WO2019098959A2 - Sun protection composition developed for agricultural products - Google Patents

Sun protection composition developed for agricultural products Download PDF

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Publication number
WO2019098959A2
WO2019098959A2 PCT/TR2018/050379 TR2018050379W WO2019098959A2 WO 2019098959 A2 WO2019098959 A2 WO 2019098959A2 TR 2018050379 W TR2018050379 W TR 2018050379W WO 2019098959 A2 WO2019098959 A2 WO 2019098959A2
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Prior art keywords
weight
solution
protection composition
sun protection
proportion
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PCT/TR2018/050379
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French (fr)
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WO2019098959A3 (en
Inventor
Mustafa BASARAN
Oguzhan UZUN
Serkan SAHAN
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Dogatech Arastirma Gelistirme Tar.Ur.Gida Hay.San. Ve Tic.Ltd.Sti
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Priority to EP18878593.5A priority Critical patent/EP3657944A4/en
Publication of WO2019098959A2 publication Critical patent/WO2019098959A2/en
Publication of WO2019098959A3 publication Critical patent/WO2019098959A3/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N3/00Preservation of plants or parts thereof, e.g. inhibiting evaporation, improvement of the appearance of leaves or protection against physical influences such as UV radiation using chemical compositions; Grafting wax
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof

Definitions

  • the present invention relates to a sun protection composition developed for providing a more efficient feeding by protecting from the harmful effects of sun rays with foliar application for agricultural products particularly like fruit and vegetable.
  • Photosynthesis is one of the feeding mechanisms which provide growth of plant.
  • the sun rays absorbed by the plant react with water and carbon dioxide and they form simple sugars and oxygen. While oxygen is given to the outer medium, simple sugars provide a nutrient source for the plant and they provide development of the plant.
  • simple sugars provide a nutrient source for the plant and they provide development of the plant.
  • sun rays are useful for the plants, they lead to formation of a high temperature on leafage and fruits of plants particularly in periods where very high temperatures are observed.
  • the physiological temperature stress resulting from this condition decelerates photosynthesis, chlorophyll and protein synthesis, nutrient element assimilation and transportation of nutrient elements like calcium and thus, it leads to stopping of the development of the plant.
  • UV-B rays whose wavelength changes between 280 and 313 nm leads to deterioration of the cell wall and structure while creating biological and bio-chemical changes.
  • the nutrient substance related to the plants which are mostly affected by the temperature stress is calcium and even if there is sufficient calcium in leafage of the plants, the transportation of this calcium to the fruit decelerates under stress and even it stops. Calcium essentially reinforces the cell wall and necrosis formation in plants having high calcium ingredient decreased. Therefore, in order to increase calcium proportion in the plant, the fertilizers comprising calcium are applied to the fruits and vegetables in the form of spray.
  • foliar application the fruit surface is targeted and calcium absorption is provided through fruit shell and bitter pit formation after harvesting is tried to be prevented.
  • boron mineral which functions in carrying of calcium and in transfer of calcium into the cell can be applied to the plants by means of foliar application.
  • L-amino acids are applied for providing resistance to the plants against the stress conditions resulting from temperature, cold, disease and harmful insects. Moreover, because of the absorption and reflection property of UV rays, the usage of titanium dioxide in plants is substantially frequent.
  • the present invention relates to a protection composition comprising titanium dioxide, calcium, boron and amino acid components and which eliminates protection of fruits and vegetables against UV rays and which eliminates the problems resulting from temperature, for eliminating the above mentioned disadvantages and for bringing new advantages to the related technical field.
  • the main object of the present invention is to provide a protection composition which prevents color change and necrosis formation resulting from UV rays.
  • Another object of the present invention is to provide a protection composition which decreases temperature stress.
  • Another object of the present invention is to provide a protection composition which eliminates calcium deficiency dependent on temperature stress.
  • Another object of the present invention is to provide a protection composition which accelerates protein synthesis which decreases as a result of temperature stress.
  • the present invention is a sun protection composition prepared in the form of solution and applied onto the leafage and fruits of agricultural products and which provides protection of leafage and fruits from UV rays by means of titanium dioxide existing in the solution.
  • said sun protection composition is characterized in that the solution comprises CaO which provides transportation of calcium from the leafage to the fruits in the product which is under stress and total amino acids which provide boron and protein synthesis in order to provide transfer of said CaO.
  • the solution comprises 5-12% CaO by weight.
  • the solution comprises 0.5-2% boron by weight.
  • the solution comprises 2-5% total amino acid by weight.
  • the solution comprises 0.1 -0.5% silica gel by weight.
  • the solution comprises macro nutrient substance with proportion of 10% by weight prepared by at least one of N, P, K, S, Mg elements.
  • the solution comprises micro nutrient substance with proportion of 0.01 -1 % by weight prepared by at least one of Fe, Zn, Cu, Mo, Mn elements.
  • the solution comprises 5-45% dispersion and emulsifier mixture by weight.
  • said CaO is obtained by means of dissolving calcium chloride or calcium nitrate in water.
  • said boron is obtained from boric acid or boron ethanol amine.
  • the protection composition comprises titanium dioxide (Ti0 2 ), calcium chloride, calcium nitrate, boric acid, animal-origin or herbal total amino-acid, dispersion substance and stabilizer.
  • the protection composition is in the form of liquid or powder and it is diluted in suitable proportions and it is applied by means of spraying onto leafage and fruits of the plants by means of pulverizators.
  • Titanium dioxide which functions as sun curtain is the mineral which is known to be the whitest mineral which mostly reflects light after diamond. It absorbs and reflects UV rays. Particularly titanium dioxide rutile shows better properties in terms of reflection of light when compared with titanium dioxide anatase having crystal structure. The density thereof is 4.0- 4.1 grams/cm 3 . Thanks to its chemical stability, non-toxicity and low-cost, it can be used in various different areas. Titanium dioxide in protection composition is used for preventing biological and chemical changes in plants which result from UV-B, for preventing deterioration of the cell wall and structure and for preventing stopping of photosynthesis. Thus, the effects of harmful UV-B rays on the plants are decreased.
  • rutile form of titanium dioxide is used.
  • temperature stress occurs in plants and temperature stress leads to calcium deficiency.
  • calcium reinforces cell wall and decreases formation of necrosis.
  • Boron provides transportation of calcium and transfer of calcium into the cell. Particularly in plants where water consumption is excessive and in rainy regions, the boron need in plants is greater.
  • Plants can synthesize L-amino acid in their bodies. After amino acids are applied to the plants, resistance occurs against stress factor which occurs after temperature, cold, disease and harmful insects. L-glisin and L-glutamic acids increase chlorophyll concentration and contribute to acceleration of photosynthesis. Amino acids support continuation of macro micro nutrient intake and respiration by means of preventing closing of stomas in stress conditions. At the same time, amino acids accelerate formation of photo-hormone and development factors. L-methionine ethylene is the amino acid which is required for formation of espermidine and espermine among the plant development factors. L-arginine supports development of hormones related to flower and fruit formation. Specific amino acids provided in the protection composition support photosynthesis and they provide keeping the stomas open and they provide continuation of the plant growth also in periods where the temperature is very high.
  • the protection composition comprises 10-40% titanium dioxide by weight, preferably 5-12% calcium chloride by weight or CaO to be provided from calcium nitrate source, preferably 0.5- 2% boron by weight to be provided from boric acid, and 2-5% total amino acids by weight. Dispersion, watering and emulsifier additive are forming 15-45% of the protection composition by weight.
  • CaO is obtained with proportion of 5-12% by weight by means of dissolving calcium chloride with the stirrer in water. 0.4% boron is added to the solution from the boric acid source. Total amino acid is added to the solution with proportion of 2-5% by weight from animal-origin or herbal source. Rutile titanium dioxide having 10-400 nm particle size is added to the mixture with proportion of 10-40% by weight. 5-45% dispersion and emulsifier by weight is added to the final solution and the solution is completed to unit volume by means of water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water.
  • 0.4% boron by weight is added to the solution from boron ethanol amine source.
  • Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source.
  • 5-45% dispersion and emulsifier by weight is added to the final solution and the solution is completed to unit volume by means of water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium nitrate by means of stirrer in water medium.
  • Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source.
  • Total amino acid solution with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source.
  • Rutile titanium dioxide with proportion of 10-40% by weight and having particle size of 10-400 nm is added to the solution.
  • Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boric acid source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium nitrate with stirrer in water.
  • Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source.
  • Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source.
  • Rutile titanium dioxide, having particle size of 10-400 nm is added to the solution in the form of mixture with proportion of 10-40% by weight.
  • Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows.
  • Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boric acid source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium nitrate with stirrer in water.
  • Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source.
  • Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source.
  • Rutile titanium dioxide, having particle size of 10-400 nm is added to the solution in the form of mixture with proportion of 10-40% by weight.
  • Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows.
  • Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
  • 5-12% CaO by weight is obtained by means of dissolving calcium nitrate with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Toxicology (AREA)
  • Fertilizers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention is a sun protection composition prepared in the form of solution and applied onto the leafage and fruits of agricultural products and which provides protection of leafage and fruits from UV rays by means of titanium dioxide existing in the solution, characterized in that the solution comprises CaO which provides transportation of calcium from the leafage to the fruits in the product which is under stress and total amino acids which provide boron and protein synthesis in order to provide transfer of said CaO.

