WO2019194779A2 - Shampoing pour bébés - Google Patents

Shampoing pour bébés Download PDF

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Publication number
WO2019194779A2
WO2019194779A2 PCT/TR2018/050891 TR2018050891W WO2019194779A2 WO 2019194779 A2 WO2019194779 A2 WO 2019194779A2 TR 2018050891 W TR2018050891 W TR 2018050891W WO 2019194779 A2 WO2019194779 A2 WO 2019194779A2
Authority
WO
WIPO (PCT)
Prior art keywords
sodium
composition
composition according
agent
shampoo
Prior art date
Application number
PCT/TR2018/050891
Other languages
English (en)
Other versions
WO2019194779A3 (fr
Inventor
Ahmet Toksöz
Zafer Toksöz
Original Assignee
Montero Gida Sanayi Ve Ticaret Anonim Sirketi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from TR2017/22210A external-priority patent/TR201722210A2/tr
Priority claimed from TR2017/22098A external-priority patent/TR201722098A2/tr
Application filed by Montero Gida Sanayi Ve Ticaret Anonim Sirketi filed Critical Montero Gida Sanayi Ve Ticaret Anonim Sirketi
Publication of WO2019194779A2 publication Critical patent/WO2019194779A2/fr
Publication of WO2019194779A3 publication Critical patent/WO2019194779A3/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to sensitive cleansing compositions that can provide intensive care.
  • the present invention also relates to the use of mentioned compositions in a shampoo, particularly in a shampoo that can be used in babies.
  • compositions in this document contain various amounts of sodium lauryl ether sulfate, coconut oil, sodium acetate, cocamidopropyl betaine, sodium lauryl sarcosinate, PEG- 803, vitamin E, D-panthenol, rose extract, olive oil and water.
  • Sodium lauryl ether sulfate in the surfactant combination of this document is highly irritant, and the moisturizing agents within the composition are not suitable for use especially in newborns.
  • the present invention provides intense moisture especially in newborn skin with the plant-based active ingredients, moisturizing and care agents it contains while also cleansing the skin and preserving the sensitivity of the composition since the surfactants contained within are amphoteric and/or nonionic.
  • the present invention relates to a composition that contains Chamomilla recutita flower juice, Malva sylvest s extract, panthenol, hydrolyzed wheat proteins ve sodium levulinate. More preferably, the present invention provides a composition that contains the following components in the following amounts by weight based on the total weight of the composition;
  • the composition also contains at least one additional agent selected from a moisturizing agent, skin care agent, preservative, emollient, chelating agent, surfactants, pH regulating agent, perfuming agent, rheology agents and solvents.
  • at least one additional agent selected from a moisturizing agent, skin care agent, preservative, emollient, chelating agent, surfactants, pH regulating agent, perfuming agent, rheology agents and solvents.
  • the mentioned composition may also contain a moisturizing agent.
  • Moisturizing agemts increase the moisture on the skin and scalp and preserve the moisture for a long time.
  • These moisturizing agents can be selected from the group that comprises glucose, sorbitol, urea, glycerin, propylene glycol, hexylene glycol, butylene glycol, maltose and sodium glucuronate, wherein they provide intensive moisture and care when used in combination with an additional skin care agent.
  • Skin care agents play a role in boosting the moisture on the skin and keeping it moist for a long time.
  • the skin care agent herein can be selected from the group that contains sodium PCA and glycine.
  • composition described within the scope of the present invention may contain one or more surfactants.
  • surfactants can be selected from amphoteric and/or nonionic surfactants.
  • surfactants are preferably selected from the group that comprises cocamidopropyl betaine, sodium cocoamphoacetate, lauryl glucoside and coco-glucoside, wherein they boost the cleansing effect of the composition when used with the active composition of the invention and they are suitable for use in the sensitive skin of newborns since they are amphoteric and/or nonionic.
  • composition of the invention may also contain an emollient.
  • the emollient can be selected from the group that comprises cetearyl isononanoate, cetearyl octanoate, decyl oleate, glyceryl oleate, glyceryl stearate, isooctyl stearate, isopropyl myristate, dicaprylyl ether, myristyl lactate and dimethicone copolyol.
  • the mentioned composition may also contain a preservative, wherein the preservative can be sodium benzoate and/or potassium sorbate.
  • composition of the invention may be presented in shampoo, cream, gel or lotion form.
  • the composition is more preferably presented as a shampoo and even more preferably as a baby or children's shampoo.
  • shampoos of the invention are suitable for use in babies and children between the ages 0-10.
