WO2019115511A1 - Mélange fongicide comprenant des 3-phényl-5-(trifluorométhyl)-1,2,4-oxadiazoles substitués - Google Patents

Mélange fongicide comprenant des 3-phényl-5-(trifluorométhyl)-1,2,4-oxadiazoles substitués Download PDF

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Publication number
WO2019115511A1
WO2019115511A1 PCT/EP2018/084317 EP2018084317W WO2019115511A1 WO 2019115511 A1 WO2019115511 A1 WO 2019115511A1 EP 2018084317 W EP2018084317 W EP 2018084317W WO 2019115511 A1 WO2019115511 A1 WO 2019115511A1
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WIPO (PCT)
Prior art keywords
methyl
phenyl
chloro
ethyl
carboxamide
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PCT/EP2018/084317
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English (en)
Inventor
Maria Angelica QUINTERO PALOMAR
Violeta TERTERYAN-SEISER
Wassilios Grammenos
Christine WIEBE
Jurith Montag
Mikael COQUILLER
Torsten Neumann
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Basf Se
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Publication of WO2019115511A1 publication Critical patent/WO2019115511A1/fr

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms

Definitions

  • the present invention relates to a fungicidal mixture comprising, as active components
  • Y is O or S
  • R 1 is cyclopropyl; and wherein the cyclopropyl group is substituted with 1 , 2, 3 or up to the maximum possible number of identical or different groups R 1a ; wherein
  • R 1 is a radical
  • # denotes the position, which is bound to the group -NR 2 -;
  • R is halogen
  • R 1b is independently selected from the group consisting of halogen, cyano, NO2, OH, SH, NH2, diCi-C 6 -alkylamino, Ci-C 6 -alkyl, Ci-C 6 -alkoxy, Ci-C 6 -alkylthio, C1-C6- alkylsulfinyl, Ci-C 6 -alkylsulfonyl, C2-C6-alkenyl, C2-C6-alkynyl, C 3 -C 8 -cycloalkyl and Cs-Cs-cycloalkoxy;
  • n 0, 1 or 2;
  • R 2 is hydrogen, Ci-C 6 -alkyl, C2-C6-alkenyl, C2-C6-alkynyl, Ci-C 6 -alkoxy, Cs-Cs-cycloalkyl, C 3 -Cs-cycloalkenyl, and C 3 -C8-cycloalkyl-Ci-C4-alkyl; and wherein any of the aliphatic or cyclic groups are unsubstituted or substituted with 1 , 2, 3 or up to the maximum possible number of identical or different radicals selected from the group consisting of halogen, hydroxy, oxo, cyano, Ci-C 6 -alkyl, Ci-C 6 -alkoxy and C 3 -C 8 -cycloalkyl;
  • Inhibitors of complex III at Q 0 site azoxystrobin (A.1 .1 ), coumethoxystrobin (A.1 .2), coumoxystrobin (A.1.3), dimoxystrobin (A.1 .4), enestroburin (A.1 .5), fenaminstrobin (A.1.6), fenoxystrobin/flufenoxystrobin (A.1 .7), fluoxastrobin (A.1 .8), kresoxim-methyl (A.1.9), mande- strobin (A.1 .10), metominostrobin (A.1 .1 1 ), orysastrobin (A.1 .12), picoxystrobin (A.1.13), pyra- clostrobin (A.1 .14), pyrametostrobin (A.1 .15), pyraoxystrobin (A.1.16), trifloxystrobin (A.1.17), 2-(2-(3-(2,
  • Inhibitors of complex III at Q, site cyazofamid (A.2.1 ), amisulbrom (A.2.2),
  • Inhibitors of complex II benodanil (A.3.1 ), benzovindiflupyr (A.3.2), bixafen (A.3.3), boscalid (A.3.4), carboxin (A.3.5), fenfuram (A.3.6), fluopyram (A.3.7), flutolanil (A.3.8), fluxapyroxad (A.3.9), furametpyr (A.3.10), isofetamid (A.3.1 1 ), isopyrazam (A.3.12), mepronil (A.3.13), ox- ycarboxin (A.3.14), penflufen (A.3.15), penthiopyrad (A.3.16), pydiflumetofen (A.3.17), N-[2- (3,4-difluorophenyl)phenyl]-3-(trifluoromethyl)pyrazine-2-carboxamide (A.3.18), sedaxane (A.3.19), tecloftalam (A
  • respiration inhibitors diflumetorim (A.4.1 ); nitrophenyl derivates: binapacryl (A.4.2), dinobuton (A.4.3), dinocap (A.4.4), fluazinam (A.4.5), meptyldinocap (A.4.6), ferimzone (A.4.7); organometal compounds: fentin salts, e. g. fentin-acetate (A.4.8), fentin chloride (A.4.9) or fentin hydroxide (A.4.10); ametoctradin (A.4.11 ); silthiofam (A.4.12).
  • fentin salts e. g. fentin-acetate (A.4.8), fentin chloride (A.4.9) or fentin hydroxide (A.4.10)
  • ametoctradin A.4.11
  • silthiofam A.4.12).
  • C14 demethylase inhibitors triazoles: azaconazole (B.1.1), bitertanol (B.1.2), bromuconazole (B.1.3), cyproconazole (B.1.4), difenoconazole (B.1.5), diniconazole (B.1.6), diniconazole-M (B.1.7), epoxiconazole (B.1.8), fenbuconazole (B.1.9), fluquinconazole (B.1.10), flusilazole (B.1.11 ), flutriafol (B.1.12), hexaconazole (B.1.13), imibenconazole (B.1.14), ipconazole (B.1.15), metconazole (B.1.17), myclobutanil (B.1.18), oxpoconazole (B.1.19), paclobutrazole (B.1.20), penconazole (B.1.21), propiconazole (B.1.2
  • Deltal 4-reductase inhibitors aldimorph (B.2.1 ), dodemorph (B.2.2), dodemorph-acetate (B.2.3), fenpropimorph (B.2.4), tridemorph (B.2.5), fenpropidin (B.2.6), piperalin (B.2.7), spi- roxamine (B.2.8).
  • Inhibitors of 3-keto reductase fenhexamid (B.3.1 ).
  • Sterol biosynthesis inhibitors chlorphenomizole (B.4.1 ).
  • Phenylamides or acyl amino acid fungicides benalaxyl (C.1.1 ), benalaxyl-M (C.1.2), kiralaxyl (C.1.3), metalaxyl (C.1.4), metalaxyl-M (C.1.5), ofurace (C.1.6), oxadixyl (C.1.7).
  • nucleic acid synthesis inhibitors hymexazole (C.2.1), octhilinone (C.2.2), oxolinic acid (C.2.3), bupirimate (C.2.4), 5-fluorocytosine (C.2.5), 5-fluoro-2-(p-tolylmethoxy)pyrimidin- 4-amine (C.2.6), 5-fluoro-2-(4-fluorophenylmethoxy)pyrimidin-4-amine (C.2.7), 5-fluoro- 2-(4-chlorophenylmethoxy)pyrimidin-4 amine (C.2.8).
  • Tubulin inhibitors benomyl (D.1.1), carbendazim (D.1.2), fuberidazole (D1.3), thiabendazole (D.1.4), thiophanate-methyl (D.1.5), 3-chloro-4-(2,6-difluorophenyl)-6-methyl-5-phenyl-pyrida- zine (D.1.6), 3-chloro-6-methyl-5-phenyl-4-(2,4,6-trifluorophenyl)pyridazine (D.1.7), N-ethyl-2- [(3-ethynyl-8-methyl-6-quinolyl)oxy]butanamide (D.1.8), N-ethyl-2-[(3-ethynyl-8-methyl- 6-quinolyl)oxy]-2-methylsulfanyl-acetamide (D.1.9), 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]- N-(2-fluoroethyl)butan
  • diethofencarb (D.2.1), ethaboxam (D.2.2), pencycuron (D.2.3), fluopicolide (D.2.4), zoxamide (D.2.5), metrafenone (D.2.6), pyriofenone (D.2.7).
  • Methionine synthesis inhibitors cyprodinil (E.1.1), mepanipyrim (E.1.2), pyrimethanil (E.1.3).
  • Protein synthesis inhibitors blasticidin-S (E.2.1 ), kasugamycin (E.2.2), kasugamycin hydro- chloride-hydrate (E.2.3), mildiomycin (E.2.4), streptomycin (E.2.5), oxytetracyclin (E.2.6).
  • MAP / histidine kinase inhibitors fluoroimid (F.1.1 ), iprodione (F.1.2), procymidone (F.1.3), vinclozolin (F.1.4), fludioxonil (F.1.5).
  • G protein inhibitors quinoxyfen (F.2.1 ).
  • G Lipid and membrane synthesis inhibitors Phospholipid biosynthesis inhibitors: edifenphos (G .1.1), iprobenfos (G.1 .2), pyrazophos (G.1.3), isoprothiolane (G.1 .4).
  • Lipid peroxidation dicloran (G.2.1 ), quintozene (G.2.2), tecnazene (G.2.3), tolclofos-methyl (G.2.4), biphenyl (G.2.5), chloroneb (G.2.6), etridiazole (G.2.7).
  • Phospholipid biosynthesis and cell wall deposition dimethomorph (G.3.1 ), flumorph (G.3.2), mandipropamid (G.3.3), pyrimorph (G.3.4), benthiavalicarb (G.3.5), iprovalicarb (G.3.6), valifenalate (G.3.7).
