WO2020004554A1 - Nonwoven fabric for absorbent articles, back sheet for absorbent articles, absorbent article and method for producing nonwoven fabric for absorbent articles - Google Patents

Nonwoven fabric for absorbent articles, back sheet for absorbent articles, absorbent article and method for producing nonwoven fabric for absorbent articles Download PDF

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Publication number
WO2020004554A1
WO2020004554A1 PCT/JP2019/025619 JP2019025619W WO2020004554A1 WO 2020004554 A1 WO2020004554 A1 WO 2020004554A1 JP 2019025619 W JP2019025619 W JP 2019025619W WO 2020004554 A1 WO2020004554 A1 WO 2020004554A1
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WO
WIPO (PCT)
Prior art keywords
sheath
core
composite fiber
fiber
nonwoven fabric
Prior art date
Application number
PCT/JP2019/025619
Other languages
French (fr)
Japanese (ja)
Inventor
保紀 中村
Original Assignee
ダイワボウホールディングス株式会社
ダイワボウポリテック株式会社
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Application filed by ダイワボウホールディングス株式会社, ダイワボウポリテック株式会社 filed Critical ダイワボウホールディングス株式会社
Publication of WO2020004554A1 publication Critical patent/WO2020004554A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/514Backsheet, i.e. the impermeable cover or layer furthest from the skin
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs

Definitions

  • the present invention relates to a nonwoven fabric for an absorbent article, a backsheet and an absorbent article for an absorbent article, and a method for producing a nonwoven fabric for an absorbent article.
  • Absorbent articles such as disposable diapers, sanitary napkins, incontinence pads, panty liners, and the like include, besides the absorber, a sheet (also referred to as a “top sheet” in some documents) located on the skin side of the user, And a sheet (also referred to as a “back sheet” in some documents) located on the side opposite to the skin side (outside) of the user and on the clothes side of the user.
  • Patent Literature 1 discloses that a back sheet is required to be hard for a user to feel stuffy between an absorbent article and a user's clothes.
  • Patent Document 1 discloses a laminated nonwoven fabric having a two-layer structure of a clothing side layer and a skin side layer as a back sheet (exterior sheet).
  • the clothing side layer of the laminated nonwoven fabric is made of PET / PE composite fiber (fineness 2.8 dtex, average fiber length 45 mm, basis weight 20 g / m 2 ), and the skin side layer is made of two types of PET / PE composite fiber ( Composite fiber A: Fineness 2.2 dtex, average fiber length 45 mm, Composite fiber B: Fineness 1.7 detx, average fiber length 45 mm, total basis weight of fibers A and B 10 g / m 2 ) and cotton (average about 27 mm, basis weight 3 g) / m 2 ) (see Table 1, Examples 1 and 2 of Patent Document 1).
  • Patent Document 1 discloses that a disposable diaper obtained by using the laminated nonwoven fabric as a back sheet has a low transpiration rate after absorbing artificial urine, and is unlikely to be wet or stuffy (Patent Document 1 paragraph 1). No. 0105).
  • the backsheet is also required to have less fuzz and less breakage of the non-woven fabric while being required to have a better touch (smoothness and softness).
  • Patent Literature 1 When a nonwoven fabric such as a back sheet contains cotton, as disclosed in Patent Document 1, cotton is likely to exist as an aggregate, and voids are likely to exist around the cotton aggregate. Among them, it is expected that the strength will be insufficient, and it will be a portion where fluffing or breakage of the nonwoven fabric is likely to occur. In Patent Literature 1, since voids are intentionally provided around the cotton, it is expected that fluff or breakage of the nonwoven fabric is likely to occur. However, Patent Literature 1 does not mention these problems at all.
  • cotton is a natural fiber and tends to be favored by consumers as a material for absorbent articles, and cotton can provide a good tactile sensation. Therefore, the demand for absorbent articles containing cotton is high. Therefore, if cotton is used as the material of the nonwoven fabric to try to obtain a better tactile sensation, voids are likely to exist around the cotton, which is likely to exist as an aggregate, as described above, and the strength is insufficient in the nonwoven fabric. , Fuzzing is likely to occur, and it is expected that tearing of the nonwoven fabric may increase.
  • the present invention is a nonwoven fabric containing cotton as a natural material, which has a better feel (smoothness and softness), has less fuzz, and has less tearing of the nonwoven fabric.
  • An object of the present invention is to provide a nonwoven fabric having an excellent balance between the two.
  • the present inventors have found that controlling the fineness of each of the first and second core-sheath composite fibers contained in the first and second fiber layers, the first and second core-sheath composites It has been found that a nonwoven fabric for an absorbent article which can solve the above-mentioned problems can be obtained by controlling each polyethylene of the sheath component of the fiber. Further, they have found that such a nonwoven fabric for absorbent articles is suitable for a back sheet, and have completed the present invention.
  • the present invention provides, as one gist, a nonwoven fabric for an absorbent article, A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2)
  • the difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene
  • the heat of fusion ⁇ H of the sheath component of the first core-sheath type composite fiber is 130
  • the present invention provides a nonwoven fabric for an absorbent article, A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2)
  • the difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
  • the present invention provides, as a further aspect, a nonwoven fabric for an absorbent article, A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2)
  • the ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
  • the present invention provides, as yet another aspect, a nonwoven fabric for an absorbent article,
  • a nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2)
  • the ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
  • the present invention provides a method for producing a nonwoven fabric for an absorbent article, Producing a first fibrous web comprising a first core-sheath composite fiber; Producing a second fibrous web comprising a second core-sheath composite fiber and cotton; Superimposing and integrating the first fiber web and the second fiber web,
  • a method for producing a nonwoven fabric for absorbent articles comprising: The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2), The difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less,
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, The heat of fusion ⁇ H of the sheath component of the first core
  • the present invention provides, as yet another aspect, a method for producing a nonwoven fabric for an absorbent article, Producing a first fibrous web comprising a first core-sheath composite fiber; Producing a second fibrous web comprising a second core-sheath composite fiber and cotton; Superimposing and integrating the first fiber web and the second fiber web,
  • a method for producing a nonwoven fabric for absorbent articles comprising: The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2), The difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less,
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium
  • the present invention provides a method for producing a nonwoven fabric for an absorbent article, Producing a first fibrous web comprising a first core-sheath composite fiber; Producing a second fibrous web comprising a second core-sheath composite fiber and cotton; Superimposing and integrating the first fiber web and the second fiber web,
  • a method for producing a nonwoven fabric for absorbent articles comprising: The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2), The ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, The heat of fusion ⁇ H of the sheath component of the
  • the present invention provides, as yet another aspect, a method for producing a nonwoven fabric for an absorbent article, Producing a first fibrous web comprising a first core-sheath composite fiber; Producing a second fibrous web comprising a second core-sheath composite fiber and cotton; Superimposing and integrating the first fiber web and the second fiber web,
  • a method for producing a nonwoven fabric for absorbent articles comprising: The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2), The ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene
  • the present invention provides, as a preferred aspect, a nonwoven fabric for an absorbent article, A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2)
  • the fineness (F1) of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less
  • the fineness (F2) of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less.
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
  • the heat of fusion ⁇ H of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath type composite fiber is 130 J / g or more.
  • the present invention provides, as another preferred aspect, a nonwoven fabric for an absorbent article, A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2)
  • the fineness (F1) of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less
  • the fineness (F2) of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less.
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention has a good feel and can reduce fluffing and tearing of the nonwoven fabric.
  • Nonwoven fabric for absorbent articles of one embodiment of the present invention A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber
  • the difference between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.1 dtex or more and 1.5 dtex or less, and at least one of the following (i) and (ii): Meet.
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ⁇ H of the sheath component of the first sheath-core composite fiber is 130 J / g.
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
  • the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
  • the nonwoven fabric for absorbent articles of a further embodiment of the present invention includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness of the first sheath-core composite fiber is the second core.
  • the ratio of the fineness of the first core-sheath composite fiber to the fineness of the second core-sheath composite fiber is 0.55 or more, which is smaller than the fineness of the sheath-type composite fiber, and smaller than 1 and the following (i) ) And (ii).
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ⁇ H of the sheath component of the first sheath-core composite fiber is 130 J / g.
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
  • the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
  • the method for producing a nonwoven fabric for an absorbent article includes: Producing a first fibrous web comprising a first core-sheath composite fiber, producing a second fibrous web comprising a second core-sheath composite fiber and cotton, the first fibrous web and the second fibrous web And a method of producing a nonwoven fabric for an absorbent article, wherein the fineness of the first core-sheath composite fiber is smaller than the fineness of the second core-sheath composite fiber, The difference between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 0.1 dtex or more and 1.5 dtex or less, and satisfies at least one of the following (i) and (ii): .
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ⁇ H of the sheath component of the first sheath-core composite fiber is 130 J / g.
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
  • the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
  • a method for producing a nonwoven fabric for an absorbent article Producing a first fibrous web comprising a first core-sheath composite fiber, producing a second fibrous web comprising a second core-sheath composite fiber and cotton, the first fibrous web and the second fibrous web And a method of producing a nonwoven fabric for an absorbent article, wherein the fineness of the first core-sheath composite fiber is smaller than the fineness of the second core-sheath composite fiber, The ratio of the fineness of the first core-sheath composite fiber to the fineness of the second core-sheath composite fiber is 0.55 or more, smaller than 1, and satisfies at least one of the following (i) and (ii): .
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ⁇ H of the sheath component of the first sheath-core composite fiber is 130 J / g.
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
  • the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
  • Nonwoven fabric for absorbent articles of a preferred embodiment of the present invention A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
  • the first fiber layer includes a first sheath-core composite fiber
  • the second fiber layer includes a second sheath-core composite fiber and cotton
  • the fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber
  • the fineness of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less
  • the fineness of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less, At least one of the following (i) and (ii) is satisfied.
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ⁇ H of the sheath component of the first sheath-core composite fiber is 130 J / g.
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
  • the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention is a nonwoven fabric including a first fiber layer and a second fiber layer located on one main surface of the first fiber layer.
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention is a topsheet constituting the absorbent article, wherein the first fiber layer is on the side (outside) opposite to the skin side of the user, and is worn by the user. It can be suitably used as a sheet (also referred to as a back sheet) located on the side.
  • the first fiber layer ensures the smoothness of the nonwoven fabric
  • the second fiber layer ensures the softness, cushioning property and bulkiness of the nonwoven fabric
  • the first fiber layer includes a first sheath-core composite fiber.
  • the first fiber layer preferably contains the first core-sheath type conjugate fiber in an amount of 50% by mass or more, more preferably 70% by mass or more, with the mass of the first fiber layer being 100% by mass, and more preferably 100% by mass. % Is even more preferred.
  • the first fiber layer may include fibers other than the first core-sheath composite fiber.
  • the other fibers may be, for example, synthetic fibers other than the core-sheath type composite fiber.
  • the first fiber layer may not include cotton.
  • the second fiber layer includes a second core-sheath composite fiber and cotton.
  • the second fiber layer contains the second core-sheath type composite fiber in an amount of 70% by mass or more and 99% by mass or less and 1% by mass or more and 30% by mass or less of cotton, with the mass of the second fiber layer being 100% by mass. More preferably, the second core / sheath composite fiber is contained in an amount of 75% by mass or more and 98% by mass or less, and the cotton is more preferably contained in a content of 2% by mass or more and 25% by mass or less. % To 95% by mass, and even more preferably 5 to 15% by mass of cotton.
  • the second fiber layer contains the second core-sheath type composite fiber in an amount of 70% by mass or more and 99% by mass or less and 1% by mass or more and 30% by mass or less of cotton, with the mass of the second fiber layer being 100% by mass.
  • the nonwoven fabric has an excellent effect of having a soft touch.
  • the second fiber layer may include fibers other than the second core-sheath composite fiber and cotton.
  • the other fibers may be, for example, synthetic fibers other than the core-sheath type composite fiber.
  • the cotton contained in the second fiber layer is not particularly limited as long as the nonwoven fabric targeted by the present invention can be obtained.
  • the cotton for example, upland cotton, barbadense cotton, desi cotton and the like can be exemplified.
  • the fineness of the cotton is not particularly limited, and may be, for example, 0.6 dtex or more and 5.6 dtex or less, particularly 1.4 dtex or more and 4.4 dtex or less, and more particularly 1.7 dtex or more and 3.3 dtex or less. When the fineness of the cotton is in this range, the nep does not become too large, and a smooth feel can be obtained.
  • the fineness of cotton can be calculated according to a method using JIS L 1019 7.4.1 micronail (the same applies to the following).
  • the fiber length of the cotton is not particularly limited, and may be appropriately selected according to the method of producing the nonwoven fabric.
  • the average fiber length of the cotton may be, for example, 15 mm or more and 100 mm or less, particularly 20 mm or more and 70 mm or less.
  • Plant-derived natural fibers such as cotton are generally supplied in a form in which the fiber length is not constant, but such forms may be used in the present embodiment.
  • the second fiber layer preferably contains the cotton in a ratio of 1% by mass or more and 30% by mass or less, based on the total mass of the second fiber layer, and more preferably contains 2% by mass or more and 25% by mass or less. More preferably, the content is 5% by mass or more and 15% by mass or less.
  • the nonwoven fabric has an excellent effect of having a soft touch.
  • the fineness (F1) of the first core-sheath composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 ⁇ F2).
  • the fineness (F1) of the first core-sheath composite fiber is 1.0 dtex or more and 2.9 dtex or less on the assumption that the fineness (F2) of the second core-sheath composite fiber is smaller (F1 ⁇ F2). It is preferably from 1.0 dtex to 2.4 dtex, more preferably from 1.0 dtex to 2.0 dtex, even more preferably from 1.2 dtex to 1.9 dtex. It is even more preferred that the number be 4 dtex or more and 1.8 dtex or less.
  • the fineness means a mass average value.
  • the fineness similarly means a mass average value.
  • the first core-sheath type composite fiber is a cotton blend containing two or more kinds of core-sheath type composite fibers
  • each fineness is included in the above numerical range
  • the second core-sheath type composite fiber is In the case of a cotton blend containing two or more kinds of core-sheath type composite fibers, it is preferable that each fineness is included in the above numerical range.
  • the ratio of the fineness (F1) of the first sheath-core composite fiber to the fineness (F2) of the second sheath-core composite fiber (the fineness of the first sheath-core composite fiber / the fineness of the second sheath-core composite fiber) ) (F1 / F2) is smaller than 1 and preferably 0.95 or less, more preferably 0.38 or more and 0.93 or less, and more preferably 0.40 or more and 0.93 or less. More preferably, it is 0.55 or more and 0.92 or less, and even more preferably 0.70 or more and 0.90 or less.
  • the fibers constituting the second fiber layer When the ratio (F1 / F2) between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is smaller than 1 and 0.55 or more, the fibers constituting the second fiber layer And the number of places where the fibers constituting the first fiber layer adhere to the fibers constituting the second fiber layer does not decrease, thereby providing an advantageous effect that the nonwoven fabric is less likely to fluff or break.
  • the nonwoven fabric has a soft and smooth touch when it is not less than 0.55 and not more than 0.92.
  • the fineness of the first core-sheath composite fiber is 1.0 dtex or more and 2.9 dtex or less. It is preferable that the fineness of the second core-sheath composite fiber is 1.7 dtex or more and 4.4 dtex or less, and the nonwoven fabric can have a soft and smooth tactile sensation.
  • the fineness of the fiber is 1.0 dtex or more and 2.0 dtex or less, and the fineness of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less, the nonwoven fabric has a soft and smooth touch. Has the effect.
  • the fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber
  • the fineness of the first sheath-core composite fiber and the fineness of the second sheath-core composite fiber is preferably 0.1 dtex or more and 1.5 dtex or less, and is 0.2 dtex or more and 1.2 dtex or less. It is more preferably 0.3 dtex or more and 1.0 dtex or less.
  • the difference between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.1 dtex or more and 1.5 dtex or less, the number of fibers constituting the second fiber layer is small.
  • the advantageous effect that the nonwoven fabric is less likely to be fluffed or torn can be obtained. .
  • the basis weight of the first fiber layer is preferably smaller than the basis weight of the second fiber layer.
  • the basis weight of the first fiber layer 5 g / preferably m is 2 or more 20 g / m 2 or less, more preferably 7 g / m 2 or more 18 g / m 2 or less, 8 g / m 2 or more 15 g / m Even more preferably, it is 2 or less.
  • the basis weight of the second fiber layer, 7 g / preferably m is 2 or more 25 g / m 2 or less, more preferably 9 g / m 2 or more 23 g / m 2 or less, 10 g / m 2 or more 20 g / m Even more preferably, it is 2 or less.
  • the ratio of the basis weight of the first fiber layer to the basis weight of the second fiber layer is smaller than 1, preferably 0.95 or less, and 0.20 or less. It is more preferably not less than 0.90 and not more than 0.40, and still more preferably not less than 0.45 and not more than 0.80.
  • the basis weight of the first fiber layer is 5 g / m 2 or more and 20 g / m 2 or less
  • the basis weight of the second fiber layer is 7 g / m 2 or more and 25 g / m 2 or less
  • the nonwoven fabric has a soft touch. It has an excellent effect of having.
  • the first core-sheath conjugate fiber is a so-called concentric core-sheath conjugate fiber (also referred to as a concentric core-sheath conjugate fiber) in which two different resin components constituting the conjugate fiber are concentrically arranged.
  • a so-called eccentric core-sheath type conjugate fiber in which the center of gravity of the core component in the fiber cross section is different from the center of gravity of the entire conjugate fiber may be used. More preferably, it is a concentric core-sheath type composite fiber. It is presumed that the concentric core-sheath type composite fiber has more intersection points between the fibers than the eccentric core-sheath type composite fiber, and thus it is easy to suppress fluffing and tearing of the nonwoven fabric.
  • the first core-sheath conjugate fiber preferably contains 50% by mass or more, more preferably 70% by mass or more, of the concentric core-sheath conjugate fiber. Particularly preferred are conjugate fibers.
  • the first core-sheath type conjugate fiber contains 50% by mass or more of the concentric core-sheath type conjugate fiber, the thickness of the nonwoven fabric can be suppressed, and the nonwoven fabric has an excellent effect of having a smooth touch.
  • the core component of the first core-sheath type conjugate fiber is not particularly limited as long as the nonwoven fabric targeted by the present invention can be obtained.
  • polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate Polyester resins such as polylactic acid, polyolefin resins such as polypropylene and polymethylpentene, polyamide resins such as nylon 66, nylon 12, and nylon 6, acrylic resins, and polycarbonate, polyacetal, polystyrene, and cyclic polyolefin.
  • the core component of the first core-sheath composite fiber contains at least 50% by mass of at least one resin selected from a polyester resin and a polyolefin resin, the card processability of the first core-sheath composite fiber is reduced. It has an excellent effect of being good.
  • the core component may contain other components such as other resins and various additives usually added to the resin constituting the core component, as long as the nonwoven fabric targeted by the present invention can be obtained.
  • the sheath component of the first core-sheath type composite fiber contains polyethylene.
  • the polyethylene contained in the sheath component is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained. Examples thereof include polyethylene, medium-density polyethylene, low-density polyethylene, and linear low-density polyethylene, and it is preferably at least one selected from high-density polyethylene and medium-density polyethylene.
  • the polyethylene is at least one selected from high-density polyethylene and medium-density polyethylene
  • the first core-sheath type conjugate fiber has an excellent effect in that the card processability is good.
  • the polyethylene is at least one selected from high-density polyethylene and medium-density polyethylene
  • an excellent effect that fluff and tear of the nonwoven fabric can be reduced can be achieved.
  • High-density polyethylene and medium-density polyethylene are assumed to be able to reduce the fluff and tear of the non-woven fabric because the resin is harder than the low-density polyethylene and linear low-density polyethylene, so that the adhesive force between the fibers increases. Is done.
  • the sheath component may contain other components such as other resins and various additives usually added to polyethylene as long as the sheath component is 100% by mass and the polyethylene is 50% by mass or more.
  • the sheath component may contain polyethylene by 70% by mass or more, 80% by mass or more, 90% by mass or more, or 95% by mass or more, with the whole sheath component being 100% by mass.
  • the sheath component may be substantially polyethylene.
  • the heat of fusion ⁇ H of the sheath component of the first core-sheath composite fiber is 130 J / g or more
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more
  • the heat of fusion ⁇ H of the sheath component of the first core-sheath composite fiber is 140 J / g or more and 270 J / g or less
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 140 J / g or more and 270 J / g.
  • the following is more preferable.
  • the heat of fusion ⁇ H of the sheath component of the first core-sheath composite fiber is 150 J / g or more and 220 J / g or less
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 150 J / g or more and 220 J / g. It is even more preferred that:
  • the heat of fusion ⁇ H of the sheath component of the first core-sheath composite fiber is 130 J / g or more and the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more
  • the nonwoven fabric is fluffed.
  • the sheath component which requires a large amount of energy for melting, has a high adhesive strength, so that fluffing of the nonwoven fabric and tearing of the nonwoven fabric can be suppressed.
  • the heat of fusion ⁇ H of the sheath component of the conjugate fiber can be measured and obtained by the method described in Examples.
  • the difference between the heat of fusion ⁇ H of the sheath component of the first core-sheath composite fiber and the heat of fusion ⁇ H of the sheath component of the second sheath-core composite fiber is preferably 80 J / g or less in absolute value, and 50 J / g or less. Is more preferable, and it is more preferable that it is 30 J / g or less.
  • the melt flow rate of the sheath component of the first core-sheath composite fiber is preferably 15 g / 10 min or more, more preferably 16 g / 10 min or more and 30 g / 10 min or less, and 18 g / 10 min or more and 25 g. It is even more preferable that the time is / 10 minutes or less.
  • the melt flow rate of the sheath component of the first core-sheath type composite fiber is 15 g / 10 minutes or more, an excellent effect of suppressing fluffing of the nonwoven fabric and tearing of the nonwoven fabric is exhibited.
  • the melt flow rate is measured by the method described in the examples.
  • the core / sheath ratio (core / shell component mass ratio) of the core / sheath component of the first core / sheath type composite fiber is preferably 20/80 to 80/20, and 30/70 to 70/70.
  • the ratio is more preferably 30, more preferably 40/60 to 60/40, and particularly preferably 40/60 to 55/45.
  • the core / sheath ratio (core component / sheath component mass ratio) between the core component and the sheath component of the first core / sheath conjugate fiber is 20/80 to 80/20.
  • the average fiber length of the first core-sheath type composite fiber is preferably 20 mm or more and 110 mm or less, more preferably 30 mm or more and 70 mm or less, and even more preferably 35 mm or more and 55 mm or less.
  • the average fiber length of the first core-in-sheath type conjugate fiber is 20 mm or more and 110 mm or less, an excellent effect that the card processability of the first core-in-sheath type conjugate fiber is good is exhibited.
  • the second core-sheath composite fiber is a so-called concentric core-sheath composite fiber (also referred to as a concentric core-sheath composite fiber) in which two different resin components constituting the composite fiber are concentrically arranged.
  • a so-called eccentric core-sheath type conjugate fiber in which the center of gravity of the core component in the fiber cross section is different from the center of gravity of the entire conjugate fiber may be used. More preferably, it is a concentric core-sheath type composite fiber.
  • the concentric core-sheath type composite fiber has more intersections between the fibers than the eccentric core-sheath type composite fiber, so that the number of bonding points with the fibers constituting the first fiber layer increases, so that it is easy to suppress fluffing and tearing of the nonwoven fabric. You.
  • the second core-sheath conjugate fiber preferably contains 50% by mass or more, more preferably 70% by mass or more, of the concentric core-sheath conjugate fiber. Particularly preferred are conjugate fibers.
  • the second core-sheath type conjugate fiber contains 50% by mass or more of the concentric core-sheath type conjugate fiber, the thickness of the nonwoven fabric can be suppressed, and the nonwoven fabric has an excellent effect of having a smooth touch.
  • the core component of the second core-sheath type conjugate fiber is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained.
  • Polyester resins such as polylactic acid, polyolefin resins such as polypropylene and polymethylpentene, polyamide resins such as nylon 66, nylon 12, and nylon 6, acrylic resins, and polycarbonate, polyacetal, polystyrene, and cyclic polyolefin.
  • the resin preferably contains at least one resin selected from engineering plastics in an amount of 50% by mass or more, more preferably contains a polyester-based resin in an amount of 50% by mass or more, and contains polyethylene terephthalate in an amount of 50% by mass. It is even more preferred, including percent.
  • the core component of the second core-sheath composite fiber contains at least 50% by mass of at least one resin selected from a polyester resin and a polyolefin resin, the card processability of the second core-sheath composite fiber is reduced. It has an excellent effect of being good.
  • the second core-sheath type composite fiber has a sheath component containing polyethylene.
  • the polyethylene contained in the sheath component is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained. Examples thereof include polyethylene resin, medium-density polyethylene, low-density polyethylene, linear low-density polyethylene, and the like, and it is preferably at least one selected from high-density polyethylene and medium-density polyethylene.
  • the polyethylene is at least one selected from high-density polyethylene and medium-density polyethylene, an excellent effect is obtained in that the cardability of the second core-sheath composite fiber is good.
  • the melt flow rate of the sheath component of the second core-sheath type composite fiber is preferably 10 g / 10 min or more, more preferably 15 g / 10 min or more and 30 g / 10 min or less, and 17 g / 10 min or more and 25 g. It is even more preferable that the time is / 10 minutes or less.
  • the melt flow rate of the sheath component of the second core-sheath composite fiber is 10 g / 10 minutes or more, an excellent effect of suppressing fluffing of the nonwoven fabric and tearing of the nonwoven fabric can be achieved.
  • the melt flow rate is measured by the method described in the examples.
  • the core-to-sheath ratio (core component / sheath component ⁇ mass ratio) between the core component and the sheath component is preferably 20/80 to 80/20, and 30/70 to 70/30. Is more preferable, and even more preferably 40/60 to 60/40.
  • the core-sheath ratio (core component / sheath component ⁇ mass ratio) of the core component and the sheath component is 20/80 to 80/20, the card processability of the second core-sheath type composite fiber and the suppression of fluffing of the nonwoven fabric are improved. An excellent effect that both can be achieved is exhibited.
  • the average fiber length of the second core-sheath type composite fiber is preferably 20 mm or more and 110 mm or less, more preferably 30 mm or more and 70 mm or less, and even more preferably 35 mm or more and 55 mm or less.
  • the average fiber length of the second core-sheath type composite fiber is 20 mm or more and 110 mm or less, an excellent effect that the card processability of the second core-sheath type composite fiber is good is exhibited.
  • the combination of the resin contained in the core component and the resin contained in the sheath component of the first core-sheath type composite fiber and the second core-sheath type composite fiber may be the same or different.
  • the first fiber layer and the second fiber layer used in the present invention can be manufactured by using various methods for manufacturing a fiber web.
  • the production method is not particularly limited as long as the nonwoven fabric for an absorbent article intended by the present invention can be obtained.
  • a card method such as a parallel web, a cross web, a Chris cross web, a semi-random web and a random web, an air lay method, and the like can be exemplified.
  • the fiber web is preferably a card web.
  • the first fiber layer and the second fiber layer may be different types of fibrous webs.
  • the present invention provides a method for producing a nonwoven fabric for an absorbent article of the embodiment of the present disclosure, Producing a first fibrous web comprising a first core-sheath composite fiber; Producing a second fibrous web comprising a second core-sheath composite fiber and cotton; Superimposing and integrating the first fiber web and the second fiber web, including.
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention can be manufactured by laminating and integrating a first fiber web serving as a first fiber layer and a second fiber web serving as a second fiber layer.
  • the production method is not particularly limited as long as the nonwoven fabric for an absorbent article intended by the present invention can be obtained. Therefore, in order to integrate the first fiber web and the second fiber web, the first fiber web and the second fiber web are overlapped and entangled, for example, a needle punching process or a water entanglement process is performed so that the two fiber webs are entangled.
  • An integrated nonwoven fabric may be used, but it is preferable that the first fibrous web and the second fibrous web are overlapped and bonded to form an integrated nonwoven fabric.
  • a heat-bonded nonwoven fabric in which the first fiber web and the second fiber web are bonded by a thermal bonding method in which heat treatment is performed also referred to as a thermal bond nonwoven fabric in some documents.
  • the heat-bonded non-woven fabric has remarkable effects such as flexibility in the thickness direction, bulk recovery, and smooth texture of the non-woven fabric surface.
  • the method of heat treatment that is, the method of thermal bonding can be performed by a known method, for example, an air through method (hot air penetration heat treatment method), a hot air blowing heat treatment method, a heat roll method, an infrared heat treatment method, and the like.
  • a heat treatment machine in which pressure such as wind pressure is not applied much to the fiber web is preferably used, and an air-through method (hot air penetration heat treatment method) is more preferable.
  • the heat treatment conditions such as the heat treatment temperature are selected and performed, for example, such that the sheath component is sufficiently melted and / or softened and the fibers are joined at the contact points or intersections.
  • the heat treatment temperature is equal to or higher than Tm (Tm + 50 ° C.) when the melting point of the thermoplastic resin having the lowest melting point among the thermoplastic resins constituting the synthetic fibers contained in the first fiber web and the second fiber web is Tm (° C.).
  • the heat treatment is preferably performed in the range of (° C) or less, more preferably in the range of (Tm + 3 ° C) or more and (Tm + 40 ° C) or less, and performed in the range of (Tm + 5 ° C) or more and (Tm + 30 ° C) or less. Is particularly preferred.
  • the hot air penetration type heat treatment method is not particularly limited, and can be performed by a known method.
  • a transport support for example, a conveyor belt
  • the first fibrous web is placed so as to be in contact with a transport support (for example, a conveyor belt) of a heat treatment machine, and is heat-treated by blowing hot air at a predetermined temperature from the second fibrous web.
  • the first fiber web serving as the first fiber layer is in contact with the supporting carrier during the heat treatment, and hot air is blown from the second fiber web side serving as the second fiber layer, The first fibrous web is pressed against the support during the heat treatment, resulting in a smoother surface. Therefore, a smoother feel is imparted to the surface of the nonwoven fabric.
  • the nonwoven fabric for absorbent articles of the embodiment of the present invention may further have, if necessary, an additional layer usually included in the nonwoven fabric.
  • the fibers of the first fiber layer and the second fiber layer may be entangled and integrated, but the fibers are bonded and integrated. It is more preferable that the fibers are integrated by thermal bonding.
  • the first fiber layer and the second fiber layer are bonded and integrated by the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber.
  • the fibers are preferably bonded to each other by a sheath component of a first core-sheath composite fiber, and the second fiber layer is bonded to each other by a sheath component of a second core-sheath composite fiber. Is preferred.
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention may be subjected to additional processing such as embossing, if necessary, and may have such additional forms and shapes.
  • the basis weight of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but it is 12 g / m 2 or more and 45 g / m 2 or less. Is preferably 16 g / m 2 or more and 41 g / m 2 or less, and more preferably 18 g / m 2 or more and 35 g / m 2 or less. When the basis weight of the nonwoven fabric is 12 g / m 2 or more and 45 g / m 2 or less, an excellent effect that the thickness of the nonwoven fabric is in an appropriate range is exhibited.
  • the thickness of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric targeted by the present invention can be obtained, but may be 0.20 mm or more and 3.0 mm or less. More preferably, it is 0.30 mm or more and 1.5 mm or less, and even more preferably 0.40 mm or more and 1.0 mm or less. When the thickness of the nonwoven fabric is 0.20 mm or more and 3.0 mm or less, the nonwoven fabric has an excellent effect of having a soft touch.
  • the specific volume of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is 5 cm 3 / g or more and 150 cm 3 / g or less. It is more preferably 7 cm 3 / g or more and 130 cm 3 / g or less, and still more preferably 10 cm 3 / g or more and 100 cm 3 / g or less.
  • the specific volume of the nonwoven fabric is 5 cm 3 / g or more and 150 cm 3 / g or less, the nonwoven fabric has an excellent effect of having a soft touch.
  • the tensile strength (CD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is not less than 1 N / 5 cm and not more than 17 N / 5 cm. Is preferable, and it is more preferable that it is 2 N / 5 cm or more and 15 N / 5 cm or less, and it is even more preferable that it is 3 N / 5 cm or more and 12 N / 5 cm or less.
  • the tensile strength (CD) of the nonwoven fabric is 1 N / 5 cm or more and 15 N / 5 cm or less, there is an excellent effect that the nonwoven fabric has good workability when producing an absorbent article.
  • the elongation (MD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is 10% or more and 70% or less. Is preferably 15% or more and 60% or less, and more preferably 20% or more and 50% or less.
  • the elongation (MD) of the nonwoven fabric is 10% or more and 70% or less, an excellent effect that the workability of the nonwoven fabric at the time of manufacturing an absorbent article is good is exhibited.
  • the elongation (CD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained. Is preferably 60% or more and 140% or less, and more preferably 70% or more and 130% or less. When the elongation (CD) of the nonwoven fabric is 50% or more and 150% or less, there is an excellent effect that workability of the nonwoven fabric at the time of manufacturing an absorbent article is good.
  • the stress at 10% elongation (MD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is, for example, 2N / 5cm to 25N. / 5 cm or less, preferably 3 N / 5 cm or more and 25 N / 5 cm or less, more preferably 5 N / 5 cm or more and 20 N / 5 cm or less, and more preferably 6 N / 5 cm or more and 15 N / 5 cm or less. Even more preferred.
  • the 10% elongation stress (MD) of the nonwoven fabric is 2 N / 5 cm or more and 25 N / 5 cm or less, an excellent effect that the workability of the nonwoven fabric at the time of manufacturing an absorbent article is good is exhibited.
  • the stiffness (MD direction) of the nonwoven fabric of the embodiment of the present invention is preferably 40 cN or less, more preferably 30 cN or less, still more preferably 10.0 cN or less, and more preferably 7 cN or less. Is even more preferably 5 cN or less.
  • the rigidity (MD direction) of the nonwoven fabric is 40 cN or less, the nonwoven fabric has an excellent effect of having a soft touch.
  • the stiffness (CD direction) of the nonwoven fabric of the embodiment of the present invention is preferably 70 cN or less, more preferably 60 cN or less, still more preferably 20.0 cN or less, and more preferably 15 cN or less. Is still more preferred, and particularly preferably 12 cN or less.
  • the rigidity (CD direction) of the nonwoven fabric is 70 cN or less, the nonwoven fabric has an excellent effect of having a soft touch.
  • the stiffness (nonwoven fabric) of the nonwoven fabric of the embodiment of the present invention is preferably 110 cN or less, more preferably 90 cN or less, still more preferably 16.0 cN or less, and more preferably 15.0 cN or less. It is even more preferred that it is less than or equal to 14.0 cN, even more preferably 13.0 cN or less.
  • the rigidity of the nonwoven fabric is 110 cN or less, the nonwoven fabric has an excellent effect of having a soft touch.
  • the nonwoven fabric of the embodiment of the present invention preferably has a fuzz of 30 or less, more preferably 20 or less, and even more preferably 15 or less.
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention can be used for various absorbent articles such as disposable diapers, sanitary napkins, incontinence pads and panty liners. Since the nonwoven fabric for an absorbent article of the present invention is excellent in tactile sensation, it can be used for any member as long as it is various absorbent articles.
  • the nonwoven fabric for an absorbent article of the present invention can also be used as a top sheet, side gathers, a back sheet, or a sheet of a waist portion in a pants-type disposable diaper.
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention is preferably used as a backsheet. Accordingly, the present invention provides a backsheet for an absorbent article, including the nonwoven fabric for an absorbent article of the embodiment of the present invention.
  • the present invention can provide various absorbent articles including such a nonwoven fabric for absorbent articles. It is preferable that the absorbent article according to the embodiment of the present invention includes a backsheet for an absorbent article, and the first fiber layer of the backsheet for the absorbent article be disposed on a side close to clothing of a user. Therefore, the present invention provides an absorbent article in which the first fiber layer of the backsheet for an absorbent article is disposed on the side close to the clothes of the user, and includes the backsheet for the absorbent article.
  • the nonwoven fabric for the absorbent article has the first fiber layer disposed on the clothing side.
  • the first fiber layer secures the smoothness of the nonwoven fabric
  • the second fiber layer secures the softness, cushioning property, and bulkiness of the nonwoven fabric.
  • Fiber A polyethylene terephthalate (melting point: 260 ° C.) as a core, high-density polyethylene (melting point: 132 ° C., MFR: 20 g / 10 min) as a sheath, and a composite ratio (core / sheath, mass ratio) of 50 / Concentric core-sheath type conjugate fiber having a fineness of 1.7 dtex (fiber diameter 13.8 ⁇ m) and a fiber length of 45 mm, which is 50 (trade name NBF (SH) manufactured by Daiwabo Polytech Co., Ltd.)
  • Fiber B polyethylene terephthalate (melting point: 260 ° C.) as a core, high-density polyethylene (melting point: 132 ° C., MFR: 19 g / 10 min) as a sheath, and a composite ratio (core
  • melt flow rate MFR
  • the polyethylene resin constituting the sheath component of the core-sheath type composite fiber was measured under the conditions of a measurement temperature of 190 ° C. and a load of 21.18 N based on JIS K7210-1.
  • DSC Differential scanning calorimetry
  • the temperature was increased again at a temperature increasing speed of 10 ° C./min.
  • the heat of fusion ⁇ H of the sheath component was determined from the melting peak when the temperature was raised again. If the melting peak is reached when the temperature is raised again, it is considered that the temperature is close to the heat of fusion of the sheath component after the thermal bonding during the production of the nonwoven fabric.
  • the heat of fusion ⁇ H of the sheath component refers to the heat of fusion ⁇ H per mass of the sheath component.
  • a first fiber web to be a first fiber layer was produced using a parallel card machine.
  • the target basis weight of the first fiber web was 10 g / m 2 .
  • fiber B as the second core-sheath composite fiber, 91% by mass of fiber B and 9% by mass of fiber F are mixed, and the second fiber web to be the second fiber layer is formed by using a parallel card machine.
  • the target basis weight of the second fiber web was 15 g / m 2 .
  • the obtained first fiber web and second fiber web are superimposed to produce a laminated fiber web, and the laminated fiber web is heat-treated for 12 seconds by a hot air penetration heat treatment machine set at a temperature of 135 ° C.
  • the fibers are adhered to each other by a polyethylene resin component of the first core-sheath type conjugate fiber and the second core-sheath type conjugate fiber contained in each of the first fiber web and the second fiber web, so that the first fiber layer and the second fiber layer are separated from each other.
  • the weight of the actually manufactured nonwoven fabric is not always as intended and has an error, the weight of the actually obtained nonwoven fabric is described in Table 1 for some examples and comparative examples. are doing.
  • Example 2 A nonwoven fabric of Example 2 was obtained using the same method as that described in Example 1 except that the fiber C was used as the second core-sheath type composite fiber.
  • a nonwoven fabric of Comparative Example 1 was obtained using the same method as that described in Example 1 except that the fiber D was used as the second core-sheath type composite fiber.
  • Example 2 (Production of the nonwoven fabric of Comparative Example 2)
  • a nonwoven fabric of Comparative Example 2 was obtained using 50% by mass of fiber C and 50% by mass of fiber E as the first core-sheath type composite fiber.
  • (2.0 + 3.3) /2 2.65 dtex, which is a mass average value of the fineness of the fiber C and the fineness of the fiber E, was used as the fineness of the second core-sheath composite fiber of Comparative Example 2.
  • Example 4 was repeated using the same method as described in Example 2 except that the target weight of the first fiber layer was 7 g / m 2 and the target weight of the second fiber layer was 18 g / m 2. Was obtained.
  • Example 5 (Production of nonwoven fabric of Example 5) The nonwoven fabric of Example 5 was produced using the same method as that described in Example 1 except that fiber C was used as the first core-sheath composite fiber and fiber G was used as the second core-sheath composite fiber. Got.
  • Example 6 (Production of the nonwoven fabric of Example 6) A nonwoven fabric of Example 6 was obtained using the same method as that described in Example 1 except that the fiber H was used as the second core-sheath type composite fiber.
  • Example 7 (Production of the nonwoven fabric of Example 7) A nonwoven fabric of Example 7 was obtained using the same method as that described in Example 2, except that 80% by mass of the fiber C and 20% by mass of the fiber F were mixed.
  • the nonwoven fabric of Comparative Example 3 was produced using the same method as that described in Example 1 except that fiber G was used as the first core-sheath composite fiber and fiber G was used as the second core-sheath composite fiber. Got.
  • the thickness of the nonwoven fabric was measured using a thickness measuring machine (trade name: THICKNESS GAUGE model CR-60A manufactured by Daiei Kagaku Seiki Seisaku-sho, Ltd.) with a load of 294 Pa applied to the nonwoven fabric. .
  • the specific volume was determined by calculation from the basis weight and the thickness.
  • the rigidity of the nonwoven fabric was measured according to JIS L 1096 (2010) 8.21.5 E method (handle ometer method). Specifically, it measured by the following procedures. A sample piece having a size of 20 cm ⁇ 20 cm in the MD direction ⁇ CD direction is placed on the sample table so that the measurement direction of the sample piece is perpendicular to the slot (gap width: 10 mm). Next, the blade of the penetrator adjusted so as to be lowered to 8 mm from the surface of the sample table is lowered, and when the sample piece is pushed in, 6.7 cm (1 / of the width of the sample piece) from one of the sides is obtained.
  • the resistance value against the pressing in is read at different positions (total of four positions) in the MD (vertical) direction and the CD (horizontal) direction, respectively.
  • the highest value (cN) indicated by the microammeter is read as the resistance value.
  • the sum of the maximum values of the two sides in the MD direction is obtained as the bending stiffness (cN) in the MD direction
  • the sum of the maximum values of the two sides in the CD direction is obtained as the bending stiffness (cN) in the CD direction.
  • the total value of the bending resistance in the MD direction and the bending resistance in the CD direction is defined as the bending resistance (cN) of the entire nonwoven fabric. Note that the maximum value of each side is an average value obtained by performing three measurements.
  • a friction test was performed using a Martindale fluff tester (trade name “Martindale Abrasion and Pilling Tester No. 1309” manufactured by James Heal). Two samples (140 mm in diameter and 38 mm in diameter each) were prepared for the nonwoven fabrics of Examples and Comparative Examples. A felt having a diameter of 140 mm was placed on a friction table (Abrading Table), and a sample having a diameter of 140 mm was laminated instead of the SM25 friction cloth (SM25 Abrasice Cloth), and the sample was fixed with a clamping ring (Clamp Ring).
  • sample Holder a sample having a diameter of 38 mm and polyurethane having a diameter of 38 mm were placed in a sample holder (Sample Holder), and the sample holder was placed on a table (Abrading Tables) without placing a loading weight on the sample holder.
  • the two samples were set on a tester such that the first fiber layers were in contact with each other.
  • a friction test was performed by setting the number of friction times to 100 and setting the motion to 60.5 mm Lissajous motion.
  • the two samples after the friction test were observed, the presence or absence of breakage of the nonwoven fabric was confirmed, and the number of fluff was counted.
  • Three friction tests were performed (using a total of six samples). The average value of the number of fluffs was recorded.
  • a break in the nonwoven fabric was recorded as torn if observed in one of the three tests, and torn if none was observed.
  • the first fiber layer contains the first core-sheath composite fiber
  • the second fiber layer contains the second core-sheath composite fiber and cotton
  • the fineness of the conjugate fiber is smaller than the fineness of the second sheath-core composite fiber
  • the difference between the fineness F1 of the first sheath-core composite fiber and the fineness F2 of the second sheath-core composite fiber (F2-F1) Is not less than 0.1 dtex and not more than 1.5 dtex, and satisfies at least one of the following (i) and (ii).
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ⁇ H of the sheath component of the first sheath-core composite fiber is 130 J / g.
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
  • the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene. Therefore, the nonwoven fabrics of Examples 1 to 7 exhibit a smooth and soft touch while having excellent nonwoven fabric strength. Further, the nonwoven fabrics of Examples 1 to 7 have little fuzz and tear of the nonwoven fabric.
  • the first fiber layer contains the first core-sheath type composite fiber
  • the second fiber layer contains the second core-sheath type composite fiber and cotton
  • the fineness of the sheath-type composite fiber is smaller than the fineness of the second core-sheath type composite fiber
  • the ratio (F1 / F1) between the fineness F1 of the first core-sheath type composite fiber and the fineness F2 of the second core-sheath type composite fiber F2) is 0.55 or more, smaller than 1, and satisfies at least one of the following (i) and (ii).
  • the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ⁇ H of the sheath component of the first sheath-core composite fiber is 130 J / g.
  • the heat of fusion ⁇ H of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
  • the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene. Therefore, the nonwoven fabrics of Examples 1 to 7 exhibit a smooth and soft touch while having excellent nonwoven fabric strength. Further, the nonwoven fabrics of Examples 1 to 7 have little fuzz and tear of the nonwoven fabric.
  • the heat of fusion ⁇ H of at least one of the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber is less than 130 J / g.
  • at least one of the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber is not high-density polyethylene. Therefore, the nonwoven fabric of Comparative Example 1 does not exhibit a smooth and soft touch while having excellent nonwoven fabric strength. Furthermore, the nonwoven fabric of Comparative Example 1 has many fluffs, and the nonwoven fabric is broken.
  • the nonwoven fabric of Comparative Example 2 the fineness of the first core-sheath composite fiber is not smaller than the fineness of the second core-sheath composite fiber. Therefore, the nonwoven fabric of Comparative Example 2 does not exhibit a smooth and soft touch.
  • the nonwoven fabric of Comparative Example 2 used bulky fiber (fiber E), but did not show a smooth and soft touch, and used a bulky fiber with less fuzz. As a result, the nonwoven fabric is broken.
  • the difference (F2-F1) between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 1.6 dtex.
  • the ratio (F1 / F2) of the fineness of the first core-sheath composite fiber to the fineness of the second core-sheath composite fiber is 0.52. Therefore, the nonwoven fabric of Comparative Example 4 has a lot of fluff and breaks the nonwoven fabric.
  • Examples 2 and 4 were slightly superior to Example 3 in softness of the nonwoven fabric. In Examples 2 and 4, since the basis weight of the first fiber layer is smaller than the basis weight of the second fiber layer, it is assumed that the softness of the nonwoven fabric is improved.
  • the nonwoven fabric for an absorbent article according to the embodiment of the present invention has a good tactile sensation, can reduce fluff and tear of the nonwoven fabric, and can be suitably used as a back sheet.
  • Related Application claims priority based on Article 4 of the Paris Convention based on Japanese Patent Application No. 2018-122291 filed on June 27, 2018 in Japan. The contents of this basic application are incorporated herein by reference.

