WO2019224639A1 - Mélanges herbicides aqueux - Google Patents

Mélanges herbicides aqueux Download PDF

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Publication number
WO2019224639A1
WO2019224639A1 PCT/IB2019/053769 IB2019053769W WO2019224639A1 WO 2019224639 A1 WO2019224639 A1 WO 2019224639A1 IB 2019053769 W IB2019053769 W IB 2019053769W WO 2019224639 A1 WO2019224639 A1 WO 2019224639A1
Authority
WO
WIPO (PCT)
Prior art keywords
multipart
amine component
herbicidal
herbicide
intermixture
Prior art date
Application number
PCT/IB2019/053769
Other languages
English (en)
Inventor
Prakash Mahadeo Jadhav
Stephen SKORCZYNSKI
Emily CHIARELLA
Cody Jack GRAY
Jaidev Rajnikant Shroff
Vikram Rajnikant Shroff
Original Assignee
Upl Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upl Ltd filed Critical Upl Ltd
Priority to CN201980038376.2A priority Critical patent/CN112423591A/zh
Priority to UAA202008071A priority patent/UA127152C2/uk
Priority to CA3101106A priority patent/CA3101106A1/fr
Priority to MX2020012577A priority patent/MX2020012577A/es
Priority to PE2020001889A priority patent/PE20211386A1/es
Priority to AU2019273057A priority patent/AU2019273057A1/en
Publication of WO2019224639A1 publication Critical patent/WO2019224639A1/fr
Priority to PH12020552005A priority patent/PH12020552005A1/en
Priority to CONC2020/0015294A priority patent/CO2020015294A2/es
Priority to ZA2020/07891A priority patent/ZA202007891B/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds

Definitions

  • the invention relates to herbicidal intermixtures. More particularly, the invention relates to essentially aqueous homogeneous herbicide compositions comprising electrolytic herbicides and a multipart amine component.
  • “Arid” implies prolonged dryness, and is used with respect to the climate and the land below it. In such regions the ability to produce agricultural crops is restricted. Usually on arid lands the potential evaporation of water from the land exceeds the rainfall. The land may be characterized according to the degree of aridity as dry forest, chaparral or brushland, grassland or savannah, or desert. "Arid” does not adequately characterize the soils, however, for they may vary in many ways. Often they are alkaline or saline.
  • An arid ecosystem differs in many respects from one of tropical or temperate zones. Unlike temperate zones, an arid zone is characterized as an area of low precipitation, high temperature, and high rate of evaporation. Frequency of rainfall does not describe accurately the type of the arid zone nor does the amount of precipitation govern the type of vegetation. Among the various agronomic practices that could bring about immediate positive results in dryland and arid areas, optimum and effective weed control is the first and foremost management practice. However many weeds growing naturally in the arid region have evolved a more complicate overall drought adaptation strategy which usually involves several mechanisms of drought escape, tolerance and avoidance.
  • the leaf shedding option, the tight stomatal control and the development of a prolific root system are all specific characteristics developed by the vegetation destined to grow in arid regions.
  • the plants adopt to osmoregulation and increase in elasticity of the cell and a decrease in cell size. Due to such natural adaption of the plants/weeds to the specific conditions, they are tougher than those growing under normal conditions and is difficult to control. Further such weeds have thick and waxy cuticle layers defending them from the penetration of any use of foliar herbicides. It has been observed that the commonly used non-selective herbicide such as glufosinate based formulations were not providing an effective weed control in arid regions.
  • Glufosinate is a non-selective foliage application type herbicide which kills or controls many species of weeds.
  • Pesticide Manual 15 th Edition glufosinate has been described as being widely used in burn-down segments, and for control of a wide range of broad-leaved weeds and grasses and sedges in cereals, cotton, corn and soy, fruit orchards, vineyards, rubber and oil palm plantations, ornamental trees and bushes, non-crop land, and pre-emergence in vegetables.
  • Glufosinate being a contact herbicide is known to be used with various adjuvants to improve the efficacy or to induce certain specific properties as required.
  • US6642177 discloses that to be effective, glufosinate must be formulated with a high concentration of surfactants to get the required bio efficacy.
  • DE 3931051 discloses salts of herbicidal acids with long-chain nitrogen bases such as fatty amines.
  • the primary object of the present invention is the designing and preparation of a novel composition of glufosinate which is highly efficacious particularly in arid region where the weeds are having thick and waxy leaves and is difficult to penetrate with usual foliar herbicidal formulations.
  • Yet another object of the present invention is to provide a method for controlling unwanted plants in arid regions.
  • the present invention provides an herbicidal intermixture comprising:
  • the present invention provides an herbicidal intermixture comprising:
  • the present invention further provides an herbicidal intermixture comprising: a) a phosphinic acid herbicide, its salts, its isomers, mixture of isomers, derivatives, or lower alkyl esters thereof;
  • aqueous herbicidal composition comprising:
  • said multipart amine component comprises at least one tertiary amine having an alkyl group of at least 8 carbon atoms.
  • Another aspect of the present invention is to provide a method controlling unwanted plants in crop and non-crop areas, said method comprising applying to the plants, unwanted plants or to their locus, a herbicidally effective amount of herbicidal intermixtures according to the present invention.
  • the present invention further provides a method of controlling unwanted plants in crop and non-crop areas in arid region, said method comprising applying to the plants, unwanted plants or to their locus in arid region, an herbicidally effective amount of herbicidal intermixtures according to the present invention.
  • an herbicidal intermixture comprising:
  • the intermixture comprises water.
  • the present invention thus provides an herbicidal intermixture comprising:
  • the intermixture of the present invention possesses superior herbicidal activity.
  • the term intermixture includes an admixture.
  • the term intermixture includes the mixtures resulting from any one of the processes selected from reaction, solubilisation, neutralization or partial neutralization occurring between the components of the intermixture.
  • the term intermixture includes a composition or formulation according to the present invention. Accordingly, in certain other embodiments, there is provided an herbicidal mixture comprising:
  • the herbicidal mixture comprises water.
  • an herbicidal mixture comprising:
  • the herbicidal mixture of the present invention possesses superior herbicidal activity.
  • the electrolytic herbicide is selected from phospinic acid herbicides.
  • the phosphinic acid herbicide is selected from the group comprising glufosinate and glyphosate.
  • glufosinate refers to its derivatives selected from lower alkyl esters thereof or salts thereof with acids or bases such as its hydrochloride, monosodium salt, disodium salt, monopotassium salt, dipotassium salt, monocalcium salt, ammonium salt, -NH3(CH3)+ salt, -NH2(CH3)2+ salt, - NH(CH3)3+ salt, -NH(CH3)2(C2H40H)+, -NH2(CH3)(C2H40H)+, or its methyl ester, ethyl ester, propyl ester or butyl ester.
  • glufosinate refers to isomers or mixture of isomers.
  • the isomer is glufosinate-P.
