WO2019181511A1 - Contact element and method for manufacturing contact element - Google Patents
Contact element and method for manufacturing contact element Download PDFInfo
- Publication number
- WO2019181511A1 WO2019181511A1 PCT/JP2019/008888 JP2019008888W WO2019181511A1 WO 2019181511 A1 WO2019181511 A1 WO 2019181511A1 JP 2019008888 W JP2019008888 W JP 2019008888W WO 2019181511 A1 WO2019181511 A1 WO 2019181511A1
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- WIPO (PCT)
- Prior art keywords
- contact
- base metal
- base
- metal
- manufacturing
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/10—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating making use of vibrations, e.g. ultrasonic welding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H1/00—Contacts
- H01H1/06—Contacts characterised by the shape or structure of the contact-making surface, e.g. grooved
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H11/00—Apparatus or processes specially adapted for the manufacture of electric switches
- H01H11/04—Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
- H01H11/06—Fixing of contacts to carrier ; Fixing of contacts to insulating carrier
Definitions
- This invention relates to the contactor with which contactors, such as a circuit breaker and a switch, are provided, and the manufacturing method of a contactor.
- Contactors such as circuit breakers and switches are provided with movable contacts and fixed contacts.
- Each of the movable contact and the fixed contact is configured by a contact and a base metal on which the contact is provided.
- brazing method a resistance welding method, and the like as a method of joining the contact to the base metal.
- a flux for activating the metal interface is necessary, and a cleaning step after joining the contact to the base metal is necessary.
- the contact and the base metal may be softened.
- Patent Document 1 discloses a method for manufacturing a contact using an ultrasonic bonding method.
- a plurality of grooves are provided on the contact-side surface of the base metal to prevent slippage between the contact point and the base metal when ultrasonic vibration is applied.
- the end of the anvil on the base metal side is subjected to uneven knurling.
- an uneven knurling process is applied to the end of the horn on the contact side. Yes.
- the present invention has been made in view of the above, and an object of the present invention is to obtain a contactor capable of suppressing progress of wear of a contact connected to a base metal by ultrasonic welding.
- the contact according to the present invention includes a base metal and a contact fixed to the base metal.
- the contact is provided between the base metal and the contact, and includes a conductive member having a hardness lower than the contact hardness and capable of plastic flow.
- the outer peripheral surface of the base metal is recessed in a direction perpendicular to the direction in which the base metal, the conductive member, and the contact are arranged, and a recess into which a jig provided on the movable part of the ultrasonic welding machine is fitted is formed. .
- FIG. 1 is a diagram showing a configuration of a contact according to an embodiment of the present invention.
- FIG. 2 is a diagram showing details of the configuration of the movable contact shown in FIG.
- FIG. 1 shows a contactor 100 including a contact 1 according to an embodiment of the present invention.
- the contactor 100 is a low-voltage or high-voltage circuit breaker or switch having a function of opening a contact when an overcurrent is generated in the distribution line.
- the contact 1 includes a fixed contact 11, a movable contact 12, and a peeling mechanism 2.
- the movable contact 12 is physically separated from the fixed contact 11 by the peeling mechanism 2 when an electric current of a certain level or more flows in the electric circuit in which the contactor 100 is provided. Thereby, the electric current which flows into the electric circuit where the contact 1 is connected is interrupted
- the fixed contact 11 includes a rectangular first base 31 that is a conductive fixed piece fixed to a housing (not shown) constituting the contactor 100, a first contact 41 that is a fixed contact, A first intermediate member 61 that is a conductive member provided between the base 31 and the first contact 41 is provided.
- the arrangement direction of the first base metal 31, the first intermediate member 61, and the first contact 41 is the X axis direction
- the direction orthogonal to the X axis direction is the Y axis direction
- the X axis A direction orthogonal to both the direction and the Y-axis direction is taken as a Z-axis direction.
- Examples of the material of the first metal 31 include electrolytic copper and oxygen-free copper.
- FIG. 1 shows a first end surface 3A, a second end surface 3B, a third end surface 3C, a fourth end surface 3D, and a sixth end surface 3F among the six end surfaces included in the first base metal 31.
