WO2019192227A1 - 电极组件、其制造方法及气溶胶生成装置 - Google Patents

电极组件、其制造方法及气溶胶生成装置 Download PDF

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Publication number
WO2019192227A1
WO2019192227A1 PCT/CN2018/125681 CN2018125681W WO2019192227A1 WO 2019192227 A1 WO2019192227 A1 WO 2019192227A1 CN 2018125681 W CN2018125681 W CN 2018125681W WO 2019192227 A1 WO2019192227 A1 WO 2019192227A1
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WIPO (PCT)
Prior art keywords
permanent magnet
electrode
manufacturing
magnet component
component
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PCT/CN2018/125681
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English (en)
French (fr)
Inventor
罗建鹏
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赫斯提亚深圳生物科技有限公司
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Publication of WO2019192227A1 publication Critical patent/WO2019192227A1/zh

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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/70Manufacture
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/40Constructional details, e.g. connection of cartridges and battery parts
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/10Devices using liquid inhalable precursors

Definitions

  • the present invention relates to an electrode assembly, a method of manufacturing the same, and an aerosol generating device.
  • the electrodes for forming electrical connections between the power supply portion and the power-consuming portion are usually made of metal, such as electrodes of copper, silver, gold or the like.
  • FIG. 8 it is a schematic diagram of the assembly between the conventional electronic device 3 and the charger 4.
  • the positive electrode and the negative electrode 41 of the charger extend out of the surface of the charger, and the charging positive electrode and the negative electrode 31 of the electronic device are recessed inward, and the electrodes of the charger extend into the electrodes of the electronic device to form an electrical connection, and the electrodes are usually metal. of.
  • the present invention provides an electrode assembly having a simple structure and a method of manufacturing the same, which can provide reliable magnetic attraction and achieve electrical conductivity.
  • the present invention provides a method of manufacturing an electrode assembly, comprising the steps of: step S1, assembling the permanent magnet member and the connecting member at a temperature at which the conductive permanent magnet member is demagnetized; The permanent magnet member is used as an electrode; in step S2, the permanent magnet member and the connecting member are placed in a magnetic field to magnetize the permanent magnet member.
  • the present invention also provides an electrode assembly manufactured by any of the above-described manufacturing methods.
  • the present invention also provides an aerosol generating device for cooperating with a disposable aerosol generating article, comprising the electrode assembly, further comprising a device housing; the electrode assembly being fixed to the device housing Internally, the device housing is provided with a receiving cavity for inserting the disposable aerosol-generating article, the permanent magnet component is disposed at a bottom of the receiving cavity, and the disposable aerosol is adsorbed by the permanent magnet component An electrode of the article is produced, the aerosol generating device adsorbing the disposable aerosol-generating article.
  • the electrode assembly provided by the invention magnetizes the permanent magnet component after welding, can ensure the magnetic property of the permanent magnet component, avoids the magnetic temperature of the permanent magnet component caused by the ambient temperature during the welding process; in addition, the electrode assembly also has good electrical conductivity. performance.
  • the conductivity of the electrode can be further improved, and the heat generated during the working process can be further reduced, thereby reducing the risk of demagnetization of the permanent magnet component.
  • the ability of the electrode assembly to withstand a larger operating current is also improved.
  • the present electrode assembly When the present electrode assembly is applied to an aerosol generating device, the external electrode of the device adsorbs the outer electrode of the product of the disposable aerosol-generating article, thereby making it easy for the aerosol generating device to adsorb the disposable aerosol-generating article.
  • the magnetic electrode assembly which is magnetic, conductive and connected, has a simpler structure than the magnetic structure of the existing electronic cigarette.
  • FIG. 1 is a schematic structural view of an aerosol generating system according to an embodiment of the present invention.
  • Figure 2 is a partial cross-sectional view of Figure 1;
  • Figure 3 is an exploded view of the disposable aerosol-generating article of Figure 1;
  • Figure 4 is a cross-sectional structural view of the atomizing assembly of the disposable aerosol generating article of Figure 3;
  • Figure 5 is a cross-sectional view showing the internal electrode of the device of the aerosol generating device of Figure 1;
  • Figure 6 is a partial structural view showing an aerosol generating system according to an embodiment of the present invention.
  • Figure 7 is a schematic exploded view of a portion of the structure of Figure 6;
  • Figure 8 is a partial cross-sectional view showing an aerosol generating system according to another embodiment of the present invention.
  • Figure 9 is a partial cross-sectional view showing an aerosol generating system according to another embodiment of the present invention.
  • FIG. 10 is a schematic diagram of a conventional mobile electronic device 3 mated with a charging stand 4;
  • FIG. 11 is a schematic diagram of a mobile electronic device 5 and a charging stand 6 according to an embodiment of the present invention
  • Figure 12 is a flow chart showing a method of manufacturing an electrode assembly in accordance with an embodiment of the present invention.
  • a method of manufacturing an electrode assembly includes the following steps:
  • Step S10 assembling the permanent magnet member and the connector together at a temperature at which the conductive permanent magnet member is demagnetized; wherein the permanent magnet member functions as an electrode.
  • Step S11 the permanent magnet member and the connecting member are placed in a magnetic field to magnetize the permanent magnet member.
  • the present permanent magnet component can be used as an electrode for electrical connection of any electronic device, such as an electrode between an electronic device and its adapted charger.
  • the connector may be any component that is assembled with the permanent magnet component, such as a PCB board that provides electrical connection, or a mount that provides only mechanical support, or a connector that is fixed to the permanent magnet component by injection molding, or the like.
  • the permanent magnet member and the connecting member can be formed into an electrode assembly to facilitate mounting the electrode assembly in any electronic device, so that the permanent magnet member can be used to adsorb the corresponding electrode by magnetic force and can also serve as an electrode.
  • Conductive the structure is very simple.
  • the temperature of the environment in which the above assembly is located is generally prone to demagnetization of the electrically conductive permanent magnet component, for example, by soldering the permanent magnet component to the PCB board using a reflow soldering machine, or by placing the permanent magnet component into the mold, using in-mold molding. Forming a connection to the permanent magnet component that is fixed to the permanent magnet component, etc., is at a higher temperature.
