WO2019100312A1 - Antibacterial, wear-resistant and anti-slip back gum for use in carpet - Google Patents

Antibacterial, wear-resistant and anti-slip back gum for use in carpet Download PDF

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Publication number
WO2019100312A1
WO2019100312A1 PCT/CN2017/112771 CN2017112771W WO2019100312A1 WO 2019100312 A1 WO2019100312 A1 WO 2019100312A1 CN 2017112771 W CN2017112771 W CN 2017112771W WO 2019100312 A1 WO2019100312 A1 WO 2019100312A1
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layer
resistant
antibacterial
slip
wear
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PCT/CN2017/112771
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French (fr)
Chinese (zh)
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张唯舟
汪济奎
陈银
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苏州康邦新材料有限公司
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Priority to PCT/CN2017/112771 priority Critical patent/WO2019100312A1/en
Publication of WO2019100312A1 publication Critical patent/WO2019100312A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material

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  • the utility model relates to an antibacterial, wear-resistant and anti-slip adhesive for carpet.
  • thermoplastic elastomer TPE is a material with high elasticity, high strength, high resilience and the characteristics of injection mold processing. It has environmental protection, non-toxic safety, wide hardness range, excellent coloring property, soft touch, weather resistance, fatigue resistance and temperature resistance. It has excellent processing performance, no need for vulcanization, and can be recycled to reduce costs. It can be used for double injection molding. It can be coated with a base material such as PP, PE, PC, PS or ABS, or it can be molded separately.
  • Thermoplastic elastomers have the physical and mechanical properties of vulcanized rubber and the processability of thermoplastics. Since there is no need for thermal vulcanization, the production of the product can be completed using general-purpose plastic processing equipment. This feature has shortened the production process of the rubber industry by 1/4, saved energy by 25% to 40%, and improved efficiency by 10 to 20 times. It is another revolution in materials and process technology in the rubber industry.
  • TPE/TPR elastomer refers to the alloy elastomer modified based on SEBS and SBS.
  • TPE the elastomer modified by SEBS
  • SBS base is modified.
  • the elastomer is called TPR.
  • SEBS is a polymer material with a saturated molecular structure, while the SBS molecular structural unit contains an unsaturated double bond.
  • the unsaturated double bond is chemically unstable, so in general, SEBS has more than SBS. Excellent chemical stability (such as aging resistance, UV resistance). Accordingly, TPE has better aging and UV resistance than TPR.
  • the TPE of the TPE.SEBS substrate which is usually selected from the SEBS substrate can generally achieve a UV resistance of 3.5.
  • a UV resistance for the aging resistance, some non-authoritative effects from some users indicate
  • the SEBS TPE can usually be used in conventional non-extreme outdoor conditions for about 6 months without yellowing (UV resistance), while the use of 12 months of material does not cause significant aging and performance degradation.
  • Patent Publication No.: CN105111979A discloses an environmentally-friendly antibacterial flame-retardant TPE carpet backing powder, the preparation thereof comprises: MAH-g-SEBS, MAH-g-PP, polyquaternium-chitosan-hyperbranched Polyurethane composite and sulfonated polyimide modified graphene oxide.
  • the invention also discloses a preparation method of the environmentally-friendly antibacterial flame-retardant TPE carpet backing powder.