- the first end surface 3A of the first base metal 31 is an end surface of the first base metal 31 on the movable contact 12 side.
- the second end surface 3B of the first base metal 31 is an end surface on the opposite side of the first base metal 31 from the movable contact 12 side.
- the third end face 3C of the first base metal 31 is one of the two end faces in the Y-axis direction.
- the fourth end surface 3D of the first base metal 31 is the other end surface of the two end surfaces in the Y-axis direction.
- the sixth end surface 3F of the first base metal 31 is a first surface in a direction in which a normal line perpendicular to the surface including the first contact 41, the first intermediate member 61, and the first base metal 31 extends.
- the direction in which the normal line extends is equal to the Z-axis direction.
- a fifth end surface is formed on the opposite side of the first base 31 from the first surface.
- the sixth end surface 3F of the first base 31 is provided with a recess 301 that is recessed from the sixth end surface 3F toward the fifth end surface.
- a recess similar to the recess 301 is provided on the fifth end face side of the first base 31.
- the first intermediate member 61 is in contact with the first end face 3A of the first base 31.
- a conductive material whose hardness is lower than that of the first contact point 41 and capable of plastic flow is used. Examples of this conductive material include silver.
- the first intermediate member 61 is, for example, a surface of the first contact 41 on the first metal base 31 side, which is separated by the difference in specific gravity of a plurality of materials constituting the first contact 41 when the first contact 41 is manufactured. It is formed by solidifying.
- the first intermediate member 61 can be formed on the surface of the first contact 41 on the side of the first base metal 31 by a vacuum vapor deposition method, a plating method, or the like in addition to the separation due to the specific gravity difference.
- the first contact point 41 is fixed to the first base 31 via the first intermediate member 61.
- a sintered metal having a hardness higher than that of the first intermediate member 61 is used as the material of the first contact 41.
- the sintered metal include silver tungsten alloy, tungsten carbide, a composite alloy of silver and copper, and silver graphite.
- the movable contact 12 includes a rectangular second base 32 that is a conductive movable piece that is operated by the peeling mechanism 2, a second contact 42 that is a movable contact, a second base 32, and a second contact 42. 2nd intermediate member 62 which is an electroconductive member provided between these.
- the same material as the material of the first metal 31 is used for the material of the second metal 32.
- FIG. 1 shows a first end surface 3A, a second end surface 3B, a third end surface 3C, a fourth end surface 3D, and a fifth end surface 3E among the six end surfaces of the second base metal 32.
- the first end surface 3A of the second base metal 32 is an end surface of the second base metal 32 on the fixed contact 11 side.
- the second end face 3 ⁇ / b> B of the second base metal 32 is an end face opposite to the fixed contact 11 side of the second base metal 32.
- the third end face 3C of the second base metal 32 is one of the two end faces in the Y-axis direction.
- the fourth end surface 3D of the second base metal 32 is the other end surface of the two end surfaces in the Y-axis direction.
- the fifth end surface 3E of the second base metal 32 is a first surface in a direction in which a normal line perpendicular to the surface including the second contact 42, the second intermediate member 62, and the second base metal 32 extends.
- the direction in which the normal line extends is equal to the Z-axis direction.
- the second base metal 32 is formed with a sixth end surface on the side opposite to the first surface side of the second base metal 32.
- a recess 300 that is recessed from the fifth end surface 3E toward the sixth end surface is provided.
- a recess similar to the recess 300 is provided on the sixth end face side of the second base metal 32.
- the second intermediate member 62 is in contact with the first end face 3A of the second base metal 32.
- a material similar to the material of the first intermediate member 61 is used as the material of the second intermediate member 62.
- the second intermediate member 62 is, for example, a surface separated by the specific gravity difference of a plurality of materials constituting the second contact 42 when the second contact 42 is manufactured. It is formed by solidifying.
- the second intermediate member 62 can be formed on the surface of the second contact 42 on the second metal base 32 side by a vacuum deposition method, a plating method, or the like, in addition to the separation by the specific gravity difference.
- the second contact 42 is fixed to the second base metal 32 via the second intermediate member 62.