  • the temperature of the permanent magnet component exceeds a certain temperature, its magnetic properties will gradually recede, and when its temperature exceeds the Curie temperature, its magnetic properties will all disappear.
  • the conductive permanent magnet member remains magnetic, thereby ensuring a reliable adsorption connection and electrical connection between the electrode assembly and the corresponding electrode. Otherwise, if the permanent magnet component is magnetized first, and then the permanent magnet component is assembled with the connector, the high temperature in the assembly environment may easily cause the magnetism of the permanent magnet component to decrease or disappear.
  • the electrode assembly described above can be used in an electronic device, an aerosol generating system.
  • the aerosol-generating matrix refers to a substance which can be mixed with air under certain conditions to form an aerosol, which may be in a liquid state or in a solid state.
  • a liquid aerosol generating matrix it is usually necessary to volatilize the aerosol generating matrix into a gas under heating conditions, and after the temperature drops to a certain temperature, the aerosol matrix gas condenses in the air to form an aerosol.
  • the composition of the aerosol-forming matrix in liquid form comprises heating a volatile fuming oil, which may include glycerol (glycerol), propylene glycol, flavor (or fragrance) and nicotine (nicotine), among the above-mentioned cigarette oils, nicotine and / or flavor can be replaced by tobacco extract.
  • Smoke oil may also not contain nicotine.
  • the aerosol generating system 10 includes an aerosol generating device 100 and a disposable aerosol generating article 200 that cooperates with the aerosol generating device 100.
  • the aerosol generating device 100 includes a device housing 110, and a battery 130 and an electrode assembly disposed within the device housing 110.
  • the electrode assembly includes a power supply PCB board 120, an internal electrode 121, and an external electrode 122.
  • the power supply PCB board 120 is fixed in the device housing 110, the battery 130 is disposed under the power supply PCB board 120, and the device inner electrode 121 and the device outer electrode 122 are respectively soldered to the positive output terminal and the negative output terminal of the power supply PCB board 120, thereby forming electricity. connection.
  • the device housing 110 is provided with a receiving cavity 111 for inserting the disposable aerosol generating article 200.
  • the receiving cavity 111 is disposed above the power supply PCB board 120, and the device inner electrode 121 and the device outer electrode 122 are located at the bottom of the receiving cavity 111.
  • the battery 130 is for outputting electrical energy to the power supply PCB board 120 for outputting electrical energy to the mating disposable aerosol-generating article 200 to produce an aerosol.
  • the device outer electrode 122 is a conductive permanent magnet component to adsorb the disposable aerosol-generating article 200.
  • FIG. 3 is a schematic cross-sectional structural view of a disposable aerosol-generating article according to an embodiment of the present invention
  • FIG. 4 is a cross-sectional structural view of the atomizing assembly of the disposable aerosol-generating article of FIG.
  • the disposable aerosol-generating article 200 includes a product outer casing 250, a product PCB board 260, an inner product electrode 261, an outer product electrode 262, an atomizing assembly 240, an oil storage assembly 230, a nozzle holder 220, and a suction nozzle 210.
  • the product PCB board 260, the atomizing assembly 240 and the oil storage assembly 230 are sequentially disposed in the product housing 250, the nozzle holder 220 is fixed on the top of the product housing 250, the suction nozzle 210 is sleeved on the nozzle holder 220, and the inner electrode 261 of the product
  • the outer electrode 262 of the article is soldered to the side of the product PCB 260 near the bottom of the article.
  • the atomizing assembly 240 includes a heating member 243 and an oil guiding member 242 which are respectively welded to the product PCB board 260 and electrically connected to the product inner electrode 261 and the product outer electrode 262.
  • the liquid storage assembly 230 stores a liquid aerosol generating substrate.
  • the oil guiding member 242 is configured to adsorb the aerosol generating substrate of the oil storage assembly 230.
  • the heating member 243 heats the aerosol generating substrate under the power supply of the power supply PCB 120 to form a gas. Sol.
  • the length of the accommodating cavity 111 of the aerosol generating device 100 is smaller than the length of the disposable aerosol-generating article 200, so that when the disposable aerosol-generating article 200 is inserted into the accommodating cavity 111, the nozzle 210 of the disposable aerosol-generating article 200 is exposed. Outside the accommodating chamber 111, the user is in contact with the suction nozzle 210 to suck the aerosol.
  • the device outer electrode 122 When the disposable aerosol-generating article 200 is inserted into the accommodating cavity 111, the device outer electrode 122 adsorbs the outer product electrode 262, thereby causing the aerosol generating device 100 to adsorb the disposable aerosol-generating article 200; and, the device outer electrode 122 and the outer electrode of the article
  • the electrical connection 121 is electrically connected to the inner electrode 261 of the article, and the battery 130 can supply power to the heating member 243. It can be seen that the external electrode 122 of the device functions as a magnetic attraction, a mechanical connection, and an electrical connection.
  • the method of manufacturing the above electrode assembly includes the following steps.
  • the conductive permanent magnet component (ie, the device outer electrode 122) is soldered to the power supply PCB, and the permanent magnet component is electrically connected to the power supply terminal of the power supply PCB.
  • Conductive permanent magnet components include neodymium iron boron magnets, samarium cobalt magnets, etc. In contrast, ferrite magnets are generally non-conductive.
  • the permanent magnet component and the power supply PCB board are placed in a magnetic field to magnetize the permanent magnet component.
  • the power supply PCB board and the permanent magnet part are placed in a magnetic field to magnetize the permanent magnet material part, thereby making the permanent magnet part magnetic.
  • the power supply PCB board can be placed in a magnetizer for magnetization.
  • the conductive permanent magnet member remains magnetic, thereby ensuring a reliable adsorption connection and electrical connection between the aerosol generating device 100 and the disposable aerosol-generating article 200. Otherwise, if the permanent magnet component is magnetized first, and then the permanent magnet component is soldered to the power supply PCB board, the high temperature in the soldering environment may easily cause the magnetic properties of the permanent magnet component to decrease or disappear.
  • step S1 it is also possible to solder other circuit components other than the permanent magnet component to the power supply PCB to maintain the magnetic properties of the permanent magnet component.
  • the device inner electrode 121 is soldered to the power supply PCB. Otherwise, if the other circuit components are soldered to the power supply PCB after the permanent magnet components are magnetized, the high temperature in the soldering environment may also reduce the magnetic properties of the permanent magnet components.
