WO2019235110A1

WO2019235110A1 - Exhaust gas processing device

Info

Publication number: WO2019235110A1
Application number: PCT/JP2019/017912
Authority: WO
Inventors: 通孝古林; 睦史加藤
Original assignee: 日立造船株式会社
Priority date: 2018-06-06
Filing date: 2019-04-26
Publication date: 2019-12-12
Also published as: CN112165981B; CN112165981A; JP2019209273A; JP7106357B2

Abstract

In this exhaust gas processing device (4), a collected dust and ash returning unit (44) transports collected dust and ash, which have been collected at a dust collection machine (43), along a return route (441) that is different from a flue (3), to a position (P2) between the dust collection machine (43) and a combustion chamber (2) in the flue (3). A collected dust and ash distribution unit (45) distributes the collected dust and ash, which have been collected at the dust collection machine (43), to the collected dust and ash returning unit (44) and the collected dust and ash discharge unit (47) disposed at a discharge position external to the flue (3). Concentration measurement units (481, 482) acquire measurement values for the mercury concentration within the exhaust gas. In a highly concentrated state, wherein an evaluation value that is based on the measurement values is greater than a threshold value, the distribution ratio of the collected dust and ash to the collected dust and ash discharge unit (47) by the collected dust and ash distribution unit (45) is increased from that in an ordinary state. In this manner, a return of collected dust and ash containing large amounts of mercury to the flue (3) can be suppressed, and as a result, the mercury concentration in the exhaust gas can be reduced more reliably in this exhaust gas processing device (4).

Description

Exhaust gas treatment equipment

The present invention relates to an exhaust gas treatment apparatus.

Conventionally, municipal solid waste such as municipal waste is incinerated at the waste incineration facility. The exhaust gas generated by the incineration process contains harmful substances such as dust, hydrogen chloride (HCl), sulfur oxide (SOx), nitrogen oxide (NOx), heavy metals (Pb, Hg, etc.). Therefore, a treatment for removing these harmful substances from the exhaust gas is performed by the exhaust gas treatment device, and the treated exhaust gas is discharged to the atmosphere.

For example, in the apparatus disclosed in Japanese Patent Application Laid-Open No. 2014-24052 (Document 1), a sodium-based drug is introduced into an exhaust gas flue on the bag filter inlet side, and an unreacted sodium-based drug collected by the bag filter is included. Part of the fly ash is returned to the flue gas flue on the bag filter inlet side. Thereby, a sodium-type chemical | medical agent is utilized efficiently in removal of acidic gas. Further, Patent Document 1 also discloses a method of supplying activated carbon together with a sodium-based drug to remove mercury contained in exhaust gas. In this method, activated carbon is also circulated as part of fly ash, and activated carbon is used efficiently.

Note that Japanese Patent Application Laid-Open No. 2016-97321 proposes an exhaust gas treatment device that supplies activated carbon to the exhaust gas flue at a downstream position of the dust collector. In the apparatus, activated carbon contained in the exhaust gas is collected by an activated carbon collector provided separately from the dust collector, and the collected activated carbon is supplied to the exhaust gas flue at a downstream position of the dust collector. . Japanese Patent No. 6173621 discloses a detection device that detects the amount of zero-valent atomic mercury contained in exhaust gas in a state where divalent mercury constituting the mercury compound is not reduced to atomic mercury. .

Incidentally, in the apparatus of Document 1, activated carbon that has adsorbed a large amount of mercury may be circulated as part of fly ash. There is a possibility that the mercury of the activated carbon that has adsorbed a large amount of mercury is desorbed in the exhaust gas and the concentration of mercury in the exhaust gas is increased.

The present invention is directed to an exhaust gas treatment device, and aims to reduce the mercury concentration in the exhaust gas more reliably.

An exhaust gas treatment apparatus according to the present invention includes a dust collector provided in a flue through which exhaust gas flows, and an adsorbent supply unit that supplies a mercury adsorbent to a position between the exhaust gas generation source and the dust collector in the flue. The dust collection ash return unit that transports the dust collection ash collected by the dust collector to a position between the generation source and the dust collector in the flue along a return path different from the flue A dust collection ash discharge section disposed at a discharge position outside the flue, a dust collection ash distribution section that distributes the dust collection ash to the dust collection ash return section and the dust collection ash discharge section, and the exhaust gas A concentration measuring unit for obtaining a measured value of mercury concentration in the medium; The dust ash content is increased so that the distribution ratio to the dust ash discharge section increases. And a control unit for controlling the parts.

According to the present invention, the mercury concentration in the exhaust gas can be more reliably lowered.

In one preferable mode of the present invention, when the evaluation value is larger than the threshold value, the control unit is configured so that the distribution ratio to the dust collection ash discharge unit is 100%. To control.

In another preferred embodiment of the present invention, the intake port of the concentration measurement unit is disposed on the upstream side of the adsorbent supply unit in the flue, and the evaluation value is the measurement value of the concentration measurement unit. .

In another preferred embodiment of the present invention, the exhaust gas treatment device further includes another concentration measurement unit that acquires a measurement value of the mercury concentration in the exhaust gas, and an intake port of the concentration measurement unit is provided in the flue. Arranged upstream of the dust collector, the intake of the other concentration measuring unit is disposed downstream of the dust collector in the flue, and the evaluation value is the measurement of the other concentration measuring unit. It is a difference value obtained by subtracting the measured value of the concentration measuring unit from the value.

In another preferred embodiment of the present invention, in the high concentration state, the control unit shortens the dust collection ash removal period in the dust collector from the normal state.

In another preferred embodiment of the present invention, the control unit controls the amount of the mercury adsorbent supplied to the flue by the adsorbent supply unit based on the measurement value of the concentration measurement unit.

In another preferred embodiment of the present invention, the concentration measuring unit is disposed on the upstream side of the dust collector in the flue, and measures the concentration of zero-valent mercury contained in the exhaust gas and the zero-valence contained in the exhaust gas. The total concentration of mercury and divalent mercury is selectively measured.