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Abstract

A nonwoven fabric for absorbent articles, which comprises a first fiber layer and a second fiber layer that is positioned on one main surface of the first fiber layer, and which is configured such that: the first fiber layer contains first sheath-core type composite fibers; the second fiber layer contains second sheath-core type composite fibers and cotton; the fineness (F1) of the first sheath-core type composite fibers is lower than the fineness (F2) of the second sheath-core type composite fibers; the value of (F2 - F1) is from 0.1 dtex to 1.5 dtex (inclusive); and the requirements described below are satisfied. (i) The sheath component of the first sheath-core type composite fibers and the sheath component of the second sheath-core type composite fibers contain a polyethylene; the heat of fusion ∆H of the sheath component of the first sheath-core type composite fibers is 130 J/g or more; and the heat of fusion ∆H of the sheath component of the second sheath-core type composite fibers is 130 J/g or more.

Description

吸収性物品用不織布、吸収性物品用バックシート及び吸収性物品、並びに吸収性物品用不織布の製造方法Nonwoven fabric for absorbent article, backsheet and absorbent article for absorbent article, and method for producing nonwoven fabric for absorbent article
 本発明は、吸収性物品用不織布、吸収性物品用バックシート及び吸収性物品、並びに吸収性物品用不織布の製造方法に関する。 The present invention relates to a nonwoven fabric for an absorbent article, a backsheet and an absorbent article for an absorbent article, and a method for producing a nonwoven fabric for an absorbent article.
 使い捨ておむつ、生理用ナプキン、失禁パッド及びパンティライナー等の吸収性物品は、吸収体の他に、使用者の肌側に位置するシート(文献によっては「トップシート」とも称される)、使用者の肌側と反対側(外側)であって、使用者の着衣側に位置するシート(文献によっては「バックシート」とも称される)等を含む。 Absorbent articles such as disposable diapers, sanitary napkins, incontinence pads, panty liners, and the like include, besides the absorber, a sheet (also referred to as a “top sheet” in some documents) located on the skin side of the user, And a sheet (also referred to as a “back sheet” in some documents) located on the side opposite to the skin side (outside) of the user and on the clothes side of the user.
 特許文献1は、バックシートには、使用者が吸収性物品と使用者の着衣との間に蒸れを感じにくいことが要求されることを開示する。
 その課題を解決するために、特許文献1は、バックシート(外装シート)として、着衣側層と肌側層の2層構造を有する積層不織布を開示する。その積層不織布の着衣側層は、PET/PE複合繊維(繊度2.8dtex、平均繊維長45mm、坪量20g/m2)でできており、肌側層は、2種類のPET/PE複合繊維(複合繊維A:繊度2.2dtex、平均繊維長45mm、複合繊維B:繊度1.7detx、平均繊維長45mm、繊維AとBの合計の坪量10g/m2)とコットン(平均約27mm、坪量3g/m2)でできている(特許文献1表1実施例1及び2参照)。
 特許文献1は、その積層不織布をバックシートとして使用して得られる使い捨ておむつは、人工尿吸収後の蒸散率が低く、濡れた状態、蒸れ等が発生しにくいことを開示する(特許文献1段落番号0105参照)。
Patent Literature 1 discloses that a back sheet is required to be hard for a user to feel stuffy between an absorbent article and a user's clothes.
In order to solve the problem, Patent Document 1 discloses a laminated nonwoven fabric having a two-layer structure of a clothing side layer and a skin side layer as a back sheet (exterior sheet). The clothing side layer of the laminated nonwoven fabric is made of PET / PE composite fiber (fineness 2.8 dtex, average fiber length 45 mm, basis weight 20 g / m 2 ), and the skin side layer is made of two types of PET / PE composite fiber ( Composite fiber A: Fineness 2.2 dtex, average fiber length 45 mm, Composite fiber B: Fineness 1.7 detx, average fiber length 45 mm, total basis weight of fibers A and B 10 g / m 2 ) and cotton (average about 27 mm, basis weight 3 g) / m 2 ) (see Table 1, Examples 1 and 2 of Patent Document 1).
Patent Document 1 discloses that a disposable diaper obtained by using the laminated nonwoven fabric as a back sheet has a low transpiration rate after absorbing artificial urine, and is unlikely to be wet or stuffy (Patent Document 1 paragraph 1). No. 0105).
特許第6093002号公報Japanese Patent No. 6090302
 バックシートには、更に、より良好な触感(滑らかさ及び柔らかさ)が求められつつ、毛羽立ちが少ないこと及び不織布の破れが少ないことも求められる。 The backsheet is also required to have less fuzz and less breakage of the non-woven fabric while being required to have a better touch (smoothness and softness).
 バックシート等の不織布がコットンを含む場合、特許文献1が開示するように、コットンは集合体として存在しやすく、コットン集合体の周囲に空隙が存在し易いので、コットン集合体の周辺は、不織布の中で強度が不足し、毛羽立ち又は不織布の破れが生じやすい部分となることが予想される。特許文献1では、コットンの周囲に空隙を意図的に存在させるので、毛羽立ち又は不織布の破れが生じやすいことが予想されるが、特許文献1は、これらの課題について、何ら言及していない。 When a nonwoven fabric such as a back sheet contains cotton, as disclosed in Patent Document 1, cotton is likely to exist as an aggregate, and voids are likely to exist around the cotton aggregate. Among them, it is expected that the strength will be insufficient, and it will be a portion where fluffing or breakage of the nonwoven fabric is likely to occur. In Patent Literature 1, since voids are intentionally provided around the cotton, it is expected that fluff or breakage of the nonwoven fabric is likely to occur. However, Patent Literature 1 does not mention these problems at all.
 一方、コットンは天然繊維であり、吸収性物品の素材として、消費者に好まれる傾向があり、またコットンは良好な触感を付与することができるので、コットンを含む吸収性物品の需要は高い。
 従って、コットンを不織布の素材として使用して、より良好な触感を得ることを試みると、上述のように集合体として存在しやすいコットンの周囲に空隙が存在し易いので、不織布の中で強度不足を生じ、毛羽立ちが生じやすく、不織布の破れが増加し得ることが予想される。
On the other hand, cotton is a natural fiber and tends to be favored by consumers as a material for absorbent articles, and cotton can provide a good tactile sensation. Therefore, the demand for absorbent articles containing cotton is high.
Therefore, if cotton is used as the material of the nonwoven fabric to try to obtain a better tactile sensation, voids are likely to exist around the cotton, which is likely to exist as an aggregate, as described above, and the strength is insufficient in the nonwoven fabric. , Fuzzing is likely to occur, and it is expected that tearing of the nonwoven fabric may increase.
 従って、本発明は、天然素材のコットンを含む不織布であって、より良好な触感(滑らかさ及び柔らかさ)を有し、かつ、毛羽立ちが少なく、不織布の破れが少ない不織布であり、これらの性質のバランスに優れる不織布を提供することを目的とする。 Accordingly, the present invention is a nonwoven fabric containing cotton as a natural material, which has a better feel (smoothness and softness), has less fuzz, and has less tearing of the nonwoven fabric. An object of the present invention is to provide a nonwoven fabric having an excellent balance between the two.
 本発明者等は、鋭意検討を重ねた結果、第1及び第2繊維層が含む第1及び第2芯鞘型複合繊維の各々の繊度を制御すること、第1及び第2芯鞘型複合繊維の鞘成分の各々のポリエチレンを制御することなどで、上述の課題を解決できる吸収性物品用不織布が得られることを見出した。更に、そのような吸収性物品用不織布はバックシート用に好適であることを見出して、本発明を完成させるに至った。 As a result of intensive studies, the present inventors have found that controlling the fineness of each of the first and second core-sheath composite fibers contained in the first and second fiber layers, the first and second core-sheath composites It has been found that a nonwoven fabric for an absorbent article which can solve the above-mentioned problems can be obtained by controlling each polyethylene of the sheath component of the fiber. Further, they have found that such a nonwoven fabric for absorbent articles is suitable for a back sheet, and have completed the present invention.
 即ち、本発明は、一の要旨として、吸収性物品用不織布を提供し、それは、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との差(F2-F1)が、0.1dtex以上、1.5dtex以下であり、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
 前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
That is, the present invention provides, as one gist, a nonwoven fabric for an absorbent article,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less,
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
The heat of fusion ΔH of the sheath component of the second core-sheath type composite fiber is 130 J / g or more.
 また、本発明は、他の要旨として、吸収性物品用不織布を提供し、それは、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との差(F2-F1)が、0.1dtex以上、1.5dtex以下であり、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
In another aspect, the present invention provides a nonwoven fabric for an absorbent article,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less,
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 更に、本発明は、更なる要旨として、吸収性物品用不織布を提供し、それは、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との比(F1/F2)が、0.55以上であり、1より小さく、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
 前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
Further, the present invention provides, as a further aspect, a nonwoven fabric for an absorbent article,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
The heat of fusion ΔH of the sheath component of the second core-sheath type composite fiber is 130 J / g or more.
 更にまた、本発明は、更に他の要旨として、吸収性物品用不織布を提供し、それは、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との比(F1/F2)が、0.55以上であり、1より小さく、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
Still further, the present invention provides, as yet another aspect, a nonwoven fabric for an absorbent article,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 また、本発明は、別の要旨として、吸収性物品用不織布の製造方法を提供し、それは、
 第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
 第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
 前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
を含む吸収性物品用不織布の製造方法であって、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との差(F2-F1)が、0.1dtex以上1.5dtex以下であり、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
 前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
In another aspect, the present invention provides a method for producing a nonwoven fabric for an absorbent article,
Producing a first fibrous web comprising a first core-sheath composite fiber;
Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
Superimposing and integrating the first fiber web and the second fiber web,
A method for producing a nonwoven fabric for absorbent articles, comprising:
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less,
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
The heat of fusion ΔH of the sheath component of the second core-sheath type composite fiber is 130 J / g or more.
 更にまた、本発明は、更に別の要旨として、吸収性物品用不織布の製造方法を提供し、それは、
 第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
 第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
 前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
を含む吸収性物品用不織布の製造方法であって、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との差(F2-F1)が、0.1dtex以上1.5dtex以下であり、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
Furthermore, the present invention provides, as yet another aspect, a method for producing a nonwoven fabric for an absorbent article,
Producing a first fibrous web comprising a first core-sheath composite fiber;
Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
Superimposing and integrating the first fiber web and the second fiber web,
A method for producing a nonwoven fabric for absorbent articles, comprising:
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The difference (F2-F1) between the fineness (F1) of the first sheath-core composite fiber and the fineness (F2) of the second sheath-core composite fiber is 0.1 dtex or more and 1.5 dtex or less,
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 また、本発明は、別の要旨として、吸収性物品用不織布の製造方法を提供し、それは、
 第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
 第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
 前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
を含む吸収性物品用不織布の製造方法であって、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との比(F1/F2)が、0.55以上であり、1より小さく、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
 前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
In another aspect, the present invention provides a method for producing a nonwoven fabric for an absorbent article,
Producing a first fibrous web comprising a first core-sheath composite fiber;
Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
Superimposing and integrating the first fiber web and the second fiber web,
A method for producing a nonwoven fabric for absorbent articles, comprising:
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
The heat of fusion ΔH of the sheath component of the second core-sheath type composite fiber is 130 J / g or more.
 更にまた、本発明は、更に別の要旨として、吸収性物品用不織布の製造方法を提供し、それは、
 第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
 第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
 前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
を含む吸収性物品用不織布の製造方法であって、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)と前記第2芯鞘型複合繊維の繊度(F2)との比(F1/F2)が、0.55以上であり、1より小さく、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
Furthermore, the present invention provides, as yet another aspect, a method for producing a nonwoven fabric for an absorbent article,
Producing a first fibrous web comprising a first core-sheath composite fiber;
Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
Superimposing and integrating the first fiber web and the second fiber web,
A method for producing a nonwoven fabric for absorbent articles, comprising:
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The ratio (F1 / F2) of the fineness (F1) of the first core-sheath type composite fiber to the fineness (F2) of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 本発明は、好ましい要旨として、吸収性物品用不織布を提供し、それは、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)が1.0dtex以上2.0dtex以下であり、かつ、前記第2芯鞘型複合繊維の繊度(F2)が1.7dtex以上2.6dtex以下であり、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
 前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
The present invention provides, as a preferred aspect, a nonwoven fabric for an absorbent article,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The fineness (F1) of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less, and the fineness (F2) of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less. Yes,
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
The heat of fusion ΔH of the sheath component of the second core-sheath type composite fiber is 130 J / g or more.
 本発明は、好ましい他の要旨として、吸収性物品用不織布を提供し、それは、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度(F1)が前記第2芯鞘型複合繊維の繊度(F2)よりも小さく(F1<F2)、
 前記第1芯鞘型複合繊維の繊度(F1)が1.0dtex以上2.0dtex以下であり、かつ、前記第2芯鞘型複合繊維の繊度(F2)が1.7dtex以上2.6dtex以下であり、
 前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
The present invention provides, as another preferred aspect, a nonwoven fabric for an absorbent article,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness (F1) of the first sheath-core composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2),
The fineness (F1) of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less, and the fineness (F2) of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less. Yes,
The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 本発明の実施形態の吸収性物品用不織布は、良好な触感を有し、かつ、毛羽立ちと不織布の破れを少なくすることができる。 不 織布 The nonwoven fabric for an absorbent article according to the embodiment of the present invention has a good feel and can reduce fluffing and tearing of the nonwoven fabric.
 本発明の一の実施形態の吸収性物品用不織布は、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
 前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差が、0.1dtex以上、1.5dtex以下であり、下記(i)及び(ii)の少なくともいずれかを満たす。
 (i)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
 (ii)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
Nonwoven fabric for absorbent articles of one embodiment of the present invention,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
The difference between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.1 dtex or more and 1.5 dtex or less, and at least one of the following (i) and (ii): Meet.
(I) The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ΔH of the sheath component of the first sheath-core composite fiber is 130 J / g. The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
(Ii) The sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 本発明の更なる実施形態の吸収性物品用不織布は、
 第1繊維層が、第1芯鞘型複合繊維を含み、第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との比が、0.55以上であり、1より小さく、下記(i)及び(ii)の少なくともいずれかを満たす。
 (i)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
 (ii)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
The nonwoven fabric for absorbent articles of a further embodiment of the present invention,
The first fiber layer includes a first sheath-core composite fiber, the second fiber layer includes a second sheath-core composite fiber and cotton, and the fineness of the first sheath-core composite fiber is the second core. The ratio of the fineness of the first core-sheath composite fiber to the fineness of the second core-sheath composite fiber is 0.55 or more, which is smaller than the fineness of the sheath-type composite fiber, and smaller than 1 and the following (i) ) And (ii).
(I) The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ΔH of the sheath component of the first sheath-core composite fiber is 130 J / g. The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
(Ii) The sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 本発明の実施形態の吸収性物品用不織布の製造方法は、
 第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、を含む吸収性物品用不織布の製造方法であって、前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差が、0.1dtex以上1.5dtex以下であり、下記(i)及び(ii)の少なくともいずれかを満たす。
 (i)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
 (ii)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
The method for producing a nonwoven fabric for an absorbent article according to the embodiment of the present invention includes:
Producing a first fibrous web comprising a first core-sheath composite fiber, producing a second fibrous web comprising a second core-sheath composite fiber and cotton, the first fibrous web and the second fibrous web And a method of producing a nonwoven fabric for an absorbent article, wherein the fineness of the first core-sheath composite fiber is smaller than the fineness of the second core-sheath composite fiber, The difference between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 0.1 dtex or more and 1.5 dtex or less, and satisfies at least one of the following (i) and (ii): .
(I) The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ΔH of the sheath component of the first sheath-core composite fiber is 130 J / g. The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
(Ii) The sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 本発明の更なる実施形態の吸収性物品用不織布の製造方法は、
 第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、を含む吸収性物品用不織布の製造方法であって、前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との比が、0.55以上であり、1より小さく、下記(i)及び(ii)の少なくともいずれかを満たす。
 (i)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
 (ii)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
A method for producing a nonwoven fabric for an absorbent article according to a further embodiment of the present invention,
Producing a first fibrous web comprising a first core-sheath composite fiber, producing a second fibrous web comprising a second core-sheath composite fiber and cotton, the first fibrous web and the second fibrous web And a method of producing a nonwoven fabric for an absorbent article, wherein the fineness of the first core-sheath composite fiber is smaller than the fineness of the second core-sheath composite fiber, The ratio of the fineness of the first core-sheath composite fiber to the fineness of the second core-sheath composite fiber is 0.55 or more, smaller than 1, and satisfies at least one of the following (i) and (ii): .
(I) The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ΔH of the sheath component of the first sheath-core composite fiber is 130 J / g. The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
(Ii) The sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 本発明の好ましい実施形態の吸収性物品用不織布は、
 第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
 前記第1繊維層が、第1芯鞘型複合繊維を含み、
 前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
 前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
 前記第1芯鞘型複合繊維の繊度が1.0dtex以上2.0dtex以下であり、かつ、前記第2芯鞘型複合繊維の繊度が1.7dtex以上2.6dtex以下であり、
 下記(i)及び(ii)の少なくともいずれかを満たす。
 (i)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
 (ii)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
Nonwoven fabric for absorbent articles of a preferred embodiment of the present invention,
A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
The first fiber layer includes a first sheath-core composite fiber,
The second fiber layer includes a second sheath-core composite fiber and cotton,
The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
The fineness of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less, and the fineness of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less,
At least one of the following (i) and (ii) is satisfied.
(I) The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ΔH of the sheath component of the first sheath-core composite fiber is 130 J / g. The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
(Ii) The sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
 本発明の実施形態の吸収性物品用不織布は、第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布である。本発明の実施形態の吸収性物品用不織布は、吸収性物品を構成する表面シートであって、第1繊維層が、使用者の肌側と反対側(外側)であって、使用者の着衣側に位置するシート(バックシートとも称される)等として、好適に使用することができる。 不 織布 The nonwoven fabric for an absorbent article according to the embodiment of the present invention is a nonwoven fabric including a first fiber layer and a second fiber layer located on one main surface of the first fiber layer. The nonwoven fabric for an absorbent article according to the embodiment of the present invention is a topsheet constituting the absorbent article, wherein the first fiber layer is on the side (outside) opposite to the skin side of the user, and is worn by the user. It can be suitably used as a sheet (also referred to as a back sheet) located on the side.
 本発明では、第1繊維層が不織布の滑らかさを確保し、第2繊維層が不織布の柔らかさ、クッション性及び嵩高性を確保する。 で は In the present invention, the first fiber layer ensures the smoothness of the nonwoven fabric, and the second fiber layer ensures the softness, cushioning property and bulkiness of the nonwoven fabric.
 前記第1繊維層は、第1芯鞘型複合繊維を含む。
 前記第1繊維層は、前記第1繊維層の質量を100質量%として、前記第1芯鞘型複合繊維を50質量%以上含むことが好ましく、70質量%以上含むことがより好ましく、100質量%含むことが更により好ましい。
 前記第1繊維層は、前記第1繊維層の質量を100質量%として、前記第1芯鞘型複合繊維を50質量%以上含む場合、不織布の毛羽立ちや不織布の破れが低減するという優れた効果を奏する。
 第1繊維層は、第1芯鞘型複合繊維以外の他の繊維が含まれていてよい。他の繊維は、例えば、芯鞘型複合繊維以外の合成繊維であってよい。
 第1繊維層は、コットンを含まなくてよい。
The first fiber layer includes a first sheath-core composite fiber.
The first fiber layer preferably contains the first core-sheath type conjugate fiber in an amount of 50% by mass or more, more preferably 70% by mass or more, with the mass of the first fiber layer being 100% by mass, and more preferably 100% by mass. % Is even more preferred.
When the first fiber layer includes the first core-sheath type composite fiber in an amount of 50% by mass or more, with the mass of the first fiber layer being 100% by mass, an excellent effect of reducing fluffing of the nonwoven fabric and tearing of the nonwoven fabric. To play.
The first fiber layer may include fibers other than the first core-sheath composite fiber. The other fibers may be, for example, synthetic fibers other than the core-sheath type composite fiber.
The first fiber layer may not include cotton.
 前記第2繊維層は、第2芯鞘型複合繊維とコットンとを含む。
 前記第2繊維層は、前記第2繊維層の質量を100質量%として、前記第2芯鞘型複合繊維を70質量%以上99質量%以下含み、コットンを1質量%以上30質量%以下含むことが好ましく、前記第2芯鞘型複合繊維を75質量%以上98質量%以下含み、コットンを2質量%以上25質量%以下含むことがより好ましく、前記第2芯鞘型複合繊維を85質量%以上95質量%以下含み、コットンを5質量%以上15質量%以下含むことが更により好ましい。
 前記第2繊維層は、前記第2繊維層の質量を100質量%として、前記第2芯鞘型複合繊維を70質量%以上99質量%以下含み、コットンを1質量%以上30質量%以下含む場合、不織布は柔らかい触感を有するという優れた効果を奏する。
