WO2019106834A1 - Quality-improved cooked rice and method for producing same - Google Patents

Quality-improved cooked rice and method for producing same Download PDF

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Publication number
WO2019106834A1
WO2019106834A1 PCT/JP2017/043321 JP2017043321W WO2019106834A1 WO 2019106834 A1 WO2019106834 A1 WO 2019106834A1 JP 2017043321 W JP2017043321 W JP 2017043321W WO 2019106834 A1 WO2019106834 A1 WO 2019106834A1
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rice
glucomannan
quality
dextrin
raw
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PCT/JP2017/043321
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French (fr)
Japanese (ja)
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清水 秀樹
清水 寿夫
隆介 清水
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清水化学株式会社
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Priority to PCT/JP2017/043321 priority Critical patent/WO2019106834A1/en
Publication of WO2019106834A1 publication Critical patent/WO2019106834A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products

Definitions

  • the present invention relates to quality-improved rice and its production method.
  • Patent Document 1 provides a method for maintaining the texture of chilled or frozen preserved rice, which comprises adding protease, glucomannan and lactate at the time of cooking of cooked rice;
  • a texture modifier for chilled or frozen rice is described which is characterized in that it contains a protease, glucomannan and lactate.
  • a rice improver containing 3% by mass of protease, 1% by mass of protease, 2% by mass of glucomannan, 30% by mass of calcium lactate, 3% by mass of soybean polysaccharide and 64% by mass of dextrin It is described that it adds to it, cooks rice and preserves cooked rice.
  • a dietary fiber package characterized in that rice grains are attached with a hydrated gel of glucomannan, and this is heat-treated to cause irreversible gelation. Arrival of rice is described.
  • the amount of mannan hydrate gel can be used in an amount of 0.2 to 1.3 parts by weight, preferably 0.4 to 1.0 parts by weight, based on 1 part by weight of rice, and the amount of mannan hydrate gel It is stated that if the amount is less than this range, the purpose of use can not be achieved and is insufficient, while if it is more than this range, the texture is impaired.
  • Example 1 of Patent Document 2 water is added to the rapidly dissolving glucomannan composition, starch and calcium hydroxide, and stirring is performed for about 3 minutes, and pasty mannan hydrate is obtained.
  • the mixture is added to and kneaded with water-washed rice and uniformly entangled, and allowed to stand for about 30 minutes to promote gelation of mannan hydrate, which is subjected to about 10 minutes with a soft resin spatula at about 50 ° C. It is described that stirring was carried out while sending hot air and separation was carried out to obtain an encapsulated rice in which mannan hydrate without gelation of rice grains was gelled.
  • Patent Document 1 Japanese Patent Application Laid-Open No. 2013-51945
  • Patent Document 2 in order to attach rice grains with hydrated gel of glucomannan and heat-process it to cause irreversible gelation, paste-like mannan hydration is first performed. It is necessary to obtain a product, and furthermore, even after entangling mannan hydrate with rice, a complicated process is required.
  • rice grains can be glucomannan even without containing other additives, by making at least a specific amount of glucomannan, preferably further dextrin, to raw rice. It has been found that the cooked rice is frozen and thawed with good gloss, and it is possible to keep the haze low without having to go through complicated processes such as packaging with a hydrated gel of the present invention.
  • the present invention relates to a quality-modified rice which can be kept glossy and keep a low level even after freezing and thawing cooked rice by adding at least glucomannan, preferably further dextrin, and
  • the purpose is to provide a manufacturing method.
  • the quality-modified cooked rice according to the present invention is a quality-modified cooked rice in which raw rice and at least glucomannan are cooked, and the glucomannan has a weight ratio of glucomannan: raw rice of 0. 1 to raw rice. It is contained in 5: 150 to 1.5: 150.
  • the quality-modified cooked rice according to the present invention is a quality-modified cooked rice in which raw rice, glucomannan and dextrin are cooked, and the dextrin has a mass ratio of dextrin: raw rice of 0. 1 to raw rice. It is preferable that the content be 5: 150 to 0.75: 150.
  • the raw rice is preferably Japonica rice, Indica rice, Thai rice, or Javanese rice.
  • the method for producing quality-modified cooked rice according to the present invention includes adding at least glucomannan to raw rice and cooking, and the glucomannan has a weight ratio of glucomannan: raw rice of 0. 0 to the raw rice. It is contained in 5: 150 to 1.5: 150.
  • the method for producing quality-modified cooked rice according to the present invention includes adding glucomannan and further dextrin to raw rice and cooking rice, and the dextrin has a mass ratio of dextrin: raw rice of 0 to raw rice.
  • the content is preferably in the range of 5: 150 to 0.75: 150.
  • the quality-modified cooked rice according to the present invention is produced by adding and cooking at least glucomannan, preferably further dextrin, to raw rice.
  • at least glucomannan, preferably further dextrin may be used, and other additives may be added as needed.
  • the raw rice is preferably Japonica rice.
  • Raw rice may be indica rice, Thai rice, or Javanese rice.
  • refined rice or brown rice may be used.
  • Glucomannan is a natural polysaccharide complex contained in konjac. Glucomannan dissolves in water to form a high viscosity hydrosol. The sol is reacted with alkali to form a water-insoluble elastic irreversible gel. This process has long been used to produce konjac from konjac or konjac flour.
