WO2019109720A1 - 一种复杂型面工件切向渐变热喷涂涂层设计方法 - Google Patents
一种复杂型面工件切向渐变热喷涂涂层设计方法 Download PDFInfo
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- WO2019109720A1 WO2019109720A1 PCT/CN2018/109138 CN2018109138W WO2019109720A1 WO 2019109720 A1 WO2019109720 A1 WO 2019109720A1 CN 2018109138 W CN2018109138 W CN 2018109138W WO 2019109720 A1 WO2019109720 A1 WO 2019109720A1
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- 230000003628 erosive effect Effects 0.000 claims abstract description 75
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- 238000005507 spraying Methods 0.000 claims abstract description 13
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Images
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- G06F30/20—Design optimisation, verification or simulation
- G06F30/28—Design optimisation, verification or simulation using fluid dynamics, e.g. using Navier-Stokes equations or computational fluid dynamics [CFD]
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- G06F—ELECTRIC DIGITAL DATA PROCESSING
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
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- C23C4/073—Metallic material containing MCrAl or MCrAlY alloys, where M is nickel, cobalt or iron, with or without non-metal elements
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
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Definitions
- the invention belongs to the technical field of thermal spraying, and in particular relates to a design method of a tangentially graded thermal spray coating for a complex profile workpiece.
- Erosion rate is an important indicator to measure erosion wear. It is greatly affected by the impact angle between the incident particles and the complex surface and the brittle plasticity of the coating material. As shown in Figure 1, 2, the brittle coating material is at a small angle. The lower erosion resistance is good, and the plastic material has good erosion resistance at large angles, and the erosion resistance is different in the range of impact angle [0°, 90°].
- the present invention provides a tangentially graded thermal spray coating design method for a complex profile workpiece, which exhibits a large difference in erosion resistance performance according to different impact angles of the plastic material and the brittle material.
- Theoretical calculation, software simulation and experiment are combined to obtain the plastic-brittle ratio of the coating (the plastic material accounts for the mass fraction of the mixed powder), the corresponding relationship between the erosion rate and the impact angle, and the coating structure of the spray material along the surface of the complex surface is constructed.
- the coating's erosion resistance is matched to the requirements of various parts of the complex profile.
- a tangentially graded thermal spray coating design method for a complex profile workpiece comprising the following steps:
- Step 1 According to the complex profile workpiece structure and working condition, determine the variation law of the impact angle between the surface of the complex profile workpiece and the erosion particle;
- Step 2 Select anti-erosion coating materials, including brittle materials and plastic materials, according to the requirements of working conditions;
- Step 3 spraying the workpiece with the anti-erosion coating material of step 2, and performing an erosion test, and obtaining the relationship between the impact angle of the anti-erosion coating-plastic embrittlement ratio and the erosion rate;
- Step 4 According to steps 1 and 3, combining the erosion threshold threshold conditions of the complex profile workpiece, the correspondence between the plastic-brittle ratio of the erosion resistant coating and the impact angle is determined;
- Step 5 Determine the correspondence between the coating plastic-brittle ratio and the surface position of the complex profile workpiece by the corresponding relationship of the step 4, and thermally spray the surface of the complex profile workpiece.
- the working conditions include erosion particle properties (type, particle size, shape) and environmental conditions (gas-solid two-phase flow velocity, pressure, and temperature).
- step 1 analyzing the service condition of the complex profile workpiece, theoretically calculating and extracting the gas phase boundary condition and the particle boundary condition, and using the fluid simulation software simulation analysis to obtain the impact angle between the surface of the complex profile workpiece and the erosion particle.
- the law of change is a condition in which the service condition of the complex profile workpiece is analyzed.
- the types of the brittle material and the plastic material in the erosion resistant coating material are specifically determined.
- the erosion resistant coating material is mechanically mixed from the plastic material and the brittle material.
- the plastic-brittle ratio of the erosion-resistant coating material ranges from [0, 1].
- step 3 is:
- the anti-erosion coating material obtained by mixing the brittle material and the plastic material selected in step 2 with different mixing ratios is sprayed on the workpiece, and the multi-factor erosion test is designed by orthogonal test method to obtain the impact angle and the plastic-brittle ratio. And experimental data of erosion rate, and fitting to obtain the three relational surfaces.