In another preferred embodiment of the present invention, the dust collection ash discharge unit is conveyed to the discharge position in the high concentration state with an immobilization unit that immobilizes heavy metals contained in the dust collection ash by mixing a chelating agent. A mercury removal unit that performs a mercury removal process on the dust collection ash.

In another preferred embodiment of the present invention, the mercury adsorbent is activated carbon, and the mercury adsorbent is constantly supplied to the flue while the exhaust gas flows through the flue.

In another preferred embodiment of the present invention, the exhaust gas treatment device further includes a hydrogen chloride concentration measurement unit that is disposed downstream of the dust collector and that measures a hydrogen chloride concentration of the exhaust gas, and the control unit includes the hydrogen chloride Based on the measured value of the concentration measuring unit, the amount of the dust collecting ash supplied to the flue by the dust collecting ash returning unit is controlled.

The above object and other objects, features, aspects, and advantages will become apparent from the following detailed description of the present invention with reference to the accompanying drawings.

It is a figure which shows the structure of incineration equipment. It is a figure which shows the structure of an exhaust gas processing apparatus. It is a figure which shows the flow of waste gas treatment. It is a figure which shows the flow of waste gas treatment. It is a figure which shows the other example of an adsorption agent supply part.

FIG. 1 is a diagram showing a configuration of an incineration facility 1 according to an embodiment of the present invention. The incineration facility 1 is a facility for incinerating waste such as municipal waste. The incineration facility 1 includes a combustion chamber 2, a flue 3, an exhaust gas treatment device 4, an induction fan 51, and a chimney 52. In the combustion chamber 2, combustion of garbage and combustion of combustible gas generated from the garbage are performed. The flue 3 connects the combustion chamber 2 and the chimney 52. The exhaust gas treatment device 4 and the induction fan 51 are provided in the flue 3. The induction fan 51 discharges exhaust gas (combustion gas) generated in the combustion chamber 2 to the flue 3 and guides it to the chimney 52 through the exhaust gas treatment device 4. In the incineration facility 1, the exhaust gas having the combustion chamber 2 as a generation source flows in the flue 3 from the combustion chamber 2 toward the chimney 52, and the exhaust gas treatment device 4 performs a predetermined process on the exhaust gas. The chimney 52 releases exhaust gas to the atmosphere. In FIG. 1, the flue 3 is indicated by a thick solid line.

FIG. 2 is a diagram showing a configuration of the exhaust gas treatment device 4. The exhaust gas treatment apparatus 4 includes a control unit 40, a temperature reducing tower 41, a chemical supply unit 42, a dust collector 43, a dust collection ash return unit 44, a dust collection ash distribution unit 45, and a dust collection ash discharge unit 47. , An upstream concentration measuring unit 481 and a downstream concentration measuring unit 482 are provided. The control unit 40 is responsible for overall control of the exhaust gas treatment device 4. The control unit 40 may also serve as the control unit of the incineration facility 1. In the flue 3, a temperature reducing tower 41, a chemical supply unit 42, and a dust collector 43 are sequentially provided from the combustion chamber 2 toward the chimney 52, that is, from the upstream side to the downstream side in the flow direction of the exhaust gas. Actually, a denitration device or the like may be provided between the dust collector 43 and the chimney 52.

The temperature reducing tower 41 sprays water into the exhaust gas flowing from the combustion chamber 2 to lower the temperature of the exhaust gas. The temperature of the exhaust gas discharged from the temperature reducing tower 41 is about 170 ° C., for example. The drug supply unit 42 includes an alkali storage unit 421, an adsorbent storage unit 422, a drug pumping unit 423, a drug supply line 424, and

quantitative supply units

425 and 426. One end of the medicine supply line 424 is connected to the medicine pumping unit 423, and the other end is at a position P1 between the temperature reducing tower 41 and the dust collector 43 in the flue 3 (hereinafter, referred to as “medicine supply position P1”). Connected. The chemical pumping unit 423 is a blower and sends air toward the flue 3 in the chemical supply line 424. The alkali storage unit 421 stores an alkaline chemical. As the alkaline agent, for example, powdered slaked lime (calcium hydroxide (Ca (OH) ₂ )) that is a calcium (Ca) -based agent is used. Slaked lime is a desalting and desulfurizing agent. A fixed amount supply unit 425 is attached to the lower part of the alkali storage unit 421. The fixed amount supply unit 425 is, for example, a table feeder, and extracts (cuts out) a set amount of slaked lime per unit time from the alkali storage unit 421. The fixed amount supply unit 425 is connected to the drug supply line 424, and the slaked lime taken out from the alkali storage unit 421 is supplied into the drug supply line 424.

The adsorbent storage unit 422 stores a powdery mercury adsorbent. The mercury adsorbent is, for example, activated carbon. As the mercury adsorbent, for example, an impregnated activated carbon in which iodine or sulfur is impregnated on the surface of the activated carbon may be used. A fixed amount supply unit 426 is attached to the lower part of the adsorbent storage unit 422, and a set amount of mercury adsorbent is taken out from the adsorbent storage unit 422 per unit time. The quantitative supply unit 426 is connected to the drug supply line 424, and the mercury adsorbent taken out from the adsorbent storage unit 422 is supplied into the drug supply line 424. By the chemical supply section 42 having such a configuration, slaked lime and a mercury adsorbent (hereinafter collectively referred to as “exhaust gas treatment chemical”) are supplied (injected) into the flue 3 at the chemical supply position P1. The exhaust gas treatment chemical may include other calcium-based chemicals (calcium-containing chemicals) such as dolomite hydroxide [Ca (OH) ₂ .Mg (OH) ₂ ] instead of or together with slaked lime. A sodium-based drug (sodium-containing drug) such as sodium bicarbonate (NaHCO ₃ ) may be used as the alkaline drug.