 第2繊維層は、第2芯鞘型複合繊維およびコットン以外の他の繊維が含まれていてよい。他の繊維は、例えば、芯鞘型複合繊維以外の合成繊維であってよい。
The second fiber layer includes a second core-sheath composite fiber and cotton.
The second fiber layer contains the second core-sheath type composite fiber in an amount of 70% by mass or more and 99% by mass or less and 1% by mass or more and 30% by mass or less of cotton, with the mass of the second fiber layer being 100% by mass. More preferably, the second core / sheath composite fiber is contained in an amount of 75% by mass or more and 98% by mass or less, and the cotton is more preferably contained in a content of 2% by mass or more and 25% by mass or less. % To 95% by mass, and even more preferably 5 to 15% by mass of cotton.
The second fiber layer contains the second core-sheath type composite fiber in an amount of 70% by mass or more and 99% by mass or less and 1% by mass or more and 30% by mass or less of cotton, with the mass of the second fiber layer being 100% by mass. In this case, the nonwoven fabric has an excellent effect of having a soft touch.
The second fiber layer may include fibers other than the second core-sheath composite fiber and cotton. The other fibers may be, for example, synthetic fibers other than the core-sheath type composite fiber.
 前記第2繊維層に含まれるコットンは、本発明が目的とする不織布を得ることができる限り特に制限されることはない。コットンとして、例えば、アップランドコットン、バルバデンセコットン、デシ綿等を例示することができる。
 コットンの繊度は特に限定されず、例えば、0.6dtex以上5.6dtex以下、特に1.4dtex以上4.4dtex以下、より特には1.7dtex以上3.3dtex以下であってよい。コットンの繊度がこの範囲であるとネップが大きくなりすぎず、滑らかな触感を有することができる。なお、コットンの繊度は、JIS L 1019 7.4.1 マイクロネヤによる方法に準じ、算出できる(以下においても同じ)。
 コットンの繊維長は特に限定されず、不織布の製造方法等に応じて適宜選択してよい。カードウェブを作製して不織布を製造する場合、コットンの平均繊維長は例えば15mm以上100mm以下であってよく、特に20mm以上70mm以下であってよい。コットンのような植物由来の天然繊維は、一般には、繊維長が一定でない形態で供給されるが、そのような形態のものを本実施形態で使用してよい。
The cotton contained in the second fiber layer is not particularly limited as long as the nonwoven fabric targeted by the present invention can be obtained. As the cotton, for example, upland cotton, barbadense cotton, desi cotton and the like can be exemplified.
The fineness of the cotton is not particularly limited, and may be, for example, 0.6 dtex or more and 5.6 dtex or less, particularly 1.4 dtex or more and 4.4 dtex or less, and more particularly 1.7 dtex or more and 3.3 dtex or less. When the fineness of the cotton is in this range, the nep does not become too large, and a smooth feel can be obtained. In addition, the fineness of cotton can be calculated according to a method using JIS L 1019 7.4.1 micronail (the same applies to the following).
The fiber length of the cotton is not particularly limited, and may be appropriately selected according to the method of producing the nonwoven fabric. When a card web is produced to produce a nonwoven fabric, the average fiber length of the cotton may be, for example, 15 mm or more and 100 mm or less, particularly 20 mm or more and 70 mm or less. Plant-derived natural fibers such as cotton are generally supplied in a form in which the fiber length is not constant, but such forms may be used in the present embodiment.
 前記第2繊維層が、前記第2繊維層の総質量を基準として、前記コットンを1質量%以上30質量%以下の割合で含むことが好ましく、2質量%以上25質量%以下含むことがより好ましく、5質量%以上15質量%以下含むことが更により好ましい。
 前記第2繊維層が、前記第2繊維層の総質量を基準として、前記コットンを1質量%以上30質量%以下の割合で含む場合、不織布は柔らかい触感を有するという優れた効果を奏する。
The second fiber layer preferably contains the cotton in a ratio of 1% by mass or more and 30% by mass or less, based on the total mass of the second fiber layer, and more preferably contains 2% by mass or more and 25% by mass or less. More preferably, the content is 5% by mass or more and 15% by mass or less.
When the second fiber layer contains the cotton at a ratio of 1% by mass or more and 30% by mass or less based on the total mass of the second fiber layer, the nonwoven fabric has an excellent effect of having a soft touch.
 前記第1芯鞘型複合繊維の繊度(F1)は、前記第2芯鞘型複合繊維の繊度(F2)よりも小さい(F1<F2)。
 前記第1芯鞘型複合繊維の繊度(F1)は、前記第2芯鞘型複合繊維の繊度(F2)より小さいこと(F1<F2)を前提として、1.0dtex以上2.9dtex以下であることが好ましく、1.0dtex以上2.4dtex以下であることが好ましく、1.0dtex以上2.0dtex以下であることが好ましく、1.2dtex以上1.9dtex以下であることが更により好ましく、1.4dtex以上1.8dtex以下であることが更により好ましい。
 前記第2芯鞘型複合繊維の繊度(F2)は、前記第1芯鞘型複合繊維の繊度(F1)より大きいこと(F1<F2)を前提として、1.7dtex以上4.4dtex以下であることが好ましく、1.7dtex以上3.5dtex以下であることが好ましく、1.7dtex以上2.6dtex以下であることが好ましく、1.8dtex以上2.5dtex以下であることがより好ましく、1.9dtex以上2.4dtex以下であることが更により好ましい。
The fineness (F1) of the first core-sheath composite fiber is smaller than the fineness (F2) of the second sheath-core composite fiber (F1 <F2).
The fineness (F1) of the first core-sheath composite fiber is 1.0 dtex or more and 2.9 dtex or less on the assumption that the fineness (F2) of the second core-sheath composite fiber is smaller (F1 <F2). It is preferably from 1.0 dtex to 2.4 dtex, more preferably from 1.0 dtex to 2.0 dtex, even more preferably from 1.2 dtex to 1.9 dtex. It is even more preferred that the number be 4 dtex or more and 1.8 dtex or less.
The fineness (F2) of the second core-sheath type composite fiber is 1.7 dtex or more and 4.4 dtex or less on the assumption that the fineness (F1) of the first core-sheath type composite fiber is larger (F1 <F2). It is preferably 1.7 dtex or more and 3.5 dtex or less, preferably 1.7 dtex or more and 2.6 dtex or less, more preferably 1.8 dtex or more and 2.5 dtex or less, and 1.9 dtex. It is even more preferable that the number be 2.4 dtex or less.
 本明細書において、第1芯鞘型複合繊維が2種類以上の芯鞘型複合繊維を含む混綿の場合、その繊度は質量平均値を意味する。第2芯鞘型複合繊維が同様に2種類以上の芯鞘型複合繊維を含む混綿の場合、その繊度は同様に質量平均値を意味する。また、第1芯鞘型複合繊維が2種類以上の芯鞘型複合繊維を含む混綿の場合、各々の繊度がいずれも上述した数値範囲に含まれることが好ましく、第2芯鞘型複合繊維が2種類以上の芯鞘型複合繊維を含む混綿の場合、各々の繊度がいずれも上述した数値範囲に含まれることが好ましい。 に お い て In the present specification, in the case where the first core-sheath conjugate fiber is a cotton blend containing two or more kinds of core-sheath conjugate fibers, the fineness means a mass average value. In the case where the second core-sheath type composite fiber is a cotton blend containing two or more kinds of core-sheath type composite fibers, the fineness similarly means a mass average value. Further, when the first core-sheath type composite fiber is a cotton blend containing two or more kinds of core-sheath type composite fibers, it is preferable that each fineness is included in the above numerical range, and the second core-sheath type composite fiber is In the case of a cotton blend containing two or more kinds of core-sheath type composite fibers, it is preferable that each fineness is included in the above numerical range.
 また、第1芯鞘型複合繊維の繊度(F1)と第2芯鞘型複合繊維の繊度(F2)との比(第1芯鞘型複合繊維の繊度/第2芯鞘型複合繊維の繊度)(F1/F2)は、1より小さく、0.95以下であることが好ましく、0.38以上0.93以下であることがより好ましく、0.40以上0.93以下であることがより好ましく、0.55以上0.92以下であることが更に好ましく、0.70以上0.90以下であることが更により好ましい。前記第1芯鞘型複合繊維の繊度と第2芯鞘型複合繊維の繊度との比(F1/F2)は、1より小さく、0.55以上である場合、第2繊維層を構成する繊維の本数が少なくならず、第1繊維層を構成する繊維が第2繊維層を構成する繊維と接着する箇所が少なくならないため、それにより不織布の毛羽立ちや破れが発生しにくくなるという有利な効果を奏することができ、0.55以上、0.92以下である場合、不織布は柔らかく滑らかな触感を有する。
 前記第1芯鞘型複合繊維の繊度は、前記第2芯鞘型複合繊維の繊度より小さいことを前提として、前記第1芯鞘型複合繊維の繊度は、1.0dtex以上2.9dtex以下であることが好ましく、前記第2芯鞘型複合繊維の繊度は、1.7dtex以上4.4dtex以下であることが好ましく、不織布は柔らかく滑らかな触感を有することができ、前記第1芯鞘型複合繊維の繊度は、1.0dtex以上2.0dtex以下であり、前記第2芯鞘型複合繊維の繊度は、1.7dtex以上2.6dtex以下である場合、不織布は柔らかく滑らかな触感を有するという優れた効果を奏する。
Further, the ratio of the fineness (F1) of the first sheath-core composite fiber to the fineness (F2) of the second sheath-core composite fiber (the fineness of the first sheath-core composite fiber / the fineness of the second sheath-core composite fiber) ) (F1 / F2) is smaller than 1 and preferably 0.95 or less, more preferably 0.38 or more and 0.93 or less, and more preferably 0.40 or more and 0.93 or less. More preferably, it is 0.55 or more and 0.92 or less, and even more preferably 0.70 or more and 0.90 or less. When the ratio (F1 / F2) between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is smaller than 1 and 0.55 or more, the fibers constituting the second fiber layer And the number of places where the fibers constituting the first fiber layer adhere to the fibers constituting the second fiber layer does not decrease, thereby providing an advantageous effect that the nonwoven fabric is less likely to fluff or break. The nonwoven fabric has a soft and smooth touch when it is not less than 0.55 and not more than 0.92.
Assuming that the fineness of the first core-sheath composite fiber is smaller than the fineness of the second core-sheath composite fiber, the fineness of the first core-sheath composite fiber is 1.0 dtex or more and 2.9 dtex or less. It is preferable that the fineness of the second core-sheath composite fiber is 1.7 dtex or more and 4.4 dtex or less, and the nonwoven fabric can have a soft and smooth tactile sensation. When the fineness of the fiber is 1.0 dtex or more and 2.0 dtex or less, and the fineness of the second core-sheath composite fiber is 1.7 dtex or more and 2.6 dtex or less, the nonwoven fabric has a soft and smooth touch. Has the effect.
 前記第1芯鞘型複合繊維の繊度は、前記第2芯鞘型複合繊維の繊度より小さいことを前提として、前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差(第2芯鞘型複合繊維の繊度-第1芯鞘型複合繊維の繊度)が、0.1dtex以上1.5dtex以下であることが好ましく、0.2dtex以上1.2dtex以下であることが好ましく、0.3dtex以上1.0dtex以下であることがより好ましい。前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差が、0.1dtex以上1.5dtex以下である場合、第2繊維層を構成する繊維の本数が少なくならず、第1繊維層を構成する繊維が第2繊維層を構成する繊維と接着する箇所が少なくならないため、それにより不織布の毛羽立ちや破れが発生しにくくなるという有利な効果を奏することができる。 Assuming that the fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber, the fineness of the first sheath-core composite fiber and the fineness of the second sheath-core composite fiber (The fineness of the second core-sheath type composite fiber−the fineness of the first core-sheath type composite fiber) is preferably 0.1 dtex or more and 1.5 dtex or less, and is 0.2 dtex or more and 1.2 dtex or less. It is more preferably 0.3 dtex or more and 1.0 dtex or less. When the difference between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.1 dtex or more and 1.5 dtex or less, the number of fibers constituting the second fiber layer is small. In addition, since the number of places where the fibers constituting the first fiber layer adhere to the fibers constituting the second fiber layer does not decrease, the advantageous effect that the nonwoven fabric is less likely to be fluffed or torn can be obtained. .
 前記第1繊維層の目付は、前記第2繊維層の目付よりも小さいことが好ましい。前記第1繊維層の目付は、前記第2繊維層の目付よりも小さい場合、不織布は柔らかい触感を有するという優れた効果を奏する。
 前記第1繊維層の目付は、5g/m以上20g/m以下であることが好ましく、7g/m以上18g/m以下であることがより好ましく、8g/m以上15g/m以下であることが更により好ましい。
 前記第2繊維層の目付は、7g/m以上25g/m以下であることが好ましく、9g/m以上23g/m以下であることがより好ましく、10g/m以上20g/m以下であることが更により好ましい。
The basis weight of the first fiber layer is preferably smaller than the basis weight of the second fiber layer. When the basis weight of the first fiber layer is smaller than the basis weight of the second fiber layer, the nonwoven fabric has an excellent effect of having a soft touch.
The basis weight of the first fiber layer, 5 g / preferably m is 2 or more 20 g / m 2 or less, more preferably 7 g / m 2 or more 18 g / m 2 or less, 8 g / m 2 or more 15 g / m Even more preferably, it is 2 or less.
The basis weight of the second fiber layer, 7 g / preferably m is 2 or more 25 g / m 2 or less, more preferably 9 g / m 2 or more 23 g / m 2 or less, 10 g / m 2 or more 20 g / m Even more preferably, it is 2 or less.
 第1繊維層の目付と第2繊維層の目付との比(第1繊維層の目付/第2繊維層の目付)は、1より小さく、0.95以下であることが好ましく、0.20以上0.90以下であることがより好ましく、0.45以上0.80以下であることが更により好ましい。
 前記第1繊維層の目付は、5g/m以上20g/m以下であり、前記第2繊維層の目付は、7g/m以上25g/m以下である場合、不織布は柔らかい触感を有するという優れた効果を奏する。
The ratio of the basis weight of the first fiber layer to the basis weight of the second fiber layer (the basis weight of the first fiber layer / the basis weight of the second fiber layer) is smaller than 1, preferably 0.95 or less, and 0.20 or less. It is more preferably not less than 0.90 and not more than 0.40, and still more preferably not less than 0.45 and not more than 0.80.
When the basis weight of the first fiber layer is 5 g / m 2 or more and 20 g / m 2 or less, and the basis weight of the second fiber layer is 7 g / m 2 or more and 25 g / m 2 or less, the nonwoven fabric has a soft touch. It has an excellent effect of having.
 前記第1芯鞘型複合繊維は、複合繊維を構成する異なる二つの樹脂成分が同心円状に配置された、いわゆる同心芯鞘型複合繊維(同心円断面の芯鞘型複合繊維とも称される)や、繊維断面における芯成分の重心位置が、複合繊維全体の重心位置とは違う位置にある、いわゆる偏心芯鞘型複合繊維であってよい。同心芯鞘型複合繊維であることがより好ましい。同心芯鞘型複合繊維は繊維同士の交点が偏心芯鞘型複合繊維よりも多いため不織布の毛羽立ちや破れを抑えやすくなると推測される。 The first core-sheath conjugate fiber is a so-called concentric core-sheath conjugate fiber (also referred to as a concentric core-sheath conjugate fiber) in which two different resin components constituting the conjugate fiber are concentrically arranged. A so-called eccentric core-sheath type conjugate fiber in which the center of gravity of the core component in the fiber cross section is different from the center of gravity of the entire conjugate fiber may be used. More preferably, it is a concentric core-sheath type composite fiber. It is presumed that the concentric core-sheath type composite fiber has more intersection points between the fibers than the eccentric core-sheath type composite fiber, and thus it is easy to suppress fluffing and tearing of the nonwoven fabric.
 前記第1芯鞘型複合繊維は、同心芯鞘型複合繊維を50質量%以上含むことが好ましく、70質量%以上含むことがより好ましく、前記第1芯鞘型複合繊維は、同心芯鞘型複合繊維であることが特に好ましい。前記第1芯鞘型複合繊維は、同心芯鞘型複合繊維を50質量%以上含む場合、不織布の厚さを抑えることができ、不織布は滑らかな触感を有するという優れた効果を奏する。 The first core-sheath conjugate fiber preferably contains 50% by mass or more, more preferably 70% by mass or more, of the concentric core-sheath conjugate fiber. Particularly preferred are conjugate fibers. When the first core-sheath type conjugate fiber contains 50% by mass or more of the concentric core-sheath type conjugate fiber, the thickness of the nonwoven fabric can be suppressed, and the nonwoven fabric has an excellent effect of having a smooth touch.
 前記第1芯鞘型複合繊維の芯成分は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、ポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート、ポリ乳酸等のポリエステル系樹脂、ポリプロピレン、ポリメチルペンテン等のポリオレフィン系樹脂、ナイロン66、ナイロン12、ナイロン6等のポリアミド系樹脂、アクリル系樹脂、および、ポリカーボネート、ポリアセタール、ポリスチレン、環状ポリオレフィンなどのエンジニアリング・プラスチックから選択される少なくとも1種の樹脂を50質量%以上含むことが好ましく、ポリエステル系樹脂を50質量%以上含むことがより好ましく、ポリエチレンテレフタレートを50質量%以上含むことが更により好ましい。前記第1芯鞘型複合繊維の芯成分は、ポリエステル系樹脂、およびポリオレフィン系樹脂から選択される少なくとも1種の樹脂を50質量%以上含む場合、第1芯鞘型複合繊維のカード工程性が良いという優れた効果を奏する。尚、芯成分は、本発明が目的とする不織布を得ることができる限り、他の樹脂及び芯成分を構成する樹脂に通常添加される各種添加剤等の他の成分を含むことができる。 The core component of the first core-sheath type conjugate fiber is not particularly limited as long as the nonwoven fabric targeted by the present invention can be obtained. However, polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate Polyester resins such as polylactic acid, polyolefin resins such as polypropylene and polymethylpentene, polyamide resins such as nylon 66, nylon 12, and nylon 6, acrylic resins, and polycarbonate, polyacetal, polystyrene, and cyclic polyolefin. It is preferable to contain at least one resin selected from engineering plastics in an amount of 50% by mass or more, more preferably 50% by mass or more of a polyester resin, and 50% by mass of polyethylene terephthalate. Even more preferably comprise more. When the core component of the first core-sheath composite fiber contains at least 50% by mass of at least one resin selected from a polyester resin and a polyolefin resin, the card processability of the first core-sheath composite fiber is reduced. It has an excellent effect of being good. The core component may contain other components such as other resins and various additives usually added to the resin constituting the core component, as long as the nonwoven fabric targeted by the present invention can be obtained.
 前記第1芯鞘型複合繊維の鞘成分は、ポリエチレンを含む。
 鞘成分に含まれるポリエチレンは、本発明が目的とする不織布を得ることができる限り、特に制限されることはないが、通常、当業者がポリエチレンと認識する樹脂であればよく、例えば、高密度ポリエチレン、中密度ポリエチレン、低密度ポリエチレン、直鎖状低密度ポリエチレン等を例示でき、高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種であることが好ましい。ポリエチレンが、高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種である場合、第1芯鞘型複合繊維のカード工程性が良いという優れた効果を奏する。また、ポリエチレンが高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種である場合、不織布の毛羽立ちや破れを少なくすることができるという優れた効果を奏する。高密度ポリエチレン及び中密度ポリエチレンは、低密度ポリエチレン及び直鎖状低密度ポリエチレンと比較して樹脂が硬いため、繊維同士の接着力が高くなり、不織布の毛羽立ちや破れを少なくすることができると推測される。尚、鞘成分は、鞘成分全体を100質量%として、ポリエチレンを50質量%以上含む限り、他の樹脂及びポリエチレンに通常添加される各種添加剤等の他の成分を含むことができる。鞘成分は、鞘成分全体を100質量%として、ポリエチレンを70質量%以上含んでよく、80質量%以上含んでよく、90質量%以上含んでよく、95質量%以上含んでよい。鞘成分は、実質的にポリエチレンであってよい。
The sheath component of the first core-sheath type composite fiber contains polyethylene.
The polyethylene contained in the sheath component is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained. Examples thereof include polyethylene, medium-density polyethylene, low-density polyethylene, and linear low-density polyethylene, and it is preferably at least one selected from high-density polyethylene and medium-density polyethylene. When the polyethylene is at least one selected from high-density polyethylene and medium-density polyethylene, the first core-sheath type conjugate fiber has an excellent effect in that the card processability is good. In addition, when the polyethylene is at least one selected from high-density polyethylene and medium-density polyethylene, an excellent effect that fluff and tear of the nonwoven fabric can be reduced can be achieved. High-density polyethylene and medium-density polyethylene are assumed to be able to reduce the fluff and tear of the non-woven fabric because the resin is harder than the low-density polyethylene and linear low-density polyethylene, so that the adhesive force between the fibers increases. Is done. The sheath component may contain other components such as other resins and various additives usually added to polyethylene as long as the sheath component is 100% by mass and the polyethylene is 50% by mass or more. The sheath component may contain polyethylene by 70% by mass or more, 80% by mass or more, 90% by mass or more, or 95% by mass or more, with the whole sheath component being 100% by mass. The sheath component may be substantially polyethylene.
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であることが、好ましい。
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが140J/g以上270J/g以下であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが140J/g以上270J/g以下であることが、より好ましい。
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが150J/g以上220J/g以下であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが150J/g以上220J/g以下であることが、更により好ましい。
 前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である場合、不織布の毛羽立ちや不織布の破れが抑えられるという優れた効果を奏する。融解するのに必要なエネルギーが大きい鞘成分は接着強力が高くなるため、不織布の毛羽立ちや不織布の破れが抑えられると推測される。
 複合繊維の鞘成分の融解熱ΔHは、実施例に示す方法で、測定して得ることができる。
 第1芯鞘型複合繊維の鞘成分の融解熱ΔHと第2芯鞘型複合繊維の鞘成分の融解熱ΔHとの差は絶対値で80J/g以下であることが好ましく、50J/g以下であることがより好ましく、30J/g以下であることが更に好ましい。
Preferably, the heat of fusion ΔH of the sheath component of the first core-sheath composite fiber is 130 J / g or more, and the heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
The heat of fusion ΔH of the sheath component of the first core-sheath composite fiber is 140 J / g or more and 270 J / g or less, and the heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 140 J / g or more and 270 J / g. The following is more preferable.
The heat of fusion ΔH of the sheath component of the first core-sheath composite fiber is 150 J / g or more and 220 J / g or less, and the heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 150 J / g or more and 220 J / g. It is even more preferred that:
When the heat of fusion ΔH of the sheath component of the first core-sheath composite fiber is 130 J / g or more and the heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more, the nonwoven fabric is fluffed. And an excellent effect that tearing of the nonwoven fabric is suppressed. It is presumed that the sheath component, which requires a large amount of energy for melting, has a high adhesive strength, so that fluffing of the nonwoven fabric and tearing of the nonwoven fabric can be suppressed.
The heat of fusion ΔH of the sheath component of the conjugate fiber can be measured and obtained by the method described in Examples.
The difference between the heat of fusion ΔH of the sheath component of the first core-sheath composite fiber and the heat of fusion ΔH of the sheath component of the second sheath-core composite fiber is preferably 80 J / g or less in absolute value, and 50 J / g or less. Is more preferable, and it is more preferable that it is 30 J / g or less.
 前記第1芯鞘型複合繊維の鞘成分のメルトフローレートが15g/10分以上であることが好ましく、16g/10分以上30g/10分以下であることがより好ましく、18g/10分以上25g/10分以下であることが更により好ましい。
 前記第1芯鞘型複合繊維の鞘成分のメルトフローレートが15g/10分以上である場合、不織布の毛羽立ちや不織布の破れが抑えられるという優れた効果を奏する。
 メルトフローレートは、実施例に記載した方法で測定する。
The melt flow rate of the sheath component of the first core-sheath composite fiber is preferably 15 g / 10 min or more, more preferably 16 g / 10 min or more and 30 g / 10 min or less, and 18 g / 10 min or more and 25 g. It is even more preferable that the time is / 10 minutes or less.
When the melt flow rate of the sheath component of the first core-sheath type composite fiber is 15 g / 10 minutes or more, an excellent effect of suppressing fluffing of the nonwoven fabric and tearing of the nonwoven fabric is exhibited.
The melt flow rate is measured by the method described in the examples.
 前記第1芯鞘型複合繊維の、芯成分と鞘成分との芯鞘比(芯成分/鞘成分 質量比)は、20/80~80/20であることが好ましく、30/70~70/30であることがより好ましく、40/60~60/40であることが更に好ましく、40/60~55/45であることが特に好ましい。
 前記第1芯鞘型複合繊維の、芯成分と鞘成分との芯鞘比(芯成分/鞘成分 質量比)は、20/80~80/20である場合、第1芯鞘型複合繊維のカード工程性と不織布の毛羽立ち抑制とを両立させることができるという優れた効果を奏する。
The core / sheath ratio (core / shell component mass ratio) of the core / sheath component of the first core / sheath type composite fiber is preferably 20/80 to 80/20, and 30/70 to 70/70. The ratio is more preferably 30, more preferably 40/60 to 60/40, and particularly preferably 40/60 to 55/45.
When the core / sheath ratio (core component / sheath component mass ratio) between the core component and the sheath component of the first core / sheath conjugate fiber is 20/80 to 80/20, An excellent effect that both the card processability and the suppression of fluffing of the nonwoven fabric can be achieved is achieved.
 前記第1芯鞘型複合繊維の平均繊維長は、20mm以上110mm以下であることが好ましく、30mm以上70mm以下であることがより好ましく、35mm以上55mm以下であることが更により好ましい。
 前記第1芯鞘型複合繊維の平均繊維長は、20mm以上110mm以下である場合、第1芯鞘型複合繊維のカード工程性が良いという優れた効果を奏する。
The average fiber length of the first core-sheath type composite fiber is preferably 20 mm or more and 110 mm or less, more preferably 30 mm or more and 70 mm or less, and even more preferably 35 mm or more and 55 mm or less.
When the average fiber length of the first core-in-sheath type conjugate fiber is 20 mm or more and 110 mm or less, an excellent effect that the card processability of the first core-in-sheath type conjugate fiber is good is exhibited.