  • the patent mainly imparts antibacterial and flame retardant properties to the carpet backing by changing the composition, and the addition of graphene will affect its wear resistance and anti-slip performance.
  • the utility model aims to provide an antibacterial, wear-resistant and anti-slip TPE adhesive for carpets, which has the characteristics of high production efficiency, environmental protection, anti-skid and yellowing resistance, and is effectively improved.
  • An antibacterial, wear-resistant, non-slip TPE adhesive for carpets comprising: a backing layer, a plurality of circular grooves are formed on the other side of the carpet, the inner diameter is 0.1-0.2 mm; and the inner-outer coating is applied to the The anti-adhesive layer, the wear-resistant layer and the anti-slip layer of the adhesive layer on the other side of the carpet; the backing layer is formed by melt extrusion of the thermoplastic elastomer TPE.
  • the antibacterial layer is a silver-loaded nano-SiO 2 antibacterial layer having a thickness of 0.1 to 0.5 mm.
  • the wear-resistant layer is a biaxially oriented polypropylene film layer having a thickness of 0.5 to 1 cm.
  • the anti-slip layer is a polyvinyl chloride foam layer having a thickness of 1 to 3 cm.
  • the anti-slip layer is provided with an anti-slip pattern on the other side of the wear-resistant layer.
  • the TPE sealing ring has a hardness of 35 to 55 A.
  • the TPE sealing ring has a specific gravity of 1.1 to 1.3.
  • the TPE adhesive has the characteristics of high production efficiency, environmental protection, anti-slip, yellowing resistance, etc., and effectively improves the defects of the yellow edge, sticky floor and large smell of the latex produced by the customer, and has comfortable hand feeling, recovery property, good elasticity and wear resistance. Good performance, high temperature resistance, machine wash resistance, washing machine without washing, environmental protection, non-toxic and odorless, simple processing technology, high output and low cost.
  • FIG. 1 is a schematic view showing the structure of an antibacterial, wear-resistant and anti-slip TPE adhesive for a carpet according to an embodiment of the present invention.
  • an antibacterial, wear-resistant and anti-slip TPE adhesive for a carpet comprises: a backing layer 1 , and a plurality of circular grooves (not shown) are opened on the other side of the carpet, and the inner diameter is 0.1 to 0.2 mm; applied from the inside to the outside in the antibacterial layer 2, the wear layer 3 and the anti-slip layer 4 on the other side of the backing layer 1; the backing layer 1 is made of a thermoplastic elastomer TPE Melt extrusion is formed.
  • the antibacterial layer 2 is a silver-loaded nano-SiO 2 antibacterial layer having a thickness of 0.1 to 0.5 mm.
  • the wear-resistant layer 3 is a biaxially oriented polypropylene film layer having a thickness of 0.5 to 1 cm.
  • the anti-slip layer 4 is a polyvinyl chloride foam layer having a thickness of 1 to 3 cm.
  • the anti-slip layer 4 is provided with an anti-slip pattern (not shown) on the other side of the wear-resistant layer.
  • the TPE sealing ring has a hardness of 35 to 55 A.
  • the TPE sealing ring has a specific gravity of 1.1 to 1.3.
  • the utility model relates to an antibacterial, wear-resistant and anti-slip TPE adhesive for carpets, which has the characteristics of high production efficiency, environmental protection, anti-skid and yellowing resistance, and effectively improves the yellow edge of the customer to use latex production, and sticks the floor.
  • Large odor and other defects comfortable feel, recovery, good elasticity, good wear resistance, high temperature resistance, machine wash resistance, washing machine without washing, environmental protection, non-toxic and odorless, simple processing technology, high output and low cost.