In the drug supply unit 42, an alkaline drug supply unit 427 that supplies an alkaline drug (here, slaked lime) to the drug supply position P1 is configured by the alkali storage unit 421, the drug pumping unit 423, the drug supply line 424, and the quantitative supply unit 425. Is done. Further, the adsorbent storage unit 422, the drug pumping unit 423, the drug supply line 424, and the quantitative supply unit 426 constitute an adsorbent supply unit 428 that supplies a mercury adsorbent to the drug supply position P1. The alkaline chemical supply unit 427 and the adsorbent supply unit 428 may be realized by other structures, and may be provided separately from each other.

The dust collector 43 is, for example, a filtration type, and removes fly ash contained in the exhaust gas with a filter cloth. The dust collector 43 is also called a bag filter. The exhaust gas treatment chemical (here, slaked lime and mercury adsorbent) supplied by the chemical supply unit 42 is deposited on the filter cloth. When the exhaust gas passes through the filter cloth inside the dust collector 43, the acidic gas (hydrogen chloride, sulfur oxide, etc.) contained in the exhaust gas reacts with slaked lime, and the acidic gas is removed. Further, the mercury adsorbent adsorbs mercury contained in the exhaust gas. The reaction between the acid gas and slaked lime and the adsorption of mercury in the mercury adsorbent also occur in the flue 3. The mercury adsorbent may have an effect of further adsorbing dioxins and the like contained in the exhaust gas.

In the dust collector 43, fly ash (including slaked lime, a reaction product of slaked lime and acid gas, a mercury adsorbent that adsorbs mercury, etc.) accumulated on the filter cloth is removed by backwashing operation using compressed gas. It is. In the backwashing operation, compressed gas (pulse jet) is supplied to the filter cloth from the downstream side to the upstream side in the exhaust gas flow direction. The compressed gas is, for example, compressed air. In the following description, a cycle in which the backwashing operation is performed in the dust collector 43 is referred to as a “dispensing cycle”. Also, fly ash (including exhaust gas treatment chemicals) removed from the filter cloth is called “dust collection ash”. The dust collection ash is a collected matter in the dust collector 43.

The dust collection ash distribution unit 45 includes a conveyor 451 and a gate 452. The conveyor 451 is, for example, a flight conveyor (also called a scraper conveyor). The conveyor 451 extends from below the dust collector 43 to a predetermined discharge position. The discharge position is outside the flue 3, and the dust collection ash discharge part 47 is arranged at the discharge position. The dust collection ash removed from the filter cloth of the dust collector 43 is received by the conveyor 451 below the dust collector 43 and is transported along the transport path toward the discharge position. The gate 452 is provided in the dust collection ash conveyance path in the conveyor 451. In a state where the gate 452 is closed, the dust collection ash is supplied to the dust collection ash discharge unit 47 by the conveyor 451. In a state where the gate 452 is opened, the dust collection ash is supplied to the dust collection ash return unit 44 through the gate 452. As described above, the dust collection ash distribution unit 45 distributes the dust collection ash from the dust collector 43 to the dust collection ash discharge unit 47 and the dust collection ash return unit 44 by opening and closing the gate 452. The structure of the dust collection ash distribution unit 45 may be changed as appropriate.

Below the gate 452, a dust collection ash storage unit (not shown) of the dust collection ash return unit 44 is provided. The dust collection ash supplied through the gate 452 is stored in the dust collection ash storage section. In the dust collection ash storage unit, the storage amount of the dust collection ash is acquired by a level meter. In the basic operation of the exhaust gas treatment device 4, when the amount of dust collection ash stored in the dust collection ash storage unit is less than the maximum storable amount, the gate 452 is opened and the dust collection ash is stored in the dust collection ash storage unit. Supplied. When the storage amount of the dust collection ash reaches the maximum amount, the gate 452 is closed and the dust collection ash is supplied to the dust collection ash discharge unit 47.

The dust collection ash return unit 44 includes a return path 441. The return path 441 connects the gate 452 of the dust collection ash distribution unit 45 and a position P2 between the temperature reducing tower 41 and the dust collector 43 in the flue 3 (hereinafter referred to as “dust collection ash supply position P2”). To do. In FIG. 2, the return path 441 is indicated by a thick solid line. The return path 441 is a path different from the flue 3. The dust collection ash return unit 44 conveys (returns) the dust collection ash containing the mercury adsorbent and slaked lime to the dust collection ash supply position P2 in the flue 3 along the return path 441, thereby processing the exhaust gas. In this case, both the mercury adsorbent and slaked lime can be used efficiently.

The dust collection ash discharge unit 47 includes an immobilization unit 471, a mercury removal unit 472, and a discharge distribution unit 473. The discharge distribution unit 473 distributes the dust collection ash conveyed to the discharge position to the immobilization unit 471 and the mercury removal unit 472. The structure of the discharge distribution unit 473 is the same as the structure of the dust collection ash distribution unit 45, and includes a conveyor 474 and a gate 475. In a state where the gate 475 is closed, the dust collection ash is supplied to the fixing unit 471 by the conveyor 474. In a state where the gate 475 is opened, the dust collection ash is supplied to the mercury removing unit 472 via the gate 475.

In the immobilization unit 471, a chelating agent that is a heavy metal stabilizer and dust collection ash are mixed (kneaded). Thereby, the heavy metal contained in the dust collection ash is fixed, that is, the heavy metal elution is suppressed in the dust collection ash. The mercury removing unit 472 performs a mercury removing process for volatilizing mercury contained in the dust collection ash by heating the dust collection ash. The heating temperature of the dust collection ash is, for example, 300 to 450 ° C. The mercury removing process may be performed by reducing the pressure around the dust collection ash. Volatilized mercury is collected by a mercury collecting unit (not shown). The dust collection ash after the mercury removal process is supplied to the immobilization unit 471, and the heavy metal contained in the dust collection ash is immobilized.

