WO2019215380A1 - Flotation cell - Google Patents

Flotation cell Download PDF

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Publication number
WO2019215380A1
WO2019215380A1 PCT/FI2018/050355 FI2018050355W WO2019215380A1 WO 2019215380 A1 WO2019215380 A1 WO 2019215380A1 FI 2018050355 W FI2018050355 W FI 2018050355W WO 2019215380 A1 WO2019215380 A1 WO 2019215380A1
Authority
WO
WIPO (PCT)
Prior art keywords
flotation
slurry
tank
flotation cell
infeed
Prior art date
Application number
PCT/FI2018/050355
Other languages
English (en)
French (fr)
Inventor
Peter Bourke
Steve Schmidt
Antti Rinne
Jere Tuominen
Valtteri VAARNA
Aleksi Peltola
Original Assignee
Outotec (Finland) Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Outotec (Finland) Oy filed Critical Outotec (Finland) Oy
Priority to BR112020023010A priority Critical patent/BR112020023010A8/pt
Priority to MX2020012021A priority patent/MX2020012021A/es
Priority to RU2020139774U priority patent/RU203651U1/ru
Priority to AU2018403988A priority patent/AU2018403988A1/en
Priority to PE2020001832A priority patent/PE20210382A1/es
Priority to PCT/FI2018/050355 priority patent/WO2019215380A1/en
Priority to CN201890001623.2U priority patent/CN215997104U/zh
Publication of WO2019215380A1 publication Critical patent/WO2019215380A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/24Pneumatic
    • B03D1/247Mixing gas and slurry in a device separate from the flotation tank, i.e. reactor-separator type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/1443Feed or discharge mechanisms for flotation tanks
    • B03D1/1456Feed mechanisms for the slurry
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/1443Feed or discharge mechanisms for flotation tanks
    • B03D1/1462Discharge mechanisms for the froth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/1493Flotation machines with means for establishing a specified flow pattern
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02Ores
    • B03D2203/04Non-sulfide ores
    • B03D2203/08Coal ores, fly ash or soot

Definitions

  • the current disclosure relates to a flotation cell for separating valuable material containing particles from particles suspended in slurry and to a flotation line and its use.
  • the flotation cell according to the current disclosure is characterized by what is presented in claim 1.
  • the flotation line according to the current disclosure is characterized by what is presented in claim 19.
  • a flotation cell for treating particles suspended in slurry and for separating the slurry into an underflow and an overflow.
  • the flotation cell comprises a flotation tank comprising a centre, a perimeter, and a sidewall with a vertical wall part and a conical bottom part comprising a vertex; a launder and a launder lip surrounding the perimeter of the tank; and a downcomer through which slurry infeed is arranged to be introduced into the flotation tank; wherein the height, measured as the distance between the vertex and the launder lip, to diameter, measured as the diameter of the flotation tank at the perimeter of the straight wall segment, ratio is 0,9 or lower.
  • the flotation cell is characterized in that the downcomer comprises an inlet nozzle for feeding slurry infeed into the downcomer; an inlet for pressurized air, the slurry infeed subjected to the pressurized air as it is discharged from the inlet nozzle; an elongated chamber arranged to receive under pressure the slurry infeed; and an outlet nozzle configured to restrict the flow of slurry infeed from the outlet nozzle, and to maintain slurry infeed in the elongated chamber under pressure.
  • a flotation line comprises a flotation stage, and it is characterized in that a first flotation stage comprises a flotation cell according to the invention.
  • use of the flotation line according to the invention is intended for treating coal particles suspended in slurry .
  • the particles may, for example, comprise mineral ore particles such as particles comprising a metal, or coal particles.
  • upgrading the concentrate is directed to an intermediate particle size range between 40 ym to 150 ym. Fine particles are thus particles with a diameter of 0 to 40 ym, and ultrafine particles can be identified as falling in the lower end of the fine particle size range. Coarse particles have a diameter greater than 150 ym. In froth flotation of coal, upgrading the concentrate is directed to an intermediate particle size range between 40 ym to 300 ym. Fine particles in coal treatment are particles with a diameter of 0 to 40 ym, and ultrafine particles those that fall into the lower end of the fine particle size range. Coarse coal particles have a diameter greater than 300 ym.
