WO2019216296A1 - Aqueous suspended agrochemical composition - Google Patents

Aqueous suspended agrochemical composition Download PDF

Info

Publication number
WO2019216296A1
WO2019216296A1 PCT/JP2019/018203 JP2019018203W WO2019216296A1 WO 2019216296 A1 WO2019216296 A1 WO 2019216296A1 JP 2019018203 W JP2019018203 W JP 2019018203W WO 2019216296 A1 WO2019216296 A1 WO 2019216296A1
Authority
WO
WIPO (PCT)
Prior art keywords
mass
parts
group
manufactured
agricultural chemical
Prior art date
Application number
PCT/JP2019/018203
Other languages
French (fr)
Japanese (ja)
Inventor
裕也 石田
泰弘 深見
雅仁 堀
Original Assignee
日産化学株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日産化学株式会社 filed Critical 日産化学株式会社
Priority to JP2020518291A priority Critical patent/JPWO2019216296A1/en
Publication of WO2019216296A1 publication Critical patent/WO2019216296A1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles

Definitions

  • the present invention relates to an aqueous suspension agricultural chemical composition.
  • Aqueous suspended pesticidal compositions in which pesticidal active ingredients are dispersed and suspended in water have the problem that pesticidal active ingredient particles grow during storage due to aggregation, recrystallization, etc., and sometimes biologically active May be reduced.
  • a method of blending a resin such as petroleum resin, coumarone resin, ester gum or the like is known.
  • compounding a resin and a lignin sulfonate having a specific average molecular weight further suppresses the particle growth of active agricultural chemical ingredients during storage and deteriorates the fluidity of the composition during storage at high temperatures. It is known not to do so (for example, see Patent Document 3).
  • particle growth may not be sufficiently suppressed.
  • JP 52-148625 A Japanese Patent Laid-Open No. 9-175904 International Publication No. 2007/145221 International Publication No. 2015/119246 Special table 2016-501197
  • the present invention has been made in view of the above problems, and an object of the present invention is to provide an aqueous suspended agricultural chemical composition in which particle growth of an agricultural chemical active ingredient is suppressed and storage stability is good.
  • the present invention provides the following aqueous suspension pesticide composition.
  • (A) (Z) -N- [2- (3-Chloro-5- [cyclopropylethynyl] pyridin-2-yl) -2- (isopropoxyimino) ethyl] -3- (difluoromethyl) -1- Agrochemical active ingredients including methyl-1H-pyrazole-4-carboxamide,
  • An aqueous suspension pesticide composition comprising (b) an adjuvant and (c) a dispersant. 2.
  • the adjuvant is at least one selected from an esterified polyol alkoxylate represented by the following formula (1A), (1B) or (1C) and a polyoxyalkylene alkyl ether represented by the following formula (2)
  • P OA is the residue of trimethylolpropane
  • P OB is a residue of glycerol
  • P OC is a sorbitan residue
  • Each R 1 is independently a hydrogen atom or —C ( ⁇ O) —R 1 ′ (wherein R 1 ′ is a monovalent hydrocarbon group having 1 to 28 carbon atoms).
  • At least one is —C ( ⁇ O) —R 1 ′;
  • R 2 is an alkyl group having 10 to 14 carbon atoms;
  • a 1 is an alkanediyl group having 2 to 4 carbon atoms;
  • a 2 is an alkanediyl group having 2 to 4 carbon atoms;
  • m is each independently an integer of 1 to 100;
  • n is an integer of 1 to 100.
  • the adjuvant is an esterified polyol alkoxylate represented by the formula (1A), (1B) or (1C), polyoxyethylene isodecyl ether, polyoxyethylene tridecyl ether, polyoxyethylene (C12-14) 2.
  • An aqueous pesticide composition according to 2 which is at least one selected from secondary alcohol ethers and polyoxyalkylene branched decyl ethers. 4).
  • the dispersant is selected from a (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain, an alcohol-initiated EO / PO block copolymer, a polyoxyethylene polyoxypropylene block copolymer, and a polyoxyethylene styryl phenyl ether
  • the aqueous suspension agricultural chemical composition according to any one of 1 to 4, which is at least one kind. 6).
  • the aqueous suspension pesticide composition of the present invention is excellent in storage stability because particle growth of the pesticide active ingredient during storage is suppressed.
  • the aqueous suspension pesticide composition of the present invention comprises (a) an agrochemical active ingredient, (b) an adjuvant, and (c) a dispersant.
  • agrochemical active ingredient of component (a) is represented by the following formula (A): (Z) -N- [2- (3-chloro-5- [cyclopropylethynyl] pyridin-2-yl) -2- ( Isopropoxyimino) ethyl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide [generic name: pyrapropoyne. Hereinafter also referred to as Compound A. ], For example, described in International Publication No. 2014/010737 and Japanese Patent Application Laid-Open No. 2016-011286.
  • the pesticidal active ingredient may contain other pesticidal active ingredients other than Compound A.
  • Other agrochemical active ingredients include other fungicides, insecticides, acaricides, nematicides, anthelmintic agents, antifungal agents, antibacterial agents and the like.
  • Examples of other agrochemical active ingredients include compounds described in The Pesticide Manual, 15th edition, 2009, and the like. Specific examples of the general name are as follows, but the general name is not limited thereto.
  • Bactericides include acibenzolar-S-methyl, acipetacs, aldimorph, allyl alcohol, ametoctradin, aminopyrifen, amisulbrom ), Amobam, ampropylfos, anilazine, azaconazole, azithiram, azoxystrobin, barium polysulfide, benalaxyl, benalaxyl -M (benalaxyl-M), benodanil, benomyl, benquinox, bentaluron, benthiavalicarb-isopropyl, benthiazole, benzacryl amacril), benzamorf, benzovindiflupyr, binapacryl, biphenyl, bitertanol, bixafen, blasticidin-S, bordeaux mixture, boscalid, bromoconazole, bupirimate, buthiobate, butylamine, calcium polysulfide,
  • Insecticides include abamectin, acephate, acequinocyl, acetamipirid, acrinathrin, afidopyropen, afoxolaner, carb, al, carb, alanicarb Allethrin, alpha-cypermethrin, alpha-endosulfan, amidoflumet, amitraz, azamethiphos, azinphos-ethyl, azinphos -Methyl (azinphos-methyl), azocyclotin, bacillus thuringiensis, bendiocarb, benfluthrin, benfuracarb, bens Bensultap, benzoximate, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin ), Bistrifluron, broflanilide, bromo
  • Acaricides include acequinocyl, acrinathrin, amidoflumet, amitraz, azocyclotin, benzoximate, bifenazate, and bromopropylate.
  • the nematicides include aldoxycarb, benclothiaz, cadusafos, DDBCP, dichlofenthion, DSP (DSP), etoprophos, fenamiphos , Fensulfothion, fluazaindolizine, fluensulfone, fosthiazate, fosthietan, imicyafos, isamifofos, isazofos, isazoxox, oxamyl Examples thereof include thiaxazafen, thionazin, tioxazafen and the like.
  • antifungal agents examples include ketoconazole and miconazole nitrate.
  • Antibacterial agents include amoxicillin, ampicillin, bethoxazin, bithionol, bronopol, cefapirin, cefazolin, cefquinome, cefquinome, cefthiome, ftfur Chlortetracycline, clavulanic acid, danofloxacin, difloxacin, dinitroxam, dinitolmide, enrofloxacin, florfenicol, lincomycin, Lomefloxacin, marbofloxacin, miloxacin, mimycin, nitrapyrin, norfloxacin, octhilinone Ofloxacin, orbifloxacin, oxolinic acid, oxytetracycline, penicillin, streptomycin, thiamphenicol, tiamulin fumarate ), Tilmicosin phosphate, tyrosin phosphate, tylosin phosphate, tulathromycin,
  • the content of Compound A is preferably 0.1 to 30% by mass in the composition of the present invention.
  • the lower limit of the content of Compound A is more preferably 0.5% by mass, even more preferably 1% by mass, still more preferably 3% by mass, still more preferably 4% by mass, and most preferably 5% by mass.
  • the upper limit is more preferably 25% by mass, still more preferably 20% by mass, still more preferably 18% by mass, and most preferably 15% by mass.
  • the other agrochemical active ingredient When the other agrochemical active ingredient is contained, its content is arbitrary as long as the effects of the present invention are not impaired, but it is usually about 0.01 to 20% by mass in the composition of the present invention, and 0.1. About 15% by mass is preferable. However, when (a) the pesticidal active ingredient contains Compound A and other pesticidal active ingredients, the total of these is preferably 30% by mass or less.
  • the adjuvant has a function of enhancing the biological effect of the pesticidal active ingredient, and in the present invention, esterified polyol alkoxylate, polyoxyalkylene alkyl ether, and the like are preferable.
  • the esterified polyol alkoxylate is represented by the following formula (1A), (1B) or (1C).
  • the esterified polyol alkoxylate represented by the formula (1A) is a compound in which the hydrogen atom of the hydroxy group of trimethylolpropane is substituted with a group represented by the following formula (1 ′), and the formula (1B)
  • the esterified polyol alkoxylate represented by the formula is a compound in which the hydrogen atom of the hydroxy group of glycerol is substituted with a group represented by the following formula (1 ′), and the esterified polyol alkoxy represented by the formula (1C)
  • the rate is a compound in which the hydrogen atom of the hydroxy group of sorbitan is substituted with a group represented by the following formula (1 ′).
  • a 1 is an alkanediyl group having 2 to 4 carbon atoms.
  • alkanediyl group having 2 to 4 carbon atoms include ethane-1,2-diyl group, propane-1,2-diyl group, propane-1,3-diyl group, butane-1,2-diyl group, butane -1,3-diyl group, butane-1,4-diyl group and the like.
  • each A 1 may be the same as or different from each other.
  • m represents an average number of —A 1 —O— groups and is an integer of 1 to 100.
  • m is preferably 2 to 80, more preferably 5 to 60, still more preferably 10 to 50, and still more preferably 18 to 30.
  • each R 1 is independently a hydrogen atom or —C ( ⁇ O) —R 1 ′ (wherein R 1 ′ is a monovalent hydrocarbon group having 1 to 28 carbon atoms). Where at least one is —C ( ⁇ O) —R 1 ′.
  • the monovalent hydrocarbon group having 1 to 28 carbon atoms is preferably linear or branched, and examples thereof include an alkyl group having 1 to 28 carbon atoms and an alkenyl group having 2 to 28 carbon atoms.
  • the alkyl group preferably has 5 to 26 carbon atoms, more preferably 10 to 24 carbon atoms, and still more preferably 16 to 22 carbon atoms.
  • Examples of the alkyl group having 1 to 28 carbon atoms include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, and tridecyl group.
  • Tetradecyl group pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, henicosyl group, docosyl group, tricosyl group, tetracosyl group, pentacosyl group, hexacosyl group, heptacosyl group, octacosyl group Isomers and the like.
  • dodecyl group tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, and branched isomers thereof are preferable.
  • the alkenyl group preferably has 5 to 26 carbon atoms, more preferably 10 to 24, and still more preferably 16 to 22.
  • Examples of the alkenyl group having 2 to 28 carbon atoms include vinyl group, propenyl group, butenyl group, pentenyl group, hexenyl group, heptenyl group, octenyl group, nonenyl group, decenyl group, undecenyl group, dodecenyl group, tridecenyl group, tetradecenyl group , Pentadecenyl group, hexadecenyl group, heptadecenyl group, octadecenyl group, nonadecenyl group, eicosenyl group, hemicosenyl group, dococenyl group, tricosenyl group, tetracosenyl group, pentacocenyl group, he
  • dodecenyl group tridecenyl group, tetradecenyl group, pentadecenyl group, hexadecenyl group, heptadecenyl group, octadecenyl group, nonadecenyl group, eicocenyl group, and branched isomers thereof are preferable.
  • —C ( ⁇ O) —R 1 ′ may be a fatty acid residue.
  • the “fatty acid residue” means an alkanoyl group derived from a fatty acid, which is obtained by an esterification reaction of a fatty acid.
  • the fatty acid is preferably a linear or branched fatty acid.
  • the fatty acid may be a saturated fatty acid or an unsaturated fatty acid.
  • the unsaturated fatty acid has at least one unsaturated carbon-carbon double bond, preferably has 1 to 3 carbon-carbon double bonds, and has one carbon-carbon double bond. Those are more preferred. Carbon-carbon double bonds can exist in either a cis or trans configuration.
  • saturated fatty acid examples include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, lignoceric acid, and serotic acid. Of these, lauric acid, myristic acid, palmitic acid, stearic acid, and isostearic acid are preferred.
  • Examples of the unsaturated fatty acid include myristoleic acid, palmitoleic acid, sapienoic acid, oleic acid, elaidic acid, vaccenic acid, linoleic acid, linoelaidic acid, ⁇ -linolenic acid, arachidonic acid, eicosapentaenoic acid, erucic acid, docosahexaenoic acid Etc.
  • oleic acid, linoleic acid, linolenic acid, palmitoleic acid, and elaidic acid are preferred, and oleic acid is more preferred.
  • the fatty acid may be a mixture of unsaturated fatty acids obtained from natural fats and oils such as sunflower oil, soybean oil, olive oil, rapeseed oil, cottonseed oil or tall oil.
  • the fatty acid residue is particularly preferably derived from a linear monounsaturated fatty acid.
  • the polyoxyalkylene alkyl ether is represented by the following formula (2).
  • R 2 is an alkyl group having 10 to 14 carbon atoms.
  • the alkyl group having 10 to 14 carbon atoms is preferably linear or branched, and examples thereof include a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a tetradecyl group, and branched isomers thereof.
  • a 2 is an alkanediyl group having 2 to 4 carbon atoms.
  • alkanediyl group having 2 to 4 carbon atoms include ethane-1,2-diyl group, propane-1,2-diyl group, propane-1,3-diyl group, butane-1,2-diyl group, butane -1,3-diyl group, butane-1,4-diyl group and the like.
  • each A 2 may be the same as or different from each other.
  • n represents the average number of —A 2 —O— groups and is an integer of 1 to 100, preferably 5 to 80, more preferably 10 to 50.
  • polyoxyalkylene alkyl ether represented by the formula (2) examples include polyoxyethylene isodecyl ether, polyoxyethylene tridecyl ether, polyoxyethylene (C12-14) secondary alcohol ether, and polyoxyalkylene branched decyl ether. Etc. are preferred.
  • esterified polyol alkoxylate represented by the formula (1A) a commercially available product can be used, and specific examples thereof include Atplus (registered trademark) UEP-100 manufactured by Croda.
  • esterified polyol alkoxylate represented by the formula (1B) a commercially available product can be used. Specific examples thereof include Neugen (registered trademark) GIS series (GIS-108 manufactured by Daiichi Kogyo Seiyaku Co., Ltd.). Etc.).
  • Commercially available products can be used as the esterified polyol alkoxylate represented by the formula (1C), and specific examples thereof include Croda's Tween (registered trademark) 20, 21, 80, and the like.
  • polyoxyalkylene alkyl ether represented by the formula (2) a commercially available product can be used. Specific examples thereof include Neugen (registered trademark) SD series (SD-110 manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.). SD-70 etc.), TDS series (TDS-80, TDS-120 etc.), ET series (ET-135, ET-69, ET-109, ET-129, ET-149, ET-159 etc.), XL Series (XL-40, XL-100 etc.), TDX series (TDX-50, TDX-100D, TDX-120D etc.) etc. are mentioned.
  • Neugen registered trademark
  • SD series SD-110 manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.
  • TDS-80, TDS-120 etc. TDS series
  • ET series ET-135, ET-69, ET-109, ET-129, ET-149, ET-159 etc.
  • XL Series XL-40, XL-100
  • the esterified polyol alkoxylate represented by the formula (1A) and the esterified polyol alkoxy represented by the formula (1B) Among the rates, the HLB value calculated by the Griffin equation is about 12 to 17, and the esterified polyol alkoxylate represented by the formula (1C) has an HLB value calculated by the Griffin equation of about 12 to 17, Of the polyoxyalkylene alkyl ethers represented by the formula (2), those having an HLB value calculated by the Griffin formula of about 11 to 16 are preferred, and the esterified polyol alkoxylate represented by the formula (1A) is more preferred.
  • the content of the adjuvant is preferably 0.01 to 25% by mass in the composition of the present invention.
  • the lower limit of the content of the adjuvant is more preferably 0.1% by mass, even more preferably 0.5% by mass, still more preferably 1% by mass, and most preferably 3% by mass. Further, the upper limit is more preferably 25% by mass, still more preferably 20% by mass, still more preferably 15% by mass, and most preferably 13% by mass.
  • An adjuvant may be used individually by 1 type and may be used in combination of 2 or more type. When using in combination of 2 or more types, the ratio is arbitrary.
  • a dispersing agent is a component for disperse
  • (C) Although it does not specifically limit as a dispersing agent, For example, (meth) acrylic acid graft copolymer which has an alkylene oxide chain in a side chain; Alcohol start EO / PO block copolymer; Polyoxyethylene polyoxypropylene block copolymer; Polyoxy Ethylene styryl phenyl ether; alkyd polyethylene oxide resin; polyvinyl alcohol resin; alcohol alkoxylate; lignosulfonate; formaldehyde condensate of naphthalene sulfonate or alkyl naphthalene sulfonate; condensed methyl naphthalene sulfonate; alkylphenol, formaldehyde and optional And an anionic condensate of sodium sulfite; a salt of
  • Examples of the (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain include a (meth) acrylic acid graft copolymer having an ethylene oxide chain or a propylene oxide chain in the side chain.
  • Examples of the alcohol-initiated EO / PO block copolymer include 4-butoxy-1-butanol-initiated EO / PO block copolymer.
  • polyoxyethylene polyoxypropylene block copolymer or polyoxyethylene styryl phenyl ether those having an HLB value calculated by the Griffin equation of about 7 to 17 are particularly preferable from the viewpoint of suppressing particle growth. .
  • a commercially available product can be used as the dispersing agent, and specific examples thereof include an Atlox (registered trademark) 4913 manufactured by Croda as a (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain. Is mentioned.
  • Examples of alcohol-initiated EO / PO block copolymers include Atlas (registered trademark) G-5000 and G-5002L manufactured by Croda, SYNPERONIC (registered trademark) PE / L 62, PE / L 44, PE / F 127 manufactured by Croda, PE / L 31 etc. are mentioned.
  • Examples of the polyoxyethylene styryl phenyl ether include Solpol (registered trademark) T20 manufactured by Toho Chemical Industry Co., Ltd.
  • Examples of the mixture of the polyoxyethylene styryl phenyl ether and the polyoxyethylene polyoxypropylene block copolymer include Solpol 3353 manufactured by Toho Chemical Industry Co., Ltd.
  • Examples of the polyoxyethylene polyoxypropylene block copolymer include Pluronic (registered trademark) PE series manufactured by BASF, New Pole PE series manufactured by Sanyo Chemical Industries, Ltd., and the like.
  • the content of the dispersant is preferably 0.1 to 15% by mass in the composition of the present invention.
  • the lower limit of the content of the dispersant is more preferably 0.2% by mass, still more preferably 0.3% by mass, still more preferably 0.4% by mass, and most preferably 0.5% by mass.
  • the upper limit is more preferably 7.5% by mass, even more preferably 5% by mass, still more preferably 4% by mass, and most preferably 3% by mass.
  • a dispersing agent may be used individually by 1 type, and may be used in combination of 2 or more type. When using in combination of 2 or more types, the ratio is arbitrary.
  • the dispersant is preferably an alcohol-initiated EO / PO block copolymer or a polyoxyethylene polyoxypropylene block copolymer, and more preferably an alcohol-initiated EO / PO block copolymer.
  • a block copolymer dispersant When the block copolymer dispersant is used, the block copolymer dispersant may be added so that the ratio of the content of the component (a) which is an agrochemical active ingredient to the content of the block copolymer dispersant is 15 or less.
  • the block copolymer dispersant is more preferably added to be 14 or less, still more preferably 13 or less, still more preferably 12 or less, and 11.5 or less. Most preferably, it is added.
  • the block copolymer dispersant in such an added amount, the growth rate of the particles can be made smaller.
  • the minimum of the said ratio is not specifically limited, Usually, it is about 3 and 5 or more are preferable.
  • composition of the present invention may further contain various adjuvants.
  • the auxiliary agent is not particularly limited as long as it is used in an aqueous suspension agricultural chemical composition, and specifically, a thickener, an antifreezing agent, an antifoaming agent, an antifungal and antifungal agent, a coloring agent. Agents and the like.
  • the thickener is not particularly limited, and organic, inorganic natural products, synthetic products, and semi-synthetic products can be used.
  • heteropolysaccharides such as xanthan gum, welan gum, and rhamzan gum
  • polyvinyl alcohol, polyvinyl pyrrolidone poly Water-soluble polymer compounds such as acrylic acid, sodium polyacrylate and polyacrylamide
  • cellulose derivatives such as methylcellulose, carboxymethylcellulose, carboxyethylcellulose, hydroxyethylcellulose and hydroxypropylcellulose
  • thickeners may be used alone or in combination of two or more, and the ratio in the case of mixing can be freely selected. These thickeners may be added as they are, or those previously dispersed in water may be added. In the composition of the present invention, the content of the thickener is not particularly limited as long as the effects of the present invention are not impaired.
  • the antifreezing agent examples include ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, 1,3-propanediol, polyethylene glycol, sorbitol, glycerol and the like.
  • ethylene glycol, diethylene glycol, propylene glycol, and 1,3-propanediol are preferable, and propylene glycol is more preferable because the growth rate of particles can be reduced.
  • the antifreezing agent When the antifreezing agent is included, its content is not particularly limited as long as the effect of the present invention is not impaired, but 1 to 30% by mass is preferable in the composition of the present invention.
  • the lower limit of the content is more preferably 2% by mass, even more preferably 3% by mass, still more preferably 4% by mass, and most preferably 5% by mass.
  • the upper limit is more preferably 25% by mass, still more preferably 20% by mass, still more preferably 15% by mass, and most preferably 10% by mass.
  • the antifreezing agent may be used alone or in combination of two or more. When using in combination of 2 or more types, the ratio is arbitrary.
  • an antifoaming agent such as a silicone-based emulsion, an antibacterial and antifungal agent, a coloring agent, and the like may be blended within a range not impairing the effects of the present invention.
  • the method for producing the composition of the present invention is not particularly limited.
  • the composition can be obtained by adding the above-described components to water and mixing with a stirrer.
  • the pesticidal active ingredient, adjuvant, dispersant and other adjuvants may be pulverized by a dry or wet pulverizer alone or in combination.
  • Dry pulverization can be performed with an impact pulverizer, a ball mill, a jet mill or the like.
  • the fine pulverization by wet pulverization can be performed by a wet pulverizer such as an attritor, a sand grinder, a dyno mill, a pearl mill, an apex mill, a visco mill, or an ultra visco mill.
  • composition of the present invention is, for example, a method in which it is directly sprayed on a paddy field as it is, or a method in which it is diluted 50 to 5,000 times with water and sprayed on a crop or soil in which it grows using a sprayer or the like. It can be applied from the air by using a helicopter, drone, etc., in the form of a raw solution or by diluting it with water to about 2 to 100 times.
  • Preparation of Pregel [Preparation Example 1] Preparation of Prigel A To 98.5 parts by mass of water, 1.0 part by mass of xanthan gum (trade name: KELZAN S, CP Kelco) and 1,2-benzisothiazoline-3 -On (trade name: PROXEL GXL, Lonza) 0.5 parts by mass was dispersed in this order to obtain 100 parts by mass of pregel A.
  • xanthan gum trade name: KELZAN S, CP Kelco
  • 1,2-benzisothiazoline-3 -On trade name: PROXEL GXL, Lonza
  • Preparation Example 2 Preparation of pregel B 4.00 parts by mass of smectite clay (trade name: VEEGUM R, manufactured by R. T. Vanderbilt) was dispersed in 96.0 parts by mass of water to obtain 100 parts by mass of pregel B.
  • smectite clay trade name: VEEGUM R, manufactured by R. T. Vanderbilt
  • Example 1-1 Preparation of aqueous suspension agricultural chemical composition
  • A1 Preparation of pulverized slurry In 17.04 parts by mass of water, 1.50 parts by mass of an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda), butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 1. 50 parts by mass, silicone-based antifoaming agent (trade name: Xiameter AFE-1530 Antifoam Emulsion, manufactured by DOW CORNING) 0.30 part by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96.
  • acrylic copolymer solution trade name: Atlox 4913, manufactured by Croda
  • butyl block copolymer trade name: Atlas G-5002L, manufactured by Croda
  • silicone-based antifoaming agent trade name: Xiameter AFE-1530 Antifoam Emulsion, manufactured by DOW CORNING
  • dispersion medium To 44.45 parts by mass of water, 0.10 parts by mass of 1,2-benzoisothiazolin-3-one (trade name: PROXEL GXL, manufactured by Lonza), xanthan gum (trade name: KELZAN, manufactured by CP Kelco) ) 0.15 parts by mass and 0.30 parts by mass of smectite clay (trade name: VEEGUM R, manufactured by RT Vanderbilt) were dispersed in this order to obtain 45 parts by mass of dispersion medium A.
  • PROXEL GXL manufactured by Lonza
  • xanthan gum trade name: KELZAN, manufactured by CP Kelco
  • smectite clay trade name: VEEGUM R, manufactured by RT Vanderbilt
  • Aqueous Suspended Pesticide Composition 45 parts by weight of pulverized slurry A, 45 parts by weight of dispersion medium A and 10 parts by weight of alkoxylated polyol ester (trade name: Atplus UEP-100, manufactured by Croda) are mixed to form a uniform aqueous suspension. 100 parts by mass of a pesticide composition A1 was obtained.
  • Example 1-2 Preparation of aqueous suspension agricultural chemical composition A2 1.50 parts by mass of an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) and a butyl block copolymer (trade name: Atlas G-5002L, Croda) Example 1-1 except that in place of 1.50 parts by mass of polyoxyethylene styryl phenyl ether (trade name: Solpol T-20, manufactured by Toho Chemical Co., Ltd.) of 3.00 parts by mass In the same manner as above, 100 parts by mass of the aqueous suspended agricultural chemical composition A2 was obtained.
  • an acrylic copolymer solution trade name: Atlox 4913, manufactured by Croda
  • a butyl block copolymer trade name: Atlas G-5002L, Croda
  • Example 1-1 except that in place of 1.50 parts by mass of polyoxyethylene styryl phenyl ether (trade name: Solpol T-20, manufactured by Toho Chemical Co., Ltd.) of 3.00 parts by mass
  • Example 1-3 Preparation of aqueous suspension pesticide composition A3
  • pulverized slurry In 22.20 parts by mass of water, 3.00 parts by mass of a mixture of polyoxyethylene styryl phenyl ether and polyoxyethylene polyoxypropylene block copolymer (trade name: Solpol 3353, manufactured by Toho Chemical Co., Ltd.) Silicone-based antifoaming agent (trade name: KM-73, manufactured by Shin-Etsu Chemical Co., Ltd.) 0.10 parts by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96.6%) 14.70 parts by mass Was dispersed with a sand grinder (manufactured by AIMEX Co., Ltd.) using 50 mL of 0.8-1.2 mm ⁇ glass beads to obtain 50 parts by mass of pulverized slurry B.
  • a sand grinder manufactured by AIMEX Co., Ltd.
  • dispersion medium In 16.0 parts by mass of water, 14.0 parts by mass of Prigel A, 7.5 parts by mass of Prigel B, and polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 12.5 parts by mass were dispersed in this order to obtain 50 parts by mass of dispersion medium B.
  • Example 1-4 Preparation of aqueous suspension pesticide composition A4
  • Polyoxyethylene tridecyl ether instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition A4 was obtained in the same manner as in Example 1-3, except that (trade name: Neugen TDS-120, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used.
  • Example 1-5 Preparation of aqueous suspension pesticide composition A5
  • Polyoxyethylene tridecyl ether instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition A5 was obtained in the same manner as in Example 1-3 except that (trade name: Neugen TDS-80, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used.
  • Example 1-6 Preparation of aqueous suspension pesticide composition A6
  • Example 1-7 Preparation of aqueous suspension agricultural chemical composition A7
  • Polyoxyalkylene branched decyl ether instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition A7 was obtained in the same manner as in Example 1-3, except that (trade name: Neugen XL-100, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used.
  • Example 1-8 Preparation of aqueous suspension pesticide composition B1 Preparation of pulverized slurry To 17.04 parts by mass of water, 3.00 parts by mass of polyoxyethylene styryl phenyl ether (trade name: Solpol T-20, manufactured by Toho Chemical Co., Ltd.), silicone antifoaming agent (trade name: KM-73 (manufactured by Shin-Etsu Chemical Co., Ltd.) 0.30 parts by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96.9%) 14.66 parts by mass were dispersed to obtain 0.8-1. Using 50 mL of 0.2 mm ⁇ glass beads, wet grinding was performed with a sand grinder (manufactured by IMEX Co., Ltd.) to obtain 45 parts by mass of pulverized slurry C.
  • a sand grinder manufactured by IMEX Co., Ltd.
  • Aqueous Suspended Pesticide Composition 45 parts by weight of the slurry C45, 45 parts by weight of the dispersion medium C, and 10 parts by weight of trisiloxane ethoxylate (trade name: Silwet L-77, manufactured by Momentive Performance Materials Inc.) 100 parts by mass of the aqueous suspended agricultural chemical composition B1 was obtained.
  • aqueous suspension pesticide composition of the present invention has good storage stability because particle growth of the pesticidal active ingredient during storage is suppressed.
  • aqueous suspension agricultural chemical composition 90.64 parts by mass of pulverized slurry D, 0.15 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) and alkoxylated polyol ester (trade name: Atplus UEP-100, Croda) 9) 21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition C1.
  • Example 3-2 Preparation of aqueous suspension agricultural chemical composition C2
  • Water and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) were used in amounts of 60.81 parts by mass and 1.50 parts by mass, respectively.
  • the amount of the obtained pulverized slurry and xanthan gum (trade name: KELZAN, CP Kelco) was 90.24 parts by mass and 0.55 parts by mass, respectively.
  • 100 parts by mass of the aqueous suspended agricultural chemical composition C2 was obtained.
  • Example 3-3 Preparation of aqueous suspension agricultural chemical composition C3
  • the amounts of water, butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) and compound A (purity 96.3%) were used.
  • 100 parts by weight of an aqueous suspended agricultural chemical composition C3 was obtained in the same manner as in Example 3-1, except that the amount was 63.43 parts by weight, 1.50 parts by weight, and 15.00 parts by weight, respectively.
  • Example 3-4 Preparation of aqueous suspension pesticide composition C4
  • Water and butyl block copolymer (trade name: Atlas G-5002L) were used without using an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda).
  • Croda) and Compound A were used in the same manner as in Example 3-1, except that the amounts used were 64.93 parts by weight, 1.50 parts by weight, and 15.00 parts by weight, respectively. 100 mass parts of composition C4 was obtained.
  • Example 3-5 Preparation of aqueous suspension pesticide composition C5
  • the amounts of water and compound A (purity 96.3%) used were 63.43 parts by mass and 15.00 parts by mass, respectively.
  • a polyalkylene oxide block copolymer (Product name: Atlas G-5000, manufactured by Croda) was used except that 1.50 parts by mass were used.
  • 100 parts by mass of the aqueous suspended agricultural chemical composition C5 was obtained.
  • Example 3-6 Preparation of aqueous suspension pesticide composition C6
  • Polyoxyethylene polyoxypropylene block copolymer (trade name: Trade name: Atlas G-5000, manufactured by Croda) instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda) 100 parts by mass of the aqueous suspended agricultural chemical composition C6 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / L 62, manufactured by Croda, HLB: 7) was used.
  • Example 3-7 Preparation of Aqueous Suspended Pesticide Composition C7
  • Polyoxyethylene polyoxypropylene block copolymer (trade name: trade name: Atlas G-5000, manufactured by Croda) instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda) 100 parts by mass of an aqueous suspended agricultural chemical composition C7 was obtained in the same manner as in Example 3-5 except that SYNPERONIC PE / L 44, manufactured by Croda, HLB: 16) was used.
  • Example 3-8 Preparation of aqueous suspension pesticide composition C8 Preparation of pulverized slurry To 17.04 parts by mass of water, 3.00 parts by mass of polyoxyethylene styryl phenyl ether (trade name: Solpol T-20, manufactured by Toho Chemical Co., Ltd., HLB: 13.3), silicone-based antifoaming agent (Product name: Xiameter AFE-1530 Antifoam Emulsion, manufactured by DOW CORNING) 0.30 parts by mass, 10.00 parts by mass of propylene glycol, and 14.66 parts by mass of compound A (purity 96.9%) were dispersed, and 0 Using 0.8-1.2 mm ⁇ glass beads, wet pulverization was performed with a sand grinder (manufactured by IMEX Co., Ltd.) to obtain 45 parts by mass of pulverized slurry E.
  • a sand grinder manufactured by IMEX Co., Ltd.
  • dispersion medium To 44.45 parts by mass of water, 0.10 parts by mass of 1,2-benzoisothiazolin-3-one (trade name: PROXEL GXL, manufactured by Lonza), xanthan gum (trade name: KELZAN, manufactured by CP Kelco) ) 0.15 parts by mass and 0.30 parts by mass of smectite clay (trade name: VEEGUM R, manufactured by RT Vanderbilt) were dispersed in this order to obtain 45 parts by mass of dispersion medium E.
  • PROXEL GXL manufactured by Lonza
  • xanthan gum trade name: KELZAN, manufactured by CP Kelco
  • smectite clay trade name: VEEGUM R, manufactured by RT Vanderbilt
  • Example 3-9 Preparation of aqueous suspension pesticide composition C9
  • pulverized slurry To 13.45 parts by mass of water, 1.50 parts by mass of butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), silicone antifoaming agent (trade name: Xiameter AFE-1530 Antifoam Emulsion, DOW CORNING Co., Ltd.) 0.30 parts by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96.3%) 14.75 parts by mass are dispersed using 0.8-1.2 mm ⁇ glass beads.
  • Wet pulverization was performed with a sand grinder (manufactured by IMEX Co., Ltd.) to obtain 40 parts by mass of pulverized slurry F.
  • dispersion medium To 49.45 parts by mass of water, 0.10 parts by mass of 1,2-benzisothiazolin-3-one (trade name: PROXEL GXL, manufactured by Lonza), xanthan gum (trade name: KELZAN, manufactured by CP Kelco) ) 0.15 parts by mass and smectite clay (trade name: VEEGUM R, RT Vanderbilt) 0.30 parts by mass were dispersed in this order to obtain 50 parts by mass of dispersion medium F.
  • PROXEL GXL manufactured by Lonza
  • xanthan gum trade name: KELZAN, manufactured by CP Kelco
  • smectite clay trade name: VEEGUM R, RT Vanderbilt
  • Example 3-10 Preparation of aqueous suspension agricultural chemical composition C10 Instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2), polyoxy Aqueous suspension pesticide composition in the same manner as in Example 3-9, except that alkylene tridecyl ether (trade name: Neugen TDX-100D, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.5) was used. 100 parts by mass of C10 was obtained.
  • polyoxyethylene isodecyl ether trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2
  • alkylene tridecyl ether trade name: Neugen TDX-100D, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.5
  • Example 3-11 Preparation of aqueous suspension pesticide composition C11 Polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) Aqueous suspension pesticide composition in the same manner as in Example 3-9, except that alkylene tridecyl ether (trade name: Neugen TDX-120D, Daiichi Pharmaceutical Co., Ltd., HLB: 14.3) was used. 100 parts by mass of C11 was obtained.
  • alkylene tridecyl ether trade name: Neugen TDX-120D, Daiichi Pharmaceutical Co., Ltd., HLB: 14.3
  • Example 3-12 Preparation of aqueous suspension pesticide composition C12 Monolauric acid instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) 100 masses of the aqueous suspended agricultural chemical composition C12 was carried out in the same manner as in Example 3-9, except that polyoxyethylene (20) sorbitan (trade name: Tween 20, manufactured by Croda, HLB: 17) was used. I got a part.
  • polyoxyethylene (20) sorbitan trade name: Tween 20, manufactured by Croda, HLB: 17
  • Example 3-13 Preparation of aqueous suspension agricultural chemical composition C13 Monoolein instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2)
  • Aqueous suspension pesticide composition C13 was prepared in the same manner as in Example 3-9 except that acid polyoxyethylene (20) sorbitan (trade name: Tween 80, Croda, HLB: 15) was used. A mass part was obtained.
  • Example 3-14 Preparation of aqueous suspension agricultural chemical composition C14 Monolauric acid instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) Except for using polyoxyethylene (4) sorbitan (trade name: Tween 21, Croda, HLB: 13), 100 mass of the aqueous suspended agricultural chemical composition C14 was obtained in the same manner as in Example 3-9. I got a part.
  • polyoxyethylene isodecyl ether trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2
  • polyoxyethylene (4) sorbitan trade name: Tween 21, Croda, HLB: 13
  • Example 3-15 Preparation of aqueous suspended agricultural chemical composition C15 Isostearic acid instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-9, except that polyoxyethylene glyceryl (trade name: Neugen GIS-108, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., HLB: 12.1) was used. 100 parts by mass of C15 was obtained.
  • polyoxyethylene glyceryl trade name: Neugen GIS-108, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., HLB: 12.1
  • Example 3-16 Preparation of aqueous suspension pesticide composition C16
  • pulverized slurry To 55.08 parts by mass of water, 1.50 parts by mass of butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), 9.21 parts by mass of propylene glycol, and compound A (purity 96.3) %) 15.00 parts by mass were dispersed and wet-pulverized with a sand grinder (manufactured by IMEX Co., Ltd.) using 0.8-1.2 mm ⁇ glass beads to obtain 80.79 parts by mass of pulverized slurry G.
  • a sand grinder manufactured by IMEX Co., Ltd.
  • Kelzan Prigel 1.50 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) is dispersed in 98.50 parts by mass of water to obtain 100 parts by mass of 1.5% by mass Kelzan Prigel. It was.
  • aqueous suspension agricultural chemical composition 80.79 parts by weight of pulverized slurry G, 10 parts by weight of the above-mentioned 1.5% by weight Kelzan Prigel and polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, Daiichi Pharmaceutical Co., Ltd.) Manufactured, HLB: 11.2) 9.21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspension agricultural chemical composition C16.
  • Example 3-17 Preparation of aqueous suspension pesticide composition C17 Polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, manufactured by Daiichi Pharmaceutical Industries, Ltd., HLB: 11.2) Aqueous suspended agricultural chemical composition in the same manner as in Example 3-16, except that alkylene oleyl cetyl ether (trade name: Neugen ET-159, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 11.2) was used. 100 parts by mass of C17 was obtained.
  • alkylene oleyl cetyl ether trade name: Neugen ET-159, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 11.2
  • Example 3-18 Preparation of aqueous suspension pesticide composition C18 Polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-9, except that alkylene oleyl cetyl ether (trade name: Neugen ET-159, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.4) was used. 100 parts by mass of C18 was obtained.
  • alkylene oleyl cetyl ether trade name: Neugen ET-159, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.4
  • Kelzan Prigel 1.50 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) is dispersed in 98.50 parts by mass of water to obtain 100 parts by mass of 1.5% by mass Kelzan Prigel. It was.
  • aqueous suspension agricultural chemical composition 80.79 parts by weight of pulverized slurry H, 10 parts by weight of the above-mentioned 1.5% by weight Kelzan pregel and alkoxylated polyol ester (trade name: Atplus UEP-100, manufactured by Croda) 9.21 parts by weight Were mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition C19.
  • Example 3-20 Preparation of aqueous suspension pesticide composition C20 A butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), except that 7.00 parts by mass was used instead of 5.00 parts by mass In the same manner as in Example 3-19, 100 parts by mass of the aqueous suspended agricultural chemical composition C20 was obtained.
  • a butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), except that 7.00 parts by mass was used instead of 5.00 parts by mass
  • 100 parts by mass of the aqueous suspended agricultural chemical composition C20 was obtained.
  • Example 3-21 Preparation of aqueous suspension pesticide composition C21 A butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), except that 10.00 parts by mass was used instead of 5.00 parts by mass In the same manner as in Example 3-19, 100 parts by mass of the aqueous suspended agricultural chemical composition C21 was obtained.
  • Example 3-22 Preparation of Aqueous Suspension Pesticide Composition C22
  • An acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) was not used, the amount of water used was 55.08 parts by mass, and propylene glycol was used. Instead of using ethylene glycol, 100 parts by mass of an aqueous suspended agricultural chemical composition C22 was obtained in the same manner as in Example 3-19.
  • Example 3-23 Preparation of aqueous suspended agricultural chemical composition C23 Aqueous suspended agricultural chemical composition C23 was prepared in the same manner as in Example 3-22 except that diethylene glycol was used instead of propylene glycol. A mass part was obtained.
  • Example 3-24 Preparation of aqueous suspended pesticidal composition C24 Aqueous suspended pesticidal composition C24 was prepared in the same manner as in Example 3-22, except that dipropylene glycol was used instead of propylene glycol. 100 parts by mass was obtained.
  • Example 3-25 Preparation of aqueous suspended agricultural chemical composition C25 An aqueous suspended agricultural chemical in the same manner as in Example 3-22, except that 1,3-propanediol was used instead of propylene glycol. 100 mass parts of composition C25 were obtained.
  • Example 3-26 Preparation of aqueous suspended pesticidal composition C26 Aqueous suspended pesticidal composition C26 was prepared in the same manner as in Example 3-22, except that polyethylene glycol 400 was used instead of propylene glycol. 100 parts by mass was obtained.
  • Example 3-27 Preparation of aqueous suspension pesticide composition C27 Except that propylene glycol was used, D-sorbitol (trade name: sorbitol F, component weight 60%, manufactured by Food Science Co., Ltd.) was used. In the same manner as in Example 3-22, 100 parts by mass of the aqueous suspended agricultural chemical composition C27 was obtained.
  • Example 4-1 Preparation of aqueous suspension pesticide composition D1
  • pulverized slurry In 59.58 parts by mass of water, 3.68 parts by mass of an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda), butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) is 0.5. 55 parts by mass and 17.22 parts by mass of Compound A (purity 96.3%) were dispersed, wet-ground with a sand grinder (manufactured by Imex Co., Ltd.) using 0.8-1.2 mm ⁇ glass beads, and pulverized 81.03 parts by mass of slurry I were obtained.
  • an acrylic copolymer solution trade name: Atlox 4913, manufactured by Croda
  • butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) is 0.5. 55 parts by mass and 17.22 parts by mass of Compound A (purity 96.3%) were dispersed, wet
  • Aqueous Suspended Pesticide Composition 81.03 parts by weight of pulverized slurry I, 9.21 parts by weight of glycerol, 0.55 parts by weight of xanthan gum (trade name: KELZAN, CP Kelco) and alkoxylated polyol ester (trade name: (Atplus UEP-100, manufactured by Croda) 9.21 parts by mass was mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition D1.
  • Example 4-2 Preparation of aqueous suspension pesticide composition D2 Aqueous suspension pesticide composition D2 was prepared in the same manner as in Example 4-1, except that propylene glycol was used instead of glycerol. A mass part was obtained.
  • Example 4-3 Preparation of Aqueous Suspended Pesticide Composition D3
  • the amounts of water and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) used were 62.21 parts by mass and 0.50, respectively.
  • 100 parts by mass of the aqueous suspended agricultural chemical composition D3 was obtained in the same manner as in Example 3-1, except that the amount was changed to parts by mass.
  • Example 4-4 Preparation of aqueous suspension pesticide composition D4
  • the amounts of water and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) used were 61.71 parts by mass and 1.00, respectively.
  • 100 parts by weight of an aqueous suspended agricultural chemical composition D4 was obtained in the same manner as in Example 3-1, except that the amount was changed to parts by weight.
  • Example 4-5 Preparation of aqueous suspension pesticide composition D5 Water, acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 100 parts by mass of the aqueous suspended pesticide composition D5 in the same manner as in Example 4-1, except that the amount used was 60.81 parts by mass, 1.00 part by mass and 2.00 parts by mass, respectively. I got a part.
  • Example 4-6 Preparation of aqueous suspension pesticide composition D6
  • acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) 1.50 parts by mass
  • butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 1. 50 parts by weight, 9.21 parts by weight of glycerol, and 15.00 parts by weight of Compound A (purity 96.3%) were dispersed, and a sand grinder (manufactured by IMEX Co., Ltd.) using 0.8-1.2 mm ⁇ glass beads. )
  • a sand grinder manufactured by IMEX Co., Ltd.
  • Aqueous Suspended Pesticide Composition 90.64 parts by weight of pulverized slurry J, 0.15 parts by weight of xanthan gum (trade name: KELZAN, CP Kelco) and alkoxylated polyol ester (trade name: Atplus UEP-100, Croda) (Product made) 9.21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition D6.
  • Example 4-7 Preparation of aqueous suspension agricultural chemical composition D7 Instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda), polyoxyethylene polyoxypropylene block copolymer (trade name: 100 parts by mass of the aqueous suspended agricultural chemical composition D7 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / F 127, manufactured by Croda, HLB: 22) was used.
  • polyalkylene oxide block copolymer trade name: Atlas G-5000, manufactured by Croda
  • polyoxyethylene polyoxypropylene block copolymer trade name: 100 parts by mass of the aqueous suspended agricultural chemical composition D7 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / F 127, manufactured by Croda, HLB: 22
  • Example 4-8 Preparation of aqueous suspension agricultural chemical composition D8 Instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda), polyoxyethylene polyoxypropylene block copolymer (trade name: 100 parts by weight of an aqueous suspended agricultural chemical composition D8 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / L 31, Croda, HLB: 22) was used.
  • polyalkylene oxide block copolymer trade name: Atlas G-5000, manufactured by Croda
  • polyoxyethylene polyoxypropylene block copolymer trade name: 100 parts by weight of an aqueous suspended agricultural chemical composition D8 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / L 31, Croda, HLB: 22
  • Example 4-9 Preparation of aqueous suspension pesticide composition D9
  • Polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) instead of polyoxy Aqueous suspension pesticide composition in the same manner as in Example 3-9, except that alkylene tridecyl ether (trade name: Neugen TDX-50, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 9) was used. 100 parts by mass of D9 was obtained.
  • Example 4-10 Preparation of aqueous suspension pesticide composition D10 Polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, manufactured by Daiichi Pharmaceutical Industries, Ltd., HLB: 11.2) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-16 except that alkylene oleyl cetyl ether (trade name: Neugen ET-109, manufactured by Daiichi Pharmaceutical Industries, Ltd., HLB: 8.4) was used. 100 parts by mass of D10 was obtained.
  • alkylene oleyl cetyl ether trade name: Neugen ET-109, manufactured by Daiichi Pharmaceutical Industries, Ltd., HLB: 8.4
  • Example 4-11 Preparation of aqueous suspension pesticide composition D11 Polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 11.2) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-16 except that alkylene oleyl cetyl ether (trade name: Neugen ET-129, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 10.2) was used. 100 parts by mass of D11 was obtained.
  • alkylene oleyl cetyl ether trade name: Neugen ET-129, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 10.2
  • Example 4-12 Preparation of aqueous suspension pesticide composition D12 Trisiloxane ethoxylate (product) instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition D12 was obtained in the same manner as in Example 3-9 except that Silwet L-77 (manufactured by Momentive Performance Materials Inc.) was used.
  • Kelzan Prigel 1.50 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) is dispersed in 98.50 parts by mass of water to obtain 100 parts by mass of 1.5% by mass Kelzan Prigel. It was.
  • Aqueous Suspended Agricultural Composition 80.79 parts by weight of pulverized slurry K, 10 parts by weight of 1.5% by weight Kelzan Prigel and polyoxyalkylene tridecyl ether (trade name: Neugen TDX-50, Daiichi Pharmaceutical Co., Ltd.) Manufactured, HLB: 9) 9.21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspension agricultural chemical composition E1.
  • Comparative Example 1-3 Preparation of Aqueous Suspended Pesticide Composition E3 Trisiloxane instead of polyoxyalkylene tridecyl ether (trade name: Neugen TDX-50, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 9) 100 parts by weight of an aqueous suspended agricultural chemical composition E3 was obtained in the same manner as in Comparative Example 1-1 except that ethoxylate (trade name: Silwet L-77, manufactured by Momentive Performance Materials Inc.) was used.
  • ethoxylate trade name: Silwet L-77, manufactured by Momentive Performance Materials Inc.
  • aqueous suspension pesticide composition of the present invention has good storage stability because the particle growth of the pesticidal active ingredient during storage is suppressed.