  • the above permanent magnet member is formed by sintering using a material such as neodymium iron boron.
  • a material such as neodymium iron boron.
  • a method of sintering a neodymium iron boron magnet disclosed in the prior art documents such as CN107475631A, CN107316727A, and CN107146672A (publication number) can be referred to.
  • the permanent magnet member is also subjected to a plating treatment after step S1 such that the surface of the permanent magnet member has a metal plating covering the permanent magnet member, so that the permanent magnet member and the metal plating layer integrally form the device outer electrode 122.
  • the metal coating protects the permanent magnet component from damage to the permanent magnet component or reacts with substances in the air (for example, when the permanent magnet component is iron-iron boron, the coating is less likely to rust) and the magnetic force is reduced; in addition, the metal coating is improved.
  • the electrical conductivity of the external electrode 122 of the whole device is low, and the temperature of the external electrode 122 of the whole device is low during operation, and the low temperature is favorable for the operation of the external electrode 122 of the device. In some embodiments, even at high currents (e.g., 4-6 A), the temperature of the outer electrode 122 of the device is not too high (below 100 °C).
  • the rare earth magnet is a magnet with a strong magnetic force made of a rare earth material, including a neodymium iron boron magnet, a samarium cobalt magnet, etc., and the ferromagnetic magnet is relative to an ordinary ferrite.
  • the low temperature is particularly advantageous for maintaining the stability of the permanent magnet component, in particular maintaining magnetic properties. If the temperature is too high, the magnetic properties of the permanent magnet components will weaken or even disappear. It can be seen that a metal plating layer is provided on the surface of the permanent magnet member to reduce the heat generated by the current, and the permanent magnet member can be kept magnetic.
  • the conductive permanent magnet member is not limited to being the device outer electrode 122, but may be used as the device inner electrode 121, the outer product electrode 262, and the inner product electrode 261.
  • the atomizing assembly 240 further includes an insulated atomizing cup 241 disposed above the product PCB board 260.
  • the heating member 243 and the oil guiding member 242 are disposed in the heat insulating atomizing cup 241 to insulate the heat.
  • the atomizing cup 241 can effectively reduce the transfer of heat generated by the heating member 243 to the permanent magnet member to keep the permanent magnet member magnetic.
  • the metal plating layer comprises a plurality of sub-metal plating layers, and the adjacent metal plating layers are made of different metals to improve the adhesion between the sub-metal plating layers and the metal plating layer from the surface of the permanent magnet component while improving the electrical conductivity. Falling off, thereby reducing the electrical conductivity of the outer electrode 122 of the device.
  • the plurality of sub-metal plating layers are first nickel layers, copper layers, and second nickel layers disposed outwardly from the permanent magnet members. The adhesion between the copper layer and the first nickel layer and the second nickel layer is good, and it is not easy to fall off, and also has good electrical conductivity.
  • the nickel layer can be fused with the solder and firmly adhered to each other, so that the permanent magnet member can be stably fixed to the power supply PCB.
  • the aerosol generating device 100 further includes a rigid connecting sleeve 112, a flexible sleeve 113 (eg, a silicone sleeve), and the device housing 110 includes an upper device housing 1101 and a lower device housing 1102.
  • the first end of the rigid connecting sleeve 112 is fixed in the upper device housing 1101, the second end is extended out of the lower device housing 1102; the upper device housing 1101 is detachably sleeved on the second end of the rigid connecting sleeve 112, and the flexible sleeve 113 is rigidly connected
  • the inner wall of the sleeve 112 is closely fitted.
  • the power supply PCB board 120 and the device outer electrode 122 are fixed in the flexible sleeve 113.
  • the power supply PCB board 120 to which the device outer electrode 122 and the device inner electrode 121 are soldered is fixed in the flexible sleeve 113, and the flexible sleeve 113 is fixed in the rigid connection sleeve 112, which is very convenient to assemble.
  • FIG. 6 is a partial structural view of an aerosol generating system according to an embodiment of the present invention
  • FIG. 7 is a partial exploded view of the aerosol generating device of FIG.
  • the flexible sleeve 113 is provided with a first annular flange 1131 near one end of the aerosol-generating article, and a second annular flange 1132 is disposed at one end of the flexible sleeve 113 near the battery 130.
  • the first annular flange 1131 The device outer electrode 122 is disposed above the edge of the device outer electrode 122, the device outer electrode 122 is abutted against the first annular flange 1131, and the power supply PCB plate 120 is abutted against the second annular flange 1132.
  • the device inner electrode 121 includes a conductive base, a conductive spring 1212, and a conductive post 1213.
  • the conductive base has a base cavity 12111 and a base opening.
  • the conductive spring 1212 is disposed in the base cavity 12111 and is electrically conductive.
  • One end of the column 1213 is confined in the base cavity 12111 and abuts against one end of the conductive spring 1212, the other end of the conductive post 1213 protrudes from the base opening to the outside of the base cavity 12111, and the other end of the conductive spring 1212 abuts the base
  • the bottom wall of the cavity 12111, the conductive pillars 1213 are movable along the base cavity 12111, and the surfaces of the conductive base (inner surface and outer surface), the conductive springs 1212 and the conductive pillars 1213 have a gold plating layer.
  • the conductive post 1213 When the device outer electrode 122 is attracted to the outer product electrode 262, the conductive post 1213 is pushed downward by the inner electrode 261 of the article from the initial position, and the conductive spring 1212 is pressed; when the outer electrode 122 of the device is separated from the outer electrode 262 of the product, The conductive post 1213 returns to the initial position under the thrust of the conductive spring 1212. Since the surface of the electrode 121 in the device has a gold plating layer, the conductivity of the electrode 121 in the device can be effectively improved, and the heat generated even in the case of a large current is small, so that the magnetic properties of the external electrode 122 of the device are not affected.
  • the bottom of the conductive base may be soldered to the upper surface of the power supply PCB board 120; as shown in FIG. 2, the conductive base may also pass through the PCB board, and extend the side wall of the lower surface of the power supply PCB board 120 and the power supply PCB board.