  • Inhibitors of oxysterol binding protein oxathiapiprolin (G.5.1 ), 2- ⁇ 3-[2-(1 - ⁇ [3,5-bis(difluoro- methyl-1 H-pyrazol-1 -yl]acetyl ⁇ piperidin-4-yl)-1 ,3-thiazol-4-yl]-4,5-dihydro-1 ,2-oxazol-5-yl ⁇ - phenyl methanesulfonate (G.5.2), 2- ⁇ 3-[2-(1 - ⁇ [3, 5-bis(difluoromethyl)-1 H-pyrazol-1 -yl]- acetyl ⁇ piperidin-4-yl) 1 ,3-thiazol-4-yl]-4,5-dihyd ro-1 ,2-oxazol-5-yl ⁇ -3-chlorophenyl methane- sulfonate (G.5.3), 4-[1 -[2-[3-(difluoromethyl)
  • Inorganic active substances Bordeaux mixture (H.1 .1 ), copper (H.1.2), copper acetate (H.1 .3), copper hydroxide (H.1.4), copper oxychloride (H.1 .5), basic copper sulfate (H.1 .6), sulfur (H.1 .7).
  • Organochlorine compounds anilazine (H.3.1 ), chlorothalonil (H.3.2), captafol (H.3.3), captan (H.3.4), folpet (H.3.5), dichlofluanid (H.3.6), dichlorophen (H.3.7), hexachlorobenzene (H.3.8), pentachlorphenole (H.3.9) and its salts, phthalide (H.3.10), tolylfluanid (H.3.1 1 ).
  • Guanidines and others guanidine (H.4.1 ), dodine (H.4.2), dodine free base (H.4.3), guazatine (H.4.4), guazatine-acetate (H.4.5), iminoctadine (H.4.6), iminoctadine-triacetate (H.4.7), iminoctadine-tris(albesilate) (H.4.8), dithianon (H.4.9), 2,6-dimethyl-1 H,5H-[1 ,4]dithiino[2,3- c:5,6-c']dipyrrole-1 ,3,5,7(2H,6H)-tetraone (H.4.10).
  • Inhibitors of glucan synthesis validamycin (1.1.1 ), polyoxin B (1.1 .2). Melanin synthesis inhibitors: pyroquilon (1.2.1), tricyclazole (1.2.2), carpropamid (1.2.3), dicy- clomet (1.2.4), fenoxanil (I.2.5).
  • Bronopol (K.1.1 ), chinomethionat (K.1.2), cyflufenamid (K.1.3), cymoxanil (K.1.4), dazomet (K.1.5), debacarb (K.1.6), diclocymet (K.1.7), diclomezine (K.1.8), difenzoquat (K.1.9), di- fenzoquat-methylsulfate (K.1.10), diphenylamin (K.1.11 ), fenitropan (K.1.12), fenpyrazamine (K.1.13), flumetover (K.1.14), flusulfamide (K.1.15), flutianil (K.1.16), harpin (K.1.17), metha- sulfocarb (K.1.18), nitrapyrin (K.1.19), nitrothal-isopropyl (K.1.20), tolprocarb (K.1.21 ), oxin- copper (K.1.2
  • abscisic acid (M.1.1 ), amidochlor, ancymidol, 6-benzylaminopurine, brassinolide, butralin, chlormequat, chlormequat chloride, choline chloride, cyclanilide, daminozide, dikegulac, dime- thipin, 2,6-dimethylpuridine, ethephon, flumetralin, flurprimidol, fluthiacet, forchlorfenuron, gib- berellic acid, inabenfide, indole-3-acetic acid , maleic hydrazide, mefluidide, mepiquat, mepi- quat chloride, naphthaleneacetic acid, N-6-benzyladenine, paclobutrazol, prohexadione, pro- hexadione-calcium, prohydrojasmon, thidiazuron, triapenthenol, tributyl phosphorotrith
  • N.1 Lipid biosynthesis inhibitors alloxydim (N.1.1 ), alloxydim-sodium (N.1.2), butroxydim (N.1.3), clethodim (N.1.4), clodinafop (N.1.5), clodinafop-propargyl (N.1.6), cycloxydim (N.1.7), cyhalofop (N.1.8), cyhalofop-butyl (N.1.9), diclofop(N.1.10), diclofop-methyl (N.1.1 1), fenoxa- prop (N.1.12), fenoxaprop-ethyl (N.1.13), fenoxaprop-P (N.1.14), fenoxaprop-P-ethyl (N.1.15), fluazifop (N.1.16), fluazifop-butyl (N.1.17), fluazifop-P (N.1.18), fluazifo
  • N.1.27 quizalofop (N.1.28), quizalofop-ethyl (N.1.29), quizalofop-tefuryl (N.1.30), quizalofop- P (N.1.31 ), quizalofop-P-ethyl (N.1.32), quizalofop-P-tefuryl (N.1.33), sethoxydim (N.1.34), tepraloxydim (N.1.35), tralkoxydim (N.1.36), 4-(4'-chloro-4-cyclo ⁇ , propyl-2'-fluoro[1 ,1 '- biphenyl]-3-yl)-5-hydroxy-2,2,6,6-tetramethyl-2H-pyran-3(6H)-one ((N.1.37) CAS 1312337-72- 6); 4-(2',4'-dichloro-4-cyclopropyl[1 ,1 '-biphenyl]-3
  • N.1.57 molinate (N.1.58), orbencarb (N.1.59), pebulate (N.1.60), prosulfocarb (N.1.61), TCA (N.1.62), thiobencarb (N.1.63), tiocarbazil (N.1.64), triallate (N.1.65) and vernolate (N.1.66);
  • N.2 ALS inhibitors amidosulfuron (N.2.1 ), azimsulfuron (N.2.2), bensulfuron (N.2.3), bensul- furon-methyl (N.2.4), chlohmuron (N.2.5), chlorimuron-ethyl (N.2.6), chlorsulfuron (N.2.7), cinosulfuron (N.2.8), cyclosulfamuron (N.2.9), ethametsulfuron (N.2.10), ethametsulfuron- methyl (N.2.1 1), ethoxysulfuron (N.2.12), flazasulfuron (N.2.13), flucetosulfuron (N.2.14), flupyrsulfuron (N.2.15), flupyrsulfuron-methyl-sodium (N.2.16), foramsulfuron (N.2.17), halosul- furon (N.2.18), halosulfuron-methyl (N.2.19),
  • N.3 Photosynthesis inhibitors amicarbazone (N.3.1); chlorotriazine (N.3.2); ametryn (N.3.3), atrazine (N.3.4), chloridazone (N.3.5), cyanazine (N.3.6), desmetryn (N.3.7), dimethametryn (N.3.8),hexazinone (N.3.9), metribuzin (N.3.10), prometon (N.3.11 ), prometryn (N.3.12), pro- pazine (N.3.13), simazine (N.3.14), simetryn (N.3.15), terbumeton (N.3.16), terbuthylazin (N.3.17), terbutryn (N.3.18), trietazin (N.3.19); chlorobromuron (N.3.20), chlorotoluron
  • N.3.21 chloroxuron (N.3.22), dimefuron (N.3.23), diuron (N.3.24), fluometuron (N.3.25), iso- proturon (N.3.26), isouron (N.3.27), linuron (N.3.28), metamitron (N.3.29), methabenzthiazuron (N.3.30), metobenzuron (N.3.31 ), metoxuron (N.3.32), monolinuron (N.3.33), neburon
  • N.3.34 siduron (N.3.35), tebuthiuron (N.3.36), thiadiazuron (N.3.37), desmedipham (N.3.38), karbutilat (N.3.39), phenmedipham (N.3.40), phenmedipham-ethyl (N.3.41 ), bromofenoxim (N.3.42), bromoxynil (N.3.43) and its salts and esters, ioxynil (N.3.44) and its salts and esters, bromacil (N.3.45), lenacil (N.3.46), terbacil (N.3.47), bentazon (N.3.48), bentazon-sodium (N.3.49), pyridate (N.3.50), pyridafol (N.3.51 ), pentanochlor (N.3.52), propanil (N.3.53); diquat (N.3.54), diquat-dibromide (N.3.55)
  • N.4 protoporphyrinogen-IX oxidase inhibitors acifluorfen (N.4.1 ), acifluorfen-sodium (N.4.2), azafenidin (N.4.3), bencarbazone (N.4.4), benzfendizone (N.4.5), bifenox (N.4.6), butafenacil (N.4.7), carfentrazone (N.4.8), carfentrazone-ethyl (N.4.9), chlormethoxyfen (N.4.10), cinidon- ethyl (N.4.1 1 ), fluazolate (N.4.12), flufenpyr (N.4.13), flufenpyr-ethyl (N.4.14), flumiclorac (N.4.15), flumiclorac-pentyl (N.4.16), flumioxazin (N.4.17), fluoroglycofen (N.4.18), fluorogly- cofen-ethyl (
  • N.5 Bleacher herbicides beflubutamid (N.5.1 ), diflufenican (N.5.2), fluridone (N.5.3), flurochlo- ridone (N.5.4), flurtamone (N.5.5), norflurazon (N.5.6), picolinafen (N.5.7), 4-(3- trifluoromethyhphenoxy)-2-(4-trifluoromethylphenyl) _, pyrimidine ((N.5.8) CAS 180608-33-7); benzobicyclon (N.5.9), benzofenap (N.5.10), bicyclopyrone (N.5.1 1 ), clomazone (N.5.12), fenquintrione (N.5.13), isoxaflutole (N.5.14), mesotrione (N.5.15), pyrasulfotole (N.5.16), pyra- zolynate (N.5.17), pyrazoxyfen (N.5.18),
  • N.6 EPSP synthase inhibitors glyphosate (N.6.1 ), glyphosate-isopropylammonium (N.6.2), glyposate-potassium (N.6.3), glyphosate-trimesium (sulfosate) (N.6.4); N.7 Glutamine synthase inhibitors: bilanaphos (bialaphos) (N.7.1 ), bilanaphos-sodium (N.7.2), glufosinate (N.7.3), glufosinate-P (N.7.4), glufosinate-ammonium (N.7.5);
  • N.8 DHP synthase inhibitors asulam (N.8.1 );
  • Mitosis inhibitors benfluralin (N.9.1 ), butralin (N.9.2), dinitramine (N.9.3), ethalfluralin (N.9.4), fluchloralin (N.9.5), oryzalin (N.9.6), pendimethalin (N.9.7), prodiamine (N.9.8), triflu- ralin (N.9.9); amiprophos (N.9.10), amiprophos-methyl (N.9.1 1 ), butamiphos (N.9.12); chlorthal (N.9.13), chlorthal-dimethyl (N.9.14), dithiopyr (N.9.15), thiazopyr (N.9.16), propyzamide (N.9.17), tebutam (N.9.18); carbetamide (N.9.19), chlorpropham (N.9.20), flamprop (N.9.21 ), flamprop-isopropyl (N.9.22), flamprop-methyl (N.9.9.