Abstract

Provided is an aqueous suspended agrochemical composition including: (a) an agrochemically active ingredient containing (Z)-N-[2-(3-chloro-5-[cyclopropylethynyl]pyridine-2-yl)-2-(isopropoxy-imino)ethyl]-3-(difluoro methyl)-1-methyl-1H-pyrazole-4-carboxamide; (b) an adjuvant; and (c) a dispersant.

Description

水性懸濁状農薬組成物Aqueous suspension pesticide composition
　本発明は、水性懸濁状農薬組成物に関する。 The present invention relates to an aqueous suspension agricultural chemical composition.
　農薬活性成分を水に分散・懸濁させた水性懸濁状農薬組成物は、保存中に凝集や再結晶等により農薬活性成分の粒子が成長するという問題を有しており、時として生物活性の低下を招く場合がある。 Aqueous suspended pesticidal compositions in which pesticidal active ingredients are dispersed and suspended in water have the problem that pesticidal active ingredient particles grow during storage due to aggregation, recrystallization, etc., and sometimes biologically active May be reduced.
　農薬活性成分の粒子成長を防止又は抑制する手段としては、石油樹脂、クマロン樹脂、エステルガム等の樹脂を配合する方法（例えば、特許文献１及び２参照）が知られている。また、樹脂と特定の平均分子量を有するリグニンスルホン酸塩とを配合することで、保存中の農薬活性成分の粒子成長がより抑制されるとともに、高温での保存中に組成物の流動性が悪化しないことが知られている（例えば、特許文献３参照）。しかしながら、農薬活性成分の種類や保存条件によっては、十分に粒子成長を抑制できない場合があった。 As a means for preventing or suppressing the particle growth of the agrochemical active ingredient, a method of blending a resin such as petroleum resin, coumarone resin, ester gum or the like (for example, see Patent Documents 1 and 2) is known. In addition, compounding a resin and a lignin sulfonate having a specific average molecular weight further suppresses the particle growth of active agricultural chemical ingredients during storage and deteriorates the fluidity of the composition during storage at high temperatures. It is known not to do so (for example, see Patent Document 3). However, depending on the type and storage conditions of the pesticidal active ingredient, particle growth may not be sufficiently suppressed.
特開昭５２－１４８６２５号公報JP 52-148625 A 特開平９－１７５９０４号公報Japanese Patent Laid-Open No. 9-175904 国際公開第２００７／１４５２２１号International Publication No. 2007/145221 国際公開第２０１５／１１９２４６号International Publication No. 2015/119246 特表２０１６－５０１１９７号公報Special table 2016-501197
　本発明は、前記問題に鑑みなされたものであり、農薬活性成分の粒子成長が抑制され、保存安定性が良好な水性懸濁状農薬組成物を提供することを目的とする。 The present invention has been made in view of the above problems, and an object of the present invention is to provide an aqueous suspended agricultural chemical composition in which particle growth of an agricultural chemical active ingredient is suppressed and storage stability is good.
　本発明者らは、前記課題を解決すべく鋭意検討を重ねた結果、(Ｚ)－Ｎ－[２－(３－クロロ－５－[シクロプロピルエチニル]ピリジン－２－イル)－２－(イソプロポキシイミノ)エチル]－３－(ジフルオロメチル)－１－メチル－１Ｈ－ピラゾール－４－カルボキサミドを農薬活性成分として含む水性懸濁状農薬組成物に、所定のアジュバント及び分散剤を添加することで、前記農薬活性成分の粒子成長が抑制され、保存安定性が良好であることを見出し、本発明を完成した。 As a result of intensive studies to solve the above problems, the present inventors have found that (Z) -N- [2- (3-chloro-5- [cyclopropylethynyl] pyridin-2-yl) -2- ( A predetermined adjuvant and dispersant are added to an aqueous suspension pesticide composition containing isopropoxyimino) ethyl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide as an agrochemical active ingredient. Thus, the present inventors have found that the particle growth of the pesticidal active ingredient is suppressed and the storage stability is good, and the present invention has been completed.
　すなわち、本発明は、下記水性懸濁状農薬組成物を提供する。
１．（ａ）(Ｚ)－Ｎ－[２－(３－クロロ－５－[シクロプロピルエチニル]ピリジン－２－イル)－２－(イソプロポキシイミノ)エチル]－３－(ジフルオロメチル)－１－メチル－１Ｈ－ピラゾール－４－カルボキサミドを含む農薬活性成分、
（ｂ）アジュバント、及び
（ｃ）分散剤
を含む水性懸濁状農薬組成物。
２．（ｂ）アジュバントが、下記式（１Ａ）、（１Ｂ）又は（１Ｃ）で表されるエステル化ポリオールアルコキシレート、並びに下記式（２）で表されるポリオキシアルキレンアルキルエーテルから選ばれる少なくとも１種である１の水性懸濁状農薬組成物。
Figure JPOXMLDOC01-appb-C000002
 （式中、ＰOAは、トリメチロールプロパンの残基であり；
　ＰOBは、グリセロールの残基であり；
　ＰOCは、ソルビタンの残基であり；
　Ｒ1は、それぞれ独立に、水素原子、又は－Ｃ(＝Ｏ)－Ｒ1'（式中、Ｒ1'は、炭素数１～２８の１価炭化水素基である。）であるが、少なくとも１つは－Ｃ(＝Ｏ)－Ｒ1'であり；
　Ｒ2は、炭素数１０～１４のアルキル基であり；
　Ａ1は、炭素数２～４のアルカンジイル基であり；
　Ａ2は、炭素数２～４のアルカンジイル基であり；
　ｍは、それぞれ独立に、１～１００の整数であり；
　ｎは、１～１００の整数である。）
３．（ｂ）アジュバントが、式（１Ａ）、（１Ｂ）又は（１Ｃ）で表されるエステル化ポリオールアルコキシレート、ポリオキシエチレンイソデシルエーテル、ポリオキシエチレントリデシルエーテル、ポリオキシエチレン(C12-14)第２級アルコールエーテル及びポリオキシアルキレン分岐デシルエーテルから選ばれる少なくとも１種である２の水性懸濁状農薬組成物。
４．（ｂ）アジュバントが、少なくとも式（１Ａ）で表されるエステル化ポリオールアルコキシレートを含む３の水性懸濁状農薬組成物。
５．（ｃ）分散剤が、アルキレンオキシド鎖を側鎖に有する(メタ)アクリル酸グラフトコポリマー、アルコール開始ＥＯ／ＰＯブロックコポリマー、ポリオキシエチレンポリオキシプロピレンブロックコポリマー、及びポリオキシエチレンスチリルフェニルエーテルから選ばれる少なくとも１種である１～４のいずれかの水性懸濁状農薬組成物。
６．（ｃ）分散剤が、少なくともアルコール開始ＥＯ／ＰＯブロックコポリマーを含む５の水性懸濁状農薬組成物。
７．（ａ）成分の含有量の、前記アルコール開始ＥＯ／ＰＯブロックコポリマーの含有量に対する比が、１５以下である６の水性懸濁状農薬組成物。
８．更に、凍結防止剤を含む１～７のいずれかの水性懸濁状農薬組成物。
９．前記凍結防止剤が、プロピレングリコールである８の水性懸濁状農薬組成物。
１０．水性懸濁状農薬組成物中の凍結防止剤の含有量が、１～３０質量％である８又は９の水性懸濁状農薬組成物。
１１．水性懸濁状農薬組成物中の(Ｚ)－Ｎ－[２－(３－クロロ－５－[シクロプロピルエチニル]ピリジン－２－イル)－２－(イソプロポキシイミノ)エチル]－３－(ジフルオロメチル)－１－メチル－１Ｈ－ピラゾール－４－カルボキサミドの含有量が、０.１～３０質量％である１～１０のいずれかの水性懸濁状農薬組成物。
１２．水性懸濁状農薬組成物中のアジュバントの含有量が、０.０１～２５質量％である１～１１のいずれかの水性懸濁状農薬組成物。
１３．水性懸濁状農薬組成物中の分散剤の含有量が、０.１～１５質量％である１～１２のいずれかの水性懸濁状農薬組成物。 That is, the present invention provides the following aqueous suspension pesticide composition.
1. (A) (Z) -N- [2- (3-Chloro-5- [cyclopropylethynyl] pyridin-2-yl) -2- (isopropoxyimino) ethyl] -3- (difluoromethyl) -1- Agrochemical active ingredients including methyl-1H-pyrazole-4-carboxamide,
An aqueous suspension pesticide composition comprising (b) an adjuvant and (c) a dispersant.
2. (B) The adjuvant is at least one selected from an esterified polyol alkoxylate represented by the following formula (1A), (1B) or (1C) and a polyoxyalkylene alkyl ether represented by the following formula (2) The aqueous suspension pesticide composition of 1.
Figure JPOXMLDOC01-appb-C000002
 Where P OA is the residue of trimethylolpropane;
P OB is a residue of glycerol;
P OC is a sorbitan residue;
Each R 1 is independently a hydrogen atom or —C (═O) —R 1 ′ (wherein R 1 ′ is a monovalent hydrocarbon group having 1 to 28 carbon atoms). At least one is —C (═O) —R 1 ′;
R 2 is an alkyl group having 10 to 14 carbon atoms;
A 1 is an alkanediyl group having 2 to 4 carbon atoms;
A 2 is an alkanediyl group having 2 to 4 carbon atoms;
m is each independently an integer of 1 to 100;
n is an integer of 1 to 100. )
3. (B) The adjuvant is an esterified polyol alkoxylate represented by the formula (1A), (1B) or (1C), polyoxyethylene isodecyl ether, polyoxyethylene tridecyl ether, polyoxyethylene (C12-14) 2. An aqueous pesticide composition according to 2, which is at least one selected from secondary alcohol ethers and polyoxyalkylene branched decyl ethers.
4). (B) The aqueous suspension pesticide composition according to 3, wherein the adjuvant contains at least an esterified polyol alkoxylate represented by the formula (1A).
5). (C) The dispersant is selected from a (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain, an alcohol-initiated EO / PO block copolymer, a polyoxyethylene polyoxypropylene block copolymer, and a polyoxyethylene styryl phenyl ether The aqueous suspension agricultural chemical composition according to any one of 1 to 4, which is at least one kind.
6). (C) The aqueous suspension pesticide composition of 5, wherein the dispersant comprises at least an alcohol-initiated EO / PO block copolymer.
7). 6. The aqueous suspended pesticidal composition according to 6, wherein the ratio of the content of the component (a) to the content of the alcohol-initiated EO / PO block copolymer is 15 or less.
8). The aqueous suspension agricultural chemical composition according to any one of 1 to 7, further comprising an antifreezing agent.
9. 8. The aqueous suspension pesticide composition according to 8, wherein the cryoprotectant is propylene glycol.
10. 8. The aqueous suspension pesticide composition according to 8 or 9, wherein the content of the cryoprotectant in the aqueous suspension pesticide composition is 1 to 30% by mass.
11. (Z) -N- [2- (3-Chloro-5- [cyclopropylethynyl] pyridin-2-yl) -2- (isopropoxyimino) ethyl] -3- (in aqueous suspension pesticide composition The aqueous suspended pesticidal composition according to any one of 1 to 10, wherein the content of (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide is 0.1 to 30% by mass.
12 The aqueous suspended pesticidal composition according to any one of 1 to 11, wherein the content of the adjuvant in the aqueous suspended pesticidal composition is 0.01 to 25% by mass.
13. The aqueous suspended pesticidal composition according to any one of 1 to 12, wherein the content of the dispersant in the aqueous suspended pesticidal composition is 0.1 to 15% by mass.
　本発明の水性懸濁状農薬組成物は、保存中の農薬活性成分の粒子成長が抑制され、保存安定性に優れる。 The aqueous suspension pesticide composition of the present invention is excellent in storage stability because particle growth of the pesticide active ingredient during storage is suppressed.
　本発明の水性懸濁状農薬組成物は、（ａ）農薬活性成分、（ｂ）アジュバント、及び（ｃ）分散剤を含む。 The aqueous suspension pesticide composition of the present invention comprises (a) an agrochemical active ingredient, (b) an adjuvant, and (c) a dispersant.
［（ａ）農薬活性成分］
　（ａ）成分の農薬活性成分は、下記式（Ａ）で表される(Ｚ)－Ｎ－[２－(３－クロロ－５－[シクロプロピルエチニル]ピリジン－２－イル)－２－(イソプロポキシイミノ)エチル]－３－(ジフルオロメチル)－１－メチル－１Ｈ－ピラゾール－４－カルボキサミド［一般名：ピラプロポイン（pyrapropoyne）。以下、化合物Ａともいう。］を含むものであり、例えば国際公開第２０１４／０１０７３７号や特開２０１６－０１１２８６号公報に記載されている。
Figure JPOXMLDOC01-appb-C000003
 [(A) Agrochemical active ingredient]
The agrochemical active ingredient of component (a) is represented by the following formula (A): (Z) -N- [2- (3-chloro-5- [cyclopropylethynyl] pyridin-2-yl) -2- ( Isopropoxyimino) ethyl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide [generic name: pyrapropoyne. Hereinafter also referred to as Compound A. ], For example, described in International Publication No. 2014/010737 and Japanese Patent Application Laid-Open No. 2016-011286.
Figure JPOXMLDOC01-appb-C000003
　（ａ）農薬活性成分は、化合物Ａ以外のその他の農薬活性成分を含んでもよい。その他の農薬活性成分としては、他の殺菌剤、殺虫剤、殺ダニ剤、殺線虫剤、駆虫剤、抗真菌剤、抗菌剤等が挙げられる。 (A) The pesticidal active ingredient may contain other pesticidal active ingredients other than Compound A. Other agrochemical active ingredients include other fungicides, insecticides, acaricides, nematicides, anthelmintic agents, antifungal agents, antibacterial agents and the like.
　その他の農薬活性成分としては、例えば、ザ・ペスティサイド・マニュアル（The Pesticide Manual）１５版、２００９年等に記載されている化合物等が挙げられる。具体的にその一般名を例示すれば次のとおりであるが、これらに限定されない。 Examples of other agrochemical active ingredients include compounds described in The Pesticide Manual, 15th edition, 2009, and the like. Specific examples of the general name are as follows, but the general name is not limited thereto.
　殺菌剤としては、アシベンゾラル－Ｓ－メチル（acibenzolar-S-methyl）、アシペタックス（acypetacs）、アルジモルフ（aldimorph）、アリルアルコール（allyl alcohol）、アメトクトラジン（ametoctradin）、アミノピリフェン（aminopyrifen）、アミスルブロム（amisulbrom）、アンバム（amobam）、アムプロピルホス（ampropylfos）、アニラジン（anilazine）、アザコナゾール（azaconazole）、アジチラム（azithiram）、アゾキシストロビン（azoxystrobin）、バリウムポリサルファイド（barium polysulfide）、ベナラキシル（benalaxyl）、ベナラキシル－Ｍ（benalaxyl-M）、ベノダニル（benodanil）、ベノミル（benomyl）、ベンキノックス（benquinox）、ベンタルロン（bentaluron）、ベンチアバリカルブ－イソプロピル（benthiavalicarb-isopropyl）、ベンチアゾール（benthiazole）、ベンザマクリル（benzamacril）、ベンザモルフ（benzamorf）、ベンゾビンディフルピル（benzovindiflupyr）、ビナパクリル（binapacryl）、ビフェニル（biphenyl）、ビテルタノール（bitertanol）、ビキサフェン（bixafen）、ブラストサイジン－Ｓ（blasticidin-S）、ボルドー液（bordeaux mixture）、ボスカリド（boscalid）、ブロムコナゾール（bromoconazole）、ブピリメート（bupirimate）、ブチオベート（buthiobate）、ブチルアミン（butylamine）、石灰硫黄合剤（calcium polysulfide）、キャプタフォール（captafol）、キャプタン（captan）、カルバモルフ（carbamorph）、カルベンダジム（carbendazim）、カルボキシン（carboxin）、カルプロパミド（carpropamid）、カルボン（carvone）、チェシュントミクスチャ（cheshunt mixture）、キノメチオネート（chinomethionat）、クロベンチアゾン（chlobenthiazone）、クロラニフォルメタン（chloraniformethane）、クロラニル（chloranil）、クロルフェナゾール（chlorfenazole）、クロロネブ（chloroneb）、クロルピクリン（chloropicrin）、クロロタロニル（chlorothalonil）、クロルキノックス（chlorquinox）、クロゾリネート（chlozolinate）、クリムバゾール（climbazole）、カッパーアセテイト（copper acetate）、塩基性炭酸銅（copper carbonate, basic）、水酸化第二銅（copper hydroxide）、カッパーナフテネート（copper naphthenate）、カッパーオレエート（copper oleate）、塩基性塩化銅（copper oxychloride）、硫酸銅（copper sulfate）、塩基性硫酸銅（copper sulfate, basic）、カッパージンククロメイト（copper zinc chromate）、クモキシストロビン（coumoxystrobin）、クレゾール（cresol）、クフラネブ（cufraneb）、クプロバム（cuprobam）、シアゾファミド（cyazofamid）、シクラフラミド（cyclafuramid）、シクロヘキシミド（cycloheximide）、シフルフェナミド（cyflufenamid）、シモキサニル（cymoxanil）、シペンダゾール（cypendazole）、シプロコナゾール（cyproconazole）、シプロジニル（cyprodinil）、シプロフラム（cyprofuram）、ダゾメット（dazomet）、デバカルブ（debacarb）、デカフェンチン（decafentin）、デハイドロアセテイト（dehydroacetic acid）、ジクロベンチアゾクス（dichlobentiazox）、ジクロフルアニド（dichlofluanid）、ジクロン（dichlone）、ジクロロフェン（dichlorophen）、ジクロゾリン（dichlozoline）、ジクロブトラゾール（diclobutrazol）、ジクロシメット（diclocymet）、ジクロメジン（diclomezine）、ジクロラン（dicloran）、ジエトフェンカルブ（diethofencarb）、ジフェノコナゾール（difenoconazole）、ジフルメトリム（diflumetorim）、ジメチリモール（dimethirimol）、ジメトモルフ（dimethomorph）、ジモキシストロビン（dimoxystrobin）、ジニコナゾール（diniconazole）、ジニコナゾール－Ｍ（diniconazole-M）、ジノブトン（dinobuton）、ジノカップ（dinocap）、ジノカップ－４（dinocap-4）、ジノカップ－６（dinocap-6）、ジノクトン（dinocton）、ジノスルフォン（dinosulfon）、ジノテルボン（dinoterbon）、ジフェニルアミン（diphenylamine）、ジピメチトロン（dipymetitrone）、ジピリチオン（dipyrithione）、ジスルフィラム（disulfiram）、ジタリムホス（ditalimfos）、ジチアノン（dithianon）、デーエヌオーシー（DNOC）、ドデモルフ（dodemorph）、ドジン（dodine）、ドラゾキソロン（drazoxolon）、エディフェンホス（edifenphos）、エネストロビン（enestrobin）、エノキサストロビン（enoxastrobin）、エポキシコナゾール（epoxiconazole）、エタボキサム（ethaboxam）、エタコナゾール（etaconazole）、エテム（etem）、エチリモール（ethirimol）、エトキシキン（ethoxyquin）、エトリジアゾール（etridiazole）、ファモキサドン（famoxadone）、フェナミドン（fenamidone）、フェナミノスルフ（fenaminosulf）、フェナミンストロビン（fenaminstrobin）、フェナパニル（fenapanil）、フェナリモル（fenarimol）、フェンブコナゾール（fenbuconazole）、フェンフラム（fenfuram）、フェンヘキサミド（fenhexamid）、フェニトロパン（fenitropan）、フェノキサニル（fenoxanil）、フェンピクロニル（fenpiclonil）、フェンピコキサミド（fenpicoxamid）、フェンプロピジン（fenpropidin）、フェンプロピモルフ（fenpropimorph）、フェンピラザミン（fenpyrazamine）、フェンチン（fentin）、ファーバム（ferbam）、フェリムゾン（ferimzone）、フロリルピコキサミド（florylpicoxamid）、フルアジナム（fluazinam）、フルジオキソニル（fludioxonil）、フルフェノキシストロビン（flufenoxystrobin）、フルインダピル（fluindapyr）、フルメトベル（flumetover）、フルモルフ（flumorph）、フルオピコリド（fluopicolide）、フルオピモミド（fluopimomide）、フルオピラム（fluopyram）、フルオルイミド（fluoroimide）、フルオトリマゾール（fluotrimazole）、フルオキサストロビン（fluoxastrobin）、フルキンコナゾール（fluquinconazole）、フルシラゾール（flusilazole）、フルスルファミド（flusulfamide）、フルトラニル（flutolanil）、フルチアニル（flutianil）、フルトリアホール（flutriafol）、フルキサピロキサド（fluxapyroxad）、フォルペット（folpet）、ホセチル－アルミニウム（fosetyl-aluminium）、フサライド（fthalide）、フベリダゾール（fuberidazole）、フララキシル（furalaxyl）、フラメトピル（furametpyr）、フルカルバニル（furcarbanil）、フルコナゾール（furconazole）、フルコナゾール－シス（furconazole-cis）、フルメシクロックス（furmecyclox）、フロファネート（furophanate）、グリジン（glyodin）、グリセオフルビン（griseofulvin）、グアザチン（guazatine）、ハラクリネート（halacrinate）、ヘキサクロロベンゼン（hexachlorobenzene）、ヘキサコナゾール（hexaconazole）、ヘキシルチオフォス（hexylthiofos）、硫酸オキシキノリン（8-hydroxyquinoline sulfate）、ヒメキサゾール（hymexazol）、イマザリル（imazalil）、イミベンコナゾール（imibenconazole）、イミノクタジン－アルベシル酸塩（iminoctadine-albesilate）、イミノクタジン酢酸塩（iminoctadine-triacetate）、インピルフルキサム（inpyrfluxam）、イオドカルブ（iodocarb）、イプコナゾール（ipconazole）、イプフェントリフルコナゾール（ipfentrifluconazole）、イプフルフェノキン（ipflufenoquin）、イプロベンホス（iprobenfos）、イプロジオン（iprodione）、イプロバリカルブ（iprovalicarb）、イソフェタミド（isofetamid）、イソフルシプラム（isoflucypram）、イソチアニル（isotianil）、イソプロチオラン（isoprothiolane）、イソピラザム（isopyrazam）、イソバレジオン（isovaledione）、カスガマイシン（kasugamycin）、クレソキシム－メチル（kresoxim-methyl）、ラミナリン（laminarin）、マンカッパー（mancopper）、マンコゼブ（ｍａｎｃｏｚｅｂ）、マンデストロビン（mandestrobin）、マンジプロパミド（mandipropamid）、マンネブ（maneb）、メベニル（mebenil）、メカルビンジッド（mecarbinzid）、メフェントリフルコナゾール（mefentrifluconazole）、メパニピリム（mepanipyrim）、メプロニル（mepronil）、メプチルジノカップ（meptyldinocap）、メタラキシル（metalaxyl）、メタラキシル－Ｍ（metalaxyl-M）、メタム（metam）、メタゾキソロン（metazoxolon）、メトコナゾール（metconazole）、メタスルホカルブ（methasulfocarb）、メトフロキサム（methfuroxam）、メチルテトラプロール（metyltetraprole）、メチラム（metiram）、メトミノストロビン（metominostrobin）、メトラフェノン（metrafenone）、メトスルフォバックス（metsulfovax）、ミルネブ（milneb）、ミクロブタニル（myclobutanil）、ミクロゾリン（myclozolin）、ナーバム（nabam）、ナフティフィン（naftifine）、ナタマイシン（natamycin）、有機ニッケル（nickel bis (dimethyldithiocarbamate)）、ニトロスチレン（nitrostyrene）、ニトロタル－イソプロピル（nitrothal-isopropyl）、ヌアリモール（nuarimol）、オクチノリン（octhilinone）、オフレース（ofurace）、オリサストロビン（orysastrobin）、オキサジキシル（oxadixyl）、オキサチアピプロリン（oxathiapiprolin）、オキシキノリン銅（oxine copper）、オキスポコナゾールフマル酸塩（oxpoconazole fumarate）、オキシカルボキシン（oxycarboxin）、ペフラゾエート（pefurazoate）、ペンコナゾール（penconazole）、ペンシクロン（pencycuron）、ペンフルフェン（penflufen）、ペンタクロロフェノール（pentachlorophenol）、ペンチオピラド（penthiopyrad）、オルソフェニルフェノール（2-phenylphenol）、ホスダイフェン（phosdiphen）、フサライド（phthalide）、ピカルブトラゾクス（picarbutrazox）、ピコキシストロビン（picoxystrobin）、ピペラリン（piperalin）、ポリカーバメート（polycarbamate）、ポリオキシン（polyoxins）、ポリオキシン－Ｄ（polyoxorim）、ポタシウムアジド（potassium azide）、炭酸水素カリウム（potassium hydrogen carbonate）、プロベナゾール（probenazole）、プロクロラズ（prochloraz）、プロシミドン（procymidone）、プロパモカルブ塩酸塩（propamocarb hydrochloride）、プロピコナゾール（propiconazole）、プロピネブ（propineb）、プロキナジド（proquinazid）、プロチオカルブ（prothiocarb）、ピラゾホス（pyrazophos）、ピリベンカルブ（pyribencarb）、ピリフェノックス（pyrifenox）、ピリメタニル（pyrimethanil）、ピリミノストロビン（pyriminostrobin）、ピロキロン（pyroquilon）、プロチオカルブ（prothiocarb）、プロチオコナゾール（prothioconazole）、ピジフルメトフェン（pydiflumetofen）、ピラカルボリド（pyracarbolid）、ピラクロストロビン（pyraclostrobin）、ピラメトストロビン（pyrametostrobin）、ピラオキシストロビン（pyraoxystrobin）、ピラプロポイン（pyrapropoyne）、ピラジフルミド（pyraziflumid）、ピリダクロメチル（pyridachlometyl）、ピリジニトリル（pyridinitril）、ピリオフェノン（pyriofenone）、ピリソキサゾール（pyrisoxazole）、ピロキシクロル（pyroxychlor）、ピロキシフル（pyroxyfur）、キナセトール－スルフェート（quinacetol-sulfate）、キナザミド（quinazamid）、キンコナゾール（quinconazole）、キノキシフェン（quinoxyfen）、キノフメリン（quinofumelin）、キントゼン（quintozene）、ラベンザゾール（rabenzazole）、サリチルアニリド（salicylanilide）、セダキサン（sedaxane）、シルチオファム（silthiofam）、シメコナゾール（simeconazole）、炭酸水素ナトリウム（sodium hydrogen carbonate）、次亜塩素酸ナトリウム（sodium hypochlorite）、スピロキサミン（spiroxamine）、硫黄（sulfur）、テブコナゾール（tebuconazole）、テブフロキン（tebufloquin）、テフロクタラム（tecloftalam）、テクナゼン（tecnazene）、テコラム（tecoram）、テトラコナゾール（tetraconazole）、チアベンダゾール（thiabendazole）、チアジフルオール（thiadifluor）、チシオフェン（thicyofen）、チフルザミド（thifluzamide）、チオクロルフェンヒム
（thiochlorfenphim）、チオファネート（thiophanate）、チオファネート－メチル（thiophanate-methyl）、チウラム（thiram）、チアジニル（tiadinil）、チオキシミド（tioxymid）、トルクロホス－メチル（tolclofos-methyl）、トルプロカルブ（tolprocarb）、トリルフルアニド（tolylfluanid）、トリアジメホン（triadimefon）、トリアジメノール（triadimenol）、トリアミホス（triamiphos）、トリアリモール（triarimol）、トリアズブチル（triazbutil）、トリアゾキシド（triazoxide）、トリブチル錫オキシド（tributyltin oxide）、トリクラミド（trichlamide）、トリクロピリカルブ（triclopyricarb）、トリシクラゾール（tricyclazole）、トリデモルフ（tridemorph）、トリフロキシストロビン（trifloxystrobin）、トリフルミゾール（triflumizole）、トリホリン（triforine）、トリチコナゾール（triticonazole）、バリダマイシン（validamycin）、バリフェナレート（valifenalate）、ビンクロゾリン（vinclozolin）、ザリラミド（zarilamid）、ジンクナフテネート（zinc naphthenate）、硫酸亜鉛（zinc sulfate）、ジネブ（zineb）、ジラム（ziram）、ゾキサミド（zoxamide）、シイタケ菌糸体抽出物（shiitake mycelium extract）、シイタケ子実体抽出物（shiitake fruiting body extract）等が挙げられる。 Bactericides include acibenzolar-S-methyl, acipetacs, aldimorph, allyl alcohol, ametoctradin, aminopyrifen, amisulbrom ), Amobam, ampropylfos, anilazine, azaconazole, azithiram, azoxystrobin, barium polysulfide, benalaxyl, benalaxyl -M (benalaxyl-M), benodanil, benomyl, benquinox, bentaluron, benthiavalicarb-isopropyl, benthiazole, benzacryl amacril), benzamorf, benzovindiflupyr, binapacryl, biphenyl, bitertanol, bixafen, blasticidin-S, bordeaux mixture, boscalid, bromoconazole, bupirimate, buthiobate, butylamine, calcium polysulfide, captafol, captan , Carbamorph, carbendazim, carboxin, carpropamid, carvone, cheshunt mixture, chinomethionat, clobenthiazone, chloranif Chloraniformethane, chloranil, chlorfenazole, chloroneb, chloropicrin, chlorothalonil, chlorquinox, chlozolinate, crimazole, copper Acetate (copper acetate), basic copper carbonate (copper carbonate, basic), cupric hydroxide (copper hydroxide), copper naphthenate (copper naphthenate), copper oleate (copper oleate), basic copper chloride (copper) oxychloride, copper sulfate, copper sulfate, basic, copper zinc chromate, coumoxystrobin, cresol, cufraneb, cuprobam (Cuprobam), cyazofamid, cycla Cyclafuramid, cycloheximide, cyflufenamid, cymoxanil, cypendazole, cyproconazole, cyprodinil, cyprofuram, dazomet (dazomet) ), Decafentin, dehydroacetic acid, diclobentiazox, dichlofluanid, dichlone, dichlorophen, dichlozoline, diclob Tolazole (diclobutrazol), dicromemet (dicloyzine), diclomezine (dicloran), dietofencarb (dithofencarb), difenoconazole, diflumetorim, dimethi Dimethirimol, dimethomorph, dimoxystrobin, diniconazole, diniconazole-M, dinobuton, dinocap, dinocap-4 , Dinocap-6, dinocton, dinosulfon, dinoterbon, diphenylamine, dipymetitrone, dipyrithione, disulfiram, ditalfos dital , Dithianon, DNOC, dodemorph, dodine, drazoxolon, edifenphos, enestrobin, enoxastrobin, epoxiconazole (Epox iconazole, ethaboxam, etaconazole, etem, etirimol, ethoxyquin, etridiazole, famoxadone, fenamidone, fenaminosulf, fenaminosulf Fenaminstrobin, fenapanil, fenarimol, fenbuconazole, fenfuram, fenhexamid, fenitropan, fenoxanil, fenpiclonil, Fenpicoxamid, fenpropidin, fenpropimorph, fenpyrazamine, fentin, ferbam, ferrimzone (feri) mzone), florylpicoxamid, fluazinam, fludioxonil, fluphenoxystrobin, fluindapyr, flumetapyr, flumetover, flumorph, fluopicolide, Fluopimomide, fluopyram, fluorimide, fluotrimazole, fluoxastrobin, fluquinconazole, flusilazole, flusulfamide, flutolanil ), Flutianil, flutriafol, fluxapyroxad, folpet, fosetyl-aluminium, fthalide Fuberidazole, furaxax (fururalaxyl), furametpyr, furcarbanil, furconazole, furconazole-cis, furmecyclox, furophanate, glyodin , Griseofulvin, guazatine, halacrinate, hexachlorobenzene, hexaconazole, hexylthiofos, oxyquinoline sulfate, hymexazol , Imazalil, imibenconazole, iminoctadine-albesilate, iminoctadine-triacetate, inpyrfluxam ), Iodocarb, ipconazole, ipfentrifluconazole, ipflufenoquin, iprobenfos, iprodione, iprovalicarb, isofetamid, isofetamid Isoflucypram, isotianil, isoprothiolane, isopyrazam, isovaledione, kasugamycin, cresoxim-methyl, laminarin, mancopper, mancopper Mancozeb, mandestrobin, mandipropamid, maneb, mebenil, mecarbinzid, mefentriflucona Mefentrifluconazole, mepanipyrim, mepronil, meptyldinocap, metalaxyl, metalaxyl-M, metam, metazoxolon, metconazole metconazole), metasulfocarb (methasulfocarb), metfuroxam (methfuroxam), methyltetraprole (metyltetraprole), metiram (metiram), mettominostrobin (metominostrobin), metrafenone (metrafenone), metsulfovax (metsulfovax), milneb (milneb) , Microbutanil, myclozolin, nabam, naftifine, natamycin, nickel bis (dimethyldithiocarbamate), nitrostyrene, nitrotal-isopropyl (Nitrothal-isopropyl), nuarimol, octhilinone, offurace, orysastrobin, oxadixyl, oxathiapiprolin, oxinecopper, oxine copper Poconazole fumarate, oxycarboxin, pefurazoate, penconazole, penciclone, penflufen, pentachlorophenol, penthiopyrad, ortho 2-phenylphenol, phosdiphen, phthalide, picarbutrazox, picoxystrobin, piperalin, polycarbamate Polyoxins, polyoxin-D (polyoxorim), potassium azide, potassium hydrogen carbonate, probenazole, prochloraz, procymidone, propamocarb hydrochloride , Propiconazole, propineb, proquinazid, prothioazib, prothiocarb, pyrazophos, pyribencarb, pyrifenox, pyrimethanil, pyriminostrobin ( pyriminostrobin), pyroquilon, prothiocarb, prothioconazole, pydiflumetofen, pyracarbolid, pyraclostrobin Pyrametostrobin, pyraoxystrobin, pyrapropoyne, pyraziflumid, pyridachlometyl, pyridinitryl, pyriofenone, pyrisoxazole, pyroxoxazole ), Pyroxyfur, quinacetol-sulfate, quinazamid, quinconazole, quinoxyfen, quinofumelin, quintozene, rabenzazole, salicyl salicylanilide, sedaxane, silthiofam, simeconazole, sodium hydrogen carbonate, sodium hypochlorite (sodium) hypochlorite, spiroxamine, sulfur, tebuconazole, tebufloquin, tecloftalam, tecnazene, tecoram, tetraconazole, thiabendazole, Thiadifluor, thicyofen, thifluzamide, thiochlorfenphim, thiophanate, thiophanate-methyl, thiram, thiadinyl, thioximide (Tioxymid), tolclofos-methyl, tolprocarb, tolylfluanid, triadimefon, triadimenol, triamiphos, triarimo Triarimol, triazbutil, triazoxide, tributyltin oxide, trichlamide, triclopyricarb, tricyclazole, triridemorph, trifloxystrobin (Trifloxystrobin), triflumizole, triforine, triticonazole, validamycin, valifenalate, vinclozolin, zarilamid, zinc naphthenate naphthenate, zinc sulfate, zineb, ziram, zoxamide, shiitake mycelium extract, shiitake fruiting body extract It is done.