  • the lower surface of the 120 is soldered, and the conductive base extends from the side wall of one end of the upper surface of the power supply PCB 120 to the upper surface of the power supply PCB 120, so that the internal electrode 121 of the device can be more stably fixed.
  • an air inlet 1103 is provided at the bottom of the device housing 110, and a first passage 1104 through which a gas flows is provided between the battery 130 and the device housing 110, and between the external electrode 122 of the device and the internal electrode 121 of the device.
  • the device outer electrode 122 is further provided with an electrode louver 1222 through which the gas flows (the louver may be in the form of a hole, a notch, etc.).
  • a first gap 1133 is defined between the flexible sleeve 113 and the rigid connecting sleeve 112.
  • the flexible sleeve 113 is provided with a flexible sleeve plenum 1134 for gas flow (the louver may be in the form of a hole or a notch), and the power supply PCB board 120 and the flexible sleeve
  • the inner wall of 113 forms a close fitting connection such that gas enters the device electrode gap 123 via the first gap 1133, the flexible plenum 1134, and the electrode louver 1222.
  • the side wall of the flexible sleeve 113 (for example, the lower portion of the flexible sleeve window 1134), the device outer electrode 122 and the power supply PCB board form a cavity for accommodating the liquid, and the cavity also partially overlaps the device electrode gap 123, where the liquid may be It is the condensed water generated during the operation of the aerosol generating device 100, or the aerosol generating matrix flowing down from the disposable aerosol generating article 200.
  • the cavity can temporarily store a part of the liquid, so that the liquid can be prevented from flowing directly through the power supply PCB to the battery or the control circuit portion, thereby causing damage to the battery or the control circuit portion.
  • a product electrode gap 263 for isolating the outer electrode 262 of the product and the inner electrode 261 of the product to prevent electrical connection therebetween, and at the same time, Air flows through.
  • a PCB board air hole 264 is provided on the product PCB board 260.
  • the bottom of the heat insulating atomization cup 241 is provided with an atomizing cup air hole 2411, and the side wall of the heat insulating atomizing cup 241 is further provided with an atomizing cup air window 2412.
  • the oil storage assembly 230 includes a storage tank 232, an oil seal cover 234, and an oil permeable member 233.
  • the storage tank 232 stores a liquid aerosol generating substrate.
  • the storage tank 232 is fixed in the product casing 250 and located below the suction nozzle 210.
  • the storage tank 232 has an opening at one end, and the oil sealing cover 234 and the oil leakage member 233 are sequentially disposed in the opening.
  • the heat insulating atomization cup 241 is disposed below the storage tank 232, and the oil guiding member 242 contacts the oil leakage member 233.
  • a second passage 231 through which the aerosol passes is also provided in the reservoir 232 and the article housing 250.
  • the first annular flange 1131 surrounds the bottom of the aerosol-generating article, and the gas from the gap between the aerosol-generating article and the accommodating cavity 111 into the slab hole 264 can be reduced.
  • the air enters the aerosol generating device 100 from the air inlet 1103, and then passes through the first passage 1104, the first gap 1133, the flexible plenum 1134, and the electrode louver 1222, and then flows into the device electrode gap 123, and then passes through the product electrode.
  • the gap 263, the PCB plate air holes 264, and the atomizing cup air holes 2411 enter the heat insulating atomization cup 241 to form an aerosol.
  • the aerosol After passing through the atomizing cup louver 2412, the second passage 231, and the nozzle holder 220, the aerosol enters the suction nozzle 210 and is finally sucked by the user.
  • the electrode assembly of the aerosol generating device 100 may be soldered to the device outer electrode 122 and the device inner electrode 121 without using the power supply PCB 120, for example, soldering.
  • the device outer electrode 122 and the device inner electrode 121 power is supplied to the device outer electrode 122 and the device inner electrode 121.
  • the device outer electrode 122 and the device inner electrode 121 are fixed to the connector 113 and pass through the connector 113.
  • One end of the power supply wire 32 is soldered to the outer electrode 122 of the device, and the other end is soldered to a voltage output end of a voltage output circuit (not shown) of the aerosol generating device 100.
  • One end of the power supply wire 31 is soldered to the inner electrode 121 of the device, and the other end is welded. Soldering is coupled to another voltage output of the voltage output circuit, wherein the voltage output circuit is operative to convert the voltage of the battery 130 to a desired output voltage.
  • the method of manufacturing the electrode assembly shown in Fig. 8 includes the following steps.
  • the power supply wire 32 is soldered to the device outer electrode 122, and the power supply wire 31 is soldered to the device inner electrode 121.
  • the connecting member 113 may be made of high temperature resistant plastic, silica gel or the like.
  • the power supply lead 32 may not be soldered to the external electrode 122 of the device, but may be soldered to the metal piece 40.
  • the metal piece 40 is magnetically attracted to the external electrode 122 by the device.
  • the metal piece 40 may be made of a soft magnetic or electrically conductive material, so that the power supply wire 32 may be electrically connected to the device outer electrode 122 through the metal piece 40.
  • the method of manufacturing the electrode assembly shown in Fig. 9 includes the following steps.
  • the power supply lead 32 is soldered to the metal piece 32, for example, to the bottom surface of the metal piece 32.
  • the connecting member 113 may be made of high temperature resistant plastic, silica gel or the like.
  • the metal piece 40 is magnetically attracted by the device outer electrode 122, and then the power supply wire 32 is soldered to the voltage output end of the voltage output circuit.
  • the above electrode assembly can also be applied to other electronic devices to magnetically connect the first portion and the second portion of the electronic device, and to make the first portion and the second portion electrically conductive.
  • FIG. 11 is a schematic diagram of the mobile electronic device 5 mated with the charging stand 6. At least one of the electrode 51 of the mobile electronic device 5 and the electrode 61 of the charging stand 6 adopts the above-mentioned conductive permanent magnet component to realize the mobile electronic device. 5 and the charging stand 6 are mutually attracted and electrically conductive.