  • flotation gas is introduced into a flotation cell or tank via a mechanical agitator.
  • the thus generated flotation gas bubbles have a relatively large size range, typically from 0,8 to 2,0 mm, or even larger, and are not particularly suitable for collecting particles having a finer particle size.
  • column cells are typically restricted to use in cleaner flotation lines or circuits, where the amount of solid material in the slurry is considerably lower than in a typical rougher flotation line or circuit.
  • feed rate of a column flotation cell, as well as the solid material amount in the slurry to be treated must be lower than in a mechanical flotation cell to prevent settling of particles into the bottom of the flotation cell.
  • flotation gas bubble- ore particle agglomerates for the most part takes place in the pulp within a flotation tank or other liquid holding vessel. Sufficient time must be provided to allow the agglomerates to rise to the froth layer and to be transported in the froth layer to the overflow launder to be collected as overflow or concentrate in an overflow launder.
  • so-called pneumatic flotation cells are used, where flotation gas is introduced in a high-shear device such as a downcomer with slurry infeed, thereby creating finer flotation gas bubbles that are able entrap also finer particles already during the bubble formation in the downcomer.
  • a high-shear device such as a downcomer with slurry infeed
  • such high-throughput flotation cell requires a vacuum to be created in the downcomer to effectively achieve the required bubble formation rate to entrap the desired particles in the short time slurry infeed resides in the downcomer.
  • the flotation gas bubble- particle agglomerates rise immediately towards the froth layer on the top part of the flotation cell, and no further entrapment of particles take place in the part of the flotation cell downwards from the downcomer outlet. This may lead to significant part of particles comprising a desired material (mineral or coal) to simply drop to the bottom of the flotation tank and ending up in tailings, which reduces the recovery rate of the flotation cell.
  • a desired material mineral or coal
  • the so-called high- throughput flotation cells or pneumatic flotation cells of the Jameson cell type do not include any flow restriction for controlling the pressure within the downcomer after the formation of flotation air bubble- particle agglomerates has taken place.
  • Such control of pressure is advantageous also in view of the pressure at which flotation gas bubbles are formed (effect on bubble size) , but also for the adjustment of relative pressure at which they are to be used in the flotation tank. In that way, the coalescence of bubbles may be minimized after their formation. This is especially advantageous, as the rate of entrapment of particles by flotation gas bubbles decreases as the bubble size increases (provided that the air to liquid ratio remains the same) .
  • the so-called high-throughput flotation cells may be used in coal liberation operations, where there typically is a flotation line comprising one or two such flotation cells at the end of the liberation circuit for the recovery of especially fine coal particles.
  • a process water recirculation system circulating water from the end part of the circuit (i.e. from the flotation line and a dewatering circuit) back to the front circuit (beginning of the liberation circuit) .
  • Flotation chemicals, especially frothers typically cause problems in the processes preceding the flotation line.
  • the problems may be alleviated to some extent by minimizing the use of frothers in the flotation line, but if not enough frother is added into the flotation process, the froth formation in downcomers according to state of the art may suffer, which leads to unstable process conditions and especially unstable downcomer operation and froth layer in a flotation cell, which in turn affects the recovery of desired particles negatively, particularly coarse particles.
  • the amount of frother required to optimize the flotation process may be significantly reduced without significantly compromising bubble formation, bubble to particle engagement, stable froth layer formation or the recovery of desired material.
  • problems associated with recirculating process water from downstream circuit to front circuit can be alleviated.
  • a downcomer operating under pressure is completely independent of the flotation tank. A better flotation gas flowrate may be reached, and finer bubbles created, and frother usage optimized, as the downcomer operation is not dependent of frother dosage.
  • problems relate especially to limitations to the amount of flotation gas that can be supplied relative to the amount of liquid flowing through the downcomer, and to the need for relatively high concentrations of frothers or other expensive surface-active agents to produce small bubbles.
  • flotation of fine and ultrafine particles comprising for example mineral ore or coal may be improved by reducing the size of the flotation gas bubbles introduced to slurry infeed in a downcomer, by increasing the flotation gas supply rate relative to the flow rate of particles suspended in the slurry, and by increasing the shear intensity or energy dissipation rate either in or adjacent to the downcomer.