　殺虫剤としては、アバメクチン（abamectin）、アセフェート（acephate）、アセキノシル（acequinocyl）、アセタミピリド（acetamipirid）、アクリナトリン（acrinathrin）、アフィドピロペン（afidopyropen）、アフォクソラネル（afoxolaner）、アラニカルブ（alanycarb）、アルジカルブ（aldicarb）、アレスリン（allethrin）、アルファ－シペルメトリン（alpha-cypermethrin）、アルファ－エンドスルファン（alpha-endosulfan）、アミドフルメット（amidoflumet）、アミトラズ（amitraz）、アザメチホス（azamethiphos）、アジンホス－エチル（azinphos-ethyl）、アジンホス－メチル（azinphos-methyl）、アゾシクロチン（azocyclotin）、バチルスチューリンゲンシス（bacillus thuringiensis）、ベンダイオカルブ（bendiocarb）、ベンフルトリン（benfluthrin）、ベンフラカルブ（benfuracarb）、ベンスルタップ（bensultap）、ベンゾキシメート（benzoximate）、ベータ－シフルトリン（beta-cyfluthrin）、ベータ－シペルメトリン（beta-cypermethrin）、ビフェナゼート（bifenazate）、ビフェントリン（bifenthrin）、ビオアレスリン（bioallethrin）、ビオレスメトリン（bioresmethrin）、ビストリフルロン（bistrifluron）、ブロフラニリド（broflanilide）、ブロモプロピレート（bromopropylate）、ブプロフェジン（buprofezin）、ブトカルボキシム（butocarboxim）、カルバリル（carbaryl）、カルボフラン（carbofuran）、カルボスルファン（carbosulfan）、カルタップ（cartap）、チノメチオネート（chinomethionat）、クロルアントラニリプロール（chlorantraniliprole）、クロルエトキシホス（chlorethxyfos）、クロルフェナピル（chlorfenapyr）、クロルフェンビンホス（chlorfenvinphos）、クロルフルアズロン（chlorfluazuron）、クロルメホス（chlormephos）、クロロベンジラート（chlorobezilate）、クロロプラレスリン（chloroprallethrin）、クロルピリホス（chlorpyrifos）、クロピリホス－メチル（chlorpyrifos-methyl）、クロマフェノジド（chromafenozide）、クロフェンテジン（clofentezine）、クロチアニジン（clothianidin）、シアノホス（cyanophos）、シアントラニリプロール（cyantraniliprole）、シクラニリプロール（cyclaniliprole）、シクロプロトリン（cycloprothrin）、シエノピラフェン（cyenopyrafen）、シフルメトフェン（cyflumetofen）、シフルメトフェン（cyflumetofen）、シフルトリン（cyfluthrin）、シハロジアミド（cyhalodiamide）、シハロトリン（cyhalothrin）、サイヘキサチン（cyhexatine）、シペルメトリン（cypermethrin）、シフェノトリン（cyphenothrin）、シロマジン（cyromazine）、デルタメトリン（deltamethrin）、ジアクロデン（diacloden）、ジアフェンチウロン（diafenthiuron）、ダイアジノン（diazinon）、ジクロルボス（dichlorvos）、ジクロロメゾチアズ（dicloromezotiaz）、ジコホール（dicofol）、ジエノクロル（dienochlor）、ジフロビダジン（diflovidazin）、ジフルベンズロン（diflubenzuron）、ジメフルトリン（dimefluthrin）、ジメトエート（dimethoate）、ジメチルビンホス（dimethylvinphos）、ジノテフラン（dinotefuran）、ジオフェノラン（diofenolan）、ジスルフォトン（disulfoton）、デーエヌオーシー（DNOC）、ｄ－Ｔ－８０－フタルスリン（d-tetramethrin）、エマメクチンベンゾエート（emamectin-benzoate）、エンペントリン（empenthrin）、エンドスルファン（endosulfan）、イーピーエヌ（EPN）、イプシロン－メトフルトリン（epsilon-metofluthrin）、イプシロン－モムフルオロトリン（epsilon-momfluorothrin）、エスフェンバレレート（esfenvalerate）、エチオフェンカルブ（ethiofencarb）、エチプロール（ethiprole）、エトフェンプロックス（etofenprox）、エトキサゾール（etoxazole）、エトリムホス（etrimfos）、フェバンテル（Febantel）、フェナザキン（fenazaquin）、フェンブタチンオキシド（fenbutatin oxide）、フェニトロチオン（fenitrothion）、フェノブカルブ（fenobucarb）、フェノチオカルブ（fenothiocarb）、フェノキシカルブ（fenoxycarb）、フェンプロパトリン（fenpropathrin）、フェンプロパトリン（fenpropathrin）、フェンピロキシメート（fenpyroximate）、フェンチオン（fenthion）、フェンバレレート（fenvalerate）、フィプロニル（fipronil）、フロメトキン（flometoquin）、フロニカミド（flonicamid）、フルアクリピリム（fluacrypyrim）、フルアズロン（fluazuron）、フルベンジアミド（flubendiamide）、フルシクロクスロン（flucycloxuron）、フルシトリネート（flucythrinate）、フルフェネリム（flufenerim）、フルフェノクスロン（flufenoxuron）、フルフェンプロックス（flufenprox）、フルフィプロール（flufiprole）、フルヘキサホン（fluhexafon）、フルメトリン（flumethrin）、フルピラジフロン（flupyradifurone）、フルララネル（fluralaner）、フルバリネート（fluvalinate）、フルキサメタミド（fluxametamide）、ホノホス（fonophos）、ホルメタネート（formetanate）、フォルモチオン（formothion）、フラチオカルブ（furathiocarb）、ガンマ－シハロトリン（gamma-cyhalothrin）、ハルフェンプロックス（halfenprox）、ハロフェノジド（halofenozide）、ヘプタフルトリン（heptafluthrin）、ヘキサフルムロン（hexaflumuron）、ヘキシチアゾクス（hexythiazox）、ヒドラメチルノン（hydramethylnon）、イミプロトリン（imiprothrin）、インドキサカルブ（indoxacarb）、インドキサカルブ－ＭＰ（indoxacarb-MP）、イソフェンホス（isofenphos）、イソプロカルブ（isoprocarb）、イソキサチオン（isoxathion）、カッパ－ビフェントリン（kappa-bifenthrin）、カッパ－テフルトリン（kappa-tefluthrin）、ラムダ－シハロトリン（lambda-cyhalothrin）、レピメクチン（lepimectin）、ルフェヌロン（lufenuron）、マラチオン（malathion）、メペルフルスリン（meperfluthrin）、メタフルミゾン（metaflumizone）、メタルカルブ（metalcarb）、メタルデヒド（metaldehyde）、メタクリホス（methacrifos）、メタミドホス（methamidophos）、メチダチオン（methidathion）、メソミル（methomyl）、メソプレン（methoprene）、メトキシクロル（methoxychlor）、メトキシフェノジド（methoxyfenozide）、臭化メチル（methyl bromide）、メトフルトリン（metofluthrin）、ミルベメクチン（milbemectin）、モムフルオロトリン（momfluorothrin）、モノクロトホス（monocrotophos）、ムスカルア（muscalure）、ニテンピラム（nitenpyram）、ノバルロン（novaluron）、ノビフルムロン（noviflumuron）、オメトエート（omethoate）、オキサゾスルフィル（oxazosulfyl）、オキシデメトン－メチル（oxydemeton-methyl）、オキシデプロホス（oxydeprofos）、パラチオン（parathion）、パラチオン－メチル（parathion-methyl）、ペンタクロロフェノール（pentachlorophenol）、ペルメトリン（permethrin）、フェノトリン（phenothrin）、フェントエート（phenthoate）、ホレート（phorate）、ホサロン（phosalone）、ホスメット（phosmet）、ホスファミドン（phosphamidon）、ホキシム（phoxim）、ピリミカーブ（pirimicarb）、ピリミホス－メチル（pirimiphos-methyl）、プラジクアンテル（Praziquantel）、プロフェノホス（profenofos）、プロフルトリン（profluthrin）、プロパホス（propaphos）、プロパルギット（propargite）、プロチオホス（prothiofos）、プロトリフェンブト（protrifenbute）、ピフルブミド（pyflubumide）、ピメトロジン（pymetrozine）、ピラクロホス（pyraclofos）、ピラフルプロール（pyrafluprole）、ピレトリン（pyrethrins）、ピリダベン（pyridaben）、ピリダリル（pyridalyl）、ピリフルキナゾン（pyrifluquinazon）、ピリミジフェン（pyrimidifen）、ピリプロール（pyriprole）、ピリプロキシフェン（pyriproxyfen）、レスメトリン（resmethrin）、ロテノン（rotenone）、シラフルオフェン（silafluofen）、スピネトラム（spinetoram）、スピノサド（spinosad）、スピロジクロフェン（spirodiclofen）、スピロメシフェン（spiromesifen）、スピロテトラマート（spirotetramat）、スピロメシフェン（spyromesifen）、スルホテップ（sulfotep）、スルホキサフロル（sulfoxaflor）、スルプロホス（sulprofos）、タウ－フルバリネート（tau-fluvalinate）、テブフェノジド（tebfenozide）、テブフェンピラド（tebufenpyrad）、テフルベンズロン（teflubenzuron）、テフルトリン（tefluthorin）、テルブホス（terbufos）、テトラクロラントラニリプロール（tetrachlorantraniliprole）、テトラクロロビンホス（tetrachlorvinphos）、テトラメトリン（tetramethrin）、テトラメチルフルスリン（tetramethylfluthrin）、テトラニリプロール（tetraniliprole）、チアクロプリド（thiacloprid）、チアメトキサム（thiamethoxam）、チオシクラム（thiocyclam）、チオジカルブ（thiodicarb）、チオファノックス（thiofanox）、チオメトン（thiometon）、トルフェンピラド（tolfenpyrad）、トラロメトリン（tralomethrin）、トランスフルトリン（transfluthrin）、トリアザメート（triazamate）、トリアズロン（triazuron）、トリクロルホン（trichlorfon）、トリフルメゾピリム（triflumezopyrim）、トリフルムロン（triflumuron）、チクロピラゾフロル（tyclopyrazoflor）、バミドチオン（vamidothion）、ゼタ－シペルメトリン（zeta-cypermethrin）等が挙げられる。 Insecticides include abamectin, acephate, acequinocyl, acetamipirid, acrinathrin, afidopyropen, afoxolaner, carb, al, carb, alanicarb Allethrin, alpha-cypermethrin, alpha-endosulfan, amidoflumet, amitraz, azamethiphos, azinphos-ethyl, azinphos -Methyl (azinphos-methyl), azocyclotin, bacillus thuringiensis, bendiocarb, benfluthrin, benfuracarb, bens Bensultap, benzoximate, beta-cyfluthrin, beta-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin ), Bistrifluron, broflanilide, bromopropylate, buprofezin, butocarboxim, carbaryl, carbofuran, carbosulfan, Cartap, chinomethionat, chlorantraniliprole, chlorethxyfos, chlorfenapyr, chlorfenvinphos, chlorflua Chlorfluazuron, chlormephos, chlorobezilate, chloroprallethrin, chlorpyrifos, chlorpyrifos-methyl, chromafenozide, clofentezine, clofentezine Clothianidin, cyanophos, cyantraniliprole, cyclaniliprole, cycloprothrin, cyenopyrafen, cyflumetofen, cyflumetofen, cyflumetofen cyfluthrin, cyhalodiamide, cyhalothrin, cyhexatine, cypermethrin, cyphenothrin, cyromazine , Deltamethrin, diacloden, diafenthiuron, diazinon, dichlorvos, dicloromezotiaz, dicohol, dienochlor, difloazin ), Diflubenzuron, dimefluthrin, dimethoate, dimethylvinphos, dinotefuran, diofenolan, disulfoton, denoc (DNOC), d-T- 80-phthalthrin (d-tetramethrin), emamectin-benzoate, empenthrin, endosulfan, EPN, epsilon-metofluthrin, Epsifen-momfluorothrin, esfenvalerate, ethiofencarb, ethiprole, etofenprox, etoxazole, etrimfos, febantel, febantel Fenazaquin, fenbutatin oxide, fenitrothion, fenobucarb, fenothiocarb, phenoxycarb, fenpropathrin, fenpropathrin, fenpropathrin (Fenpyroximate), fenthion, fenvalerate, fipronil, flometoquin, flonicamid, fluacrylpyrim (Fluacrypyrim), fluazuron, flubendiamide, flucycloxuron, flucythrinate, flufenerim, flufenoxuron, flufenprox, flufenprox, flufenprox Flufiprole, fluhexafon, flumethrin, flupyradifurone, fluralaner, fluvalinate, fluxametamide, fonophos, formetanate, formothionate, formothionate ), Furathiocarb, gamma-cyhalothrin, halfenprox, halofenozide, heptafluthrin, hexaflumuuron (h exaflumuron, hexythiazox, hydramethylnon, imiprothrin, indoxacarb, indoxacarb-MP, indoxacarb-MP, isofenphos, isoprocarb, isoxathione (isoprocarb) isoxathion, kappa-bifenthrin, kappa-tefluthrin, lambda-cyhalothrin, lambda-cyhalothrin, lepimectin, lufenuron, malathion, meperfluthrin, meperthrin Metaflumizone, metalcarb, metalaldehyde, metaldehyde, methacrifos, metamidophos, methidathion, methomyl, methoprene, methoxy Methoxychlor, methoxyfenozide, methyl bromide, metofluthrin, milbemectin, momfluorothrin, monocrotophos, muscalure, nitenpyram , Novaluron, noviflumuron, omethoate, oxazosulfyl, oxydemeton-methyl, oxydeprofos, parathion, parathion-parathion -methyl), pentachlorophenol, permethrin, phenothrin, phenthoate, phorate, phorate, phosalone, phosmet, phosphamidone (phos) phamidon, phoxim, pirimicarb, pirimiphos-methyl, praziquantel, profenfos, profluthrin, propaphos, propargite, proargite, prothiophos ), Protrifenbute, Pyflubumide, Pymetrozine, Pyraclofos, Pyrafluprole, Pyrethrins, Pyridaben, Pyridalyl, Pyriflunazone, Pyriflunazone ), Pyrimidifen, pyriprole, pyriproxyfen, resmethrin, rotenone, silafluofen, spinetoram, spineram Nosado (spinosad), spirodiclofen, spiromesifen (spiromesifen), spirotetramat, spiromesifen, sulfotep (sulfotep), sulfoxaflor, sulprofos, tau- Fluvalinate, tebfenozide, tebufenpyrad, teflubenzuron, tefluthorin, terbufos, tetrachlorantraniliprole, tetrachlorphos chlortetraphos , Tetramethrin, tetramethylfluthrin, tetraniliprole, thiacloprid, thiamethoxam, thiocyclam, thio Carb (thiodicarb), thiofanox, thiometon, tolfenpyrad, tralomethrin, transfluthrin, triazamate, triazuron, trichlorfon, trichlorfon Examples include triflumezopyrim, triflumuron, tyclopyrazoflor, bamidothion, zeta-cypermethrin and the like.
　殺ダニ剤としては、アセキノシル（acequinocyl）、アクリナトリン（acrinathrin）、アミドフルメット（amidoflumet）、アミトラズ（amitraz）、アゾシクロチン（azocyclotin）、ベンゾキシメート（benzoximate）、ビフェナゼート（bifenazate）、ブロモプロピレート（bromopropylate）、クロフェンテジン（clofentezine）、シエノピラフェン（cyenopyrafen）、シフルメトフェン（cyflumetofen）、ジコホール（dicofol）、ジエノクロル（dienochlor）、エトキサゾール（etoxazole）、フェナザキン（fenazaquin）、フェンブタチン－オキシド（fenbutatin oxide）、フェノチオカルブ（fenothiocarb）、フェンプロパトリン（fenpropathrin）、フェンピロキシメート（fenpyroximate）、フルアクリピリム（fluacrypyrim）、ホルメタネート（formetanate）、ハルフェンプロックス（halfenprox）、ヘキシチアゾクス（hexythiazox）、ミルベメクチン（milbemectin）、プロパルギット（propargite）、ピフルブミド（pyflubumide）、ピリダベン（pyridaben）、ピリミジフェン（pyrimidifen）、スピロジクロフェン（spirodiclofen）、スピロメシフェン（spiromesifen）、テブフェンピラド（tebufenpyrad）、ＮＡ－８９（試験名）等が挙げられる。 Acaricides include acequinocyl, acrinathrin, amidoflumet, amitraz, azocyclotin, benzoximate, bifenazate, and bromopropylate. , Clofentezine, cyenopyrafen, cyflumetofen, dicohol, dienochlor, etoxazole, fenazaquin, fenbutatin oxide, fenothiocarb , Fenpropathrin, fenpyroximate, fluacrypyrim, formetanate, halfenprox, hexitazo Hexythiazox, milbemectin, propargite, piflubumide, pyridaben, pyrimidifen, spirodiclofen, spirodisifen, tebufenpyrad, tebufenpyrad -89 (test name).
　殺線虫剤としては、アルドキシカルブ（aldoxycarb）、ベンクロチアズ（benclothiaz）、カズサホス（cadusafos）、デービーシーピー（DBCP）、ジクロフェンチオン（dichlofenthion）、デーエスピー（DSP）、エトプロホス（ethoprophos）、フェナミホス（fenamiphos）、フェンスルホチオン（fensulfothion）、フルアザインドリジン（fluazaindolizine）、フルエンスルホン（fluensulfone）、ホスチアゼート（fosthiazate）、フォスチエタン（fosthietan）、イミシアホス（imicyafos）、イサミドホス（isamidofos）、イサゾホス（isazofos）、オキサミル（oxamyl）、チオキサザフェン（thiaxazafen）、チオナジン（thionazin）、チオキサザフェン（tioxazafen）等が挙げられる。 The nematicides include aldoxycarb, benclothiaz, cadusafos, DDBCP, dichlofenthion, DSP (DSP), etoprophos, fenamiphos , Fensulfothion, fluazaindolizine, fluensulfone, fosthiazate, fosthietan, imicyafos, isamifofos, isazofos, isazoxox, oxamyl Examples thereof include thiaxazafen, thionazin, tioxazafen and the like.
　駆虫剤としては、アクリフラビン（acriflavine）、アルベンダゾール（albendazole）、アトバコン（atovaguone）、アジスロマイシン（azithromycin）、ビチオノール（bithionol）、ブロムフェノホス（bromofenofos）、カンベンダゾール（cambendazole）、カルニダゾール（carnidazole）、クロロキン（chloroquine）、クラズリル（clazuril）、クリンダマイシン（clindamycin hydrochloride）、クロルスロン（clorsulon）、クロサンテル（closantel）、クマホス（coumaphos）、シミアゾル（cymiazol）、ジクロロフェン（dichlorophen）、ジエチルカルバマジン（diethylcarbamazine）、ジミナゼン（diminazene）、ジソフェノール（disophenol）、ヨウ化ジチアザニン（dithiazanine iodide）、ドキシサイクリン（doxycycline hydrochloride）、ドラメクチン（doramectin）、エモデプシド（emodepside）、エプリノメクチン（eprinomectin）、フェバンテル（febantel）、フェンベンダゾール（fenbendazole）、フルベンダゾール（flubendazole）、フラゾリドン（furazolidone）、グリカルピラミド（glycalpyramide）、イミドカルブ（imidocarb）、イベルメクチン（ivermectin）、レバミゾール（levamisole）、メベンダゾール（mebendazole）、メフロキン（mefloquine）、メラルソミン二塩酸塩（melarsamine hydrochloride）、メトロニダゾール（metronidazole）、メチリジン（metyridine）、ミルベマイシンオキシム（milbemycin oxime）、モネパンテル（monepantel）、酒石酸モランテル（morantel tartrate）、モキシデクチン（moxidectin）、ナイカルバジン（nicarbazin）、ニクロサミド（niclosamide）、ニトロスカネート（nitroscanate）、ニトロキシニル（nitroxynil）、オムファロチン（omphalotin）、パモ酸オキサンテル（oxantel pamoate）、酒石酸オキサンテル（oxantel tartrate）、オクスフェンダゾール（oxfendazolee）、オキシベンダゾール（oxibendazole）、オキシクロザニド（oxyclozanide）、パマキン（pamaquine）、フェノチアジン（phenothiazine）、アジピン酸ピペラジン（piperazine adipate）、クエン酸ピペラジン（piperazine citrate）、リン酸ピペラジン（piperazine phosphate）、ＰＮＵ－９７３３３（paraherquamide A）、ＰＮＵ－１４１９６２（2-deoxyparaherquamide）、プラジクアンテル（praziquantel）、プリマキン（primaquine）、プロペタムホス（propetamphos）、プロポクスル（propoxur）、パモ酸ピランテル（pyrantel pamoate）、ピリメタミン（pyrimethamine）、サントニン（santonin）、セラメクチン（selamectin）、スルファジメトキシン（sulfadimethoxine）、スルファドキシン（sulfadoxine）、スルファメラジン（sulfamerazine）、スルファモノメトキシン（sulfamonomethoxine）、スルファモイルダプソン（sulfamoildapsone）、チアベンダゾール（thiabendazole）、チニダゾール（tinidazole）、トルトラズリル（toltrazuril）、トリブロムサラン（tribromsalan）、トリクラベンダゾール（triclabendazole）等が挙げられる。 As an anthelmintic agent, acriflavine, albendazole, atovaguone, azithromycin, bithionol, bromfenofos, cambendazole, carnidazole, Chloroquine, clazuril, clindamycin hydrochloride, clorsulon, closantel, coumaphos, cymiazol, dichlorophen, diethylcarbamazine , Diminazene, diisophenol, dithiazanine iodide, doxycycline hydrochloride, doramectin, emodepside, eprinomec Eprinomectin, febantel, fenbendazole, flubendazole, furazolidone, glycalpyramide, imidocarb, ivermectin, levamisole, Mebendazole, mefloquine, melarsamine dihydrochloride, metronidazole, metyridine, milbemycin oxime, monepantel, morantel motartrate moxidectin, nicarbazin, niclosamide, nitroscanate, nitroxynil, omphalotin, oxantel pamoate pamoate), oxantel tartrate, oxfendazolee, oxibendazole, oxyclozanide, pamaquine, phenothiazine, piperazine adipate, citric acid (Piperazine citrate), piperazine 酸 phosphate, PNU-97333 (paraherquamide A), PNU-141962 (2-deoxyparaherquamide), praziquantel, primaquine, propetamphos, propoxur, Pyrantel pamoate, pyrimethamine, santonin, selamectin, sulfadimethoxine, sulfadoxine, sulfamelazi (Sulfamerazine), sulfamonomethoxine, sulfamoildapsone, thiabendazole, tinidazole, toltrazuril, tribromsalan, triclabendazole, etc. Is mentioned.
　抗真菌剤としては、ケトコナゾール（ketoconazole）、ミコナゾール硝酸塩（miconazole nitrate）等が挙げられる。 Examples of antifungal agents include ketoconazole and miconazole nitrate.
　抗菌剤としては、アモキシシリン（amoxicillin）、アンピシリン（ampicillin）、ベトキサジン（bethoxazin）、ビチオノール（bithionol）、ブロノポール（bronopol）、セファピリン（cefapirin）、セファゾリン（cefazolin）、セフキノム（cefquinome）、セフチオフル（ceftiofur）、クロルテトラサイクリン（chlortetracycline）、クラブラン酸（clavulanic acid）、ダノフロキサシン（danofloxacin）、ジフロキサシン（difloxacin）、ジニトルミド（dinitolmide）、エンロフロキサシン（enrofloxacin）、フロルフェニコール（florfenicol）、リンコマイシン（lincomycin）、ロメフロキサシン（lomefloxacin）、マルボフロキサシン（marbofloxacin）、ミロキサシン（miloxacin）、ミロサマイシン（mirosamycin）、ニトラピリン（nitrapyrin）、ノルフロキサシン（norfloxacin）、オクチリノン（octhilinone）、オフロキサシン（ofloxacin）、オルビフロキサシン（orbifloxacin）、オキソリニック酸（oxolinic acid）、オキシテトラサイクリン（oxytetracycline）、ペニシリン（penicillin）、ストレプトマイシン（streptomycin）、チアンフェニコール（thiamphenicol）、フマル酸チアムリン（tiamulin fumarate）、リン酸チルミコシン（tilmicosin phosphate）、酢酸イソ吉草酸タイロシン（acetylisovaleryltylosin）、リン酸タイロシン（tylosin phosphate）、ツラスロマイシン（tulathromycin）、バルネムリン（valnemulin）、貝殻焼成カルシウム（酸化カルシウム）、タラロマイセス属菌、トリコデルマ属菌、ユニオチリウム属菌等が挙げられる。 Antibacterial agents include amoxicillin, ampicillin, bethoxazin, bithionol, bronopol, cefapirin, cefazolin, cefquinome, cefquinome, cefthiome, ftfur Chlortetracycline, clavulanic acid, danofloxacin, difloxacin, dinitroxam, dinitolmide, enrofloxacin, florfenicol, lincomycin, Lomefloxacin, marbofloxacin, miloxacin, mirosamycin, nitrapyrin, norfloxacin, octhilinone Ofloxacin, orbifloxacin, oxolinic acid, oxytetracycline, penicillin, streptomycin, thiamphenicol, tiamulin fumarate ), Tilmicosin phosphate, tyrosin phosphate, tylosin phosphate, tulathromycin, valnemulin, shell calcined calcium (calcium oxide), Talalomyces , Trichoderma spp., Unioniolium spp.
　（ａ）農薬活性成分のうち、化合物Ａの含有量は、本発明の組成物中、０.１～３０質量％が好ましい。化合物Ａの含有量の下限は、０.５質量％がより好ましく、１質量％がより一層好ましく、３質量％が更に好ましく、４質量％が更に好ましく、５質量％が最も好ましい。また、その上限は、２５質量％がより好ましく、２０質量％がより一層好ましく、１８質量％が更に好ましく、１５質量％が最も好ましい。 (A) Among the pesticidal active ingredients, the content of Compound A is preferably 0.1 to 30% by mass in the composition of the present invention. The lower limit of the content of Compound A is more preferably 0.5% by mass, even more preferably 1% by mass, still more preferably 3% by mass, still more preferably 4% by mass, and most preferably 5% by mass. Further, the upper limit is more preferably 25% by mass, still more preferably 20% by mass, still more preferably 18% by mass, and most preferably 15% by mass.
　前記その他の農薬活性成分を含む場合、その含有量は、本発明の効果を損なわない限り任意であるが、通常、本発明の組成物中０.０１～２０質量％程度であり、０.１～１５質量％程度が好ましい。ただし、（ａ）農薬活性成分が化合物Ａとその他の農薬活性成分を含む場合、これらの合計は、３０質量％以下であることが好ましい。 When the other agrochemical active ingredient is contained, its content is arbitrary as long as the effects of the present invention are not impaired, but it is usually about 0.01 to 20% by mass in the composition of the present invention, and 0.1. About 15% by mass is preferable. However, when (a) the pesticidal active ingredient contains Compound A and other pesticidal active ingredients, the total of these is preferably 30% by mass or less.
［（ｂ）アジュバント］
　（ｂ）アジュバントは、農薬活性成分の生物効果を増強する機能を有するものであり、本発明においては、エステル化ポリオールアルコキシレート、ポリオキシアルキレンアルキルエーテル等が好ましい。 [(B) Adjuvant]
(B) The adjuvant has a function of enhancing the biological effect of the pesticidal active ingredient, and in the present invention, esterified polyol alkoxylate, polyoxyalkylene alkyl ether, and the like are preferable.
　前記エステル化ポリオールアルコキシレートは、下記式（１Ａ）、（１Ｂ）又は（１Ｃ）で表されるものである。
Figure JPOXMLDOC01-appb-C000004
 The esterified polyol alkoxylate is represented by the following formula (1A), (1B) or (1C).
Figure JPOXMLDOC01-appb-C000004
　式（１Ａ）中、ＰOAは、トリメチロールプロパンの残基である。式（１Ｂ）中、ＰOBは、グリセロールの残基である。式（１Ｃ）中、ＰOCは、ソルビタンの残基である。すなわち、式（１Ａ）で表されるエステル化ポリオールアルコキシレートは、トリメチロールプロパンのヒドロキシ基の水素原子が下記式（１'）で表される基で置換された化合物であり、式（１Ｂ）で表されるエステル化ポリオールアルコキシレートは、グリセロールのヒドロキシ基の水素原子が下記式（１'）で表される基で置換された化合物であり、式（１Ｃ）で表されるエステル化ポリオールアルコキシレートは、ソルビタンのヒドロキシ基の水素原子が下記式（１'）で表される基で置換された化合物である。
Figure JPOXMLDOC01-appb-C000005
 In the formula (1A), P OA is a residue of trimethylolpropane. In the formula (1B), P OB is a residue of glycerol. In the formula (1C), P OC is a sorbitan residue. That is, the esterified polyol alkoxylate represented by the formula (1A) is a compound in which the hydrogen atom of the hydroxy group of trimethylolpropane is substituted with a group represented by the following formula (1 ′), and the formula (1B) The esterified polyol alkoxylate represented by the formula is a compound in which the hydrogen atom of the hydroxy group of glycerol is substituted with a group represented by the following formula (1 ′), and the esterified polyol alkoxy represented by the formula (1C) The rate is a compound in which the hydrogen atom of the hydroxy group of sorbitan is substituted with a group represented by the following formula (1 ′).
Figure JPOXMLDOC01-appb-C000005
　前記式中、Ａ1は、炭素数２～４のアルカンジイル基である。前記炭素数２～４のアルカンジイル基としては、エタン－１,２－ジイル基、プロパン－１,２－ジイル基、プロパン－１,３－ジイル基、ブタン－１,２－ジイル基、ブタン－１,３－ジイル基、ブタン－１,４－ジイル基等が挙げられる。これらのうち、エタン－１,２－ジイル基、プロパン－１,２－ジイル基、ブタン－１,３－ジイル基、ブタン－１,４－ジイル基が好ましく、エタン－１,２－ジイル基、プロパン－１,２－ジイル基がより好ましい。なお、ｍ≧２のとき、各Ａ1は、互いに同一であってもよく、異なっていてもよい。 In the above formula, A 1 is an alkanediyl group having 2 to 4 carbon atoms. Examples of the alkanediyl group having 2 to 4 carbon atoms include ethane-1,2-diyl group, propane-1,2-diyl group, propane-1,3-diyl group, butane-1,2-diyl group, butane -1,3-diyl group, butane-1,4-diyl group and the like. Of these, ethane-1,2-diyl group, propane-1,2-diyl group, butane-1,3-diyl group and butane-1,4-diyl group are preferable, and ethane-1,2-diyl group A propane-1,2-diyl group is more preferable. When m ≧ 2, each A 1 may be the same as or different from each other.
　前記式中、ｍは、－Ａ1－Ｏ－基の平均数を表し、１～１００の整数である。ｍは、２～８０が好ましく、５～６０がより好ましく、１０～５０がより一層好ましく、１８～３０が更に好ましい。 In the above formula, m represents an average number of —A 1 —O— groups and is an integer of 1 to 100. m is preferably 2 to 80, more preferably 5 to 60, still more preferably 10 to 50, and still more preferably 18 to 30.
　前記式中、Ｒ1は、それぞれ独立に、水素原子、又は－Ｃ(＝Ｏ)－Ｒ1'（式中、Ｒ1'は、炭素数１～２８の１価炭化水素基である。）であるが、少なくとも１つは－Ｃ(＝Ｏ)－Ｒ1'である。前記炭素数１～２８の１価炭化水素基としては、直鎖状又は分岐状のものが好ましく、例えば、炭素数１～２８のアルキル基、炭素数２～２８のアルケニル基等が挙げられる。 In the above formula, each R 1 is independently a hydrogen atom or —C (═O) —R 1 ′ (wherein R 1 ′ is a monovalent hydrocarbon group having 1 to 28 carbon atoms). Where at least one is —C (═O) —R 1 ′. The monovalent hydrocarbon group having 1 to 28 carbon atoms is preferably linear or branched, and examples thereof include an alkyl group having 1 to 28 carbon atoms and an alkenyl group having 2 to 28 carbon atoms.