  • N.10 VLCFA inhibitors acetochlor (N.10.1 ), alachlor (N.10.2), butachlor (N.10.3), dimethachlor (N.10.4), dimethenamid (N.10.5), dimethenamid-P (N.10.6), metazachlor (N.10.7), metolachlor (N.10.8), metolachlor-S (N.10.9), pethoxamid (N.10.10), pretilachlor (N.10.1 1 ), propachlor (N.10.12), propisochlor (N.10.13), thenylchlor (N.10.14), flufenacet (N.10.15), mefenacet (N.10.16), diphenamid (N.10.17), naproanilide (N.10.18), napropamide (N.10.19), napro- pamide-M (N.10.20), fentrazamide (N.10.21 ), anilofos (N.10.22),
  • N.1 1 Cellulose biosynthesis inhibitors: chlorthiamid (N.1 1 .1 ), dichlobenil (N.1 1 .2), flupoxam (N.1 1.3), indaziflam (N.1 1.4), isoxaben (N.1 1 .5), triaziflam (N.1 1.6), 1 -cyclohexyl-5- pentafluorphenyloxy-14-[1 ,2,4,6]thiatriazin-3-ylamine ((N.1 1 .7) CAS 175899-01 -1 );
  • N.12 Decoupler herbicides: dinoseb (N.12.1 ), dinoterb (N.12.2), DNOC (N.12.3) and its salts;
  • N.13 Auxinic herbicides 2,4-D (N.13.1 ) and its salts and esters, clacyfos (N.13.2), 2,4-DB (N.13.3) and its salts and esters, aminocyclopyrachlor (N.13.4) and its salts and esters, ami- nopyralid (N.13.5) and its salts such as aminopyralid-dimethylammonium (N.13.6), aminopyra- lid-tris(2-hydroxypropyl)ammonium (N.13.7) and its esters, benazolin (N.13.8), benazolin-ethyl (N.13.9), chloramben (N.13.10) and its salts and esters, clomeprop (N.13.1 1 ), clopyralid (N.13.12) and its salts and esters, dicamba (N.13.13) and its salts and esters, dichlorprop (N.13.14)
  • N.14 Auxin transport inhibitors diflufenzopyr (N.14.1 ), diflufenzopyr-sodium (N.14.2), naptalam (N.14.3) and naptalam-sodium (N.14.4);
  • N.15 Other herbicides: bromobutide (N.15.1 ), chlorflurenol (N.15.2), chlorflurenol-methyl (N.15.3), cinmethylin (N.15.4), cumyluron (N.15.5), cyclopyrimorate ((N.15.6) CAS 499223-49- 3) and its salts and esters, dalapon (N.15.7), dazomet (N.15.8), difenzoquat (N.15.9), difen- zoquat-metilsulfate (N.15.10), dimethipin (N.15.1 1 ), DSMA (N.15.12), dymron (N.15.13), endo- thal (N.15.14) and its salts, etobenzanid (N.15.15), flurenol (N.15.16), flurenol-butyl (N.15.17), flurpri
  • N.15.21 maleic hydrazide (N.15.22), mefluidide (N.15.23), metam (N.15.24), methiozolin ((N.15.25) CAS 403640-27-7), methyl azide (N.15.26), methyl bromide (N.15.27), methyl- dymron (N.15.28), methyl iodide (N.15.29), MSMA (N.15.30), oleic acid (N.15.31 ), oxaziclome- fone (N.15.32), pelargonic acid (N.15.33), pyributicarb (N.15.34), quinoclamine (N.15.35), tri- diphane (N.15.36);
  • Acetylcholine esterase (AChE) inhibitors aldicarb (0.1.1 ), alanycarb (0.1 .2), bendiocarb (0.1.3), benfuracarb (0.1.4), butocarboxim (0.1.5), butoxycarboxim (0.1.6), carbaryl (0.1 .7), carbofuran (0.1.8), carbosulfan (0.1.9), ethiofencarb (0.1 .10), fenobucarb (0.1 .1 1 ), formetan- ate (0.1 .12), furathiocarb (0.1.13), isoprocarb (0.1.14), methiocarb (0.1 .15), methomyl (0.1.16), metolcarb (0.1.17), oxamyl (0.1.18), pirimicarb (0.1 .19), propoxur (0.1.20), thiodi- carb (0.1.21 ), thiofanox (AChE) inhibitors: aldicarb (0.1.1 ),
  • methamidophos 0.1.61
  • methidathion 0.1 .62
  • mevinphos 0.1.63
  • GABA-gated chloride channel antagonists endosulfan (0.2.1 ), chlordane (0.2.2);
  • ethiprole (0.2.3), fipronil (0.2.4), flufiprole (0.2.5), pyrafluprole (0.2.6), pyriprole (0.2.7);
  • Nicotinic acetylcholine receptor agonists acetamiprid (0.4.1 ), clothianidin (0.4.2), cycloxaprid (0.4.3), dinotefuran (0.4.4), imidacloprid (0.4.5), nitenpyram (0.4.6), thia- cloprid (0.4.7), thiamethoxam (0.4.8); (2E)-1-[(6-chloropyridin-3-yl)methyl]-N'-nitro-2- pentylidenehydrazinecarboximidamide (0.4.9); 1-[(6-chloropyridin-3-yl)methyl]-7-methyl-8- nitro-5-propoxy-1 ,2,3,5,6,7-hexahydroimidazo[1 ,2-a]pyridine (0.4.10); nicotine (0.4.11 );
  • Nicotinic acetylcholine receptor allosteric activators spinosad (0.5.1 ), spinetoram (0.5.2);
  • Chloride channel activators abamectin (0.6.1 ), emamectin benzoate (0.6.2), ivermectin (0.6.3), lepimectin (0.6.4), milbemectin (0.6.5);
  • 0.8 miscellaneous non-specific (multi-site) inhibitors methyl bromide (0.8.1 ) and other alkyl halides; chloropicrin (0.8.2), sulfuryl fluoride (0.8.3), borax (0.8.4), tartar emetic (0.8.5);
  • Mite growth inhibitors clofentezine (0.10.1 ), hexythiazox (0.10.2), diflovidazin (0.10.3); etoxazole (0.10.4);
  • 0.1 1 Microbial disruptors of insect midgut membranes the Bt crop proteins: CrylAb, Cry1 Ac, Cryl Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1 ;
  • Inhibitors of mitochondrial ATP synthase diafenthiuron (0.12.1 ); azocyclotin (0.12.2), cyhexatin (0.12.3), fenbutatin oxide (0.12.4), propargite (0.12.5), tetradifon (0.12.6);
  • chlorfenapyr (0.13.1), DNOC (0.13.2), sulfluramid (0.13.3);
  • Nicotinic acetylcholine receptor (nAChR) channel blockers bensultap (0.14.1 ), cartap hydrochloride (0.14.2), thiocyclam (0.14.3), thiosultap sodium (0.14.4);
  • Inhibitors of the chitin biosynthesis type 0 bistrifluron (0.15.1 ), chlorfluazuron (0.15.2), diflubenzuron (0.15.3), flucycloxuron (0.15.4), flufenoxuron (0.15.5), hexaflumuron (0.15.6), lufenuron (0.15.7), novaluron (0.15.8), noviflumuron (0.15.9), teflubenzuron (0.15.10), tri- flumuron (0.15.11 );
  • Inhibitors of the chitin biosynthesis type 1 buprofezin (0.16.1);
  • Ecdyson receptor agonists methoxyfenozide (0.18.1), tebufenozide (0.18.2), halofeno- zide (0.18.3), fufenozide (0.18.4), chromafenozide (0.18.5);
  • Octopamin receptor agonists amitraz (0.19.1 );
  • Mitochondrial complex III electron transport inhibitors hydramethylnon (0.20.1 ), acequi- nocyl (0.20.2), fluacrypyrim (0.20.3);
  • Mitochondrial complex I electron transport inhibitors fenazaquin (0.21.1), fenpyroximate (0.21.2), pyrimidifen (0.21.3), pyridaben (0.21.4), tebufenpyrad (0.21.5), tolfenpyrad
  • Inhibitors of the of acetyl CoA carboxylase spirodiclofen (0.23.1 ), spiromesifen (0.23.2), spirotetramat (0.23.3);
  • Mitochondrial complex IV electron transport inhibitors aluminium phosphide (0.24.1 ), calcium phosphide (0.24.2), phosphine (0.24.3), zinc phosphide (0.24.4), cyanide (0.24.5);
  • insecticidal active compounds of unknown or uncertain mode of action afidopyropen (0.27.1 ), afoxolaner (0.27.2), azadirachtin (0.27.3), amidoflumet (0.27.4), benzoximate (0.27.5), bifenazate (0.27.6), broflanilide (0.27.7), bromopropylate (0.27.8), chinomethionat (0.27.9), cryolite (0.27.10), dicloromezotiaz (0.27.11 ), dicofol (0.27.12), flufenerim (0.27.13), flometoquin (0.27.14), fluensulfone (0.27.15), fluhexafon (0.27.16), fluopyram (0.27.17), flupyradifurone (0.27.18), fluralaner (0.27.19), metoxadiazone (0.27.20), piperonyl butoxide (0.27.21 ), pyflubumide (0.27.1
  • the invention also relates to a method for controlling phytopathogenic harmful fungi using mix- tures comprising as component 1 ) at least one compound of the formula I and as component 2) at least one compound II; to the use of mixtures comprising compounds I and compounds II for controlling phytopathogenic harmful fungi; to agrochemical compositions comprising these mix- tures; and to agrochemical compositions further comprising seed.