  • the present invention also relates to a method that includes the following steps for producing a composition that contains Chamomilla recutita flower juice, Malva sylvestris extract, panthenol, hydrolyzed wheat proteins ve sodium levulinate: adding Chamomilla recutita flower juice and Malva sylvestris extract as active ingredients into water and mixing while heating,
  • panthenol and sodium levulinate as care agents into the mentioned mixture, mixing until the mixture is homogenous and obtaining the final product.
  • the mentioned heating process can be continued until reaching 45°C.
  • the present invention relates to the use of a composition that contains Chamomilla recutita flower juice, Malva sylvestris extract, panthenol and sodium levulinate in a shampoo composition.
  • Shampoos are prepared with combinations of various surfactants and these surfactants provide cleansing following the steps of wetting the surface, removing dirt from the surface and keeping the dirt in a stable solution or a suspension.
  • shampoo compositions may also contain additional components besides surfactants in order to bring the physical and chemical properties of the composition to the desired level. These additional components can be for example, thickening agents, stabilizers, preservatives, various perfumes and aroma, care agents, thinners and opacifiers.
  • additional components can be for example, thickening agents, stabilizers, preservatives, various perfumes and aroma, care agents, thinners and opacifiers.
  • it is aimed to provide baby and children's shampoos that contain sensitive cleansing compositions.
  • compositions described in the present invention essentially contain an active ingredient and care agent group.
  • the active ingredient group encompasses a group that is responsible for hair and scalp care, wherein these ingredients also provide antimicrobial effect, show synergistic action with the care agent group and keep the scalp and skin of especially newborns moist and provide intensive care.
  • the active ingredient group that is a component of the main embodiment of the present invention is responsible for providing hair, scalp and skin care.
  • One of the cosmetically active substances in this group is Chamomilla recutita (Matricaria) flower juice.
  • Chamomilla recutita has soothing effects on the skin in addition to antibacterial, antiviral and antifungal effects.
  • This natural ingredient which is also used as an anti-inflammatory agent, exhibits moisturizing effect in the compositions of the present invention that are deemed suitable for use in newborns, who are more sensitive and whose epidermal barrier is not completely developed.
  • the amount of Chamomilla recutita flower juice in the composition described in the present invention is between 5-35%, preferably 10-25% by weight in the total composition.
  • Malva sylvestris extract Malva sylvestris plant has been used since the past in herbal treatments due to its sedative effects. Similar to Chamomilla recutita flower juice, it is used for its moisturizing, nurturing and antimicrobial effects.
  • the amount of Malva sylvestris extract is between 0,1-5%, preferably 0,1-1% by weight in the total composition.
  • Some additional care agents, especially those effective in hair care can be added to the active composition used in the main embodiment of the invention. For instance, sodium glutamate is suitable for adding to this group.
  • panthenol Panthenol has been used since the past in various pharmaceutical and cosmetic compositions due to its wound healing and moisturizing effects.
  • the amount of panthenol in the present invention is between 0,1-5%, preferably 0,1-1% by weight in the total composition.
  • Another care agent is sodium levulinate. This agent acts as a preservative and skin care agent while it also provides more intensive care and keeps the skin and scalp soft and moist when combined with panthenol.
  • the amount of sodium levulinate is between 0,1-5%, preferably 0,1-1% by weight in the total composition.
  • the care group can also contain hydrolyzed wheat proteins, as the last ingredient. Hydrolyzed wheat proteins are effective in the scalp as well as hair.
  • the amount of hydrolyzed wheat proteins that are included in the present invention is higher than 0 and lower than or equal to 1%, preferably higher than 0 and lower than or equal to 0,1% by weight in the total composition.
  • the present invention may contain certain moisturizing agents besides the described care group in order to especially increase the scalp care effect and provide care for a longer time.
  • Moisturizing agents increase the amount of moisture on the scalp and skin.
  • These moisturizers can be selected from the group that comprises glucose, sorbitol, urea, glycerin, propylene glycol, hexylene glycol, butylene glycol, maltose and sodium glucuronate.
  • One or more agents can be selected from this group, whereas the combination of glycerin, glucose, sorbitol and urea further boosts the moisturizing effect
  • the amount of moisturizing agent(s] is between 0,1-10%, preferably 0,1-5% by weight in the total composition.