  • the konjak flour includes crude konjak flour called rough flour, and partially refined konjak flour called refined flour obtained by removing impurities such as starch and fibers from the rough flour by wind selection.
  • Glucomannan is used to improve the quality of foods other than konjac, since it has high thickening, gelling, and binding effects at low concentrations and has physiological action as a low-calorie dietary fiber.
  • konjac flour has impurities such as trimethylamine and sulfite remaining, and it is difficult to use it to improve the quality of other food products since it has a unique pungent odor. Therefore, water soluble glucomannan produced by the method disclosed in Japanese Patent Publication No. 6-97960 of the applicant is suitable for food. In this product, most of the impurities such as trimethylamine and sulfite contained in konjac flour are removed, and the average particle size thereof is crushed to about 180 ⁇ m.
  • the viscosity of the hydrosol when dissolved in water is, for example, about 38,000 mPa ⁇ s in a 1% solution, and the time to reach the peak viscosity is also long. (Note: glucomannan forms a hydrosol, so it is exactly “swelling”, but we use the term “dissolution” here).
  • Glucomannan is a ⁇ -1,4 linked polysaccharide with a molar ratio of D-glucose and D-mannose of approximately 1: 1.6, and an acetyl group is esterified at a ratio of approximately 1 per 19 sugar residues. It is connected.
  • the molecular weight of natural glucomannan varies depending on the production area and variety of konjak, and is generally 1,000,000 or more (polymerization degree: about 6,200).
  • Reox RS manufactured by Shimizu Chemical Co., Ltd.
  • Reolex One manufactured by Shimizu Chemical Co., Ltd.
  • the average particle size of the Reolex RS is about 100 ⁇ m
  • the average particle size of the Reolex One is about 25-30 ⁇ m.
  • glucomannan is contained at a mass ratio of glucomannan: raw rice of 0.5: 150 to 1.5: 150 with respect to the raw rice.
  • the dextrin has a DE (dextrose equivalent) value of 10 or less, preferably one of DE 7 to 9.
  • the dextrin be contained at a weight ratio of dextrin: raw rice of 0.5: 150 to 0.75: 150 with respect to the raw rice.
  • rice cooking additive In addition to glucomannan and dextrin, one generally used as a so-called rice cooking additive may be added as needed.
  • rice cooking oil corn salad oil, rice oil, germ oil, vegetable oil, soy lecithin, vegetable lecithin, vitamin C, natural vitamin E, sugar, milk protein, phosphate, fatty acid glycerin ester, enzyme-degraded lecithin You may add.
  • enzymes for example, as a taste-improving additive, enzymes, amylase, actinase, protease, kelp extract, maltite, papaya, dibasic calcium phosphate, sucrose fatty acid ester, calcium carbonate, sake refined, rice bran oil, chlorella extract, ethanol, L-lysine Hydrochloride, sodium L-glutamate, sodium 5-inosinate, sodium 5-guanylate may be added.
  • Boiling of rice is carried out according to a conventional method by adding water in the amount of drops to fresh rice and at least glucomannan, preferably further to dextrin, and using a pressure cooker such as a rice cooker.
  • a pressure cooker such as a rice cooker.
  • a rice cooker For example, an electric rice cooker, a gas rice cooker, an electromagnetic heating type rice cooker etc. can be used.
  • seasoning may be added to cook.
  • the quality-improved rice of the present invention was manufactured using Koshihikari (no-wash rice) from Kashihara, Hiroshima Prefecture as raw rice.
  • Koshihikari no-wash rice
  • Example 1 and Example 2 an additive consisting only of glucomannan and dextrin was added to raw rice and cooked.
  • the trade name Leolex RS (manufactured by Shimizu Chemical Co., Ltd.) was used as glucomannan.
  • Reolex XP manufactured by Shimizu Chemical Co., Ltd.
  • blended with glucomannan and dextrin at 4: 6 was used as an additive.
  • Reolex XP is a glucomannan and dextrin granulated to improve dispersibility, and has an average particle size of about 30 to 35 ⁇ m.
  • an additive consisting only of glucomannan was added to raw rice and cooked.
  • the gloss and texture of the sample were confirmed after freezing. Further, stress relaxation tests were performed on the pre-freezing sample and the post-freezing sample, and the initial compression distance (compression distance of the pre-freezing sample) and the post-freezing compression distance (compression distance of the post-freezing sample) were measured.
  • Example 4 the quality-improved rice of the present invention was produced using Thai rice produced in Thailand as raw rice.
  • Example 4 and Example 5 an additive consisting only of glucomannan and dextrin was added to raw rice and cooked.
  • the trade name Leolex RS (manufactured by Shimizu Chemical Co., Ltd.) was used as glucomannan.
  • Reolex XP (manufactured by Shimizu Chemical Co., Ltd.) blended with glucomannan and dextrin at 4: 6 was used as an additive.
  • the raw rice and the additive of the quantity shown in Table 3 were put into a rice cooker, and it cooked rice like Example 1, and produced the "sample before freezing” and the “sample after freezing.” Similar to Example 1, the gloss and texture of the frozen sample were evaluated. Moreover, the stress relaxation test of the sample before freezing and the sample after freezing was carried out similarly to Example 1, and the compression distance after compression (the compression distance of the sample before freezing) and the compression distance after freezing (compression distance of the sample after freezing) were measured. .
