WO2019093875A1 - Multi-action liquid degreaser - Google Patents

Multi-action liquid degreaser Download PDF

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Publication number
WO2019093875A1
WO2019093875A1 PCT/MX2018/000119 MX2018000119W WO2019093875A1 WO 2019093875 A1 WO2019093875 A1 WO 2019093875A1 MX 2018000119 W MX2018000119 W MX 2018000119W WO 2019093875 A1 WO2019093875 A1 WO 2019093875A1
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WIPO (PCT)
Prior art keywords
degreaser
add
removal
minutes
acid
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PCT/MX2018/000119
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Spanish (es)
French (fr)
Inventor
Ramón Antonio MARTÍNEZ ROMERO
Original Assignee
Martinez Romero Ramon Antonio
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Publication of WO2019093875A1 publication Critical patent/WO2019093875A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds

Definitions

  • degreaser product that has the ability to remove or remove grease or oil from surfaces.
  • degreasers of domestic and industrial type, some with high risk in their use.
  • degreasers based on citrus, for floors of heavy industry, with enzymes, alkalis, acids, for cleaning electronic surfaces, micro-emulsion cleaner, for cleaning and maintenance of vehicles, with phosphatic amines, amines and quaternary compounds, for use heavy, biodegradable amphoteric surfactants, for engines, solvent base, soda base, domestic use, etc. Most of those used in the industry are more specific to a certain type of work. In the research on degreasers the following were found:
  • Cleaner agent for electronic surfaces Publication No.: CN105713742 A, with publication date: 2016-06-29.
  • Aqueous micro-emulsion cleaning / degreasing composition containing an improved builder Publication No .: WO 1991000337 Al, date of publication: 1991-01-10
  • Stable aqueous cleaning / degreasing compositions formulated in the form of true micro-emulsions and containing an improved component comprise (a) at least one moderately water-soluble organic solvent characterized by (i) has a solubility in water in a range of about 0.2 about 6% by weight, (ii) not being hydrocarbon or halide; (iii) has one or more functional groups similar or similar to oxygen, nitrogen, sulfur or phosphorus (iv) has a solvent for hydrophobic serum and (v) has an amount greater than the value of its solubility present; (b) a builder, (c) a solubilizing additive consisting of approximately 0.1% of its weight of a surfactant and from about 0 to 99.9 by weight of a coupler, this solubilizing additive is present in an amount not exceeding substantially the amount required to transform the combination of the organic solvent said builder of a true macro emulsion and less than required to form a solution and (d) such a composition exhibits an impro
  • a detergent for vehicle washing / a concentrated foam solution for the use of automatic vehicle washing equipment (a) 67-90% water as a dilution solvent (b) 9-14% ADBS as a foaming detergent; (c) at least 0.5% of a pH modifying substance, sufficient to stabilize the pH around 7.0 selected from mono, di and triethanolamine.
  • Detergent composition comprising phosphate amines. Publication No.: - CN104629963A, with publication date: 2015-05-20.
  • the invention describes a blood and oil ink stain remover, fruit juice and iron oxides that belong in the household chemical production of cleaning products.
  • the remover consists of remover compounds to remove ink stains on clothing, blood stains, printing ink and rust stains, vegetable oil, mixed stain remover, ink stains for ballpoint pens, oil-resistant printing ink, fruit juice and blood stains, mildew , stains of yellow mold, the invention describes the composition of the remover, which can efficiently remove dirt, oil stains and stains from mold and fist spots and different stains, vegetable oil, ballpoint ink stains, stains of rust, yellow mold, fruit juice and similar to other vegetable stains that can not be removed by detergents or fabric cloth cleaners.
  • the clothes are soft and fragrant.
  • the components used are: sodium sulfate, sodium EDTA, ethanolamine, polyoxyethylene of alkyl ether, alkyl sulfate, triethanolamine, butyl cellosolve, ethanol, deionized water among other compounds.
  • the invention relates to a wet leveling solution composition and its uses in particular exceeding that the wet leveling solutions in the prior art can not be used normally due to the cold weather in winter in northern China.
  • the problem can be overcome by a technical scheme, the composition of the leveling solution in proportion of the components by weight, a) 5-50 parts of an antioxidant agent, b) 1-12 parts of a cleaning agent, c) 0.5 -10 parts of a lubricant, d) 3-15 parts of an antifreeze, e) 3-12 parts of a pH conditioning agent and) f 28-73.5 parts of water.
  • the composition of the leveling solution can be used in a cold leveling process for rolled steel sheets. Determine / Oes. Publication No .: GB1293613A, date of publication: 1972-10- 18
  • the composition is a liquid detergent consisting of (i) of an aminolytic, lipolytic or protein enzyme optionally, (ii) at least 88% of a liquid surface active agent and (iii) water.
  • the enzyme can be an alpha mylase, glucoamylase, amino 1,6 alpha glucosidase, oligo 1,6-glucosidase, gastric lipase, pancreatic lipase, plant lipase, fungal lipase, bacterial lipase, pepsin, trypsin, chymotrypsin, elastase, papain, carboxypepsidase, keratin, aminopepsidase or a mixture of this.
  • the surface active agent may be a mixture of a mono salt, triethanolamine of an alkyl benzene or alkyl toluene, sulfuric acid, a mono fatty acid or diethanolamine or isopropanolamine and a polyoxyethylamine or an alcohol oxypropylene or alkyl phenol.