  • the present invention may contain various skin care agents in order to obtain softness and moisture in newborn skin for a long time. These agents provide scalp and skin care, wherein they are more effective especially with moisturizing agents. Examples of these agents that enable keeping the skin and scalp moist, as provided by moisturizing agents, for a long time can be sodium PCA and glycine.
  • compositions of the present invention are more effective with the surfactants added thereto.
  • surfactants are added into a liquid, they reduce the surface tension of liquids and hence improve the surface wetting capacity of these liquids.
  • Surfactants contained within cleansing compositions play a role in retaining and removing dirt.
  • Surfactants are studied under four groups, i.e. anionic, cationic, amphoteric and nonionic. Anionic surfactants in this group cause severe irritation in the skin and eyes although they lead to intense foam formation. Therefore, surfactants that can be added to the composition of the present invention can be selected from amphoteric and nonionic surfactants. These surfactants can be used alone or in combination.
  • Amphoteric surfactants can be selected from the group that comprises cocamidopropyl betaine, cocodimethylsulfopropyl betaine and lauryl-betaine, wherein cocamidopropyl betaine within this group is preferably used in the present invention alone or in combination with other amphoteric and/or nonionic surfactants as it facilitates foaming of the cleansing composition and especially renders the foam more bulky and creamy with finer particles.
  • the amount of amphoteric surfactant is between 5-30%, preferably 10-25% by weight in the total composition.
  • Nonionic surfactants can be selected from the group that contains sodium cocoamphoacetate, lauryl glucoside, octaethylene glycol monododecyl ether, glyceryl laurate, cocamide DEA and coco-glucoside or a combination thereof.
  • Nonionic surfactant increases the cleansing capacity and stability of the generated foam when used in combination with amphoteric surfactants. Especially the combination of coco-glucoside and cocamidopropyl is effective in generating a softer and smoother foam.
  • the amount of nonionic surfactant(s] is between 1-10%, preferably 1-5% by weight in the total composition.
  • composition described in some embodiments of the invention may contain emollients in order to prevent possible harsh effects on the sensitive skin of a baby.
  • this group helps increase the viscosity of compositions described within the scope of the present invention. While only one emollient can be used, the use of emollients in combination facilitates further enhancing the softness.
  • These emollients can be selected from cetearyl isononanoate, cetearyl octanoate, decyl oleate, glyceryl oleate, isooctyl stearate, isopropyl myristate, dicaprylyl ether, myristyl lactate and dimethicone copolyol. When myristyl lactate and glyceryl oleate are used in combination, they exhibit viscosity-enhancing effects in the compositions that especially contain surfactants.
  • the invention may contain one or more preservatives in order to prevent microbial contamination that can be encountered during storage of the composition and/or to ensure physical stability.
  • This preservative is particularly important from the aspect of ensuring the absence of pathogenic organisms that can lead to eye irritation in newborns. This is because, it is possible to see harmful organism formation in the compositions of the present invention that contain plant extracts.
  • the preservative can be selected from the group that comprises potassium sorbate and sodium benzoate. Preservatives can be used alone or in combination.
  • chelating agents can be used to boost the activity of the preservative. Today, the most widely used such agent is EDTA.
  • Tetrasodium glutamate diacetate can be used here, considering that EDTA has recently caused some environmental concerns. Tetrasodium glutamate diacetate can prevent the formation and accumulation of calcium and magnesium soaps as well as other substances that can lead to undesired changes in the product, especially when water hardness is high. Besides, this component, which is biocompatible, is suitable for use in the sensitive and mild composition of the invention. The amount thereof can be maximum 0,5% by weight in the total composition. pH value of the compositions of the invention are of significant importance since they are intended for use especially in babies. Controlled pH values are preferred rather than very high or very low pH values.
  • pH value of the compositions of the invention is between 5-6, and preferably 5,5. Since pH value of the hair and scalp is between 4-6, pH values of the invention are consistent with this value. Keeping the pH at a slightly acidic value is significantly important as it prevents bacteria and fungi development in the hair and scalp.
  • the present invention recommends using a pH-regulating agent in order to keep the acidity at the desired value. This agent can be selected from lactic acid or citric acid group or be a combination thereof. In the formulation of the present invention, lactic acid also has a moisturizing effect.
