WO2020010427A1 - Procédé respiratoire inverse pour l'absorption de dioxyde de carbone - Google Patents

Procédé respiratoire inverse pour l'absorption de dioxyde de carbone Download PDF

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Publication number
WO2020010427A1
WO2020010427A1 PCT/BR2019/050270 BR2019050270W WO2020010427A1 WO 2020010427 A1 WO2020010427 A1 WO 2020010427A1 BR 2019050270 W BR2019050270 W BR 2019050270W WO 2020010427 A1 WO2020010427 A1 WO 2020010427A1
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WO
WIPO (PCT)
Prior art keywords
carbon dioxide
dioxide absorption
respiratory process
inverse
continuous
Prior art date
Application number
PCT/BR2019/050270
Other languages
English (en)
Portuguese (pt)
Inventor
Leonardo GARNICA
Original Assignee
Garnica Leonardo
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Garnica Leonardo filed Critical Garnica Leonardo
Publication of WO2020010427A1 publication Critical patent/WO2020010427A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84—Biological processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M1/00—Apparatus for enzymology or microbiology
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/14—Fungi; Culture media therefor
    • C12N1/145—Fungal isolates
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/14—Fungi; Culture media therefor
    • C12N1/16—Yeasts; Culture media therefor
    • C12N1/18—Baker's yeast; Brewer's yeast
    • C12N1/185—Saccharomyces isolates
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/06—Ethanol, i.e. non-beverage
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12R—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES C12C - C12Q, RELATING TO MICROORGANISMS
    • C12R2001/00—Microorganisms ; Processes using microorganisms
    • C12R2001/645—Fungi ; Processes using fungi
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12R—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES C12C - C12Q, RELATING TO MICROORGANISMS
    • C12R2001/00—Microorganisms ; Processes using microorganisms
    • C12R2001/645—Fungi ; Processes using fungi
    • C12R2001/85—Saccharomyces
    • C12R2001/865—Saccharomyces cerevisiae
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/59—Biological synthesis; Biological purification