  • mixtures of different active corn- pounds are conventionally employed for controlling harmful fungi.
  • active corn- pounds having different mechanisms of action, it is possible to ensure successful control over a relatively long period of time.
  • compositions comprising at least one compound I and at least one compound II.
  • halogen refers to fluorine, chlorine, bromine and iodine.
  • Ci-C 6 -alkyl refers to a straight-chained or branched saturated hydrocarbon group having 1 to 6 carbon atoms, for example methyl, ethyl, propyl, 1 -methylethyl, butyl, 1 - methylpropyl, 2-methylpropyl, and 1 ,1 -dimethylethyl.
  • C2-C6-alkenyl refers to a straight-chain or branched unsaturated hydrocarbon radical having 2 to 6 carbon atoms and a double bond in any position, such as ethenyl, 1 -propenyl, 2- propenyl (allyl), 1 -methylethenyl, 1 -butenyl, 2-butenyl, 3-butenyl, 1 -methyl-1 -propenyl, 2-methyl-
  • C2-C6-alkynyl refers to a straight-chain or branched unsaturated hydrocarbon radical having 2 to 6 carbon atoms and containing at least one triple bond, such as ethynyl, 1 -propynyl,
  • Ci-C 6 -haloalkyl refers to a straight-chained or branched alkyl group having 1 to 6 carbon atoms (as defined above), wherein some or all of the hydrogen atoms in these groups may be replaced by halogen atoms as mentioned above, for example chloromethyl, bromome- thyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoro- methyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2- fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2- difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-
  • Ci-C 6 -alkoxy refers to a straight-chain or branched alkyl group having 1 to 6 carbon atoms (as defined above) which is bonded via an oxygen, at any position in the alkyl group, for example methoxy, ethoxy, n-propoxy, 1-methylethoxy, butoxy, 1-methylpropoxy, 2- methylpropoxy or 1 ,1-dimethylethoxy.
  • Cs-Cs-cycloalkyl refers to monocyclic saturated hydrocarbon radicals having 3 to 8 carbon ring members such as cyclopropyl (C 3 H 5 ), cyclobutyl, cyclopentyl, cyclohexyl, cyclohep- tyl or cyclooctyl.
  • aliphatic refers to compounds or radicals composed of carbon and hydrogen and which are non-aromatic compounds.
  • An“alicyclic” compound or radical is an organic compound that is both aliphatic and cyclic. They contain one or more all-carbon rings which may be either saturated or unsaturated, but do not have aromatic character.
  • cyclic group refers to a radical which is an alicyclic ring or an aromatic ring, such as, for example, phenyl or heteroaryl.
  • any of the aliphatic or cyclic groups are unsubstituted or substituted with...” refers to aliphatic groups, cyclic groups and groups, which contain an aliphatic and a cyclic moiety in one group, such as in, for example, C3-C8-cycloalkyl-Ci-C4-alkyl; therefore a group which contains an aliphatic and a cyclic moiety both of these moieties may be substituted or unsubstituted independently of each other.
  • Agriculturally acceptable salts of the active compounds I, II and III encompass especially the salts of those cations or the acid addition salts of those acids whose cations and anions, re- spectively, have no adverse effect on the fungicidal action of the active compounds.
  • Suitable cations are thus in particular the ions of the alkali metals, preferably sodium and potassium, of the alkaline earth metals, preferably calcium, magnesium and barium, of the transition metals, preferably manganese, copper, zinc and iron, and also the ammonium ion which, if desired, may carry 1 to 4 Ci-C 4 -alkyl substituents and/or one phenyl or benzyl substituent, preferably diisopropylammonium, tetramethylammonium, tetrabutylammonium, trimethylbenzylammonium, furthermore phosphonium ions, sulfonium ions, preferably tri(Ci-C4-alkyl)sulfonium, and sulfox- onium ions, preferably tri(Ci-C4-alkyl)sulfoxonium.
  • Anions of useful acid addition salts are pri- marily chloride, bromide, fluoride, hydrogensulfate, sulfate, dihydrogenphosphate, hydrogen- phosphate, phosphate, nitrate, bicarbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate, and the anions of Ci-C4-alkanoic acids, preferably formate, acetate, propionate and butyrate. They can be formed by reacting a compound I with an acid of the corresponding ani- on, preferably of hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid or nitric ac- id.
  • the scope of the present invention includes mixtures of the (R)- and (S)-isomers and the race- mates of compounds I and/or II and /or III having one or more chiral centers.
  • atrope isomers of active compounds I and/or II and/or III may be present. They also form part of the subject matter of the invention.
  • Y is S
  • a sulfonation reagent preferably Lawessons reagent (2,4-Bis-(4- methoxyphenyl)-1 ,3,2,4-dithiadiphosphetan-2,4-disulfid)
  • an organic solvent preferably at temperatures between 20 °C and 150 °C, preferably at 1 10 °C, as previously d
  • the present invention relates to mixtures comprising as component 1 ) at least one active compound of the formula I, or an N-oxide, or an agriculturally useful salt there- of, wherein:
  • Y is O or S
  • R 1 is cyclopropyl; and wherein the cyclopropyl group is substituted with 1 or 2 identical or different groups R 1a ; wherein
  • R 1a is Ci-C 6 -alkyl, halogen, Ci-C 6 -haloalkyl or Ci-C 6 -alkoxy; preferably methyl, ethyl or iso-propyl;
  • R 2 is hydrogen or Ci-C 6 -alkyl.
  • the present invention relates to mixtures comprising as component 1 ) at least one active compound of the formula I, or an N-oxide, or an agriculturally useful salt there- of, wherein:
  • Y is O;
  • R 1 is cyclopropyl; and wherein the cyclopropyl group is substituted with 1 or 2 identical or different groups R 1a ; and wherein one group R 1a is located in the 1 -position of the cyclo- propyl group;
  • R 1a is methyl, ethyl or iso-propyl
  • R 2 is hydrogen
  • the present invention relates to mixtures comprising as component 1 ) at least one active compound of the formula I, or an N-oxide, or an agriculturally useful salt there- of, wherein:
  • Y is O or S
  • R 1 is a radical
  • # denotes the position, which is bound to the group -NR 2 -;
  • R is chlorine or fluorine
  • R 1b is independently selected from the group consisting of halogen, cyano, NO2, OH, SH, NH2, diCi-C 6 -alkylamino, Ci-C 6 -alkyl, Ci-C 6 -alkoxy, Ci-C 6 -alkylthio, Ci-C 6 -alkyl- sulfinyl, Ci-C 6 -alkylsulfonyl, C2-C6-alkenyl, C2-C6-alkynyl, Cs-Cs-cycloalkyl and Cs-Cs-cycloalkoxy;
  • n 0 or 1 ;
  • R 2 is hydrogen, Ci-C 6 -alkyl, C2-C6-alkenyl, ethynyl, propargyl or Cs-Cs-cycloalkyl.
  • the present invention relates to mixtures comprising as component 1 ) at least one active compound of the formula I, or an N-oxide, or an agriculturally useful salt there- of, wherein:
  • Y is O
  • R 1 is a radical
  • # denotes the position, which is bound to the group -NR 2 -;
  • R is fluorine
  • R 1b is halogen, cyano, Ci-C 6 -alkyl, Ci-C 6 -haloalkyl, Ci-C 6 -alkoxy or Ci-C 6 -haloalkoxy; m is 0 or 1 ;
  • R 2 is hydrogen
  • Particularly preferred active compounds of the formula I are selected from the group consisting of compounds I .A to I.F:
  • I.C N-(2-methylcyclopropyl)-4-[5-(trifluoromethyl)-1 ,2,4-oxadiazol-3-yl]benzamide
  • I.D N-(1 -methylcyclopropyl)-4-[5-(trifluoromethyl)-1 ,2,4-oxadiazol-3-yl]benzamide;
  • mixtures comprising as component 2) at least one active compound selected from inhibitors of complex III at Q 0 site in group A), more preferably selected from compounds (A.1.1 ), (A.1.4), (A.1.8), (A.1.9), (A.1.10), (A.1.1 1 ), (A.1.12), (A.1 .13), (A.1.14), (A.1.17), (A.1.21 ), (A.1.21 a), (A.1.24), (A.1 .25), (A.1.26), (A.1 .27), (A.1.30), (A.1.31 ), (A.1 .32), (A.1.34) and (A.1.35); particularly selected from (A.1 .1 ), (A.1 .8), (A.1 .9), (A.1.10), (A.1.1 1 ), (A.1.13), (A.1 .14), (A.1 .17), (A.1.25), and (A.1 .34)
  • mixtures comprising as component 2) at least one active compound selected from inhibitors of complex III at Q, site in group A), more preferably selected from corn- pounds (A.2.1 ), (A.2.3), (A.2.4), (A.2.5) and (A.2.6); particularly selected from (A.2.4) and (A.2.6).