  • the composition may contain some perfuming components in addition to active agents. These components may be various essences, perfumes or natural plant extracts. However, the amount of perfuming agents in the composition should not be very high in case they are synthetic. High amounts of synthetic perfuming agents, i.e. various perfumes, may irritate the baby's skin. Therefore, the amount of synthetic perfuming agent should preferably be less than 1% by weight in the total composition.
  • compositions described within the scope of the present invention are suitable for topical application and can be in shampoo, cream, gel, lotion or liquid form.
  • the preferred form is the shampoo form.
  • Compositions of the present invention can provide cleansing as well as intensive care. In any case, these compositions are suitable for use in shampoo, hair conditioner, moisturizer and care compositions as well as shower gels or creams. From the aspect of the objects of this invention, shampoo is the preferred form, baby and children's shampoo is a more preferred form and newborn shampoo is the most preferred form.
  • Viscosity value of the compositions described within the scope of the invention should be kept under control in a manner similar to pH. In a preferred embodiment, the viscosity value is 4000-8000 mPas at 20°C.
  • the present invention relates to a method that includes the following steps for producing a composition that contains Chamomilla recutita flower juice, Malva sylvestris extract, panthenol and sodium levulinate. adding Chamomilla recutita flower juice and Malva sylvestris extract as active ingredients into water and mixing while heating,
  • panthenol and sodium levulinate as care agents into the mentioned mixture, mixing until the mixture is homogenous and obtaining the end product
  • the expression "until the mixture is homogenous” means that the particles and fluids in the composition are processed until a homogenous mixture is obtained.
  • the heating process is continued until 45°C, preferably until 40 °C, and more preferably until 35 °C maximum.
  • the mixing process is preferably performed in a turbo-emulsifier.
  • Chamomilla recutita flower juice Malva sylvestris extract, lauryl glucoside, tetrasodium glutamate diacetate, glycerin, sodium chloride, glucose, sorbitol, moisturizing mixture (sodium glutamate, urea, sodium PCA, glycine, lactic acid, hydrolyzed wheat protein, panthenol], sodium levulinate, potassium sorbate, coco-glucoside, glyceryl oleate, sodium cocoamphoacetate, scent essence, myristyl lactate, cocamidopropyl betaine, sodium benzoate and citric acid were respectively added into the water inside a turbo emulsifier, heated until 35“and mixed until the mixture is completely homogenous.
  • composition of the invention was prepared so as to contain the components, whose w/w percentages are provided in Table 2 below.
  • Cocamidopropyl betaine 10,9500 Lauryl Glucoside 2,1200 Sodium Chloride 1,8250 Myristyl Lactate 1,8000 Sodium Chloride 1,8250 Sodium Cocoamphoacetate 0,8000 Sodium Levulinate 0,5400 Coco-Glucoside 0,5250 Panthenol 0,5050 Glycerin 0,4975 Glyceryl Oleate 0,4800 Perfume 0,3000
  • the composition According to the ordinary use of the composition, it was applied as a leave on or 10% standard concentration rinse-off composition.
  • Liquid composition was applied to the skin at 20 m ⁇ dose.
  • Solid and semi solid compositions were applied at a dose of 20 pg.
  • Finn chamber plastic that contains 7 mm aluminum disc and absorbent paper discs] is a patch test device that provides good occlusion.
  • For liquid compositions, Finn chamber contains blotting papers that were immersed in a certain amount (20 m ⁇ ] of the sample that will be tested.
  • the compositions (20 pg] that will be tested are directly applied to the skin.
  • the relevant area on the skin was cleaned using 70% alcoholic solution.
  • the composition was applied at an amount of 0,02 g or ml/cm 2 skin.
  • the relevant area of the skin was covered by the Finn chamber.
  • Composition was maintained in contact with the skin for 24 hours.
  • Finn chamber was removed. Skin reactions were analyzed at minute 15, hour 1 and 24 after removing the Finn chamber.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne des compositions sensibles qui peuvent procurer un soin intense et posséder des propriétés nettoyantes et antimicrobiennes. La présente invention concerne également l'utilisation desdites compositions dans un shampoing, en particulier dans un shampoing qui peut être utilisé pour les bébés.
PCT/TR2018/050891 2017-12-27 2018-12-25 Shampoing pour bébés WO2019194779A2 (fr)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
TR2017/22098 2017-12-27
TR2017/22210 2017-12-27
TR2017/22210A TR201722210A2 (tr) 2017-12-27 2017-12-27 Temi̇zli̇k ve bakim sağlayan hassas bi̇leşi̇mler
TR2017/22098A TR201722098A2 (tr) 2017-12-27 2017-12-27 Saç uzamasini sti̇müle etmek i̇çi̇n topi̇kal kompozi̇syon
TR2018/06197 2018-05-02
TR2018/06197A TR201806197A2 (tr) 2017-12-27 2018-05-02 Bebek şampuani