  • glyphosate refers to glyphosate-mono ammonium, glyphosate diammonium, glyphosate-isopropylammonium, glyphosate-potassium or glyphosate isopropyl amine salt.
  • an herbicidal intermixture comprising:
  • a phosphinic acid herbicide a phosphinic acid herbicide, its salts, its isomers, mixture of isomers, derivatives, or their lower alkyl esters thereof;
  • the intermixture of the invention possesses superior herbicidal activity.
  • the multipart amine component comprises one or more tertiary amines having alkyl groups of 8 to 20 carbon atoms. In another embodiment the multipart amine component comprises one or more tertiary dimethyl alkylamines wherein the alkyl groups have 8 to 20 carbon atoms.
  • the multipart amine component comprises one or more tertiary dimethyl alkylamines wherein the alkyl groups have 10 to 20 carbon atoms.
  • the multipart amine component according to the present invention comprises at least two tertiary amines having alkyl groups of 8 to 20 carbon atoms. In another embodiment, the multipart amine component according to the present invention comprises at least three tertiary amines having alkyl groups of 8 to 20 carbon atoms. In an embodiment, the multipart amine component according to the present invention comprises at least four tertiary amines having alkyl groups of 8 to 20 carbon atoms.
  • the multipart amine component according to the present invention comprises at least two tertiary dimethyl alkylamines having alkyl groups of 8 to 20 carbon atoms. In another embodiment, the multipart amine component according to the present invention comprises at least three tertiary dimethyl alkylamines having alkyl groups of 8 to 20 carbon atoms.
  • the multipart amine component according to the present invention comprises at least four tertiary dimethyl alkylamines having alkyl groups of 8 to 20 carbon atoms.
  • the multipart amine component according to the present invention comprises at least one tertiary dimethyl alkylamine having alkyl groups of 10 to 18 carbon atoms.
  • the multipart amine component according to the present invention comprises at least two tertiary dimethyl alkylamines having alkyl groups of 8 to 20 carbon atoms wherein said tertiary dimethyl alkylamines are present in a ratio of 1 :99 to 99: 1.
  • the multipart amine component according to the present invention comprises at least two tertiary dimethyl alkylamines having alkyl groups of 8 to 20 carbon atoms wherein at least one dimethyl alkylamine is present at least in an amount about 50% by weight of the multipart amine component.
  • the term intermixture or admixture according to the present invention includes a composition or a formulation.
  • the composition comprises from about 0.1% to about 60% by weight of phosphinic acid herbicide.
  • the composition comprises from about 1 % to about 50% by weight of phosphinic acid herbicide. In an embodiment the composition comprises from about 0.1% to about 60% by weight of multipart amine component.
  • the composition comprises from about 1 % to about 50% by weight of multipart amine component.
  • the composition comprises phosphinic acid herbicide and multipart amine component in a molar ratio of from about 1 : 1.5 to about 1.5:1.
  • the composition comprises phosphinic acid herbicide and multipart amine component in a molar ratio of about 1 : 1.5
  • composition comprises phosphinic acid herbicide and multipart amine component in an equimolar ratio.
  • compositions according to the present invention further comprises organic solvents.
  • aqueous herbicidal composition comprising:
  • a phosphinic acid herbicide a phosphinic acid herbicide, its salts, its isomers, mixture of isomers, derivatives, or their lower alkyl esters thereof;
  • said multipart amine component comprises at least one tertiary amine having an alkyl group of at least 8 carbon atoms.
  • the solvents may be selected from but are not limited to: a water miscible polar/non-polar or a water immiscible polar/non-polar solvent, for example, alkyl esters of pthalic acid and trimellitic acid; aromatic hydrocarbons such as xylene, solvesso-100, solvesso-150, solvesso-200, alkyl benzenes; methylnaphthalene; mixtures of aromatics aliphatic or cycloaliphatic hydrocarbon such as hexane and heptanes; phthalates; ketones such as cyclohexanone, 2- octanone or acetophenone, methyl isobutyl ketone - saturated or unsaturated cyclic ketones such as isophorone, chlorinated hydrocarbons; vegetable oils and modified vegetable oils; glycols and their derivatives, polyglycols; aliphatic alcohols, alkoxy aliphatic alcohols or mixtures
  • solvents can be alkylene carbonates (like propylene carbonate), alkyl amides, and esters such as alkyl esters of monocarboxylic acids and dicarboxylic acid, ester- amides, cyclic ethers such furan and its derivatives or mixtures thereof.
  • the herbicidal intermixtures further comprises other agrochemical excipients.
  • other agronomically suitable excipients are selected from but are not limited to surfactants, solvent, fertilizer, pH modifiers, crystallization inhibitors, viscosity modifiers, suspending agents, spray droplet modifiers, pigments, antioxidants, foaming agents, light-blocking agents, compatibilizing agents, antifoam agents, sequestering agents, neutralizing agents, corrosion inhibitors, dyes, odorants, spreading agents, penetration aids, micronutrients, emollients, lubricants, sticking agents, dispersing agents, thickening agents, freezing point depressants, antimicrobial agents, and the like.
  • the herbicidal intermixture of the present invention may be combined with at least another active ingredient selected from the group comprising herbicides, insecticides, fungicides, biological agents, plant growth activators, fertilizers or combinations thereof.
  • the herbicidal intermixture according to the present invention may be combined with an herbicide.
  • exemplary herbicides that may be combined with the herbicidal intermixture of the present invention may include, but are not limited to, herbicides selected from classes such as ACCase inhibitors, ALS inhibitors, EPSP synthase inhibitors, synthetic auxins, auxin transport inhibitors, HPPD inhibitors, lipid synthesis inhibitors, long chain fatty acid inhibitors, as well as herbicides with unknown modes of action.