  • mixtures comprising as component 2) at least one active compound selected from inhibitors of complex II in group A), more preferably selected from compounds (A.3.2), (A.3.3), (A.3.4), (A.3.7), (A.3.9), (A.3.1 1 ), (A.3.12), (A.3.15), (A.3.16), (A.3.17), (A.3.18), (A.3.19), (A.3.20), (A.3.21 ), (A.3.22), (A.3.23), (A.3.24), (A.3.25), (A.3.26), (A.3.27), (A.3.28), (A.3.29), (A.3.31 ), (A.3.32), (A.3.33), (A.3.34), (A.3.35), (A.3.36), (A.3.37), (A.3.38) and
  • (A.3.39) particularly selected from (A.3.2), (A.3.3), (A.3.4), (A.3.7), (A.3.9), (A.3.17), (A.3.24), (A.3.28), (A.3.29), (A.3.31 ), (A.3.32), (A.3.33), (A.3.34), (A.3.35), (A.3.36), (A.3.37), (A.3.38) and (A.3.39).
  • mixtures comprising as component 2) at least one active compound selected from other respiration inhibitors in group A), more preferably selected from compounds (A.4.5) and (A.4.1 1 ).
  • mixtures comprising as component 2) at least one active compound selected from C14 demethylase inhibitors in group B), more preferably selected from corn- pounds (B.1.4), (B.1 .5), (B.1 .8), (B.1.10), (B.1 .1 1 ), (B.1.12), (B.1 .13), (B.1 .17), (B.1.18),
  • mixtures comprising as component 2) at least one active compound selected from Deltal 4-reductase inhibitors in group B), more preferably selected from corn- pounds (B.2.4), (B.2.5), (B.2.6) and (B.2.8); in particular (B.2.4) and (B.2.6).
  • mixtures comprising as component 2) at least one active compound selected from phenylamides and acyl amino acid fungicides in group C), more preferably se- lected from compounds (C.1.1 ), (C.1.2), (C.1 .4) and (C.1.5).
  • mixtures comprising as component 2) at least one active compound selected from other nucleic acid synthesis inhibitors in group C), more preferably selected from compounds (C.2.6),(C.2.7) and (C.2.8).
  • mixtures comprising as component 2) at least one active compound selected from group D), more preferably selected from compounds (D.1 .1 ), (D.1.2), (D.1 .5), (D.2.4), (D.2.6) and (D.2.7); particularly selected from (D.2.6) and (D.2.7).
  • mixtures comprising as component 2) at least one active compound selected from group E), more preferably selected from compounds (E.1.1 ), (E.1.3), (E.2.2) and (E.2.3); in particular (E.1.1 ).
  • mixtures comprising as component 2) at least one active compound selected from group H), more preferably selected from compounds (H.1 .5), (H.1 .7), (H.2.2), (H.2.3), (H.2.5), (H.2.7), (H.2.8), (H.3.2), (H.3.4), (H.3.5), (H.4.9) and (H.4.10); particularly se- lected from (H.1.5), (H.1 .7), (H.2.2), (H.3.2) and (H.3.5).
  • active compound selected from group H more preferably selected from compounds (H.1 .5), (H.1 .7), (H.2.2), (H.2.3), (H.2.5), (H.2.7), (H.2.8), (H.3.2), (H.3.4), (H.3.5), (H.4.9) and (H.4.10); particularly se- lected from (H.1.5), (H.1 .7), (H.2.2), (H.3.2) and (H.3.5).
  • mixtures comprising as component 2) at least one active compound selected from group I), more preferably selected from compounds (1.2.2) and (1.2.5).
  • mixtures comprising as component 2) at least one active compound selected from group J), more preferably selected from compounds (J.1.2), (J.1 .5), (J.1 .8), (J.1.1 1 ) and (J.1.12).
  • mixtures comprising as component 2) at least one active compound selected from group K), more preferably selected from compounds (K.1.3), (K.1 .29), (K.1.30), (K.1.31 ), (K.1.32), (K.1.41 ), (K.1 .42), (K.1.44), (K.1 .45), (K.1.47), (K.1.49), (K.1 .53) and
  • binary mixtures A-1 to A-739 listed in Table A, wherein compounds I (component 1 , a group represented by the expression“(I)” consisting of corn- pounds I .A, I.B, I.C, I.D, I.E, and I.F and one pesticide II selected from the groups A) to O) as defined herein (component 2, for example, (A.1 .1 ) or azoxystrobin, in mixture A-1 ).
  • A-1 (l)+(A.1 .1 ), A-2: (l)+(A.1 .2), A-3: (l)+(A.1 .3), A-4: (l)+(A.1 .4), A-5: (l)+(A.1 .5), A-6:
  • A-561 (l)+(0.9.1 ), A-553: (l)+(0.9.2), A-554: (l)+(0.9.3), A-555: (l)+(O.10.1), A-556: (l)+(0.11.1), A-557 : (l)+(0.1 1.2), A-558: (l)+(0.11.3), A-559: (l)+(0.1 1.4), A-560: (l)+(0.12.1 ), A-561 :
  • A-580 (l)+(0.16.5), A-580: (l)+(0.16.6), A-581 : (l)+(0.17.1 ), A-582: (l)+(0.18.1 ), A-583: (l)+(0.18.2), A-584: (l)+(0.18.3), A-585: (l)+(0.18.4), A-586: (l)+(0.18.5), A-587: (l)+(0.19.1 ), A-588:
  • the weight ratio of compound I to compound I is between 100:1 and 1 :100 in mixtures A-1 to A-739 of Table A.
  • the weight ratio of compound I to compound I is between 50:1 and 1 :50 in mixtures A-1 to A-739 of Table A.
  • the weight ratio of compound I to compound I is between 20:1 and 1 :20 in mixtures A-1 to A-739 of Table A.
  • the weight ratio of compound I to compound I is between 5:1 and 1 :5 in mixtures A-1 to A-739 of Table A.
  • the weight ratio of compound I to compound I is 3:1 in mixtures A-1 to A- 739 of Table A.
  • the weight ratio of compound I to compound I is 1 :1 in mixtures A-1 to A- 739 of Table A.
  • the weight ratio of compound I to compound I is 1 :3 in mixtures A-1 to A- 739 of Table A.
  • the mixtures A-1 to A-739 of Table A and in particular when the weight ratios of compound I to compound II are as disclosed for these mixtures as herein before mentioned, are used against Puccinia spp. (rusts) on various plants, in particular P. triticina (brown or leaf rust), P. striiformis (stripe or yellow rust), P. hordei (dwarf rust), P. graminis (stem or black rust) or P. recondita (brown or leaf rust), P. coronata (crown rust of grasses including oats) und P. helianthi (sunflower rust) on cereals, such as e. g.
  • binary mixtures listed in Table B1 to Table B6 for example mix- tures B1-1 to B1-161 in table B1 , wherein component 1) is compound I.
  • component 1) is compound I.
  • corn- pounds II are selected from groups A) to K), as defined herein.
  • B1-1 I.A + (A.1.1 ), B1-2: I.A + (A.1.4), B1-3: I.A + (A.1.8), B1-4: I.A + (A.1.9), B1-5: I.A + (A.1.10), B1-6: I.A + (A.1.11 ), B1-7: I.A + (A.1.12), B1-8: I.A + (A.1.13), B1-9: I.A + (A.1.14), B1- 10: I.A + (A.1.17), B1-1 1 : I.A + (A.1.21 ), B1-12: I.A + (A.1 21a), B1-13: I.A + (A.1.24), B1-14: I.A + (A.1.25), B1-15: I.A + (A.1.26), B1-16: I.A + (A.1.27), B1-17: I.
  • B1-45 I.A + (A.3.26)
  • B1-46 I.A + (A.3.27)
  • B1-47 I.A + (A.3.28)
  • B1-48 I.A +
  • B1-49 I.A + (A.3.31)
  • B1-50 I.A + (A.3.32)
  • B1-51 I.A + (A.3.33)
  • B1-52 I.A +
  • B1-53 I.A + (A.3.35)
  • B1-54 I.A + (A.3.36)
  • B1-55 I.A + (A.3.37)
  • B1-56 I.A +
  • B1-57 I.A + (A.3.39)
  • B1-58 I.A+ (A.4.5)
  • B1-59 I.A + (A.4.11)
  • B1-60 I.A+ (B.1.4)
  • B1-61 I.A+ (B.1.5)
  • B1-62 I.A + (B.1.8.)
  • B1-63 I.A + (B.1.10)
  • B1-64 I.A + (B.1.11)
  • B1-65 I.A + (B.1.12)
  • B1-66 I.A + (B.1.13)
  • B1-67 I.A + (B.1.17)
  • B1-69 I.A + (B.1.21)
  • B1-70 I.A + (B.1.22)
  • B1-71 I.A + (B.1.23)
  • B1-72 I.A + (B.1.25)
  • B1-73 I.A +
  • B.1.26 B1-74: I.A + (B.1.29)
  • B1-75 I.A + (B.1.33)
  • B1-76 I.A + (B.1.34)
  • B1-77 I.A +
  • B1-113 I.A + (G.5.6), B1-114: I.A + (G.5.7), B1-115: I.A + (G.5.8), B1-116: I.A +
  • B1-154 I.A + (0.26.2), B1-155: I.A + (0.26.3), B1-156: I.A + (0.26.4), B1-157: I.A + (0.26.5), B1-158: I.A + (0.27.7), B1-159: I.A + (0.27.76), B1-160: I.A + (0.27.78), B1-161: I.A + (0.27.79).
  • Table B2 Mixtures B2-1 to B2-161 are defined as mixtures B1-1 to B1-161 of Table B1, wherein compound I.A in each mixture is replaced with compound I.B.