  • the quality-improved cooked rice of the present invention had the luster and texture like freshly cooked rice even after freezing and thawing.

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  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Cereal-Derived Products (AREA)

Abstract

Provided are: quality-improved cooked rice capable of retaining a good gloss and a good texture even when frozen; and a method for producing the same. This quality-improved cooked rice is obtained by cooking uncooked rice and at least glucomannan, wherein the glucomannan is contained at a mass ratio of 0.5:150 to 1.5:150 (glucomannan:uncooked rice) relative to the uncooked rice. This method for producing the quality-improved cooked rice comprises cooking uncooked rice after adding at least glucomannan, wherein the glucomannan is contained at a mass ratio of 0.5:150 to 1.5:150 (glucomannan:uncooked rice) relative to the uncooked rice.

Description

品質改良米飯とその製造方法Quality-improved cooked rice and its manufacturing method
 本発明は、品質を改良された米飯とその製造方法に関する。 The present invention relates to quality-improved rice and its production method.
 従来、チルドまたは冷凍保存される米飯の艶や食感を、炊きたての米飯の艶や食感に近づけるよう、工夫がされている。 In the past, devices have been devised to bring the gloss and texture of chilled or frozen stored rice closer to the gloss and texture of freshly cooked rice.
 例えば、特開2013-51945号公報(特許文献1)には、プロテアーゼ、グルコマンナンおよび乳酸塩を米飯の炊飯時に添加することを特徴とするチルドまたは冷凍保存された米飯の食感保持方法と、プロテアーゼ、グルコマンナンおよび乳酸塩を含有することを特徴とするチルドまたは冷凍米飯用食感改良剤が記載されている。具体的には、例えば、プロテアーゼ1質量%、グルコマンナン2質量%、乳酸カルシウム30質量%、大豆多糖類3質量%、デキストリン64質量%が配合された米飯用改良剤3gを、生米300gに対して添加し、炊飯して米飯を保存することが記載されている。 For example, Japanese Patent Application Laid-Open No. 2013-51945 (Patent Document 1) provides a method for maintaining the texture of chilled or frozen preserved rice, which comprises adding protease, glucomannan and lactate at the time of cooking of cooked rice; A texture modifier for chilled or frozen rice is described which is characterized in that it contains a protease, glucomannan and lactate. Specifically, for example, 3 g of a rice improver containing 3% by mass of protease, 1% by mass of protease, 2% by mass of glucomannan, 30% by mass of calcium lactate, 3% by mass of soybean polysaccharide and 64% by mass of dextrin It is described that it adds to it, cooks rice and preserves cooked rice.
 また例えば、特開2001-121号公報(特許文献2)には、米粒をグルコマンナンの水和ゲルで包着し、これを加熱処理して不可逆的ゲル化したことを特徴とする食物繊維包着米が記載されている。マンナン水和物のゲルの量は、米1重量部に対し0.2~1.3重量部、好ましくは0.4~1.0重量部使用することができ、マンナン水和物ゲルの量がこの範囲より少ないと使用目的が達せられず不十分であり、一方、多いと食感を損なうなど不良であることが記載されている。また、特許文献2の実施例1には、具体的には、即溶解性グルコマンナン組成物、デンプン及び水酸化カルシウムに対し水を加えて約3分間撹拌し、糊状のマンナン水和物を得て、これを水洗い米に添加混練して万遍なく絡ませた後、約30分静置してマンナン水和物のゲル進行を図り、これを軟性の樹脂ヘラで約10分、約50℃の熱風を送りながらかき回して分離させ、米粒の連結がないマンナン水和物がゲル化した包着米を取得したことが記載されている。 For example, in Japanese Patent Application Laid-Open No. 2001-121 (patent document 2), a dietary fiber package characterized in that rice grains are attached with a hydrated gel of glucomannan, and this is heat-treated to cause irreversible gelation. Arrival of rice is described. The amount of mannan hydrate gel can be used in an amount of 0.2 to 1.3 parts by weight, preferably 0.4 to 1.0 parts by weight, based on 1 part by weight of rice, and the amount of mannan hydrate gel It is stated that if the amount is less than this range, the purpose of use can not be achieved and is insufficient, while if it is more than this range, the texture is impaired. In addition, specifically, in Example 1 of Patent Document 2, water is added to the rapidly dissolving glucomannan composition, starch and calcium hydroxide, and stirring is performed for about 3 minutes, and pasty mannan hydrate is obtained. The mixture is added to and kneaded with water-washed rice and uniformly entangled, and allowed to stand for about 30 minutes to promote gelation of mannan hydrate, which is subjected to about 10 minutes with a soft resin spatula at about 50 ° C. It is described that stirring was carried out while sending hot air and separation was carried out to obtain an encapsulated rice in which mannan hydrate without gelation of rice grains was gelled.
特開2013-51945号公報JP, 2013-51945, A 特開2001-121号公報JP 2001-121 A
 しかしながら、特開2013-51945号公報(特許文献1)では、プロテアーゼ、グルコマンナン、乳酸カルシウム、大豆多糖類、デキストリン、といった多数の添加物を組み合わせて使用する必要があり、米飯を摂取者は米の品質をごまかされ、酸化した米に含まれる過酸化脂質、塩分、油分の過剰摂取になる場合がある。 However, in Japanese Patent Application Laid-Open No. 2013-51945 (Patent Document 1), it is necessary to use many additives such as protease, glucomannan, calcium lactate, soybean polysaccharide, and dextrin in combination, and those who consume rice are rice In some cases, it may lead to excess intake of lipid peroxide, salt and oil contained in oxidized rice.