  • the probability of finer particles attaching to or being entrapped by smaller flotation gas bubbles is increased, and the recovery rate of desired material such as a mineral or coal, improved.
  • sufficiently small flotation gas bubbles so-called ultra-fine bubbles, may be created to ensure efficient entrapment of fine ore particles.
  • ultra-fine bubbles may have a bubble size distribution of 0,1 mm to 0,8 mm.
  • recovery of coarser particles may be kept at an acceptable level by achieving a high flotation gas fraction in the slurry, by the absence of high turbulence areas in the region below the forth layer. Further, the upwards motion of slurry or pulp within the flotation tank increases the probability of also coarser particles rise towards the froth layer with the flow of slurry.
  • Flotation involves phenomena related to the relative buoyancy of objects.
  • Flotation is a process for separating hydrophobic materials from hydrophilic materials by adding flotation gas, for example air, to the process.
  • Flotation could be made based on natural hydrophobic/hydrophilic difference or based on hydrophobic/hydrophilic differences made by addition of a surfactant or collector chemical.
  • Gas can be added to the feedstock subject of flotation (slurry or pulp) by a number of different ways. Further, frothers or frothing chemicals are typically used to promote the formation of a froth layer from which the desired material is collected.
  • flotation aims at recovering a concentrate of ore particles comprising a valuable material such as a mineral, or coal.
  • concentrate herein is meant the part of slurry recovered in overflow led out of a flotation cell.
  • valuable mineral is meant any mineral, metal or other material of commercial value .
  • Flotation involves phenomena related to the relative buoyancy of objects.
  • the term flotation includes all flotation techniques.
  • Flotation can be for example froth flotation, dissolved air flotation (DAF) or induced gas flotation.
  • DAF dissolved air flotation
  • Froth flotation is a process for separating hydrophobic materials from hydrophilic materials by adding gas, for example air, to process.
  • Froth flotation could be made based on natural hydrophilic/hydrophobic difference or based on hydrophilic/hydrophobic differences made by addition of a surfactant or collector chemical.
  • a flotation line herein is meant an assembly or arrangement comprising a number of flotation units or flotation cells in which a flotation stage is performed, and which are arranged in fluid connection with each other for allowing either gravity-driven or pumped slurry flow between flotation cells, to form a flotation line.
  • a flotation line a number of flotation cells are arranged in fluid connection with each other so that the underflow of each preceding flotation cell is directed to the following or subsequent flotation cell as a infeed until the last flotation cell of the flotation line, from which the underflow is directed out of the line as tailings or reject flow.
  • a flotation line may comprise only one flotation stage performed either in one flotation cell or for example in two or more parallel flotation cells.
  • Flotation line may be a part of a larger treatment plant containing one or more flotation lines, and a number of other process stages for the liberation, cleaning and other treatment of a desired material. Therefore, a number of different pre treatment and post-treatment devices or arrangements may be in operational connection with the components of the flotation line, as is known to the person skilled in the art.
  • a flotation cell is herein meant a tank or vessel in which a step or stage of a flotation process is performed.
  • a flotation cell is typically cylindrical in shape, the shape defined by a sidewall or an outer wall/ walls.
  • the flotation cells regularly have a circular cross-section.
  • the flotation cells may have a polygonal, such as rectangular, square, triangular, hexagonal or pentagonal, or otherwise radially symmetrical cross-section, as well.
  • overflow herein is meant the part of the slurry collected into the launder of the flotation cell and thus leaving the flotation cell as concentrate. Overflow may comprise froth, froth and slurry, or in certain cases, only or for the largest part slurry.
  • underflow herein is meant the fraction or part of the slurry which is not floated into the surface of the slurry in the flotation process.
  • Underflow is a reject flow or tailings leaving a flotation cell via an outlet which typically is arranged in the lower part of the flotation cell.
  • concentrate herein is meant the floated part or fraction of slurry of ore particles comprising a valuable material such as a mineral or coal.
  • ultra-fine bubbles herein is meant flotation gas bubbles falling into a size range of 0,1 mm to 0,8 mm, introduced into the slurry in a downcomer.
