolver was stirred at 1,000 RPM for 1 hour to prepare an antimicrobial, antifungal and high functional coating solution. Workability board manufacture proceeded similarly.
실시예 5Example 5
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 18 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 24 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate, 8 parts by weight of Trimethylolpropane Triacrylate, 2 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 18 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for improving adhesion, and 24 parts by weight of Acrylic Acrylate Oligomer II in coating. For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
비교예 5Comparative Example 5
실시예 5에서 사용된 ZnO Sol 코팅액을 제외하고 2-Hydoxypropyl Acylate를 코팅액 중 1 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 35 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 25 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 20 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다. 가공성 보드 제조는 동일하게 진행하였다.Except for the ZnO Sol coating solution used in Example 5, 1 part by weight of 2-Hydoxypropyl Acylate was added, 2 parts by weight of 2-Hydroxyethyl Metha Acrylate, 3 parts by weight of Trimethylolpropane Triacrylate was added, 8 parts by weight of Pentaerythritol Triacrylate was added. By weight, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 35 parts by weight of Acrylate Oligomer having 6 functional groups or more for improving hardness, 25 parts by weight of Acrylic Acrylate Oligomer I for improving adhesion, and 25 parts by weight of Acrylic Acrylate Oligomer II for coating 20 parts by weight of the antifoaming agent, 0.1 parts by weight of the coating solution for defoaming, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution and 3 parts by weight of Hydroxy dimethyl acetophenone were added from the external light source. Room temperature (2) for homogeneous mixing of the composition in a batch reactor capable of blocking UV rays to prevent photocuring. 3 ° C ± 3 ° C) using a mechanical stirrer and a dissolver was stirred at 1,000 RPM for 1 hour to prepare an antimicrobial, antifungal and high functional coating solution. Workability board manufacture proceeded similarly.
실시예 6Example 6
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 5 중량부, Trimethylolpropane Triacrylate를 코팅액 중 6 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 23 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 5 parts by weight of 2-Hydroxyethyl Metha Acrylate, 6 parts by weight of Trimethylolpropane Triacrylate, 2 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 23 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for coating, and 18 parts by weight of Acrylic Acrylate Oligomer II for coating. For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
실시예 7Example 7
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 5 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 0.3 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 23 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 5 parts by weight of 2-Hydroxyethyl Metha Acrylate, 8 parts by weight of Trimethylolpropane Triacrylate, 0.3 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 23 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for coating, and 18 parts by weight of Acrylic Acrylate Oligomer II for coating. For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent A mechanical stirrer and a dissolver were used to prepare an antimicrobial, antifungal and high functional coating solution by stirring at 1,000 RPM for 1 hour.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
실시예 8Example 8
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 6 중량부, Pentaerythritol Triacrylate를 코팅액 중 4 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 23 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate, 6 parts by weight of Trimethylolpropane Triacrylate, 4 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 23 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for coating, and 18 parts by weight of Acrylic Acrylate Oligomer II for coating. For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
실시예 9Example 9
