WO2019193325A1 - Cleaning wipe - Google Patents

Cleaning wipe Download PDF

Info

Publication number
WO2019193325A1
WO2019193325A1 PCT/GB2019/050947 GB2019050947W WO2019193325A1 WO 2019193325 A1 WO2019193325 A1 WO 2019193325A1 GB 2019050947 W GB2019050947 W GB 2019050947W WO 2019193325 A1 WO2019193325 A1 WO 2019193325A1
Authority
WO
WIPO (PCT)
Prior art keywords
wet cleaning
cleaning wipe
wipe
liquid
active agent
Prior art date
Application number
PCT/GB2019/050947
Other languages
French (fr)
Inventor
Joanne MANTERFIELD
Original Assignee
Nice-Pack International
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nice-Pack International filed Critical Nice-Pack International
Priority to GB2016422.4A priority Critical patent/GB2587928B/en
Priority to DE112019001811.6T priority patent/DE112019001811T5/en
Publication of WO2019193325A1 publication Critical patent/WO2019193325A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049Cleaning or scouring pads; Wipes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0047Other compounding ingredients characterised by their effect pH regulated compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • C11D3/42Brightening agents ; Blueing agents
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0004General aspects of dyeing
    • D06P1/0012Effecting dyeing to obtain luminescent or phosphorescent dyeings

Definitions

  • the present invention relates to cleaning wipes.
  • wet cleaning wipes are generally moistened with water based liquid including a cleaning agent, typically a surfactant.
  • a cleaning agent typically a surfactant.
  • the surfactant may become exhausted before the wipe loses its moistness, with the result that the user lacks indication of whether the use of the wipe is being as effective as it might be.
  • a colouring agent can be arranged to be dissipated from a wet wipe at a rate that not only can be similar to the rate at which the cleaning agent is dissipated, but also at a rate such as to be invisible on the surface being cleaned.
  • Dyes which are more readily seen to be present are fluorescent dyes and yellow fluorescent dyes in particular. Surprisingly, these are not reliably visible on wet wipes unless the cleaning agent liquid is neutral to mildly alkaline.
  • the object of the present invention is to provide an improved wet cleaning wipe.
  • a wet cleaning wipe comprising:
  • the substrate will be non-woven fabric.
  • the preferred material of the substrate is blendless viscose fibre. However it is anticipated that a blend of up to 25% at the most and normally up to 10% of other fibres can be used.
  • the fluorescent dye could be of other colours but is preferably yellow. We have found Liquitint Yellow FLW from Milliken to be suitable.
  • the alkalinity additive will act as a pH buffer, rendering the liquid to be between 7.0 pH and 10.0 pH and preferably between 9.0 pH and 10.0 pH.
  • the alkalinity additive can be an acid, such as citric acid, where the liquid is otherwise too alkaline. However it can also be an alkali, such as sodium hydroxide or sodium citrate.
  • the active agent will normally be a surfactant. Whilst anionic and cationic surfactants can be used, normally amphoteric or non-ionic surfactants will be used. Preferably, the surfactant will be alkaline stable for example amphopropionates and alkyl polyglycosides.
  • the active agent can also be a biocidal agent. Indeed both types of active agents can be used together.
  • Chelating agents to boost preservation and typically sodium gluconate or tetrasodiu glutamate diacetate
  • Solvents to aid removal of dirt by dissolving it typically alcohols, glycols, and esters, and
  • Typical w/w compositions of the liquid are as follows:
  • Suitable preservatives are:
  • the preservative and/or biocidal agent will be added first to the water, normally de-ionised.
  • the surfactants are then added.
  • the fragrance will be added with the surfactant as a pre-mix.
  • the chelating agents, polymers and finally the colourant are added.
  • the pH of the solution is adjusted with buffers, including, but not restricted to the following Citric Acid or Sodium Citrate or Sodium Hydroxide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)

Abstract

A wet cleaning comprising a blendless or low blend material substrate. The wipe is moistened with a cleaning liquid that has a fluorescent dye, an alkalinity additive and an active agent. The dye provides visual indication for a user in respect of the moistness of the wipe, allowing them to determine whether the wipe is suitable for use. The additive renders the cleaning liquid to be mildly alkaline in order to ensure the visibility of the dye is reliable.