  • Specific examples include sulfuric acid: branched undecylbenzene, sulfonic acid, dodecyl benzene sulphonic acid, branched dodecyl benzene sulphonic acid, tridecyl benzene sulfonic acid and 11-15 alkyl benzene sulfonic acid; fatty acid alkanolamine from coconut oil, fatty acid from diethanolamine, lauryl diethanolamine acid, alcohol alkene, a mixture of alcohol 10-14 with oxyphenol and nonyl phenol. Amine and quaternary ammonium compounds made of ketone and aldehydes and their derivatives. Publication No .: US6235914B1, with publication date: 2001-05- 22.
  • a process for manufacturing a tertiary amine of the following formula (i) the process comprises a) reacting aldehyde or ketone with a glycol from a ketal or acetal !, (b) reacting a ketal or acetal with an acryloxytritrile of an ether , (c) reducing the nitrile ether to a tertiary acetal amine or a tertiary amine acetal, (d) Hydroxylating tertiary amino ketal or acetal tertiary amine a tertiary amine diol (e) esterifying the dial tertiary amino of the formula tertiary amino ester (1) where R1 and R2 are independent to a linear, branched or alkyl acid, alkene, alkyl or aryl hydrogen atom, containing a group of 1 to 18 carbons, independently of one another, having radicals of ac.
  • Biodegradable amphoteric surfactants based on linear C6a CU and predominant linear alcohols Publication No .: US12014577A1, with publication date: 2012- 06-07.
  • Amphoteric surfactant biodegradable to the surfactant having an excellent coupling, moderate foam, good detergency.
  • the radical-based amphoteric surfactant is a predominantly linear alkyl alkyl radical of 6 to 11 carbons and mixtures thereof are also disclosed.
  • composition is biodegradable, the amphoteric surfactant has an excellent efficient low coupling cleaning foam, clean surface and good detergency.
  • aqueous cleaner degreaser cleaner is formulated with at least one sparingly soluble organic solvent that has characteristics of specific composition, an active solubilizer and water.
  • the solubilizing additive may consist of 0.1% by weight, of a surfactant of 0 to 99.9% by weight and a coupler present in a minimum amount to solubilize the entire content of the organic solvent, but sufficient to emulsify the unsolubilized portion of the total content of the organic solvent.
  • the emulsion compositions thus formulated provide improvements to the degreaser.
  • the selected sulfactants are: dodecyl benzene sulphonic acid, monoethanolamine, triethanolamine, iso-propylamine, tridecyl benzene sulfonate, dodecyl potassium sulfonate, benzene and several other compounds.
  • the degreasers Chemically the way in which all degreasers work is dissolving the grease, for this the degreasers have a hydrophilic part and a lipophilic part.
  • the hydrophilic part allows us to dissolve all the compounds that are soluble in water and the lipophilic part dissolves all the compounds that are soluble in oils and fats.
  • the degreasers contain in their formulation, detergents that help to clean removing the dirt mainly.
  • the soda hydrolyzes the fat to form the lipophilic zone and can dissolve the fat.
  • the multi-action liquid degreaser efficiently removes dirt and grease, but the main difference with other degreasers is that it also cleans on graffiti based on indelible ink or enamel, on acid rain on facade panels , in tartar of surfaces of porcelain or marble, in spots of adhesive, as well as of cleaning of shiny or chromed metals.
  • Tartar is the accumulation of carbonate salts mainly, which come from water (CaCO 3 calcium carbonate or MgCO 3 Magnesium Carbonate) and which adhere to surfaces where there is moisture, as time passes.
  • carbonate salts mainly, which come from water (CaCO 3 calcium carbonate or MgCO 3 Magnesium Carbonate) and which adhere to surfaces where there is moisture, as time passes.
  • sarricides which are diluted acids and when reacting with carbonates the following reaction occurs:
  • the sarricides are elaborated mainly with hydrochloric acid and these get to damage the surfaces of porcelain, marble or stainless steel, burning or oxidizing the surfaces and, mostly, causing an irreversible damage when using these acidic products.
  • the multi-action liquid degreaser by its formulation removes carbonates (tartar) and fats or oils burned or called carbonized.
  • carbonates tartar
  • fats or oils burned or called carbonized In the industry there is a great variety where there are problems of carbonization as in kitchens, the lines of the pneumatic system in the transport sector. And this degreaser effectively removes tartar and burned oil
  • the liquid degreaser of multiple action besides being able to clean the aforementioned surfaces, has in its formulation the goodness of not being aggressive in its use, so the degree of risk in its handling is 1 in health under the safety standard of NFPN.
  • the multiple action liquid degreaser is a slightly alkaline degreaser, whose composition is indicated below, indicating the synonyms of the compounds and their CAS numbers respectively:
  • the multiple action degreaser contains in its formulation acidic and alkaline compounds, which neutralize each other, having properties of acidic pH, which allows the removal of carbonates and alkaline pH, which makes it an excellent fat cleanser. It also contains an excellent solvent that helps remove inks or enamels. It also has the surfactant nonyl phenol ethoxylated 10 moles, which is an excellent non-ionic surfactant, since it contains a hydrophilic part by its functional group -OH and a lipophilic part by the carbon chain, so it is used for the For the elaboration of detergents and degreasers, the pH of the chemical mixture results in an alkaline pH.