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  • Carpets (AREA)

Abstract

An antibacterial, wear-resistant and anti-slip thermoplastic elastomer (TPE) back gum for use in a carpet, comprising: a back gum layer, in which opened on a side opposite to a carpet are a plurality of circular grooves having an inner diameter of 0.1-0.2 mm; an antibacterial layer, a wear-resistant layer and an anti-slip layer are sequentially coated from the inside to the outside on the back gum layer on the side opposite to the carpet; the back gum layer is formed by means of performing melt extrusion on a TPE. The TPE back gum has characteristics such as high production efficiency, environmental friendliness, being anti-slip and yellowing-resistant, and the like, and effectively overcomes defects in latex products currently used by customers, such as rapid yellowing of the edge, adhesiveness to a floor and significant odor.

Description

一种地毯用抗菌、耐磨、防滑背胶Antibacterial, wear-resistant and anti-slip adhesive for carpet 技术领域Technical field
本实用新型涉及一种地毯用抗菌、耐磨、防滑背胶。The utility model relates to an antibacterial, wear-resistant and anti-slip adhesive for carpet.
背景技术Background technique
热塑性弹性体TPE(Thermoplastic Elastomer)是一种具有橡胶的高弹性,高强度,高回弹性,又具有可注塑加工的特征的材料。具有环保无毒安全,硬度范围广,有优良的着色性,触感柔软,耐候性,抗疲劳性和耐温性,加工性能优越,无须硫化,可以循环使用降低成本,既可以二次注塑成型,与PP、PE、PC、PS、ABS等基体材料包覆粘合,也可以单独成型。The thermoplastic elastomer TPE (Thermoplastic Elastomer) is a material with high elasticity, high strength, high resilience and the characteristics of injection mold processing. It has environmental protection, non-toxic safety, wide hardness range, excellent coloring property, soft touch, weather resistance, fatigue resistance and temperature resistance. It has excellent processing performance, no need for vulcanization, and can be recycled to reduce costs. It can be used for double injection molding. It can be coated with a base material such as PP, PE, PC, PS or ABS, or it can be molded separately.
热塑性弹性体(TPE)具有硫化橡胶的物理机械性能和热塑性塑料的工艺加工性能。由于不需经过热硫化,使用通用的塑料加工设备即可完成产品生产。这一特点使橡胶工业生产流程缩短了1/4,节约能耗25%~40%,提高效率10倍~20倍,堪称橡胶工业又一次材料和工艺技术革命。Thermoplastic elastomers (TPE) have the physical and mechanical properties of vulcanized rubber and the processability of thermoplastics. Since there is no need for thermal vulcanization, the production of the product can be completed using general-purpose plastic processing equipment. This feature has shortened the production process of the rubber industry by 1/4, saved energy by 25% to 40%, and improved efficiency by 10 to 20 times. It is another revolution in materials and process technology in the rubber industry.
TPE/TPR弹性体指的是基于SEBS,SBS基础改性的合金弹性体.为便于理解沟通,本文沿用业内TPE生产企业的习惯,将SEBS基础改性的弹性体称TPE,将SBS基础改性的弹性体称TPR.SEBS为饱和分子结构的高分子材料,而SBS分子结构单元中含有不饱和双键.不饱和双键的化学性不稳定,因此,一般而言,SEBS比SBS具有更为优良的化学稳定性(如耐老化,抗紫外线UV性能)。相应地,TPE比TPR具有更为良好的耐老化抗UV性能。TPE/TPR elastomer refers to the alloy elastomer modified based on SEBS and SBS. In order to facilitate understanding and communication, this article follows the habit of TPE manufacturers in the industry, and the elastomer modified by SEBS is called TPE, and the SBS base is modified. The elastomer is called TPR.SEBS is a polymer material with a saturated molecular structure, while the SBS molecular structural unit contains an unsaturated double bond. The unsaturated double bond is chemically unstable, so in general, SEBS has more than SBS. Excellent chemical stability (such as aging resistance, UV resistance). Accordingly, TPE has better aging and UV resistance than TPR.