Description

SUN PROTECTION COMPOSITION DEVELOPED FOR AGRICULTURAL PRODUCTS
TECHNICAL FIELD
The present invention relates to a sun protection composition developed for providing a more efficient feeding by protecting from the harmful effects of sun rays with foliar application for agricultural products particularly like fruit and vegetable.
PRIOR ART
Photosynthesis is one of the feeding mechanisms which provide growth of plant. By means of photosynthesis, the sun rays absorbed by the plant react with water and carbon dioxide and they form simple sugars and oxygen. While oxygen is given to the outer medium, simple sugars provide a nutrient source for the plant and they provide development of the plant. While sun rays are useful for the plants, they lead to formation of a high temperature on leafage and fruits of plants particularly in periods where very high temperatures are observed. The physiological temperature stress resulting from this condition decelerates photosynthesis, chlorophyll and protein synthesis, nutrient element assimilation and transportation of nutrient elements like calcium and thus, it leads to stopping of the development of the plant. Besides, increase of the fruit surface temperatures to values in the range of 42 and 46°C leads to deterioration of the colors and leads to high level of necrosis. Moreover, harmful effects of sun rays on the fruits and vegetables are created by means of ultraviolet (UV) rays. Due to this, UV-B rays whose wavelength changes between 280 and 313 nm leads to deterioration of the cell wall and structure while creating biological and bio-chemical changes.
The nutrient substance related to the plants which are mostly affected by the temperature stress is calcium and even if there is sufficient calcium in leafage of the plants, the transportation of this calcium to the fruit decelerates under stress and even it stops. Calcium essentially reinforces the cell wall and necrosis formation in plants having high calcium ingredient decreased. Therefore, in order to increase calcium proportion in the plant, the fertilizers comprising calcium are applied to the fruits and vegetables in the form of spray. In this application named as foliar application, the fruit surface is targeted and calcium absorption is provided through fruit shell and bitter pit formation after harvesting is tried to be prevented. In a similar manner, boron mineral which functions in carrying of calcium and in transfer of calcium into the cell can be applied to the plants by means of foliar application. After foliar and soil applications, L-amino acids are applied for providing resistance to the plants against the stress conditions resulting from temperature, cold, disease and harmful insects. Moreover, because of the absorption and reflection property of UV rays, the usage of titanium dioxide in plants is substantially frequent.
As can be seen, an efficient feeding of agricultural products like fruit and vegetable is realized in the presence of pluralities of components. These components are synthesized by plants by means of routine applications. Besides, plants shall be protected from the negative rays of the sun. For this reason, in the application with number US8986741 , said product is a composition using titanium dioxide, zinc oxide and silicon dioxide in order to provide protection of the grass plant from temperature stress resulting from sun rays. In said invention, while sun curtain effect can be obtained, there are no additional components which will support protein assimilation under stress conditions and in calcium deficiency resulting from temperature stress particularly in fruits and vegetables. Besides, in fruit and vegetable production, in order to prevent color deterioration and necrosis forming depending on UV radiation, formulations comprising kaolin clay and calcium carbonate are used. However, since the spots, which are left by these applications on the fruit, make the marketing of agricultural product difficult, they are not preferred much.
Said applications and similar applications need application again since the active substances are washed after rain and pesticide applications. This leads to increase of the application frequency and leads to increase in the product cost. Moreover, labor increases and labor costs related to this also increases.
As a result, because of all of the abovementioned problems, an improvement is required in the related technical field.
BRIEF DESCRIPTION OF THE INVENTION
The present invention relates to a protection composition comprising titanium dioxide, calcium, boron and amino acid components and which eliminates protection of fruits and vegetables against UV rays and which eliminates the problems resulting from temperature, for eliminating the above mentioned disadvantages and for bringing new advantages to the related technical field.
The main object of the present invention is to provide a protection composition which prevents color change and necrosis formation resulting from UV rays. Another object of the present invention is to provide a protection composition which decreases temperature stress.
Another object of the present invention is to provide a protection composition which eliminates calcium deficiency dependent on temperature stress.
Another object of the present invention is to provide a protection composition which accelerates protein synthesis which decreases as a result of temperature stress.