　前記アルキル基としては、炭素数が５～２６のものが好ましく、１０～２４のものがより好ましく、１６～２２のものがより一層好ましい。前記炭素数１～２８のアルキル基としては、メチル基、エチル基、プロピル基、ブチル基、ペンチル基、ヘキシル基、ヘプチル基、オクチル基、ノニル基、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、ノナデシル基、エイコシル基、ヘニコシル基、ドコシル基、トリコシル基、テトラコシル基、ペンタコシル基、ヘキサコシル基、ヘプタコシル基、オクタコシル基、これらの分岐状の異性体等が挙げられる。これらのうち、ドデシル基、トリデシル基、テトラデシル基、ペンタデシル基、ヘキサデシル基、ヘプタデシル基、オクタデシル基、ノナデシル基、エイコシル基、これらの分岐状の異性体が好ましい。 The alkyl group preferably has 5 to 26 carbon atoms, more preferably 10 to 24 carbon atoms, and still more preferably 16 to 22 carbon atoms. Examples of the alkyl group having 1 to 28 carbon atoms include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, and tridecyl group. , Tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, henicosyl group, docosyl group, tricosyl group, tetracosyl group, pentacosyl group, hexacosyl group, heptacosyl group, octacosyl group Isomers and the like. Of these, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, and branched isomers thereof are preferable.
　前記アルケニル基としては、炭素数が５～２６のものが好ましく、１０～２４のものがより好ましく、１６～２２のものがより一層好ましい。前記炭素数２～２８のアルケニル基としては、ビニル基、プロペニル基、ブテニル基、ペンテニル基、ヘキセニル基、ヘプテニル基、オクテニル基、ノネニル基、デセニル基、ウンデセニル基、ドデセニル基、トリデセニル基、テトラデセニル基、ペンタデセニル基、ヘキサデセニル基、ヘプタデセニル基、オクタデセニル基、ノナデセニル基、エイコセネニル基、ヘミコセニル基、ドコセニル基、トリコセニル基、テトラコセニル基、ペンタコセニル基、ヘキサコセニル基、ヘプタコセニル基、オクタコセニル基、これらの分岐状の異性体等が挙げられる。これらのうち、ドデセニル基、トリデセニル基、テトラデセニル基、ペンタデセニル基、ヘキサデセニル基、ヘプタデセニル基、オクタデセニル基、ノナデセニル基、エイコセニル基、これらの分岐状の異性体が好ましい。 The alkenyl group preferably has 5 to 26 carbon atoms, more preferably 10 to 24, and still more preferably 16 to 22. Examples of the alkenyl group having 2 to 28 carbon atoms include vinyl group, propenyl group, butenyl group, pentenyl group, hexenyl group, heptenyl group, octenyl group, nonenyl group, decenyl group, undecenyl group, dodecenyl group, tridecenyl group, tetradecenyl group , Pentadecenyl group, hexadecenyl group, heptadecenyl group, octadecenyl group, nonadecenyl group, eicosenyl group, hemicosenyl group, dococenyl group, tricosenyl group, tetracosenyl group, pentacocenyl group, hexacocenyl group, heptacocenyl group, octacocenyl group, and branched isomers thereof Etc. Of these, dodecenyl group, tridecenyl group, tetradecenyl group, pentadecenyl group, hexadecenyl group, heptadecenyl group, octadecenyl group, nonadecenyl group, eicocenyl group, and branched isomers thereof are preferable.
　また、－Ｃ(＝Ｏ)－Ｒ1'は、脂肪酸残基であってもよい。ここで、「脂肪酸残基」とは、脂肪酸のエステル化反応により得られる、脂肪酸に由来するアルカノイル基を意味する。 In addition, —C (═O) —R 1 ′ may be a fatty acid residue. Here, the “fatty acid residue” means an alkanoyl group derived from a fatty acid, which is obtained by an esterification reaction of a fatty acid.
　前記脂肪酸は、直鎖状又は分岐状の脂肪酸が好ましい。また、前記脂肪酸は、飽和脂肪酸であっても不飽和脂肪酸であってもよい。前記不飽和脂肪酸は、少なくとも１つの不飽和炭素－炭素二重結合を含むものであるが、１～３個の炭素－炭素二重結合を有するものが好ましく、１個の炭素－炭素二重結合を有するものがより好ましい。炭素－炭素二重結合は、シス又はトランス配置のいずれかで存在することができる。 The fatty acid is preferably a linear or branched fatty acid. The fatty acid may be a saturated fatty acid or an unsaturated fatty acid. The unsaturated fatty acid has at least one unsaturated carbon-carbon double bond, preferably has 1 to 3 carbon-carbon double bonds, and has one carbon-carbon double bond. Those are more preferred. Carbon-carbon double bonds can exist in either a cis or trans configuration.
　前記飽和脂肪酸としては、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、アラキジン酸、ベヘン酸、リグノセリン酸、セロチン酸等が挙げられる。これらのうち、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸が好ましい。 Examples of the saturated fatty acid include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, lignoceric acid, and serotic acid. Of these, lauric acid, myristic acid, palmitic acid, stearic acid, and isostearic acid are preferred.
　前記不飽和脂肪酸としては、ミリストレイン酸、パルミトレイン酸、サピエン酸、オレイン酸、エライジン酸、バクセン酸、リノール酸、リノエライジン酸、α－リノレン酸、アラキドン酸、エイコサペンタエン酸、エルカ酸、ドコサヘキサエン酸等が挙げられる。これらのうち、オレイン酸、リノール酸、リノレン酸、パルミトレイン酸、エライジン酸が好ましく、オレイン酸がより好ましい。 Examples of the unsaturated fatty acid include myristoleic acid, palmitoleic acid, sapienoic acid, oleic acid, elaidic acid, vaccenic acid, linoleic acid, linoelaidic acid, α-linolenic acid, arachidonic acid, eicosapentaenoic acid, erucic acid, docosahexaenoic acid Etc. Of these, oleic acid, linoleic acid, linolenic acid, palmitoleic acid, and elaidic acid are preferred, and oleic acid is more preferred.
　また、前記脂肪酸は、天然の脂肪及び油、例えばヒマワリ油、大豆油、オリーブ油、菜種油、綿実油又はトール油から得られる不飽和脂肪酸混合物であってもよい。 The fatty acid may be a mixture of unsaturated fatty acids obtained from natural fats and oils such as sunflower oil, soybean oil, olive oil, rapeseed oil, cottonseed oil or tall oil.
　前記脂肪酸残基としては、特に、直鎖モノ不飽和脂肪酸に由来するものが好ましい。 The fatty acid residue is particularly preferably derived from a linear monounsaturated fatty acid.
　前記ポリオキシアルキレンアルキルエーテルは、下記式（２）で表されるものである。
Figure JPOXMLDOC01-appb-C000006
 The polyoxyalkylene alkyl ether is represented by the following formula (2).
Figure JPOXMLDOC01-appb-C000006
　式（２）中、Ｒ2は、炭素数１０～１４のアルキル基である。前記炭素数１０～１４のアルキル基としては、直鎖状又は分岐状のものが好ましく、デシル基、ウンデシル基、ドデシル基、トリデシル基、テトラデシル基、及びこれらの分岐状の異性体が挙げられる。 In the formula (2), R 2 is an alkyl group having 10 to 14 carbon atoms. The alkyl group having 10 to 14 carbon atoms is preferably linear or branched, and examples thereof include a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a tetradecyl group, and branched isomers thereof.
　式（２）中、Ａ2は、炭素数２～４のアルカンジイル基である。前記炭素数２～４のアルカンジイル基としては、エタン－１,２－ジイル基、プロパン－１,２－ジイル基、プロパン－１,３－ジイル基、ブタン－１,２－ジイル基、ブタン－１,３－ジイル基、ブタン－１,４－ジイル基等が挙げられる。これらのうち、エタン－１,２－ジイル基、プロパン－１,２－ジイル基、ブタン－１,３－ジイル基、ブタン－１,４－ジイル基が好ましく、エタン－１,２－ジイル基、プロパン－１,２－ジイル基がより好ましい。なお、ｎ≧２のとき、各Ａ2は、互いに同一であってもよく、異なっていてもよい。 In the formula (2), A 2 is an alkanediyl group having 2 to 4 carbon atoms. Examples of the alkanediyl group having 2 to 4 carbon atoms include ethane-1,2-diyl group, propane-1,2-diyl group, propane-1,3-diyl group, butane-1,2-diyl group, butane -1,3-diyl group, butane-1,4-diyl group and the like. Of these, ethane-1,2-diyl group, propane-1,2-diyl group, butane-1,3-diyl group and butane-1,4-diyl group are preferable, and ethane-1,2-diyl group A propane-1,2-diyl group is more preferable. When n ≧ 2, each A 2 may be the same as or different from each other.
　式（２）中、ｎは、－Ａ2－Ｏ－基の平均数を表し、１～１００の整数であるが、５～８０が好ましく、１０～５０がより好ましい。 In the formula (2), n represents the average number of —A 2 —O— groups and is an integer of 1 to 100, preferably 5 to 80, more preferably 10 to 50.
　式（２）で表されるポリオキシアルキレンアルキルエーテルとしては、ポリオキシエチレンイソデシルエーテル、ポリオキシエチレントリデシルエーテル、ポリオキシエチレン(C12-14)第２級アルコールエーテル及びポリオキシアルキレン分岐デシルエーテル等が好ましい。 Examples of the polyoxyalkylene alkyl ether represented by the formula (2) include polyoxyethylene isodecyl ether, polyoxyethylene tridecyl ether, polyoxyethylene (C12-14) secondary alcohol ether, and polyoxyalkylene branched decyl ether. Etc. are preferred.
　式（１Ａ）で表されるエステル化ポリオールアルコキシレートとしては、市販品を使用することができ、その具体例としては、Croda社製Atplus（登録商標）UEP-100等が挙げられる。式（１Ｂ）で表されるエステル化ポリオールアルコキシレートとしては、市販品を使用することができ、その具体例としては、第一工業製薬(株)製ノイゲン（登録商標）ＧＩＳシリーズ（GIS-108等）等が挙げられる。式（１Ｃ）で表されるエステル化ポリオールアルコキシレートとしては、市販品を使用することができ、その具体例としては、Croda社製Tween（登録商標）20、21、80等が挙げられる。 As the esterified polyol alkoxylate represented by the formula (1A), a commercially available product can be used, and specific examples thereof include Atplus (registered trademark) UEP-100 manufactured by Croda. As the esterified polyol alkoxylate represented by the formula (1B), a commercially available product can be used. Specific examples thereof include Neugen (registered trademark) GIS series (GIS-108 manufactured by Daiichi Kogyo Seiyaku Co., Ltd.). Etc.). Commercially available products can be used as the esterified polyol alkoxylate represented by the formula (1C), and specific examples thereof include Croda's Tween (registered trademark) 20, 21, 80, and the like.
　式（２）で表されるポリオキシアルキレンアルキルエーテルとしては、市販品を使用することができ、その具体例としては、第一工業製薬(株)製ノイゲン（登録商標）ＳＤシリーズ（SD-110、SD-70等）、ＴＤＳシリーズ（TDS-80、TDS-120等）、ＥＴシリーズ（ET-135、ET-69、ET-109、ET-129、ET-149、ET-159等）、ＸＬシリーズ（XL-40、XL-100等）、ＴＤＸシリーズ（TDX-50、TDX-100D、TDX-120D等）等が挙げられる。 As the polyoxyalkylene alkyl ether represented by the formula (2), a commercially available product can be used. Specific examples thereof include Neugen (registered trademark) SD series (SD-110 manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.). SD-70 etc.), TDS series (TDS-80, TDS-120 etc.), ET series (ET-135, ET-69, ET-109, ET-129, ET-149, ET-159 etc.), XL Series (XL-40, XL-100 etc.), TDX series (TDX-50, TDX-100D, TDX-120D etc.) etc. are mentioned.
　これらのうち、（ｂ）成分のアジュバントとしては、粒子成長を抑制する効果が大きいことから、式（１Ａ）で表されるエステル化ポリオールアルコキシレート、式（１Ｂ）で表されるエステル化ポリオールアルコキシレートのうちグリフィンの式により算出したＨＬＢ値が１２～１７程度のもの、式（１Ｃ）で表されるエステル化ポリオールアルコキシレートのうちグリフィンの式により算出したＨＬＢ値が１２～１７程度のもの、式（２）で表されるポリオキシアルキレンアルキルエーテルのうちグリフィンの式により算出したＨＬＢ値が１１～１６程度のものが好ましく、式（１Ａ）で表されるエステル化ポリオールアルコキシレートがより好ましい。 Among these, as the adjuvant of the component (b), since the effect of suppressing particle growth is great, the esterified polyol alkoxylate represented by the formula (1A) and the esterified polyol alkoxy represented by the formula (1B) Among the rates, the HLB value calculated by the Griffin equation is about 12 to 17, and the esterified polyol alkoxylate represented by the formula (1C) has an HLB value calculated by the Griffin equation of about 12 to 17, Of the polyoxyalkylene alkyl ethers represented by the formula (2), those having an HLB value calculated by the Griffin formula of about 11 to 16 are preferred, and the esterified polyol alkoxylate represented by the formula (1A) is more preferred.
　（ｂ）アジュバントの含有量は、本発明の組成物中、０.０１～２５質量％が好ましい。（ｂ）アジュバントの含有量の下限は、０.１質量％がより好ましく、０.５質量％がより一層好ましく、１質量％が更に好ましく、３質量％が最も好ましい。また、その上限は、２５質量％がより好ましく、２０質量％がより一層好ましく、１５質量％が更に好ましく、１３質量％が最も好ましい。（ｂ）アジュバントは、１種単独で使用してもよく、２種以上を組み合わせて使用してもよい。２種以上を組み合わせて使用する場合、その比は任意である。 (B) The content of the adjuvant is preferably 0.01 to 25% by mass in the composition of the present invention. (B) The lower limit of the content of the adjuvant is more preferably 0.1% by mass, even more preferably 0.5% by mass, still more preferably 1% by mass, and most preferably 3% by mass. Further, the upper limit is more preferably 25% by mass, still more preferably 20% by mass, still more preferably 15% by mass, and most preferably 13% by mass. (B) An adjuvant may be used individually by 1 type and may be used in combination of 2 or more type. When using in combination of 2 or more types, the ratio is arbitrary.
［（ｃ）分散剤］
　（ｃ）分散剤は、水難溶性である（ａ）農薬活性成分を水中に分散させるための成分である。（ｃ）分散剤としては、特に限定されないが、例えば、アルキレンオキシド鎖を側鎖に有する(メタ)アクリル酸グラフトコポリマー；アルコール開始ＥＯ／ＰＯブロックコポリマー；ポリオキシエチレンポリオキシプロピレンブロックコポリマー；ポリオキシエチレンスチリルフェニルエーテル；アルキドポリエチレンオキシド樹脂；ポリビニルアルコール樹脂；アルコールアルコキシレート；リグノスルホン酸塩；ナフタレンスルホン酸塩又はアルキルナフタレンスルホン酸塩のホルムアルデヒド縮合物；縮合メチルナフタレンスルホン酸塩；アルキルフェノール、ホルムアルデヒド及び任意により亜硫酸ナトリウムのアニオン性縮合物；ポリカルボン酸の塩；トリスチリルフェノールエトキシレートのリン酸エステル等が挙げられる。なお、「ＥＯ／ＰＯ」は、「エチレンオキシド／プロピレンオキシド」を意味する。 [(C) Dispersant]
(C) A dispersing agent is a component for disperse | distributing the agrochemical active ingredient which is sparingly water-soluble in water. (C) Although it does not specifically limit as a dispersing agent, For example, (meth) acrylic acid graft copolymer which has an alkylene oxide chain in a side chain; Alcohol start EO / PO block copolymer; Polyoxyethylene polyoxypropylene block copolymer; Polyoxy Ethylene styryl phenyl ether; alkyd polyethylene oxide resin; polyvinyl alcohol resin; alcohol alkoxylate; lignosulfonate; formaldehyde condensate of naphthalene sulfonate or alkyl naphthalene sulfonate; condensed methyl naphthalene sulfonate; alkylphenol, formaldehyde and optional And an anionic condensate of sodium sulfite; a salt of polycarboxylic acid; a phosphate ester of tristyrylphenol ethoxylate, and the like. “EO / PO” means “ethylene oxide / propylene oxide”.
　前記アルキレンオキシド鎖を側鎖に有する(メタ)アクリル酸グラフトコポリマーとしては、エチレンオキシド鎖やプロピレンオキシド鎖を側鎖に有する(メタ)アクリル酸グラフトコポリマーが挙げられる。前記アルコール開始ＥＯ／ＰＯブロックコポリマーとしては、４－ブトキシ－１－ブタノール開始ＥＯ／ＰＯブロックコポリマー等が挙げられる。 Examples of the (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain include a (meth) acrylic acid graft copolymer having an ethylene oxide chain or a propylene oxide chain in the side chain. Examples of the alcohol-initiated EO / PO block copolymer include 4-butoxy-1-butanol-initiated EO / PO block copolymer.
　（ｃ）分散剤としては、本発明においては、アルキレンオキシド鎖を側鎖に有する(メタ)アクリル酸グラフトコポリマー、アルコール開始ＥＯ／ＰＯブロックコポリマー、ポリオキシエチレンポリオキシプロピレンブロックコポリマー、ポリオキシエチレンスチリルフェニルエーテル等が好ましい。前記分散剤としてポリオキシエチレンポリオキシプロピレンブロックコポリマー又はポリオキシエチレンスチリルフェニルエーテルを用いる場合は、特に、グリフィンの式により算出したＨＬＢ値が７～１７程度のものが粒子成長を抑制する観点から好ましい。 (C) As the dispersant, in the present invention, (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain, alcohol-initiated EO / PO block copolymer, polyoxyethylene polyoxypropylene block copolymer, polyoxyethylene styryl Phenyl ether and the like are preferable. When polyoxyethylene polyoxypropylene block copolymer or polyoxyethylene styryl phenyl ether is used as the dispersant, those having an HLB value calculated by the Griffin equation of about 7 to 17 are particularly preferable from the viewpoint of suppressing particle growth. .
　（ｃ）分散剤としては、市販品を使用することができ、その具体例は、アルキレンオキシド鎖を側鎖に有する(メタ)アクリル酸グラフトコポリマーとしては、Croda社製Atlox（登録商標）4913等が挙げられる。アルコール開始ＥＯ／ＰＯブロックコポリマーとしては、Croda社製Atlas（登録商標）G-5000、G-5002L等、Croda社製SYNPERONIC（登録商標）PE/L 62、PE/L 44、PE/F 127、PE/L 31等が挙げられる。ポリオキシエチレンスチリルフェニルエーテルとしては、東邦化学工業(株)製ソルポール（登録商標）T20等が挙げられる。ポリオキシエチレンスチリルフェニルエーテルとポリオキシエチレンポリオキシプロピレンブロックコポリマーとの混合物としては、東邦化学工業(株)製ソルポール3353等が挙げられる。ポリオキシエチレンポリオキシプロピレンブロックコポリマーとしては、BASF社製Pluronic（登録商標）PEシリーズ、三洋化成工業(株)製ニューポールPEシリーズ等が挙げられる。 (C) A commercially available product can be used as the dispersing agent, and specific examples thereof include an Atlox (registered trademark) 4913 manufactured by Croda as a (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain. Is mentioned. Examples of alcohol-initiated EO / PO block copolymers include Atlas (registered trademark) G-5000 and G-5002L manufactured by Croda, SYNPERONIC (registered trademark) PE / L 62, PE / L 44, PE / F 127 manufactured by Croda, PE / L 31 etc. are mentioned. Examples of the polyoxyethylene styryl phenyl ether include Solpol (registered trademark) T20 manufactured by Toho Chemical Industry Co., Ltd. Examples of the mixture of the polyoxyethylene styryl phenyl ether and the polyoxyethylene polyoxypropylene block copolymer include Solpol 3353 manufactured by Toho Chemical Industry Co., Ltd. Examples of the polyoxyethylene polyoxypropylene block copolymer include Pluronic (registered trademark) PE series manufactured by BASF, New Pole PE series manufactured by Sanyo Chemical Industries, Ltd., and the like.
　（ｃ）分散剤の含有量は、本発明の組成物中、０.１～１５質量％が好ましい。（ｃ）分散剤の含有量の下限は、０.２質量％がより好ましく、０.３質量％がより一層好ましく、０.４質量％が更に好ましく、０.５質量％が最も好ましい。また、その上限は、７.５質量％がより好ましく、５質量％がより一層好ましく、４質量％が更に好ましく、３質量％が最も好ましい。（ｃ）分散剤は、１種単独で使用してもよく、２種以上を組み合わせて使用してもよい。２種以上を組み合わせて使用する場合、その比は任意である。 (C) The content of the dispersant is preferably 0.1 to 15% by mass in the composition of the present invention. (C) The lower limit of the content of the dispersant is more preferably 0.2% by mass, still more preferably 0.3% by mass, still more preferably 0.4% by mass, and most preferably 0.5% by mass. Moreover, the upper limit is more preferably 7.5% by mass, even more preferably 5% by mass, still more preferably 4% by mass, and most preferably 3% by mass. (C) A dispersing agent may be used individually by 1 type, and may be used in combination of 2 or more type. When using in combination of 2 or more types, the ratio is arbitrary.
　特に、本発明において（ｃ）分散剤としては、アルコール開始ＥＯ／ＰＯブロックコポリマー又はポリオキシエチレンポリオキシプロピレンブロックコポリマーが好ましく、アルコール開始ＥＯ／ＰＯブロックコポリマーがより好ましい。以下、これらを総称してブロックコポリマー分散剤という。ブロックコポリマー分散剤を使用する場合、農薬活性成分である（ａ）成分の含有量の、前記ブロックコポリマー分散剤の含有量に対する比が、１５以下となるようにブロックコポリマー分散剤を添加することが好ましく、１４以下となるように添加することがより好ましく、１３以下となるように添加することがより一層好ましく、１２以下となるように添加することが更に好ましく、１１.５以下となるように添加することが最も好ましい。このような添加量でブロックコポリマー分散剤を使用することで、粒子の成長率をより小さいものとすることができる。なお、前記比の下限は、特に限定されないが、通常３程度であり、５以上が好ましい。 In particular, in the present invention, (c) the dispersant is preferably an alcohol-initiated EO / PO block copolymer or a polyoxyethylene polyoxypropylene block copolymer, and more preferably an alcohol-initiated EO / PO block copolymer. Hereinafter, these are collectively referred to as a block copolymer dispersant. When the block copolymer dispersant is used, the block copolymer dispersant may be added so that the ratio of the content of the component (a) which is an agrochemical active ingredient to the content of the block copolymer dispersant is 15 or less. Preferably, it is more preferably added to be 14 or less, still more preferably 13 or less, still more preferably 12 or less, and 11.5 or less. Most preferably, it is added. By using the block copolymer dispersant in such an added amount, the growth rate of the particles can be made smaller. In addition, although the minimum of the said ratio is not specifically limited, Usually, it is about 3 and 5 or more are preferable.
［その他の成分（補助剤）］
　本発明の組成物は、更に各種補助剤を含んでもよい。前記補助剤としては、水性懸濁状農薬組成物に使用されるものであれば特に限定されないが、具体的には、増粘剤、凍結防止剤、消泡剤、防菌防黴剤、着色剤等が挙げられる。 [Other ingredients (adjuvant)]
The composition of the present invention may further contain various adjuvants. The auxiliary agent is not particularly limited as long as it is used in an aqueous suspension agricultural chemical composition, and specifically, a thickener, an antifreezing agent, an antifoaming agent, an antifungal and antifungal agent, a coloring agent. Agents and the like.
　増粘剤としては、特に限定されず、有機、無機の天然物、合成品及び半合成品を用いることができ、例えば、キサンタンガム、ウェランガム及びラムザンガム等のヘテロ多糖類；ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸、ポリアクリル酸ナトリウム及びポリアクリルアミド等の水溶性高分子化合物；メチルセルロース、カルボキシメチルセルロース、カルボキシエチルセルロース、ヒドロキシエチルセルロース及びヒドロキシプロピルセルロース等のセルロース誘導体；モンモリロナイト、サポナイト、ヘクトライト、ベントナイト、ラポナイト及び合成スメクタイト等のスメクタイト系粘土鉱物等が挙げられる。これらの増粘剤は、１種単独で又は２種以上を混合して使用してもよく、混合する場合の比も自由に選択できる。これらの増粘剤は、そのまま添加してもよく、あらかじめ水に分散させたものを添加してもよい。本発明の組成物中、増粘剤の含有量は、本発明の効果を損なわない限り、特に限定されない。 The thickener is not particularly limited, and organic, inorganic natural products, synthetic products, and semi-synthetic products can be used. For example, heteropolysaccharides such as xanthan gum, welan gum, and rhamzan gum; polyvinyl alcohol, polyvinyl pyrrolidone, poly Water-soluble polymer compounds such as acrylic acid, sodium polyacrylate and polyacrylamide; cellulose derivatives such as methylcellulose, carboxymethylcellulose, carboxyethylcellulose, hydroxyethylcellulose and hydroxypropylcellulose; montmorillonite, saponite, hectorite, bentonite, laponite and synthetic smectite And other smectite clay minerals. These thickeners may be used alone or in combination of two or more, and the ratio in the case of mixing can be freely selected. These thickeners may be added as they are, or those previously dispersed in water may be added. In the composition of the present invention, the content of the thickener is not particularly limited as long as the effects of the present invention are not impaired.
　凍結防止剤としては、エチレングリコール、ジエチレングリコール、プロピレングリコール、ジプロピレングリコール、１,３－プロパンジオール、ポリエチレングリコール、ソルビトール、グリセロール等が挙げられる。これらのうち、前記凍結防止剤としては、粒子の成長率をより小さいものとすることができることから、エチレングリコール、ジエチレングリコール、プロピレングリコール、１,３－プロパンジオールが好ましく、プロピレングリコールがより好ましい。 Examples of the antifreezing agent include ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, 1,3-propanediol, polyethylene glycol, sorbitol, glycerol and the like. Among these, as the antifreeze agent, ethylene glycol, diethylene glycol, propylene glycol, and 1,3-propanediol are preferable, and propylene glycol is more preferable because the growth rate of particles can be reduced.
　凍結防止剤を含む場合、その含有量は、本発明の効果を損なわない限り特に限定されないが、本発明の組成物中、１～３０質量％が好ましい。含有量の下限は、２質量％がより好ましく、３質量％がより一層好ましく、４質量％が更に好ましく、５質量％が最も好ましい。また、その上限は、２５質量％がより好ましく、２０質量％がより一層好ましく、１５質量％が更に好ましく、１０質量％が最も好ましい。前記凍結防止剤は、１種単独で使用してもよく、２種以上を組み合わせて使用してもよい。２種以上を組み合わせて使用する場合、その比は任意である。 When the antifreezing agent is included, its content is not particularly limited as long as the effect of the present invention is not impaired, but 1 to 30% by mass is preferable in the composition of the present invention. The lower limit of the content is more preferably 2% by mass, even more preferably 3% by mass, still more preferably 4% by mass, and most preferably 5% by mass. Further, the upper limit is more preferably 25% by mass, still more preferably 20% by mass, still more preferably 15% by mass, and most preferably 10% by mass. The antifreezing agent may be used alone or in combination of two or more. When using in combination of 2 or more types, the ratio is arbitrary.
　更に、シリコーン系エマルション等の消泡剤、防菌防黴剤、着色剤等を、本発明の効果を損なわない範囲で配合してもよい。 Furthermore, an antifoaming agent such as a silicone-based emulsion, an antibacterial and antifungal agent, a coloring agent, and the like may be blended within a range not impairing the effects of the present invention.
　本発明の組成物の製造方法は、特に限定されないが、例えば、水に前述の各成分を加え、攪拌機により混合して得られる。また、必要に応じて、農薬活性成分、アジュバント、分散剤及びその他補助剤は、それぞれ単独で又は混合して乾式又は湿式粉砕機により微粉砕してもよい。 The method for producing the composition of the present invention is not particularly limited. For example, the composition can be obtained by adding the above-described components to water and mixing with a stirrer. If necessary, the pesticidal active ingredient, adjuvant, dispersant and other adjuvants may be pulverized by a dry or wet pulverizer alone or in combination.
　乾式粉砕は、衝撃式粉砕機、ボールミル、ジェットミル等で行うことができる。湿式粉砕による微粉砕は、アトライター、サンドグラインダー、ダイノミル、パールミル、アペックスミル、ビスコミル、ウルトラビスコミル等の湿式粉砕機により行うことができる。 Dry pulverization can be performed with an impact pulverizer, a ball mill, a jet mill or the like. The fine pulverization by wet pulverization can be performed by a wet pulverizer such as an attritor, a sand grinder, a dyno mill, a pearl mill, an apex mill, a visco mill, or an ultra visco mill.
　本発明の組成物は、例えば、原液のまま水田に直接散布する方法、水で５０～５,０００倍程度に希釈して、噴霧機等を用いて作物又はそれが生育する土壌に散布する方法、空中からヘリコプター、ドローン等を使用して、原液のまま又は水で２～１００倍程度に希釈して散布する方法等で施用することができる。 The composition of the present invention is, for example, a method in which it is directly sprayed on a paddy field as it is, or a method in which it is diluted 50 to 5,000 times with water and sprayed on a crop or soil in which it grows using a sprayer or the like. It can be applied from the air by using a helicopter, drone, etc., in the form of a raw solution or by diluting it with water to about 2 to 100 times.
　以下、調製例、実施例及び比較例を挙げて、本発明をより具体的に説明するが、本発明は、下記実施例に限定されない。 Hereinafter, the present invention will be described more specifically with reference to preparation examples, examples and comparative examples, but the present invention is not limited to the following examples.
［１］プリゲルの調製
［調製例１］プリゲルＡの調製
　水９８.５質量部に、キサンタンガム（商品名：KELZAN S、CP Kelco社製）１.０質量部及び１,２－ベンゾイソチアゾリン－３－オン（商品名：PROXEL GXL、Lonza社製）０.５質量部をこの順で分散させ、プリゲルＡを１００質量部得た。 [1] Preparation of Pregel [Preparation Example 1] Preparation of Prigel A To 98.5 parts by mass of water, 1.0 part by mass of xanthan gum (trade name: KELZAN S, CP Kelco) and 1,2-benzisothiazoline-3 -On (trade name: PROXEL GXL, Lonza) 0.5 parts by mass was dispersed in this order to obtain 100 parts by mass of pregel A.