  • "normal" flotation gas bubbles utilized in froth flotation display a size range of approximately 0,8 to 2 mm. Larger flotation gas bubbles may have a tendency to coalesce into even larger bubbles during their residence in the mixing zone where collisions between particles and flotation gas bubbles, as well as only between flotation gas bubbles take place. As ultra-fine bubbles are introduced into slurry infeed prior to its feeding into a flotation tank, such coalescence is not likely to happen with ultra-fine bubbles, and their size may remain smaller throughout their residence in the flotation cell, thereby affecting the ability of the ultra-fine bubbles to catch fine particles.
  • the height to diameter ratio is 0,3 to 0,9.
  • the outlet nozzle comprises a throttle for restricting the flow of slurry infeed.
  • the outlet nozzle is configured to induce a supersonic shockwave into the slurry infeed as it exits the elongated chamber.
  • a supersonic shockwave is created when the velocity of slurry infeed passing through the outlet nozzle exceeds the speed of sound, i.e. the flow of slurry infeed becomes choked when the ratio of the absolute pressure upstream the outlet nozzle to the absolute pressure downstream of the throttle of the outlet nozzle exceeds a critical value) .
  • the pressure ratio is above the critical value, flow of slurry infeed downstream of the throttle part of the outlet nozzle becomes supersonic and a shock wave is formed) .
  • Small flotation gas bubbles in slurry infeed mixture are split into even smaller by being forced through the shock wave, and forced into contact with hydrophobic ore particles in slurry infeed, thus creating flotation gas bubble-ore particle agglomerates .
  • the downcomer further comprises an impinger configured to contact a flow of slurry infeed from the outlet nozzle and to direct the flow of slurry infeed radially outwards and upwards of the impinger.
  • the impinger comprises an impingement surface made of wear-resistant material.
  • the impinger deflects the flow of slurry infeed radially outwards to the flotation tank sidewall and upwards towards the flotation tank upper surface (i.e. to the froth layer) .
  • Slurry is highly agitated by the energy of the deflected flow, and forms vortexes in which the size of the bubbles may be further reduced by the shear forces acting upon them.
  • the high-shear conditions favourably also induce high number of contacts between flotation gas bubbles and particles in the slurry within the flotation tank.
  • the flotation cell further comprises a conditioning circuit.
  • the conditioning circuit comprises a pump tank in fluid communication with the flotation tank, in which pump tank infeed of fresh slurry and a slurry fraction taken from the flotation tank via an outlet are arranged to be combined into slurry infeed.
  • the conditioning circuit further comprises a pump arranged to intake the slurry fraction from the flotation tank and to forward slurry infeed from the pump tank.
  • the conditioning circuit further comprises a distribution unit arranged to distribute infeed.
  • the flotation cell comprises 2-24 downcomers, preferably 10-24 downcomers.
  • the downcomers are arranged concentric to the perimeter of the flotation tank, at a distance from the centre of the flotation tank.
  • the downcomers are arranged parallel to the sidewall of the flotation tank, at a distance from the sidewall .
  • the exact number of downcomers within a flotation cell may depend on the flotation tank size or volume, on the type of material to be collected and other process parameters. By arranging a sufficient number of downcomers into a flotation cell, even distribution of ultra-fine bubbles may be ensured, as well as even mixing effect caused by the shear forces within tank secured.
  • the conical bottom part of the sidewall of the flotation tank has a slant angle of 10-45°, measured in relation to a horizontal of the flotation cell.
  • the slant angle is 30-40°.
  • the slant angle is 15-25°.
  • This kind of construction may be especially beneficial for recovering coal particles suspended in slurry .
  • the height of the vertical wall part of the flotation tank is 1,8 m or lower .
  • the volume of the flotation tank is at least 10 m 3 .
  • the flotation process may be better controlled.
  • the ascent distance to the froth layer on the top part of the flotation tank does not become too large, which may help to ensure that the flotation gas bubble-ore particle agglomerates remain together until the froth layer and particle drop-back may be reduced. Further, a suitable bubble rise velocity may be reached to maintain a good concentrate quality.
  • the flotation line comprises 1-2 flotation stages wherein the first flotation stage comprises a flotation cell according to the invention described herein.