The upstream concentration measuring unit 481 and the downstream concentration measuring unit 482 acquire a measured value of the mercury concentration in the exhaust gas by taking in and analyzing a part of the exhaust gas flowing through the flue 3. The intake port of the upstream concentration measuring unit 481 may be anywhere between the combustion chamber 2 in the flue 3 and the chemical supply position P1, for example, between the combustion chamber 2 in the flue 3 and the temperature reducing tower 41. Be placed. The intake port of the downstream concentration measuring unit 482 is disposed between the dust collector 43 and the chimney 52 in the flue 3. In other words, in the flow direction of the exhaust gas, the upstream concentration measuring unit 481 (intake port) is disposed on the upstream side of the dust collector 43, and the downstream concentration measuring unit 482 is disposed on the downstream side of the dust collector 43. The position of the upstream concentration measuring unit 481 is also upstream of the medicine supply position P1 and the dust collection ash supply position P2. The downstream concentration measuring unit 482 may be provided in the chimney 52.

In the exhaust gas treatment device 4 of FIG. 2, the downstream concentration measuring unit 482 includes a reduction catalyst that reduces the mercury compound contained in the exhaust gas to atomic mercury, and zero-valent atomic mercury originally contained in the exhaust gas, and the mercury compound The measurement value (measurement value of the total concentration of zero-valent mercury and divalent mercury) is obtained based on the total amount with divalent mercury constituting the. That is, the downstream concentration measuring unit 482 detects both atomic mercury and mercury compounds such as soluble mercury salts.

On the other hand, the upstream concentration measuring unit 481 measures the concentration of zero-valent mercury contained in the exhaust gas flowing through the flue 3 and measures the total concentration of zero-valent mercury and divalent mercury contained in the exhaust gas. It can be done selectively. In measuring the concentration of zero-valent mercury, a measurement value is obtained based on the amount of atomic mercury contained in the exhaust gas in a state where the mercury compound contained in the exhaust gas is not reduced to atomic mercury. That is, in measuring the concentration of zero-valent mercury, the upstream concentration measurement unit 481 detects atomic mercury but does not detect mercury compounds such as soluble mercury salts. In this case, the upstream concentration measurement unit 481 can acquire the measurement value of the mercury concentration in a short time by omitting the time required to reduce the mercury compound to atomic mercury. The measured value of the zero-valent mercury concentration by the upstream concentration measuring unit 481 is, for example, the atomic mercury concentration (zero-valent mercury concentration) to the total mercury concentration (total concentration of zero-valent mercury and divalent mercury). Correction (calibration) may be performed using a correction table created by estimation.

FIG. 3A is a diagram showing the flow of exhaust gas treatment in the exhaust gas treatment device 4. In the following description, a processing example mainly using the upstream concentration measurement unit 481 will be described first, and then a processing example using a difference value derived from both the upstream concentration measurement unit 481 and the downstream concentration measurement unit 482 will be described. .

In the exhaust gas treatment in the exhaust gas treatment device 4, the upstream concentration measurement unit 481 acquires a measurement value of mercury concentration in the exhaust gas on the upstream side of the dust collector 43 (hereinafter referred to as “upstream measurement value”) (step S11). Here, it is assumed that the measured value of the zero-valent mercury concentration is acquired as the upstream measured value by the upstream concentration measuring unit 481. The upstream measurement value may be the total concentration of zero-valent mercury and divalent mercury. In the exhaust gas treatment device 4, the downstream concentration measurement unit 482 also acquires a measurement value of mercury concentration in the exhaust gas on the downstream side of the dust collector 43 (hereinafter referred to as “downstream measurement value”). The upstream measurement value and the downstream measurement value are output to the control unit 40. Actually, the upstream measurement value and the downstream measurement value are repeatedly acquired at a predetermined cycle.

Further, an exhaust gas treatment chemical containing slaked lime and a mercury adsorbent is supplied by the chemical supply unit 42 to the chemical supply position P1 (in principle, continuously). When the mercury adsorbent is activated carbon, it is preferable that the mercury adsorbent is constantly supplied to the flue 3 while the exhaust gas flows through the flue 3. In the control unit 40, when the upstream measurement value and / or the downstream measurement value is relatively high, the supply amount of the mercury adsorbent to the drug supply position P1 is increased, and the upstream measurement value and / or the downstream measurement value is relatively low. In this case, the supply amount of the mercury adsorbent to the medicine supply position P1 is decreased. The supply amount (supply amount per unit time) of the mercury adsorbent to the medicine supply position P1 is controlled by adjusting the output of the quantitative supply unit 426, for example, the number of rotations of the table in the quantitative supply unit 426 which is a table feeder. Is possible. By controlling the amount of mercury adsorbent supplied to the flue 3 by the adsorbent supply unit 428 based on the upstream measurement value acquired in a short time (for example, PI control), the mercury concentration in the exhaust gas is It can be efficiently reduced with a small amount of mercury adsorbent and in a short time.

Similarly, the amount of dust collection ash supplied to the flue 3 by the dust collection ash return unit 44 may be controlled based on the upstream measurement value and / or the downstream measurement value. In this case, the output of the quantitative supply unit provided in the dust collection ash return unit 44 is adjusted. For example, when the upstream measurement value and / or the downstream measurement value suddenly rises, the flue 3 by the dust collection ash return unit 44 is collected for the collected ash before the upstream measurement value and / or the downstream measurement value suddenly rises. It is preferable that the supply amount of the dust collection ash is increased or quantitatively supplied. In addition, when the supply amount of dust collection ash is increased, the hydrogen chloride concentration in the exhaust gas may decrease, but hydrogen chloride in the exhaust gas promotes mercury adsorption by activated carbon. From the viewpoint of carrying out, it is preferable that the supply amount of the dust collection ash is increased in a range (for example, 2 to 3 ppm) in which the hydrogen chloride concentration in the exhaust gas on the downstream side of the dust collector 43 does not extremely decrease. That is, based on the measured value of the hydrogen chloride concentration in the exhaust gas by the hydrogen chloride concentration measuring unit (not shown) arranged downstream of the dust collector 43, the dust ash returning unit 44 supplies the flue 3 with the dust collecting ash returning unit 44. It is preferable that the amount of dust collection ash is controlled. The amount of slaked lime supplied to the medicine supply position P1 can also be controlled by adjusting the output of the quantitative supply unit 425. Chlorination by the hydrogen chloride concentration measurement unit and / or the measurement unit arranged downstream of the dust collector 43 is possible. The supply amount of slaked lime (alkali chemical) may be controlled according to the measured value of the hydrogen concentration.