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 3 중량부, Trimethylolpropane Triacrylate를 코팅액 중 5 중량부, Pentaerythritol Triacrylate를 코팅액 중 5 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 2 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 23 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 3 parts by weight of 2-Hydroxyethyl Metha Acrylate, 5 parts by weight of Trimethylolpropane Triacrylate, 5 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 2 parts by weight in the coating solution, 23 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for coating, and 18 parts by weight of Acrylic Acrylate Oligomer II for coating. For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
실시예 10Example 10
ZnO Sol을 코팅액 중 19 중량부, 2-Hydoxypropyl Acylate를 코팅액 중 2 중량부, 2-Hydroxyethyl Metha Acrylate를 코팅액 중 5 중량부, Trimethylolpropane Triacrylate를 코팅액 중 8 중량부, Pentaerythritol Triacrylate를 코팅액 중 2 중량부, 접착 증진제인 Phosphate methacrylate를 코팅액 중 5 중량부, 경도 향상을 위한 6관능기 이상의 Acrylate Oligomer를 23 중량부, 접착력 향상을 위한 Acrylic Acrylate Oligomer Ⅰ를 코팅액 중 18 중량부 및 Acrylic Acrylate Oligomer Ⅱ를 코팅액 중 19 중량부, 탈포를 위해 소포제를 코팅액 중 0.1 중량부, 광개시제인 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine을 코팅액 중 1 중량부 및 Hydroxy dimethyl acetophenone을 코팅액 중 3 중량부를 첨가하여 외부의 광원으로부터 광경화를 방지하기 위해 자외선 차단이 가능한 회분식 반응조 안에서 조성물의 균질한 혼합을 위하여 상온 (23 ℃ ± 3℃)에서 메카니컬 스터러와 디졸버를 사용하여 1,000 RPM으로 1 시간 동안 교반 하여 항균성, 항곰팡이성 및 고기능성 코팅액을 제조하였다.19 parts by weight of ZnO Sol, 2 parts by weight of 2-Hydoxypropyl Acylate, 5 parts by weight of 2-Hydroxyethyl Metha Acrylate, 8 parts by weight of Trimethylolpropane Triacrylate, 2 parts by weight of Pentaerythritol Triacrylate, Phosphate methacrylate, an adhesion promoter, 5 parts by weight in the coating solution, 23 parts by weight of Acrylate Oligomer with at least 6 functional groups to improve hardness, 18 parts by weight of Acrylic Acrylate Oligomer I for coating, and 18 parts by weight of Acrylic Acrylate Oligomer II for coating. For the defoaming, 0.1 parts by weight of the antifoaming agent was added, 2, 4, 6-Trimethylbenzoyl-diphenyl Phosphine, a photoinitiator, 1 part by weight of the coating solution, and 3 parts by weight of hydroxy dimethyl acetophenone were added to the coating solution. At room temperature (23 ° C ± 3 ° C) for homogeneous mixing of the composition in a batch-reactor with UV protection to prevent The mixture was stirred for one hour to 1,000 RPM using a Carney curl stirrer and dissolver to prepare an anti-microbial, anti-fungal, and a high functional coating.
항균성, 항곰팡이성 및 고기능성 가공성 보드를 형성하기 위해 기재 보드로 사용한 ㈜ 유니드의 LPM 보드 위에 상기와 같이 제조된 항균성, 항곰팡이성 및 고기능성 코팅액을 도포한 후 UV 경화를 통하여 가공성 보드를 제조하였다.The antimicrobial, antifungal and high functional coatings were prepared on the LPM board of Unide Co., Ltd., which was used as a base board to form the antimicrobial, antifungal and high functional coating boards. It was.
상기 실시예 1 내지 실시예 10과, 비교예 1 내지 5를 하기 분석방법을 통하여 결과를 도출하였다.Examples 1 to 10 and Comparative Examples 1 to 5 were derived through the following analysis method.
1. 평균 입도1. Average particle size
제조한 ZnO Sol의 평균 입도는 입도분석기 (사 모델)를 이용하여 측정하였다.The average particle size of the prepared ZnO Sol was measured using a particle size analyzer (four models).
제조한 ZnO Sol에서 0.1 g취하여 에탄올 10.0 g에 첨가 후 1분 동안 Vortexing한 용액을 이용하여 평균 입도를 측정하였다.0.1 g of the prepared ZnO Sol was added to 10.0 g of ethanol, and the average particle size was measured using a solution that was vortexed for 1 minute.
2. 연필경도2. Pencil Hardness
ASTM D3502 측정법에 따라 연필경도시험기를 사용하여 750 g 하중으로 연필경도를 측정하였다.Pencil hardness was measured at 750 g load using a pencil hardness tester according to ASTM D3502 measurement.
3. 표면 광택3.surface polished
KS M ISO 2813 측정법에 따라 구현된 코팅막의 광택은 Glossmeter (사 모델)를 이용하여 측정하였다. 코팅막 표면 세 곳의 평균값 (60 o기준)으로 광택 값을 결정하였다.The glossiness of the coating film according to the KS M ISO 2813 measurement method was measured using a Glossmeter (Company model). The gloss value was determined from the average value (60 o ) of the three coating layer surfaces.
1) 광택 값은 광택도 단위(GU)로 표시한다. 광택 값을 “% 반사”로 해석하고 표현하는 것은 허용되지 않는다.1) Gloss value is expressed in gloss unit (GU). Interpretation and representation of gloss values as “% reflection” is not allowed.
2) 도막에서 측정된 광택 값은 (소수 없이) 가장 가까운 정수로 반올림하여 표시한다.2) The gloss value measured in the coating film is rounded up to the nearest integer (without decimal).