  • the method for manufacturing the multi-action degreaser comprises the following steps:
  • the control temperature of the process is at room temperature, not higher than 25 ° C.
  • the color obtained from the degreaser is amber.
  • the present invention protects, in addition to the components of the formulation, percentages of the chemical mixture, its manufacturing process and the dilutions in which it wishes to use.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to the formulation of a mixture, and the associated process, resulting in a liquid degreaser having multiple applications, since it can be used to remove dirt and grease in an efficient manner, as well as for cleaning acid rain, indelible ink and enamel paint stains (graffiti), adhesives stuck to smooth surfaces, rust spots, carbonised oils, shiny metals, scale on porcelain or marble surfaces, inter alia. The chemical mixture consists of 10 moles of nonylphenol ethoxylate, dodecylbenzene sulfonic acid, monoethanolamine, 2-butoxyethanol, preservative and additives. The degreaser is suitable for industrial and domestic use, and its use poses a low risk according to the NFPA standard system. The invention also relates to the formulation, the production method and the use of the degreaser in different dilutions.

Description

DESENGRASANTE LÍQUIDO DE ACCIÓN MÚLTIPLE  DEGREASER OF MULTIPLE ACTION LIQUID
DESCRIPCIÓN OBJETO DE LA INVENCIÓN DESCRIPTION OBJECT OF THE INVENTION
Proporcionar a la industria un producto de limpieza que, además de remover de manera eficiente mugre y grasa, como todos los desengrasantes, remueva también lluvia árida, manchas de plumón de tinta indeleble y pintura de esmalte (grafitis), adhesivos pegados en superficies lisas, manchas de óxidos, aceite carbonizado, metales brillosos y manchas de sarro, sin dañar las superficies de porcelanato o mármol, entre otros. Provide the industry with a cleaning product that, in addition to efficiently removing dirt and grease, like all degreasers, also removes arid rain, indelible ink downstains and enamel paint (graffiti), adhesives stuck to smooth surfaces, oxides stains, carbonized oil, shiny metals and tartar stains, without damaging porcelain or marble surfaces, among others.
ANTECEDENTES BACKGROUND
La definición general de desengrasante es: producto que tiene la capacidad para remover o quitar grasa o aceite de superficies. Existe una gran variedad de desengrasantes de tipo doméstico e industrial, algunos con alto riesgo en su uso. The general definition of degreaser is: product that has the ability to remove or remove grease or oil from surfaces. There is a wide variety of degreasers of domestic and industrial type, some with high risk in their use.
Podemos encontrar desengrasantes a base de cítricos, para suelos de industria pesada, con enzimas, alcalinos, ácidos, para limpieza de superficies electrónicas, micro- emulsión limpiadora, para limpieza y mantenimiento de vehículos, con aminas fosfatadas, aminas y compuestos cuaternarios, de uso pesado, tensoactivos anfóteros biodegradables, para motores, base solvente, base sosa, uso doméstico, etc. La mayoría de los utilizados en la industria son más específicos para determinado tipo de trabajo. En la investigación sobre desengrasantes se encontraron los siguientes: We can find degreasers based on citrus, for floors of heavy industry, with enzymes, alkalis, acids, for cleaning electronic surfaces, micro-emulsion cleaner, for cleaning and maintenance of vehicles, with phosphatic amines, amines and quaternary compounds, for use heavy, biodegradable amphoteric surfactants, for engines, solvent base, soda base, domestic use, etc. Most of those used in the industry are more specific to a certain type of work. In the research on degreasers the following were found:
Agente Limpiador de superficies electrónicas; No. de Publicación: CN105713742 A, con fecha de publicación: 2016-06-29. Incluye 32-36 partes de peso de trifosfato de sodio, 34-38 partes de peso de esterato de sacarosa, 30-34 partes de peso de nonil fenol éter, 28-32 partes de peso de ácido etidrónico, 28-32 partes de peso de etilen glicol mono butil éter, 30-34 partes de peso de dilaurate de butil estaño, 28-32 partes de peso ácido graso de dietanolamina, 34-38 partes de peso de mercapto benzotiazol de sodio, 30-34 partes de peso de acetato de metilo, 28-32 partes de peso de monooleato de sorbitan, 34-38 partes de alquil fenol éter, 30-34 partes de peso de polidimetil siloxano metil, 30-34 partes de peso ftalato di- butílico, 28-32 partes de peso de aldehido cinámico. Cleaner agent for electronic surfaces; Publication No.: CN105713742 A, with publication date: 2016-06-29. Includes 32-36 parts by weight of sodium triphosphate, 34-38 parts by weight of sucrose stearate, 30-34 parts by weight of nonyl phenol ether, 28-32 parts by weight of etidronic acid, 28-32 parts by weight of ethylene glycol mono butyl ether, 30-34 weight parts of butyl tin dilaurate, 28-32 weight parts of diethanolamine fatty acid, 34-38 weight parts of sodium mercapto benzothiazole, 30-34 weight parts of acetate of methyl, 28-32 parts by weight of sorbitan monooleate, 34-38 parts of alkyl phenol ether, 30-34 parts by weight of polydimethyl siloxane methyl, 30-34 parts by weight di-butyl phthalate, 28-32 parts by weight weight of cinnamic aldehyde.