［調製例２］プリゲルＢの調製
　水９６.０質量部にスメクタイトクレー（商品名：VEEGUM R、R. T. Vanderbilt社製）４.００質量部を分散させ、プリゲルＢを１００質量部得た。 [Preparation Example 2] Preparation of pregel B 4.00 parts by mass of smectite clay (trade name: VEEGUM R, manufactured by R. T. Vanderbilt) was dispersed in 96.0 parts by mass of water to obtain 100 parts by mass of pregel B.
［２］水性懸濁状農薬組成物の調製
［実施例１－１］水性懸濁状農薬組成物Ａ１の調製
１．粉砕スラリーの調製
　水１７.０４質量部に、アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）１.５０質量部、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）１.５０質量部、シリコーン系消泡剤（商品名：Xiameter AFE-1530 Antifoam Emulsion、DOW CORNING社製）０.３０質量部、プロピレングリコール１０.００質量部、及び農薬活性成分として化合物Ａ（純度９６.９％）１４.６６質量部を分散させ、０.８－１.２ｍｍφガラスビーズ４５ｍＬを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＡを４５質量部得た。 [2] Preparation of aqueous suspension agricultural chemical composition [Example 1-1] Preparation of aqueous suspension agricultural chemical composition A1 Preparation of pulverized slurry In 17.04 parts by mass of water, 1.50 parts by mass of an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda), butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 1. 50 parts by mass, silicone-based antifoaming agent (trade name: Xiameter AFE-1530 Antifoam Emulsion, manufactured by DOW CORNING) 0.30 part by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96. 9%) 14.66 parts by mass were dispersed and wet-pulverized with a sand grinder (manufactured by Imex Co., Ltd.) using 45 mL of 0.8-1.2 mmφ glass beads to obtain 45 parts by mass of pulverized slurry A.
２．分散媒の調製
　水４４.４５質量部に、１,２－ベンゾイソチアゾリン－３－オン（商品名：PROXEL GXL、Lonza社製）０.１０質量部、キサンタンガム（商品名：KELZAN、CP Kelco社製）０.１５質量部及びスメクタイトクレー（商品名：VEEGUM R、R. T. Vanderbilt社製）０.３０質量部をこの順で分散させ、分散媒Ａを４５質量部得た。 2. Preparation of dispersion medium To 44.45 parts by mass of water, 0.10 parts by mass of 1,2-benzoisothiazolin-3-one (trade name: PROXEL GXL, manufactured by Lonza), xanthan gum (trade name: KELZAN, manufactured by CP Kelco) ) 0.15 parts by mass and 0.30 parts by mass of smectite clay (trade name: VEEGUM R, manufactured by RT Vanderbilt) were dispersed in this order to obtain 45 parts by mass of dispersion medium A.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＡ４５質量部、分散媒Ａ４５質量部及びアルコキシル化ポリオールエステル（商品名：Atplus UEP-100、Croda社製）１０質量部を混合し、均一な水性懸濁状農薬組成物Ａ１を１００質量部得た。 3. Preparation of Aqueous Suspended Pesticide Composition 45 parts by weight of pulverized slurry A, 45 parts by weight of dispersion medium A and 10 parts by weight of alkoxylated polyol ester (trade name: Atplus UEP-100, manufactured by Croda) are mixed to form a uniform aqueous suspension. 100 parts by mass of a pesticide composition A1 was obtained.
［実施例１－２］水性懸濁状農薬組成物Ａ２の調製
　アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）１.５０質量部及びブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）１.５０質量部のかわりにポリオキシエチレンスチリルフェニルエーテル（商品名：ソルポールT-20、東邦化学工業(株)製）３.００質量部を用いた以外は、実施例１－１と同様の方法で、水性懸濁状農薬組成物Ａ２を１００質量部得た。 [Example 1-2] Preparation of aqueous suspension agricultural chemical composition A2 1.50 parts by mass of an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) and a butyl block copolymer (trade name: Atlas G-5002L, Croda) Example 1-1 except that in place of 1.50 parts by mass of polyoxyethylene styryl phenyl ether (trade name: Solpol T-20, manufactured by Toho Chemical Co., Ltd.) of 3.00 parts by mass In the same manner as above, 100 parts by mass of the aqueous suspended agricultural chemical composition A2 was obtained.
［実施例１－３］水性懸濁状農薬組成物Ａ３の調製
１．粉砕スラリーの調製
　水２２.２０質量部に、ポリオキシエチレンスチリルフェニルエーテルとポリオキシエチレンポリオキシプロピレンブロックコポリマーとの混合物（商品名：ソルポール3353、東邦化学(株)製）３.００質量部、シリコーン系消泡剤（商品名：KM-73、信越化学工業(株)製）０.１０質量部、プロピレングリコール１０.００質量部、及び化合物Ａ（純度９６.６％）１４.７０質量部を分散させ、０.８－１.２ｍｍφガラスビーズ５０ｍＬを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＢを５０質量部得た。 [Example 1-3] Preparation of aqueous suspension pesticide composition A3 Preparation of pulverized slurry In 22.20 parts by mass of water, 3.00 parts by mass of a mixture of polyoxyethylene styryl phenyl ether and polyoxyethylene polyoxypropylene block copolymer (trade name: Solpol 3353, manufactured by Toho Chemical Co., Ltd.) Silicone-based antifoaming agent (trade name: KM-73, manufactured by Shin-Etsu Chemical Co., Ltd.) 0.10 parts by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96.6%) 14.70 parts by mass Was dispersed with a sand grinder (manufactured by AIMEX Co., Ltd.) using 50 mL of 0.8-1.2 mmφ glass beads to obtain 50 parts by mass of pulverized slurry B.
２．分散媒の調製
　水１６.０質量部に、プリゲルＡ１４.０質量部、プリゲルＢ７.５質量部及びポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-110、第一製薬工業(株)製）１２.５質量部をこの順で分散させ、分散媒Ｂを５０質量部得た。 2. Preparation of dispersion medium In 16.0 parts by mass of water, 14.0 parts by mass of Prigel A, 7.5 parts by mass of Prigel B, and polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 12.5 parts by mass were dispersed in this order to obtain 50 parts by mass of dispersion medium B.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＢ５０質量部及び分散媒Ｂ５０質量部を混合し、均一な水性懸濁状農薬組成物Ａ３を１００質量部得た。 3. Preparation of Aqueous Suspended Pesticide Composition 50 parts by mass of pulverized slurry B and 50 parts by mass of dispersion medium B were mixed to obtain 100 parts by mass of uniform aqueous suspended agrochemical composition A3.
［実施例１－４］水性懸濁状農薬組成物Ａ４の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-110、第一製薬工業(株)製）のかわりにポリオキシエチレントリデシルエーテル（商品名：ノイゲンTDS-120、第一工業製薬(株)製）を用いた以外は、実施例１－３と同様の方法で、水性懸濁状農薬組成物Ａ４を１００質量部得た。 [Example 1-4] Preparation of aqueous suspension pesticide composition A4 Polyoxyethylene tridecyl ether instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition A4 was obtained in the same manner as in Example 1-3, except that (trade name: Neugen TDS-120, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used.
［実施例１－５］水性懸濁状農薬組成物Ａ５の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-110、第一製薬工業(株)製）のかわりにポリオキシエチレントリデシルエーテル（商品名：ノイゲンTDS-80、第一工業製薬(株)製）を用いた以外は、実施例１－３と同様の方法で、水性懸濁状農薬組成物Ａ５を１００質量部得た。 [Example 1-5] Preparation of aqueous suspension pesticide composition A5 Polyoxyethylene tridecyl ether instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition A5 was obtained in the same manner as in Example 1-3 except that (trade name: Neugen TDS-80, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used.
［実施例１－６］水性懸濁状農薬組成物Ａ６の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-110、第一製薬工業(株)製）のかわりにポリオキシエチレン(C12-14)第２級アルコールエーテル（商品名：ノイゲンET-135、第一工業製薬(株)製）を用いた以外は、実施例１－３と同様の方法で、水性懸濁状農薬組成物Ａ６を１００質量部得た。 [Example 1-6] Preparation of aqueous suspension pesticide composition A6 Polyoxyethylene (C12-) instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 14) Aqueous suspended agricultural chemical composition A6 in the same manner as in Example 1-3, except that secondary alcohol ether (trade name: Neugen ET-135, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used. 100 parts by mass was obtained.
［実施例１－７］水性懸濁状農薬組成物Ａ７の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-110、第一製薬工業(株)製）のかわりにポリオキシアルキレン分岐デシルエーテル（商品名：ノイゲンXL-100、第一工業製薬(株)製）を用いた以外は、実施例１－３と同様の方法で、水性懸濁状農薬組成物Ａ７を１００質量部得た。 [Example 1-7] Preparation of aqueous suspension agricultural chemical composition A7 Polyoxyalkylene branched decyl ether instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-110, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition A7 was obtained in the same manner as in Example 1-3, except that (trade name: Neugen XL-100, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) was used.
［実施例１－８］水性懸濁状農薬組成物Ｂ１の調製
１．粉砕スラリーの調製
　水１７.０４質量部に、ポリオキシエチレンスチリルフェニルエーテル（商品名：ソルポールT-20、東邦化学工業(株)製）３.００質量部、シリコーン系消泡剤（商品名：KM-73、信越化学工業(株)製）０.３０質量部、プロピレングリコール１０.００質量部、及び化合物Ａ（純度９６.９％）１４.６６質量部を分散させ、０.８－１.２ｍｍφガラスビーズ５０ｍＬを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＣを４５質量部得た。 [Example 1-8] Preparation of aqueous suspension pesticide composition B1 Preparation of pulverized slurry To 17.04 parts by mass of water, 3.00 parts by mass of polyoxyethylene styryl phenyl ether (trade name: Solpol T-20, manufactured by Toho Chemical Co., Ltd.), silicone antifoaming agent (trade name: KM-73 (manufactured by Shin-Etsu Chemical Co., Ltd.) 0.30 parts by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96.9%) 14.66 parts by mass were dispersed to obtain 0.8-1. Using 50 mL of 0.2 mmφ glass beads, wet grinding was performed with a sand grinder (manufactured by IMEX Co., Ltd.) to obtain 45 parts by mass of pulverized slurry C.
２．分散媒の調製
　水４４.４０質量部に、１,２－ベンゾイソチアゾリン－３－オン（商品名：PROXEL GXL、Lonza社製）０.１０質量部、キサンタンガム（商品名：KELZAN、CP Kelco社製）０.２０質量部及びスメクタイトクレー（商品名：VEEGUM R、R. T. Vanderbilt社製）０.３０質量部をこの順で分散させ、分散媒Ｃを４５質量部得た。 2. Preparation of dispersion medium To 44.40 parts by mass of water, 0.10 parts by mass of 1,2-benzisothiazolin-3-one (trade name: PROXEL GXL, Lonza), xanthan gum (trade name: KELZAN, CP Kelco) ) 0.20 part by mass and smectite clay (trade name: VEEGUM R, manufactured by RT Vanderbilt) 0.30 part by mass were dispersed in this order to obtain 45 parts by mass of dispersion medium C.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＣ４５質量部、分散媒Ｃ４５質量部及びトリシロキサンエトキシレート（商品名：Silwet L-77、Momentive Performance Materials Inc.製）１０質量部を混合し、均一な水性懸濁状農薬組成物Ｂ１を１００質量部得た。 3. Preparation of Aqueous Suspended Pesticide Composition Mix 45 parts by weight of the slurry C45, 45 parts by weight of the dispersion medium C, and 10 parts by weight of trisiloxane ethoxylate (trade name: Silwet L-77, manufactured by Momentive Performance Materials Inc.) 100 parts by mass of the aqueous suspended agricultural chemical composition B1 was obtained.
［３］保存安定性の評価
［実施例２－１～２－８］
　水性懸濁状農薬組成物Ａ１～Ａ７及びＢ１をそれぞれ３０ｍＬ容バイアル瓶に入れ、５４℃の恒温槽で２週間保存した。製造直後及び保存後のメジアン径（Ｄ50）を、(株)堀場製作所製粒度分布測定装置LA-960Sを用いてレーザ回折散乱法で測定した。結果を表１に示す。なお、粒子成長率は、下記式によって算出した。
　　粒子成長率（％）＝[(保存後のＤ50－製造直後のＤ50)／製造直後のＤ50]×１００ [3] Evaluation of storage stability [Examples 2-1 to 2-8]
Aqueous suspended pesticidal compositions A1 to A7 and B1 were each placed in a 30 mL vial and stored in a constant temperature bath at 54 ° C. for 2 weeks. The median diameter (D 50 ) immediately after production and after storage was measured by a laser diffraction scattering method using a particle size distribution analyzer LA-960S manufactured by Horiba, Ltd. The results are shown in Table 1. The particle growth rate was calculated by the following formula.
Grain growth rate (%) = [- / immediately after preparation D 50 (after storage D 50 D 50 immediately after manufacture)] × 100
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
　表１に示した結果より、本発明の水性懸濁状農薬組成物は、保存中の農薬活性成分の粒子成長が抑制され、保存安定性が良好であることがわかった。 From the results shown in Table 1, it was found that the aqueous suspension pesticide composition of the present invention has good storage stability because particle growth of the pesticidal active ingredient during storage is suppressed.
［４］水性懸濁状農薬組成物の調製
［実施例３－１］水性懸濁状農薬組成物Ｃ１の調製
１．粉砕スラリーの調製
　水５９.３１質量部に、アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）１.５０質量部、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）３.００質量部、プロピレングリコール９.２１質量部、及び農薬活性成分として化合物Ａ（純度９６.３％）１７.２２質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＤを９０.６４質量部得た。 [4] Preparation of aqueous suspension agricultural chemical composition [Example 3-1] Preparation of aqueous suspension agricultural chemical composition C1 Preparation of pulverized slurry In 59.31 parts by mass of water, 1.50 parts by mass of acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda), butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 3. 00 parts by mass, 9.21 parts by mass of propylene glycol, and 17.22 parts by mass of compound A (purity 96.3%) as an agrochemical active ingredient were dispersed, and a sand grinder (0.8-1.2 mmφ glass beads) was used. 90.64 parts by mass of pulverized slurry D was obtained.
２．水性懸濁状農薬組成物の調製
　粉砕スラリーＤ９０.６４質量部、キサンタンガム（商品名：KELZAN、CP Kelco社製）０.１５質量部及びアルコキシル化ポリオールエステル（商品名：Atplus UEP-100、Croda社製）９.２１質量部を混合し、均一な水性懸濁状農薬組成物Ｃ１を１００質量部得た。 2. Preparation of aqueous suspension agricultural chemical composition 90.64 parts by mass of pulverized slurry D, 0.15 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) and alkoxylated polyol ester (trade name: Atplus UEP-100, Croda) 9) 21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition C1.
［実施例３－２］水性懸濁状農薬組成物Ｃ２の調製
　水及びブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）使用量をそれぞれ６０.８１質量部及び１.５０質量部とし、得られた粉砕スラリー及びキサンタンガム（商品名：KELZAN、CP Kelco社製）の使用量をそれぞれ９０.２４質量部及び０.５５質量部とした以外は、実施例３－１と同様の方法で、水性懸濁状農薬組成物Ｃ２を１００質量部得た。 [Example 3-2] Preparation of aqueous suspension agricultural chemical composition C2 Water and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) were used in amounts of 60.81 parts by mass and 1.50 parts by mass, respectively. And the amount of the obtained pulverized slurry and xanthan gum (trade name: KELZAN, CP Kelco) was 90.24 parts by mass and 0.55 parts by mass, respectively. Thus, 100 parts by mass of the aqueous suspended agricultural chemical composition C2 was obtained.
［実施例３－３］水性懸濁状農薬組成物Ｃ３の調製
　水、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）及び化合物Ａ（純度９６.３％）の使用量を、それぞれ６３.４３質量部、１.５０質量部及び１５.００質量部とした以外は、実施例３－１と同様の方法で、水性懸濁状農薬組成物Ｃ３を１００質量部得た。 [Example 3-3] Preparation of aqueous suspension agricultural chemical composition C3 The amounts of water, butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) and compound A (purity 96.3%) were used. 100 parts by weight of an aqueous suspended agricultural chemical composition C3 was obtained in the same manner as in Example 3-1, except that the amount was 63.43 parts by weight, 1.50 parts by weight, and 15.00 parts by weight, respectively.
［実施例３－４］水性懸濁状農薬組成物Ｃ４の調製
　アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）を使用せず、水、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）及び化合物Ａの使用量をそれぞれ６４.９３質量部、１.５０質量部及び１５.００質量部とした以外は、実施例３－１と同様の方法で、水性懸濁状農薬組成物Ｃ４を１００質量部得た。 [Example 3-4] Preparation of aqueous suspension pesticide composition C4 Water and butyl block copolymer (trade name: Atlas G-5002L) were used without using an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda). Croda) and Compound A were used in the same manner as in Example 3-1, except that the amounts used were 64.93 parts by weight, 1.50 parts by weight, and 15.00 parts by weight, respectively. 100 mass parts of composition C4 was obtained.
［実施例３－５］水性懸濁状農薬組成物Ｃ５の調製
　水及び化合物Ａ（純度９６.３％）の使用量をそれぞれ６３.４３質量部及び１５.００質量部とし、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）３.００質量部のかわりにポリアルキレンオキシドブロックコポリマー（商品名：Atlas G-5000、Croda社製）１.５０質量部を用いた以外は、実施例３－１と同様の方法で、水性懸濁状農薬組成物Ｃ５を１００質量部得た。 [Example 3-5] Preparation of aqueous suspension pesticide composition C5 The amounts of water and compound A (purity 96.3%) used were 63.43 parts by mass and 15.00 parts by mass, respectively. (Product name: Atlas G-5002L, manufactured by Croda) Instead of using 3.00 parts by mass, a polyalkylene oxide block copolymer (Product name: Atlas G-5000, manufactured by Croda) was used except that 1.50 parts by mass were used. In the same manner as in Example 3-1, 100 parts by mass of the aqueous suspended agricultural chemical composition C5 was obtained.
［実施例３－６］水性懸濁状農薬組成物Ｃ６の調製
　ポリアルキレンオキシドブロックコポリマー（商品名：Atlas G-5000、Croda社製）のかわりにポリオキシエチレンポリオキシプロピレンブロックコポリマー（商品名：SYNPERONIC PE/L 62、Croda社製、HLB: 7）を用いた以外は、実施例３－５と同様の方法で、水性懸濁状農薬組成物Ｃ６を１００質量部得た。 [Example 3-6] Preparation of aqueous suspension pesticide composition C6 Polyoxyethylene polyoxypropylene block copolymer (trade name: Trade name: Atlas G-5000, manufactured by Croda) instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda) 100 parts by mass of the aqueous suspended agricultural chemical composition C6 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / L 62, manufactured by Croda, HLB: 7) was used.
［実施例３－７］水性懸濁状農薬組成物Ｃ７の調製
　ポリアルキレンオキシドブロックコポリマー（商品名：Atlas G-5000、Croda社製）のかわりにポリオキシエチレンポリオキシプロピレンブロックコポリマー（商品名：SYNPERONIC PE/L 44、Croda社製、HLB: 16）を用いた以外は、実施例３－５と同様の方法で、水性懸濁状農薬組成物Ｃ７を１００質量部得た。 Example 3-7 Preparation of Aqueous Suspended Pesticide Composition C7 Polyoxyethylene polyoxypropylene block copolymer (trade name: trade name: Atlas G-5000, manufactured by Croda) instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda) 100 parts by mass of an aqueous suspended agricultural chemical composition C7 was obtained in the same manner as in Example 3-5 except that SYNPERONIC PE / L 44, manufactured by Croda, HLB: 16) was used.
［実施例３－８］水性懸濁状農薬組成物Ｃ８の調製
１．粉砕スラリーの調製
　水１７.０４質量部に、ポリオキシエチレンスチリルフェニルエーテル（商品名：ソルポールT-20、東邦化学工業(株)製、HLB: 13.3）３.００質量部、シリコーン系消泡剤（商品名：Xiameter AFE-1530 Antifoam Emulsion、DOW CORNING社製）０.３０質量部、プロピレングリコール１０.００質量部、及び化合物Ａ（純度９６.９％）１４.６６質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＥを４５質量部得た。 [Example 3-8] Preparation of aqueous suspension pesticide composition C8 Preparation of pulverized slurry To 17.04 parts by mass of water, 3.00 parts by mass of polyoxyethylene styryl phenyl ether (trade name: Solpol T-20, manufactured by Toho Chemical Co., Ltd., HLB: 13.3), silicone-based antifoaming agent (Product name: Xiameter AFE-1530 Antifoam Emulsion, manufactured by DOW CORNING) 0.30 parts by mass, 10.00 parts by mass of propylene glycol, and 14.66 parts by mass of compound A (purity 96.9%) were dispersed, and 0 Using 0.8-1.2 mmφ glass beads, wet pulverization was performed with a sand grinder (manufactured by IMEX Co., Ltd.) to obtain 45 parts by mass of pulverized slurry E.
２．分散媒の調製
　水４４.４５質量部に、１,２－ベンゾイソチアゾリン－３－オン（商品名：PROXEL GXL、Lonza社製）０.１０質量部、キサンタンガム（商品名：KELZAN、CP Kelco社製）０.１５質量部及びスメクタイトクレー（商品名：VEEGUM R、R. T. Vanderbilt社製）０.３０質量部をこの順で分散させ、分散媒Ｅを４５質量部得た。 2. Preparation of dispersion medium To 44.45 parts by mass of water, 0.10 parts by mass of 1,2-benzoisothiazolin-3-one (trade name: PROXEL GXL, manufactured by Lonza), xanthan gum (trade name: KELZAN, manufactured by CP Kelco) ) 0.15 parts by mass and 0.30 parts by mass of smectite clay (trade name: VEEGUM R, manufactured by RT Vanderbilt) were dispersed in this order to obtain 45 parts by mass of dispersion medium E.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＥ４５質量部、分散媒Ｅ４５質量部及びアルコキシル化ポリオールエステル（商品名：Atplus UEP-100、Croda社製）１０質量部を混合し、均一な水性懸濁状農薬組成物Ｃ８を１００質量部得た。 3. Preparation of Aqueous Suspended Pesticide Composition Mixing 45 parts by weight of pulverized slurry E45, 45 parts by weight of dispersion medium E and 10 parts by weight of alkoxylated polyol ester (trade name: Atplus UEP-100, manufactured by Croda), uniform aqueous suspension 100 parts by mass of a pesticide composition C8 was obtained.
［実施例３－９］水性懸濁状農薬組成物Ｃ９の調製
１．粉砕スラリーの調製
　水１３.４５質量部に、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）１.５０質量部、シリコーン系消泡剤（商品名：Xiameter AFE-1530 Antifoam Emulsion、DOW CORNING社製）０.３０質量部、プロピレングリコール１０.００質量部、及び化合物Ａ（純度９６.３％）１４.７５質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＦ４０質量部を得た。 [Example 3-9] Preparation of aqueous suspension pesticide composition C9 Preparation of pulverized slurry To 13.45 parts by mass of water, 1.50 parts by mass of butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), silicone antifoaming agent (trade name: Xiameter AFE-1530 Antifoam Emulsion, DOW CORNING Co., Ltd.) 0.30 parts by mass, propylene glycol 10.00 parts by mass, and compound A (purity 96.3%) 14.75 parts by mass are dispersed using 0.8-1.2 mmφ glass beads. Wet pulverization was performed with a sand grinder (manufactured by IMEX Co., Ltd.) to obtain 40 parts by mass of pulverized slurry F.
２．分散媒の調製
　水４９.４５質量部に、１,２－ベンゾイソチアゾリン－３－オン（商品名：PROXEL GXL、Lonza社製）０.１０質量部、キサンタンガム（商品名：KELZAN、CP Kelco社製）０.１５質量部及びスメクタイトクレー（商品名：VEEGUM R、R. T. Vanderbilt社製）０.３０質量部をこの順で分散させ、分散媒Ｆ５０質量部を得た。 2. Preparation of dispersion medium To 49.45 parts by mass of water, 0.10 parts by mass of 1,2-benzisothiazolin-3-one (trade name: PROXEL GXL, manufactured by Lonza), xanthan gum (trade name: KELZAN, manufactured by CP Kelco) ) 0.15 parts by mass and smectite clay (trade name: VEEGUM R, RT Vanderbilt) 0.30 parts by mass were dispersed in this order to obtain 50 parts by mass of dispersion medium F.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＦ４０質量部、分散媒Ｆ５０質量部及びポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13.2）１０質量部を混合し、均一な水性懸濁状農薬組成物Ｃ９を１００質量部得た。 3. Preparation of Aqueous Suspended Pesticide Composition Grinding slurry F 40 parts by mass, dispersion medium F 50 parts by mass and polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) 10 100 parts by mass of a uniform aqueous suspension agricultural chemical composition C9 was obtained by mixing parts by mass.
［実施例３－１０］水性懸濁状農薬組成物Ｃ１０の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13.2）のかわりにポリオキシアルキレントリデシルエーテル（商品名：ノイゲンTDX-100D、第一製薬工業(株)製、HLB: 13.5）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｃ１０を１００質量部得た。 [Example 3-10] Preparation of aqueous suspension agricultural chemical composition C10 Instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2), polyoxy Aqueous suspension pesticide composition in the same manner as in Example 3-9, except that alkylene tridecyl ether (trade name: Neugen TDX-100D, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.5) was used. 100 parts by mass of C10 was obtained.
［実施例３－１１］水性懸濁状農薬組成物Ｃ１１の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13.2）のかわりにポリオキシアルキレントリデシルエーテル（商品名：ノイゲンTDX-120D、第一製薬工業(株)製、HLB: 14.3）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｃ１１を１００質量部得た。 [Example 3-11] Preparation of aqueous suspension pesticide composition C11 Polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) Aqueous suspension pesticide composition in the same manner as in Example 3-9, except that alkylene tridecyl ether (trade name: Neugen TDX-120D, Daiichi Pharmaceutical Co., Ltd., HLB: 14.3) was used. 100 parts by mass of C11 was obtained.
［実施例３－１２］水性懸濁状農薬組成物Ｃ１２の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13.2）のかわりにモノラウリン酸ポリオキシエチレン(20)ソルビタン（商品名：Tween 20、Croda社製、HLB: 17）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｃ１２を１００質量部得た。 [Example 3-12] Preparation of aqueous suspension pesticide composition C12 Monolauric acid instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) 100 masses of the aqueous suspended agricultural chemical composition C12 was carried out in the same manner as in Example 3-9, except that polyoxyethylene (20) sorbitan (trade name: Tween 20, manufactured by Croda, HLB: 17) was used. I got a part.