3) 광택 척도를 규정하기 위해 587.6 nm의 파장에서 1.567의 굴절률을 지닌 윤을 낸 흑유리(polished black glass)는 20, 60 및 85 배치 형태에서 100으로 정의한다.3) To define the gloss scale, polished black glass with a refractive index of 1.567 at a wavelength of 587.6 nm is defined as 100 in 20, 60, and 85 batches.
4) 광택 값은 시료의 표면 특성(예: 거칠기, 질감, 구조)에 의해 영향을 받는다.4) The gloss value is affected by the surface properties (eg roughness, texture, structure) of the sample.
4. 접착성4. Adhesive
KS M ISO 2409 시험법에 따라 2 X 2 mm 눈금 25 개 중에서 테이프 접착성 시험 후 박리된 부분의 정도를 아래와 같이 분류하여 평가하였다. According to the KS M ISO 2409 test method, the degree of peeled part after tape adhesion test in 25 2 X 2 mm scales was classified and evaluated as follows.
1) 분류 0 (5B): 절단면이 매끄럽다. 박리된 사각형 격자가 없다.1) Class 0 (5B): Cutting surface is smooth. There is no stripped rectangular grid.
2) 분류 1 (4B): 절단선 교차점에서 도막의 작은 조각이 박리된다. 박리된 크로스컷 영역은 5% 이내2) Classification 1 (4B): A small piece of coating is peeled off at the intersection of the cutting lines. Peeled crosscut area is within 5%
3) 분류 2 (3B): 도막이 절단면을 따라 및/또는 절단선 교차점에서 작은 조각으로 박리된다. 박리된 크로스컷 영역은 5% ~ 15%3) Class 2 (3B): The coating is peeled into small pieces along the cut plane and / or at the cut line intersection. Stripped crosscut area is 5% to 15%
4) 분류 3 (2B): 도막이 커다란 리본 형태로 일부 또는 전체가 절단면을 따라 및/또는 사각형의 다른 부분에서 일부 또는 전체가 작은 조각으로 박리된다. 박리된 크로스컷 영역은 15% ~ 35%4) Classification 3 (2B): The coating is peeled off in small ribbons, in part or in whole, along the cutting plane and / or in other parts of the rectangle in the form of large ribbons. Exfoliated crosscut area is 15% to 35%
5) 분류 4 (1B): 도막이 커다란 리본 형태로 절단면을 따라 작은 조각으로 박리되고/거나 사각형의 일부 또는 전체가 박리된다. 박리된 크로스컷 영역은 35% ~ 65%5) Classification 4 (1B): The coating is peeled off into small pieces along the cut surface in the form of a large ribbon and / or part or all of the rectangle is peeled off. Exfoliated crosscut area is 35% to 65%
6) 분류 5 (0B): 분류 4에도 해당하지 않는 플레이킹6) Class 5 (0B): Flaking not applicable to Class 4
5. 내오염성5. Pollution resistance
고압 화장판-열경화성 수지 시트의 표준규격(KS M ISO 4586-2)에 따라 측정 방법에서 명시 된 결과 표시에 따라 아래와 같이 분류하였다.According to the standard specification (KS M ISO 4586-2) of high-pressure veneer-thermosetting resin sheet (KS M ISO 4586-2), according to the results indicated in the measurement method is classified as follows.
1) 5등급: 외관상 변화 없음1) Grade 5: No change in appearance
2) 4등급: 어떤 시야 각도에서만 관찰되는 광택 및/또는 색의 미약한 변화2) Grade 4: A slight change in gloss and / or color observed only at certain viewing angles
3) 3등급: 광택 및/또는 색의 중간 변화3) Grade 3: Medium change in gloss and / or color
4) 2등급: 광택 및/또는 색의 현저한 변화4) Grade 2: Significant change in gloss and / or color
1등급: 광택 표면 비틀림 및/또는 부풀음Grade 1: Glossy surface torsion and / or swelling
상기 분석방법을 통하여 하기 결과를 확인할 수 있다.Through the analysis method, the following results can be confirmed.
하기 [표1] 내지 [표2]와 같이 실시예 내지 비교예를 통하여 표준 시험방법에 따라 공인시험기관에서 진행하였다.In accordance with the standard test method through the Examples and Comparative Examples as shown in the following [Table 1] to [Table 2].