Description

CLEANING WIPE
The present invention relates to cleaning wipes.
Wet cleaning wipes are generally moistened with water based liquid including a cleaning agent, typically a surfactant. The surfactant may become exhausted before the wipe loses its moistness, with the result that the user lacks indication of whether the use of the wipe is being as effective as it might be.
We have determined that a colouring agent can be arranged to be dissipated from a wet wipe at a rate that not only can be similar to the rate at which the cleaning agent is dissipated, but also at a rate such as to be invisible on the surface being cleaned.
Dyes which are more readily seen to be present are fluorescent dyes and yellow fluorescent dyes in particular. Surprisingly, these are not reliably visible on wet wipes unless the cleaning agent liquid is neutral to mildly alkaline.
The object of the present invention is to provide an improved wet cleaning wipe.
According to the invention there is provided a wet cleaning wipe, comprising:
• a blendless or low blend material substrate and
• a cleaning liquid moistening the wipe, the liquid having:
• a fluorescent dye;
• an alkalinity additive in concentration to render the liquid to be from
substantially neutral to mildly alkaline and
• an active agent.
Normally the substrate will be non-woven fabric. The preferred material of the substrate is blendless viscose fibre. However it is anticipated that a blend of up to 25% at the most and normally up to 10% of other fibres can be used. The fluorescent dye could be of other colours but is preferably yellow. We have found Liquitint Yellow FLW from Milliken to be suitable.
Normally the alkalinity additive will act as a pH buffer, rendering the liquid to be between 7.0 pH and 10.0 pH and preferably between 9.0 pH and 10.0 pH. The alkalinity additive can be an acid, such as citric acid, where the liquid is otherwise too alkaline. However it can also be an alkali, such as sodium hydroxide or sodium citrate.
The active agent will normally be a surfactant. Whilst anionic and cationic surfactants can be used, normally amphoteric or non-ionic surfactants will be used. Preferably, the surfactant will be alkaline stable for example amphopropionates and alkyl polyglycosides. The active agent can also be a biocidal agent. Indeed both types of active agents can be used together.
Other ingredients will normally be included in the liquid, as well, typically:
• Chelating agents, to boost preservation and typically sodium gluconate or tetrasodiu glutamate diacetate
• Preservatives
• Solvents to aid removal of dirt by dissolving it, typically alcohols, glycols, and esters, and
• Fragrances.
Typical w/w compositions of the liquid are as follows:
De-ionised water up to 95%
Colourant(s) up to 1%
Chelating agent(s) up to l%
Preservative(s) up to 3%
Antibacterial Active(s) up to 3%
Surfactants up to 5%
Polymer(s) up to 5%
Solvents up to 20%
Fragrance(s) up to 5% Alkalinity additive(s) Quantum satis.
Suitable preservatives are:
Methylisothiazolinone / Benzisothiazolinone
Phenoxyethanol / Isothiazolinone
Methylchloroisothiazolinone,
Methylisothiazolinone,
Bronopol.
Typically, in production the cleaning liquid, the preservative and/or biocidal agent will be added first to the water, normally de-ionised. The surfactants are then added. Typically the fragrance will be added with the surfactant as a pre-mix. The chelating agents, polymers and finally the colourant are added. The pH of the solution is adjusted with buffers, including, but not restricted to the following Citric Acid or Sodium Citrate or Sodium Hydroxide.
The invention is not intended to be restricted to the details of the above described embodiment. For instance, wipes for atypical uses may require additional atypical ingredients.

Claims

CLAIMS:
1. A wet cleaning wipe, comprising:
• a blendless or low blend material substrate, and
• a cleaning liquid moistening wipe, the liquid having:
• a fluorescent dye;
• an alkalinity additive in concentration to render the liquid to be from
substantially neutral to mildly alkaline; and
• an active agent.
2. A wet cleaning wipe as claimed in claim 1 , wherein the substrate is a blendless viscose fibre.
3. A wet cleaning wipe as claimed in claim 1 or claim 2, wherein the substrate is a non-woven fabric.
4. A wet cleaning wipe as claimed in claim 1 , claim 2 or claim 3, wherein the substrate is a blend of up to 10% other fibres.
5. A wet cleaning wipe as claimed in any preceding claim, wherein the substrate is a blend of no more than 25% other fibres.
6. A wet cleaning wipe as claimed in claim 1 , wherein the fluorescent dye is yellow.
7. A wet cleaning wipe as claimed in claim 6, wherein the fluorescent dye could be of any visible colour.
8. A wet cleaning wipe as claimed in claim any preceding claim, wherein the alkalinity additive is added to the cleaning liquid to act as a pH buffer, rendering the pH of the liquid to be between 7.0 and 10.0.
9. A wet cleaning wipe as claimed in claim 8, wherein the pH buffering additive renders the pH of the cleaning liquid to be between 9.0 and 10.0.
10. A wet cleaning wipe as claimed in claim 9, wherein the pH buffering additive is an acid.
11. A wet cleaning wipe as claimed in claim 9, wherein the pH buffering additive is an alkali.
12. A wet cleaning wipe as claimed in claim 1 , wherein the active agent is a surfactant.
13. A wet cleaning wipe as claimed in claim 12, wherein the active agent is an amphoteric or non-ionic surfactant.
14. A wet cleaning wipe as claimed in claim 12, wherein the active agent is an anionic or cationic surfactant.
15. A wet cleaning wipe as claimed in any preceding claim, wherein the active agent is a biocidal agent.
PCT/GB2019/050947 2018-04-06 2019-04-02 Cleaning wipe WO2019193325A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB2016422.4A GB2587928B (en) 2018-04-06 2019-04-02 Cleaning wipe
DE112019001811.6T DE112019001811T5 (en) 2018-04-06 2019-04-02 CLEANING CLOTH