［実施例３－１３］水性懸濁状農薬組成物Ｃ１３の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13.2）のかわりにモノオレイン酸ポリオキシエチレン(20)ソルビタン（商品名：Tween 80、Croda社製、HLB: 15）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｃ１３を１００質量部得た。 [Example 3-13] Preparation of aqueous suspension agricultural chemical composition C13 Monoolein instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) Aqueous suspension pesticide composition C13 was prepared in the same manner as in Example 3-9 except that acid polyoxyethylene (20) sorbitan (trade name: Tween 80, Croda, HLB: 15) was used. A mass part was obtained.
［実施例３－１４］水性懸濁状農薬組成物Ｃ１４の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13.2）のかわりにモノラウリン酸ポリオキシエチレン(4)ソルビタン（商品名：Tween 21、Croda社製、HLB: 13）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｃ１４を１００質量部得た。 [Example 3-14] Preparation of aqueous suspension agricultural chemical composition C14 Monolauric acid instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) Except for using polyoxyethylene (4) sorbitan (trade name: Tween 21, Croda, HLB: 13), 100 mass of the aqueous suspended agricultural chemical composition C14 was obtained in the same manner as in Example 3-9. I got a part.
［実施例３－１５］水性懸濁状農薬組成物Ｃ１５の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13）のかわりにイソステアリン酸ポリオキシエチレングリセリル（商品名：ノイゲンGIS-108、第一工業製薬(株)製、HLB: 12.1）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｃ１５を１００質量部得た。 [Example 3-15] Preparation of aqueous suspended agricultural chemical composition C15 Isostearic acid instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-9, except that polyoxyethylene glyceryl (trade name: Neugen GIS-108, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., HLB: 12.1) was used. 100 parts by mass of C15 was obtained.
［実施例３－１６］水性懸濁状農薬組成物Ｃ１６の調製
１．粉砕スラリーの調製
　水５５.０８質量部に、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）１.５０質量部、プロピレングリコール９.２１質量部、及び化合物Ａ（純度９６.３％）１５.００質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＧ８０.７９質量部を得た。 [Example 3-16] Preparation of aqueous suspension pesticide composition C16 Preparation of pulverized slurry To 55.08 parts by mass of water, 1.50 parts by mass of butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), 9.21 parts by mass of propylene glycol, and compound A (purity 96.3) %) 15.00 parts by mass were dispersed and wet-pulverized with a sand grinder (manufactured by IMEX Co., Ltd.) using 0.8-1.2 mmφ glass beads to obtain 80.79 parts by mass of pulverized slurry G.
２．１.５質量％ケルザンプリゲルの調製
　水９８.５０質量部に、キサンタンガム（商品名：KELZAN、CP Kelco社製）１.５０質量部を分散させ、１.５質量％ケルザンプリゲル１００質量部を得た。 2. Preparation of 1.5% by mass Kelzan Prigel 1.50 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) is dispersed in 98.50 parts by mass of water to obtain 100 parts by mass of 1.5% by mass Kelzan Prigel. It was.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＧ８０.７９質量部、前記１.５質量％ケルザンプリゲル１０質量部及びポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-149、第一製薬工業(株)製、HLB: 11.2）９.２１質量部を混合し、均一な水性懸濁状農薬組成物Ｃ１６を１００質量部得た。 3. Preparation of aqueous suspension agricultural chemical composition 80.79 parts by weight of pulverized slurry G, 10 parts by weight of the above-mentioned 1.5% by weight Kelzan Prigel and polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, Daiichi Pharmaceutical Co., Ltd.) Manufactured, HLB: 11.2) 9.21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspension agricultural chemical composition C16.
［実施例３－１７］水性懸濁状農薬組成物Ｃ１７の調製
　ポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-149、第一製薬工業(株)製、HLB: 11.2）のかわりにポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-159、第一製薬工業(株)製、HLB: 11.2）を用いた以外は、実施例３－１６と同様の方法で、水性懸濁状農薬組成物Ｃ１７を１００質量部得た。 [Example 3-17] Preparation of aqueous suspension pesticide composition C17 Polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, manufactured by Daiichi Pharmaceutical Industries, Ltd., HLB: 11.2) Aqueous suspended agricultural chemical composition in the same manner as in Example 3-16, except that alkylene oleyl cetyl ether (trade name: Neugen ET-159, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 11.2) was used. 100 parts by mass of C17 was obtained.
［実施例３－１８］水性懸濁状農薬組成物Ｃ１８の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13）のかわりにポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-159、第一製薬工業(株)製、HLB: 13.4）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｃ１８を１００質量部得た。 [Example 3-18] Preparation of aqueous suspension pesticide composition C18 Polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-9, except that alkylene oleyl cetyl ether (trade name: Neugen ET-159, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.4) was used. 100 parts by mass of C18 was obtained.
［実施例３－１９］水性懸濁状農薬組成物Ｃ１９の調製
１．粉砕スラリーの調製
　水４７.８６質量部に、アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）１.５０質量部、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）５.００質量部、プロピレングリコール９.２１質量部、及び化合物Ａ（純度９６.３％）１５.００質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＨ８０.７９質量部を得た。 [Example 3-19] Preparation of aqueous suspension pesticide composition C19 Preparation of pulverized slurry: 47.86 parts by mass of water, 1.50 parts by mass of acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda), butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 00 parts by weight, propylene glycol 9.21 parts by weight, and compound A (purity 96.3%) 15.00 parts by weight were dispersed, and a sand grinder (IMEX Co., Ltd.) using 0.8-1.2 mmφ glass beads. Manufactured) to obtain 80.79 parts by mass of pulverized slurry H.
２．１.５質量％ケルザンプリゲルの調製
　水９８.５０質量部に、キサンタンガム（商品名：KELZAN、CP Kelco社製）１.５０質量部を分散させ、１.５質量％ケルザンプリゲル１００質量部を得た。 2. Preparation of 1.5% by mass Kelzan Prigel 1.50 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) is dispersed in 98.50 parts by mass of water to obtain 100 parts by mass of 1.5% by mass Kelzan Prigel. It was.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＨ８０.７９質量部、前記１.５質量％ケルザンプリゲル１０質量部及びアルコキシル化ポリオールエステル（商品名：Atplus UEP-100、Croda社製）９.２１質量部を混合し、均一な水性懸濁状農薬組成物Ｃ１９を１００質量部得た。 3. Preparation of aqueous suspension agricultural chemical composition 80.79 parts by weight of pulverized slurry H, 10 parts by weight of the above-mentioned 1.5% by weight Kelzan pregel and alkoxylated polyol ester (trade name: Atplus UEP-100, manufactured by Croda) 9.21 parts by weight Were mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition C19.
［実施例３－２０］水性懸濁状農薬組成物Ｃ２０の調製
　ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）５.００質量部のかわりに７.００質量部を用いた以外は、実施例３－１９と同様の方法で、水性懸濁状農薬組成物Ｃ２０を１００質量部得た。 [Example 3-20] Preparation of aqueous suspension pesticide composition C20 A butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), except that 7.00 parts by mass was used instead of 5.00 parts by mass In the same manner as in Example 3-19, 100 parts by mass of the aqueous suspended agricultural chemical composition C20 was obtained.
［実施例３－２１］水性懸濁状農薬組成物Ｃ２１の調製
　ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）５.００質量部のかわりに１０.００質量部を用いた以外は、実施例３－１９と同様の方法で、水性懸濁状農薬組成物Ｃ２１を１００質量部得た。 [Example 3-21] Preparation of aqueous suspension pesticide composition C21 A butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda), except that 10.00 parts by mass was used instead of 5.00 parts by mass In the same manner as in Example 3-19, 100 parts by mass of the aqueous suspended agricultural chemical composition C21 was obtained.
［実施例３－２２］水性懸濁状農薬組成物Ｃ２２の調製
　アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）を使用せず、水の使用量を５５.０８質量部及びプロピレングリコールのかわりにエチレングリコールを用いた以外は、実施例３－１９と同様の方法で、水性懸濁状農薬組成物Ｃ２２を１００質量部得た。 [Example 3-22] Preparation of Aqueous Suspension Pesticide Composition C22 An acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) was not used, the amount of water used was 55.08 parts by mass, and propylene glycol was used. Instead of using ethylene glycol, 100 parts by mass of an aqueous suspended agricultural chemical composition C22 was obtained in the same manner as in Example 3-19.
［実施例３－２３］水性懸濁状農薬組成物Ｃ２３の調製
　プロピレングリコールのかわりにジエチレングリコールを用いた以外は、実施例３－２２と同様の方法で、水性懸濁状農薬組成物Ｃ２３を１００質量部得た。 [Example 3-23] Preparation of aqueous suspended agricultural chemical composition C23 Aqueous suspended agricultural chemical composition C23 was prepared in the same manner as in Example 3-22 except that diethylene glycol was used instead of propylene glycol. A mass part was obtained.
［実施例３－２４］水性懸濁状農薬組成物Ｃ２４の調製
　プロピレングリコールのかわりにジプロピレングリコールを用いた以外は、実施例３－２２と同様の方法で、水性懸濁状農薬組成物Ｃ２４を１００質量部得た。 [Example 3-24] Preparation of aqueous suspended pesticidal composition C24 Aqueous suspended pesticidal composition C24 was prepared in the same manner as in Example 3-22, except that dipropylene glycol was used instead of propylene glycol. 100 parts by mass was obtained.
［実施例３－２５］水性懸濁状農薬組成物Ｃ２５の調製
　プロピレングリコールのかわりに１、３－プロパンジオールを用いた以外は、実施例３－２２と同様の方法で、水性懸濁状農薬組成物Ｃ２５を１００質量部得た。 [Example 3-25] Preparation of aqueous suspended agricultural chemical composition C25 An aqueous suspended agricultural chemical in the same manner as in Example 3-22, except that 1,3-propanediol was used instead of propylene glycol. 100 mass parts of composition C25 were obtained.
［実施例３－２６］水性懸濁状農薬組成物Ｃ２６の調製
　プロピレングリコールのかわりにポリエチレングリコール４００を用いた以外は、実施例３－２２と同様の方法で、水性懸濁状農薬組成物Ｃ２６を１００質量部得た。 [Example 3-26] Preparation of aqueous suspended pesticidal composition C26 Aqueous suspended pesticidal composition C26 was prepared in the same manner as in Example 3-22, except that polyethylene glycol 400 was used instead of propylene glycol. 100 parts by mass was obtained.
［実施例３－２７］水性懸濁状農薬組成物Ｃ２７の調製
　プロピレングリコールのかわりにＤ－ソルビトール（商品名：ソルビトールＦ、成分重量６０％、物産フードサイエンス(株)製）を用いた以外は、実施例３－２２と同様の方法で、水性懸濁状農薬組成物Ｃ２７を１００質量部得た。 [Example 3-27] Preparation of aqueous suspension pesticide composition C27 Except that propylene glycol was used, D-sorbitol (trade name: sorbitol F, component weight 60%, manufactured by Food Science Co., Ltd.) was used. In the same manner as in Example 3-22, 100 parts by mass of the aqueous suspended agricultural chemical composition C27 was obtained.
［実施例４－１］水性懸濁状農薬組成物Ｄ１の調製
１．粉砕スラリーの調製
　水５９.５８質量部に、アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）３.６８質量部、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）０.５５質量部、及び化合物Ａ（純度９６.３％）１７.２２質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＩを８１.０３質量部得た。 [Example 4-1] Preparation of aqueous suspension pesticide composition D1 Preparation of pulverized slurry In 59.58 parts by mass of water, 3.68 parts by mass of an acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda), butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) is 0.5. 55 parts by mass and 17.22 parts by mass of Compound A (purity 96.3%) were dispersed, wet-ground with a sand grinder (manufactured by Imex Co., Ltd.) using 0.8-1.2 mmφ glass beads, and pulverized 81.03 parts by mass of slurry I were obtained.
２．水性懸濁状農薬組成物の調製
　粉砕スラリーＩ８１.０３質量部、グリセロール９.２１質量部、キサンタンガム（商品名：KELZAN、CP Kelco社製）０.５５質量部及びアルコキシル化ポリオールエステル（商品名：Atplus UEP-100、Croda社製）９.２１質量部を混合し、均一な水性懸濁状農薬組成物Ｄ１を１００質量部得た。 2. Preparation of Aqueous Suspended Pesticide Composition 81.03 parts by weight of pulverized slurry I, 9.21 parts by weight of glycerol, 0.55 parts by weight of xanthan gum (trade name: KELZAN, CP Kelco) and alkoxylated polyol ester (trade name: (Atplus UEP-100, manufactured by Croda) 9.21 parts by mass was mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition D1.
［実施例４－２］水性懸濁状農薬組成物Ｄ２の調製
　グリセロールのかわりにプロピレングリコールを用いた以外は、実施例４－１と同様の方法で、水性懸濁状農薬組成物Ｄ２を１００質量部得た。 [Example 4-2] Preparation of aqueous suspension pesticide composition D2 Aqueous suspension pesticide composition D2 was prepared in the same manner as in Example 4-1, except that propylene glycol was used instead of glycerol. A mass part was obtained.
［実施例４－３］水性懸濁状農薬組成物Ｄ３の調製
　水及びブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）の使用量を、それぞれ６２.２１質量部及び０.５０質量部とした以外は、実施例３－１と同様の方法で、水性懸濁状農薬組成物Ｄ３を１００質量部得た。 [Example 4-3] Preparation of Aqueous Suspended Pesticide Composition D3 The amounts of water and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) used were 62.21 parts by mass and 0.50, respectively. 100 parts by mass of the aqueous suspended agricultural chemical composition D3 was obtained in the same manner as in Example 3-1, except that the amount was changed to parts by mass.
［実施例４－４］水性懸濁状農薬組成物Ｄ４の調製
　水及びブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）の使用量を、それぞれ６１.７１質量部及び１.００質量部とした以外は、実施例３－１と同様の方法で、水性懸濁状農薬組成物Ｄ４を１００質量部得た。 [Example 4-4] Preparation of aqueous suspension pesticide composition D4 The amounts of water and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) used were 61.71 parts by mass and 1.00, respectively. 100 parts by weight of an aqueous suspended agricultural chemical composition D4 was obtained in the same manner as in Example 3-1, except that the amount was changed to parts by weight.
［実施例４－５］水性懸濁状農薬組成物Ｄ５の調製
　水、アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）及びブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）の使用量を、それぞれ６０.８１質量部、１.００質量部及び２.００質量部とした以外は、実施例４－１と同様の方法で、水性懸濁状農薬組成物Ｄ５を１００質量部得た。 [Example 4-5] Preparation of aqueous suspension pesticide composition D5 Water, acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) and butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 100 parts by mass of the aqueous suspended pesticide composition D5 in the same manner as in Example 4-1, except that the amount used was 60.81 parts by mass, 1.00 part by mass and 2.00 parts by mass, respectively. I got a part.
［実施例４－６］水性懸濁状農薬組成物Ｄ６の調製
１．粉砕スラリーの調製
　水６３.４３質量部に、アクリルコポリマー溶液（商品名：Atlox 4913、Croda社製）１.５０質量部、ブチルブロックコポリマー（商品名：Atlas G-5002L、Croda社製）１.５０質量部、グリセロール９.２１質量部、及び化合物Ａ（純度９６.３％）１５.００質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＪを９０.６４質量部得た。 [Example 4-6] Preparation of aqueous suspension pesticide composition D6 Preparation of pulverized slurry In 63.43 parts by mass of water, acrylic copolymer solution (trade name: Atlox 4913, manufactured by Croda) 1.50 parts by mass, butyl block copolymer (trade name: Atlas G-5002L, manufactured by Croda) 1. 50 parts by weight, 9.21 parts by weight of glycerol, and 15.00 parts by weight of Compound A (purity 96.3%) were dispersed, and a sand grinder (manufactured by IMEX Co., Ltd.) using 0.8-1.2 mmφ glass beads. ) To obtain 90.64 parts by mass of pulverized slurry J.
２．水性懸濁状農薬組成物の調製
　粉砕スラリーＪ９０.６４質量部、キサンタンガム（商品名：KELZAN、CP Kelco社製）０.１５質量部及びアルコキシル化ポリオールエステル（商品名：Atplus UEP-100、Croda社製）９.２１質量部を混合し、均一な水性懸濁状農薬組成物Ｄ６を１００質量部得た。 2. Preparation of Aqueous Suspended Pesticide Composition 90.64 parts by weight of pulverized slurry J, 0.15 parts by weight of xanthan gum (trade name: KELZAN, CP Kelco) and alkoxylated polyol ester (trade name: Atplus UEP-100, Croda) (Product made) 9.21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspended agricultural chemical composition D6.
［実施例４－７］水性懸濁状農薬組成物Ｄ７の調製
　ポリアルキレンオキシドブロックコポリマー（商品名：Atlas G-5000、Croda社製）のかわりにポリオキシエチレンポリオキシプロピレンブロックコポリマー（商品名：SYNPERONIC PE/F 127、Croda社製、HLB: 22）を用いた以外は、実施例３－５と同様の方法で、水性懸濁状農薬組成物Ｄ７を１００質量部得た。 [Example 4-7] Preparation of aqueous suspension agricultural chemical composition D7 Instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda), polyoxyethylene polyoxypropylene block copolymer (trade name: 100 parts by mass of the aqueous suspended agricultural chemical composition D7 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / F 127, manufactured by Croda, HLB: 22) was used.
［実施例４－８］水性懸濁状農薬組成物Ｄ８の調製
　ポリアルキレンオキシドブロックコポリマー（商品名：Atlas G-5000、Croda社製）のかわりにポリオキシエチレンポリオキシプロピレンブロックコポリマー（商品名：SYNPERONIC PE/L 31、Croda社製、HLB: 22）を用いた以外は、実施例３－５と同様の方法で、水性懸濁状農薬組成物Ｄ８を１００質量部得た。 [Example 4-8] Preparation of aqueous suspension agricultural chemical composition D8 Instead of polyalkylene oxide block copolymer (trade name: Atlas G-5000, manufactured by Croda), polyoxyethylene polyoxypropylene block copolymer (trade name: 100 parts by weight of an aqueous suspended agricultural chemical composition D8 was obtained in the same manner as in Example 3-5, except that SYNPERONIC PE / L 31, Croda, HLB: 22) was used.
［実施例４－９］水性懸濁状農薬組成物Ｄ９の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製、HLB: 13.2）のかわりにポリオキシアルキレントリデシルエーテル（商品名：ノイゲンTDX-50、第一製薬工業(株)製、HLB: 9）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｄ９を１００質量部得た。 [Example 4-9] Preparation of aqueous suspension pesticide composition D9 Polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 13.2) instead of polyoxy Aqueous suspension pesticide composition in the same manner as in Example 3-9, except that alkylene tridecyl ether (trade name: Neugen TDX-50, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 9) was used. 100 parts by mass of D9 was obtained.
［実施例４－１０］水性懸濁状農薬組成物Ｄ１０の調製
　ポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-149、第一製薬工業(株)製、HLB: 11.2）のかわりにポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-109、第一製薬工業(株)製、HLB: 8.4）を用いた以外は、実施例３－１６と同様の方法で、水性懸濁状農薬組成物Ｄ１０を１００質量部得た。 [Example 4-10] Preparation of aqueous suspension pesticide composition D10 Polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, manufactured by Daiichi Pharmaceutical Industries, Ltd., HLB: 11.2) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-16 except that alkylene oleyl cetyl ether (trade name: Neugen ET-109, manufactured by Daiichi Pharmaceutical Industries, Ltd., HLB: 8.4) was used. 100 parts by mass of D10 was obtained.
［実施例４－１１］水性懸濁状農薬組成物Ｄ１１の調製
　ポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-149、第一製薬工業(株)製、HLB: 11.2）のかわりにポリオキシアルキレンオレイルセチルエーテル（商品名：ノイゲンET-129、第一製薬工業(株)製、HLB: 10.2）を用いた以外は、実施例３－１６と同様の方法で、水性懸濁状農薬組成物Ｄ１１を１００質量部得た。 [Example 4-11] Preparation of aqueous suspension pesticide composition D11 Polyoxyalkylene oleyl cetyl ether (trade name: Neugen ET-149, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 11.2) An aqueous suspended agricultural chemical composition in the same manner as in Example 3-16 except that alkylene oleyl cetyl ether (trade name: Neugen ET-129, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 10.2) was used. 100 parts by mass of D11 was obtained.
［実施例４－１２］水性懸濁状農薬組成物Ｄ１２の調製
　ポリオキシエチレンイソデシルエーテル（商品名：ノイゲンSD-70、第一製薬工業(株)製）のかわりにトリシロキサンエトキシレート（商品名：Silwet L-77、Momentive Performance Materials Inc.製）を用いた以外は、実施例３－９と同様の方法で、水性懸濁状農薬組成物Ｄ１２を１００質量部得た。 [Example 4-12] Preparation of aqueous suspension pesticide composition D12 Trisiloxane ethoxylate (product) instead of polyoxyethylene isodecyl ether (trade name: Neugen SD-70, manufactured by Daiichi Pharmaceutical Co., Ltd.) 100 parts by mass of the aqueous suspended agricultural chemical composition D12 was obtained in the same manner as in Example 3-9 except that Silwet L-77 (manufactured by Momentive Performance Materials Inc.) was used.
［比較例１－１］水性懸濁状農薬組成物Ｅ１の調製
１．粉砕スラリーの調製
　水５６.５８質量部に、プロピレングリコール９.２１質量部及び化合物Ａ（純度９６.３％）１５.００質量部を分散させ、０.８－１.２ｍｍφガラスビーズを用いてサンドグラインダー（アイメックス(株)製）で湿式粉砕し、粉砕スラリーＫ８０.７９質量部を得た。 [Comparative Example 1-1] Preparation of Aqueous Suspended Pesticide Composition E1 Preparation of pulverized slurry Disperse 9.21 parts by mass of propylene glycol and 15.00 parts by mass of Compound A (purity 96.3%) in 56.58 parts by mass of water, and use 0.8-1.2 mmφ glass beads. Wet pulverization was performed with a sand grinder (manufactured by IMEX Co., Ltd.) to obtain 80.79 parts by mass of pulverized slurry K.
２．１.５質量％ケルザンプリゲルの調製
　水９８.５０質量部に、キサンタンガム（商品名：KELZAN、CP Kelco社製）１.５０質量部を分散させ、１.５質量％ケルザンプリゲル１００質量部を得た。 2. Preparation of 1.5% by mass Kelzan Prigel 1.50 parts by mass of xanthan gum (trade name: KELZAN, CP Kelco) is dispersed in 98.50 parts by mass of water to obtain 100 parts by mass of 1.5% by mass Kelzan Prigel. It was.
３．水性懸濁状農薬組成物の調製
　粉砕スラリーＫ８０.７９質量部、前記１.５質量％ケルザンプリゲル１０質量部及びポリオキシアルキレントリデシルエーテル（商品名：ノイゲンTDX-50、第一製薬工業(株)製、HLB: 9）９.２１質量部を混合し、均一な水性懸濁状農薬組成物Ｅ１を１００質量部得た。 3. Preparation of Aqueous Suspended Agricultural Composition 80.79 parts by weight of pulverized slurry K, 10 parts by weight of 1.5% by weight Kelzan Prigel and polyoxyalkylene tridecyl ether (trade name: Neugen TDX-50, Daiichi Pharmaceutical Co., Ltd.) Manufactured, HLB: 9) 9.21 parts by mass were mixed to obtain 100 parts by mass of a uniform aqueous suspension agricultural chemical composition E1.
［比較例１－２］水性懸濁状農薬組成物Ｅ２の調製
　プロピレングリコールのかわりにグリセロールを用いた以外は、比較例１－１と同様の方法で、水性懸濁状農薬組成物Ｅ２を１００質量部得た。 [Comparative Example 1-2] Preparation of Aqueous Suspended Pesticide Composition E2 Aqueous suspended agrochemical composition E2 was prepared in the same manner as in Comparative Example 1-1 except that glycerol was used instead of propylene glycol. A mass part was obtained.
［比較例１－３］水性懸濁状農薬組成物Ｅ３の調製
　ポリオキシアルキレントリデシルエーテル（商品名：ノイゲンTDX-50、第一製薬工業(株)製、HLB: 9）のかわりにトリシロキサンエトキシレート（商品名：Silwet L-77、Momentive Performance Materials Inc.製）を用いた以外は、比較例１－１と同様の方法で、水性懸濁状農薬組成物Ｅ３を１００質量部得た。 Comparative Example 1-3 Preparation of Aqueous Suspended Pesticide Composition E3 Trisiloxane instead of polyoxyalkylene tridecyl ether (trade name: Neugen TDX-50, manufactured by Daiichi Pharmaceutical Co., Ltd., HLB: 9) 100 parts by weight of an aqueous suspended agricultural chemical composition E3 was obtained in the same manner as in Comparative Example 1-1 except that ethoxylate (trade name: Silwet L-77, manufactured by Momentive Performance Materials Inc.) was used.
［５］保存安定性の評価
［実施例５－１～５－２７、実施例６－１～６－１２、比較例２－１～２－３］
　水性懸濁状農薬組成物Ｃ１～Ｃ２７、Ｄ１～Ｄ１２及びＥ１～Ｅ３をそれぞれ３０ｍＬ容バイアル瓶に入れ、５４℃の恒温槽で２週間保存した。製造直後及び保存後のメジアン径（Ｄ50）を、(株)堀場製作所製粒度分布測定装置LA-960Sを用いてレーザ回折散乱法で測定した。結果を表２～４に示す。なお、粒子成長率は、下記式によって算出した。
　　粒子成長率（％）＝[(保存後のＤ50－製造直後のＤ50)／製造直後のＤ50]×１００ [5] Evaluation of storage stability [Examples 5-1 to 5-27, Examples 6-1 to 6-12, Comparative examples 2-1 to 2-3]
Aqueous suspended pesticidal compositions C1 to C27, D1 to D12, and E1 to E3 were placed in 30 mL vials and stored in a constant temperature bath at 54 ° C. for 2 weeks. The median diameter (D 50 ) immediately after production and after storage was measured by a laser diffraction scattering method using a particle size distribution analyzer LA-960S manufactured by Horiba, Ltd. The results are shown in Tables 2-4. The particle growth rate was calculated by the following formula.
Grain growth rate (%) = [- / immediately after preparation D 50 (after storage D 50 D 50 immediately after manufacture)] × 100
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000009
Figure JPOXMLDOC01-appb-T000010
Figure JPOXMLDOC01-appb-T000010
　表２～４に示した結果より、本発明の水性懸濁状農薬組成物は、保存中の農薬活性成分の粒子成長が抑制され、保存安定性が良好であることがわかった。 From the results shown in Tables 2 to 4, it was found that the aqueous suspension pesticide composition of the present invention has good storage stability because the particle growth of the pesticidal active ingredient during storage is suppressed.