  • the present invention further provides a process for preparing herbicidal intermixtures according to the invention.
  • the present invention provides a process for preparing herbicidal intermixture according to the invention, said process comprising the steps:
  • the present invention provides a process for preparing herbicidal compositions according to the invention, said process comprising: a) mixing a multipart amine component with water;
  • step d) intermixing an electrolytic herbicide with the mixture obtained in step c) until a clear solution is obtained.
  • the present invention provides a process for preparing herbicidal compositions according to the invention, said process comprising the steps:
  • step c) intermixing a phosphinic acid herbicide, its salts, its isomers, mixture of isomers, derivatives, or their lower alkyl esters thereof with the mixture obtained in step c) until a clear solution is obtained.
  • the phosphinic acid herbicide is selected from glufosinate, its salts, its isomers, mixture of isomers, derivatives, or their lower alkyl esters thereof.
  • the present invention provides a process for preparing herbicidal compositions according to the invention, said process comprising the steps:
  • the present invention provides a process for preparing herbicidal compositions according to the invention, said process comprising the steps:
  • step c) intermixing glufosinate, its salts, its isomers, mixture of isomers, derivatives, or their lower alkyl esters thereof with the mixture obtained in step c) until a clear solution is obtained.
  • the multipart amine component comprises one or more tertiary amines having alkyl groups of 8 to 20 carbon atoms.
  • the multipart amine component comprises one or more tertiary dimethyl alkylamines wherein the alkyl groups have 8 to 20 carbon atoms. In some embodiments, the multipart amine component comprises one or more tertiary dimethyl alkylamines wherein the alkyl groups have 10 to 18 carbon atoms.
  • the present invention further provides a method of controlling unwanted plants in crop and non-crop areas, said method comprising applying to the plants, unwanted plants or to their locus a herbicidally effective amount of compositions according to the present invention.
  • the present invention provides a method of controlling unwanted plants in arid regions said method comprising applying to the to the plants, unwanted plants or to their locus a herbicidally effective amount of compositions according to the present invention.
  • the present invention provides a method of controlling unwanted plants in both crop and non-crop areas in arid region said method comprising applying to the unwanted plants or to their locus a herbicidally effective amount of compositions according to the present invention.
  • a weed control method in arid region comprising applying to the weeds or to their locus a herbicidally effective amount of herbicidal intermixture comprising:
  • a weed control method in arid region comprising applying to the weeds or to their locus a herbicidally effective amount of herbicidal intermixture comprising:
  • a phosphinic acid herbicide a phosphinic acid herbicide, its salts, its isomers, mixture of isomers, derivatives, or their lower alkyl esters thereof;
  • Example 1 A herbicidal intermixture according to the present invention comprising glufosinate ammonium is prepared as follows:
  • composition is prepared by a process as follows:
  • Example 2 A herbicidal intermixture according to the present invention comprising glufosinate acid is prepared as follows:
  • composition was prepared by following process given for example 1.
  • Example 3 A herbicidal intermixture according to the present invention comprising glufosinate dipotassium salt is prepared as follows:
  • Example 4 A herbicidal intermixture according to the present invention comprising glufosinate acid is prepared as follows:
  • Example 5 A herbicidal intermixture according to the present invention comprising glufosinate ammonium is prepared as follows
  • Example 6 A herbicidal intermixture according to the present invention comprising glufosinate acid is prepared as follows:
  • Example 7 A herbicidal intermixture according to the present invention comprising glufosinate ammonium and glyphosate isopropyl amine is prepared as follows:
  • Example 8 A herbicidal intermixture according to the present invention comprising glufosinate acid and glyphosate isopropyl amine is prepared as follows:
  • Example 9 A herbicidal intermixture according to the present invention comprising glufosinate acid and glyphosate isopropyl amine is prepared as follows:
  • Example 10 A herbicidal intermixture according to the present invention comprising glufosinate acid and glyphosate isopropyl amine is prepared as follows
  • Example 11 A herbicidal intermixture according to the present invention comprising glufosinate acid and glyphosate acid is prepared as follows
  • Example 12 A herbicidal intermixture according to the present invention comprising glufosinate acid and glyphosate acid is prepared as follows:
  • Example 13 A herbicidal intermixture according to the present invention comprising glufosinate acid and glyphosate acid is prepared as follows:
  • Example 14 A herbicidal intermixture according to the present invention comprising glufosinate acid is prepared as follows:
  • composition of glufosinate acid (in the absence of multipart amine component) was prepared as follows:
  • composition of glufosinate salt (in the absence of multipart amine component) was prepared as follows:
  • compositions were diluted with water and applied to broad leave weeds, grasses and sedges in the arid region.
  • composition (Example 14) prepared according to the present invention After treatment using composition (Example 14) prepared according to the present invention, chlorosis followed by necrosis of the weeds were observed demonstrating the bio-efficacy of the new compositions. Comparative compositions (Example 15 and Example 16) and market sample of glufosinate ammonium (Liberty 280 SL Glufosinate ammonium) were also tested to compare the results. The observations at 7 days, 14 days and 21 days after application were summarized in below table (table 1).