Also, the control unit 40 uses the upstream measurement value as the first evaluation value, and the first evaluation value is compared with a predetermined first threshold value. When the first evaluation value is equal to or less than the first threshold value, it is determined that the mercury concentration in the exhaust gas is in a normal state (step S12). In the normal state, the dust collector 43 removes the dust collection ash on the filter cloth at a predetermined removal cycle, and the dust collection ash distribution unit 45 returns the dust collection ash to the dust collection ash according to the basic operation described above. It is distributed to the part 44 and the dust collection ash discharge part 47. Moreover, the dust collection ash supplied to the dust collection ash discharge part 47 is directly supplied to the immobilization part 471, and a heavy metal is fixed using a chelating agent. In the exhaust gas treatment device 4, the first evaluation value is compared with the first threshold value every time the upstream measurement value is acquired.

When the first evaluation value is larger than the first threshold value, it is determined that the mercury in the exhaust gas is in a high concentration state (step S12). For example, when a waste containing a lot of mercury is burned in the combustion chamber 2, the first evaluation value becomes larger than the first threshold value. In the high concentration state, the control unit 40 controls the dust collection ash distribution unit 45 so that the distribution ratio of the dust collection ash collected by the dust collector 43 to the dust collection ash discharge unit 47 is increased as compared with the normal state. (Step S13). Preferably, all dust collection ash collected by the dust collector 43 is forcibly conveyed to the dust collection ash discharge unit 47. The first threshold value at which all the dust collection ash is conveyed to the dust collection ash discharge unit 47 is preferably set, for example, at a total mercury concentration of 100 μg / m ³ or more.

As described above, in the basic operation of the exhaust gas treatment device 4, the dust collection ash distribution unit 45 prevents the dust collection ash storage amount in the dust collection ash storage unit of the dust collection ash return unit 44 from exceeding the maximum amount. The dust collection ash is distributed to the dust collection ash return unit 44 and the dust collection ash discharge unit 47. On the other hand, in the high concentration state, even when the amount of dust collection ash stored in the dust collection ash storage unit is less than the maximum amount, the distribution ratio to the dust collection ash discharge unit 47 is preferably 100%. Thereby, it is suppressed that the mercury adsorbent which adsorb | sucked a lot of mercury is stored in the dust collection ash storage part. When the amount of dust collection ash stored in the dust collection ash storage unit reaches the maximum amount, all dust collection ash is supplied to the dust collection ash discharge unit 47 as a basic operation. The distribution ratio to the discharge unit 47 does not increase from the normal state.

In a high concentration state, the dust collection ash conveyed to the dust collection ash discharge unit 47 may be supplied to the mercury removal unit 472 by the discharge distribution unit 473. In this case, the mercury removal unit 472 performs mercury removal processing by heating the dust collection ash, and the mercury contained in the dust collection ash volatilizes and is collected by the collection unit (step S14). The mercury removal process is a dedicated process for the dust collection ash transported to the discharge position in a high concentration state. The dust collection ash after the mercury removal process is supplied to the immobilization unit 471 and mixed with the chelating agent, thereby immobilizing heavy metals contained in the dust collection ash. Depending on the design of the exhaust gas treatment device 4, the heavy metal immobilization process for the dust collection ash after the mercury removal process may be omitted.

While the state where the first evaluation value is larger than the first threshold value is maintained (steps S11 and S12), the distribution ratio of the dust collection ash to the dust collection ash discharge unit 47 is continuously increased, and the mercury removal unit 472. The mercury removal process is executed in step S13 and step S14.

When the first evaluation value is equal to or less than the first threshold value (steps S11 and S12), the operations in the dust collection ash distribution unit 45 and the dust collection ash discharge unit 47 are returned to the normal operation. Thereby, in the dust collection ash distribution unit 45, the dust collection ash is distributed to the dust collection ash return unit 44 and the dust collection ash discharge unit 47 in accordance with the basic operation. In addition, the dust collection ash supplied to the dust collection ash discharge unit 47 is directly supplied to the immobilization unit 471. Actually, after the first evaluation value becomes equal to or less than the first threshold, the dust collection ash collected by the dust collector 43 is delayed by a time that is assumed to contain no mercury adsorbent that adsorbs a large amount of mercury. Thus, it is preferable that the operation of the dust collection ash distribution unit 45 and the like is returned to the normal operation. In FIG. 3A, illustration of processing for returning the operations in the dust collection ash distribution unit 45 and the dust collection ash discharge unit 47 to the normal operation is omitted.

Next, an example of processing using both the upstream concentration measurement unit 481 and the downstream concentration measurement unit 482 will be described with reference to FIG. 3B. In the processing using the upstream concentration measurement unit 481 and the downstream concentration measurement unit 482, the upstream measurement value is acquired by the upstream concentration measurement unit 481, and the downstream measurement value is acquired by the downstream concentration measurement unit 482 (step S11). The upstream measurement value and the downstream measurement value are output to the control unit 40. The upstream measurement value is a value of the total concentration of zero-valent mercury and divalent mercury contained in the exhaust gas, or a value corrected from the concentration of zero-valent mercury using the correction table described above (0 Value corresponding to the total concentration of valent mercury and divalent mercury).