 また、特開2001-121号公報(特許文献2)では、米粒をグルコマンナンの水和ゲルで包着し、これを加熱処理して不可逆的ゲル化するために、まず糊状のマンナン水和物を得る必要があり、さらに、マンナン水和物を米に絡ませた後にも、煩雑な工程が必要である。 In addition, in Japanese Patent Application Laid-Open No. 2001-121 (Patent Document 2), in order to attach rice grains with hydrated gel of glucomannan and heat-process it to cause irreversible gelation, paste-like mannan hydration is first performed. It is necessary to obtain a product, and furthermore, even after entangling mannan hydrate with rice, a complicated process is required.
 本発明者らは、鋭意研究の結果、少なくともグルコマンナン、好ましくはさらにデキストリンを生米に対して特定の含有量にすることによって、その他の添加剤を含まなくても、また、米粒をグルコマンナンの水和ゲルで包着するような煩雑な工程を経なくても、炊飯された米飯を冷凍し、解凍した後でも艶がよく、ぱさつきを少なく保つことが可能であることを見出した。 As a result of earnest research, the present inventors have also found that rice grains can be glucomannan even without containing other additives, by making at least a specific amount of glucomannan, preferably further dextrin, to raw rice. It has been found that the cooked rice is frozen and thawed with good gloss, and it is possible to keep the haze low without having to go through complicated processes such as packaging with a hydrated gel of the present invention.
 そこで本発明は、少なくともグルコマンナン、好ましくはさらにデキストリンを添加することによって、炊飯された米飯を冷凍し、解凍した後でも、艶がよく、ぱさつきを少なく保つことが可能な品質改良米飯と、その製造方法を提供することを目的とする。 Therefore, the present invention relates to a quality-modified rice which can be kept glossy and keep a low level even after freezing and thawing cooked rice by adding at least glucomannan, preferably further dextrin, and The purpose is to provide a manufacturing method.
 本発明に従った品質改良米飯は、生米と、少なくともグルコマンナンとが炊飯された品質改良米飯であって、グルコマンナンは、生米に対して、グルコマンナン:生米の質量比が0.5:150~1.5:150で含有されている。 The quality-modified cooked rice according to the present invention is a quality-modified cooked rice in which raw rice and at least glucomannan are cooked, and the glucomannan has a weight ratio of glucomannan: raw rice of 0. 1 to raw rice. It is contained in 5: 150 to 1.5: 150.
 本発明に従った品質改良米飯は、生米とグルコマンナンと、さらにデキストリンとが炊飯された品質改良米飯であって、デキストリンは、生米に対して、デキストリン:生米の質量比が0.5:150~0.75:150で含有されていることが好ましい。 The quality-modified cooked rice according to the present invention is a quality-modified cooked rice in which raw rice, glucomannan and dextrin are cooked, and the dextrin has a mass ratio of dextrin: raw rice of 0. 1 to raw rice. It is preferable that the content be 5: 150 to 0.75: 150.
 本発明に従った品質改良米飯においては、生米は、ジャポニカ米、インディカ米、タイ米、または、ジャバニカ米であることが好ましい。 In the quality-modified rice according to the present invention, the raw rice is preferably Japonica rice, Indica rice, Thai rice, or Javanese rice.
 本発明に従った品質改良米飯の製造方法は、生米に少なくともグルコマンナンを添加して炊飯することを含み、グルコマンナンは、生米に対して、グルコマンナン:生米の質量比が0.5:150~1.5:150で含有されている。 The method for producing quality-modified cooked rice according to the present invention includes adding at least glucomannan to raw rice and cooking, and the glucomannan has a weight ratio of glucomannan: raw rice of 0. 0 to the raw rice. It is contained in 5: 150 to 1.5: 150.
 本発明に従った品質改良米飯の製造方法は、生米にグルコマンナンと、さらにデキストリンを添加して炊飯することを含み、デキストリンは、生米に対して、デキストリン:生米の質量比が0.5:150~0.75:150で含有されていることが好ましい。 The method for producing quality-modified cooked rice according to the present invention includes adding glucomannan and further dextrin to raw rice and cooking rice, and the dextrin has a mass ratio of dextrin: raw rice of 0 to raw rice. The content is preferably in the range of 5: 150 to 0.75: 150.
 以下、本発明の実施の形態を説明するが、本発明はこれに限定されるものではない。 Hereinafter, although an embodiment of the present invention is described, the present invention is not limited to this.
 本発明に従った品質改良米飯は、少なくともグルコマンナン、好ましくはさらにデキストリンとを生米に添加して炊飯することによって製造される。添加物としては、少なくともグルコマンナン、好ましくはさらにデキストリンが用いられればよく、必要に応じて、他の添加物が添加されてもよい。 The quality-modified cooked rice according to the present invention is produced by adding and cooking at least glucomannan, preferably further dextrin, to raw rice. As an additive, at least glucomannan, preferably further dextrin, may be used, and other additives may be added as needed.