- the same sintered metal as the material of the first contact 41 is used for the material of the second contact 42.
- the fixed contact 11 and the movable contact 12 thus configured are arranged in the contactor 100 so that the first contact 41 faces the second contact 42.
- the contactor 100 shown in FIG. 1 is provided with one fixed contact 11 and one movable contact 12, but the number of each of the fixed contact 11 and the movable contact 12 is limited to one. Instead, a plurality may be used according to the number of distribution lines connected to the contactor 100.
- FIG. 2 the first side surface of the second metal base 32 viewed from the fifth end surface 3 ⁇ / b> E, the cross section of the second contact 42, the second intermediate member 62 and the second metal base 32, and the second side of the second metal base 32 are shown.
- the second side surface viewed from the 6 end surface 3F is shown.
- the cross section is a cross section taken along line AA shown in FIG.
- Step part 300b and step part 301b are formed in the second base metal 32.
- the step portion 300b corresponds to a boundary portion between the bottom surface 300a of the recess 300 and the fifth end surface 3E.
- the step portion 301b corresponds to a boundary portion between the bottom surface 301a of the recess 301 and the sixth end surface 3F.
- the dimensions of the movable contact 12 are set so as to satisfy t ′ ⁇ 0.5t, b ⁇ L ′ ⁇ L, b ⁇ L ′′ ⁇ L, W ′ ⁇ W, W ′′ ⁇ W.
- T is the width of the second base metal 32 in the Z-axis direction.
- t ′ is the width in the Z-axis direction from the bottom surface 300 a of the recess 300 to the bottom surface 301 a of the recess 301.
- L is the width of the second base metal 32 in the Y-axis direction.
- L ′ is the width of the bottom surface 300 a of the recess 300 in the Y-axis direction.
- L ′′ is the width in the Y-axis direction of the bottom surface 301 a of the recess 301.
- W is the width of the second base metal 32 in the X-axis direction.
- W ′ is the width of the bottom surface 300 a of the recess 300 in the X-axis direction.
- W ′′ is the width of the bottom surface 301 a of the recess 301 in the X-axis direction.
- b is the width of the second contact 42 in the Y-axis direction.
- each part of the movable contact 12 is t ′ ⁇ 2.5 mm, 8 mm ⁇ L ′ ⁇ 100 mm, 8 mm ⁇ L ′′ ⁇ 100 mm, W ′ ⁇ 20 mm, and W ′′ ⁇ 20 mm.
- FIG. 3 is a diagram showing a manufacturing process of the movable contact 12 shown in FIG.
- FIG. 4 is a diagram showing an ultrasonic welding machine used in the manufacturing process of the movable contact 12 shown in FIG.
- FIG. 4 shows a front view of the ultrasonic welder 200 and a side view of the ultrasonic welder 200.
- step 1 the second metal base 32 and the second contact 42 are manufactured. At this time, a recess 300 and a recess 301 are formed in the second base metal 32.
- the concave portion 300 may be formed by cutting the fifth end surface 3E, or may be formed by applying pressure to the second base metal 32 by a press machine to plastically deform the fifth end surface 3E.
- the recess 301 is formed by the same method as the recess 300.
- Step 2 the second intermediate member 62 is formed on the surface of the second contact 42 on the second metal base 32 side.
- Step 3 the second metal base 32 manufactured in Step 1 is installed in the fixing portion 6b provided in the fixing base 6 of the ultrasonic welding machine 200.
- the first end face 3 ⁇ / b> A of the second base metal 32 is installed so as to face the pressing tool 8 of the ultrasonic welding machine 200.
- Step 4 by moving the two movable parts 6a provided on the fixed base 6 in the direction indicated by the arrow A, the second base metal 32 is sandwiched between the two movable parts 6a. At this time, the fixed jig 6a1 provided in one movable portion 6a enters the recess 300, and the fixed jig 6a2 provided in the other movable portion 6a enters the recess 301.
- each of the fixed jig 6a1 and the fixed jig 6a2 has a tapered shape with a tapered tip, for example.