In the control unit 40, a value obtained by subtracting the upstream measurement value from the downstream measurement value (hereinafter referred to as “difference value”) is obtained as the second evaluation value. At this time, the time required for the exhaust gas flowing through the flue 3 to pass through the vicinity of the upstream concentration measuring unit 481 and after passing through the vicinity of the downstream concentration measuring unit 482 is taken into consideration. In addition, the time required to reduce the mercury compound to atomic mercury in the upstream concentration measurement unit 481 and the downstream concentration measurement unit 482 is also taken into consideration. Thus, the second evaluation value is obtained from the upstream measurement value and the downstream measurement value acquired for the exhaust gas generated at approximately the same time in the combustion chamber 2. Then, the second evaluation value is compared with a predetermined second threshold value. When the second evaluation value is equal to or less than the second threshold value, it is determined that the concentration of mercury in the exhaust gas on the downstream side of the dust collector 43 is in a normal state (step S12). The operation in the normal state is the same as in the above processing example. In the exhaust gas treatment device 4, the second evaluation value is compared with the second threshold value every time the upstream measurement value and the downstream measurement value corresponding to each other are acquired.

If the second evaluation value is greater than the second threshold value for a predetermined time, it is determined that the mercury in the exhaust gas on the downstream side of the dust collector 43 is in a high concentration state (step S12). For example, the mercury adsorbent present in the flue 3 such as on the filter cloth of the dust collector 43 contains an equilibrium adsorption amount of mercury with respect to the mercury concentration of the exhaust gas, and mercury is desorbed from the mercury adsorbent (mercury adsorption). The second evaluation value is greater than the second threshold value. As in the above processing example, in the high concentration state, the control unit 40 controls the dust collection ash distribution unit 45, whereby the distribution ratio of the dust collection ash collected by the dust collector 43 to the dust collection ash discharge unit 47 is as follows. Is increased from the normal state (step S13). Preferably, all dust collection ash collected by the dust collector 43 is forcibly conveyed to the dust collection ash discharge unit 47, and the distribution ratio of the dust collection ash to the dust collection ash discharge unit 47 is 100%. . Thereby, the mercury adsorbent that adsorbs a large amount of mercury is suppressed from being stored in the dust collection ash storage section of the dust collection ash return section 44.

Further, in a high concentration state, mercury removal processing by the mercury removal unit 472 is performed on the dust collection ash transported to the dust collection ash discharge unit 47 (step S14). Furthermore, the pay-off period in the dust collector 43 is made shorter than the normal state (step S15). That is, the mercury adsorbent is removed from the filter cloth as a part of the fly ash at a cycle shorter than the normal state. In addition, when it is assumed that the mercury adsorption amount in the mercury adsorbent is not large, step S14 may not be performed.

While the state where the second evaluation value is larger than the second threshold is maintained (steps S11 and S12), the processes of steps S13 to S15 are continued. When the second evaluation value is equal to or lower than the second threshold value (steps S11 and S12), the operations in the dust collection ash distribution unit 45, the dust collector 43, and the dust collection ash discharge unit 47 are returned to normal operations. That is, in the dust collector 43, the dust collection ash removal period is returned to the value in the normal state.

In the present processing example in which a value obtained by subtracting the upstream measurement value from the downstream measurement value is obtained as the second evaluation value, the second threshold value is, for example, 0 μg / m ³ . The second evaluation value may be obtained as a moving average over a fixed time. In this case, when the moving average (second evaluation value), for example, continuously exceeds the second threshold for a predetermined time, it is determined that the exhaust gas is in a high concentration state, and all the dust collection ash is discharged. It is conveyed to the unit 47. Also in the process using the second evaluation value, a delay time is set until the operation of the dust collecting ash distribution unit 45 and the like is returned to the normal operation after the second evaluation value becomes equal to or less than the second threshold value. Also good. In the exhaust gas treatment device 4, the process using the first evaluation value and the process using the second evaluation value may be performed in parallel. In this case, when the first evaluation value is larger than the first threshold value and when the second evaluation value is larger than the second threshold value, the processes of steps S13 to S15 are performed.

As described above, in the exhaust gas treatment device 4, the dust collection ash distribution unit 45 that distributes the dust collection ash collected by the dust collector 43 to the dust collection ash return unit 44 and the dust collection ash discharge unit 47. Provided. Further, the measurement values of mercury concentration in the exhaust gas are acquired by the

concentration measuring units

481 and 482. And in the high concentration state where the evaluation value based on the measured value is larger than the threshold value, the distribution ratio of the dust collection ash to the dust collection ash discharge unit 47 by the dust collection ash distribution unit 45 is increased compared to the normal state. Thereby, it is possible to suppress the dust collection ash containing a large amount of mercury from being returned to the flue 3. As a result, in the exhaust gas treatment device 4, the mercury concentration in the exhaust gas can be more reliably reduced.

Also, in the high concentration state, the dust collection ash removal period in the dust collector 43 is made shorter than the normal state. Thereby, the detachment | desorption of mercury from the mercury adsorbent deposited on the filter cloth of the dust collector 43 can be suppressed, and the concentration of mercury in the exhaust gas flowing downstream of the dust collector 43 can be reduced more reliably. In the process based on the first evaluation value, the process of step S15 for shortening the payout period may be performed.

The upstream concentration measurement unit 481 obtains a measurement value based on the amount of atomic mercury contained in the exhaust gas without reducing the mercury compound contained in the exhaust gas to atomic mercury, so the measurement value of the mercury concentration is shortened. It is possible to get in time. Therefore, a rapid increase in the mercury concentration in the exhaust gas can be detected immediately, and the mercury concentration in the exhaust gas discharged from the chimney 52 can be stably reduced.

By the way, in the immobilization of heavy metals using a chelating agent, mercury may be eluted from the dust collection ash when the dust collection ash discharged to the discharge position contains a large amount of mercury adsorbent and mercury. On the other hand, in the dust collection ash discharge unit 47 of the exhaust gas treatment device 4, the mercury removal unit 472 performs mercury removal processing on the dust collection ash conveyed to the discharge position in a high concentration state. Thereby, it is possible to prevent mercury from being eluted in the immobilization process for the dust collection ash after the mercury removal process.

