CN103549860A - Durable hardening-resistant anti-slipping mat - Google Patents
Durable hardening-resistant anti-slipping mat Download PDFInfo
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- CN103549860A CN103549860A CN201310492733.7A CN201310492733A CN103549860A CN 103549860 A CN103549860 A CN 103549860A CN 201310492733 A CN201310492733 A CN 201310492733A CN 103549860 A CN103549860 A CN 103549860A
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Abstract
The invention discloses a durable hardening-resistant anti-slipping mat. The durable hardening-resistant anti-slipping mat is provided with a soft layer woven by sisal and jute and an anti-slipping layer made of thermoplastic elastomer materials, and the thermoplastic elastomer materials are made of the following components, parts by weight, 30-40 hydrogenated styrene-butadiene-styrene block copolymer, 15-20 liquid paraffin, 10-20 liquid polybutadiene, 20-30 phenylacetate-isoprene-styrene block copolymer, 0.5-1 2,6-Di-tert-butyl-4-hydroxymethylphenol, and 0.5-1 sulfurylidene-dibutyric acid-diastearin ester. The soft layer of the anti-slipping mat is woven by the sisal and the jute, so that the comfort level of the mat is better, and the thread is not easy to loosen, the elastic resilience of the thermoplastic elastomer materials of the anti-slipping layer is good, heat-resisting and ageing-resisting performance is good, the physical property cannot reduce significantly due to over-high temperature, and the adhesion of the anti-slipping layer and the soft layer are strong, so that the durable hardening-resistant anti-slipping mat is more durable.
Description
Technical field
The present invention relates to a kind of Anti-slip ground cushion, specifically, is a kind of durable, the Anti-slip ground cushion that is difficult for coming unstuck.
Background technology
Anti-slip ground cushion is a kind ofly can effectively in porch, scrape desilt dirt and moisture content, keeps the clean and tidy product in flooring, and the back side generally adopts the materials such as rubber, has anti-skidding effect.Anti-slip ground cushion elastomeric flexible, comfortable foot feeling, water-proof skid-proof, be widely used in the places such as toilet, kitchen, front door, liked by consumers in general.
Thermoplastic elastomer (TPE) (TPE, Thermo plastic Elastomer) be a kind of high resiliency, high strength, high resilience with rubber, the material again with feature that can injection molding, there is the advantages such as environment-protecting asepsis safety, coloring that hardness range is wide, good, soft-touch, weatherability, fatigue resistance and temperature tolerance are better, processing characteristics is superior, need not vulcanize, can recycle and reduce costs, both can secondary injection molding, with the matrix material coating and bondings such as PP, PE, PC, PS, ABS, also moulding separately.The Anti-slip ground cushion of being made as anti-slip material by thermoplastic elastomer (TPE) has that elasticity is good, good antiskid effect, toughness is good, tension force is strong, the feature of recyclable and recycling.But the heat resistance of thermoplastic elastic material is not as rubber, along with temperature rising, physical property declines by a big margin, if Anti-slip ground cushion is for outdoor environment, tanning by the sun for a long time of experience daylight in summer, temperature is for a long time in higher state, the physical property such as its compressive deformation, elastic recovery can significantly decline, and reduces the use sense organ of ground cushion, reduction of service life.Therefore, research and development heat resistance is good, aging-resistant thermoplastic elastic material, and it is very necessary preparing the free of contamination Anti-slip ground cushion of durable recoverable.
Summary of the invention
The object of the invention is for deficiency of the prior art the Anti-slip ground cushion that provide a kind of durable, is difficult for coming unstuck.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of durable, the Anti-slip ground cushion that is difficult for coming unstuck, be provided with soft suitable layer and skid resistant course, described soft suitable layer is formed by sisal hemp and jute braiding, described skid resistant course is made by thermoplastic elastic material, described thermoplastic elastic material is made by each component of following weight portion: hydrogenated styrene-butadiene-styrene block copolymers 30-40 part, atoleine 15-20 part, liquid polybutadiene 10-20 part, phenylacetic acid-isoprene-styrene block copolymer 20-30 part, 4-methylol-2, 6-DI-tert-butylphenol compounds 0.5-1 part, sulfurous base two butyric acid distearyl ester 0.5-1 parts.
Preferably, the weight ratio of described atoleine, liquid polybutadiene, phenylacetic acid-isoprene-styrene block copolymer is 4: 3: 5.
Preferably, described 4-methylol-2, the weight ratio of 6-DI-tert-butylphenol compounds and sulfurous base two butyric acid distearyl esters is 1: 1.
Preferably, described thermoplastic elastic material is made by each component of following weight portion: 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, 20 parts of atoleines, 15 parts of liquid polybutadienes, 25 parts of phenylacetic acid-isoprene-styrene block copolymers, 4-methylol-2,0.8 part of 6-DI-tert-butylphenol compounds, 0.8 part of sulfurous base two butyric acid distearyl ester.