  • Table B3 Mixtures B3-1 to B3-161 are defined as mixtures B1-1 to B1-161 of Table B1, wherein compound I.A in each mixture is replaced with compound I.C.
  • Table B4 Mixtures B4-1 to B4-161 are defined as mixtures B1-1 to B1-161 of Table B1, wherein compound I.A in each mixture is replaced with compound I.D.
  • Mixtures B5-1 to B5-161 are defined as mixtures B1-1 to B1-161 of Table B1, wherein compound I .A in each mixture is replaced with compound I.E.
  • Mixtures B6-1 to B6-161 are defined as mixtures B1-1 to B1-161 of Table B1, wherein compound I .A in each mixture is replaced with compound I.F.
  • the weight ratio of component 1) to compound II is between 100:1 and 1:100 in mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5- 161, and B6-1 to B6-161 of Tables B1 to B6.
  • the weight ratio of component 1 ) to compound II is between 50:1 and 1 :50 in mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5-161, and B6-1 to B6-161 of Tables B1 to B6.
  • the weight ratio of component 1) to compound II is between 20:1 and 1:20 in mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5-161, and B6-1 to B6-161 of Tables B1 to B6.
  • the weight ratio of component 1) to compound II is between 5:1 and 1 :5 in mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5-161, and B6-1 to B6-161 of Tables B1 to B6.
  • the weight ratio of component 1) to compound II is 3:1 in mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5-161, and B6-1 to B6-161 of Tables B1 to B6.
  • the weight ratio of component 1) to compound II is 1:1 in mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5-161, and B6-1 to B6-161 of Tables B1 to B6.
  • the weight ratio of component 1) to compound II is 1 :3 in mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5-161, and B6-1 to B6-161 of Tables B1 to B6.
  • the mixtures B1-1 to B1-161, B2-1 to B2-161, B3-1 to B3-161, B4-1 to B4-161, B5-1 to B5-161, and B6-1 to B6-161 of Tables B1 to B6 and in particular when the weight ratios of compound I to compound II are as disclosed for these mixtures as herein before mentioned, are used against Puccinia spp. (rusts) on various plants, in particular P. triticina (brown or leaf rust), P. striiformis (stripe or yellow rust), P. hordei (dwarf rust), P. graminis (stem or black rust) or P. recondita (brown or leaf rust), P.
  • coronata (crown rust of grasses including oats) on cereals, such as e. g. wheat, barley or rye, and Puccinia sorghi (common rust) on maize, Puccinia polysora (southern rust) on maize, and P. helianthi (sunflower rust); Hemileia vastatrix und Hemileia coffeicola (leaf rust and grey rust of coffee); Uromyces spp. on various crops; and Phakopsoraceae spp. on various plants, in particular Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans.
  • E.1 to E.144 listed in Table B7 relate to binary mixtures as de- fined in Tables B1 to B6 in particular weight ratios of compound I to compound II.
  • a preferred embodiment relates to the use of the mixtures according to embodiments E.1 to E.144 of Table B7 against Puccinia spp. (rusts) on various plants, in particular P. triticina (brown or leaf rust), P. striiformis (stripe or yellow rust), P. hordei (dwarf rust), P. graminis (stem or black rust) or P. recondita (brown or leaf rust), P. coronata (crown rust of grasses including oats) on cereals, such as e. g.
  • Puccinia sorghi common rust
  • Puccinia polysora sinflower rust
  • P. helianthi unsunflower rust
  • Hemileia vastatrix and Hemileia coffeicola leaf rust and grey rust of coffee
  • Uromyces spp. on various crops
  • Phakopsoraceae spp. on various plants, in particular Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans..
  • the binary mixtures above comprise besides at least one compound I and at least one compound II as component 3) at least one further active compound III, result- ing in a ternary mixture.
  • the components 1) and 2), or, all three components 1 ), 2) and 3), in these mixtures are present in a synergistically effective amount.
  • one embodiment relates to ternary mixtures comprising, as active components
  • component 2) at least one active compound II selected from groups A) to O) as defined for component 2) in binary mixtures above, or an N-oxide, or an agriculturally useful salt thereof;
  • the at least one active compound III of component 3 is not identical with the at least one active compound II of component 2).
  • the invention also relates to a method for controlling phytopathogenic harmful fungi using the abovementioned ternary mixtures; to agrochemical compositions comprising these ternary mix- tures; and to agrochemical compositions further comprising seed comprising these mixtures.
  • the ternary mixtures comprise as compounds III fungicidal compounds that are independently of each other selected from the groups A), B), C), D), E), F), G), H), I), J), K) and O); and wherein the at least one active compound III of component 3) is not identical with the at least one active compound II of component 2).
  • ternary mixtures based on binary mixtures disclosed herein, corn- prising as component 3) at least one active compound selected from C14 demethylase inhibi- tors in group B), more preferably selected from compounds (B.1.4), (B.1.5), (B.1.8), (B.1.10), (B.1.11 ), (B.1.12), (B.1.13), (B.1.17), (B.1.18), (B.1.21), (B.1.22), (B.1.23), (B.1.25), (B.1.26), (B.1.29), (B.1.33), (B.1.34), (B.1.37), (B.1.38), (B.1.43) and (B.1.46); particularly selected from (B.1.4), (B.1.5), (B.1.8), (B.1.17), (B.1.22), (B.1.23), (B.1.25), (B.1.29), and (B.1.38); and where- in the at least one active compound III of component 3) is not identical
  • the present invention relates furthermore to the mixtures as defined in Tables C1 to C6 corn- prising as component 1 ) one of the compounds selected from I .A, I.B, I.C, I.D, I.E and I.F as defined above, and as component 2) one of the compounds II as defined and numbered above from groups A) to K), and as component 3) a compound III from groups A) to K) as defined herein.
  • the compositions comprise the active substances in synergistically effective amounts.
  • Table C1 Ternary mixtures C1 -1 to C1 -6865 comprising compound I. A as defined herein as component 1 ) and one compound II as defined above as component 2) and one compound III as defined above as component 3).
  • the components 1 ), 2) and 3) are written down in this order (comp. 1 )+comp. 2)+comp. 3)), so that one mixture, for example mixture C1 -1 , comprises as component 1 ) compound I. A, as component 2) compound (A.1 .4) and as component 3) corn- pound (A.1 .1 ).
  • C1-1 I.A + (A.1.4) + (A.1.1)
  • C1-2 I.A + (A.1.8) + (A.1.1)