 前記第2芯鞘型複合繊維は、複合繊維を構成する異なる二つの樹脂成分が同心円状に配置された、いわゆる同心芯鞘型複合繊維(同心円断面の芯鞘型複合繊維とも称される)や、繊維断面における芯成分の重心位置が、複合繊維全体の重心位置とは違う位置にある、いわゆる偏心芯鞘型複合繊維であってよい。同心芯鞘型複合繊維であることがより好ましい。同心芯鞘型複合繊維は繊維同士の交点が偏心芯鞘型複合繊維よりも多いため、第1繊維層を構成する繊維との接着箇所が多くなるため不織布の毛羽立ちや破れを抑えやすくなると推測される。 The second core-sheath composite fiber is a so-called concentric core-sheath composite fiber (also referred to as a concentric core-sheath composite fiber) in which two different resin components constituting the composite fiber are concentrically arranged. A so-called eccentric core-sheath type conjugate fiber in which the center of gravity of the core component in the fiber cross section is different from the center of gravity of the entire conjugate fiber may be used. More preferably, it is a concentric core-sheath type composite fiber. It is presumed that the concentric core-sheath type composite fiber has more intersections between the fibers than the eccentric core-sheath type composite fiber, so that the number of bonding points with the fibers constituting the first fiber layer increases, so that it is easy to suppress fluffing and tearing of the nonwoven fabric. You.
 前記第2芯鞘型複合繊維は、同心芯鞘型複合繊維を50質量%以上含むことが好ましく、70質量%以上含むことがより好ましく、前記第2芯鞘型複合繊維は、同心芯鞘型複合繊維であることが特に好ましい。前記第2芯鞘型複合繊維は、同心芯鞘型複合繊維を50質量%以上含む場合、不織布の厚さを抑えることができ、不織布は滑らかな触感を有するという優れた効果を奏する。 The second core-sheath conjugate fiber preferably contains 50% by mass or more, more preferably 70% by mass or more, of the concentric core-sheath conjugate fiber. Particularly preferred are conjugate fibers. When the second core-sheath type conjugate fiber contains 50% by mass or more of the concentric core-sheath type conjugate fiber, the thickness of the nonwoven fabric can be suppressed, and the nonwoven fabric has an excellent effect of having a smooth touch.
 前記第2芯鞘型複合繊維の芯成分は、本発明が目的とする不織布を得ることができるかぎり特に制限されることはないが、ポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート、ポリ乳酸等のポリエステル系樹脂、ポリプロピレン、ポリメチルペンテン等のポリオレフィン系樹脂、ナイロン66、ナイロン12、ナイロン6等のポリアミド系樹脂、アクリル系樹脂、および、ポリカーボネート、ポリアセタール、ポリスチレン、環状ポリオレフィンなどのエンジニアリング・プラスチックから選択される少なくとも1種の樹脂を50質量%以上含むことが好ましく、ポリエステル系樹脂を50質量%以上含むことがより好ましく、ポリエチレンテレフタレートを50質量%以上含むことが更により好ましい。前記第2芯鞘型複合繊維の芯成分は、ポリエステル系樹脂、およびポリオレフィン系樹脂から選択される少なくとも1種の樹脂を50質量%以上含む場合、第2芯鞘型複合繊維のカード工程性が良いという優れた効果を奏する。 The core component of the second core-sheath type conjugate fiber is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained. Polyester resins such as polylactic acid, polyolefin resins such as polypropylene and polymethylpentene, polyamide resins such as nylon 66, nylon 12, and nylon 6, acrylic resins, and polycarbonate, polyacetal, polystyrene, and cyclic polyolefin. The resin preferably contains at least one resin selected from engineering plastics in an amount of 50% by mass or more, more preferably contains a polyester-based resin in an amount of 50% by mass or more, and contains polyethylene terephthalate in an amount of 50% by mass. It is even more preferred, including percent. When the core component of the second core-sheath composite fiber contains at least 50% by mass of at least one resin selected from a polyester resin and a polyolefin resin, the card processability of the second core-sheath composite fiber is reduced. It has an excellent effect of being good.
 前記第2芯鞘型複合繊維は、鞘成分がポリエチレンを含む。
 鞘成分に含まれるポリエチレンは、本発明が目的とする不織布を得ることができる限り、特に制限されることはないが、通常、当業者がポリエチレンと認識する樹脂であればよく、例えば、高密度ポリエチレン樹脂、中密度ポリエチレン、低密度ポリエチレン、直鎖状低密度ポリエチレン等を例示でき、高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種であることが好ましい。ポリエチレンが、高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種である場合、第2芯鞘型複合繊維のカード工程性が良いという優れた効果を奏する。また、ポリエチレンが高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種である場合、第1芯鞘型複合繊維についての記載と同様に、不織布の毛羽立ちや破れを少なくすることができるという優れた効果を奏する。尚、鞘成分は、鞘成分全体を100質量%として、ポリエチレンを50質量%以上含む限り、他の樹脂及びポリエチレンに通常添加される各種添加剤等の他の成分を含むことができる。鞘成分は、鞘成分全体を100質量%として、ポリエチレンを70質量%以上含んでよく、80質量%以上含んでよく、90質量%以上含んでよく、95質量%以上含んでよい。鞘成分は、実質的にポリエチレンであってよい。
The second core-sheath type composite fiber has a sheath component containing polyethylene.
The polyethylene contained in the sheath component is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained. Examples thereof include polyethylene resin, medium-density polyethylene, low-density polyethylene, linear low-density polyethylene, and the like, and it is preferably at least one selected from high-density polyethylene and medium-density polyethylene. When the polyethylene is at least one selected from high-density polyethylene and medium-density polyethylene, an excellent effect is obtained in that the cardability of the second core-sheath composite fiber is good. Further, when the polyethylene is at least one selected from high-density polyethylene and medium-density polyethylene, as in the description of the first core-in-sheath type conjugate fiber, it is possible to reduce fluffing and tearing of the nonwoven fabric. It works. The sheath component may contain other components such as other resins and various additives usually added to polyethylene as long as the sheath component is 100% by mass and the polyethylene is 50% by mass or more. The sheath component may contain polyethylene by 70% by mass or more, 80% by mass or more, 90% by mass or more, or 95% by mass or more, with the whole sheath component being 100% by mass. The sheath component may be substantially polyethylene.
 前記第2芯鞘型複合繊維の鞘成分のメルトフローレートが10g/10分以上であることが好ましく、15g/10分以上30g/10分以下であることがより好ましく、17g/10分以上25g/10分以下であることが更により好ましい。
 前記第2芯鞘型複合繊維の鞘成分のメルトフローレートが10g/10分以上である場合、不織布の毛羽立ちと不織布の破れを抑制できるという優れた効果を奏する。
 メルトフローレートは、実施例に記載した方法で測定する。
The melt flow rate of the sheath component of the second core-sheath type composite fiber is preferably 10 g / 10 min or more, more preferably 15 g / 10 min or more and 30 g / 10 min or less, and 17 g / 10 min or more and 25 g. It is even more preferable that the time is / 10 minutes or less.
When the melt flow rate of the sheath component of the second core-sheath composite fiber is 10 g / 10 minutes or more, an excellent effect of suppressing fluffing of the nonwoven fabric and tearing of the nonwoven fabric can be achieved.
The melt flow rate is measured by the method described in the examples.
 前記第2芯鞘型複合繊維は、芯成分と鞘成分との芯鞘比(芯成分/鞘成分 質量比)は、20/80~80/20であることが好ましく30/70~70/30であることがより好ましく、40/60~60/40であることが更により好ましい。芯成分と鞘成分との芯鞘比(芯成分/鞘成分 質量比)が、20/80~80/20である場合、第2芯鞘型複合繊維のカード工程性と不織布の毛羽立ち抑制とを両立させることができるという優れた効果を奏する。 In the second core-sheath type composite fiber, the core-to-sheath ratio (core component / sheath component 比 mass ratio) between the core component and the sheath component is preferably 20/80 to 80/20, and 30/70 to 70/30. Is more preferable, and even more preferably 40/60 to 60/40. When the core-sheath ratio (core component / sheath component 成分 mass ratio) of the core component and the sheath component is 20/80 to 80/20, the card processability of the second core-sheath type composite fiber and the suppression of fluffing of the nonwoven fabric are improved. An excellent effect that both can be achieved is exhibited.
 前記第2芯鞘型複合繊維の平均繊維長は、20mm以上110mm以下であることが好ましく、30mm以上70mm以下であることがより好ましく、35mm以上55mm以下であることが更により好ましい。
 前記第2芯鞘型複合繊維の平均繊維長は、20mm以上110mm以下である場合、第2芯鞘型複合繊維のカード工程性が良いという優れた効果を奏する。
The average fiber length of the second core-sheath type composite fiber is preferably 20 mm or more and 110 mm or less, more preferably 30 mm or more and 70 mm or less, and even more preferably 35 mm or more and 55 mm or less.
When the average fiber length of the second core-sheath type composite fiber is 20 mm or more and 110 mm or less, an excellent effect that the card processability of the second core-sheath type composite fiber is good is exhibited.
 尚、前記第1芯鞘型複合繊維と前記第2芯鞘型複合繊維は、芯成分に含まれる樹脂と鞘成分に含まれる樹脂との組み合わせが同じでも、異なっていてもよい。 The combination of the resin contained in the core component and the resin contained in the sheath component of the first core-sheath type composite fiber and the second core-sheath type composite fiber may be the same or different.
 本発明で使用する第1繊維層及び第2繊維層は、種々の繊維ウェブの製造方法を用いて製造することができる。本発明が目的とする吸収性物品用不織布を得ることができる限り、その製造方法は特に制限されることはない。そのような製造方法として、例えば、パラレルウェブ、クロスウェブ、クリスクロスウェブ、セミランダムウェブ及びランダムウェブ等のカード法、エアレイ法等を例示することができる。吸収性物品用バックシートは柔軟性や繊維間にある程度空隙が存在する、適度な空隙率を有していることが求められるため、繊維ウェブはカードウェブであることが好ましい。第1繊維層と第2繊維層は、異なる種類の繊維ウェブであってもよい。 第 The first fiber layer and the second fiber layer used in the present invention can be manufactured by using various methods for manufacturing a fiber web. The production method is not particularly limited as long as the nonwoven fabric for an absorbent article intended by the present invention can be obtained. As such a production method, for example, a card method such as a parallel web, a cross web, a Chris cross web, a semi-random web and a random web, an air lay method, and the like can be exemplified. Since the back sheet for an absorbent article is required to have flexibility and an appropriate porosity in which some gaps exist between fibers, the fiber web is preferably a card web. The first fiber layer and the second fiber layer may be different types of fibrous webs.
 本発明は、本開示の実施形態の吸収性物品用不織布の製造方法を提供し、それは、
 第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
 第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
 前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
を含む。
The present invention provides a method for producing a nonwoven fabric for an absorbent article of the embodiment of the present disclosure,
Producing a first fibrous web comprising a first core-sheath composite fiber;
Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
Superimposing and integrating the first fiber web and the second fiber web,
including.
 本発明の実施形態の吸収性物品用不織布は、第1繊維層となる第1繊維ウェブと第2繊維層となる第2繊維ウェブを重ね合わせて、一体化することで製造することができる。本発明が目的とする吸収性物品用不織布を得ることができる限り、その製造方法は特に制限されることはない。従って、第1繊維ウェブと第2繊維ウェブを一体化させるため、第1繊維ウェブと第2繊維ウェブを重ね合わせて交絡処理、例えばニードルパンチ処理や水流交絡処理を行って両繊維ウェブが交絡し、一体化した不織布としてもよいが、第1繊維ウェブと第2繊維ウェブを重ね合わせ、接着して一体化した不織布とすることが好ましい。例えば、熱処理を行うサーマルボンディング法で製造し、第1繊維ウェブと第2繊維ウェブが接着した熱接着不織布(文献によってはサーマルボンド不織布とも称す)とすることがより好ましい。熱接着不織布の形態であれば、厚さ方向の柔軟性、嵩回復性、並びに不織布表面の滑らかな風合い等の効果を顕著に発揮するからである。 不 織布 The nonwoven fabric for an absorbent article according to the embodiment of the present invention can be manufactured by laminating and integrating a first fiber web serving as a first fiber layer and a second fiber web serving as a second fiber layer. The production method is not particularly limited as long as the nonwoven fabric for an absorbent article intended by the present invention can be obtained. Therefore, in order to integrate the first fiber web and the second fiber web, the first fiber web and the second fiber web are overlapped and entangled, for example, a needle punching process or a water entanglement process is performed so that the two fiber webs are entangled. An integrated nonwoven fabric may be used, but it is preferable that the first fibrous web and the second fibrous web are overlapped and bonded to form an integrated nonwoven fabric. For example, it is more preferable to produce a heat-bonded nonwoven fabric in which the first fiber web and the second fiber web are bonded by a thermal bonding method in which heat treatment is performed (also referred to as a thermal bond nonwoven fabric in some documents). This is because the heat-bonded non-woven fabric has remarkable effects such as flexibility in the thickness direction, bulk recovery, and smooth texture of the non-woven fabric surface.
 熱処理の方法、即ち、サーマルボンディングの方法は公知の方法にて行うことができ、例えば、エアスルー法(熱風貫通式熱処理法)、熱風吹付け式熱処理法、ヒートロール法、赤外線式熱処理法等、風圧等の圧力が繊維ウェブにあまり加わらない熱処理機が好ましく用いられ、エアスルー法(熱風貫通式熱処理法)がより好ましい。熱処理温度等の熱処理条件は、例えば、鞘成分が十分に溶融及び/又は軟化して、繊維同士が接点又は交点において接合するような条件を選択して実施する。例えば、熱処理温度は、第1繊維ウェブ及び第2繊維ウェブに含まれる合成繊維を構成する熱可塑性樹脂の中で、最も融点が低いものの融点をTm(℃)としたときTm以上(Tm+50℃)以下(℃)の範囲で熱処理することが好ましく、(Tm+3℃)以上(Tm+40℃)以下の範囲で熱処理することがより好ましく、(Tm+5℃)以上(Tm+30℃)以下の範囲で熱処理することが特に好ましい。 The method of heat treatment, that is, the method of thermal bonding can be performed by a known method, for example, an air through method (hot air penetration heat treatment method), a hot air blowing heat treatment method, a heat roll method, an infrared heat treatment method, and the like. A heat treatment machine in which pressure such as wind pressure is not applied much to the fiber web is preferably used, and an air-through method (hot air penetration heat treatment method) is more preferable. The heat treatment conditions such as the heat treatment temperature are selected and performed, for example, such that the sheath component is sufficiently melted and / or softened and the fibers are joined at the contact points or intersections. For example, the heat treatment temperature is equal to or higher than Tm (Tm + 50 ° C.) when the melting point of the thermoplastic resin having the lowest melting point among the thermoplastic resins constituting the synthetic fibers contained in the first fiber web and the second fiber web is Tm (° C.). The heat treatment is preferably performed in the range of (° C) or less, more preferably in the range of (Tm + 3 ° C) or more and (Tm + 40 ° C) or less, and performed in the range of (Tm + 5 ° C) or more and (Tm + 30 ° C) or less. Is particularly preferred.
 熱風貫通式熱処理法は特に限定なく、公知の方法で行うことができるが、不織布の製造時、即ち、熱処理を行う際、第1繊維ウェブと第2繊維ウェブとを重ね合わせた積層ウェブを、第1繊維ウェブが、熱処理機の搬送支持体(例えばコンベアベルト)と接触するように載置し、第2繊維ウェブ側から所定温度の熱風を吹き付けて熱処理することが好ましい。熱風貫通式熱処理において、第1繊維層となる第1繊維ウェブが熱処理中に支持搬送体と接した状態であり、且つ熱風が第2繊維層となる第2繊維ウェブ側から吹き付けられることで、第1繊維ウェブは熱処理されている間、支持体に押し付けられ、表面がより平滑となる。したがって、より滑らかな触感が不織布の表面に付与される。なお、本発明の形態の吸収性物品用不織布は、必要に応じて、更に、不織布が通常有する追加の層を有することができる。 The hot air penetration type heat treatment method is not particularly limited, and can be performed by a known method.When manufacturing the nonwoven fabric, that is, when performing the heat treatment, a laminated web in which the first fiber web and the second fiber web are overlapped with each other, It is preferable that the first fibrous web is placed so as to be in contact with a transport support (for example, a conveyor belt) of a heat treatment machine, and is heat-treated by blowing hot air at a predetermined temperature from the second fibrous web. In the hot air penetrating heat treatment, the first fiber web serving as the first fiber layer is in contact with the supporting carrier during the heat treatment, and hot air is blown from the second fiber web side serving as the second fiber layer, The first fibrous web is pressed against the support during the heat treatment, resulting in a smoother surface. Therefore, a smoother feel is imparted to the surface of the nonwoven fabric. In addition, the nonwoven fabric for absorbent articles of the embodiment of the present invention may further have, if necessary, an additional layer usually included in the nonwoven fabric.
 従って、本発明の実施形態の吸収性物品用不織布は、第1繊維層と第2繊維層の繊維同士が交絡して一体化していてもよいが、繊維同士が接着して一体していることが好ましく、繊維同士が熱接着で一体化していることがより好ましい。特に第1繊維層と第2繊維層は第1芯鞘型複合繊維の鞘成分と第2芯鞘型複合繊維の鞘成分により繊維同士が接着して一体化していることが好ましい。第1繊維層は繊維同士が第1芯鞘型複合繊維の鞘成分により接着されていることが好ましく、また、第2繊維層は繊維同士が第2芯鞘型複合繊維の鞘成分により接着されていることが好ましい。 Therefore, in the nonwoven fabric for an absorbent article of the embodiment of the present invention, the fibers of the first fiber layer and the second fiber layer may be entangled and integrated, but the fibers are bonded and integrated. It is more preferable that the fibers are integrated by thermal bonding. In particular, it is preferable that the first fiber layer and the second fiber layer are bonded and integrated by the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber. In the first fiber layer, the fibers are preferably bonded to each other by a sheath component of a first core-sheath composite fiber, and the second fiber layer is bonded to each other by a sheath component of a second core-sheath composite fiber. Is preferred.
 本発明の実施形態の吸収性物品用不織布は、必要に応じて、エンボス加工等の追加の加工が施されてよく、そのような追加の形態及び形状等を有してよい。 不 織布 The nonwoven fabric for an absorbent article according to the embodiment of the present invention may be subjected to additional processing such as embossing, if necessary, and may have such additional forms and shapes.
 本発明の実施形態の吸収性物品用不織布の目付は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、12g/m以上45g/m以下であることが好ましく、16g/m以上41g/m以下であることがより好ましく、18g/m以上35g/m以下であることが更により好ましい。
 不織布の目付は、12g/m以上45g/m以下である場合、不織布の厚さが適度な範囲になるという優れた効果を奏する。
The basis weight of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but it is 12 g / m 2 or more and 45 g / m 2 or less. Is preferably 16 g / m 2 or more and 41 g / m 2 or less, and more preferably 18 g / m 2 or more and 35 g / m 2 or less.
When the basis weight of the nonwoven fabric is 12 g / m 2 or more and 45 g / m 2 or less, an excellent effect that the thickness of the nonwoven fabric is in an appropriate range is exhibited.
 本発明の実施形態の吸収性物品用不織布の厚さは、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、0.20mm以上3.0mm以下であることが好ましく、0.30mm以上1.5mm以下であることがより好ましく、0.40mm以上1.0mm以下であることが更により好ましい。
 不織布の厚さは、0.20mm以上3.0mm以下である場合、不織布は柔らかな触感を有するという優れた効果を奏する。
The thickness of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric targeted by the present invention can be obtained, but may be 0.20 mm or more and 3.0 mm or less. More preferably, it is 0.30 mm or more and 1.5 mm or less, and even more preferably 0.40 mm or more and 1.0 mm or less.
When the thickness of the nonwoven fabric is 0.20 mm or more and 3.0 mm or less, the nonwoven fabric has an excellent effect of having a soft touch.
 本発明の実施形態の吸収性物品用不織布の比容積は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、5cm/g以上150cm/g以下であることが好ましく、7cm/g以上130cm/g以下であることがより好ましく、10cm/g以上100cm/g以下であることが更により好ましい。
 不織布の比容積は、5cm/g以上150cm/g以下である場合、不織布は柔らかな触感を有するという優れた効果を奏する。
The specific volume of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is 5 cm 3 / g or more and 150 cm 3 / g or less. It is more preferably 7 cm 3 / g or more and 130 cm 3 / g or less, and still more preferably 10 cm 3 / g or more and 100 cm 3 / g or less.
When the specific volume of the nonwoven fabric is 5 cm 3 / g or more and 150 cm 3 / g or less, the nonwoven fabric has an excellent effect of having a soft touch.
 本発明の実施形態の吸収性物品用不織布の引張強さ(MD)は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、例えば5N/5cm以上60N/5cm以下であり、5N/5cm以上50N/5cm以下であることが好ましく、10N/5cm以上45N/5cm以下であることがより好ましく、20N/5cm以上40N/5cm以下であることが更により好ましい。
 不織布の引張強さ(MD)は、5N/5cm以上60N/5cm以下である場合、吸収性物品を製造する際の不織布の加工性が良いという優れた効果を奏する。
The tensile strength (MD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric targeted by the present invention can be obtained. For example, the tensile strength is 5 N / 5 cm or more and 60 N / 5 cm. Or less, preferably 5 N / 5 cm or more and 50 N / 5 cm or less, more preferably 10 N / 5 cm or more and 45 N / 5 cm or less, and even more preferably 20 N / 5 cm or more and 40 N / 5 cm or less.
When the tensile strength (MD) of the nonwoven fabric is 5 N / 5 cm or more and 60 N / 5 cm or less, there is an excellent effect that the workability of the nonwoven fabric in producing an absorbent article is good.
 本発明の実施形態の吸収性物品用不織布の引張強さ(CD)は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、1N/5cm以上17N/5cm以下であることが好ましく、2N/5cm以上15N/5cm以下であることがより好ましく、3N/5cm以上12N/5cm以下であることが更により好ましい。
 不織布の引張強さ(CD)は、1N/5cm以上15N/5cm以下である場合、吸収性物品を製造する際の不織布の加工性が良いという優れた効果を奏する。
The tensile strength (CD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is not less than 1 N / 5 cm and not more than 17 N / 5 cm. Is preferable, and it is more preferable that it is 2 N / 5 cm or more and 15 N / 5 cm or less, and it is even more preferable that it is 3 N / 5 cm or more and 12 N / 5 cm or less.
When the tensile strength (CD) of the nonwoven fabric is 1 N / 5 cm or more and 15 N / 5 cm or less, there is an excellent effect that the nonwoven fabric has good workability when producing an absorbent article.
 本発明の実施形態の吸収性物品用不織布の伸び率(MD)は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、10%以上70%以下であることが好ましく、15%以上60%以下であることがより好ましく、20%以上50%以下であることが更により好ましい。
 不織布の伸び率(MD)は、10%以上70%以下である場合、吸収性物品を製造する際の不織布の加工性が良いという優れた効果を奏する。
The elongation (MD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is 10% or more and 70% or less. Is preferably 15% or more and 60% or less, and more preferably 20% or more and 50% or less.
When the elongation (MD) of the nonwoven fabric is 10% or more and 70% or less, an excellent effect that the workability of the nonwoven fabric at the time of manufacturing an absorbent article is good is exhibited.
 本発明の実施形態の吸収性物品用不織布の伸び率(CD)は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、50%以上150%以下であることが好ましく、60%以上140%以下であることがより好ましく、70%以上130%以下であることが更により好ましい。
 不織布の伸び率(CD)は、50%以上150%以下である場合、吸収性物品を製造する際の不織布の加工性が良いという優れた効果を奏する。
The elongation (CD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained. Is preferably 60% or more and 140% or less, and more preferably 70% or more and 130% or less.
When the elongation (CD) of the nonwoven fabric is 50% or more and 150% or less, there is an excellent effect that workability of the nonwoven fabric at the time of manufacturing an absorbent article is good.
 本発明の実施形態の吸収性物品用不織布の10%伸長時応力(MD)は、本発明が目的とする不織布を得ることができる限り特に制限されることはないが、例えば2N/5cm以上25N/5cm以下であることが好ましく、3N/5cm以上25N/5cm以下であることが好ましく、5N/5cm以上20N/5cm以下であることがより好ましく、6N/5cm以上15N/5cm以下であることが更により好ましい。
 不織布の10%伸長時応力(MD)は、2N/5cm以上25N/5cm以下である場合、吸収性物品を製造する際の不織布の加工性が良いという優れた効果を奏する。
The stress at 10% elongation (MD) of the nonwoven fabric for an absorbent article according to the embodiment of the present invention is not particularly limited as long as the nonwoven fabric aimed at by the present invention can be obtained, but is, for example, 2N / 5cm to 25N. / 5 cm or less, preferably 3 N / 5 cm or more and 25 N / 5 cm or less, more preferably 5 N / 5 cm or more and 20 N / 5 cm or less, and more preferably 6 N / 5 cm or more and 15 N / 5 cm or less. Even more preferred.
When the 10% elongation stress (MD) of the nonwoven fabric is 2 N / 5 cm or more and 25 N / 5 cm or less, an excellent effect that the workability of the nonwoven fabric at the time of manufacturing an absorbent article is good is exhibited.
 本発明の実施形態の不織布の剛軟度(MD方向)は、40cN以下であることが好ましく、30cN以下であることがより好ましく、10.0cN以下であることが更に好ましく、7cN以下であることが更により好ましく、5cN以下であることが特に好ましい。
 不織布の剛軟度(MD方向)は、40cN以下である場合、不織布は柔らかな触感を有するという優れた効果を奏する。
The stiffness (MD direction) of the nonwoven fabric of the embodiment of the present invention is preferably 40 cN or less, more preferably 30 cN or less, still more preferably 10.0 cN or less, and more preferably 7 cN or less. Is even more preferably 5 cN or less.
When the rigidity (MD direction) of the nonwoven fabric is 40 cN or less, the nonwoven fabric has an excellent effect of having a soft touch.
 本発明の実施形態の不織布の剛軟度(CD方向)は、70cN以下であることが好ましく、60cN以下であることがより好ましく、20.0cN以下であることが更に好ましく、15cN以下であることが更により好ましく、12cN以下であることが特に好ましい。
 不織布の剛軟度(CD方向)は、70cN以下である場合、不織布は柔らかな触感を有するという優れた効果を奏する。
The stiffness (CD direction) of the nonwoven fabric of the embodiment of the present invention is preferably 70 cN or less, more preferably 60 cN or less, still more preferably 20.0 cN or less, and more preferably 15 cN or less. Is still more preferred, and particularly preferably 12 cN or less.
When the rigidity (CD direction) of the nonwoven fabric is 70 cN or less, the nonwoven fabric has an excellent effect of having a soft touch.
 本発明の実施形態の不織布の剛軟度(不織布全体)は、110cN以下であることが好ましく、90cN以下であることがより好ましく、16.0cN以下であることが更に好ましく、15.0cN以下であることが更により好ましく、14.0cN以下であることが更により好ましく、13.0cN以下であることが特に好ましい。
 不織布の剛軟度(不織布全体)は、110cN以下である場合、不織布は柔らかな触感を有するという優れた効果を奏する。
The stiffness (nonwoven fabric) of the nonwoven fabric of the embodiment of the present invention is preferably 110 cN or less, more preferably 90 cN or less, still more preferably 16.0 cN or less, and more preferably 15.0 cN or less. It is even more preferred that it is less than or equal to 14.0 cN, even more preferably 13.0 cN or less.