在选择耐老化抗UV的弹性体时,通常选用SEBS基材的TPE.SEBS基材的TPE一般抗UV性能可以达到3.5级,对于耐老化性,一些非权威性的来自部分用户的使用效果表明,SEBS的TPE通常可以在常规非极端户外条件使用6个月左右不发生黄变(抗UV性能),而使用12个月材料不会发生明显的老化而导致性能下降。When selecting an anti-aging and anti-UV elastomer, the TPE of the TPE.SEBS substrate which is usually selected from the SEBS substrate can generally achieve a UV resistance of 3.5. For the aging resistance, some non-authoritative effects from some users indicate The SEBS TPE can usually be used in conventional non-extreme outdoor conditions for about 6 months without yellowing (UV resistance), while the use of 12 months of material does not cause significant aging and performance degradation.
对于TPE背胶,目前国内主要存在如下专利文献:For TPE backing, there are mainly the following patent documents in China:
专利公开号:CN105111979A,公开了一种环保型抗菌阻燃TPE地毯背胶粉料,其制备原料包含:MAH-g-SEBS、MAH-g-PP、聚季铵盐-壳聚糖-超支化聚氨酯复合物以及磺化聚酰亚胺改性氧化石墨烯。本发明还公开了所述环保型抗菌阻燃TPE地毯背胶粉料的制备方法。然而,该专利主要通过成分的变换使地毯背胶具备抗菌阻燃性能,而石墨烯的加入,会影响其耐磨防滑性能。 Patent Publication No.: CN105111979A, discloses an environmentally-friendly antibacterial flame-retardant TPE carpet backing powder, the preparation thereof comprises: MAH-g-SEBS, MAH-g-PP, polyquaternium-chitosan-hyperbranched Polyurethane composite and sulfonated polyimide modified graphene oxide. The invention also discloses a preparation method of the environmentally-friendly antibacterial flame-retardant TPE carpet backing powder. However, the patent mainly imparts antibacterial and flame retardant properties to the carpet backing by changing the composition, and the addition of graphene will affect its wear resistance and anti-slip performance.
实用新型内容Utility model content
为解决上述存在的问题,本实用新型的目的在于提供一种地毯用抗菌、耐磨、防滑TPE背胶,所述TPE背胶具有生产效率高、环保、防滑、耐黄变等特性,有效改善客户目前使用乳胶生产的黄边快、粘地板、气味大等缺陷。In order to solve the above problems, the utility model aims to provide an antibacterial, wear-resistant and anti-slip TPE adhesive for carpets, which has the characteristics of high production efficiency, environmental protection, anti-skid and yellowing resistance, and is effectively improved. Customers currently use latex to produce defects such as yellow edges, sticky floors, and large odors.
为达到上述目的,本实用新型的技术方案是:In order to achieve the above object, the technical solution of the present invention is:
一种地毯用抗菌、耐磨、防滑TPE背胶,包括:背胶层,相对地毯的另一面开设有若干圆形凹槽,内径为0.1~0.2mm;由内至外依次涂覆于所述背胶层相对地毯另一面的抗菌层、耐磨层及防滑层;所述背胶层由热塑性弹性体TPE经熔融挤出形成。An antibacterial, wear-resistant, non-slip TPE adhesive for carpets, comprising: a backing layer, a plurality of circular grooves are formed on the other side of the carpet, the inner diameter is 0.1-0.2 mm; and the inner-outer coating is applied to the The anti-adhesive layer, the wear-resistant layer and the anti-slip layer of the adhesive layer on the other side of the carpet; the backing layer is formed by melt extrusion of the thermoplastic elastomer TPE.
进一步,所述抗菌层为载银纳米SiO2抗菌层,厚度为0.1~0.5mm。Further, the antibacterial layer is a silver-loaded nano-SiO 2 antibacterial layer having a thickness of 0.1 to 0.5 mm.
另,所述耐磨层为双向拉伸聚丙烯薄膜层,厚度为0.5~1cm。Further, the wear-resistant layer is a biaxially oriented polypropylene film layer having a thickness of 0.5 to 1 cm.
另有,所述防滑层为聚氯乙烯泡棉层,厚度为1~3cm。In addition, the anti-slip layer is a polyvinyl chloride foam layer having a thickness of 1 to 3 cm.
再,所述防滑层相对耐磨层的另一面设防滑纹。Further, the anti-slip layer is provided with an anti-slip pattern on the other side of the wear-resistant layer.
再有,所述TPE密封圈硬度为35~55A。Further, the TPE sealing ring has a hardness of 35 to 55 A.
且,所述TPE密封圈比重为1.1~1.3。Moreover, the TPE sealing ring has a specific gravity of 1.1 to 1.3.
本实用新型的有益效果在于:The beneficial effects of the utility model are as follows:
所述TPE背胶具有生产效率高、环保、防滑、耐黄变等特性,有效改善客户目前使用乳胶生产的黄边快、粘地板、气味大等缺陷,手感舒适,回复性,弹性好耐磨性能好,耐高温,耐机洗,洗衣机水洗不开胶,环保,无毒无气味,且加工工艺简单,产量高,降低成本。The TPE adhesive has the characteristics of high production efficiency, environmental protection, anti-slip, yellowing resistance, etc., and effectively improves the defects of the yellow edge, sticky floor and large smell of the latex produced by the customer, and has comfortable hand feeling, recovery property, good elasticity and wear resistance. Good performance, high temperature resistance, machine wash resistance, washing machine without washing, environmental protection, non-toxic and odorless, simple processing technology, high output and low cost.
附图说明DRAWINGS
图1为本实用新型实施例所提供的一种地毯用抗菌、耐磨、防滑TPE背胶的结构示意图。1 is a schematic view showing the structure of an antibacterial, wear-resistant and anti-slip TPE adhesive for a carpet according to an embodiment of the present invention.
具体实施方式Detailed ways
参见图1,本实用新型所述的一种地毯用抗菌、耐磨、防滑TPE背胶,包括:背胶层1,相对地毯的另一面开设有若干圆形凹槽(未图示),内径为0.1~0.2mm;由内至外依次涂覆于所述背胶层1相对地毯另一面的抗菌层2、耐磨层3及防滑层4;所述背胶层1由热塑性弹性体TPE经熔融挤出形成。Referring to FIG. 1 , an antibacterial, wear-resistant and anti-slip TPE adhesive for a carpet according to the present invention comprises: a backing layer 1 , and a plurality of circular grooves (not shown) are opened on the other side of the carpet, and the inner diameter is 0.1 to 0.2 mm; applied from the inside to the outside in the antibacterial layer 2, the wear layer 3 and the anti-slip layer 4 on the other side of the backing layer 1; the backing layer 1 is made of a thermoplastic elastomer TPE Melt extrusion is formed.
进一步,所述抗菌层2为载银纳米SiO2抗菌层,厚度为0.1~0.5mm。Further, the antibacterial layer 2 is a silver-loaded nano-SiO 2 antibacterial layer having a thickness of 0.1 to 0.5 mm.
另,所述耐磨层3为双向拉伸聚丙烯薄膜层,厚度为0.5~1cm。Further, the wear-resistant layer 3 is a biaxially oriented polypropylene film layer having a thickness of 0.5 to 1 cm.
另有,所述防滑层4为聚氯乙烯泡棉层,厚度为1~3cm。In addition, the anti-slip layer 4 is a polyvinyl chloride foam layer having a thickness of 1 to 3 cm.
再,所述防滑层4相对耐磨层的另一面设防滑纹(未图示)。 Further, the anti-slip layer 4 is provided with an anti-slip pattern (not shown) on the other side of the wear-resistant layer.
再有,所述TPE密封圈硬度为35~55A。Further, the TPE sealing ring has a hardness of 35 to 55 A.
且,所述TPE密封圈比重为1.1~1.3。Moreover, the TPE sealing ring has a specific gravity of 1.1 to 1.3.
本实用新型所述的一种地毯用抗菌、耐磨、防滑TPE背胶,具有生产效率高、环保、防滑、耐黄变等特性,有效改善客户目前使用乳胶生产的黄边快、粘地板、气味大等缺陷,手感舒适,回复性,弹性好耐磨性能好,耐高温,耐机洗,洗衣机水洗不开胶,环保,无毒无气味,且加工工艺简单,产量高,降低成本。The utility model relates to an antibacterial, wear-resistant and anti-slip TPE adhesive for carpets, which has the characteristics of high production efficiency, environmental protection, anti-skid and yellowing resistance, and effectively improves the yellow edge of the customer to use latex production, and sticks the floor. Large odor and other defects, comfortable feel, recovery, good elasticity, good wear resistance, high temperature resistance, machine wash resistance, washing machine without washing, environmental protection, non-toxic and odorless, simple processing technology, high output and low cost.
需要说明的是,以上实施例仅用以说明本实用新型的技术方案而非限制。尽管参照较佳实施例对本实用新型进行了详细说明,本领域的普通技术人员应当理解,可以对实用新型的技术方案进行修改或者等同替换,而不脱离本实用新型技术方案的范围,其均应涵盖在本实用新型的权利要求范围中。 It should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and are not limiting. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that the invention may be modified or equivalently substituted without departing from the scope of the present invention. It is intended to be included within the scope of the appended claims.