  • the flotation line comprises two flotation stages, of which at least the first flotation stage comprises a flotation cell according to the invention described herein.
  • a flotation stage comprises at least two parallel flotation cells according to the invention described herein .
  • frother chemicals are added into a flotation stage in an amount of 12 ppm or less.
  • Fig. 1 is a 3D projection of a flotation cell according to an embodiment of the invention
  • Fig. 2 depicts a flotation cell according to an embodiment of the invention, as seen from above,
  • Fig. 3 is a vertical cross-section of the flotation cell of Fig. 2 along a section A-A, and
  • Fig. 4a-c are schematic drawings of flotation lines according to some embodiments of the invention.
  • FIG. 1-3 illustrate a flotation cell 1 in some detail.
  • the figures are not drawn to proportion, and many of the components of the flotation cell 1 are omitted for clarity.
  • Figures 4a-c illustrate in a schematic manner embodiments of the flotation line. The direction of flows of slurry is shown in the figures by arrows.
  • the flotation cell 1 is intended for treating mineral ore particles suspended in slurry and for separating the slurry into an underflow 400 and an overflow 500, the overflow 500 comprising a concentrate of a desired mineral .
  • the flotation cell 1 comprises a flotation tank 10 that has a centre 11 and a perimeter 12.
  • a sidewall 13 of the flotation tank 10 comprises a vertical wall part 13a and a conical bottom part 13b.
  • the conical bottom part 13b has a vertex 130 facing downwards in relation to the height of the flotation cell 1.
  • the flotation cell 1 further comprises a launder 2 (not shown in figures 1 and 2, and in figure 3, for the sake of simplicity, only a central launder 2 is shown. It is to be understood that a launder 2 may comprise, alternatively or additionally, a perimeter launder arranged to surround the entire perimeter 12 of the flotation tank 10, as is known in the technical field) .
  • the overflow 500 is collected into the launder 2 as it passes over a launder lip 21, from a froth layer formed in the upper part of the flotation tank 10.
  • the flotation cell has a height h to diameter d ratio h/d of 0,9 or lower.
  • the height h is measured as the distance between the vertex 130 of the conical bottom part 13b of the sidewall 13, and the launder lip 21.
  • the diameter d is measured as the diameter of the flotation tank 10 at the perimeter 12 of the straight wall part 13a, as can be seen in figure 3, excluding any structures arranged outside the sidewall 13, i.e. collecting launders 2 arranged outside the sidewall 13, such as a perimeter launder.
  • the height h to diameter d ratio h/d of the flotation tank may be 0,3 to 0,9.
  • the h/d ratio may be, for example 0,45; or 0,5; or 0,7.
  • the conical bottom part 13b of the sidewall 13 of the flotation tank 10 has a slant angle of 10° to 45°.
  • the slant angle may be 30 to 40°. This kind of arrangement may be especially beneficial if the flotation cell 1 is used in treating slurry comprising mineral ore particle.
  • the slant angle may be 15 to 25°. This may be especially beneficial when the flotation cell 1 is used in the recovery of coal, i.e. in flotation of coal particles suspended in slurry.
  • the height of the vertical wall part 13a may have a height of 1,8 m or lower.
  • the flotation tank 10 may have a volume of at least 10 m 3 , or at least 20 m 3 .
  • the flotation tank may have a volume ranging from 10 m 3 to 100 m 3 .
  • the flotation cell 1 comprises at least one downcomer 4, through which slurry infeed 100 is arranged to be introduced into the flotation tank 11.
  • the exact number of downcomers 4 may be chosen according to the specific operation, for example the type of slurry being treated within the flotation cell 1, the volumetric feed flowrate to the flotation cell 1, the mass throughput feed to the flotation cell 1, or the volume of the flotation tank 10.
  • the downcomers 4 may be arranged concentric to the perimeter 12 of the flotation tank 10. This is the case when the flotation tank 10 is circular in cross-section.
  • the downcomers 4 may be further arranged so that each downcomer 4 is located at a distance from the centre 11 of the flotation tank 10, the distance being preferably equal for each downcomer 4.
  • the downcomers 4 may be arranged parallel to the sidewall 13 of the flotation tank 10. This is the case when the flotation tank 10 has a rectangular or square horizontal cross-section.