Composición acuosa de micro-emulsión limpiadora/desengrasante que contiene un constructor mejorado; No. de Publicación: WO 1991000337 Al, con fecha de publicación: 1991-01-10  Aqueous micro-emulsion cleaning / degreasing composition containing an improved builder; Publication No .: WO 1991000337 Al, date of publication: 1991-01-10
Las composiciones estables acuosas limpiadoras/desengrasantes formuladas en forma de micro-emulsiones verdaderas y que contienen un componente mejorado comprenden (a) al menos un disolvente orgánico moderadamente soluble al agua caracterizado por (i) tiene una solubilidad en el agua en un rango aproximado 0.2 aproximadamente 6 % en peso, (ii) no siendo hidrocarburo o halogenuro; (iii) tiene uno o más grupos funcionales similares o parecidos al oxígeno, nitrógeno, azufre o fosforo (iv) tiene un solvente por suero hidrofóbico y (v) tiene presente una cantidad superior al valor de su solubilidad; (b) un constructor, (c) un aditivo solubilizante que consiste en aproximadamente 0.1 % de su peso de un surfactante y de 0 a 99.9 aproximadamente en peso de un acoplador , este aditivo solubilizante está presente en una cantidad no excedentemente sustancial de la cantidad requerida a transformar la combinación del solvente orgánico dicho constructor de una macro emulsión verdadera y menos que lo requerido para formar una solución y (d) tal composición exhibe un limpiador improvisado. .Desengrasante eficaz que contenga otras composiciones no consideradas. Stable aqueous cleaning / degreasing compositions formulated in the form of true micro-emulsions and containing an improved component comprise (a) at least one moderately water-soluble organic solvent characterized by (i) has a solubility in water in a range of about 0.2 about 6% by weight, (ii) not being hydrocarbon or halide; (iii) has one or more functional groups similar or similar to oxygen, nitrogen, sulfur or phosphorus (iv) has a solvent for hydrophobic serum and (v) has an amount greater than the value of its solubility present; (b) a builder, (c) a solubilizing additive consisting of approximately 0.1% of its weight of a surfactant and from about 0 to 99.9 by weight of a coupler, this solubilizing additive is present in an amount not exceeding substantially the amount required to transform the combination of the organic solvent said builder of a true macro emulsion and less than required to form a solution and (d) such a composition exhibits an improvised cleaner. . Effective degreaser containing other compositions not considered.
Detergente para lavado de vehículos/ Espuma y métodos; No. de Publicación: USS534199A, con fecha de publicación: 1996-07-09 Detergent for vehicle washing / Foam and methods; Publication No .: USS534199A, date of publication: 1996-07-09
Un detergente para lavado de vehículos / una solución de espuma concentrada para uso de equipo automático de lavado de vehículos (a) 67-90 % de agua como solvente de dilución (b) 9-14 % ADBS como agente detergente formador de espuma; (c) al menos 0.5 % de una sustancia modificadora de pH, suficiente para estabilizar el pH alrededor de 7.0 seleccionado de mono, di y trietanolamina. (d) 1.8-2.S % de ácido graso de amina a 2:1 (DEA) amina de dietanol cocoamina, a 1:1 DEA, a 2:1 de monoetanolamina de coco (MEA) y 1:1 de cocoamina MEA, 82 % en agua como detergente y formador de espuma, (e) 0.9 a 1.4 de cocodimetil amino propil Betania como agente espumante, (f) 0.9 a 1.4 LESS como detergente y agente formador de espuma, (g) 0.6-1.6 de propilen glicol como solvente y (h) nonil fenol etoxilado; también es protegido el método de uso de la venta de solución (i) medida del detergente dentro del flujo del agua a una concentración de 100 a 300 partes de agua (ii) aplicación de la solución concentrada para el lavado a chorro de vehículos (iii) purificación de la solución concentrada y flujo de agua para los vehículos.  A detergent for vehicle washing / a concentrated foam solution for the use of automatic vehicle washing equipment (a) 67-90% water as a dilution solvent (b) 9-14% ADBS as a foaming detergent; (c) at least 0.5% of a pH modifying substance, sufficient to stabilize the pH around 7.0 selected from mono, di and triethanolamine. (d) 1.8-2.S% fatty acid amine to 2: 1 (DEA) cocoamine diethanol amine, 1: 1 DEA, 2: 1 coconut monoethanolamine (MEA) and 1: 1 cocoaamine MEA , 82% in water as detergent and foamer, (e) 0.9 to 1.4 cocodimethyl amino propyl Betania as foaming agent, (f) 0.9 to 1.4 LESS as detergent and foaming agent, (g) 0.6-1.6 propylene glycol as solvent and (h) nonyl phenol ethoxylate; the method of use of the sale of solution (i) is also protected by measuring the detergent within the water flow at a concentration of 100 to 300 parts of water (ii) application of the concentrated solution for jet washing of vehicles (iii) ) purification of the concentrated solution and water flow for the vehicles.
Composición de detergente que comprende aminas fosfatadas. No. de Publicación: - CN104629963A, con fecha de publicación: 2015-05-20. Detergent composition comprising phosphate amines. Publication No.: - CN104629963A, with publication date: 2015-05-20.