- the fixed jig 6a1 comes into contact with the corner portion between the step portion 300b and the fifth end surface 3E, and the fixed jig 6a1 comes into contact with the corner portion between the step portion 301b and the sixth end surface 3F. Therefore, the second base metal 32 can be firmly fixed.
- step 5 the second contact 42 is installed on the second base metal 32.
- Step 6 the second contact 42 is pushed in the vertical direction from the pressing tool 8 by the pressing tool 8 of the ultrasonic welding machine 200 moving in the direction indicated by the arrow B.
- the pressure on the second contact 42 exceeds a certain value, ultrasonic vibration is applied to the second contact 42 from the pressing tool 8.
- the first end surface 3A of the second base metal 32 and the end surface of the second intermediate member 62 on the second base metal 32 side are rubbed together, and the oxide existing on these mating surfaces is destroyed to generate a new surface.
- the second contact 42 is joined to the second base metal 32 by the plastic flow of the second intermediate member 62.
- the second contact 42 can be joined to the second base metal 32 without using a metal activator such as a flux for activating the metal interface or a brazing material.
- a metal activator such as a flux for activating the metal interface or a brazing material.
- the brazing material is unnecessary, even when the ambient temperature of the first contact 41 and the second contact 42 rises to the temperature at the time of brazing due to the shut-off operation, the brazing material at the joint is directed toward the second contact 42. Therefore, the temperature resistance of the movable contact 12 is improved.
- the fixed jig 6a1 inserted into the recess 300 contacts the stepped portion 300b, and the fixed jig 6a2 inserted into the recessed portion 301 contacts the stepped portion 301b.
- the second metal base 32 can be firmly fixed. Therefore, it is possible to suppress slippage between the second base metal 32 and the fixed portion 6b without using an anvil that has been knurled as in the prior art.
- the first end surface 3A of the second base metal 32 and the end surface of the second intermediate member 62 on the second base metal 32 side can be sufficiently rubbed together, and a new surface can be generated reliably.
- the second contact 42 can be reliably bonded to the second base metal 32, and high bonding quality can be ensured.
- vibration energy is applied to the fixed jig 6a1 and the fixed jig 6a2.
- the vibration operation stops before reaching the initially set condition, and the desired joint strength may not be ensured.
- the second base metal 32 is firmly fixed by the fixed jig 6a1 and the fixed jig 6a2, vibration energy does not escape to the fixed jig 6a1 and the fixed jig 62a2, and a desired joining is achieved. Strength can be secured.
- the second base 32 is replaced each time the second base 32 is replaced.
- the fixed position of the gold 32 can be determined accurately. Accordingly, variations in manufacturing quality of the movable contact 12 are reduced.
- the first contact 41 and the second contact by using a sintered metal whose hardness is higher than the hardness of the first intermediate member 61 and the second intermediate member 62 as the material of the first contact 41 and the second contact 42, the first contact 41 and the second contact by arc. The progress of wear of the contact 42 can be minimized.
- the silver used for the second intermediate member 62 and the electric copper or oxygen-free copper used for the second base metal 32 are metals that are easy to plastically flow. Therefore, for example, when the second contact 42 is joined to the second base metal 32 by ultrasonic joining, the second intermediate member 62 and the second base metal 32 are plastically flowed to each other. The oxide present on the mating surface of the base metal 32 is easily destroyed. Furthermore, the joining strength of the second contact 42 to the second base metal 32 is improved by mixing the mating surfaces of the second intermediate member 62 and the second base metal 32.
- FIG. 5 is a configuration diagram of a second base metal according to a modification of the embodiment of the present invention.
- the number of recesses 300 formed in the fifth end surface 3E of the second base metal 32 is not limited to one, and may be two or more.
- FIG. 5 shows an example in which a concave portion 300A and a concave portion 300B are formed on the fifth end surface 3E of the second base metal 32.
- the tip shapes of the fixed jig 6a1 and the fixed jig 6a2 are shapes that can be inserted into the plurality of recesses.
- the contact areas of the fixed jig 6a1 and the fixed jig 6a2 to the stepped portions forming the plurality of recesses are increased, and the second base metal 32 can be fixed more firmly.