[표1] 코팅액 조성물의 UV 경화 후 실시예 코팅막의 물성표[Table 1] Physical Properties of Coating Layers of Examples after UV Curing of Coating Composition
Figure PCTKR2018008416-appb-I000001
Figure PCTKR2018008416-appb-I000001
0 등급: 시험편의 접종한 부분에 균사의 발육이 인지되지 않음Grade 0: Mycelial growth is not recognized in the inoculated portion of the specimen
[표2] 코팅액 조성물의 UV 경화 후 코팅막의 비교예 물성표[Table 2] Comparative example of the coating film after UV curing of the coating liquid composition
Figure PCTKR2018008416-appb-I000002
Figure PCTKR2018008416-appb-I000002
또 이상에서 본 발명을 설명함에 있어 첨부된 도면을 참조하여 특정 형상과 구조 및 구성을 갖는 항균성, 항곰팡이성 및 고기능성 코팅액 조성물 및 이를 이용한 제품을 위주로 설명하였으나 본 발명은 당업자에 의하여 다양한 수정, 변경 및 치환이 가능하고, 이러한 수정, 변경 및 치환은 본 발명의 보호범위에 속하는 것으로 해석되어야 한다.In addition, in the above description of the present invention, the antimicrobial, antifungal and high functional coating liquid composition having a specific shape, structure, and composition, and a product using the same have been described with reference to the accompanying drawings. Modifications and substitutions are possible and such modifications, changes and substitutions should be construed as falling within the protection scope of the present invention.

Claims (15)

  1. UV 경화형 올리고머 30~70 wt%, UV 경화형 모노머 20~60 wt%, 항균성 및 항곰팡이성 물질 또는 표면처리 된 항균성 및 항곰팡이성 물질 0.1~5 wt%, 광개시제 및 기능성 첨가제 0.1~5 wt%를 포함하여 이루어지는 것을 특징으로 하는 코팅액 조성물.30 to 70 wt% of UV curable oligomers, 20 to 60 wt% of UV curable monomers, 0.1 to 5 wt% of antimicrobial and antifungal substances or surface treated antibacterial and antifungal substances, and 0.1 to 5 wt% of photoinitiators and functional additives. Coating liquid composition, comprising a.
  2. 제 1 항에 있어서,The method of claim 1,
    상기 항균성 및 항곰팡이성 물질은The antimicrobial and antifungal substance is
    산화아연, 산화티타늄, 산화텅스텐, 제올라이트, 클레이 중 하나 이상을 포함하는 금속산화물 입자와,Metal oxide particles comprising at least one of zinc oxide, titanium oxide, tungsten oxide, zeolite, clay,
    은, 구리, 아연, 금 중 하나 이상을 포함하는 금속 입자 또는 금속 이온 물질과,Metal particles or metal ionic materials comprising at least one of silver, copper, zinc, and gold,
    4차 암모늄염, 포스포늄염, 피리딘 화합물, 유기 할로겐 화합물, 티아졸린을 포함하는 유기 화합물 중 어느 하나 이상을 포함하여 이루어지는 것을 특징으로 하는 코팅액 조성물.A coating liquid composition comprising any one or more of quaternary ammonium salts, phosphonium salts, pyridine compounds, organic halogen compounds, and organic compounds including thiazolin.
  3. 제 1 항에 있어서The method of claim 1
    상기 표면처리된 항균성 및 항곰팡이성 물질은The surface-treated antimicrobial and antifungal material
    표면처리된 산화아연, 산화티타늄, 산화텅스텐, 제올라이트, 클레이 중 하나 이상을 포함하는 표면처리된 금속산화물 입자 또는Surface-treated metal oxide particles comprising at least one of surface-treated zinc oxide, titanium oxide, tungsten oxide, zeolite, clay or
    표면처리된 은, 구리, 아연, 금 중 하나 이상을 포함하는 표면처리된 금속 입자Surface-treated metal particles comprising at least one of surface-treated silver, copper, zinc, and gold
    또는 이들 모두를 포함하여 이루어지는 것을 특징으로 하는 코팅액 조성물.Or a coating liquid composition comprising all of them.