  • the downcomers 4 may be further arranged so that each downcomer 4 is located at a distance from the sidewall 13, the distance being preferably equal for each downcomer 4.
  • the downcomers 4 may be arranged at a straight line within the flotation tank 10.
  • the downcomer 4 comprises an inlet nozzle 41, intended for feeding slurry infeed 100 into the downcomer 41, more specifically to an elongated chamber
  • An inlet 42 for pressurized flotation gas such as pressurized air, is arranged in such a way that slurry infeed 100 becomes subjected to the pressurized flotation gas as it is discharged from the inlet nozzle
  • the slurry infeed 100 forms a liquid jet which, as it enters the elongated chamber 40, is mixed with pressurized flotation gas fed through the inlet 42.
  • Flotation gas is entrained through a turbulent mixing action brought about by the jet, and is dispersed into small bubbles in the slurry infeed 100 as it travels downwards through the elongated chamber 40 to an outlet nozzle 43 configured to restrict the flow of slurry infeed 100 from the outlet nozzle 43, and further configured to maintain slurry infeed 100 under pressure in the elongated chamber 40.
  • the outlet nozzle 43 comprises a throttle such as a throat-like restricting structure. From the outlet nozzle 43, more specifically from the throttle, slurry infeed 100 issues under pressure into the flotation tank 10.
  • the outlet nozzle 43 As the slurry infeed 100 passes through the outlet nozzle 43, more specifically through the throttle of the outlet nozzle 43, flotation gas bubbles are reduced in size by the pressure changes, and by the high-shear environment downstream of the outlet nozzle 43.
  • the velocity of the gas-liquid mixture in the throttle of the outlet nozzle 43 may exceed the speed of sound when the flow becomes a choked flow and flow downstream of the throttle becomes supersonic, and a shockwave forms in the diverging section of the outlet nozzle 43.
  • the outlet nozzle 43 is configured to induce a supersonic shockwave into slurry infeed 100.
  • the flow of slurry infeed 100 becomes choked when the ratio of the absolute pressure upstream the outlet nozzle to the absolute pressure downstream of the throttle of the outlet nozzle 43 exceeds a critical value.
  • a critical value When the pressure ratio is above the critical value, flow of slurry infeed 100 downstream of the throttle part of the outlet nozzle 43 becomes supersonic and a shockwave is formed. Small flotation gas bubbles in slurry infeed 100 mixture are split into even smaller by being forced through the shockwave, and forced into contact with hydrophobic ore particles in slurry infeed 100, thus creating flotation gas bubble-ore particle agglomerates .
  • the downcomer 4 may further comprise an impinger 44, configured to contact a flow of slurry infeed 100 from the outlet nozzle 43. Slurry infeed 100 exiting from the outlet nozzle 43 is therefore directed to contact the impinger 44.
  • the impinger 44 is configured to direct the flow of slurry infeed 100 radially outwards and upwards of the impinger 44.
  • the impinger 44 deflects the flow of slurry infeed 100 radially outwards to the flotation tank sidewall 13 and upwards towards the upper surface (froth layer) of the flotation tank 10.
  • Slurry is highly agitated by the energy of the deflected flow, and forms vortexes in which the size of the bubbles may be further reduced by the shear forces acting upon them.
  • the high- shear conditions favourably also induce high number of contacts between flotation gas bubbles and particles in the slurry within the flotation tank 10. As the flow of slurry is forced upwards towards the froth layer, turbulence reduces and the flow becomes relatively uniform.
  • the impinger 44 may comprise an impingement surface intended for contacting the flow of slurry infeed 100 exiting the outlet nozzle 43.
  • the impingement surface may be made of wear-resistant material to reduce the need for replacements or maintenance.
  • the slurry which in essence is a two-phase gas-liquid mixture, rising out of the impinger 44 enters the upper part of the flotation tank 10, and the flotation gas bubbles rise upwards and separate from the liquid to form a froth layer.
  • the froth rises upwards and discharges over the lip 21 into the launder 2 and out of the flotation cell 1 as overflow 500.
  • the tailings or underflow 400 from which the desired material has substantially been removed, pass out from the flotation tank 10 through an outlet arranged at the bottom part 13b, for example at the vertex 130.