La invención describe un removedor de manchas de tinta de sangre y aceite, jugo de frutas y óxidos de fierro que pertenecen en la producción operador de químicos del hogar de productos limpiadores. El removedor consiste en compuestos removedores para quitar manchas de tinta en la ropa, manchas de sangre, tinta de imprenta y manchas de óxido, aceite vegetal, desincrustante de manchas mixtas manchas de tinta de bolígrafo, tinta de impresión resistente al aceite, jugo de frutas y manchas de sangre, moho, manchas de moho amarillo, la invención describe la composición del removedor, el cual puede remover eficientemente, la suciedad, manchas de aceite y manchas de moho y manchas de puño y diferentes manchas, aceite vegetal, manchas de impresión de tinta de bolígrafo, manchas de óxido, moho amarillo, jugo de frutas y similares a otras manchas de vegetales que no pueden ser removidos por detergentes o limpiadores de telas de ropa. Tiene la función que la ropa sea suave y con fragancia. Entre los componentes que utiliza están: sulfato de sodio, EDTA de sodio, etanolamina, polioxietileno de aquil éter, sulfato de alquil, trietanolamina, butilcellosolve, etanol, agua desionizada entre otros compuestos. The invention describes a blood and oil ink stain remover, fruit juice and iron oxides that belong in the household chemical production of cleaning products. The remover consists of remover compounds to remove ink stains on clothing, blood stains, printing ink and rust stains, vegetable oil, mixed stain remover, ink stains for ballpoint pens, oil-resistant printing ink, fruit juice and blood stains, mildew , stains of yellow mold, the invention describes the composition of the remover, which can efficiently remove dirt, oil stains and stains from mold and fist spots and different stains, vegetable oil, ballpoint ink stains, stains of rust, yellow mold, fruit juice and similar to other vegetable stains that can not be removed by detergents or fabric cloth cleaners. It has the function that the clothes are soft and fragrant. Among the components used are: sodium sulfate, sodium EDTA, ethanolamine, polyoxyethylene of alkyl ether, alkyl sulfate, triethanolamine, butyl cellosolve, ethanol, deionized water among other compounds.
Una composición de solución de nivelación húmeda y sus usos. No. de Publicación: CN104342272A, con fecha de publicación: 2015-02-15  A composition of wet leveling solution and its uses. Publication No .: CN104342272A, with publication date: 2015-02-15
La invención se refiere a una composición de solución de nivelación húmeda y sus usos superando principalmente en que las soluciones de nivelación en húmedo en la técnica anterior no puede usar se normalmente debido al tiempo frió en invierno en el norte de China. El problema puede ser superado por un esquema técnico, la composición de la solución de nivelación en proporción de los componentes en peso, a) 5-50 partes de un agente antioxidante, b) 1-12 partes de un agente limpiador, c) 0.5 -10 partes de un lubricante, d) 3-15 partes de un anticongelante, e) 3-12 partes de un agente acondicionador de pH y )f 28- 73.5 partes de agua. La composición de la solución de nivelación puede usarse en un proceso de nivelación en frío para chapas de acero en rollo. Deterge/Oes. No. de Publicación: GB1293613A, con fecha de publicación: 1972-10- 18 The invention relates to a wet leveling solution composition and its uses in particular exceeding that the wet leveling solutions in the prior art can not be used normally due to the cold weather in winter in northern China. The problem can be overcome by a technical scheme, the composition of the leveling solution in proportion of the components by weight, a) 5-50 parts of an antioxidant agent, b) 1-12 parts of a cleaning agent, c) 0.5 -10 parts of a lubricant, d) 3-15 parts of an antifreeze, e) 3-12 parts of a pH conditioning agent and) f 28-73.5 parts of water. The composition of the leveling solution can be used in a cold leveling process for rolled steel sheets. Determine / Oes. Publication No .: GB1293613A, date of publication: 1972-10- 18
La composición es un detergente líquido que consiste (i) de una enzima aminolítica, lipolítica o protéica opcionalmente, (ii) al menos un 88 % de un líquido agente activo superficial y (iii) agua. La enzima puede ser una alfa milasa, glucoamilasa, amino 1, 6 alfa glucosidasa, oligo 1, 6 alfa glucosidasa, lipasa gástrica, lipasa pancreática, lipasa vegetal, lipasa fungal, lipasa bacterial, pepsina, tripsina, una quimotripsina, elastasa, papaína, carboxipepsidasa, keratina, aminopepsidasa o una mezcla de esto. El agente activo superficial puede ser una mezcla de una sal mono, dio trietanolamina de un alquil benceno o alquil tolueno, ácido sulfúrico, un ácido graso mono o dietanolamina o isopropanolamina y una polioxietilamina o alcohol oxipropietanol o alquil fenol. Ejemplos específicos incluyen ácido sulfúrico: ramificado undecilbenceno, ácido sulfonico, ácido dodecil bencen sulfónico, ramificado ácido dodecil bencen sulfónico, ácido tridecil bencen sulfónico y ácido 11-15 alquil bencen sulfonico; ácido graso alcanolamina de aceite de coco, ácido graso de dietanolamina, ácido lauril dietanolamina, alcohol alqueno, una mezcla de alcohol 10-14 con oxifenol y nonil fenol. Amina y compuestos cuaternarios de amonio hechos de cetona y aldehidos y sus derivados. No. de Publicación: US6235914B1, con fecha de publicación: 2001-05- 22.  The composition is a liquid detergent consisting of (i) of an aminolytic, lipolytic or protein enzyme optionally, (ii) at least 88% of a liquid surface active agent and (iii) water. The enzyme can be an alpha mylase, glucoamylase, amino 1,6 alpha glucosidase, oligo 1,6-glucosidase, gastric lipase, pancreatic lipase, plant lipase, fungal lipase, bacterial lipase, pepsin, trypsin, chymotrypsin, elastase, papain, carboxypepsidase, keratin, aminopepsidase or a mixture of this. The surface active agent may be a mixture of a mono salt, triethanolamine of an alkyl benzene or alkyl toluene, sulfuric acid, a mono fatty acid or diethanolamine or isopropanolamine and a polyoxyethylamine or an alcohol oxypropylene or alkyl phenol. Specific examples include sulfuric acid: branched undecylbenzene, sulfonic acid, dodecyl benzene sulphonic acid, branched dodecyl benzene sulphonic acid, tridecyl benzene sulfonic acid and 11-15 alkyl benzene sulfonic acid; fatty acid alkanolamine from coconut oil, fatty acid from diethanolamine, lauryl diethanolamine acid, alcohol alkene, a mixture of alcohol 10-14 with oxyphenol and nonyl phenol. Amine and quaternary ammonium compounds made of ketone and aldehydes and their derivatives. Publication No .: US6235914B1, with publication date: 2001-05- 22.