Definitions

  • This report refers to a reverse breathing process for carbon dioxide absorption which is generally based on the use of gases considered to be polluting, with emphasis on carbon dioxide, released into the atmosphere through a variety of means. , mainly due to industrial activities, energy transformations and transport.
  • the reverse breathing process for carbon dioxide absorption is characterized by the composition of seven (7) major technological systems that determine its operational set, namely: carbon dioxide; processing system; redox system or energization; drainage system; secondary system of food (substrates and micronutrients); exhaust system and integrated active system.
  • Figure 1 is a block diagram of the operating set defining the reverse breathing process for carbon dioxide absorption
  • Figure 2 schematically represents the functional complex in enzymatic medium (fixed bed enzyme medium) for reverse breathing process for carbon dioxide absorption;
  • Figure 3 schematically represents the functional complex in biological medium (medium with microorganisms, fungus of the genus Saccharomyces) for inverse respiratory process for carbon dioxide absorption.
  • the carbon dioxide inhalation or feeding system which makes up the reverse breathing process for carbon dioxide absorption, consists of arterial alveoli containing the enzyme complex comprised of carbonic anhydrase inserted into the transformation medium.
  • alveoli through which carbon dioxide is inhaled, assimilated and transported, carbonates, carbon dioxide fixation products, as represented in equation -3, are delivered to the transformation medium by osmotic transfer from the alveolus to the carbonate. means of transformation.
  • the Arterial Alveolus is constructed of membranous tissue, permeable to carbonates, or to the transport of equilibrium relative to equation -3.
  • the inhalation system may be employed in continuous, semi-continuous or batch-type production processes.
  • the transformation system which makes up the reverse breathing process for carbon dioxide absorption, is where enzymatic or biochemical reactions occur in which by successive reactions carbonates, together with primary fermentation reactions , are reduced, or transformed, to various metabolic.
  • the transformation system can be built in enzymatic medium, in fixed bed, or in biological medium, with fungi of the genus Saccharomyces.
  • the transformation system can operate in batch, continuous or semi-continuous mode.
  • the energizing system or Redox which makes up the reverse breathing process for carbon dioxide absorption, is responsible for supplying energy to the transformation medium to stimulate carbonate reduction reactions to ethanol, with natural increase.
  • Redox action coenzymes such as NADH coenzyme.
  • metabolic glycerol may increase, due to the natural enzymatic need of the transformation system, to regenerate coenzyme NAD.
  • the energization system is monitored and controlled by the integrated active system, establishing functionality and balance of transformation or redox reactions, depending on instant inhalation, feeding, exhaustion, drainage and instantaneous operating levels of temperature, pH , Brix and ° GL in the transformation medium.
  • the power-up system consists of capacitive converter, intelligent voltage source and ammeter, multi-channel meters and sensors.
  • the power-up system can operate in batch, continuous or semi-continuous modes.
  • the drainage system which makes up the reverse breathing process for carbon dioxide absorption, is dedicated to the drainage or withdrawal of liquid metabolites present in the transformation medium.
  • the drainage system consists of a set of drains distributed by the transformation medium.
  • Drains are constructed in membranous tissues permeable to ethanol-like metabolic, higher alcohols, acetic aldehyde, organic acids and glycerol.
  • the secondary substrate feeding system which makes up the inverse breathing process for carbon dioxide absorption, has the function of maintaining the primary fermentation reactions.
  • This substrate may be sugar for direct fermentation such as hexose monosaccharides and disaccharide.
  • the secondary micronutrient feeding system has the function of guaranteeing the balance of availability and demand of enzymatic activities, mainly by inoculating the elements: P, Zn, Mg, K, N.
  • the secondary power system can operate in batch, continuous or semi-continuous modes.
  • the exhaust system which makes up the reverse breathing process for carbon dioxide absorption, has the function of removing gases from the transformation medium.
  • Carbon dioxide may be recycled to the processing medium if recycled for recovery of entrained ethanol. In this condition the gases are recirculated by the inhalation system.
  • the exhaust system can operate in batch, continuous or semi-continuous modes.
  • the integrated active system or process which makes up the reverse breathing process for carbon dioxide absorption, is for supervisory control and data acquisition of the set of systems involved, by means of instant sensors, processors and actuators, capable of conferring the maximization and potentiation of the chemical, enzymatic and biochemical reactions, intervening in the transformation medium.
  • the capacitive converter can be built in the form of pairs or pairs of reinforcements.
  • the energy delivered to the transformation medium, either in enzymatic or biological medium, is in the range of 20J to 200KJ per hour and by converter volume: 20J / hm 3 to 200KJ / hm 3 .
  • the internal volume of the converter is in the range of 1 to 10% of the total net volume of the equipment.
  • the reinforcement spacing is between 3mm to 100mm, face to face.
  • the capacitive converter armatures can be constructed of electrical conductive material such as austenitic stainless steel, titanium or carbon.
  • the operating voltage of the voltage source is between 0.4V to 30V.
  • the capacitive converter can operate in direct current (DC), alternating (AC) or pulsating direct current (CCP) regime.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Biotechnology (AREA)
  • Biomedical Technology (AREA)
  • Genetics & Genomics (AREA)
  • General Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Botany (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Virology (AREA)
  • Sustainable Development (AREA)
  • Molecular Biology (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

L'invention concerne un procédé respiratoire inverse pour l'absorption de dioxyde de carbone, comprenant la composition de sept (7) grands systèmes technologiques qui en déterminent l'ensemble fonctionnel, soit: a) un système d'inhalation ou d'acheminement du dioxyde de carbone; b) un système de transformation; c) un système redox ou d'alimentation en énergie; d) un système de drains; e) un système secondaire d'alimentation (substrats et micronutriments); f) un système d'évacuation; et g) un système actif intégré.
PCT/BR2019/050270 2018-07-12 2019-07-11 Procédé respiratoire inverse pour l'absorption de dioxyde de carbone WO2020010427A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BRBR1020180142550 2018-07-12
BR102018014255A BR102018014255A2 (pt) 2018-07-12 2018-07-12 processo respiratório inverso para absorção de dióxido de carbono