Claims (7)

  1. 一种地毯用抗菌、耐磨、防滑背胶,其特征在于,包括:An antibacterial, abrasion-resistant and anti-slip adhesive for carpets, characterized in that it comprises:
    背胶层,相对地毯的另一面开设有若干圆形凹槽,内径为0.1~0.2mm;The backing layer is provided with a plurality of circular grooves on the other side of the carpet, and the inner diameter is 0.1 to 0.2 mm;
    由内至外依次涂覆于所述背胶层相对地毯另一面的抗菌层、耐磨层及防滑层;Applying from the inside to the outside, the anti-adhesive layer, the wear-resistant layer and the anti-slip layer of the adhesive layer on the other side of the carpet;
    所述背胶层由热塑性弹性体TPE经熔融挤出形成。The backing layer is formed by melt extrusion of a thermoplastic elastomer TPE.
  2. 根据权利要求1所述的一种地毯用抗菌、耐磨、防滑背胶,其特征在于,所述抗菌层为载银纳米SiO2抗菌层,厚度为0.1~0.5mm。The antibacterial, abrasion-resistant and anti-slip adhesive for carpets according to claim 1, wherein the antibacterial layer is a silver-loaded nano-SiO 2 antibacterial layer having a thickness of 0.1 to 0.5 mm.
  3. 根据权利要求1所述的一种地毯用抗菌、耐磨、防滑背胶,其特征在于,所述耐磨层为双向拉伸聚丙烯薄膜层,厚度为0.5~1cm。The antibacterial, abrasion-resistant and anti-slip adhesive for carpets according to claim 1, wherein the wear-resistant layer is a biaxially oriented polypropylene film layer having a thickness of 0.5 to 1 cm.
  4. 根据权利要求1所述的一种地毯用抗菌、耐磨、防滑背胶,其特征在于,所述防滑层为聚氯乙烯泡棉层,厚度为1~3cm。The antibacterial, abrasion-resistant and anti-slip adhesive for carpets according to claim 1, wherein the anti-slip layer is a polyvinyl chloride foam layer having a thickness of 1 to 3 cm.
  5. 根据权利要求1或4所述的一种地毯用抗菌、耐磨、防滑背胶,其特征在于,所述防滑层相对耐磨层的另一面设防滑纹。The antibacterial, abrasion-resistant and anti-slip adhesive for carpets according to claim 1 or 4, wherein the anti-slip layer is provided with a non-slip pattern on the other side of the wear-resistant layer.
  6. 根据权利要求1所述的一种地毯用抗菌、耐磨、防滑背胶,其特征在于,所述TPE密封圈硬度为35~55A。The antibacterial, abrasion-resistant and anti-slip adhesive for carpets according to claim 1, wherein the TPE sealing ring has a hardness of 35 to 55A.
  7. 根据权利要求1所述的一种地毯用抗菌、耐磨、防滑背胶,其特征在于,所述TPE密封圈比重为1.1~1.3。 The antibacterial, abrasion-resistant and anti-slip adhesive for carpets according to claim 1, wherein the TPE sealing ring has a specific gravity of 1.1 to 1.3.
PCT/CN2017/112771 2017-11-24 2017-11-24 Antibacterial, wear-resistant and anti-slip back gum for use in carpet WO2019100312A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203280209U (en) * 2013-05-20 2013-11-13 林彬 Floor mat with concave-convex structures
CN204323144U (en) * 2014-08-29 2015-05-13 佩尔哲汽车内饰系统(太仓)有限公司常熟分公司 A kind of vehicle skidproof foot pad
CN204743638U (en) * 2015-07-03 2015-11-11 山东东沃地毯股份有限公司 Black gum carpet
CN205615087U (en) * 2016-05-16 2016-10-05 佛山市顺德区琅美地毯制品有限公司 Sisal hemp carpet

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203280209U (en) * 2013-05-20 2013-11-13 林彬 Floor mat with concave-convex structures
CN204323144U (en) * 2014-08-29 2015-05-13 佩尔哲汽车内饰系统(太仓)有限公司常熟分公司 A kind of vehicle skidproof foot pad
CN204743638U (en) * 2015-07-03 2015-11-11 山东东沃地毯股份有限公司 Black gum carpet
CN205615087U (en) * 2016-05-16 2016-10-05 佛山市顺德区琅美地毯制品有限公司 Sisal hemp carpet

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