Un proceso para fabricar una amina terciaria de la siguiente formula, (i) el proceso comprende a) reaccionar aldehido o cetona con un glicol a partir de un cetal o aceta!, (b) reaccionando un cetal o acetal con un acriloxitrilo de un éter, (c) reduciendo el éter nitrilo a una amina terciariacetal o un acetal amina terciaria, (d) Hidroxilando cetal amino terciaria o acetal amina terciaria un diol amina terciaria (e) esterificando el dial amino terciario de la fórmula éster amino terciario (1) donde R1 y R2 independientes a un átomo de hidrogeno lineal, ramificado o alquil ácid, alqueno, alquil o aril, conteniendo un grupo de 1 a 18 carbones, siendo independientemente uno del otro, teniendo radicales de ac. Grasos de 6-22 átomos de carbono, el proceso incluye un poco más, (f) protoneando o cuarterniando la fórmula de éter aminoterciario: donde A es un anión orgánico o inorgánico. A process for manufacturing a tertiary amine of the following formula, (i) the process comprises a) reacting aldehyde or ketone with a glycol from a ketal or acetal !, (b) reacting a ketal or acetal with an acryloxytritrile of an ether , (c) reducing the nitrile ether to a tertiary acetal amine or a tertiary amine acetal, (d) Hydroxylating tertiary amino ketal or acetal tertiary amine a tertiary amine diol (e) esterifying the dial tertiary amino of the formula tertiary amino ester (1) where R1 and R2 are independent to a linear, branched or alkyl acid, alkene, alkyl or aryl hydrogen atom, containing a group of 1 to 18 carbons, independently of one another, having radicals of ac. Greases of 6-22 carbon atoms, the process includes a little more, (f) prototyping or quartering the aminotercial ether formula: where A is an organic or inorganic anion.
Composición para el mantenimiento de autos. No. de Publicación: EP350540A1, con fecha de publicación: 19904)1-17.  Composition for the maintenance of cars. Publication No .: EP350540A1, with publication date: 19904) 1-17.
Una formulación para el mantenimiento del auto, basado en una mezcla bien equilibrada de componentes activos, la presente aplicación permite la producción de composiciones adecuadas para diversos fines, como de limpieza de tapicería, retirar manchas de tapicería, limpieza de autos, lavado y encerado de autos, limpieza de cristales, como líquido de enfriamiento, como líquido de frenos, como limpiador de neumáticos, antiespesante.  A formulation for the maintenance of the car, based on a well-balanced mixture of active components, the present application allows the production of suitable compositions for various purposes, such as upholstery cleaning, removal of upholstery stains, car cleaning, washing and waxing. cars, glass cleaning, cooling fluid, brake fluid, tire cleaner, anti-thickener.
Tensoactivos anfóteros biodegradables basado en C6a CU lineal y alcoholes lineales predominantes. No. de Publicación: US12014577A1, con fecha de publicación: 2012- 06-07. Biodegradable amphoteric surfactants based on linear C6a CU and predominant linear alcohols. Publication No .: US12014577A1, with publication date: 2012- 06-07.
Se- describe tensoactivo anfótero biodegradable al tensoactivo que tiene un excelente acoplamiento, espuma moderada, buena detergencia. El tensoactivo anfótero basado radical alquilo un radical predominante lineal alquilo ® de 6 a 11 carbonos y también se describe mezclas de los mismos.  Amphoteric surfactant biodegradable to the surfactant is described having an excellent coupling, moderate foam, good detergency. The radical-based amphoteric surfactant is a predominantly linear alkyl alkyl radical of 6 to 11 carbons and mixtures thereof are also disclosed.
La composición es biodegradable, el surfactante anfotérico tiene un excelente eficiente acoplamiento baja espuma limpiadora, superficie limpia y buena detergencia. Composición de limpiador acuoso I emulsión desengrasante No. de Publicación: EPS06744A1, con fecha de publicación: 1992-10-07. The composition is biodegradable, the amphoteric surfactant has an excellent efficient low coupling cleaning foam, clean surface and good detergency. Composition of aqueous cleaner I degreasing emulsion Publication No.: EPS06744A1, with publication date: 1992-10-07.