In order to realize all of the abovementioned objects and the objects which are to be deducted from the detailed description below, the present invention is a sun protection composition prepared in the form of solution and applied onto the leafage and fruits of agricultural products and which provides protection of leafage and fruits from UV rays by means of titanium dioxide existing in the solution. Accordingly, said sun protection composition is characterized in that the solution comprises CaO which provides transportation of calcium from the leafage to the fruits in the product which is under stress and total amino acids which provide boron and protein synthesis in order to provide transfer of said CaO.
In a preferred embodiment of the present invention, the solution comprises 5-12% CaO by weight.
In another preferred embodiment of the present invention, the solution comprises 0.5-2% boron by weight.
In another preferred embodiment of the present invention, the solution comprises 2-5% total amino acid by weight.
In another preferred embodiment of the present invention, the solution comprises 0.1 -0.5% silica gel by weight.
In another preferred embodiment of the present invention, the solution comprises macro nutrient substance with proportion of 10% by weight prepared by at least one of N, P, K, S, Mg elements. In another preferred embodiment of the present invention, the solution comprises micro nutrient substance with proportion of 0.01 -1 % by weight prepared by at least one of Fe, Zn, Cu, Mo, Mn elements.
In another preferred embodiment of the present invention, the solution comprises 5-45% dispersion and emulsifier mixture by weight.
In another preferred embodiment of the present invention, said CaO is obtained by means of dissolving calcium chloride or calcium nitrate in water.
In another preferred embodiment of the present invention, said boron is obtained from boric acid or boron ethanol amine.
DETAILED DESCRIPTION OF THE INVENTION
In this detailed description, the subject matter protection composition is explained with references to examples without forming any restrictive effect only in order to make the subject more understandable.
Essentially, the protection composition comprises titanium dioxide (Ti02), calcium chloride, calcium nitrate, boric acid, animal-origin or herbal total amino-acid, dispersion substance and stabilizer. The protection composition is in the form of liquid or powder and it is diluted in suitable proportions and it is applied by means of spraying onto leafage and fruits of the plants by means of pulverizators.
Titanium dioxide which functions as sun curtain is the mineral which is known to be the whitest mineral which mostly reflects light after diamond. It absorbs and reflects UV rays. Particularly titanium dioxide rutile shows better properties in terms of reflection of light when compared with titanium dioxide anatase having crystal structure. The density thereof is 4.0- 4.1 grams/cm3. Thanks to its chemical stability, non-toxicity and low-cost, it can be used in various different areas. Titanium dioxide in protection composition is used for preventing biological and chemical changes in plants which result from UV-B, for preventing deterioration of the cell wall and structure and for preventing stopping of photosynthesis. Thus, the effects of harmful UV-B rays on the plants are decreased. Due to the high UV absorption and reflection characteristic in the protection composition, rutile form of titanium dioxide is used. By means of the heating of the surfaces of plants, temperature stress occurs in plants and temperature stress leads to calcium deficiency. Even if there is sufficient amount of calcium in leafage of a plant which is under temperature stress, the transportation of calcium to the fruit decelerates and even stops. Moreover, calcium reinforces cell wall and decreases formation of necrosis. By means of usage of titanium dioxide, in reduced stress conditions, the transportation of low concentration calcium through leafage to the fruits is facilitated.
Boron provides transportation of calcium and transfer of calcium into the cell. Particularly in plants where water consumption is excessive and in rainy regions, the boron need in plants is greater.
Plants can synthesize L-amino acid in their bodies. After amino acids are applied to the plants, resistance occurs against stress factor which occurs after temperature, cold, disease and harmful insects. L-glisin and L-glutamic acids increase chlorophyll concentration and contribute to acceleration of photosynthesis. Amino acids support continuation of macro micro nutrient intake and respiration by means of preventing closing of stomas in stress conditions. At the same time, amino acids accelerate formation of photo-hormone and development factors. L-methionine ethylene is the amino acid which is required for formation of espermidine and espermine among the plant development factors. L-arginine supports development of hormones related to flower and fruit formation. Specific amino acids provided in the protection composition support photosynthesis and they provide keeping the stomas open and they provide continuation of the plant growth also in periods where the temperature is very high.