- the shape of the stepped portion 300b that forms the concave portion 300 may be a shape into which the fixed jig 6a1 enters, and may be a polygon other than a square or a circle.
- the shape of the stepped portion 301b that forms the recess 301 is the same.
- the shape of the recess 300 may be the same as or different from the shape of the recess 301.
- the fixed jig contacts the stepped portion as compared with the case where the shape of each of the stepped portion 300b and the stepped portion 301b is a square. The area is increased, and the first base metal 31 or the second base metal 32 can be firmly fixed.
- the shapes of the first base metal 31 and the second base metal 32 are not limited to a square shape, as long as the recesses 300A and the recesses 300B are formed, may be elliptical when viewed from the Z-axis direction, or may be in the Z-axis direction. From the perspective, it may be L-shaped.
- the concave portions are provided on both the fifth end surface and the sixth end surface of the base metal.
- a concave portion is provided on either the fifth end surface or the sixth end surface of the base metal. It may be provided.
- the fixing jig can be fitted into the concave portion, and the base metal is processed as compared with the case where the concave portion is provided on both the fifth end surface and the sixth end surface of the base metal. Can be shortened.
- the position of the concave portion on the fifth end surface or the sixth end surface of the base metal is not limited to the illustrated example, but the second contact 42 is projected toward the second base metal 32 as shown in FIG. It is desirable to provide it at a position that overlaps the region and can fix the base metal with a fixing jig.
- the concave portion By providing the concave portion at such a position, the distance from the second contact 42 to the fixed jig is shortened, and the vibration of the second metal base 32 when the vibration is applied can be suppressed. Therefore, the plastic flow of the second intermediate member 62 is performed in a short time, and the bonding strength can be increased.
- the configuration described in the above embodiment shows an example of the contents of the present invention, and can be combined with another known technique, and can be combined with other configurations without departing from the gist of the present invention. It is also possible to omit or change the part.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Switches (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Contacts (AREA)
Abstract
Description
図1は本発明の実施の形態に係る接触子の構成を示す図である。図2は図1に示す可動接触子の構成の詳細を示す図である。 Embodiment.
FIG. 1 is a diagram showing a configuration of a contact according to an embodiment of the present invention. FIG. 2 is a diagram showing details of the configuration of the movable contact shown in FIG.
Claims (8)
- 台金と、
前記台金に固定される接点と、
前記台金と前記接点との間に設けられ、硬度が前記接点の硬度より低く塑性流動が可能な導電性部材と、
を備え、
前記台金の外周面には、前記台金と前記導電性部材と前記接点との配列方向に垂直な方向に窪み、超音波溶接機の可動部に設けられるジグが嵌る凹部が形成されることを特徴とする接触子。 With the base metal,
A contact fixed to the base;
A conductive member provided between the base metal and the contact and having a hardness lower than the hardness of the contact and capable of plastic flow;
With
On the outer peripheral surface of the base metal, a recess is formed that is recessed in a direction perpendicular to the arrangement direction of the base metal, the conductive member, and the contact, and into which a jig provided in the movable part of the ultrasonic welding machine is fitted. A contactor characterized by. - 前記外周面には前記凹部が複数形成されることを特徴とする請求項1に記載の接触子。 The contactor according to claim 1, wherein a plurality of the recesses are formed on the outer peripheral surface.
- 前記凹部を形作る段差部の形状は四角以上の多角形であることを特徴とする請求項1又は2に記載の接触子。 The contactor according to claim 1 or 2, wherein a shape of the stepped portion forming the concave portion is a polygon of four or more squares.
- 前記接点の材料は焼結金属であり、
前記台金の材料は電気銅又は無酸素銅であり、
前記導電性部材は銀であることを特徴とする請求項1から3の何れか一項に記載の接触子。 The material of the contact is a sintered metal,
The material of the base metal is electrolytic copper or oxygen-free copper,
The contact according to any one of claims 1 to 3, wherein the conductive member is silver. - 前記凹部は、前記接点を前記台金に向かって投影してなる領域と重なる位置に設けられることを特徴とする請求項1から4の何れか一項に記載の接触子。 The contact according to any one of claims 1 to 4, wherein the concave portion is provided at a position overlapping with a region formed by projecting the contact toward the base metal.