Composición estable, limpiador acuoso limpiador desengrasante es formulado con al menos un disolvente orgánico poco soluble que tiene características de composición específica, un activo solubilizante y agua. El aditivo solubilizante puede consistir en 0.1 % en peso, de un surfactante de 0 a 99.9 % en peso y un acoplador presente en una mínima cantidad para solubilizar todo el contenido del solvente orgánico, pero suficiente para emulsionar la porción no solubilizada del contenido total del disolvente orgánico. Las composiciones de la emulsión así formuladas aportan mejoras al desengrasante.  Stable composition, aqueous cleaner degreaser cleaner is formulated with at least one sparingly soluble organic solvent that has characteristics of specific composition, an active solubilizer and water. The solubilizing additive may consist of 0.1% by weight, of a surfactant of 0 to 99.9% by weight and a coupler present in a minimum amount to solubilize the entire content of the organic solvent, but sufficient to emulsify the unsolubilized portion of the total content of the organic solvent. The emulsion compositions thus formulated provide improvements to the degreaser.
Los sulfactantes seleccionados son: ácido dodecil bencen sulfonico, monoetanolamina, tríetanolamina, iso-propilamina, tridecil bencen sulfonato, sulfonato de potasio de dodecil, Benceno y varios compuestos más.  The selected sulfactants are: dodecyl benzene sulphonic acid, monoethanolamine, triethanolamine, iso-propylamine, tridecyl benzene sulfonate, dodecyl potassium sulfonate, benzene and several other compounds.
Químicamente la manera como trabajan todos los desengrasantes es disolviendo la grasa, para esto los desengrasantes cuentan con una parte Hidrófíla y una parte lipófíla. La parte hidrófíla nos permite disolver todos los compuestos que son solubles al agua y la parte lipófila disuelve todos los compuestos que son soluble a los aceites y grasas. Los desengrasantes contienen en su formulación, detergentes que ayudan a limpiar removiendo la mugre principalmente. Chemically the way in which all degreasers work is dissolving the grease, for this the degreasers have a hydrophilic part and a lipophilic part. The hydrophilic part allows us to dissolve all the compounds that are soluble in water and the lipophilic part dissolves all the compounds that are soluble in oils and fats. The degreasers contain in their formulation, detergents that help to clean removing the dirt mainly.
Los desengrasante que utilizan en su formulación sosa (NaOH) como desengrasante, es necesario esperar cierto tiempo para desarrollar la siguiente reacción de saponificación. The degreasers that use in their formulation soda (NaOH) as degreaser, it is necessary to wait some time to develop the next saponification reaction.
Figure imgf000009_0001
En la cual, la sosa hidroliza la grasa para formar la zona lipófila y pueda disolver la grasa.
Figure imgf000009_0001
In which, the soda hydrolyzes the fat to form the lipophilic zone and can dissolve the fat.
El desengrasante líquido de acción múltiple remueve de manera eficiente la mugre y la grasa, pero la diferencia principal con los demás desengrasantes, es que también ejerce acción de limpieza sobre grafitis a base de tinta indeleble o de esmalte, sobre lluvia ácida en paneles de fachada, en sarro de superficies de porcelanato o mármol, en manchas de adhesivo, así como de limpieza de metales brillosos o cromados. The multi-action liquid degreaser efficiently removes dirt and grease, but the main difference with other degreasers is that it also cleans on graffiti based on indelible ink or enamel, on acid rain on facade panels , in tartar of surfaces of porcelain or marble, in spots of adhesive, as well as of cleaning of shiny or chromed metals.
El sarro es la acumulación de sales de carbonato principalmente, que provienen del agua (CaCO3 carbonato de calcio ó MgCO3 Carbonato de Magnesio) y que se adhieren a las superficies donde hay humedad, a medida que va pasando el tiempo. Para la remoción del sarro es común utilizar sarricidas, que son ácidos diluidos y que al reaccionar con los carbonatos ocurre la siguiente reacción: Tartar is the accumulation of carbonate salts mainly, which come from water (CaCO 3 calcium carbonate or MgCO 3 Magnesium Carbonate) and which adhere to surfaces where there is moisture, as time passes. For the removal of tartar it is common to use sarricides, which are diluted acids and when reacting with carbonates the following reaction occurs:
Figure imgf000009_0002
A medida que el agua, en determinado lugar, es más dura, significa que contiene más carbonates, por lo que el sarro se forma más rápidamente.
Figure imgf000009_0002
As water, in a certain place, is harder, it means that it contains more carbonates, so tartar builds up more quickly.
Los sarricidas son elaborados principalmente con ácido clorhídrico y éstos llegan a dañar las superficies de porcelanatos, mármol o de acero inoxidable, quemando u oxidando las superficies y, en su mayoría, causando un daño irreversible al utilizar estos productos ácidos. Esto mismo sucede con las manchas de lluvia ácida en los paneles que se colocan en las fachadas, ya que con la lluvia y el polvo manchan fácilmente y la mayoría de los productos que' actualmente existen en el mercado, causan de igual manera daños a estas superficies de manera irreversible. The sarricides are elaborated mainly with hydrochloric acid and these get to damage the surfaces of porcelain, marble or stainless steel, burning or oxidizing the surfaces and, mostly, causing an irreversible damage when using these acidic products. The same happens with the acid rain spots on the panels that are placed on the facades, since with the rain and dust they stain easily and most of the products that currently exist on the market, also cause damage to these surfaces irreversibly.