The protection composition comprises 10-40% titanium dioxide by weight, preferably 5-12% calcium chloride by weight or CaO to be provided from calcium nitrate source, preferably 0.5- 2% boron by weight to be provided from boric acid, and 2-5% total amino acids by weight. Dispersion, watering and emulsifier additive are forming 15-45% of the protection composition by weight. Some of the examples related to protection compositions prepared by means of components obtained in different proportions and from different sources are mentioned below;
Example 1
CaO is obtained with proportion of 5-12% by weight by means of dissolving calcium chloride with the stirrer in water. 0.4% boron is added to the solution from the boric acid source. Total amino acid is added to the solution with proportion of 2-5% by weight from animal-origin or herbal source. Rutile titanium dioxide having 10-400 nm particle size is added to the mixture with proportion of 10-40% by weight. 5-45% dispersion and emulsifier by weight is added to the final solution and the solution is completed to unit volume by means of water.
Example 2
5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water. 0.4% boron by weight is added to the solution from boron ethanol amine source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. 5-45% dispersion and emulsifier by weight is added to the final solution and the solution is completed to unit volume by means of water.
Example 3
5-12% CaO by weight is obtained by means of dissolving calcium nitrate by means of stirrer in water medium. Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source. Total amino acid solution with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide with proportion of 10-40% by weight and having particle size of 10-400 nm is added to the solution. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
Example 4
5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boric acid source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
Example 5
5-12% CaO by weight is obtained by means of dissolving calcium nitrate with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water.
Example 6
5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boric acid source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water. Nutrient element mixtures like N, P, K, S, Mg with proportion of 10% by weight, which are among the macro nutrient substances, and like Fe, Zn, Cu, Mo, Mn with proportion of 0.01 -1% by weight, which are among the micro nutrient substances, are added to the solution.
Example 7
5-12% CaO by weight is obtained by means of dissolving calcium nitrate with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Silica gel with proportion of 0.1 -0.5% by weight is added to the solution in order to prevent complete decrease of photosynthesis on leaf surfaces and in order to form UV windows. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water. Nutrient element mixtures like N, P, K, S, Mg with proportion of 10% by weight, which are among the macro nutrient substances, and like Fe, Zn, Cu, Mo, Mn with proportion of 0.01 -1% by weight, which are among the micro nutrient substances, are added to the solution.
Example 8
5-12% CaO by weight is obtained by means of dissolving calcium chloride with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water. Nutrient element mixtures like N, P, K, S, Mg with proportion of 10% by weight, which are among the macro nutrient substances, and like Fe, Zn, Cu, Mo, Mn with proportion of 0.01 -1% by weight, which are among the micro nutrient substances, are added to the solution.
Example 9
5-12% CaO by weight is obtained by means of dissolving calcium nitrate with stirrer in water. Boron with proportion of 0.4% by weight is added to the solution from boron ethanol amine source. Total amino acid with proportion of 2-5% by weight is added to the solution from animal-origin or herbal source. Rutile titanium dioxide, having particle size of 10-400 nm, is added to the solution in the form of mixture with proportion of 10-40% by weight. Dispersion and emulsifier with proportion of 5-45% by weight are added to the final solution and the solution is completed to unit volume with water. Nutrient element mixtures like N, P, K, S, Mg with proportion of 10% by weight, which are among the macro nutrient substances, and like Fe, Zn, Cu, Mo, Mn with proportion of 0.01 -1% by weight, which are among the micro nutrient substances, are added to the solution.
By means of the subject matter protection composition, color change and necrosis of fruits and vegetables due to UV rays are prevented and the temperature stress is decreased and calcium deficiency depending on temperature stress is eliminated and protein synthesis which decreases depending on temperature stress is accelerated. By means of the invention, titanium dioxide, which provides sun curtain effect, continuously exists on the fruit and leaf surfaces. Moreover, by means of the presence of calcium, boron and amino acid in the composition, a cumulative effect is obtained on the decreasing of the harmful effects of UV rays.
The protection scope of the present invention is set forth in the annexed claims and cannot be restricted to the illustrative disclosures given above, under the detailed description. It is because a person skilled in the relevant art can obviously produce similar embodiments under the light of the foregoing disclosures, without departing from the main principles of the present invention.