Claims (9)

  1. 　（ａ）(Ｚ)－Ｎ－[２－(３－クロロ－５－[シクロプロピルエチニル]ピリジン－２－イル)－２－(イソプロポキシイミノ)エチル]－３－(ジフルオロメチル)－１－メチル－１Ｈ－ピラゾール－４－カルボキサミドを含む農薬活性成分、
    （ｂ）アジュバント、及び
    （ｃ）分散剤
    を含む水性懸濁状農薬組成物。     (A) (Z) -N- [2- (3-Chloro-5- [cyclopropylethynyl] pyridin-2-yl) -2- (isopropoxyimino) ethyl] -3- (difluoromethyl) -1- Agrochemical active ingredients including methyl-1H-pyrazole-4-carboxamide,
    An aqueous suspension pesticide composition comprising (b) an adjuvant and (c) a dispersant.
  2. 　（ｂ）アジュバントが、下記式（１Ａ）、（１Ｂ）又は（１Ｃ）で表されるエステル化ポリオールアルコキシレート、並びに下記式（２）で表されるポリオキシアルキレンアルキルエーテルから選ばれる少なくとも１種である請求項１記載の水性懸濁状農薬組成物。
    Figure JPOXMLDOC01-appb-C000001
     （式中、ＰOAは、トリメチロールプロパンの残基であり；
    　ＰOBは、グリセロールの残基であり；
    　ＰOCは、ソルビタンの残基であり；
    　Ｒ1は、それぞれ独立に、水素原子、又は－Ｃ(＝Ｏ)－Ｒ1'（式中、Ｒ1'は、炭素数１～２８の１価炭化水素基である。）であるが、少なくとも１つは－Ｃ(＝Ｏ)－Ｒ1'であり；
    　Ｒ2は、炭素数１０～１４のアルキル基であり；
    　Ａ1は、炭素数２～４のアルカンジイル基であり；
    　Ａ2は、炭素数２～４のアルカンジイル基であり；
    　ｍは、それぞれ独立に、１～１００の整数であり；
    　ｎは、１～１００の整数である。）     (B) The adjuvant is at least one selected from an esterified polyol alkoxylate represented by the following formula (1A), (1B) or (1C) and a polyoxyalkylene alkyl ether represented by the following formula (2) The aqueous suspended agricultural chemical composition according to claim 1.
    Figure JPOXMLDOC01-appb-C000001
     Where P OA is the residue of trimethylolpropane;
    P OB is a residue of glycerol;
    P OC is a sorbitan residue;
    Each R 1 is independently a hydrogen atom or —C (═O) —R 1 ′ (wherein R 1 ′ is a monovalent hydrocarbon group having 1 to 28 carbon atoms). At least one is —C (═O) —R 1 ′;
    R 2 is an alkyl group having 10 to 14 carbon atoms;
    A 1 is an alkanediyl group having 2 to 4 carbon atoms;
    A 2 is an alkanediyl group having 2 to 4 carbon atoms;
    m is each independently an integer of 1 to 100;
    n is an integer of 1 to 100. )
  3. 　（ｂ）アジュバントが、式（１Ａ）、（１Ｂ）又は（１Ｃ）で表されるエステル化ポリオールアルコキシレート、ポリオキシエチレンイソデシルエーテル、ポリオキシエチレントリデシルエーテル、ポリオキシエチレン(C12-14)第２級アルコールエーテル及びポリオキシアルキレン分岐デシルエーテルから選ばれる少なくとも１種である請求項２記載の水性懸濁状農薬組成物。 (B) The adjuvant is an esterified polyol alkoxylate represented by the formula (1A), (1B) or (1C), polyoxyethylene isodecyl ether, polyoxyethylene tridecyl ether, polyoxyethylene (C12-14) The aqueous suspended agricultural chemical composition according to claim 2, which is at least one selected from secondary alcohol ethers and polyoxyalkylene branched decyl ethers.
  4. 　（ｂ）アジュバントが、少なくとも式（１Ａ）で表されるエステル化ポリオールアルコキシレートを含む請求項３記載の水性懸濁状農薬組成物。 (B) The aqueous suspended agricultural chemical composition according to claim 3, wherein the adjuvant contains at least an esterified polyol alkoxylate represented by the formula (1A).
  5. 　（ｃ）分散剤が、アルキレンオキシド鎖を側鎖に有する(メタ)アクリル酸グラフトコポリマー、アルコール開始ＥＯ／ＰＯブロックコポリマー、ポリオキシエチレンポリオキシプロピレンブロックコポリマー、及びポリオキシエチレンスチリルフェニルエーテルから選ばれる少なくとも１種である請求項１～４のいずれか１項記載の水性懸濁状農薬組成物。 (C) The dispersant is selected from a (meth) acrylic acid graft copolymer having an alkylene oxide chain in the side chain, an alcohol-initiated EO / PO block copolymer, a polyoxyethylene polyoxypropylene block copolymer, and a polyoxyethylene styryl phenyl ether The aqueous suspended agricultural chemical composition according to any one of claims 1 to 4, wherein the composition is at least one.
  6. 　（ｃ）分散剤が、少なくともアルコール開始ＥＯ／ＰＯブロックコポリマーを含む請求項５記載の水性懸濁状農薬組成物。 (C) The aqueous suspended agricultural chemical composition according to claim 5, wherein the dispersant contains at least an alcohol-initiated EO / PO block copolymer.
  7. 　（ａ）成分の含有量の、前記アルコール開始ＥＯ／ＰＯブロックコポリマーの含有量に対する比が、１５以下である請求項６記載の水性懸濁状農薬組成物。 The ratio of the content of the component (a) to the content of the alcohol-initiated EO / PO block copolymer is 15 or less, and the aqueous suspended agricultural chemical composition according to claim 6.
  8. 　更に、凍結防止剤を含む請求項１～７のいずれか１項記載の水性懸濁状農薬組成物。 The aqueous suspended agricultural chemical composition according to any one of claims 1 to 7, further comprising an antifreezing agent.
  9. 　前記凍結防止剤が、プロピレングリコールである請求項８記載の水性懸濁状農薬組成物。 The aqueous suspended agricultural chemical composition according to claim 8, wherein the antifreezing agent is propylene glycol.
PCT/JP2019/018203 2018-05-08 2019-05-07 Aqueous suspended agrochemical composition WO2019216296A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2020518291A JPWO2019216296A1 (en) 2018-05-08 2019-05-07 Aqueous suspension pesticide composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2018089909 2018-05-08
JP2018-089909 2018-05-08