Publications (1)

Publication Number Publication Date
WO2020010427A1 true WO2020010427A1 (fr) 2020-01-16

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PCT/BR2019/050270 WO2020010427A1 (fr) 2018-07-12 2019-07-11 Procédé respiratoire inverse pour l'absorption de dioxyde de carbone

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BR (1) BR102018014255A2 (fr)
WO (1) WO2020010427A1 (fr)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009052500A1 (fr) * 2007-10-18 2009-04-23 Novozymes A/S Procédés de production de produits de fermentation
WO2011066304A2 (fr) * 2009-11-25 2011-06-03 Codexis, Inc. Polypeptides génétiquement modifiés de l'anhydrase carbonique de classe bêta et utilisations de ceux-ci
US20110300623A1 (en) * 2008-09-29 2011-12-08 Akermin, Inc. Process for accelerated capture of carbon dioxide
WO2012003336A2 (fr) * 2010-06-30 2012-01-05 Codexis, Inc. Anhydrases carboniques chimiquement modifiées, utiles dans les systèmes de capture du carbone
WO2013106932A1 (fr) * 2012-01-17 2013-07-25 Co2 Solutions Inc. Procédé intégré pour la double conversion biocatalytique de gaz de co2 dans des produits biologiques par l'hydratation améliorée d'un enzyme et la culture biologique
US20170058409A1 (en) * 2015-08-25 2017-03-02 Indian Oil Corporation Limited Device and method for conversion of carbon dioxide to organic compounds
WO2018027167A1 (fr) * 2016-08-05 2018-02-08 North Carolina State University Systèmes et procédés de fixation de carbone à l'aide de clostridium beijerinckii solvantogénique

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009052500A1 (fr) * 2007-10-18 2009-04-23 Novozymes A/S Procédés de production de produits de fermentation
US20110300623A1 (en) * 2008-09-29 2011-12-08 Akermin, Inc. Process for accelerated capture of carbon dioxide
WO2011066304A2 (fr) * 2009-11-25 2011-06-03 Codexis, Inc. Polypeptides génétiquement modifiés de l'anhydrase carbonique de classe bêta et utilisations de ceux-ci
WO2012003336A2 (fr) * 2010-06-30 2012-01-05 Codexis, Inc. Anhydrases carboniques chimiquement modifiées, utiles dans les systèmes de capture du carbone
WO2013106932A1 (fr) * 2012-01-17 2013-07-25 Co2 Solutions Inc. Procédé intégré pour la double conversion biocatalytique de gaz de co2 dans des produits biologiques par l'hydratation améliorée d'un enzyme et la culture biologique
US20170058409A1 (en) * 2015-08-25 2017-03-02 Indian Oil Corporation Limited Device and method for conversion of carbon dioxide to organic compounds
WO2018027167A1 (fr) * 2016-08-05 2018-02-08 North Carolina State University Systèmes et procédés de fixation de carbone à l'aide de clostridium beijerinckii solvantogénique

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHENG, L. Y. ET AL.: "Evaluation of an immobilized artificial carbonic anhydrase model for CO2 sequestration", CHEM. SCI., vol. 2, 2011, pages 1515 - 1518, XP055680696 *
JAJESNIAK, P. ET AL.: "Carbon dioxide capture and utilization using biological systems: opportunities and challenges", J BIOPROCESS BIOTECH, vol. 4, no. 3, 155, 2014, XP055460547 *
MATTHEW, A. S. ET AL.: "Enhanced ethanol production via electrostatically accelerated fermentation of glucose using Saccharomyces cerevisiae", SCIENTIFIC REPORTS, vol. 5, 15713, 2015, XP055680691 *

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