Claims

1. A sun protection composition prepared in the form of solution and applied onto the leafage and fruits of agricultural products and which provides protection of leafage and fruits from UV rays by means of titanium dioxide existing in the solution, characterized in that the solution comprises CaO which provides transportation of calcium from the leafage to the fruits in the product which is under stress and total amino acids which provide boron and protein synthesis in order to provide transfer of said CaO.
2. A sun protection composition according to claim 1 , wherein the solution comprises 5- 12% CaO by weight.
3. A sun protection composition according to claim 1 , wherein the solution comprises 0.5-2% boron by weight.
4. A sun protection composition according to claim 1 , wherein the solution comprises 2- 5% total amino acid by weight.
5. A sun protection composition according to claim 1 , wherein the solution comprises 0.1 -0.5% silica gel by weight.
6. A sun protection composition according to claim 1 , wherein the solution comprises macro nutrient substance with proportion of 10% by weight prepared by at least one of N, P, K, S, Mg elements.
7. A sun protection composition according to claim 1 , wherein the solution comprises micro nutrient substance with proportion of 0.01 -1 % by weight prepared by at least one of Fe, Zn, Cu, Mo, Mn elements.
8. A sun protection composition according to claim 1 , wherein the solution comprises 5- 45% dispersion and emulsifier mixture by weight.
9. A sun protection composition according to claim 1 or 2, wherein said CaO is obtained by means of dissolving calcium chloride or calcium nitrate in water.
10. A sun protection composition according to claim 1 or 3, wherein said boron is obtained from boric acid or boron ethanol amine.
PCT/TR2018/050379 2017-07-28 2018-07-18 Sun protection composition developed for agricultural products WO2019098959A2 (en)

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EP3915375A1 (en) 2020-05-26 2021-12-01 Everris International B.V. Improvements in foliar fertilizers
GB2601329A (en) * 2020-11-26 2022-06-01 Crop Intellect Ltd Agrochemical Method

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CN1092398A (en) * 1993-03-15 1994-09-21 四川省南充地区科委 A kind of foliar application fertilizer that is used for growing of mulberry
CN100341824C (en) * 2003-04-01 2007-10-10 栾雁 Animal and plant high effect ecological nutritive liquid and its preparation method
JP5559777B2 (en) * 2008-06-20 2014-07-23 ビーエーエスエフ ソシエタス・ヨーロピア Agrochemical formulation containing pesticide, organic UV light protection filter and coated metal oxide nanoparticles
US8557293B2 (en) * 2010-08-26 2013-10-15 Scott May Sunscreen compositions for application to plants
KR101690176B1 (en) * 2015-01-21 2017-01-09 주식회사 대유 Composite Fertilizer Compositions for Facilitating Plant Growth Under a Low- and High-Temperature Stress
CN105198644B (en) * 2015-10-28 2018-07-27 沈阳农业大学 A kind of multi-functional tomato high temperature resistance compound formulation and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3915375A1 (en) 2020-05-26 2021-12-01 Everris International B.V. Improvements in foliar fertilizers
WO2021239839A1 (en) 2020-05-26 2021-12-02 Everris International B.V. Improvements in foliar fertilizers
GB2601329A (en) * 2020-11-26 2022-06-01 Crop Intellect Ltd Agrochemical Method

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