  • C1-3 I.A + (A.1.9) + (A.1.1)
  • C1-4 I.A +
  • C1-341 I.A + (A.3.28) + (A.1.9)
  • C1-342 I.A + (A.3.29) + (A.1.9)
  • C1-343 I.A + (A.3.31 ) + (A.1.9)
  • C 1-344 I.A + (A.3.32) + (A.1.9)
  • C1-345 I.A + (A.3.33) + (A.1.9)
  • C1-341 I.A + (A.3.28) + (A.1.9)
  • C1-342 I.A + (A.3.29) + (A.1.9)
  • C1-343 I.A + (A.3.31 ) + (A.1.9)
  • C 1-344 I.A + (A.3.32) + (A.1.9)
  • C1-345 I.A + (A.3.33) + (A.1.9)
  • C1-766 I.A + (A.3.18) + (A.1.13)
  • C1-767 I.A + (A.3.19) + (A.1.13)
  • C1-768 I.A + (A.3.20) +
  • C1-772 I.A + (A.3.24) + (A.1.13)
  • C1-773 I.A + (A.3.25) + (A.1.13)
  • C1-774 I.A + (A.3.26) +
  • C1-778 I.A + (A.3.31) + (A.1.13)
  • C1-779 I.A + (A.3.32) + (A.1.13)
  • C1-780 I.A + (A.3.33) +
  • C1-790 I.A + (B.1.5) + (A.1.13)
  • C1-791 I.A + (B.1.8.) + (A.1.13)
  • C1-792 I.A + (B.1.10) +
  • C1-1442 I.A + (K.1.47) + (A.1.34)
  • C1-1443 I.A + (K.1.49) + (A.1.34)
  • C1-1444 I.A + (K.1.53) +
  • C1-1533 I.A + (E.1 .3) + (A.2.4), C1-1534: I.A + (E. C1-1535: I.A + (E.2.3) + (A.2.4), C1- 1536: I.A + (F.1.2) + (A.2.4), C1-1537: I.A + (F.1.4) 1538: I.A + (F.1.5) + (A.2.4), C1-1539: I.A + (G.3.1 ) + (A.2.4), C1-1540: I.A + (G.3.3) + (A.2.4), 01-1541 : I.A + (G.3.6) + (A.2.4), C1-1542: I.A +
  • C1-1567 I.A + (J.1 .2) + (A.2.4), C1-1568: I.A + (J.1 .5) + (A.2.4), C1-1569: I.A + (J.1 .8) + (A.2.4), C1- 1570: I.A + (J.1.1 1 ) + (A.2.4), 01-1571 : I.A + (J.1.12) + (A.2.4), C1-1572: I.A + (K.1.3) + (A.2.4), C1-1573: I.A + (K.1.29) + (A.2.4), C1-1574: I.A + (K.1.30) + (A.2.4), C1-1575: I.A + (K.1.31 ) + (A.2.4), C1-1576: I.A + (K.1.32) + (A.2.4), C1-1577: I.A + (K.1.41 ) + (A.2.4), C1-1578: I.A + (K.1.42) + (A.2.4), C
  • C1-1604 I.A + (A.3.25) + (A.2.6)
  • C1-1605 I.A + (A.3.26) + (A.2.6)
  • C1-1606 I.A + (A.3.27) +
  • C1-1628 I.A + (B.1.18) + (A.2.6)
  • C1-1629 I.A + (B.1.21 ) + (A.2.6)
  • C1-1630 I.A + (B.1.22) +
  • C1-1634 I.A + (B.1.29) + (A.2.6)
  • C1-1635 I.A + (B.1.33) + (A.2.6)
  • C1-1636 I.A + (B.1.34) +
  • C1-1640 I.A + (B.1.46) + (A.2.6), 01-1641 : I.A + (B.2.4) + (A.2.6), C1-1642: I.A + (B.2.5) + (A.2.6), C1-1643: I.A + (B.2.6) + (A.2.6), C1-1644: I.A + (B.2.8) + (A.2.6), C1-1645: I.A + (C.1.1 ) + (A.2.6), C1-1646: I.A + (C.1.2) + (A.2.6), C1-1647: I.A + (C.1 .4) + (A.2.6), C1-1648: I.A + (C.1 .5) + (A.2.6), C1- 1649: I.A + (C.2.6) + (A.2.6), C1-1650: I.A + (C.2.7) + (A.2.6), 01-1651 : I.A + (C.2.8) + (A.2.6), C1-1652
  • C1-2523 I.A + (A.1.26) + (A.3.24)
  • C1-2524 I.A + (A.1.27) + (A.3.24)
  • C1-2525 I.A + (A.1.30) + (A.3.24)
  • C1-2526 I.A + (A.1.31 ) + (A.3.24)
  • C1-2527 I.A + (A.1.32) + (A.3.24)
  • C1-2528 I.A + (A.1.35) + (A.3.24)
  • C1-2529 C1-2530: I.A + (A.2.3) + (A.3.24)
  • C1-2531 I.A + (A.2.5) + (A.3.24)
  • C1- 2532 I.A 1-2533: I.A + (A.3.12) + (A.3.24)
  • C1-2534 I.A + (A.3.15) + (A.3.24)
  • I.A 1-2536 I.A + (A.3.18) + (A.3.24)
  • C1-2537 I.A + (A.3.19) + (A.3.24), C1-
  • I.A 1-2542 I.A + (A.3.25) + (A.3.24)
  • C1-2543 I.A + (A.3.26) + (A.3.24), C1-
  • I.A 1-2551 I.A + (A.3.35) + (A.3.24)
  • C1-2552 I.A + (A.3.36) + (A.3.24)
  • I.A 1-2554 I.A + (A.3.38) + (A.3.24)
  • C1-2555 I.A + (A.3.39) + (A.3.24), C1-
  • I.A -2590 I.A + (D.1 .1 ) + (A.3.24), C1-2591 : I.A + (D.1 .2) + (A.3.24), C1-
  • I.A -2602 I.A + (F.1.5) + (A.3.24)
  • C1-2603 I.A + (G.3.1 ) + (A.3.24)
  • I.A -2605 I.A + (G.3.6) + (A.3.24)
  • C1-2606 I.A + (G.5.1 ) + (A.3.24)
  • I.A -2608 I.A + (G.5.3) + (A.3.24)
  • C1-2609 I.A + (G.5.4) + (A.3.24)
  • I.A -2614 I.A + (G.5.9) + (A.3.24)
  • C1-2615 I.A + (G.5.10) + (A.3.24)
  • C1- 2616 I.A 1-2617: I.A + (H.1.5) + (A.3.24)
  • C1-2618 I.A + (H.1.7) + (A.3.24)
  • C1- 2619 I.A -2620: I.A + (H.2.3) + (A.3.24)
  • C1-2621 I.A + (H.2.5) + (A.3.24)
  • I.A -2632 I.A + (J.1.5) + (A.3.24)
  • C1-2633 I.A + (J.1 .8) + (A.3.24)
  • C1- 2634 I.A 1-2635: I.A + (J.1.12) + (A.3.24)
  • C1-2636 I.A + (K.1.3) + (A.3.24)
  • C1- 2637 I.A 1-2638: I.A + (K.1.30) + (A.3.24)
  • C1-2639 I.A + (K.1.31 ) + (A.3.24)
  • I.A -2650 I.A + (A.1.12) + (A.3.28), C1-2651 : I.A + (A.1.21 ) + (A.3.28), C1- 2652: I.A C1-2653: I.A + (A.1.24) + (A.3.28), C1-2654: I.A + (A.1.26) + (A.3.28), C1-2655: ), C1-2656: I.A + (A.1.30) + (A.3.28), C1-2657: I.A + (A.1.31 ) + (A.3.28),
  • C1-2658 ), C1-2659: I.A + (A.1.35) + (A.3.28), C1-2660: I.A + (A.2.1 ) + (A.3.28),
  • C1-2661 C1-2662: I.A + (A.2.5) + (A.3.28), C1-2663: I.A + (A.3.1 1 ) + (A.3.28),
  • C1-2667 ), C1-2668: I.A + (A.3.19) + (A.3.28), C1-2669: I.A + (A.3.20) + (A.3.28), C1-2670: I.A + (A.3.21 ) + (A.3.28), C1-2671 : I.A + (A.3.22) + (A.3.28), C1-2672: I.A + (A.3.23) + (A.3.28),
  • C1-2679 I.A + (A.3.33) + (A.3.28)
  • C1-2680 I.A + (A.3.34) + (A.3.28)
  • C1-2681 I.A + (A.3.35) + (A.3.28)
  • C1-2685 I.A + (A.3.39) + (A.3.28)
  • C1-2686 I.A + (A.4.5) + (A.3.28)
  • C1-2687 I.A + (A.4.1 1 ) + (A.3.28)
  • C1-2688 I.A + (B.1 .4) + (A.3.28)
  • C1-2689 I.A + (B.1.5) + (A.3.28)
  • C1-2690 I.A + (B.1.8.) + (A.3.28)
  • C1-2691 I.A + (B.1.10) + (A.3.28)
  • C1-2692 I.A + (B.1.1 1 ) + (A.3.28)
  • C1-2693 I.A + (B.1.12) + (A.3.28)
  • C1-2694 I.A + (B.1.13) + (A.3.28)
  • C1-2695 I.A + (B.1.17) + (A.3.28)
  • C1-2696 I.A + (B.1.18) + (A.3.28)
  • C1-2700 I.A + (B.1.25) + (A.3.28)
  • C1-2701 I.A + (B.1.26) + (A.3.28)
  • C1-2702 I.A + (B.1.29) + (A.3.28)
  • C1-2703 I.A + (B.1.33) + (A.3.28)
  • C1-2704 I.A + (B.1.34) + (A.3.28)
  • C1-2705 I.A + (B.1.37) + (A.3.28)
  • C1-2709 I.A + (B.2.4) + (A.3.28)
  • C1-2710 I.A + (B.2.5) + (A.3.28)
  • C1-271 1 I.A + (B.2.6) + (A.3.28)
  • C1- 2712 I.A + (B.2.8) + (A.3.28)
  • C1-2713 I.A + (C.1.1 ) + (A.3.28)
  • C1-2714 I.A + (C.1 .2) + (A.3.28), C1-
  • C1-2790 I.A + (A.2.1 ) + (A.3.29), C1-2791 : I.A + (A.2.3) + (A.3.29), C1-2792: I.A + (A.2.5) + (A.3.29), C1- 2793: I.A + (A.3.1 1 ) + (A.3.29), C1-2794: I.A + (A.3.12) + (A.3.29), C1-2795: I.A + (A.3.15) + (A.3.29), C1-
  • 2904 1-2905: I.A + (K.1.49) + (A.3.29), C1-2906: I.A + (K.1.53) + (A.3.29), C1-
  • C1-2913 I.A + (A.1.26) + (A.3.31), C1-2914: I.A + (A.1.27) + (A.3.31), C1-2915: I.A + (A.1.30) + (A.3.31), C1-2916: I.A + (A.1.31) + (A.3.31), C1-2917: I.A + (A.1.32) + (A.3.31), C1-2918: I.A + (A.1.35) + (A.3.31), C1-2919: I.A + (A.2.1) + (A.3.31), C1-2920: I.A + (A.2.3) + (A.3.31), C1-2921: I.A + (A.2.5) + (A.3.31), C1- 2922: I.A + (A.3.11) + (A.3.31), C1-2923: I.A + (A.3.12) + (A.3.31), C1-2924: I.A + (A.3.15) + (A.3.31), C1
  • 2958 1-2959: I.A + (B.1.29) + (A.3.31), C1-2960: I.A + (B.1.33) + (A.3.31), C1-
  • 2961 1-2962: I.A + (B.1.37) + (A.3.31), C1-2963: I.A + (B.1.38) + (A.3.31), C1-
  • 2973 -2974: I.A + (C.2.6) + (A.3.31), C1-2975: I.A + (C.2.7) + (A.3.31), C1-
  • 2982 -2983: I.A + (E.1.1) + (A.3.31), C1-2984: I.A + (E.1.3) + (A.3.31), C1-