FIG. 4 is a diagram showing another example of the adsorbent supply unit. The adsorbent supply unit 428a of FIG. 4 includes a cyclone centrifugal dust collection unit 49 capable of separating the powdery mercury adsorbent and air. The centrifugal dust collection unit 49 includes an inlet 491, an outlet 492, an auxiliary outlet 493, a dust collection chamber 494, and a separation chamber 495. The separation chamber 495 includes a cylindrical portion 496 and a conical portion 497. The cylindrical portion 496 is a covered and bottomless cylindrical shape. The conical part 497 is a cylindrical member whose upper part continues from the cylindrical part 496, and the diameter gradually decreases downward.

The inlet portion 491 is provided on the side wall of the cylindrical portion 496. A medicine supply line 424 described later is connected to the inlet 491. The outlet portion 492 is provided on the lid portion of the cylindrical portion 496. The outlet portion 492 has a cylindrical portion that protrudes toward the inside of the cylindrical portion 496. One end of the charging line 498a is connected to the outlet 492, and the other end of the charging line 498a is connected to the medicine supply position P1 in the flue 3. The dust collection chamber 494 is connected to the lower portion of the conical portion 497, and the auxiliary outlet portion 493 is provided at the bottom of the dust collection chamber 494. One end of an auxiliary charging line 498b is connected to the auxiliary outlet portion 493, and the other end of the auxiliary charging line 498b is near the chemical supply position P1 in the flue 3, that is, between the temperature reducing tower 41 and the dust collector 43. Connected to position P3. The auxiliary charging line 498b is provided with an opening / closing part 499 such as a gate valve. In the normal state, the opening / closing part 499 is closed.

The adsorbent supply unit 428a further includes an adsorbent storage unit 422, a drug pumping unit 423, a drug supply line 424, and a quantitative supply unit 426. One end of the medicine supply line 424 is connected to the medicine pumping part 423, and the other end is connected to the inlet part 491 of the centrifugal dust collecting part 49. The adsorbent storage unit 422 stores a powdery mercury adsorbent. The mercury adsorbent taken out from the adsorbent storage unit 422 by the fixed amount supply unit 426 is supplied to the centrifugal dust collection unit 49 together with the air flowing in the drug supply line 424.

The air is blown into the separation chamber 495 along the inner peripheral surface of the cylindrical portion 496 through the inlet portion 491. Centrifugal force and gravity act on the mercury adsorbent contained in the air, and the mercury adsorbent falls to the dust collection chamber 494 while turning along the inner peripheral surfaces of the cylindrical portion 496 and the conical portion 497. In a normal state, the opening / closing part 499 of the auxiliary charging line 498b is closed, and the mercury adsorbent is separated from the air and stored in the dust collection chamber 494. After the air reaches the lower part of the conical part 497, the air is turned upward, passes through the vicinity of the central axis of the separation chamber 495, and reaches the outlet part 492. The air discharged from the outlet 492 is introduced into the flue 3 through the input line 498a.

In the centrifugal dust collecting section 49, when the mercury adsorbent stored inside reaches a predetermined amount, the mercury adsorbent blown into the separation chamber 495 is discharged from the outlet section 492 together with air, and is supplied via the input line 498a. It is supplied to the medicine supply position P1 in the flue 3. Therefore, in the normal state, the amount of mercury adsorbent supplied to the flue 3 by the adsorbent supply unit 428a can be controlled based on the upstream measurement value. Note that the amount of mercury adsorbent that starts to be discharged from the outlet 492 depends on the shape and volume of the dust collection chamber 494.

Further, when the mercury concentration in the exhaust gas suddenly increases, a relatively large amount of mercury adsorbent is applied to the position P3 in the flue 3 via the auxiliary charging line 498b by opening the opening / closing part 499. It is possible to supply. In addition, since the inside of the flue 3 is in a depressurized state by the induction fan 51 (see FIG. 1), the mercury adsorbent in the dust collection chamber 494 is easily drawn into the flue 3. When the adsorbent supply unit 428a of FIG. 4 is used, an alkaline agent supply unit having the same structure as the alkaline agent supply unit 427 of FIG. 2 or the adsorbent supply unit 428a of FIG. 4 is separately provided. Furthermore, it is also possible to supply slaked lime together with the mercury adsorbent to the medicine supply position P1 by attaching the alkali storage part 421 and the quantitative supply part 425 in FIG. 2 to the charging line 498a in FIG.

The incineration facility 1 and the exhaust gas treatment device 4 can be variously modified.

In the control of the supply amount of the mercury adsorbent, it is preferable to set in advance a set value of the supply amount of the mercury adsorbent according to at least one measurement value of the upstream concentration measurement unit 481 or the downstream concentration measurement unit 482. In addition, when the mercury adsorbent also adsorbs dioxins in the exhaust gas, for example, activated carbon, the activated carbon is normally blown into the flue 3 to adsorb and remove the dioxins in the exhaust gas. Depending on the value or at least one of the downstream measurement values, the supply amount of activated carbon is increased or decreased within a range of a predetermined amount or more.

The evaluation value for determining the high concentration state may be a downstream measurement value, as long as it is a value obtained using at least one of the upstream measurement value and the downstream measurement value.

Based on the measurement value of the upstream concentration measurement unit 481 or the downstream concentration measurement unit 482, the dust collection ash removal period in the dust collector 43 may be longer than the normal state. For example, if the upstream measurement value suddenly rises, or if the upstream measurement value is larger than the downstream measurement value and the downstream measurement value is higher than a predetermined value, the payout cycle is made longer than the normal state. It is also conceivable to thicken the mercury adsorbent (activated carbon) layer deposited on the filter cloth of the dust collector 43.

As the downstream concentration measurement unit 482, a measurement unit similar to the upstream concentration measurement unit 481, that is, a measurement unit that detects atomic mercury but does not detect mercury compounds may be provided. Further, depending on the design of the exhaust gas treatment device 4, a measurement unit similar to the downstream concentration measurement unit 482, that is, a measurement unit that detects atomic mercury and a mercury compound may be provided as the upstream concentration measurement unit 481. One of the upstream concentration measurement unit 481 or the downstream concentration measurement unit 482 may be omitted.