When the rigidity of the nonwoven fabric (the entire nonwoven fabric) is 110 cN or less, the nonwoven fabric has an excellent effect of having a soft touch.
 本発明の実施形態の不織布の毛羽立ちは、30個以下であることが好ましく、20個以下であることがより好ましく、15個以下であることが更により好ましい。 不 織布 The nonwoven fabric of the embodiment of the present invention preferably has a fuzz of 30 or less, more preferably 20 or less, and even more preferably 15 or less.
 本発明の実施形態の吸収性物品用不織布は、例えば使い捨ておむつ、生理用ナプキン、失禁パッド及びパンティライナー等の種々の吸収性物品に使用することができる。本発明の形態の吸収性物品用不織布は触感に優れるため、各種吸収性物品であればどのような部材にも使用できる。本発明の吸収性物品用不織布は、トップシート、サイドギャザー、バックシートまたは、パンツタイプの紙おむつにおけるウエスト部分のシートとしても使用できる。 不 織布 The nonwoven fabric for an absorbent article according to the embodiment of the present invention can be used for various absorbent articles such as disposable diapers, sanitary napkins, incontinence pads and panty liners. Since the nonwoven fabric for an absorbent article of the present invention is excellent in tactile sensation, it can be used for any member as long as it is various absorbent articles. The nonwoven fabric for an absorbent article of the present invention can also be used as a top sheet, side gathers, a back sheet, or a sheet of a waist portion in a pants-type disposable diaper.
 不織布の触感、毛羽立ちの低さを考慮すると、本発明の実施形態の吸収性物品用不織布は、バックシートとして使用することが好ましい。
 従って、本発明は、本発明の実施形態の吸収性物品用不織布を含む、吸収性物品用バックシートを提供する。
In consideration of the feel and low fuzziness of the nonwoven fabric, the nonwoven fabric for an absorbent article according to the embodiment of the present invention is preferably used as a backsheet.
Accordingly, the present invention provides a backsheet for an absorbent article, including the nonwoven fabric for an absorbent article of the embodiment of the present invention.
 更に、本発明は、そのような吸収性物品用不織布を含む、種々の吸収性物品を提供することができる。
 本発明の実施形態の吸収性物品は、吸収性物品用バックシートを含み、吸収性物品用バックシートの第1繊維層が、使用者の着衣に近い側に配置されることが好ましい。
 従って、本発明は、吸収性物品用バックシートの第1繊維層が、使用者の着衣に近い側に配置されて、吸収性物品用バックシートが含まれる吸収性物品を提供する。
Further, the present invention can provide various absorbent articles including such a nonwoven fabric for absorbent articles.
It is preferable that the absorbent article according to the embodiment of the present invention includes a backsheet for an absorbent article, and the first fiber layer of the backsheet for the absorbent article be disposed on a side close to clothing of a user.
Therefore, the present invention provides an absorbent article in which the first fiber layer of the backsheet for an absorbent article is disposed on the side close to the clothes of the user, and includes the backsheet for the absorbent article.
 本発明の実施形態の吸収性物品では、吸収性物品用不織布は、着衣側に第1繊維層が配置されることが好ましい。上述したように、本発明では、第1繊維層が不織布の滑らかさを確保し、第2繊維層が不織布の柔らかさ、クッション性及び嵩高性を確保する。おむつなどの吸収性物品を手にした消費者が、その手で直接触れる面は、着衣側である。着衣側が滑らかな手触りを有すると、消費者は心地よく吸収性物品を使用することができる(例えば、おむつを換えることができる)、等の優れた効果を奏し得る。 で は In the absorbent article according to the embodiment of the present invention, it is preferable that the nonwoven fabric for the absorbent article has the first fiber layer disposed on the clothing side. As described above, in the present invention, the first fiber layer secures the smoothness of the nonwoven fabric, and the second fiber layer secures the softness, cushioning property, and bulkiness of the nonwoven fabric. The side directly touched by a consumer holding an absorbent article such as a diaper is the clothes side. When the clothing side has a smooth touch, the consumer can comfortably use the absorbent article (for example, can change diapers), and can exert excellent effects.
 以下、本発明を実施例及び比較例により具体的かつ詳細に説明するが、これらの実施例は本発明の一態様にすぎず、本発明はこれらの例によって何ら限定されるものではない。 Hereinafter, the present invention will be described specifically and in detail with reference to examples and comparative examples. However, these examples are only one embodiment of the present invention, and the present invention is not limited to these examples.
 実施例及び比較例で使用した繊維とそれらの物性測定方法を示す。
 <実施例及び比較例で使用した繊維>
 繊維A:ポリエチレンテレフタレート(融点:260℃)が芯であり、高密度ポリエチレン(融点:132℃、MFR:20g/10分)が鞘であり、複合比(芯/鞘、質量比)が50/50である、繊度1.7dtex(繊維径13.8μm)、繊維長45mmの同心芯鞘型複合繊維(ダイワボウポリテック(株)製の商品名NBF(SH))
 繊維B:ポリエチレンテレフタレート(融点:260℃)が芯であり、高密度ポリエチレン(融点:132℃、MFR:19g/10分)が鞘であり、複合比(芯/鞘、質量比)が50/50である、繊度2.2dtex(繊維径15.7μm)、繊維長44mmの同心芯鞘型複合繊維(ダイワボウポリテック(株)製の商品名NBF(SH))
 繊維C:ポリエチレンテレフタレート(融点:260℃)が芯であり、高密度ポリエチレン(融点:132℃、MFR:12g/10分)が鞘であり、複合比(芯/鞘、質量比)が50/50である、繊度2.0dtex(繊維径15.0μm)、繊維長45mmの同心芯鞘型複合繊維(ダイワボウポリテック(株)製の商品名NBF(SH))
 繊維D:ポリエチレンテレフタレート(融点:260℃)が芯であり、直鎖状低密度ポリエチレン(融点:120℃、MFR:20g/10分)が鞘であり、複合比(芯/鞘、質量比)が60/40である、繊度2.0dtex(繊維径14.6μm)、繊維長45mmの同心芯鞘型複合繊維(ダイワボウポリテック(株)製の商品名NBF(SL))
 繊維E:ポリエチレンテレフタレート(融点:260℃)が芯であり、高密度ポリエチレン(融点:132℃、MFR:20g/10分)が鞘であり、複合比(芯/鞘、質量比が55/45である、繊度3.3dtex(繊維径18.8μm)、繊維長51mm、偏心率25%の偏心芯鞘型複合繊維(ダイワボウポリテック(株)製の商品名NBF(SH)V)
 繊維F:平均繊維長が35mm(繊維長10~60mm)であり、平均繊度が2.5dtexであるコットン(丸三産業(株)製の商品名MSD)
 繊維G:ポリエチレンテレフタレート(融点:260℃)が芯であり、高密度ポリエチレン(融点:132℃、MFR:12g/10分)が鞘であり、複合比(芯/鞘、質量比)が50/50である、繊度3.3dtex(繊維径19.2μm)、繊維長51mmの同心芯鞘型複合繊維(ダイワボウポリテック(株)製の商品名NBF(SH))
 繊維H:ポリエチレンテレフタレート(融点:260℃)が芯であり、中密度ポリエチレン(融点:125℃、MFR:19g/10分)が鞘であり、複合比(芯/鞘、質量比)が50/50である、繊度2.3dtex(繊維径16.0μm)、繊維長45mmの同心芯鞘型複合繊維
The fibers used in Examples and Comparative Examples and methods for measuring their physical properties are shown.
<Fibers used in Examples and Comparative Examples>
Fiber A: polyethylene terephthalate (melting point: 260 ° C.) as a core, high-density polyethylene (melting point: 132 ° C., MFR: 20 g / 10 min) as a sheath, and a composite ratio (core / sheath, mass ratio) of 50 / Concentric core-sheath type conjugate fiber having a fineness of 1.7 dtex (fiber diameter 13.8 μm) and a fiber length of 45 mm, which is 50 (trade name NBF (SH) manufactured by Daiwabo Polytech Co., Ltd.)
Fiber B: polyethylene terephthalate (melting point: 260 ° C.) as a core, high-density polyethylene (melting point: 132 ° C., MFR: 19 g / 10 min) as a sheath, and a composite ratio (core / sheath, mass ratio) of 50 / Concentric core-sheath type composite fiber having a fineness of 2.2 dtex (fiber diameter 15.7 μm) and a fiber length of 44 mm (NBF (SH) manufactured by Daiwabo Polytech Co., Ltd.) of 50
Fiber C: polyethylene terephthalate (melting point: 260 ° C.) as a core, high-density polyethylene (melting point: 132 ° C., MFR: 12 g / 10 min) as a sheath, and a composite ratio (core / sheath, mass ratio) of 50 / Concentric core-sheath type conjugate fiber having a fineness of 2.0 dtex (fiber diameter 15.0 μm) and a fiber length of 45 mm (trade name: NBF (SH) manufactured by Daiwabo Polytech Co., Ltd.) having a fiber size of 50
Fiber D: polyethylene terephthalate (melting point: 260 ° C.) as the core, linear low density polyethylene (melting point: 120 ° C., MFR: 20 g / 10 min) as the sheath, composite ratio (core / sheath, mass ratio) Is 60/40, a concentric core-sheath composite fiber having a fineness of 2.0 dtex (fiber diameter 14.6 μm) and a fiber length of 45 mm (trade name NBF (SL) manufactured by Daiwabo Polytech Co., Ltd.)
Fiber E: polyethylene terephthalate (melting point: 260 ° C.) as the core, high-density polyethylene (melting point: 132 ° C., MFR: 20 g / 10 min) as the sheath, composite ratio (core / sheath, mass ratio 55/45) Eccentric core-sheath type composite fiber with a fineness of 3.3 dtex (fiber diameter 18.8 μm), a fiber length of 51 mm and an eccentricity of 25% (trade name NBF (SH) V manufactured by Daiwabo Polytech Co., Ltd.)
Fiber F: Cotton having an average fiber length of 35 mm (fiber length 10 to 60 mm) and an average fineness of 2.5 dtex (trade name MSD manufactured by Marusan Sangyo Co., Ltd.)
Fiber G: polyethylene terephthalate (melting point: 260 ° C.) as a core, high-density polyethylene (melting point: 132 ° C., MFR: 12 g / 10 min) as a sheath, and a composite ratio (core / sheath, mass ratio) of 50 / Concentric core-sheath composite fiber (fineness: 3.3 dtex (fiber diameter: 19.2 μm), fiber length: 51 mm, trade name: NBF (SH) manufactured by Daiwabo Polytech Co., Ltd.)
Fiber H: polyethylene terephthalate (melting point: 260 ° C.) as a core, medium density polyethylene (melting point: 125 ° C., MFR: 19 g / 10 min) as a sheath, and a composite ratio (core / sheath, mass ratio) of 50 / Concentric core-sheath composite fiber with a fineness of 2.3 dtex (fiber diameter 16.0 μm) and a fiber length of 45 mm, which is 50
 <メルトフローレート(MFR)の測定>
 芯鞘型複合繊維の鞘成分を構成するポリエチレン樹脂について、JIS K 7210-1に基づいて、測定温度190℃、荷重21.18Nの条件下で測定した。
<Measurement of melt flow rate (MFR)>
The polyethylene resin constituting the sheath component of the core-sheath type composite fiber was measured under the conditions of a measurement temperature of 190 ° C. and a load of 21.18 N based on JIS K7210-1.
 <鞘成分の融解熱ΔHの測定>
 実施例及び比較例に用いた、第1芯鞘型複合繊維及び第2芯鞘型複合繊維の鞘成分について、JIS K 7122(1987)に基づいて示差走査熱量測定(DSC)を行い、融解熱ΔHを求めた。DSCは、示差走査熱量計(セイコーインスツル 製、商品名「EXSTAR6000/DSC6200」)を用いて測定した。繊維のサンプル量を3.0mgとして、10℃/minの昇温スピードで常温から300℃まで昇温して、繊維を融解させた後、10℃/minの降温スピードで20℃まで降温して、再度10℃/minの昇温スピードで昇温させて行った。鞘成分の融解熱ΔHは、再度昇温させた時の融解ピークから求めた。再度昇温させた時の融解ピークであれば、不織布製造時の熱接着を経た後において、鞘成分が有する融解熱に近いと考えられる。なお、本明細書において鞘成分の融解熱ΔHは、鞘成分の質量当たりの融解熱ΔHをいう。
<Measurement of heat of fusion ΔH of sheath component>
Differential scanning calorimetry (DSC) was performed on the sheath components of the first sheath-core composite fiber and the second sheath-core composite fiber used in Examples and Comparative Examples based on JIS K 7122 (1987), and the heat of fusion was measured. ΔH was determined. DSC was measured using a differential scanning calorimeter (trade name “EXSTAR6000 / DSC6200” manufactured by Seiko Instruments Inc.). The sample amount of the fiber was 3.0 mg, the temperature was raised from room temperature to 300 ° C. at a rate of 10 ° C./min to melt the fiber, and then the temperature was lowered to 20 ° C. at a rate of 10 ° C./min. Then, the temperature was increased again at a temperature increasing speed of 10 ° C./min. The heat of fusion ΔH of the sheath component was determined from the melting peak when the temperature was raised again. If the melting peak is reached when the temperature is raised again, it is considered that the temperature is close to the heat of fusion of the sheath component after the thermal bonding during the production of the nonwoven fabric. In this specification, the heat of fusion ΔH of the sheath component refers to the heat of fusion ΔH per mass of the sheath component.
 繊維A~繊維Hについて、上述の方法によって測定された、鞘成分の融解熱ΔHは以下の通りであった。
 繊維A:176.4J/g
 繊維B:175.6J/g
 繊維C:186.0J/g
 繊維D:98.8J/g
 繊維E:178.3J/g
 繊維G:171.6J/g
 繊維H:133.8J/g
Regarding the fibers A to H, the heat of fusion ΔH of the sheath component measured by the method described above was as follows.
Fiber A: 176.4 J / g
Fiber B: 175.6 J / g
Fiber C: 186.0 J / g
Fiber D: 98.8 J / g
Fiber E: 178.3 J / g
Fiber G: 171.6 J / g
Fiber H: 133.8 J / g
 (実施例1の不織布の製造)
 第1芯鞘型複合繊維として繊維Aを用いて、パラレルカード機を用いて、第1繊維層となる第1繊維ウェブを作製した。第1繊維ウェブの狙い目付は10g/mとした。
 第2芯鞘型複合繊維として繊維Bを用いて、繊維Bを91質量%と、繊維Fを9質量%とを混綿し、パラレルカード機を用いて、第2繊維層となる第2繊維ウェブを作製した。第2繊維ウェブの狙い目付は15g/mとした。
 得られた第1繊維ウェブと第2繊維ウェブとを重ね合わせて積層繊維ウェブを作製し、この積層繊維ウェブを、温度135℃に設定した熱風貫通式熱処理機にて、12秒間熱処理し、第1繊維ウェブおよび第2繊維ウェブそれぞれに含まれる第1芯鞘型複合繊維および第2芯鞘型複合繊維のポリエチレン樹脂成分により繊維同士を接着させて、第1繊維層と第2繊維層とからなる不織布を得た。なお、実際に製造される不織布の目付は、必ずしも狙い目付どおりとはならず誤差を有するため、幾つかの実施例および比較例については、表1において、実際に得られた不織布の目付を記載している。
(Production of the nonwoven fabric of Example 1)
Using a fiber A as the first core-sheath composite fiber, a first fiber web to be a first fiber layer was produced using a parallel card machine. The target basis weight of the first fiber web was 10 g / m 2 .
Using fiber B as the second core-sheath composite fiber, 91% by mass of fiber B and 9% by mass of fiber F are mixed, and the second fiber web to be the second fiber layer is formed by using a parallel card machine. Was prepared. The target basis weight of the second fiber web was 15 g / m 2 .
The obtained first fiber web and second fiber web are superimposed to produce a laminated fiber web, and the laminated fiber web is heat-treated for 12 seconds by a hot air penetration heat treatment machine set at a temperature of 135 ° C. The fibers are adhered to each other by a polyethylene resin component of the first core-sheath type conjugate fiber and the second core-sheath type conjugate fiber contained in each of the first fiber web and the second fiber web, so that the first fiber layer and the second fiber layer are separated from each other. Was obtained. In addition, since the weight of the actually manufactured nonwoven fabric is not always as intended and has an error, the weight of the actually obtained nonwoven fabric is described in Table 1 for some examples and comparative examples. are doing.
 (実施例2の不織布の製造)
 第2芯鞘型複合繊維として繊維Cを用いたこと以外は、実施例1に記載の方法と同様の方法を用いて、実施例2の不織布を得た。
(Production of the nonwoven fabric of Example 2)
A nonwoven fabric of Example 2 was obtained using the same method as that described in Example 1 except that the fiber C was used as the second core-sheath type composite fiber.
 (比較例1の不織布の製造)
 第2芯鞘型複合繊維として繊維Dを用いたこと以外は、実施例1に記載の方法と同様の方法を用いて、比較例1の不織布を得た。
(Production of the nonwoven fabric of Comparative Example 1)
A nonwoven fabric of Comparative Example 1 was obtained using the same method as that described in Example 1 except that the fiber D was used as the second core-sheath type composite fiber.
 (比較例2の不織布の製造)
 実施例2において、第1芯鞘型複合繊維として繊維Cを50質量%と繊維Eを50質量%とを用いて、比較例2の不織布を得た。尚、比較例2の第2芯鞘型複合繊維の繊度として、繊維Cの繊度と繊維Eの繊度の質量平均値である、(2.0+3.3)/2=2.65dtexを使用した。
(Production of the nonwoven fabric of Comparative Example 2)
In Example 2, a nonwoven fabric of Comparative Example 2 was obtained using 50% by mass of fiber C and 50% by mass of fiber E as the first core-sheath type composite fiber. In addition, (2.0 + 3.3) /2=2.65 dtex, which is a mass average value of the fineness of the fiber C and the fineness of the fiber E, was used as the fineness of the second core-sheath composite fiber of Comparative Example 2.
 (実施例3の不織布の製造)
 第1繊維層の狙い目付を12.5g/mとし、第2繊維層の狙い目付を12.5g/mとしたこと以外は、実施例2に記載の方法と同様の方法を用いて、実施例3の不織布を得た。
(Production of nonwoven fabric of Example 3)
A method similar to the method described in Example 2 was used, except that the target weight of the first fiber layer was 12.5 g / m 2 and the target weight of the second fiber layer was 12.5 g / m 2. Thus, a nonwoven fabric of Example 3 was obtained.
 (実施例4の不織布の製造)
 第1繊維層の狙い目付を7g/mとし、第2繊維層の狙い目付を18g/mとしたこと以外は、実施例2に記載の方法と同様の方法を用いて、実施例4の不織布を得た。
(Production of the nonwoven fabric of Example 4)
Example 4 was repeated using the same method as described in Example 2 except that the target weight of the first fiber layer was 7 g / m 2 and the target weight of the second fiber layer was 18 g / m 2. Was obtained.
 (実施例5の不織布の製造)
 第1芯鞘型複合繊維として繊維Cを用い、第2芯鞘型複合繊維として繊維Gを用いたこと以外は、実施例1に記載の方法と同様の方法を用いて、実施例5の不織布を得た。
(Production of nonwoven fabric of Example 5)
The nonwoven fabric of Example 5 was produced using the same method as that described in Example 1 except that fiber C was used as the first core-sheath composite fiber and fiber G was used as the second core-sheath composite fiber. Got.
 (実施例6の不織布の製造)
 第2芯鞘型複合繊維として繊維Hを用いたこと以外は、実施例1に記載の方法と同様の方法を用いて、実施例6の不織布を得た。
(Production of the nonwoven fabric of Example 6)
A nonwoven fabric of Example 6 was obtained using the same method as that described in Example 1 except that the fiber H was used as the second core-sheath type composite fiber.
 (実施例7の不織布の製造)
 繊維Cを80質量%と、繊維Fを20質量%とを混綿したこと以外は、実施例2に記載の方法と同様の方法を用いて、実施例7の不織布を得た。
(Production of the nonwoven fabric of Example 7)
A nonwoven fabric of Example 7 was obtained using the same method as that described in Example 2, except that 80% by mass of the fiber C and 20% by mass of the fiber F were mixed.
 (比較例3の不織布の製造)
 第1芯鞘型複合繊維として繊維Gを用い、第2芯鞘型複合繊維として繊維Gを用いたこと以外は、実施例1に記載の方法と同様の方法を用いて、比較例3の不織布を得た。
(Production of the nonwoven fabric of Comparative Example 3)
The nonwoven fabric of Comparative Example 3 was produced using the same method as that described in Example 1 except that fiber G was used as the first core-sheath composite fiber and fiber G was used as the second core-sheath composite fiber. Got.
 (比較例4の不織布の製造)
 第2芯鞘型複合繊維として繊維Gを用いたこと以外は、実施例1に記載の方法と同様の方法を用いて、比較例4の不織布を得た。
(Production of the nonwoven fabric of Comparative Example 4)
A nonwoven fabric of Comparative Example 4 was obtained using the same method as that described in Example 1 except that the fiber G was used as the second core-sheath type composite fiber.
 実施例1~7、比較例1~4の不織布について、厚さ、比容積、強伸度、剛軟度、触感(滑らかさ)、触感(柔らかさ)、毛羽立ち性を測定した。それらの結果を表1~3に示す。なお、これらの測定方法および評価方法を以下に示す。 不 織布 The nonwoven fabrics of Examples 1 to 7 and Comparative Examples 1 to 4 were measured for thickness, specific volume, strength and elongation, flexibility, touch (smoothness), touch (softness), and fluffiness. The results are shown in Tables 1 to 3. In addition, these measuring methods and evaluation methods are shown below.
 <不織布の厚さ、比容積の測定>
 不織布(不織布サンプルを含む)の厚さは、厚み測定機((株)大栄科学精器製作所製の商品名 THICKNESS GAUGE モデル CR-60A)を用い、不織布に294Paの荷重を加えた状態で測定した。
 比容積は目付と厚さから計算によって求めた。
<Measurement of nonwoven fabric thickness and specific volume>
The thickness of the nonwoven fabric (including the nonwoven fabric sample) was measured using a thickness measuring machine (trade name: THICKNESS GAUGE model CR-60A manufactured by Daiei Kagaku Seiki Seisaku-sho, Ltd.) with a load of 294 Pa applied to the nonwoven fabric. .
The specific volume was determined by calculation from the basis weight and the thickness.
 <不織布の引張強さ、伸び率、10%伸長時応力の測定>
 JIS L 1913(2010)1096 6.312.1 A法(ストリップ法)に準じて、定速緊張形引張試験機を用いて、試料片の幅5cm、つかみ間隔10cm、引張速度30±2cm/分の条件で引張試験に付し、切断時の荷重値(引張強さ)、伸び率、及び10%伸長時応力を測定した。引張試験は、不織布の縦方向(MD方向)および横方向(CD方向)を引張方向として行った。いずれの値についても、3点の試料について測定して、その平均値を示した。
<Measurement of tensile strength, elongation, and stress at 10% elongation of nonwoven fabric>
According to JIS L 1913 (2010) 1096 6.312.1 A method (strip method), using a constant-speed tension type tensile tester, the width of a sample piece is 5 cm, the grip interval is 10 cm, and the tensile speed is 30 ± 2 cm / min. , A load value (tensile strength), an elongation, and a stress at 10% elongation at the time of cutting were measured. The tensile test was performed with the longitudinal direction (MD direction) and the lateral direction (CD direction) of the nonwoven fabric as the tensile direction. Each value was measured for three samples, and the average value was shown.
 <剛軟度の測定>
 不織布の剛軟度は、JIS L 1096(2010) 8.21.5 E法(ハンドルオメータ法)に準じて測定した。具体的には、次の手順で測定した。
 MD方向×CD方向が20cm×20cmの試料片を試料台の上に、試料片の測定方向がスロット(隙間幅10mm)と直角になるように置く。
 次に、試料台の表面から8mmまで下がるように調整されたペネトレータのブレードを下降させ、試料片を押し込んだとき、いずれか一方の辺から6.7cm(試料片の幅の1/3)の位置で、MD(縦)方向及びCD(横)方向それぞれ表裏異なる個所(合計4箇所)について、押し込みに対する抵抗値を読み取る。抵抗値として、マイクロアンメータの示す最高値(cN)を読み取る。MD方向の2辺の最高値の合計値を求めてMD方向の剛軟度(cN)とし、CD方向の2辺の最高値の合計値を求めてCD方向の剛軟度(cN)とする。また、MD方向の剛軟度とCD方向の剛軟度の合計値を、当該不織布全体の剛軟度(cN)とする。なお各辺の最高値は、3回測定を行った平均値とする。
<Measurement of rigidity>
The rigidity of the nonwoven fabric was measured according to JIS L 1096 (2010) 8.21.5 E method (handle ometer method). Specifically, it measured by the following procedures.
A sample piece having a size of 20 cm × 20 cm in the MD direction × CD direction is placed on the sample table so that the measurement direction of the sample piece is perpendicular to the slot (gap width: 10 mm).
Next, the blade of the penetrator adjusted so as to be lowered to 8 mm from the surface of the sample table is lowered, and when the sample piece is pushed in, 6.7 cm (1 / of the width of the sample piece) from one of the sides is obtained. At the position, the resistance value against the pressing in is read at different positions (total of four positions) in the MD (vertical) direction and the CD (horizontal) direction, respectively. The highest value (cN) indicated by the microammeter is read as the resistance value. The sum of the maximum values of the two sides in the MD direction is obtained as the bending stiffness (cN) in the MD direction, and the sum of the maximum values of the two sides in the CD direction is obtained as the bending stiffness (cN) in the CD direction. . The total value of the bending resistance in the MD direction and the bending resistance in the CD direction is defined as the bending resistance (cN) of the entire nonwoven fabric. Note that the maximum value of each side is an average value obtained by performing three measurements.
 <触感(滑らかさ、柔らかさ)の測定>
 12名のパネラーによる、官能評価を行った。官能評価は以下の5段階の基準に沿って各パネラーが評価を与え、12名の評価の平均値を算出した。
 滑らかさの官能評価基準
 5:非常に滑らかである
 4:滑らかである
 3:普通
 2:少しざらつく
 1:ざらつく
 柔らかさの官能評価基準
 5:非常に柔らかである
 4:柔らかである
 3:普通
 2:少し硬い
 1:硬い
<Measurement of tactile sensation (smoothness, softness)>
Sensory evaluation was performed by 12 panelists. The sensory evaluation was evaluated by each panelist according to the following five-point criteria, and the average value of the evaluations of 12 persons was calculated.
Smoothness sensory evaluation criteria 5: Very smooth 4: Smooth 3: Normal 2: Slightly rough 1: Rough Softness sensory evaluation criteria 5: Very soft 4: Soft 3: Normal 2 : A little hard 1: Hard
 <毛羽立ち性の評価>
 マーチンデール毛羽試験機(James Heal社製、商品名「Martindale Abrasion and Pilling Tester No.1309」)を用いて摩擦テスト(Abrasion Test)を行った。
 実施例、比較例の不織布について2枚のサンプル(直径140mm及び直径38mmを1枚ずつ)を用意した。摩擦テーブル(Abrading Table)に直径140mmのフェルトを設置し、SM25摩擦布(SM25 Abrasice Cloth)の代わりに直径140mmのサンプルを積層してクランピングリング(Clamp Ring)でサンプルを固定した。次にサンプルホルダー(Sample Holder)に直径38mmのサンプルと直径38mmのポリウレタンを設置し、サンプルホルダーにローディングウェイト(Loading Weight)を設置せずにサンプルホルダーをテーブル(Abrading Tables)に設置した。なお、2枚のサンプルは、第1繊維層同士が接触するように試験機に設置した。摩擦回数を100回とし、モーションを60.5mmリサージュ(60.5mm Lissajous motion)に設定して摩擦テストを行った。摩擦テスト後の2枚のサンプルを観察し、不織布の破れの有無を確認し、また、毛羽立ちの個数を計測した。3回(合計6枚のサンプルを用いて)摩擦テストを行った。毛羽立ちの個数については、平均値を記録した。不織布の破れは、3回のテスト中、1回のテストで観察されたら、破れ有り、1回も観察されなければ破れ無しと記録した。
<Evaluation of fluffiness>
A friction test (Abrasion Test) was performed using a Martindale fluff tester (trade name “Martindale Abrasion and Pilling Tester No. 1309” manufactured by James Heal).
Two samples (140 mm in diameter and 38 mm in diameter each) were prepared for the nonwoven fabrics of Examples and Comparative Examples. A felt having a diameter of 140 mm was placed on a friction table (Abrading Table), and a sample having a diameter of 140 mm was laminated instead of the SM25 friction cloth (SM25 Abrasice Cloth), and the sample was fixed with a clamping ring (Clamp Ring). Next, a sample having a diameter of 38 mm and polyurethane having a diameter of 38 mm were placed in a sample holder (Sample Holder), and the sample holder was placed on a table (Abrading Tables) without placing a loading weight on the sample holder. The two samples were set on a tester such that the first fiber layers were in contact with each other. A friction test was performed by setting the number of friction times to 100 and setting the motion to 60.5 mm Lissajous motion. The two samples after the friction test were observed, the presence or absence of breakage of the nonwoven fabric was confirmed, and the number of fluff was counted. Three friction tests were performed (using a total of six samples). The average value of the number of fluffs was recorded. A break in the nonwoven fabric was recorded as torn if observed in one of the three tests, and torn if none was observed.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003