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Abstract

一种电极组件、电极组件制造方法及气溶胶生成装置,制造方法包括如下步骤:步骤S1,在导电的永磁部件退磁的温度下,将永磁部件与连接件装配在一起;其中,永磁部件用作电极(S10);步骤S2,将永磁部件和连接件置于磁场中对永磁部件进行充磁(S11)。电极组件在焊接之后对永磁部件进行充磁,可以保证永磁部件的磁性,避免焊接过程中的环境温度导致永磁部件的磁性减退;另外,电极组件还具有良好的导电性能。

Description

电极组件、其制造方法及气溶胶生成装置 技术领域
本发明涉及电极组件、其制造方法及气溶胶生成装置。
背景技术
现有的电子设备(包括电子烟)中,供电部分与用电部分之间用于形成电连接的电极通常是用金属制造而成的,例如铜、银、金等电极。如图8所示,是现有常见的电子设备3与充电器4之间的装配示意图。充电器的正电极和负电极41伸出充电器的表面,电子设备的充电正电极和负电极31向内凹陷,充电器的电极伸入电子设备的电极形成电连接,这些电极通常都是金属的。
为了实现电接触的可靠,需要施加一个防止电子设备3与充电器4分离的力,例如在充电器4上增设座体,从而可以使电子设备3稳定固定在充电器4上以形成可靠的电连接。
然而,这种结构需要增加额外的机械辅助结构。
发明内容
为了克服现有技术的不足,本发明提供一种结构简单的电极组件及其制造方法,可以提供可靠的磁吸力以及实现导电性能。
为了实现上述目的,本发明提供了一种电极组件的制造方法,包括如下步骤:步骤S1,在导电的永磁部件退磁的温度下,将所述永磁部件与连接件装配在一起;其中,所述永磁部件用作电极;步骤S2,将所述永磁部件和所述连接件置于磁场中对所述永磁部件进行充磁。
为了实现上述目的,本发明还提供了一种电极组件,采用任一所述的制造 方法制造得到。
为了实现上述目的,本发明还提供了一种气溶胶生成装置,用于与抛弃式气溶胶生成制品配合,包括所述的电极组件,还包括装置外壳;所述电极组件固定在所述装置外壳内,所述装置外壳设有用于供所述抛弃式气溶胶生成制品插入的容纳腔,所述永磁部件设置在所述容纳腔的底部,通过所述永磁部件吸附所述抛弃式气溶胶生成制品的电极,所述气溶胶生成装置吸附所述抛弃式气溶胶生成制品。
本发明提供的电极组件在焊接之后对永磁部件进行充磁,可以保证永磁部件的磁性,避免焊接过程中的环境温度导致永磁部件的磁性减退;另外,本电极组件还具有良好的导电性能。
由于在永磁部件的表面包裹金属镀层,可以进一步提高电极的导电性能,进一步降低工作过程中产生的热量,从而降低了永磁部件退磁的风险。同时,也提高了本电极组件承受更大工作电流的能力。
当本电极组件应用在气溶胶生成装置中时,装置外电极吸附抛弃式气溶胶生成制品的制品外电极,从而使得气溶胶生成装置吸附抛弃式气溶胶生成制品,非常方便。同时起到了磁吸、导电和连接的作用电极组件与现有电子烟的磁吸结构相比,结构更加简单。
提供本发明内容是以简化形式介绍在以下详细描述中的一些概念。本发明内容并不旨在标识所要求保护的主题的关键特征或必要特征,也不旨在用于限制所要求保护的主题的范围。
附图说明
图1是本发明一实施例气溶胶生成系统的结构示意图;
图2是图1的部分剖视示意图;
图3是图1的抛弃式气溶胶生成制品的爆炸意图;
图4是图3抛弃式气溶胶生成制品的雾化组件的剖面结构示意图;
图5是图1气溶胶生成装置的装置内电极剖视示意图;
图6是图1是本发明一实施例气溶胶生成系统的部分结构示意图;
图7是图6的部分结构爆炸示意图;
图8是本发明另一实施例气溶胶生成系统的部分剖视示意图;
图9是本发明另一实施例气溶胶生成系统的部分剖视示意图;
图10是现有技术常见的移动电子设备3与充电座4配合的示意图;
图11是本发明一种实施例的移动电子设备5与充电座6配合的示意图;
图12是本发明一种实施例的电极组件的制造方法的流程图。
具体实施方式
下面结合附图对本发明的优选实施例做详细的描述。
如图12所示,在一个实施例中,一种电极组件的制造方法,包括如下步骤:
步骤S10,在导电的永磁部件退磁的温度下,将所述永磁部件与连接件装配在一起;其中,所述永磁部件用作电极。
步骤S11,将所述永磁部件和所述连接件置于磁场中对所述永磁部件进行充磁。
本永磁部件可以用作任意电子设备的用于电连接的电极,例如电子设备与其适配的充电器之间的电极。连接件可以是任意与该永磁部件装配的部件,例如提供电气连接的PCB板、或者仅提供机械支撑的固定座,或者通过注塑成型 而与永磁部件固定的连接件等。通过步骤S1,可以使得永磁部件与连接件形成一个电极组件,以方便将该电极组件安装在任意的电子设备中,从而永磁部件即可以用于通过磁力吸附对应的电极,又能够充当电极而导电,结构非常简单。
上述装配所处的环境的温度通常容易导致导电的永磁部件退磁,例如,利用回流焊机器将永磁部件焊接至PCB板上,或者将永磁部件放入模具中,利用模内注塑方式在永磁部件上形成一个与永磁部件固定的连接件,等等,都会处在一个较高的温度。
当永磁部件的温度超过一定温度时,其磁性将逐渐退去,当其温度超出居里温度时,其磁性将全部消失。本实施例通过上述步骤,可以保证导电的永磁部件保持磁性,从而保证了电极组件与对应电极之间可靠的吸附连接和电连接。否则,如果先对永磁部件进行充磁,然后再将永磁部件与连接件进行装配,则装配环境下的高温容易导致永磁部件的磁性减小或消失。
在一个实施例中,上述电极组件可以用于一种电子设备--气溶胶生成系统。
气溶胶生成基质是指在一定条件下能与空气混合生成气溶胶的物质,其可以是液态,也可以是固态。对于液态的气溶胶生成基质而言,通常需要在加热的条件下使气溶胶生成基质挥发为气体,在温度下降至一定温度后,气溶胶基质气体在空气中冷凝形成气溶胶。液体形式的气溶胶生成基质的成分包括加热可挥发的烟油,烟油可以包括丙三醇(甘油)、丙二醇、香精(或香料)和烟碱(尼古丁),上述烟油中,烟碱和/或香精可以由烟草提取物替代。烟油也可以不包含尼古丁。