  4. 제 1 항에 있어서The method of claim 1
    상기 표면처리된 항균성 및 항곰팡이성 물질에 사용되는 표면처리제는Surface treatment agent used in the surface-treated antimicrobial and anti-fungal material
    3-(Trimethoxysilyl)propyl vinyl carbonate, 3-(Trimethoxysilyl)propyl acrylate, 3-(Trimethoxysilyl)propyl methacrylate,3- (Trimethoxysilyl) propyl vinyl carbonate, 3- (Trimethoxysilyl) propyl acrylate, 3- (Trimethoxysilyl) propyl methacrylate,
    3-(2,3-Epoxypropyloxy) propyltriethoxysilane, Tetramethyl orthosilicate 중 하나 이상을 포함하여 이루어지는 것을 특징으로 하는 코팅액 조성물Coating liquid composition comprising one or more of 3- (2,3-Epoxypropyloxy) propyltriethoxysilane and tetramethyl orthosilicate
  5. 제 1 항에 있어서,The method of claim 1,
    상기 항균성 및 항곰팡이성 물질 또는 표면처리된 항균성 및 항곰팡이성 물질 또는 이들 모두는 평균 입도가0초과 100 nm 이하거나 비표면적이 40 m2/g이상인 물질인 것을 특징으로 하는 코팅액 조성물.The antimicrobial and antifungal material or the surface-treated antimicrobial and antifungal material, or both, the coating liquid composition, characterized in that the average particle size of more than 0 nm or less or a specific surface area of more than 40 m 2 / g.
  6. 제 2 항에 있어서,The method of claim 2,
    상기 항균성 및 항곰팡이성 금속산화물 입자 또는 금속 입자 또는 이들 모두는The antimicrobial and antifungal metal oxide particles or metal particles or both
    Sphere, Rod, Plate-like, Acicular, Hollow sphere, Porous sphere, Core-shell sphere 형상 중 어느 하나 이상의 형상으로 이루어지는 것 특징으로 하는 코팅액 조성물. Coating composition, characterized in that formed in any one or more of the shape of Sphere, Rod, Plate-like, Acicular, Hollow sphere, Porous sphere, Core-shell sphere.
  7. 제 1 항에 있어서,The method of claim 1,
    상기 UV 경화형 올리고머는 1 분자 중에 1개 이상의 아크릴기를 갖는 다관능 올리고머이고,The UV curable oligomer is a multifunctional oligomer having at least one acrylic group in one molecule,
    상기 UV 경화형 모노머는 1 분자 중에 1개 이상의 아크릴기를 갖는 1~2능 모노머, 또는 다관능 모노머인 것을 특징으로 하는 항균성 및 항곰팡이성 코팅액 조성물The UV curable monomer is an antimicrobial and antifungal coating liquid composition, characterized in that the monofunctional or bifunctional monomer having one or more acrylic groups in one molecule, or a polyfunctional monomer.
  8. 제 7 항에 있어서,The method of claim 7, wherein
    상기 UV 경화형 올리고머는The UV curable oligomer
    말단과 중간에 아크릴그룹으로 치환되고, 관능기수가 4이상인 UV경화형 올리고머, 양끝 말단이 아크릴 그룹으로 치환된 UV 경화형 올리고머, 말단과 중간이 아크릴 그룹으로 치환된 UV 경화형 올리고머를 포함하여 이루어지고,It consists of a UV-curable oligomer substituted with an acryl group at the end and middle, and having 4 or more functional groups, a UV-curable oligomer substituted at both ends with an acryl group, and a UV-curable oligomer substituted at the end and an intermediate with an acrylic group.
    상기 UV 경화형 모노머는The UV curable monomer is
    2-Hydoxypropyl Acylate에 ZnO 분산액을 혼합한 혼합물과,A mixture of ZnO dispersions with 2-Hydoxypropyl Acylate,
    2-Hydoxypropyl Acylate, 2-Hydroxyethyl Metha Acrylate를 포함하는 UV 모노머 1관능기와,UV monomer monofunctional including 2-Hydoxypropyl Acylate, 2-Hydroxyethyl Metha Acrylate,
    Trimethylolpropane Triacrylate, Pentaerythritol Triacrylate를 포함하는 UV 모노머 3관능기를 포함하여 이루어지는 것을 특징으로 하는 항균성 및 항곰팡이성 코팅액 조성물.An antimicrobial and antifungal coating liquid composition comprising a trimethylolpropane Triacrylate and a UV monomer trifunctional group containing Pentaerythritol Triacrylate.
  9. 제1항에 있어서,The method of claim 1,
    상기 코팅액 조성물이 적용되는 기재는 가구재, 고분자 필름, 유리 기판, 금속 기판 및 인조가죽 중 하나 이상을 포함하여 이루어지는 것을 특징으로 하는 제품The substrate to which the coating liquid composition is applied is a product comprising at least one of furniture, polymer film, glass substrate, metal substrate and artificial leather
  10. 제1항에 기재된 항균성 코팅액 조성물로 제작된 항균제품. An antimicrobial product prepared from the antimicrobial coating solution composition according to claim 1.