 実施例1~7の不織布は、第1繊維層が、第1芯鞘型複合繊維を含み、第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、前記第1芯鞘型複合繊維の繊度F1と前記第2芯鞘型複合繊維の繊度F2との差(F2-F1)が、0.1dtex以上、1.5dtex以下であり、下記(i)及び(ii)の少なくともいずれかを満たす。
 (i)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
 (ii)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
 そのため、実施例1~7の不織布は、優れた不織布強力を有しながら、滑らかで柔らかな触感を示す。更に、実施例1~7の不織布は、毛羽立ち及び不織布の破れが少ない。
In the nonwoven fabrics of Examples 1 to 7, the first fiber layer contains the first core-sheath composite fiber, the second fiber layer contains the second core-sheath composite fiber and cotton, The fineness of the conjugate fiber is smaller than the fineness of the second sheath-core composite fiber, and the difference between the fineness F1 of the first sheath-core composite fiber and the fineness F2 of the second sheath-core composite fiber (F2-F1) Is not less than 0.1 dtex and not more than 1.5 dtex, and satisfies at least one of the following (i) and (ii).
(I) The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ΔH of the sheath component of the first sheath-core composite fiber is 130 J / g. The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
(Ii) The sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
Therefore, the nonwoven fabrics of Examples 1 to 7 exhibit a smooth and soft touch while having excellent nonwoven fabric strength. Further, the nonwoven fabrics of Examples 1 to 7 have little fuzz and tear of the nonwoven fabric.
 また、実施例1~7の不織布は、第1繊維層が、第1芯鞘型複合繊維を含み、第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、前記第1芯鞘型複合繊維の繊度F1と前記第2芯鞘型複合繊維の繊度F2との比(F1/F2)が、0.55以上であり、1より小さく、下記(i)及び(ii)の少なくともいずれかを満たす。
 (i)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である。
 (ii)前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む。
 そのため、実施例1~7の不織布は、優れた不織布強力を有しながら、滑らかで柔らかな触感を示す。更に、実施例1~7の不織布は、毛羽立ち及び不織布の破れが少ない。
Further, in the nonwoven fabrics of Examples 1 to 7, the first fiber layer contains the first core-sheath type composite fiber, the second fiber layer contains the second core-sheath type composite fiber and cotton, The fineness of the sheath-type composite fiber is smaller than the fineness of the second core-sheath type composite fiber, and the ratio (F1 / F1) between the fineness F1 of the first core-sheath type composite fiber and the fineness F2 of the second core-sheath type composite fiber F2) is 0.55 or more, smaller than 1, and satisfies at least one of the following (i) and (ii).
(I) The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene, and the heat of fusion ΔH of the sheath component of the first sheath-core composite fiber is 130 J / g. The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more.
(Ii) The sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene.
Therefore, the nonwoven fabrics of Examples 1 to 7 exhibit a smooth and soft touch while having excellent nonwoven fabric strength. Further, the nonwoven fabrics of Examples 1 to 7 have little fuzz and tear of the nonwoven fabric.
 これに対し、比較例1の不織布は、第1芯鞘型複合繊維の鞘成分及び第2芯鞘型複合繊維の鞘成分の少なくとも一方の融解熱ΔHが130J/g未満である。又は、比較例1の不織布は、第1芯鞘型複合繊維の鞘成分および第2芯鞘型複合繊維の鞘成分の少なくとも一方が高密度ポリエチレンでない。そのため、比較例1の不織布は、優れた不織布強力を有しながら、滑らかで柔らかな触感を示すということもない。更に、比較例1の不織布は、毛羽立ちが多く、不織布に破れを生ずる。 On the other hand, in the nonwoven fabric of Comparative Example 1, the heat of fusion ΔH of at least one of the sheath component of the first core-sheath composite fiber and the sheath component of the second core-sheath composite fiber is less than 130 J / g. Alternatively, in the nonwoven fabric of Comparative Example 1, at least one of the sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber is not high-density polyethylene. Therefore, the nonwoven fabric of Comparative Example 1 does not exhibit a smooth and soft touch while having excellent nonwoven fabric strength. Furthermore, the nonwoven fabric of Comparative Example 1 has many fluffs, and the nonwoven fabric is broken.
 また比較例2の不織布は、第1芯鞘型複合繊維の繊度が第2芯鞘型複合繊維の繊度よりも小さくない。そのため、比較例2の不織布は、滑らかで柔らかな触感を示すということもない。
 また比較例2の不織布は、嵩高性のある繊維(繊維E)を使用したが、滑らかなで柔らかな触感を示すということもなく、また、毛羽立ちは少ないものの、嵩高性のある繊維を使用したことで、不織布の破れが生ずる。
In the nonwoven fabric of Comparative Example 2, the fineness of the first core-sheath composite fiber is not smaller than the fineness of the second core-sheath composite fiber. Therefore, the nonwoven fabric of Comparative Example 2 does not exhibit a smooth and soft touch.
The nonwoven fabric of Comparative Example 2 used bulky fiber (fiber E), but did not show a smooth and soft touch, and used a bulky fiber with less fuzz. As a result, the nonwoven fabric is broken.
 比較例3の不織布は、第1芯鞘型複合繊維の繊度が第2芯鞘型複合繊維の繊度と同一である。そのため、比較例3の不織布は、触感が十分ではない。 不 織布 In the nonwoven fabric of Comparative Example 3, the fineness of the first core-sheath composite fiber is the same as that of the second sheath-core composite fiber. Therefore, the nonwoven fabric of Comparative Example 3 does not have a sufficient tactile sensation.
 比較例4の不織布は、第1芯鞘型複合繊維の繊度と第2芯鞘型複合繊維の繊度との差(F2-F1)が、1.6dtexである。更に、第1芯鞘型複合繊維の繊度と第2芯鞘型複合繊維の繊度との比(F1/F2)が、0.52である。そのため、比較例4の不織布は、毛羽立ちが多く、不織布に破れを生じる。 不 織布 In the nonwoven fabric of Comparative Example 4, the difference (F2-F1) between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 1.6 dtex. Further, the ratio (F1 / F2) of the fineness of the first core-sheath composite fiber to the fineness of the second core-sheath composite fiber is 0.52. Therefore, the nonwoven fabric of Comparative Example 4 has a lot of fluff and breaks the nonwoven fabric.
 実施例2~4を比較すると、不織布の柔らかさに関して実施例2及び4の方が実施例3よりも少し優位であった。実施例2及び4は第1繊維層の目付が第2繊維層の目付よりも小さいため、不織布の柔らかさが向上していると推測される。 す る と Comparing Examples 2 to 4, Examples 2 and 4 were slightly superior to Example 3 in softness of the nonwoven fabric. In Examples 2 and 4, since the basis weight of the first fiber layer is smaller than the basis weight of the second fiber layer, it is assumed that the softness of the nonwoven fabric is improved.
 本発明の実施形態の吸収性物品用不織布は、良好な触感を有し、かつ、毛羽立ちと不織布の破れを少なくすることができ、バックシートとして好適に使用することができる。