- the erosion threshold threshold condition of the complex profile workpiece is calculated according to the working condition requirement and the rated life of the complex profile workpiece.
- the average value of the erosion rate at each impact angle is the minimum optimization target, and the three relationships determined in step 3 are used as the constraint conditions, and the impact angle corresponding to each point on the surface of the complex profile workpiece is taken as the impact angle.
- the two-way powder feeding thermal spraying device with real-time adjustable powder feeding amount is used to control the powder feeding amount by the controller to realize the plastic-brittle ratio control, and the surface of the complex profile workpiece is thermally sprayed.
- the invention can design a coating with anti-erosion performance matching impact angle change on the surface of the complex surface, and solves the problem of erosion resistance of the complex surface which the homogeneous material coating cannot meet the wide range of impact angle.
- the tangentially graded coating obtained by the invention has more uniform erosion and lower overall average erosion rate, and can be used for new product reinforcement and damage repairing of damaged parts, and can effectively improve service life. .
- Figure 1 is a schematic view showing the impact angle of incident particles and complex surface
- Figure 2 shows the variation of the erosion rate of the brittle material, the plastic material and the modified material with the impact angle
- Figure 3 is a schematic diagram of coating modification
- Figure 4 shows the impact angle-plastic embrittlement ratio-erosion rate relational surface.
- the use of a homogeneous brittle coating to strengthen or repair complex profile parts does not meet the erosion resistance requirements of the coating at various impact angles.
- the present application proposes a tangentially graded thermal spray coating design method for a complex profile workpiece, which is directed to the anti-erosion performance requirements of different regions of the complex profile, and is resistant to impact at different impact angles according to the brittleness and plasticity of the material.
- the difference in etch performance (as shown in Figure 2), the performance-driven tangentially graded coating system is built, that is, the plastic material is mixed during the spraying process of the brittle coating material, and the coating performance is matched to each part by changing the plastic-brittle ratio.
- the erosion resistance which in turn increases the service life of complex profile parts.
- a brittle material is used to make a single homogeneous brittle coating.
- the coating is more flexible than the surface impact angle.
- a method for designing a tangentially graded thermal spray coating of a complex profile workpiece including the following steps:
- Step 1 According to the complex profile workpiece structure and working condition, determine the variation law of the impact angle between the surface of the complex profile workpiece and the erosion particle;
- Step 2 Select anti-erosion coating materials, including brittle materials and plastic materials, according to the requirements of working conditions;
- Step 3 spraying the workpiece with the anti-erosion coating material of step 2, and performing an erosion test, and obtaining the relationship between the impact angle of the anti-erosion coating-plastic embrittlement ratio and the erosion rate;
- Step 4 According to steps 1 and 3, combining the erosion threshold threshold conditions of the complex profile workpiece, the correspondence between the plastic-brittle ratio of the erosion resistant coating and the impact angle is determined;
- Step 5 Determine the correspondence between the coating plastic-brittle ratio and the surface position of the complex profile workpiece by the corresponding relationship of the step 4, and thermally spray the surface of the complex profile workpiece.
- operating conditions include erosion particle properties (type, particle size, shape) and environmental conditions (gas-solid two-phase flow rate, pressure, and temperature).
- step 1 the service conditions of complex profile workpieces are analyzed, and the gas phase boundary conditions and particle boundary conditions are theoretically calculated and extracted.
- the variation of the impact angle between the surface of the complex profile workpiece and the erosion particles is obtained by simulation of fluid simulation software.
- the types of the brittle material and the plastic material in the erosion resistant coating material are specifically determined.
- the erosion resistant coating material is mechanically mixed from a plastic material and a brittle material.
- the plastic-brittle ratio of the erosion-resistant coating material ranges from [0, 1].
- step 3 The specific steps of step 3 are as follows:
- the anti-erosion coating material obtained by mixing the brittle material and the plastic material selected in step 2 with different mixing ratios is sprayed on the workpiece, and the multi-factor (impact angle, plastic-brittle ratio) erosion test is designed by orthogonal test method.
- the test data of impact angle, plastic-brittle ratio and erosion rate were obtained, and the three-relational surface was obtained by Matlab fitting.
- step 4 the erosion rate threshold constraint condition of the complex profile workpiece is calculated according to the working condition requirements and the rated life of the complex profile workpiece.