Publications (2)

Publication Number Publication Date
WO2019194779A2 true WO2019194779A2 (fr) 2019-10-10
WO2019194779A3 WO2019194779A3 (fr) 2019-12-26

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Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/TR2018/050893 WO2019194780A2 (fr) 2017-12-27 2018-12-25 Compositions de soin et de nettoyage pour peau et cheveux sensibles
PCT/TR2018/050891 WO2019194779A2 (fr) 2017-12-27 2018-12-25 Shampoing pour bébés

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/TR2018/050893 WO2019194780A2 (fr) 2017-12-27 2018-12-25 Compositions de soin et de nettoyage pour peau et cheveux sensibles

Country Status (2)

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TR (2) TR201806198A2 (fr)
WO (2) WO2019194780A2 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110787091A (zh) * 2019-12-03 2020-02-14 株洲千金药业股份有限公司 一种止痒抗敏婴儿洗护制剂及其应用
CN112426375A (zh) * 2020-12-15 2021-03-02 金发拉比妇婴童用品股份有限公司 一种麦芽糖洗发水
CN112426370A (zh) * 2020-11-27 2021-03-02 天津郁美净集团有限公司 具有协同增稠和赋脂功效的洗类组合物及制备方法和应用
CN112569166A (zh) * 2020-12-15 2021-03-30 金发拉比妇婴童用品股份有限公司 一种温和的洗发水
CN115569101A (zh) * 2022-10-26 2023-01-06 广东珍宝健康日用品科技有限公司 一种多功能洗发乳

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AU2022262205A1 (en) * 2021-04-23 2023-11-09 Thomas Meneghini Disinfectant and use thereof
CN115778878A (zh) * 2022-12-22 2023-03-14 广州世航生物科技有限公司 护发组合物及其制备方法与应用

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Publication number Priority date Publication date Assignee Title
US6043202A (en) * 1998-03-06 2000-03-28 Eriksen; Karla S. Shampoo compositions and oil compositions and methods for treatment of cradle cap
US6403654B1 (en) * 2000-04-13 2002-06-11 Mariana De Oliveira Compositions for and method of treatment for psoriasis
EP2020221B1 (fr) * 2007-06-19 2012-02-29 Neubourg Skin Care GmbH & Co. KG DMS (Derma Membrane Structure) dans des crèmes moussantes
CN105997548A (zh) * 2016-08-02 2016-10-12 苏州药基美研医药科技有限公司 一种温和的基于氨基酸衍生物表面活性剂的洁面泡沫
CN107157855A (zh) * 2017-07-04 2017-09-15 北京军秀咨询有限公司 一种天然洗发水

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110787091A (zh) * 2019-12-03 2020-02-14 株洲千金药业股份有限公司 一种止痒抗敏婴儿洗护制剂及其应用
CN110787091B (zh) * 2019-12-03 2022-06-07 株洲千金药业股份有限公司 一种止痒抗敏婴儿洗护制剂及其应用
CN112426370A (zh) * 2020-11-27 2021-03-02 天津郁美净集团有限公司 具有协同增稠和赋脂功效的洗类组合物及制备方法和应用
CN112426375A (zh) * 2020-12-15 2021-03-02 金发拉比妇婴童用品股份有限公司 一种麦芽糖洗发水
CN112569166A (zh) * 2020-12-15 2021-03-30 金发拉比妇婴童用品股份有限公司 一种温和的洗发水
CN112426375B (zh) * 2020-12-15 2023-02-17 金发拉比妇婴童用品股份有限公司 一种麦芽糖洗发水
CN112569166B (zh) * 2020-12-15 2023-12-15 金发拉比妇婴童用品股份有限公司 一种温和的洗发水
CN115569101A (zh) * 2022-10-26 2023-01-06 广东珍宝健康日用品科技有限公司 一种多功能洗发乳
CN115569101B (zh) * 2022-10-26 2023-08-11 广东珍宝健康日用品科技有限公司 一种多功能洗发乳

Also Published As

Publication number Publication date
WO2019194779A3 (fr) 2019-12-26
WO2019194780A3 (fr) 2020-01-02
WO2019194780A2 (fr) 2019-10-10
TR201806197A2 (tr) 2019-07-22
TR201806198A2 (tr) 2019-07-22

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