Abstract

La présente invention concerne des compositions herbicides homogènes aqueuses comprenant des herbicides électrolytiques et un composant amine en plusieurs parties, ledit composant amine en plusieurs parties comprenant au moins une amine tertiaire ayant un groupe alkyle d'au moins 8 atomes de carbone.
PCT/IB2019/053769 2018-05-25 2019-05-08 Mélanges herbicides aqueux WO2019224639A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CN201980038376.2A CN112423591A (zh) 2018-05-25 2019-05-08 含水除草混合物
UAA202008071A UA127152C2 (uk) 2018-05-25 2019-05-08 Водні гербіцидні суміші
CA3101106A CA3101106A1 (fr) 2018-05-25 2019-05-08 Melanges herbicides aqueux
MX2020012577A MX2020012577A (es) 2018-05-25 2019-05-08 Combinaciones herbicidas acuosas.
PE2020001889A PE20211386A1 (es) 2018-05-25 2019-05-08 Combinaciones herbicidas acuosas
AU2019273057A AU2019273057A1 (en) 2018-05-25 2019-05-08 Aqueous herbicidal intermixtures
PH12020552005A PH12020552005A1 (en) 2018-05-25 2020-11-23 Aqueous herbicidal intermixtures
CONC2020/0015294A CO2020015294A2 (es) 2018-05-25 2020-12-07 Combinaciones herbicidas acuosas
ZA2020/07891A ZA202007891B (en) 2018-05-25 2020-12-17 Aqueous herbicidal intermixtures

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN201831019681 2018-05-25
IN201831019681 2018-05-25

Publications (1)

Publication Number Publication Date
WO2019224639A1 true WO2019224639A1 (fr) 2019-11-28

Family

ID=68616283

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2019/053769 WO2019224639A1 (fr) 2018-05-25 2019-05-08 Mélanges herbicides aqueux

Country Status (13)

Country Link
CN (1) CN112423591A (fr)
AR (1) AR115156A1 (fr)
AU (1) AU2019273057A1 (fr)
BR (1) BR102019010195A2 (fr)
CA (1) CA3101106A1 (fr)
CO (1) CO2020015294A2 (fr)
EC (1) ECSP20083246A (fr)
MX (1) MX2020012577A (fr)
PE (1) PE20211386A1 (fr)
PH (1) PH12020552005A1 (fr)
UA (1) UA127152C2 (fr)
WO (1) WO2019224639A1 (fr)
ZA (1) ZA202007891B (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5668085A (en) * 1987-04-29 1997-09-16 Monsanto Company Glyphosate formulations comprising alkoxylated amine surfactants
WO2002032227A1 (fr) * 2000-10-17 2002-04-25 Victorian Chemicals International Pty Ltd Composition herbicide
US7135437B2 (en) * 2000-05-19 2006-11-14 Monsanto Technology Llc Stable liquid pesticide compositions
WO2007054540A2 (fr) * 2005-11-10 2007-05-18 Rhodia Operations Composition herbicide comprenant des sels de potassium d’aminophosphate ou d’aminophosphonate
WO2012037207A1 (fr) * 2010-09-15 2012-03-22 Dow Agrosciences Llc Tensioactifs d'amine et d'oxyde d'amine pour contrôler la dérive de pulvérisation d'herbicide

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8720819D0 (en) * 1987-09-04 1987-10-14 Monsanto Europe Sa Glyphosate formulations
GT200100090A (es) * 2000-05-19 2002-01-18 Formula de glifosato de potasio
AU2003229348B8 (en) * 2002-05-10 2009-07-02 Innovative Chemical Services Pty Ltd Adjuvant composition
WO2015114483A1 (fr) * 2014-02-03 2015-08-06 Upl Ltd Compositions herbicides stables

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5668085A (en) * 1987-04-29 1997-09-16 Monsanto Company Glyphosate formulations comprising alkoxylated amine surfactants
US7135437B2 (en) * 2000-05-19 2006-11-14 Monsanto Technology Llc Stable liquid pesticide compositions
WO2002032227A1 (fr) * 2000-10-17 2002-04-25 Victorian Chemicals International Pty Ltd Composition herbicide
WO2007054540A2 (fr) * 2005-11-10 2007-05-18 Rhodia Operations Composition herbicide comprenant des sels de potassium d’aminophosphate ou d’aminophosphonate
WO2012037207A1 (fr) * 2010-09-15 2012-03-22 Dow Agrosciences Llc Tensioactifs d'amine et d'oxyde d'amine pour contrôler la dérive de pulvérisation d'herbicide

Also Published As

Publication number Publication date
PE20211386A1 (es) 2021-07-27
ECSP20083246A (es) 2021-01-29
CO2020015294A2 (es) 2020-12-21
MX2020012577A (es) 2021-01-29
CA3101106A1 (fr) 2019-11-28
ZA202007891B (en) 2023-06-28
PH12020552005A1 (en) 2021-06-28
CN112423591A (zh) 2021-02-26
BR102019010195A2 (pt) 2020-02-18
AR115156A1 (es) 2020-12-02
AU2019273057A1 (en) 2020-12-17
UA127152C2 (uk) 2023-05-17

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