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1805760.4A GB201805760D0 (en) 2018-04-06 2018-04-06 Cleaning wipe
GB1805760.4 2018-04-06

Publications (1)

Publication Number Publication Date
WO2019193325A1 true WO2019193325A1 (en) 2019-10-10

Family

ID=62202817

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2019/050947 WO2019193325A1 (en) 2018-04-06 2019-04-02 Cleaning wipe

Country Status (3)

Country Link
DE (1) DE112019001811T5 (en)
GB (2) GB201805760D0 (en)
WO (1) WO2019193325A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100175209A1 (en) * 2009-01-14 2010-07-15 The Dial Corporation Water-activated, disposable two-sided cleaning article
EP2431452A1 (en) * 2010-09-21 2012-03-21 The Procter & Gamble Company Liquid cleaning composition
WO2013043705A2 (en) * 2011-09-21 2013-03-28 Ecolab Usa Inc. Bio-based glass cleaner

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100175209A1 (en) * 2009-01-14 2010-07-15 The Dial Corporation Water-activated, disposable two-sided cleaning article
EP2431452A1 (en) * 2010-09-21 2012-03-21 The Procter & Gamble Company Liquid cleaning composition
WO2013043705A2 (en) * 2011-09-21 2013-03-28 Ecolab Usa Inc. Bio-based glass cleaner

Also Published As

Publication number Publication date
DE112019001811T5 (en) 2020-12-17
GB202016422D0 (en) 2020-12-02
GB201805760D0 (en) 2018-05-23
GB2587928A (en) 2021-04-14
GB2587928B (en) 2022-06-08

Similar Documents

Publication Publication Date Title
ES2286096T3 (en) CLEANING COMPOSITION FOR HARD SURFACES.
CA2561307A1 (en) Antibacterial cleaning wipe
BR0212164A (en) Thickened toilet cleaner
WO2017010473A1 (en) Detergent composition for hard surfaces
JP5950557B2 (en) Liquid detergent composition
CN107779280A (en) Antibiosis anti-acarien liquid detergent
AU2002246574A1 (en) Detergent compositions
KR20200125543A (en) Liquid detergent composition
CN108441342A (en) A kind of color protection liquid detergent
WO2019193325A1 (en) Cleaning wipe
KR20170082444A (en) Liquid laundry detergent
JP6523435B2 (en) Liquid cleaning agents for textiles
EP3847227B1 (en) A quick and easy cleaning formulation
JP7017950B2 (en) Mold-killing detergent composition for hard surfaces
EP2780439B2 (en) Cleaning composition
JP6249431B1 (en) Cleaning agent for leather products
KR102042507B1 (en) Liquid laundry detergenet composition
CN108085190A (en) Down jacket cleaning agent with functions
CN109868191A (en) A kind of plant cleaning agent for human secretion cleaning
KR102641461B1 (en) Washing color transfer prevention sheet
AU2011214128B2 (en) Composition
WO2001032818A1 (en) Enzyme-containing high-viscosity liquid detergents
KR102266427B1 (en) Liquid detergent composition
CN109207279A (en) A kind of antifog antifreeze detergent of vehicle glass
KR100952440B1 (en) Laundry liquid detergent composition for nature dye clothes

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 19723468

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 202016422

Country of ref document: GB

Kind code of ref document: A

Free format text: PCT FILING DATE = 20190402

122 Ep: pct application non-entry in european phase

Ref document number: 19723468

Country of ref document: EP

Kind code of ref document: A1