  11. 제1항에 기재된 항균성 코팅액 조성물로 제작된 실내장식자재 제품Interior decoration material product made of the antimicrobial coating liquid composition according to claim 1
  12. 제1항에 기재된 항균성 코팅액 조성물로 제작된 자동차 실내 제품Automotive interior products made from the antimicrobial coating solution composition according to claim 1
  13. 제1항에 기재된 항균성 코팅액 조성물로 제작된 HVAC (Heating, Ventilation, Air Conditioning) 제품HVAC (Heating, Ventilation, Air Conditioning) products made with the antimicrobial coating solution composition of claim 1
  14. 제1항에 기재된 항균성 코팅액 조성물로 제작된 의료용 제품A medical product made of the antimicrobial coating solution composition of claim 1
  15. 제1항에 기재된 항균성 코팅액 조성물로 제작된 완구 제품A toy product made of the antimicrobial coating solution composition according to claim 1
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3892690A1 (en) * 2020-04-09 2021-10-13 Kleemann Hellas SA Antibacterial coating with silver nanoparticles in a polymetric matrix for elevator components and components with high hygiene requirements
WO2022084474A1 (en) * 2020-10-21 2022-04-28 Codikoat Ltd Antimicrobial and/or antiviral nanoparticles

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210151576A (en) * 2020-06-05 2021-12-14 주식회사 알앤에프케미칼 Antibacterial composition and antibacterial film comprising the same
KR102335588B1 (en) * 2021-03-23 2021-12-06 주식회사 케미슈티칼 Antimicrobial water dispersion composition including copper citrate as an active ingredient
KR102361614B1 (en) * 2021-04-22 2022-02-14 주식회사 대림 Antibiotic board and manufacturing method thereof
KR102661420B1 (en) * 2021-08-23 2024-04-29 주식회사 매직카퍼 Anti-microbial banded glove
KR102401434B1 (en) * 2021-12-03 2022-05-24 (주)동연디자인 Furniture panel with antibacterial function and method for manufacturing the same
KR102517604B1 (en) * 2022-10-06 2023-04-06 서문팀버 주식회사 Antimicrobial UV curable paint composition, antimicrobial flooring board to which it is applied, manufacturing method thereof and manufacturing system thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07304616A (en) * 1994-05-16 1995-11-21 Sumitomo Osaka Cement Co Ltd Antimicrobial and antifungal combined fine particle dispersion, its production and transparent coating solution
WO2010065421A1 (en) * 2008-12-01 2010-06-10 Becton, Dickinson And Company Antimicrobial uv curable coating compositions
KR101009745B1 (en) * 2010-05-31 2011-01-19 (주) 베리콤 Dental cement composition with antimicrobial activity
KR20170028505A (en) * 2015-09-03 2017-03-14 한국생산기술연구원 Core-shell structure nanoparticles having water repellent and antibiotic, and coating composition comprising the same, and preparation method thereof
KR20180009447A (en) * 2016-07-19 2018-01-29 주식회사 에이켐텍 Paint coating method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07304616A (en) * 1994-05-16 1995-11-21 Sumitomo Osaka Cement Co Ltd Antimicrobial and antifungal combined fine particle dispersion, its production and transparent coating solution
WO2010065421A1 (en) * 2008-12-01 2010-06-10 Becton, Dickinson And Company Antimicrobial uv curable coating compositions
KR101009745B1 (en) * 2010-05-31 2011-01-19 (주) 베리콤 Dental cement composition with antimicrobial activity
KR20170028505A (en) * 2015-09-03 2017-03-14 한국생산기술연구원 Core-shell structure nanoparticles having water repellent and antibiotic, and coating composition comprising the same, and preparation method thereof
KR20180009447A (en) * 2016-07-19 2018-01-29 주식회사 에이켐텍 Paint coating method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3892690A1 (en) * 2020-04-09 2021-10-13 Kleemann Hellas SA Antibacterial coating with silver nanoparticles in a polymetric matrix for elevator components and components with high hygiene requirements
WO2022084474A1 (en) * 2020-10-21 2022-04-28 Codikoat Ltd Antimicrobial and/or antiviral nanoparticles
GB2615260A (en) * 2020-10-21 2023-08-02 Codikoat Ltd Antimicrobial and/or antiviral nanoparticles

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