如图1所示,是本发明一种实施例的气溶胶生成系统10的结构示意图。气溶胶生成系统10包括气溶胶生成装置100以及与气溶胶生成装置100相配合的抛弃式气溶胶生成制品200。
进一步参考图2,是图1气溶胶生成系统10的部分剖视示意图。气溶胶 生成装置100包括装置外壳110,以及设置于装置外壳110内的电池130和电极组件。其中,该电极组件包括供电PCB板120、装置内电极121、装置外电极122。
供电PCB板120固定在装置外壳110内,电池130设置在供电PCB板120下方,装置内电极121和装置外电极122分别与供电PCB板120上的正极输出端和负极输出端焊接,从而形成电连接。装置外壳110设有用于供抛弃式气溶胶生成制品200插入的容纳腔111,容纳腔111设置在供电PCB板120上方,装置内电极121、装置外电极122位于容纳腔111的底部。电池130用于输出电能至供电PCB板120,供电PCB板120用于将电能输出至于相配合的抛弃式气溶胶生成制品200以产生气溶胶。装置外电极122是导电的永磁部件,以吸附抛弃式气溶胶生成制品200。
进一步参考图3和4,图3是本发明一实施例抛弃式气溶胶生成制品的剖面结构示意图,图4是图3抛弃式气溶胶生成制品的雾化组件的剖面结构示意图。抛弃式气溶胶生成制品200包括制品外壳250、制品PCB板260、制品内电极261、制品外电极262、雾化组件240、储油组件230、吸嘴支架220和吸嘴210。制品PCB板260、雾化组件240和储油组件230依次设置在制品外壳250内,吸嘴支架220固定在制品外壳250的顶部,吸嘴210套在吸嘴支架220上,制品内电极261和制品外电极262焊接在制品PCB板260靠近制品底部的一面。雾化组件240包括加热部件243和导油件242,加热部件243的两端分别焊接至制品PCB板260上,并与制品内电极261和制品外电极262电连接。储油组件230内存储液体状的气溶胶生成基质,导油件242用于吸附储油组件230的气溶胶生成基质,加热部件243在供电PCB板120供电下加热气溶胶生成基质,以形成气溶胶。
气溶胶生成装置100的容纳腔111的长度小于抛弃式气溶胶生成制品200的长度,从而当抛弃式气溶胶生成制品200插入该容纳腔111后,抛弃式气溶胶生成制品200的吸嘴210露出在容纳腔111外面,以供用户接触吸嘴210 而吸食气溶胶。
当抛弃式气溶胶生成制品200插入容纳腔111后,装置外电极122吸附制品外电极262,从而使气溶胶生成装置100吸附抛弃式气溶胶生成制品200;并且,装置外电极122与制品外电极262电连接,装置内电极121与制品内电极261接触并导电连接,从而电池130可以向加热部件243供电。可见,装置外电极122起到了磁吸作用、机械连接作用以及电连接作用。
在一个实施例中,上述电极组件的制造方法包括以下步骤。
S20、在导电的永磁部件退磁的温度下,将导电的所述永磁部件焊接在所述供电PCB板上使所述永磁部件与所述PCB板上的供电端电连接。
将导电的永磁部件(即装置外电极122)焊接在供电PCB板上,使所述永磁部件与所述供电PCB板上的供电端电连接。导电的永磁部件包括钕铁硼磁铁、钐钴磁铁等,相比而言,铁氧体磁铁通常是不导电的。
S21、将所述永磁部件和供电PCB板置于磁场中对所述永磁部件进行充磁。
将所述供电PCB板以及所述永磁部件置于磁场中以对所述永磁材料部件进行充磁,从而使得永磁部件获得磁性。例如,可以将供电PCB板置于充磁机中进行充磁。
当永磁部件的温度超过一定温度时,其磁性将逐渐退去,当其温度超出居里温度时,其磁性将全部消失。本实施例通过上述步骤,可以保证导电的永磁部件保持磁性,从而保证了气溶胶生成装置100与抛弃式气溶胶生成制品200之间可靠的吸附连接和电连接。否则,如果先对永磁部件进行充磁,然后再将永磁部件与供电PCB板焊接,则焊接环境下的高温容易导致永磁部件的磁性减小或消失。
在上述步骤S1中,还可以将永磁部件以外的其他电路部件焊接在供电PCB板上,以保持永磁部件的磁性。例如,将装置内电极121焊接在供电PCB板上。否则,如果在永磁部件充磁后再将其他电路部件焊接在供电PCB板上,焊接环境下的高温也可能降低永磁部件的磁性。
在一个实施例中,利用钕铁硼等材料烧结形成上述永磁部件。具体方法可以参照CN107475631A、CN107316727A、CN107146672A(公开号)等现有专利文献公开的烧结制造钕铁硼磁铁的方法。
在一个实施例中,在步骤S1之后还对永磁部件进行镀层处理,使得永磁部件的表面具有包裹永磁部件的金属镀层,从而永磁部件和金属镀层整体上形成装置外电极122。金属镀层可以保护永磁部件,以防止永磁部件破损,或者与空气中的物质反应(例如当永磁部件是铁铷硼时,没有镀层容易生锈)而降低了磁力;另外,金属镀层提高了整个装置外电极122的导电性能,工作时整个装置外电极122的温度会较低,低温有利于装置外电极122的工作稳定。在一些实施例中,即使在大电流(例如4-6A)的情况下,本装置外电极122的温度也不会太高(在100℃以下)。
当永磁部件是稀土强磁磁铁时(稀土强磁磁铁是指采用稀土材料制造的磁力很强的磁铁,包括钕铁硼磁铁、钐钴磁铁等,强磁磁铁是相对于普通的铁氧体磁铁等这些磁力较弱的磁铁而言的),低温尤其有利于保持永磁部件的工作稳定,具体而言是保持磁性。如果温度过高,永磁部件的磁性将会减弱甚至消失。可见,在永磁部件的表面设置金属镀层以降低电流产生的热量,可以使永磁部件保持磁性。
导电的永磁部件并不局限于作为装置外电极122,也可以作为装置内电极121、制品外电极262和制品内电极261。
如图3和4所示,雾化组件240还包括设置在制品PCB板260的上方的隔热雾化杯241,加热部件243和导油件242设置在隔热雾化杯241内,隔热雾化杯241可以有效降低加热部件243产生的热量传递至永磁部件,以使永磁部 件保持磁性。