Preferably, described thermoplastic elastic material is made by each component of following weight portion: 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, 15 parts of atoleines, 10 parts of liquid polybutadienes, 25 parts of phenylacetic acid-isoprene-styrene block copolymers, 4-methylol-2,0.8 part of 6-DI-tert-butylphenol compounds, 0.8 part of sulfurous base two butyric acid distearyl ester.
Preferably, described thermoplastic elastic material is made by each component of following weight portion: 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, 20 parts of atoleines, 15 parts of liquid polybutadienes, 25 parts of phenylacetic acid-isoprene-styrene block copolymers, 4-methylol-2,0.6 part of 6-DI-tert-butylphenol compounds, 0.7 part of sulfurous base two butyric acid distearyl ester.
Preferably, described sisal hemp and jute are that right-angled intersection mode weaves.
The invention has the advantages that:
1, the elastic resilience of its skid resistant course material thermoplastic elastic material of Anti-slip ground cushion of the present invention is good, heat-resisting excellent with ageing resistace, can be because excess Temperature physical property significantly declines, and strong with the adhesive of soft suitable layer, make Anti-slip ground cushion of the present invention durable more;
2, the soft suitable layer employing sisal hemp of Anti-slip ground cushion of the present invention and jute right-angled intersection mode weave and form, and comfort is good, more firm and durable.
Accompanying drawing explanation
Accompanying drawing 1 is Anti-slip ground cushion structural representation of the present invention.
The specific embodiment
Below in conjunction with accompanying drawing, the specific embodiment provided by the invention is elaborated.
The Reference numeral and the part that in accompanying drawing, relate to are as follows:
1. soft suitable layer 2. skid resistant course
11. sisal hemp 12. jutes
embodiment 1 skid resistant course material---thermoplastic elastomer (TPE) preparation ()
(1) by weight, by 20 parts of atoleines, 15 parts of liquid polybutadienes, 4-methylol-2,0.8 part of 6-DI-tert-butylphenol compounds, 0.8 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 25 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 45min all melts to raw material;
(2) in step (1) gained mixture, drop into 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 45min, mix and extract out without obvious bubble to mixture, mixing speed is 115rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, must be applicable to skid resistant course material---the thermoplastic elastic material of Anti-slip ground cushion.
embodiment 2 skid resistant course materials---thermoplastic elastomer (TPE) preparation (two)
(1) by weight, by 15 parts of atoleines, 10 parts of liquid polybutadienes, 4-methylol-2,1 part of 6-DI-tert-butylphenol compounds, 1 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 20 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 40min all melts to raw material;
(2) in step (1) gained mixture, drop into 30 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 50min, mix and extract out without obvious bubble to mixture, mixing speed is 110rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, must be applicable to skid resistant course material---the thermoplastic elastic material of Anti-slip ground cushion.
embodiment 3 skid resistant course materials---thermoplastic elastomer (TPE) preparation (three)
(1) by weight, by 20 parts of atoleines, 20 parts of liquid polybutadienes, 4-methylol-2,0.5 part of 6-DI-tert-butylphenol compounds, 0.5 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 30 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 50min all melts to raw material;
(2) in step (1) gained mixture, drop into 40 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 40min, mix and extract out without obvious bubble to mixture, mixing speed is 120rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, must be applicable to skid resistant course material---the thermoplastic elastic material of Anti-slip ground cushion.
embodiment 4 skid resistant course materials---thermoplastic elastomer (TPE) preparation (four)
(1) by weight, by 15 parts of atoleines, 10 parts of liquid polybutadienes, 4-methylol-2,0.8 part of 6-DI-tert-butylphenol compounds, 0.8 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 25 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 40min all melts to raw material;
(2) in step (1) gained mixture, drop into 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 50min, mix and extract out without obvious bubble to mixture, mixing speed is 110rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, must be applicable to skid resistant course material---the thermoplastic elastic material of Anti-slip ground cushion.
embodiment 5 skid resistant course materials---thermoplastic elastomer (TPE) preparation (five)
(1) by weight, by 20 parts of atoleines, 15 parts of liquid polybutadienes, 4-methylol-2,0.6 part of 6-DI-tert-butylphenol compounds, 0.7 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 25 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 50min all melts to raw material;
(2) in step (1) gained mixture, drop into 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 40min, mix and extract out without obvious bubble to mixture, mixing speed is 120rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, must be applicable to skid resistant course material---the thermoplastic elastic material of Anti-slip ground cushion.