 本発明に従った品質改良米飯において、生米はジャポニカ米であることが好ましい。生米は、インディカ米やタイ米、ジャバニカ米であってもよい。また、精白米でも玄米でもよい。 In the quality-modified cooked rice according to the present invention, the raw rice is preferably Japonica rice. Raw rice may be indica rice, Thai rice, or Javanese rice. In addition, refined rice or brown rice may be used.
 グルコマンナンはこんにゃく芋に含まれる天然多糖類複合体である。グルコマンナンは水に溶け、高粘度のヒドロゾルを形成する。このゾルをアルカリと反応させると水に不溶な弾力性不可逆ゲルを作る。このプロセスは古くからこんにゃく芋またはこんにゃく粉からこんにゃくを製造するために利用されている。こんにゃく粉には荒粉と呼ばれる粗製こんにゃく粉と、風選により荒粉からデンプン、繊維等の不純物を取り除いた精粉と呼ばれる部分的に精製したこんにゃく粉とがある。 Glucomannan is a natural polysaccharide complex contained in konjac. Glucomannan dissolves in water to form a high viscosity hydrosol. The sol is reacted with alkali to form a water-insoluble elastic irreversible gel. This process has long been used to produce konjac from konjac or konjac flour. The konjak flour includes crude konjak flour called rough flour, and partially refined konjak flour called refined flour obtained by removing impurities such as starch and fibers from the rough flour by wind selection.
 グルコマンナンには低濃度で高い増粘作用、ゲル作用、結着作用があり、低カロリーの食物繊維として生理作用を有することから、こんにゃく以外の食品の品質を改良するために使用される。しかしながら、こんにゃく精粉はトリメチルアミンや亜硫酸塩などの不純物が残留し、特異な刺激臭を有することからこれを他の食品の品質を改良するために使用することは困難である。このため食品用には出願人の特公平6-97960号に開示されている方法などによって製造された易水溶性グルコマンナンが適している。このものはこんにゃく精粉中に含まれるトリメチルアミンや亜硫酸塩などの不純物は殆ど取り除かれ、かつその平均粒子径は約180μm程度に粉砕されている。水に溶解した時のヒドロゾルの粘度は例えば1%溶液で約38,000mPa・s程度であり、かつピーク粘度に達するまでの時間も長い。(注:グルコマンナンはヒドロゾルを形成するので、正確には「膨潤」であるが、ここでは「溶解」の用語を使用する。) Glucomannan is used to improve the quality of foods other than konjac, since it has high thickening, gelling, and binding effects at low concentrations and has physiological action as a low-calorie dietary fiber. However, konjac flour has impurities such as trimethylamine and sulfite remaining, and it is difficult to use it to improve the quality of other food products since it has a unique pungent odor. Therefore, water soluble glucomannan produced by the method disclosed in Japanese Patent Publication No. 6-97960 of the applicant is suitable for food. In this product, most of the impurities such as trimethylamine and sulfite contained in konjac flour are removed, and the average particle size thereof is crushed to about 180 μm. The viscosity of the hydrosol when dissolved in water is, for example, about 38,000 mPa · s in a 1% solution, and the time to reach the peak viscosity is also long. (Note: glucomannan forms a hydrosol, so it is exactly "swelling", but we use the term "dissolution" here).
 グルコマンナンは、D-グルコースとD-マンノースがほぼ1:1.6のモル比でβ-1,4結合した多糖類であり、ほぼ糖残基19個につき1個の割合でアセチル基がエステル結合している。天然グルコマンナンの分子量はこんにゃく芋の産地や品種によって変動し、一般に100万以上(重合度約6,200)である。 Glucomannan is a β-1,4 linked polysaccharide with a molar ratio of D-glucose and D-mannose of approximately 1: 1.6, and an acetyl group is esterified at a ratio of approximately 1 per 19 sugar residues. It is connected. The molecular weight of natural glucomannan varies depending on the production area and variety of konjak, and is generally 1,000,000 or more (polymerization degree: about 6,200).
 グルコマンナンとしては、例えば、商品名レオレックスRS(清水化学株式会社製)やレオレックスOne(清水化学株式会社製)を用いることができる。レオレックスRSの平均粒子径は約100μmであり、レオレックスOneの平均粒子径は約25~30μmである。 As glucomannan, for example, trade name Reox RS (manufactured by Shimizu Chemical Co., Ltd.) or Reolex One (manufactured by Shimizu Chemical Co., Ltd.) can be used. The average particle size of the Reolex RS is about 100 μm, and the average particle size of the Reolex One is about 25-30 μm.
 本発明に従った品質改良米飯において、グルコマンナンは、生米に対して、グルコマンナン:生米の質量比が0.5:150~1.5:150で含有されている。 In the quality-modified cooked rice according to the present invention, glucomannan is contained at a mass ratio of glucomannan: raw rice of 0.5: 150 to 1.5: 150 with respect to the raw rice.
 デキストリンは、DE(dextrose equivalent)値が10以下のもので、好ましくはDE7~9のものが好ましい。 The dextrin has a DE (dextrose equivalent) value of 10 or less, preferably one of DE 7 to 9.
 本発明に従った品質改良米飯において、デキストリンは、生米に対して、デキストリン:生米の質量比が0.5:150~0.75:150で含有されていることが好ましい。 In the quality-modified cooked rice according to the present invention, it is preferable that the dextrin be contained at a weight ratio of dextrin: raw rice of 0.5: 150 to 0.75: 150 with respect to the raw rice.