在一个实施例中,金属镀层包括多个子金属镀层,相邻的金属镀层采用不同的金属,以在提高导电性能的同时,提高子金属镀层之间的附着力,防止金属镀层从永磁部件表面脱落,进而降低装置外电极122的导电性能。在一个更加具体的实施例中,多个子金属镀层为从永磁部件向外依次设置的第一镍层、铜层和第二镍层。铜层与第一镍层和第二镍层的附着力很好,不容易脱落,同时也具有较好的导电性能。另外,镍层能够与焊锡融合并稳固地相互附着,使得永磁部件能够稳定地固定在供电PCB板上。
如图2所示,在一个实施例中,气溶胶生成装置100还包括刚性连接套112、柔性套113(例如,硅胶套),装置外壳110包括上装置外壳1101、下装置外壳1102。刚性连接套112的第一端固定在上装置外壳1101内、第二端伸出下装置外壳1102;上装置外壳1101可拆卸套在刚性连接套112的第二端上,柔性套113与刚性连接套112的内壁紧密配合。供电PCB板120、装置外电极122固定在柔性套113内。组装时,可以先将焊接固定了装置外电极122和装置内电极121的供电PCB板120固定在柔性套113内,再将柔性套113固定在刚性连接套112内,组装起来非常方便。
进一步参考图6和7,图6是图1是本发明一实施例气溶胶生成系统的部分结构示意图,图7是图1气溶胶生成装置的部分结构爆炸示意图。在一个实施例中,柔性套113靠近气溶胶生成制品的一端设有第一环状凸缘1131,柔性套113靠近电池130一端设有第二环状凸缘1132,第一环状凸缘1131设置于装置外电极122边沿的上方,装置外电极122抵于第一环状凸缘1131,供电PCB板120抵于第二环状凸缘1132。
进一步参考图5,是图1气溶胶生成装置的装置内电极剖视示意图。在一个实施例中,装置内电极121包括导电基座、导电弹簧1212、导电柱1213, 导电基座具有基座腔体12111和基座开口,导电弹簧1212设置在基座腔体12111内,导电柱1213一端被限制在基座腔体12111内并抵于导电弹簧1212的一端、导电柱1213另一端从基座开口伸出至基座腔体12111外,导电弹簧1212的另一端抵于基座腔体12111的底壁,导电柱1213可沿基座腔体12111移动,导电基座的表面(内表面和外表面)、导电弹簧1212和导电柱1213的表面具有镀金层。当装置外电极122与制品外电极262相吸附时,导电柱1213被制品内电极261推动从初始位置向下移动,并挤压导电弹簧1212;当装置外电极122与制品外电极262分离时,导电柱1213在导电弹簧1212的推力下恢复到初始位置。由于装置内电极121的表面具有镀金层,可以有效提高装置内电极121的导电性能,即使在较大电流的情况下产生的热量也很小,从而不会对装置外电极122的磁性造成影响。
导电基座的底部可以焊接在供电PCB板120的上表面;如图2所示,也可以将导电基座穿过PCB板,伸出供电PCB板120的下表面一端的侧壁与供电PCB板120的下表面焊接,导电基座伸出供电PCB板120的上表面一端的侧壁与供电PCB板120的上表面焊接,这样可以更加稳定地固定装置内电极121。
如图1和2所示,装置外壳110的底部设有空气入口1103,电池130与装置外壳110之间设有供气体流过的第一通道1104,装置外电极122与装置内电极121之间具有装置电极间隙123,该装置电极间隙123用于隔离装置外电极122和装置内电极121以防止两者电连接,同时可以供空气流过。装置外电极122上还设有供气体流过的电极气窗1222(气窗可以是孔、缺口等形式)。柔性套113与刚性连接套112之间设有第一间隙1133,柔性套113上设有供气体流过的柔性套气窗1134(气窗可以是孔、缺口等形式),供电PCB板120与柔性套113的内壁形成紧密配合连接,使得气体经由第一间隙1133、柔性套气窗1134和电极气窗1222进入装置电极间隙123。而柔性套113的侧壁(例 如柔性套气窗1134下面部分)、装置外电极122和供电PCB板之间形成容纳液体的腔体,该腔体也与装置电极间隙123部分重叠,这里的液体可能是气溶胶生成装置100工作过程中产生的冷凝水,或者从抛弃式气溶胶生成制品200流下的气溶胶生成基质。该腔体可以暂存一部分液体,从而可以避免液体直接穿过供电PCB板向下流向电池或者控制电路部分,从而带来损坏电池或控制电路部分的隐患。
如图2所示,制品外电极262与制品内电极261之间具有制品电极间隙263,该制品电极间隙263用于隔离制品外电极262和制品内电极261以防止两者电连接,同时可以供空气流过。制品PCB板260上设有PCB板气孔264。隔热雾化杯241底部设置有雾化杯气孔2411,隔热雾化杯241的侧壁还设有雾化杯气窗2412。
如图3所示,储油组件230包括储罐232、封油盖234、渗油件233。储罐232存储液体气溶胶生成基质,储罐232固定在制品外壳250内且位于吸嘴210下方,储罐232一端具有开口,封油盖234和渗油件233依次设置在开口内。隔热雾化杯241设置在储罐232下方,导油件242接触渗油件233。储罐232与制品外壳250内还设有供气溶胶通过的第二通道231。
当气溶胶生成制品插入容纳腔111后,第一环状凸缘1131环绕气溶胶生成制品的底部,可以减少从气溶胶生成制品与容纳腔111之间的缝隙进入PCB板气孔264的气体。
当用户吸气时,空气从空气入口1103进入气溶胶生成装置100,然后依次经过第一通道1104、第一间隙1133、柔性套气窗1134和电极气窗1222后流入装置电极间隙123,再经过制品电极间隙263、PCB板气孔264、雾化杯气孔2411后进入隔热雾化杯241内,以形成气溶胶。气溶胶经过雾化杯气窗2412、第二通道231、吸嘴支架220后进入吸嘴210,最终被用户吸食。