The chemical supply position P1 and the dust collection ash supply position P2 may be set, for example, between the combustion chamber 2 and the temperature reducing tower 41, or may be provided inside the dust collector 43. That is, the chemical supply position P1 and the dust collection ash supply position P2 may be set between the combustion chamber 2 and the dust collector 43 in the flue 3 (the same applies to the position P3).

The supply of the exhaust gas treatment chemical at the chemical supply position P1 and the supply of the dust ash at the dust collection ash supply position P2 do not necessarily have to be performed constantly, and may be temporarily stopped as necessary. In the dust collection ash returning unit 44, the dust collection ash may be supplied to the dust collection ash supply position P <b> 2 using a blower or the like, similarly to the chemical supply unit 42.

Depending on the type of waste incinerated in the incineration facility 1, the dust collection ash discharge unit 47 may be a container or the like for collecting the dust collection ash. The design of the dust collection ash distribution unit 45 may be changed as appropriate. For example, the dust collection ash distribution unit 45 and the discharge distribution unit 473 may share one conveyor.

In the above embodiment, the dust collection ash storage unit is included in the return path 441 of the dust collection ash return unit 44, but the dust collection ash storage unit may be provided as a part of the dust collector 43. For example, the dust collection ash removed from the filter cloth of the dust collector 43 is temporarily stored in the dust collection ash storage unit, and the dust collection ash discharged from the dust collection ash storage unit is collected by the dust collection ash distribution unit 45. It is distributed to the dust collection ash return unit 44 and the dust collection ash discharge unit 47. In the preferred exhaust gas treatment device 4, the downstream concentration measuring unit 482 is provided in the chimney 52.

In the exhaust gas treatment device 4, the supply of slaked lime may be omitted. The exhaust gas treatment device 4 may be used in facilities other than the incineration facility 1.

The configurations in the above embodiment and each modification may be combined as appropriate as long as they do not contradict each other.

Although the invention has been described in detail, the above description is illustrative and not restrictive. Therefore, it can be said that many modifications and embodiments are possible without departing from the scope of the present invention.

DESCRIPTION OF SYMBOLS 2 Combustion chamber 3 Flue 4 Exhaust gas treatment device 40 Control part 43 Dust collector 44 Dust collection ash return part 45 Dust collection ash distribution part 47 Dust collection ash discharge part 428,428a Adsorbent supply part 441 Return path 471 Immobilization part 472 Mercury removal 481 Upstream concentration measurement unit 482 Downstream concentration measurement unit

Claims

An exhaust gas treatment device,
A dust collector installed in a flue through which exhaust gas flows;
An adsorbent supply section for supplying a mercury adsorbent to a position between the exhaust gas source and the dust collector in the flue;
A dust collection ash return unit for transporting the dust collection ash collected by the dust collector to a position between the generation source in the flue and the dust collector along a return path different from the flue; ,
A dust collection ash discharge unit disposed at a discharge position outside the flue;
A dust collection ash distribution unit that distributes the dust collection ash to the dust collection ash return unit and the dust collection ash discharge unit;
A concentration measuring unit for obtaining a measured value of mercury concentration in the exhaust gas;
In a high concentration state where the evaluation value based on the measurement value is larger than a predetermined threshold value, the distribution ratio to the dust collection ash discharge unit is increased compared to the normal state where the evaluation value is equal to or less than the threshold value A control unit for controlling the dust collection ash distribution unit;
Is provided.
The exhaust gas treatment apparatus according to claim 1,
When the evaluation value is larger than the threshold value, the control unit controls the dust collection ash distribution unit so that the distribution ratio to the dust collection ash discharge unit becomes 100%.
The exhaust gas treatment apparatus according to claim 1 or 2,
The inlet of the concentration measuring unit is disposed on the upstream side of the adsorbent supply unit in the flue,
The evaluation value is the measurement value of the concentration measurement unit.
The exhaust gas treatment apparatus according to claim 1 or 2,
And further comprising another concentration measuring unit for obtaining a measured value of the mercury concentration in the exhaust gas,
The inlet of the concentration measuring unit is disposed on the upstream side of the dust collector in the flue,
The intake of the other concentration measuring unit is disposed downstream of the dust collector in the flue,
The evaluation value is a difference value obtained by subtracting the measurement value of the concentration measurement unit from the measurement value of the another concentration measurement unit.
An exhaust gas treatment apparatus according to any one of claims 1 to 4,
In the high concentration state, the control unit shortens the dust collection ash removal period in the dust collector from the normal state.
An exhaust gas treatment apparatus according to any one of claims 1 to 5,
The control unit controls the amount of the mercury adsorbent supplied to the flue by the adsorbent supply unit based on the measurement value of the concentration measurement unit.
An exhaust gas treatment apparatus according to any one of claims 1 to 6,
The concentration measuring unit is disposed on the upstream side of the dust collector in the flue, measures the concentration of zero-valent mercury contained in the exhaust gas, and determines the total of zero-valent mercury and divalent mercury contained in the exhaust gas. Concentration measurement is selectively performed.
An exhaust gas treatment apparatus according to any one of claims 1 to 7,
The dust collection ash discharge part is
An immobilization section for immobilizing heavy metals contained in the dust collection ash by mixing a chelating agent;
A mercury removal unit that performs a mercury removal process on the dust ash conveyed to the discharge position in the high concentration state;
Is provided.
An exhaust gas treatment apparatus according to any one of claims 1 to 8,
The mercury adsorbent is activated carbon;
While the exhaust gas flows through the flue, the mercury adsorbent is constantly supplied to the flue.
An exhaust gas treatment apparatus according to any one of claims 1 to 9,
Further provided with a hydrogen chloride concentration measurement unit that is disposed downstream of the dust collector and measures the hydrogen chloride concentration of the exhaust gas;
The said control part controls the quantity of the said dust collection ash supplied to the said flue by the said dust collection ash return part based on the measured value of the said hydrogen chloride concentration measurement part.