 グルコマンナンとデキストリンの他に、一般的にいわゆる炊飯添加剤として用いられるものを必要に応じて添加してもよい。例えば、炊飯油として、コーンサラダ油、米油、胚芽油、植物性油脂、大豆レシチン、植物性レシチン、ビタミンC、天然ビタミンE、糖類、乳タンパク、リン酸塩、脂肪酸グリセリンエステル、酵素分解レシチンを添加してもよい。また例えば、食味改良添加剤として、酵素、アミラーゼ、アクチアーゼ、プロテアーゼ、コンブエキス、マルチット、パパイア、第2リン酸カルシウム、ショ糖脂肪酸エステル、炭酸カルシウム、酒精、米ぬか油、クロレラ抽出液、エタノール、L-リジン塩酸塩、L-グルタミン酸ナトリウム、5-イノシン酸ナトリウム、5-グアニル酸ナトリウムを添加してもよい。 In addition to glucomannan and dextrin, one generally used as a so-called rice cooking additive may be added as needed. For example, as rice cooking oil, corn salad oil, rice oil, germ oil, vegetable oil, soy lecithin, vegetable lecithin, vitamin C, natural vitamin E, sugar, milk protein, phosphate, fatty acid glycerin ester, enzyme-degraded lecithin You may add. Also, for example, as a taste-improving additive, enzymes, amylase, actinase, protease, kelp extract, maltite, papaya, dibasic calcium phosphate, sucrose fatty acid ester, calcium carbonate, sake refined, rice bran oil, chlorella extract, ethanol, L-lysine Hydrochloride, sodium L-glutamate, sodium 5-inosinate, sodium 5-guanylate may be added.
 炊飯は、生米と少なくともグルコマンナン、好ましくはさらにデキストリンに、滴量の水を加えて、炊飯器などの常圧窯で常法により行われる。炊飯器は、特に制限はなく、例えば電気炊飯器、ガス炊飯器、電磁加熱型炊飯器等を用いることができる。添加剤の他に、調味料を加えて炊飯してもよい。 Boiling of rice is carried out according to a conventional method by adding water in the amount of drops to fresh rice and at least glucomannan, preferably further to dextrin, and using a pressure cooker such as a rice cooker. There is no restriction | limiting in particular in a rice cooker, For example, an electric rice cooker, a gas rice cooker, an electromagnetic heating type rice cooker etc. can be used. In addition to the additives, seasoning may be added to cook.
 炊きあがった米飯は、室温に放置して粗熱を取った後、冷凍して冷凍米飯にされることもできる。冷凍米飯は、常法により、-5℃以下で凍結・保存することによって製造される。また、炊きあがった米飯を、1~15℃のチルド温度帯で保存してチルド米飯にすることもできる。このようにして製造差れた冷凍米飯またはチルド米飯は、常法により調理して食される。 The cooked rice may be left at room temperature to take coarse heat, and then frozen to be frozen rice. Frozen rice is produced by freezing and storing at -5 ° C. or less according to a conventional method. Alternatively, the cooked rice can be stored in a chilled temperature range of 1 to 15 ° C. to make a chilled rice. The frozen cooked rice or chilled cooked rice produced in this manner is prepared and eaten according to a conventional method.
 以下、実施例等により本発明をさらに詳細に説明するが、本発明はこれに限定されるものではない。 Hereinafter, the present invention will be described in more detail by way of examples and the like, but the present invention is not limited thereto.
 広島県庄原産こしひかり(無洗米)を生米として用いて本願発明の品質改良米飯を製造した。実施例1と実施例2では、生米に、グルコマンナンとデキストリンのみからなる添加剤を加えて炊飯した。実施例1では、グルコマンナンとして商品名レオレックスRS(清水化学株式会社製)を用いた。実施例2では、グルコマンナンとデキストリンが4:6で配合されたレオレックスXP(清水化学株式会社製)を添加剤として用いた。レオレックスXPは、グルコマンナンとデキストリンが分散性向上のために造粒されたものであり、平均粒子径は約30~35μmである。実施例3では、生米に、グルコマンナンのみからなる添加剤を加えて炊飯した。 The quality-improved rice of the present invention was manufactured using Koshihikari (no-wash rice) from Kashihara, Hiroshima Prefecture as raw rice. In Example 1 and Example 2, an additive consisting only of glucomannan and dextrin was added to raw rice and cooked. In Example 1, the trade name Leolex RS (manufactured by Shimizu Chemical Co., Ltd.) was used as glucomannan. In Example 2, Reolex XP (manufactured by Shimizu Chemical Co., Ltd.) blended with glucomannan and dextrin at 4: 6 was used as an additive. Reolex XP is a glucomannan and dextrin granulated to improve dispersibility, and has an average particle size of about 30 to 35 μm. In Example 3, an additive consisting only of glucomannan was added to raw rice and cooked.