embodiment 6 skid resistant course materials---thermoplastic elastomer (TPE) preparation (six)
(1) by weight, by 15 parts of atoleines, 20 parts of liquid polybutadienes, 4-methylol-2,0.5 part of 6-DI-tert-butylphenol compounds, 1 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 20 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 45min all melts to raw material;
(2) in step (1) gained mixture, drop into 40 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 50min, mix and extract out without obvious bubble to mixture, mixing speed is 115rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, must be applicable to skid resistant course material---the thermoplastic elastic material of Anti-slip ground cushion.
comparative example 1
(1) by weight, by 30 parts of atoleines, 20 parts of liquid polybutadienes, 4-methylol-2,0.8 part of 6-DI-tert-butylphenol compounds, 0.8 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 160-170 ℃, material temperature is controlled at 160-170 ℃, and heating 45min all melts to raw material;
(2) in step (1) gained mixture, drop into 45 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 45min, mix and extract out without obvious bubble to mixture, mixing speed is 115rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, obtain thermoplastic elastic material.
comparative example 2
(1) by weight, by 15 parts of atoleines, 10 parts of liquid polybutadienes, 4-methylol-2,1 part of 6-DI-tert-butylphenol compounds, 1.2 parts of input conduction oil reactors of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 20 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 40min all melts to raw material;
(2) in step (1) gained mixture, drop into 30 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 50min, mix and extract out without obvious bubble to mixture, mixing speed is 110rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, obtain suitable thermoplastic elastic material.
comparative example 3
(1) by weight, by 20 parts of atoleines, 20 parts of liquid polybutadienes, 4-methylol-2,0.5 part of 6-DI-tert-butylphenol compounds, 0.4 part of input conduction oil reactor of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 30 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 50min all melts to raw material;
(2) in step (1) gained mixture, drop into 40 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 40min, mix and extract out without obvious bubble to mixture, mixing speed is 120rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, obtain thermoplastic elastic material.
comparative example 4
(1) by weight, by 20 parts of atoleines, 15 parts of liquid polybutadienes, 1.6 parts of input conduction oil reactors of sulfurous base two butyric acid distearyl ester, be warming up to 110-120 ℃, add 25 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 45min all melts to raw material;
(2) in step (1) gained mixture, drop into 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 45min, mix and extract out without obvious bubble to mixture, mixing speed is 115rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, obtain thermoplastic elastic material.
comparative example 5
(1) by weight, by 20 parts of atoleines, 15 parts of liquid polybutadienes, 4-methylol-2,1.6 parts of input conduction oil reactors of 6-DI-tert-butylphenol compounds, be warming up to 110-120 ℃, add 25 parts of phenylacetic acid-isoprene-styrene block copolymers, material temperature is controlled at 160-170 ℃, and heating 45min all melts to raw material;
(2) in step (1) gained mixture, drop into 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, closed reactor, be less than-the 0.09Mpa that is evacuated to pressure, until hydrogenated styrene-butadiene-styrene block copolymers melts completely, keep be less than-0.09Mpa of pressure, stir 45min, mix and extract out without obvious bubble to mixture, mixing speed is 115rpm, stops heating, puts vacuum;
(3) by 150 order double-level-metal net filtration dischargings for step (2) gained mixture, and adopt high temperature resistant silicone oil release liners packed products, obtain thermoplastic elastic material.
embodiment 7 skid resistant course materials---the performance test of thermoplastic elastomer (TPE)
The main performance index of thermoplastic elastic material prepared by embodiment 1-6 and comparative example 1-5 is tested, room temperature compression set and 100 ℃ of compression set testing standards are with reference to GB/T1040-2006, the adhesive of sisal hemp and jute knitting is by reviewer organoleptic analysis, according to adhesive, by low, to giving by force ten point system, given a mark, the higher expression adhesive of score value is better.Test result is as shown in table 1.The present invention adopts SBS can significantly improve the elastic resilience of thermoplastic elastic material, used 4-methylol-2,6-DI-tert-butylphenol compounds and sulfurous base two butyric acid distearyl esters, jointly as age resister, can guarantee that thermoplastic elastic material can significantly not decline because of excess Temperature physical property.Research is discovery also, and when the weight ratio of raw material liq paraffin, liquid polybutadiene, phenylacetic acid-isoprene-styrene block copolymer is 4: 3: 5, material adhesive, heat resistance and the ageing resistace of preparation are better; Age resister 4-methylol-2, the weight ratio of 6-DI-tert-butylphenol compounds and sulfurous base two butyric acid distearyl esters is 1: 1 o'clock, contribution for material adhesive, heat resistance and ageing resistace is more obvious, 4-methylol-2,6-DI-tert-butylphenol compounds and sulfurous base two butyric acid distearyl esters should couplings; And in raw material, base-material and ageing-resistant ratio are preferably controlled within the scope of the invention.