  • Some of the coarse hydrophobic particles that are carried into the froth may subsequently disengage from flotation gas bubbles and drop back into the flotation tank 10, as a result of bubble coalescence in the froth. However, the majority of such particles fall back into the flotation tank 10 in such a way and position that they may be captured by bubbles newly entering the flotation tank 10 from the downcomer 4 or downcomers 4, and carried once more into the froth layer .
  • the flotation cell 1 may also comprise a conditioning circuit (not shown in the figures in its entirety) .
  • the conditioning circuit may comprise a pump tank 30, or other such additional vessel, in which pump tank 30 infeed of fresh slurry 200 and a slurry fraction 300 taken from the flotation tank 10 via an outlet are arranged to be combined into slurry infeed 100.
  • the conditioning circuit may comprise a pump 31 arranged to intake the slurry fraction 300 from the flotation tank 11, and to forward slurry infeed 100 from the pump tank 30 to the downcomer 4 or downcomers 4.
  • the slurry fraction 300 may comprise low settling velocity particles such as fine, slow-floating particles.
  • the slurry fraction may be taken from or near the bottom of the flotation tank 10, the bottom defined as the part inside the conical bottom part 13b of the sidewall 13 of the flotation tank 10.
  • the pump 31 may also be used to forward the slurry infeed 100 into the downcomer 4 or downcomers 4.
  • a distribution unit may be utilized.
  • a flotation line 8 is presented in figures 4a-c.
  • the flotation line comprises a flotation stage 81, that is, a process step where flotation for the recovery of a concentrate is performed in a flotation cell.
  • the flotation line 8 may comprise one flotation stage 81, or a number of flotation stages 81, 82 in series and in fluid connection so that underflow from a first flotation stage 81 is led as infeed to the following flotation stage 82.
  • figures 4a-c show only two flotation stages, it is to be understood that there may also be more than two, for example three or four, flotation stages in a flotation line 8.
  • the flotation line 8 may be preceded by other processes such as grinding, classification, screening, heavy-medium process, coarse particle recovery process, spirals, and other separation processes; and other flotation processes.
  • a number of processes may follow the flotation line 8, such as regrinding, cleaner or other flotation processes, centrifuging, filtering, screening or dewatering.
  • the flotation line 8 may be preceded by sizing process (typically for finer particles, in a cyclone classification stage) from which the material to be treated by flotation is directed to the flotation line 8.
  • Overflow i.e. the concentrate of desired material, coal, is then collected led to dewatering (for example in a drum filter) .
  • a first flotation stage 81 may performed in a flotation cell 1 according to the invention, as described above (see Fig. 4a) .
  • the flotation line 8 may comprise one to two flotation stages 81, 82, wherein the first flotation stage 81 comprises a flotation cell according to the invention.
  • both flotation stages may be performed in a flotation cell 1 (Fig. 4b) .
  • a flotation stage 81, 82 may be performed in at least two parallel flotation cells 1 (Fig. 4c) .
  • slurry infeed 100 is divided to both of the flotation cells 1, and underflow 400 from the parallel flotation cells may be combined and led to a following flotation stage 82 as infeed.
  • the following flotation stage 82 may also comprise a flotation cell 1.
  • the following flotation stage 82 may also comprise at least two parallel flotation cells 1.
  • the flotation line 8 according to the invention may be used in recovering coal particles, especially fine or ultrafine coal particles suspended in slurry.
  • the amount of frother chemicals may be reduced while still accomplishing a good recovery of coal.
  • frother chemicals may be added into a flotation stage 81 in an amount of 12 ppm or less.
  • the frother chemical or chemicals may be added for example in an amount of approximately 5 ppm; 7,5 ppm; or 10 ppm.
  • the frother chemicals are added into the flotation stage in any suitable manner known to the person skilled in the art.
  • the invention is herein described in terms applicable to the separation of minerals or coal, in which the mineral ore or coal is either finely crushed, or naturally in a fine particle form, to form a slurry or suspension of particles in water, and the slurry is conditioned with collector and frother chemicals to make the desired mineral or coal species that is to be recovered by flotation hydrophobic or non-wetting, while the non-wetting or hydrophilic species that are to remain in the suspension and are discharged from the flotation vessel as tailings.