 対照1、実施例1、実施例2、実施例3のそれぞれの生米、グルコマンナン、デキストリン、水の分量は表1の通りであった。 The amounts of raw rice, glucomannan, dextrin, and water of each of Control 1, Example 1, Example 2, and Example 3 were as shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1に示す分量の生米と添加剤を炊飯器に入れ、水を加え、手で混ぜた後、30分加水し、炊飯器(株式会社東芝製 TOSHIBA RC-10HK)を用いて常法で炊飯した。炊飯後、30分間蒸らし、1個当たり約17gずつ平らに丸めて成型して試料米飯とし、ラップフィルムにくるんだ。室温に放置して粗熱を取り、-27℃で14日間、冷凍保管した。上述の試料米飯について、室温に放置して室温まで自然に放熱したものを「冷凍前試料」、米飯を冷凍した後室温で解凍したものを「冷凍後試料」とした。冷凍後試料の艶と食感を確認した。また、冷凍前試料と冷凍後試料の応力緩和試験を行い、当初圧縮距離(冷凍前試料の圧縮距離)と冷凍後圧縮距離(冷凍後試料の圧縮距離)を測定した。 Put raw rice and additives in the quantities shown in Table 1 into a rice cooker, add water, mix by hand, add water for 30 minutes, and then use a rice cooker (TOSHIBA RC-10HK made by Toshiba Corporation) in the usual way I cooked rice. After cooking, it was steamed for 30 minutes, and each piece was roughly rolled by approximately 17 g and molded into a sample rice and wrapped in a wrap film. It was left at room temperature to remove crude heat and stored frozen at -27 ° C for 14 days. About the above-mentioned sample boiled rice, what was left to stand at room temperature and released heat naturally to room temperature was made into "the sample before freezing", what thawed at room temperature after freezing boiled rice was made "sample after freezing". The gloss and texture of the sample were confirmed after freezing. Further, stress relaxation tests were performed on the pre-freezing sample and the post-freezing sample, and the initial compression distance (compression distance of the pre-freezing sample) and the post-freezing compression distance (compression distance of the post-freezing sample) were measured.
 <官能試験>
 5名のパネラーが艶と食感を0点(悪い)から5点(良い)で評価し、平均点を算出した。艶について、対照1は3.0点、実施例1は4.0点、実施例2も4.0点、実施例3は3.5であった。食感について、対照1は3.25点、実施例1は4.0点、実施例2も4.0点、実施例3は3.75であった。なお、実施例3は、実施例1,2と比較すると、糸を引き、粘っぽい食味であった。
<Sensory test>
Five panelists rated gloss and texture from 0 (bad) to 5 (good) to calculate the average score. As for the gloss, the control 1 had 3.0 points, the example 1 had 4.0 points, the example 2 had 4.0 points, and the example 3 had 3.5. As to the texture, Control 1 had 3.25 points, Example 1 had 4.0 points, Example 2 had 4.0 points, and Example 3 had 3.75. In addition, compared with Examples 1 and 2, Example 3 pulled a thread | yarn and was a sticky taste.
 <応力緩和試験>
 直径3cm、厚み1cmに成型した米飯について、株式会社レオテック製「FUDOH レオメーターRTC」を用いて、プランジャーNo.3(3cm)を用い、荷重2kg、60秒にて応力緩和試験を行って圧縮距離を測定した。結果は表2の通りであった。
<Stress relaxation test>
Using the “FUDOH Rheometer RTC” manufactured by Leotech Co., Ltd., the No. 3 plunger with a diameter of 3 cm and a thickness of 1 cm was used. Using 3 (3 cm), a stress relaxation test was performed at a load of 2 kg for 60 seconds to measure the compression distance. The results are as shown in Table 2.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 表2に示すように、実施例1,2では、米飯を冷凍した後室温で解凍したときの冷凍後圧縮距離との差が、当初圧縮距離の10%以下であり、冷凍後に解凍しても、ぱさつきが感じられない、炊きたてのようなふっくらした食感の米飯であった。 As shown in Table 2, in Examples 1 and 2, the difference between the frozen post-freeze compression distance and the post-freeze compression distance when frozen after freezing the rice is 10% or less of the initial compression distance, and even after thawing , It was a cooked rice with a plump texture like freshly cooked rice that I could not feel pasatsuki.
 次に、タイ国産のタイ米を生米として用いて本願発明の品質改良米飯を製造した。実施例4と実施例5では、生米に、グルコマンナンとデキストリンのみからなる添加剤を加えて炊飯した。実施例4では、グルコマンナンとして商品名レオレックスRS(清水化学株式会社製)を用いた。実施例5では、グルコマンナンとデキストリンが4:6で配合されたレオレックスXP(清水化学株式会社製)を添加剤として用いた。 Next, the quality-improved rice of the present invention was produced using Thai rice produced in Thailand as raw rice. In Example 4 and Example 5, an additive consisting only of glucomannan and dextrin was added to raw rice and cooked. In Example 4, the trade name Leolex RS (manufactured by Shimizu Chemical Co., Ltd.) was used as glucomannan. In Example 5, Reolex XP (manufactured by Shimizu Chemical Co., Ltd.) blended with glucomannan and dextrin at 4: 6 was used as an additive.