 関連出願
 本出願は、2018年6月27日に日本国でされた出願番号2018-122291を基礎出願とするパリ条約第4条に基づく優先権を主張する。この基礎出願の内容は、参照することによって、本明細書に組み込まれる。
The nonwoven fabric for an absorbent article according to the embodiment of the present invention has a good tactile sensation, can reduce fluff and tear of the nonwoven fabric, and can be suitably used as a back sheet.

Related Application This application claims priority based on Article 4 of the Paris Convention based on Japanese Patent Application No. 2018-122291 filed on June 27, 2018 in Japan. The contents of this basic application are incorporated herein by reference.

Claims (23)

  1.  第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
     前記第1繊維層が、第1芯鞘型複合繊維を含み、
     前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差が、0.1dtex以上1.5dtex以下であり、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
     前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
     前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である、
    吸収性物品用不織布。
    A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
    The first fiber layer includes a first sheath-core composite fiber,
    The second fiber layer includes a second sheath-core composite fiber and cotton,
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The difference between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 0.1 dtex or more and 1.5 dtex or less,
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
    The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
    The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more;
    Nonwoven fabric for absorbent articles.
  2.  第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
     前記第1繊維層が、第1芯鞘型複合繊維を含み、
     前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差が、0.1dtex以上1.5dtex以下であり、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む、
    吸収性物品用不織布。
    A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
    The first fiber layer includes a first sheath-core composite fiber,
    The second fiber layer includes a second sheath-core composite fiber and cotton,
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The difference between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 0.1 dtex or more and 1.5 dtex or less,
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene,
    Nonwoven fabric for absorbent articles.
  3.  第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
     前記第1繊維層が、第1芯鞘型複合繊維を含み、
     前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との比が、0.55以上であり、1より小さく、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
     前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
     前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である、
    吸収性物品用不織布。
    A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
    The first fiber layer includes a first sheath-core composite fiber,
    The second fiber layer includes a second sheath-core composite fiber and cotton,
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The ratio between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
    The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
    The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more;
    Nonwoven fabric for absorbent articles.
  4.  第1繊維層と、前記第1繊維層の一方の主表面に位置する第2繊維層とを含む不織布であって、
     前記第1繊維層が、第1芯鞘型複合繊維を含み、
     前記第2繊維層が、第2芯鞘型複合繊維とコットンとを含み、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との比が、0.55以上であり、1より小さく、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む、
    吸収性物品用不織布。
    A nonwoven fabric comprising a first fiber layer and a second fiber layer located on one main surface of the first fiber layer,
    The first fiber layer includes a first sheath-core composite fiber,
    The second fiber layer includes a second sheath-core composite fiber and cotton,
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The ratio between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene,
    Nonwoven fabric for absorbent articles.
  5.  前記第1芯鞘型複合繊維の繊度が、1.0dtex以上2.0dtex以下である、請求項1~4のいずれか1項に記載の吸収性物品用不織布。 (5) The nonwoven fabric for an absorbent article according to any one of (1) to (4), wherein the fineness of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less.
  6.  前記第2芯鞘型複合繊維の繊度が、1.7dtex以上2.6dtex以下である、請求項1~5のいずれか1項に記載の吸収性物品用不織布。 (6) The nonwoven fabric for an absorbent article according to any one of (1) to (5), wherein the fineness of the second core-sheath type composite fiber is 1.7 dtex or more and 2.6 dtex or less.
  7.  前記第1芯鞘型複合繊維の鞘成分のメルトフローレートが15g/10分以上である、請求項1~6のいずれか1項に記載の吸収性物品用不織布。 The nonwoven fabric for an absorbent article according to any one of claims 1 to 6, wherein the melt flow rate of the sheath component of the first core-sheath composite fiber is 15 g / 10 minutes or more.
  8.  前記第2芯鞘型複合繊維の鞘成分のメルトフローレートが10g/10分以上である、請求項1~7のいずれか1項に記載の吸収性物品用不織布。 The nonwoven fabric for an absorbent article according to any one of claims 1 to 7, wherein the melt flow rate of the sheath component of the second core-sheath composite fiber is 10 g / 10 minutes or more.
  9.  前記第2繊維層が、前記第2繊維層の総質量を基準として、前記コットンを1質量%以上30質量%以下の割合で含む、請求項1~8のいずれか1項に記載の吸収性物品用不織布。 The absorbent according to any one of claims 1 to 8, wherein the second fiber layer contains the cotton in a ratio of 1% by mass or more and 30% by mass or less based on the total mass of the second fiber layer. Non-woven fabric for goods.
  10.  前記不織布の剛軟度が、16.0cN以下である、請求項1~9のいずれか1項に記載の吸収性物品用不織布。 不 織布 The nonwoven fabric for an absorbent article according to any one of claims 1 to 9, wherein the softness of the nonwoven fabric is 16.0 cN or less.
  11.  前記第1繊維層の目付が前記第2繊維層の目付よりも小さい、請求項1~10のいずれか1項に記載の吸収性物品用不織布。 The nonwoven fabric for an absorbent article according to any one of claims 1 to 10, wherein the basis weight of the first fiber layer is smaller than the basis weight of the second fiber layer.
  12.  請求項1~11のいずれか1項に記載の吸収物品用不織布を含む、吸収性物品用バックシート。 A backsheet for an absorbent article, comprising the nonwoven fabric for an absorbent article according to any one of claims 1 to 11.
  13.  請求項12に記載の吸収性物品用バックシートの前記第1繊維層が、使用者の着衣に近い側に配置されて、請求項12に記載の吸収性物品用バックシートが含まれる吸収性物品。 An absorbent article comprising the backsheet for an absorbent article according to claim 12, wherein the first fiber layer of the backsheet for an absorbent article according to claim 12 is arranged on a side near a user's clothes. .
  14.  第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
     第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
     前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
    を含む吸収性物品用不織布の製造方法であって、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差が、0.1dtex以上1.5dtex以下であり、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
     前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
     前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である、
    吸収性物品用不織布の製造方法。
    Producing a first fibrous web comprising a first core-sheath composite fiber;
    Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
    Superimposing and integrating the first fiber web and the second fiber web,
    A method for producing a nonwoven fabric for absorbent articles, comprising:
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The difference between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 0.1 dtex or more and 1.5 dtex or less,
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
    The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
    The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more;
    A method for producing a nonwoven fabric for an absorbent article.
  15.  第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
     第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
     前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
    を含む吸収性物品用不織布の製造方法であって、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との差が、0.1dtex以上1.5dtex以下であり、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む、
    吸収性物品用不織布の製造方法。
    Producing a first fibrous web comprising a first core-sheath composite fiber;
    Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
    Superimposing and integrating the first fiber web and the second fiber web,
    A method for producing a nonwoven fabric for absorbent articles, comprising:
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The difference between the fineness of the first core-sheath composite fiber and the fineness of the second core-sheath composite fiber is 0.1 dtex or more and 1.5 dtex or less,
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene,
    A method for producing a nonwoven fabric for an absorbent article.
  16.  第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
     第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
     前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
    を含む吸収性物品用不織布の製造方法であって、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との比が、0.55以上であり、1より小さく、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分がポリエチレンを含み、
     前記第1芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上であり、
     前記第2芯鞘型複合繊維の鞘成分の融解熱ΔHが130J/g以上である、
    吸収性物品用不織布の製造方法。
    Producing a first fibrous web comprising a first core-sheath composite fiber;
    Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
    Superimposing and integrating the first fiber web and the second fiber web,
    A method for producing a nonwoven fabric for absorbent articles, comprising:
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The ratio between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber include polyethylene,
    The heat of fusion ΔH of the sheath component of the first core-sheath type composite fiber is 130 J / g or more;
    The heat of fusion ΔH of the sheath component of the second core-sheath composite fiber is 130 J / g or more;
    A method for producing a nonwoven fabric for an absorbent article.
  17.  第1芯鞘型複合繊維を含む第1繊維ウェブを作製すること、
     第2芯鞘型複合繊維とコットンとを含む第2繊維ウェブを作製すること、
     前記第1繊維ウェブと前記第2繊維ウェブとを重ね合わせて一体化すること、
    を含む吸収性物品用不織布の製造方法であって、
     前記第1芯鞘型複合繊維の繊度が前記第2芯鞘型複合繊維の繊度よりも小さく、
     前記第1芯鞘型複合繊維の繊度と前記第2芯鞘型複合繊維の繊度との比が、0.55以上であり、1より小さく、
     前記第1芯鞘型複合繊維の鞘成分および前記第2芯鞘型複合繊維の鞘成分が、両方共高密度ポリエチレン及び中密度ポリエチレンから選択される少なくとも1種を含む、
    吸収性物品用不織布の製造方法。
    Producing a first fibrous web comprising a first core-sheath composite fiber;
    Producing a second fibrous web comprising a second core-sheath composite fiber and cotton;
    Superimposing and integrating the first fiber web and the second fiber web,
    A method for producing a nonwoven fabric for absorbent articles, comprising:
    The fineness of the first sheath-core composite fiber is smaller than the fineness of the second sheath-core composite fiber,
    The ratio between the fineness of the first core-sheath type composite fiber and the fineness of the second core-sheath type composite fiber is 0.55 or more, and is smaller than 1;
    The sheath component of the first sheath-core composite fiber and the sheath component of the second sheath-core composite fiber both include at least one selected from high-density polyethylene and medium-density polyethylene,
    A method for producing a nonwoven fabric for an absorbent article.
  18.  前記第1芯鞘型複合繊維の繊度が、1.0dtex以上2.0dtex以下である、請求項14~17のいずれか1項に記載の吸収性物品用不織布の製造方法。 18. The method for producing a nonwoven fabric for an absorbent article according to any one of claims 14 to 17, wherein the fineness of the first core-sheath composite fiber is 1.0 dtex or more and 2.0 dtex or less.
  19.  前記第2芯鞘型複合繊維の繊度が、1.7dtex以上2.6dtex以下である、請求項14~18のいずれか1項に記載の吸収性物品用不織布の製造方法。 方法 The method for producing a nonwoven fabric for absorbent articles according to any one of claims 14 to 18, wherein the fineness of the second core-sheath type composite fiber is from 1.7 dtex to 2.6 dtex.
  20.  前記第1芯鞘型複合繊維の鞘成分のメルトフローレートが15g/10分以上である、請求項14~19のいずれか1項に記載の吸収性物品用不織布の製造方法。 20. The method for producing a nonwoven fabric for absorbent articles according to any one of claims 14 to 19, wherein the melt flow rate of the sheath component of the first core-sheath type conjugate fiber is 15 g / 10 minutes or more.
  21.  前記第2芯鞘型複合繊維の鞘成分のメルトフローレートが10g/10分以上である、請求項14~20のいずれか1項に記載の吸収性物品用不織布の製造方法。 The method for producing a nonwoven fabric for an absorbent article according to any one of claims 14 to 20, wherein the melt flow rate of the sheath component of the second core-sheath composite fiber is 10 g / 10 minutes or more.
  22.  前記第2繊維ウェブが、前記第2繊維ウェブの総質量を基準として、前記コットンを1質量%以上30質量%以下の割合で含む、請求項14~21のいずれか1項に記載の吸収性物品用不織布の製造方法。 The absorbent according to any one of claims 14 to 21, wherein the second fiber web contains the cotton at a ratio of 1% by mass or more and 30% by mass or less based on the total mass of the second fiber web. A method for producing a nonwoven fabric for articles.
  23.  前記第1繊維ウェブの目付が前記第2繊維ウェブの目付よりも小さい、請求項14~22のいずれか1項に記載の吸収性物品用不織布の製造方法。 The method for producing a nonwoven fabric for an absorbent article according to any one of claims 14 to 22, wherein the basis weight of the first fiber web is smaller than the basis weight of the second fiber web.
PCT/JP2019/025619 2018-06-27 2019-06-27 Nonwoven fabric for absorbent articles, back sheet for absorbent articles, absorbent article and method for producing nonwoven fabric for absorbent articles WO2020004554A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006274453A (en) * 2005-03-28 2006-10-12 Kb Seiren Ltd Nonwoven fabric having temperature-adjusting function and method for producing the same
JP2015212449A (en) * 2014-04-18 2015-11-26 ダイワボウホールディングス株式会社 Composite short fiber for absorption article, production method of the same and thermally adhered nonwoven fabric for absorption article containing the same and absorption article
JP2018051232A (en) * 2016-09-30 2018-04-05 ダイワボウホールディングス株式会社 Sheet for absorbent article

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006274453A (en) * 2005-03-28 2006-10-12 Kb Seiren Ltd Nonwoven fabric having temperature-adjusting function and method for producing the same
JP2015212449A (en) * 2014-04-18 2015-11-26 ダイワボウホールディングス株式会社 Composite short fiber for absorption article, production method of the same and thermally adhered nonwoven fabric for absorption article containing the same and absorption article
JP2018051232A (en) * 2016-09-30 2018-04-05 ダイワボウホールディングス株式会社 Sheet for absorbent article

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