  • An example of this is the separation of fine coal particles from the surrounding gangue (ash) in a mining operation.
  • a flotation cell to which the disclosure is related may comprise at least one of the embodiments described hereinbefore. It is obvious to a person skilled in the art that with the advancement of technology, the basic idea of the invention may be implemented in various ways. The invention and its embodiments are thus not limited to the examples described above; instead they may vary within the scope of the claims.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Physical Water Treatments (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Paper (AREA)
PCT/FI2018/050355 2018-05-11 2018-05-11 Flotation cell WO2019215380A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BR112020023010A BR112020023010A8 (pt) 2018-05-11 2018-05-11 Célula de flotação
MX2020012021A MX2020012021A (es) 2018-05-11 2018-05-11 Celda de flotacion.
RU2020139774U RU203651U1 (ru) 2018-05-11 2018-05-11 Флотационная камера
AU2018403988A AU2018403988A1 (en) 2018-05-11 2018-05-11 Flotation cell
PE2020001832A PE20210382A1 (es) 2018-05-11 2018-05-11 Celda de flotacion
PCT/FI2018/050355 WO2019215380A1 (en) 2018-05-11 2018-05-11 Flotation cell
CN201890001623.2U CN215997104U (zh) 2018-05-11 2018-05-11 浮选池和浮选生产线

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/FI2018/050355 WO2019215380A1 (en) 2018-05-11 2018-05-11 Flotation cell

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AU (1) AU2018403988A1 (ru)
BR (1) BR112020023010A8 (ru)
MX (1) MX2020012021A (ru)
PE (1) PE20210382A1 (ru)
RU (1) RU203651U1 (ru)
WO (1) WO2019215380A1 (ru)

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WO2021120370A1 (zh) * 2019-12-16 2021-06-24 李宾 纳米泡浮选柱

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WO2000015343A1 (en) * 1998-09-11 2000-03-23 Graeme John Jameson Internal recycle apparatus and process for flotation column cells
WO2006081611A1 (en) * 2005-02-01 2006-08-10 The University Of Newcastle Research Associates Limited Method and apparatus for contacting bubbles and particles in a flotation separation system
CN2905226Y (zh) * 2005-11-29 2007-05-30 胡满营 矿化器和含有矿化器的水压式自吸空气浮选柱
WO2009026612A1 (en) * 2007-08-28 2009-03-05 Xstrata Technology Pty Ltd Method for improving flotation cell performance
US20100263752A1 (en) * 2009-04-17 2010-10-21 Xstrata Technology Pty. Ltd. Pumpbox
CN108273668A (zh) * 2018-03-28 2018-07-13 中国矿业大学 一种基于强湍流混合矿化的快速浮选系统及浮选方法

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WO2000015343A1 (en) * 1998-09-11 2000-03-23 Graeme John Jameson Internal recycle apparatus and process for flotation column cells
WO2006081611A1 (en) * 2005-02-01 2006-08-10 The University Of Newcastle Research Associates Limited Method and apparatus for contacting bubbles and particles in a flotation separation system
CN2905226Y (zh) * 2005-11-29 2007-05-30 胡满营 矿化器和含有矿化器的水压式自吸空气浮选柱
WO2009026612A1 (en) * 2007-08-28 2009-03-05 Xstrata Technology Pty Ltd Method for improving flotation cell performance
US20100263752A1 (en) * 2009-04-17 2010-10-21 Xstrata Technology Pty. Ltd. Pumpbox
CN108273668A (zh) * 2018-03-28 2018-07-13 中国矿业大学 一种基于强湍流混合矿化的快速浮选系统及浮选方法

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Publication number Priority date Publication date Assignee Title
WO2021120370A1 (zh) * 2019-12-16 2021-06-24 李宾 纳米泡浮选柱

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AU2018403988A1 (en) 2019-11-28
AU2018403988A2 (en) 2021-07-22
MX2020012021A (es) 2021-03-29
BR112020023010A2 (pt) 2021-02-02
BR112020023010A8 (pt) 2023-03-21
RU203651U1 (ru) 2021-04-14
CN215997104U (zh) 2022-03-11

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