 対照2、実施例4、実施例5のそれぞれの生米、グルコマンナン、デキストリン、水の分量は表3の通りであった。 The amounts of raw rice, glucomannan, dextrin, and water of each of Control 2, Example 4, and Example 5 were as shown in Table 3.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 表3に示す分量の生米と添加剤を炊飯器に入れ、実施例1と同様に炊飯し、「冷凍前試料」と「冷凍後試料」を作製した。実施例1と同様に、冷凍後試料の艶と食感を評価した。また、実施例1と同様に、冷凍前試料と冷凍後試料の応力緩和試験を行い、当初圧縮距離(冷凍前試料の圧縮距離)と冷凍後圧縮距離(冷凍後試料の圧縮距離)を測定した。 The raw rice and the additive of the quantity shown in Table 3 were put into a rice cooker, and it cooked rice like Example 1, and produced the "sample before freezing" and the "sample after freezing." Similar to Example 1, the gloss and texture of the frozen sample were evaluated. Moreover, the stress relaxation test of the sample before freezing and the sample after freezing was carried out similarly to Example 1, and the compression distance after compression (the compression distance of the sample before freezing) and the compression distance after freezing (compression distance of the sample after freezing) were measured. .
 <官能試験>
 5名のパネラーが艶と食感を0点(悪い)から5点(良い)で評価し、平均点を算出した。艶について、対照2は3.0点、実施例4は3.5点、実施例5も3.5点であった。食感について、対照2は2.5点、実施例4は3.0点、実施例5も3.0点であった。
<Sensory test>
Five panelists rated gloss and texture from 0 (bad) to 5 (good) to calculate the average score. As for gloss, the control 2 had 3.0 points, the example 4 had 3.5 points, and the example 5 also had 3.5 points. As to the texture, the control 2 was 2.5 points, the example 4 was 3.0 points, and the example 5 was also 3.0 points.
 <応力緩和試験>
 実施例1と同様に、応力緩和試験を行って圧縮距離を測定した。結果は表4の通りであった。
<Stress relaxation test>
As in Example 1, a stress relaxation test was performed to measure the compression distance. The results are as shown in Table 4.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 表4に示すように、実施例4,5では、米飯を冷凍した後室温で解凍したときの冷凍後圧縮距離との差が、当初圧縮距離の10%以下であり、冷凍後に解凍しても、ぱさつきが感じられない、炊きたてのようなふっくらした食感の米飯であった。 As shown in Table 4, in Examples 4 and 5, the difference between the frozen post-freeze compression distance and the post-freeze compression distance when frozen after simmering the rice is 10% or less of the initial compression distance, and even after thawing , It was a cooked rice with a plump texture like freshly cooked rice that I could not feel pasatsuki.
 以上のように、本発明の品質改良米飯は、冷凍・解凍後でも、炊きたての米飯のような艶と食感であった。 As described above, the quality-improved cooked rice of the present invention had the luster and texture like freshly cooked rice even after freezing and thawing.
 以上に開示された実施の形態と実施例はすべての点で例示であって制限的なものではないと考慮されるべきである。本発明の範囲は、以上の実施の形態と実施例ではなく、請求の範囲によって示され、請求の範囲と均等の意味および範囲内でのすべての修正や変形を含むものである。 The embodiments and examples disclosed above should be considered in all respects as illustrative and not restrictive. The scope of the present invention is shown not by the above embodiments and examples but by the scope of claims, and includes all modifications and variations within the meaning and scope equivalent to the scope of claims.

Claims (5)

  1.  生米と、少なくともグルコマンナンとが炊飯された品質改良米飯であって、
     前記グルコマンナンは、前記生米に対して、前記グルコマンナン:前記生米の質量比が0.5:150~1.5:150で含有されている、品質改良米飯。
    Quality-modified rice, in which raw rice and at least glucomannan are cooked,
    The quality-modified cooked rice, wherein the glucomannan is contained at a mass ratio of the glucomannan to the fresh rice of 0.5: 150 to 1.5: 150 with respect to the fresh rice.
  2.  生米とグルコマンナンと、さらにデキストリンとが炊飯された品質改良米飯であって、
     前記デキストリンは、前記生米に対して、前記デキストリン:前記生米の質量比が0.5:150~0.75:150で含有されている、請求項1に記載の品質改良米飯。
    Quality-modified rice, in which raw rice, glucomannan, and dextrin are cooked,
    The quality-modified cooked rice according to claim 1, wherein the dextrin is contained in a ratio by weight of the dextrin to the fresh rice of 0.5: 150 to 0.75: 150 with respect to the fresh rice.
  3.  前記生米は、ジャポニカ米、インディカ米、タイ米、または、ジャバニカ米である、請求項1に記載の品質改良米飯。 The quality improved rice according to claim 1, wherein the uncooked rice is Japonica rice, Indica rice, Thai rice, or Javanica rice.
  4.  生米に少なくともグルコマンナンを添加して炊飯することを含み、
     前記グルコマンナンは、前記生米に対して、前記グルコマンナン:前記生米の質量比が0.5:150~1.5:150で含有されている、品質改良米飯の製造方法。
    Including adding at least glucomannan to raw rice and cooking rice,
    The method for producing quality-modified rice, wherein the glucomannan is contained at a mass ratio of the glucomannan: the raw rice of 0.5: 150 to 1.5: 150 with respect to the raw rice.
  5.  生米とグルコマンナンに、さらにデキストリンを添加して炊飯することを含み、
     前記デキストリンは、前記生米に対して、前記デキストリン:前記生米の質量比が0.5:150~0.75:150で含有されている、請求項4に記載の製造方法。
    Including adding dextrin to raw rice and glucomannan, and cooking,
    5. The method according to claim 4, wherein the dextrin is contained in a weight ratio of 0.5: 150 to 0.75: 150 for the dextrin: the raw rice relative to the raw rice.
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