- 超音波溶接機の可動部に設けられるジグが嵌る凹部が外周面に形成される台金を製造する工程と、
前記台金に固定される接点を製造する工程と、
硬度が前記接点の硬度より低く塑性流動が可能な導電性部材を前記接点に形成する工程と、
前記超音波溶接機の固定台に前記台金を設置する工程と、
前記固定台に設置された前記台金に形成される前記凹部に前記ジグを挿入する工程と、
前記台金に前記接点を設置する工程と、
前記超音波溶接機の加圧工具から前記接点に超音波振動を加える工程と、
を含むことを特徴とする接触子の製造方法。 A step of manufacturing a base metal in which a recess into which a jig provided in a movable part of an ultrasonic welding machine is fitted is formed on the outer peripheral surface;
Producing a contact fixed to the base metal;
Forming a conductive member on the contact having a hardness lower than that of the contact and capable of plastic flow;
Installing the base on a fixed base of the ultrasonic welder;
Inserting the jig into the recess formed in the base placed on the fixed base;
Installing the contacts on the base;
Applying ultrasonic vibration from the pressure tool of the ultrasonic welder to the contact;
The manufacturing method of the contactor characterized by including. - 前記台金を製造する工程では、前記台金の材料に電気銅又は無酸素銅が利用され、
前記接点を製造する工程では、前記接点の材料に焼結金属が利用され、
前記導電性部材を前記接点に形成する工程では、前記導電性部材の材料に銀が利用されることを特徴とする請求項6に記載の接触子の製造方法。 In the step of manufacturing the base metal, electrolytic copper or oxygen-free copper is used as a material of the base metal,
In the step of manufacturing the contact, sintered metal is used as the material of the contact,
The method of manufacturing a contact according to claim 6, wherein silver is used as a material of the conductive member in the step of forming the conductive member at the contact point. - 前記台金を製造する工程では、前記接点を前記台金に向かって投影してなる領域と重なる位置に前記凹部が設けられることを特徴とする請求項6又は7に記載の接触子の製造方法。 The method of manufacturing a contact according to claim 6 or 7, wherein, in the step of manufacturing the base metal, the concave portion is provided at a position overlapping a region formed by projecting the contact point toward the base metal. .
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KR1020207026115A KR102420675B1 (en) | 2018-03-20 | 2019-03-06 | Contactor and method for manufacturing the contactor |
CN201980019379.1A CN111868865B (en) | 2018-03-20 | 2019-03-06 | Contact and method for manufacturing contact |
JP2020508171A JP6952872B2 (en) | 2018-03-20 | 2019-03-06 | Contactor and manufacturing method of contactor |
TW108109044A TWI705865B (en) | 2018-03-20 | 2019-03-18 | Contactor and contactor manufacturing method |
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2019
- 2019-03-06 WO PCT/JP2019/008888 patent/WO2019181511A1/en active Application Filing
- 2019-03-06 KR KR1020207026115A patent/KR102420675B1/en active IP Right Grant
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JPS4920902B1 (en) * | 1966-11-04 | 1974-05-28 | ||
JPS5776703A (en) * | 1980-10-30 | 1982-05-13 | Tokyo Shibaura Electric Co | Electric contactor |
JPH1147956A (en) * | 1997-08-04 | 1999-02-23 | Showa Alum Corp | Ultrasonic joining method of metal container |
JP2016072305A (en) * | 2014-09-26 | 2016-05-09 | 富士電機株式会社 | Semiconductor device manufacturing apparatus and semiconductor device |
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TWI705865B (en) | 2020-10-01 |
CN111868865B (en) | 2022-11-15 |
KR102420675B1 (en) | 2022-07-13 |
JP6952872B2 (en) | 2021-10-27 |
KR20200119300A (en) | 2020-10-19 |
JPWO2019181511A1 (en) | 2020-12-03 |
TW201940271A (en) | 2019-10-16 |
CN111868865A (en) | 2020-10-30 |
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