Publications (1)

Publication Number Publication Date
WO2019216296A1 true WO2019216296A1 (en) 2019-11-14

Family

ID=68467392

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2019/018203 WO2019216296A1 (en) 2018-05-08 2019-05-07 Aqueous suspended agrochemical composition

Country Status (2)

Country Link
JP (1) JPWO2019216296A1 (en)
WO (1) WO2019216296A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024038801A1 (en) * 2022-08-18 2024-02-22 日産化学株式会社 Aqueous suspension-type agrochemical composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007246496A (en) * 2006-03-20 2007-09-27 Mitsui Chemicals Inc Paste-like agrochemical formulation
JP2011518806A (en) * 2008-04-24 2011-06-30 ビーエーエスエフ ソシエタス・ヨーロピア Cyclodextrin-containing suspension concentrate, process for its production and use thereof
JP2012107038A (en) * 2003-08-06 2012-06-07 Syngenta Ltd Agrochemical concentrate comprising adjuvant and hydrotrope
JP2016501197A (en) * 2012-11-20 2016-01-18 クローダ インターナショナル パブリック リミティド カンパニー Penetration agents for pesticide formulations
JP2016011286A (en) * 2014-01-15 2016-01-21 日産化学工業株式会社 Oxime-substituted amide compound and pest control agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012107038A (en) * 2003-08-06 2012-06-07 Syngenta Ltd Agrochemical concentrate comprising adjuvant and hydrotrope
JP2007246496A (en) * 2006-03-20 2007-09-27 Mitsui Chemicals Inc Paste-like agrochemical formulation
JP2011518806A (en) * 2008-04-24 2011-06-30 ビーエーエスエフ ソシエタス・ヨーロピア Cyclodextrin-containing suspension concentrate, process for its production and use thereof
JP2016501197A (en) * 2012-11-20 2016-01-18 クローダ インターナショナル パブリック リミティド カンパニー Penetration agents for pesticide formulations
JP2016011286A (en) * 2014-01-15 2016-01-21 日産化学工業株式会社 Oxime-substituted amide compound and pest control agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024038801A1 (en) * 2022-08-18 2024-02-22 日産化学株式会社 Aqueous suspension-type agrochemical composition

Also Published As

Publication number Publication date
JPWO2019216296A1 (en) 2021-05-13

Similar Documents

Publication Publication Date Title
JP6566217B2 (en) Suspension composition containing a crystalline polymorph of an isoxazoline-substituted benzamide compound
US9907308B2 (en) Aqueous suspension agrochemical composition
TW201427597A (en) Synergistic fungicidal mixtures for fungal control in cereals
WO2003053145A1 (en) Bactericidal composition
KR101819258B1 (en) Water-based pesticidal suspension
US9062010B2 (en) Crystalline polymorphs of isoxazoline compound and production method thereof
KR102314077B1 (en) Liquid pesticide composition
JP6677159B2 (en) Solid pesticide composition
JP2012051871A (en) Aqueous suspended agrochemical composition
WO2019216296A1 (en) Aqueous suspended agrochemical composition
TW202208341A (en) Mixtures and compositions comprising 5-fluoro-4-imino-3- methyl-1-tosyl-3,4-dihydropyrimidin-2-one, and methods of use thereof
JP6057088B2 (en) Agrochemical granular composition
JP4986023B2 (en) Plant disease control composition
JP2022136336A (en) Method for controlling sigatoka disease
WO2012043476A1 (en) Sigatoka control agent, sigatoka control method, and use of the sigatoka control agent
JP4434638B2 (en) Plant disease control composition and plant disease control method
JP2022158274A (en) Solvate
JP4484023B2 (en) Agrochemical composition with good storage stability
WO2019243112A1 (en) Amino acid based surfactants as formulants for biocides
KR20230019678A (en) Composition for disease controlling of horticultural crops
JP2018058810A (en) Hydrazone compound and pest control agent
US20220396734A1 (en) Soil wetter composition
US20200275650A1 (en) Novel polymer coated chlorothalonil particles

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 19799872

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 2020518291

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 19799872

Country of ref document: EP

Kind code of ref document: A1