- step 5 the average value of the erosion rate at each impact angle is the minimum optimization target, and the three relationships determined in step 3 are used as the constraint conditions, and the impact angle corresponding to each point on the surface of the complex surface workpiece is used as the position constraint and setting.
- the equation of the plastic-brittle ratio is the polynomial function as the continuity constraint of the coating plastic-brittle ratio.
- step 5 the two-way powder feeding thermal spraying equipment with real-time adjustable powder feeding amount is used to control the powder feeding amount by the controller to realize the plastic-brittle ratio control, and the surface of the complex surface workpiece is thermally sprayed.
- the average value of the erosion rate at each impact angle is the smallest
- the formula of the plastic-brittle ratio is about a polynomial function.
- the coefficients m i are solved. The plastic-brittle ratio of the coating at different positions of the blade surface and different impact angles is obtained, and the tangentially graded coating design of the blade surface is realized.
- Spray coating Based on the matching relationship between the tangentially graded coating and the surface impact angle of the blade, the two-way powder feeding thermal spraying equipment with real-time adjustable powder feeding amount is used for spraying.
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Abstract
Description
Claims (9)
- 一种复杂型面工件切向渐变热喷涂涂层设计方法,其特征是,包括以下步骤:步骤1:根据复杂型面工件结构、工况条件,确定复杂型面工件表面与冲蚀粒子间冲击角度的变化规律;所述步骤1中,分析复杂型面工件服役工况,理论计算并提取气相边界条件与颗粒边界条件,采用流体仿真软件仿真分析得出复杂型面工件表面与冲蚀粒子间冲击角度的变化规律;步骤2:根据使用工况需求选择抗冲蚀涂层材料,包括脆性材料与塑性材料;步骤3:采用步骤2的抗冲蚀涂层材料对工件进行喷涂,并进行冲蚀试验,测试得到抗冲蚀涂层的冲击角度-塑脆比-冲蚀率三者关系;步骤4:根据步骤1和步骤3,结合复杂型面工件的冲蚀率阈值约束条件,确定抗冲蚀涂层的塑脆比与冲击角度的对应关系;步骤5:由步骤4的对应关系,确定涂层塑脆比与复杂型面工件表面位置的对应关系,对复杂型面工件表面进行热喷涂。
- 如权利要求1所述的设计方法,其特征是,所述步骤1中,工况条件包括冲蚀粒子性能和环境条件。
- 如权利要求1所述的设计方法,其特征是,所述步骤2中,根据脆性材料和塑性材料的抗冲蚀性能,结合工件使用工况要求,具体确定抗冲蚀涂层材料中脆性材料和塑性材料的种类。
- 如权利要求1所述的设计方法,其特征是,所述步骤2中,抗冲蚀涂层材料由塑性材料和脆性材料机械混合而成。
- 如权利要求4所述的设计方法,其特征是,抗冲蚀涂层材料的塑脆比变化范围为[0,1]。
- 如权利要求1所述的设计方法,其特征是,所述步骤3的具体步骤为:采用步骤2选择的脆性材料和塑性材料以不同混合比例配比得到的抗冲蚀涂层材料,对工件进行喷涂,采用正交试验法,设计多因素冲蚀试验,得到冲击角度、塑脆比和冲蚀率的试验数据,并拟合得到三者关系曲面。
- 如权利要求1所述的设计方法,其特征是,所述步骤4中,复杂型面工件的冲蚀率阈值约束条件根据复杂型面工件使用工况要求及额定寿命计算得出。
- 如权利要求1所述的设计方法,其特征是,所述步骤5中,以各冲击角度下冲蚀率平均值最小为优化目标,以步骤3确定的三者关系作为约束条件、以复杂型面工件表面各点所对应的冲击角度作为位置约束、设定塑脆比关于冲击角度的方程作为涂层塑脆比的连续性约束,最终获得工件表面不同位置、不同冲击角度下涂层的塑脆比。
- 如权利要求1所述的设计方法,其特征是,所述步骤5中,利用送粉量实时可调的双路送粉热喷涂设备,通过控制器控制送粉量来实现塑脆比控制,对复杂型面工件表面进行热喷涂。
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US16/338,689 US10982311B2 (en) | 2017-12-08 | 2018-09-30 | Method of tangential gradient thermal spraying coating for complex profile workpieces |
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