The main performance index of thermoplastic elastic material prepared by table 1 embodiment 1-6 and comparative example 1-5
embodiment 8 Anti-slip ground cushion of the present invention
Please refer to Fig. 1, Fig. 1 is Anti-slip ground cushion structural representation of the present invention.Described Anti-slip ground cushion is rectangle, is provided with soft suitable layer 1 and skid resistant course 2, and described soft suitable layer 1 is positioned at the top of skid resistant course 2.Soft suitable layer 1 is formed by sisal hemp 11 and jute 12 braidings, and described sisal hemp 11 and jute 12 weave for right-angled intersection mode.Described skid resistant course 2 is highly 4-7mm, upper surface and the 1 tight adhesion of described soft suitable layer, and skid resistant course 2 is made by the thermoplastic elastic material of the arbitrary preparation of embodiment 1-6.
It should be noted that, described sisal hemp 11 and jute 12 are comparatively soft, can improve the comfort of Anti-slip ground cushion of the present invention; Sisal hemp 11 and jute 12 adopt right-angled intersection mode to weave, and make soft suitable layer 1 more wear-resisting, are difficult for de-head, and more attractive in appearance; Described skid resistant course 2 adopts the thermoplastic elastic material of the arbitrary preparation of embodiment 1-6 to make, its elastic resilience is good, heat-resisting excellent with ageing resistace, even long-term for the higher outdoor environment of temperature, still can keep good comfort level, and the bonding force of this thermoplastic elastic material is strong, can with soft suitable layer 1 tight adhesion, be difficult for coming unstuck, durable.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, do not departing under the prerequisite of the inventive method; can also make some improvement and supplement, these improvement and supplement and also should be considered as protection scope of the present invention.
Claims (7)
1. a durable, the Anti-slip ground cushion that is difficult for coming unstuck, be provided with soft suitable layer and skid resistant course, it is characterized in that, described soft suitable layer is formed by sisal hemp and jute braiding, described skid resistant course is made by thermoplastic elastic material, described thermoplastic elastic material is made by each component of following weight portion: hydrogenated styrene-butadiene-styrene block copolymers 30-40 part, atoleine 15-20 part, liquid polybutadiene 10-20 part, phenylacetic acid-isoprene-styrene block copolymer 20-30 part, 4-methylol-2, 6-DI-tert-butylphenol compounds 0.5-1 part, sulfurous base two butyric acid distearyl ester 0.5-1 parts.
2. Anti-slip ground cushion according to claim 1, is characterized in that, the weight ratio of described atoleine, liquid polybutadiene, phenylacetic acid-isoprene-styrene block copolymer is 4: 3: 5.
3. Anti-slip ground cushion according to claim 1, is characterized in that, described 4-methylol-2, and the weight ratio of 6-DI-tert-butylphenol compounds and sulfurous base two butyric acid distearyl esters is 1: 1.
4. Anti-slip ground cushion according to claim 1, it is characterized in that, described thermoplastic elastic material is made by each component of following weight portion: 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, 20 parts of atoleines, 15 parts of liquid polybutadienes, 25 parts of phenylacetic acid-isoprene-styrene block copolymers, 4-methylol-2,0.8 part of 6-DI-tert-butylphenol compounds, 0.8 part of sulfurous base two butyric acid distearyl ester.
5. Anti-slip ground cushion according to claim 1, it is characterized in that, described thermoplastic elastic material is made by each component of following weight portion: 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, 15 parts of atoleines, 10 parts of liquid polybutadienes, 25 parts of phenylacetic acid-isoprene-styrene block copolymers, 4-methylol-2,0.8 part of 6-DI-tert-butylphenol compounds, 0.8 part of sulfurous base two butyric acid distearyl ester.
6. Anti-slip ground cushion according to claim 1, it is characterized in that, described thermoplastic elastic material is made by each component of following weight portion: 35 parts of hydrogenated styrene-butadiene-styrene block copolymers, 20 parts of atoleines, 15 parts of liquid polybutadienes, 25 parts of phenylacetic acid-isoprene-styrene block copolymers, 4-methylol-2,0.6 part of 6-DI-tert-butylphenol compounds, 0.7 part of sulfurous base two butyric acid distearyl ester.
7. Anti-slip ground cushion according to claim 1, is characterized in that, described sisal hemp and jute are that right-angled intersection mode weaves.
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| CN201310492733.7A CN103549860A (en) | 2013-10-18 | 2013-10-18 | Durable hardening-resistant anti-slipping mat |
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| CN201310492733.7A CN103549860A (en) | 2013-10-18 | 2013-10-18 | Durable hardening-resistant anti-slipping mat |
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| CN108329872A (en) * | 2018-01-31 | 2018-07-27 | 广东金源科技股份有限公司 | A kind of environmental protection anti-slip carpet gum TPE material and preparation method thereof |
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Application publication date: 20140205 |