如图8所示,在一些实施例中,上述气溶胶生成装置100的电极组件可以 不采用供电PCB板120,而用供电导线分别焊接在装置外电极122和装置内电极121上,例如,焊接在装置外电极122和装置内电极121的底部,以对装置外电极122和装置内电极121进行供电。在更具体的实施例中,装置外电极122和装置内电极121固定在连接件113上,并穿过连接件113。供电导线32一端焊接在装置外电极122,另一端焊接在气溶胶生成装置100的电压输出电路(图中未示出)的一个电压输出端,供电导线31一端焊接在装置内电极121,另一端焊接在电压输出电路的另一个电压输出端,其中电压输出电路用于将电池130的电压转换为所需的输出电压。
图8所示的电极组件的制造方法包括如下步骤。
S30、先将供电导线32与装置外电极122焊接,将供电导线31与装置内电极121焊接。
S31、通过注塑的方式形成上述分别与装置外电极122和装置内电极121固定的连接件113,从而将装置外电极122和装置内电极121与连接件113固定在一起。在一个实施例中,装置外电极122和装置内电极121穿过连接件113以方便将供电导线31和供电导线32焊接到电压输出电路的电压输出端。在本实施例中,连接件113可以采用耐高温的塑料、硅胶等。
如图9所示,在另一个实施例中,上述供电导线32可以不焊接在装置外电极122上,而是焊接在金属片40上,金属片40被装置外电极122通过磁力吸附于所述装置外电极122的底部,金属片40可以采用软磁性、导电的材料,从而供电导线32可以通过金属片40与装置外电极122电连接。
图9所示的电极组件的制造方法包括如下步骤。
S30、将供电导线31与装置内电极121焊接。
S31、将供电导线32与金属片32焊接,例如,焊接在金属片32的底面。
S32、通过注塑的方式形成上述分别与装置外电极122和装置内电极121固定的连接件113,从而将装置外电极122和装置内电极121与连接件113固定在一起。在一个实施例中,装置外电极122和装置内电极121穿过连接件 113以方便将供电导线31焊接到电压输出电路的电压输出端。在本实施例中,连接件113可以采用耐高温的塑料、硅胶等。
S33、使金属片40被装置外电极122通过磁力吸附,然后将供电导线32焊接到电压输出电路的电压输出端。
当然,上述电极组件还可以应用在其他电子设备中,以实现磁力连接该电子设备的第一部分和第二部分,以及使该第一部分和第二部分相导电的作用。例如图11所示,是移动电子设备5与充电座6配合的示意图,移动电子设备5的电极51与充电座6的电极61的至少一者采用上述导电的永磁部件,以实现移动电子设备5与充电座6之间相互吸附和导电。
应当理解的是,以上优选实施例仅用以说明本发明的技术方案,而非用以限定,对本领域技术人员来说,可以对上述优选实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而所有这些修改和替换,都应属于本发明所附权利要求的保护范围。

Claims (14)

  1. 一种电极组件的制造方法,其特征是,包括如下步骤:
    步骤S1,在导电的永磁部件退磁的温度下,将所述永磁部件与连接件装配在一起;其中,所述永磁部件用作电极;
    步骤S2,将所述永磁部件和所述连接件置于磁场中对所述永磁部件进行充磁。
  2. 如权利要求1所述的制造方法,其特征是,
    所述连接件为PCB板;
    所述步骤S1中,将所述永磁部件与连接件装配在一起是指,
    将所述永磁部件焊接在所述PCB板上使所述永磁部件与所述PCB板上的供电端电连接。
  3. 如权利要求2所述的制造方法,其特征是,
    还包括如下步骤:
    在所述PCB板上焊接所述永磁部件以外的电路部件;
    所述步骤S2为:
    将所述PCB板、电路部件以及所述永磁部件置于磁场中,对所述永磁部件进行充磁。
  4. 如权利要求1所述的制造方法,其特征是,
    所述步骤S1中,将所述永磁部件与连接件装配在一起是指,
    通过注塑形成与所述永磁部件固定的所述连接件。
  5. 如权利要求4所述的制造方法,其特征是,
    所述步骤S1中,通过注塑形成分别与导体部件、所述永磁部件固定的所述连接件;其中,所述导体部件用作另一电极。
  6. 如权利要求5所述的制造方法,其特征是,
    在所述步骤S1之前,还包括如下步骤:
    将一导线焊接在所述永磁部件上,将另一导线焊接在所述导体部件上。
  7. 如权利要求5所述的制造方法,其特征是,
    在所述步骤S1之前,还包括如下步骤:
    将一导线焊接在所述导体部件上;
    在所述步骤S2之后,还包括如下步骤:
    使焊接有另一导线的导电金属被所述永磁部件磁力吸附。
  8. 如权利要求1所述的制造方法,其特征是,
    所述永磁部件采用稀土强磁材料烧结得到。
  9. 如权利要求1所述的制造方法,其特征是,
    所述永磁部件为强磁材料、钕铁硼磁铁或钐钴磁铁。
  10. 如权利要求1所述的制造方法,其特征是,
    所述永磁部件的表面包裹有金属镀层。
  11. 如权利要求10所述的制造方法,其特征是,
    所述金属镀层包括多个子金属镀层。
  12. 如权利要求10所述的制造方法,其特征是,
    所述金属镀层包括依次设置的第一镍镀层、铜镀层和第二镍镀层。
  13. 一种电极组件,其特征是,采用如权利要求1-12任一所述的制造方法制造得到。
  14. 一种气溶胶生成装置,用于与抛弃式气溶胶生成制品配合,其特征是,
    包括如权利要求13所述的电极组件,还包括装置外壳;
    所述电极组件固定在所述装置外壳内,所述装置外壳设有用于供所述抛弃 式气溶胶生成制品插入的容纳腔,所述永磁部件设置在所述容纳腔的底部,通过所述永磁部件吸附所述抛弃式气溶胶生成制品的电极,所述气溶胶生成装置吸附所述抛弃式气溶胶生成制品。
PCT/CN2018/125681 2018-04-04 2018-12-29 电极组件、其制造方法及气溶胶生成装置 WO2019192227A1 (zh)

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