  • 2988 -2989: I.A + (F.1.5) + (A.3.31), C1-2990: I.A + (G.3.1) + (A.3.31), C1-
  • 2994 -2995: I.A + (G.5.3) + (A.3.31), C1-2996: I.A + (G.5.4) + (A.3.31), C1-
  • 2997 -2998: I.A + (G.5.6) + (A.3.31), C1-2999: I.A + (G.5.7) + (A.3.31), C1-
  • C1-3054 I.A + (A.3.18) + (A.3.32)
  • C1-3055 I.A + (A.3.19) + (A.3.32)
  • C1-3056 I.A + (A.3.20) + (A.3.32)
  • C1-3060 I.A + (A.3.25) + (A.3.32)
  • C1-3061 I.A + (A.3.26) + (A.3.32)
  • C1-3062 I.A + (A.3.27) + (A.3.32)
  • C1-3066 I.A + (A.3.36) + (A.3.32)
  • C1-3067 I.A + (A.3.37) + (A.3.32)
  • C1-3068 I.A + (A.3.38) + (A.3.32)
  • C1-3069 I.A + (A.3.39) + (A.3.32)
  • C1-3070 I.A + (A.4.5) + (A.3.32)
  • C1-3071 I.A + (A.4.11) + (A.3.32)
  • C1-3072 I.A + (B.1.4) + (A.3.32)
  • C1-3073 I.A + (B.1.5) + (A.3.32)
  • C1-3074 I.A + (B.1.8.) + (A.3.32)
  • C1-3076 I.A + (B.1.11) + (A.3.32)
  • C1-3077 I.A + (B.1.12) + (A.3.32)
  • C1-3078 I.A + (B.1.13) + (A.3.32)
  • C1-3079 I.A + (B.1.17) + (A.3.32)
  • C1-3080 I.A + (B.1.18) + (A.3.32)
  • C1-3081 I.A + (B.1.21) + (A.3.32)
  • C1-3082 I.A + (B.1.22) + (A.3.32)
  • C1-3083 I.A + (B.1.23) + (A.3.32)
  • C1-3084 I.A + (B.1.25) + (A.3.32)
  • C1-3085 I.A + (B.1.26) + (A.3.32)
  • C1-3086 I.A + (B.1.29) + (A.3.32)
  • C1-3090 I.A + (B.1.38) + (A.3.32), C1-3091 : I.A + (B.1.43) + (A.3.32), C1-3092: I.A + (B.1.46) + (A.3.32), C1-3093: C1-3094: I.A + (B.2.5) + (A.3.32), C1-3095: I.A + (B.2.6) + (A.3.32), C1- 3096: I.A 3097: I.A + (C.1.1 ) + (A.3.32), C1-3098: I.A + (C.1 .2) + (A.3.32), C1-
  • I.A 3100 I.A + (C.1 .5) + (A.3.32), C1-3101 : I.A + (C.2.6) + (A.3.32), C1-
  • I.A 3106 I.A + (D.1 .5) + (A.3.32)
  • C1-3107 I.A + (D.2.4) + (A.3.32), C1-
  • I.A 31 12 I.A + (E.2.2) + (A.3.32)
  • C1-31 13 I.A + (E.2.3) + (A.3.32)
  • C1- 31 14 I.A + (F.1.2) + (A.3.32)
  • C1-31 15 I.A + (F.1.4) + (A.3.32)
  • C1-31 16 I.A + (F.1.5) + (A.3.32)
  • C1- 31 17 I.A + (G.3.1 ) + (A.3.32)
  • C1-31 18 I.A + (G.3.3) + (A.3.32)
  • C1-31 19 I.A + (G.3.6) + (A.3.32)
  • C1-3432 I.A + (A.3.18) + (A.3.35)
  • C1-3433 I.A + (A.3.19) + (A.3.35)
  • C1-3434 I.A + (A.3.20) + (A.3.35)
  • C1-3435 I.A + (A.3.21) + (A.3.35)
  • C1-3436 I.A + (A.3.22) + (A.3.35)
  • C1-3437 I.A + (A.3.23) + (A.3.35)
  • C1-3438 I.A + (A.3.25) + (A.3.35)
  • C1-3439 I.A + (A.3.26) + (A.3.35)
  • C1-3440 I.A + (A.3.27) + (A.3.35)
  • C1-3441 I.A + (A.3.36) + (A.3.35)
  • C1-3442 I.A + (A.3.37) + (A.3.35)
  • C1-3443 I.A + (A.3.38) + (A.3.35)
  • C1-3444 I.A + (A.3.39) + (A.3.35), C1-3445: I.A + (A.4.5) + (A.3.35), C1-3446: I.A + (A.4.11) + (A.3.35), C1-3447: I.A + (B.1.4) + (A.3.35), C1-3448: I.A + (B.1.5) + (A.3.35), C1-3449: I.A + (B.1.8.) + (A.3.35), C1-3450: I.A + (B.1.10) + (A.3.35), C1-3451 : I.A + (B.1.11) + (A.3.35), C1-3452: I.A + (B.1.12) + (A.3.35),
  • C1-3453 I.A + (B.1.13) + (A.3.35)
  • C1-3454 I.A + (B.1.17) + (A.3.35)
  • C1-3455 I.A + (B.1.18) + (A.3.35)
  • C1-3456 I.A + (B.1.21) + (A.3.35)
  • C1-3457 I.A + (B.1.22) + (A.3.35)
  • C1-3458 I.A + (B.1.23) + (A.3.35)
  • C1-3459 I.A + (B.1.25) + (A.3.35)
  • C1-3460 I.A + (B.1.26) + (A.3.35)
  • C1-3461 I.A + (B.1.29) + (A.3.35)
  • C1-3462 I.A + (B.1.33) + (A.3.35)
  • C1-3463 I.A + (B.1.34) + (A.3.35)
  • C1-3464 I.A + (B.1.37) + (A.3.35)
  • C1-3465 I.A + (B.1.38) + (A.3.35)
  • C1-3466 I.A + (B.1.43) + (A.3.35)
  • C1-3467 I.A + (B.1.46) + (A.3.35)
  • C1-3468 I.A + (B.2.4) + (A.3.35)
  • C1-3469 I.A + (B.2.5) + (A.3.35)
  • C1-3470 I.A + (B.2.6) + (A.3.35)
  • C1- 3471 I.A + (B.2.8) + (A.3.35)
  • C1-3472 I.A + (C.1.1) + (A.3.35)
  • C1-3473 I.A + (C.1.2) + (A.3.35)
  • C1-3541 I.A + (A.1 21a) + (A.3.36)
  • C1-3542 I.A + (A.1.24) + (A.3.36)
  • C1-3543 I.A + (A.1.26) + (A.3.36), C1-3544: I.A + (A.1.27) + (A.3.36), C1-3545: I.A + (A.1.30) + (A.3.36), C1-3546: I.A + (A.1.31 ) + (A.3.36), C1-3547: I.A + (A.1.32) + (A.3.36), C1-3548: I.A + (A.1.35) + (A.3.36), C1-3549: I.A + (A.2.1 ) + (A.3.36), C1-3550: I.A + (A.2.3) + (A.3.36), C1-3551 : I.A + (A.2.5) + (A.3.36), C1- 3552: I.A + (A.3.1 1 ) + (A.3.36), C1-3553: I.A + (A.3.12) + (A.3.36), C1-3554: I.A + (A.3.15) + (A
  • C1-3666 I.A + (A.1.26) + (A.3.37), C1-3667: I.A + (A.1.27) + (A.3.37), C1-3668: I.A + (A.1.30) + (A.3.37), C1-3669: I.A + (A.1.31 ) + (A.3.37), C1-3670: I.A + (A.1.32) + (A.3.37), C1-3671 : I.A + (A.1.35) + (A.3.37), C1-3672: I.A + (A.2.1 ) + (A.3.37), C1-3673: I.A + (A.2.3) + (A.3.37), C1-3674: I.A + (A.2.5) + (A.3.37), C1- 3675: I.A + (A.3.1 1 ) + (A.3.37), C1-3676: I.A + (A.3.12) + (A.3.37), C1-3677: I.A + (A.3.15) + (
  • 371 1 I.A + (B.1.43) + (A.3.37)
  • C1-3712 I.A + (B.1.46) + (A.3.37)
  • C1-3713 I.A + (B.2.4) + (A.3.37)
  • C1- 3714 I.A + (B.2.5) + (A.3.37)
  • C1-3715 I.A + (B.2.6) + (A.3.37)
  • C1-3716 I.A + (B.2.8) + (A.3.37)

Abstract

La présente invention concerne des mélanges fongicides comprenant au moins un 3-phényl-5-(trifluorométhyl)-1,2,4-oxadiazole substitué (composé I) et au moins un composé II actif ; un procédé pour lutter contre des champignons phytopathogènes nuisibles à l'aide de mélanges d'au moins un composé I et d'au moins un composé II ; l'utilisation de mélanges comprenant des composés I et des composés II pour lutter contre des champignons phytopathogènes nuisibles ; des compositions agrochimiques comprenant ces mélanges ; et des compositions agrochimiques comprenant en outre des semences.
PCT/EP2018/084317 2017-12-14 2018-12-11 Mélange fongicide comprenant des 3-phényl-5-(trifluorométhyl)-1,2,4-oxadiazoles substitués WO2019115511A1 (fr)

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WO2021180598A1 (fr) 2020-03-13 2021-09-16 Syngenta Crop Protection Ag Procédés de lutte contre ou de prévention de l'infestation de plantes par le micro-organisme phytopathogène corynespora cassiicola
WO2021180974A1 (fr) 2020-03-13 2021-09-16 Syngenta Crop Protection Ag Procédés de lutte contre ou de prévention de l'infestation de plantes par le micro-organisme phytopathogène corynespora cassiicola
WO2021180596A1 (fr) 2020-03-13 2021-09-16 Syngenta Crop Protection Ag Procédés de lutte ou de prévention de l'infestation de plantes par le micro-organisme phytopathogène corynespora cassiicola
WO2021180592A1 (fr) 2020-03-13 2021-09-16 Syngenta Crop Protection Ag Procédés pour lutter contre ou prévenir l'infestation de plantes par le micro-organisme phytopathogène corynespora cassiicola
WO2022018765A1 (fr) * 2020-07-24 2022-01-27 Rajdhani Petrochemicals Private Limited Mélange agrochimique synergique pour une application au sol
WO2022018747A1 (fr) * 2020-07-18 2022-01-27 Rajdhani Petrochemicals Private Limited Composition agrochimique synergique comprenant des diamides et des régulateurs de croissance de plantes

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