El desengrasante liquido de acción múltiple por su formulación remueve los carbonatas (sarro) y grasas o aceites quemados o llamados carbonizados. En la industria existe una gran variedad donde se presenta problemas de carbonización como en cocinas, las líneas del sistema neumático en el sector del transporte. Y este desengrasante remueve eficazmente el sarro y aceite quemado The multi-action liquid degreaser by its formulation removes carbonates (tartar) and fats or oils burned or called carbonized. In the industry there is a great variety where there are problems of carbonization as in kitchens, the lines of the pneumatic system in the transport sector. And this degreaser effectively removes tartar and burned oil
El desengrasante líquido de acción múltiple, además de poder limpiar las superficies antes mencionadas, tiene en su formulación la bondad de no ser agresivo en su uso, por lo que el grado de riesgo en su manejo es 1 en salud bajo la norma de seguridad de NFPN. DESCRIPCIÓN DETALLADA DE LA INVENCIÓN The liquid degreaser of multiple action, besides being able to clean the aforementioned surfaces, has in its formulation the goodness of not being aggressive in its use, so the degree of risk in its handling is 1 in health under the safety standard of NFPN. DETAILED DESCRIPTION OF THE INVENTION
El desengrasante líquido de acción múltiple, es un desengrasante ligeramente alcalino, cuya composición se indica a continuación, señalando los sinónimos de los compuestos y sus números CAS respectivamente:  The multiple action liquid degreaser is a slightly alkaline degreaser, whose composition is indicated below, indicating the synonyms of the compounds and their CAS numbers respectively:
Figure imgf000011_0001
Figure imgf000011_0001
El desengrasante de acción múltiple, contiene en su formulación compuestos ácidos y alcalinos, los cuales se neutralizan entre si, teniendo propiedades de pH ácido, lo que permite remover carbonates y de pH alcalino, que lo hace excelentemente eficiente limpiador de grasas. Así mismo contiene un excelente solvente que ayuda a remover tintas o esmaltes. Cuenta también con el surfactante nonil fenol etoxilado de 10 moles, el cual es un excelente surfactante no iónico, dado que contiene una parte hidrófila por su grupo funcional -OH y una parte lipófila por la cadena de carbonos, por lo que es utilizado para la elaboración de detergentes y desengrasantes, el pH de la mezcla química da como resultado un pH alcalino.  The multiple action degreaser contains in its formulation acidic and alkaline compounds, which neutralize each other, having properties of acidic pH, which allows the removal of carbonates and alkaline pH, which makes it an excellent fat cleanser. It also contains an excellent solvent that helps remove inks or enamels. It also has the surfactant nonyl phenol ethoxylated 10 moles, which is an excellent non-ionic surfactant, since it contains a hydrophilic part by its functional group -OH and a lipophilic part by the carbon chain, so it is used for the For the elaboration of detergents and degreasers, the pH of the chemical mixture results in an alkaline pH.
A continuación presento una tabla donde aparece la formulación de manera volumétrica y porcentual, donde es necesario considerar los porcentajes para multiplicar y preparar el volumen necesario. 11 Below I present a table where the formulation appears volumetric and percentage, where it is necessary to consider the percentages to multiply and prepare the necessary volume. eleven
Figure imgf000012_0001
Figure imgf000012_0001
PROCESO PROCESS
EL método para la fabricación del desengrasante de acción múltiple comprende las siguientes etapas: The method for manufacturing the multi-action degreaser comprises the following steps:
• Medir los volúmenes de los diferentes componentes.  • Measure the volumes of the different components.
• Adicionar en un tanque de preparación la cantidad de agua necesaria.  • Add the amount of water needed in a preparation tank.
• Agitar a una velocidad máxima durante todo el proceso a 80 rpm  • Shake at a maximum speed throughout the process at 80 rpm
• Agregar el Ácido dodecil bencen sulfónico.  • Add dodecyl benzenesulfonic acid.
• Dejar en agitación de 20 a 40 minutos hasta su integración total sin la presencia de grumos.  • Leave in agitation for 20 to 40 minutes until full integration without the presence of lumps.
• Mezclar en otro tanque el nonil fenol etoxilado de 10 moles y el 2 butoxi etanol a una agitación máxima de 80 rpm, durante un tiempo mínimo de 5 minutos. • Mix in another tank the ethoxylated nonyl phenol of 10 moles and the 2 butoxy ethanol at a maximum agitation of 80 rpm, for a minimum time of 5 minutes.
• Adicionar la mezcla anterior al tanque que contiene el agua-ácido dodecil bencen sulfónico. • Agitar durantelO minutos. • Add the previous mixture to the tank containing the water-dodecylbenzenesulfonic acid. • Shake for 10 minutes.
• Agregar la monoelanolamina  • Add monoelanolamine
• Continuar la agitación con un mínimo de 10 minutos.  • Continue the agitation with a minimum of 10 minutes.
• Agregar el formol.  • Add formaldehyde.
• Agitar durante cinco minutos más.  • Stir for five more minutes.
• Envasar manteniendo la agitación.  • Pack while maintaining agitation.
Consideraciones: Considerations:
La temperatura de control del proceso es a temperatura ambiente, no mayor a 25° C. El color obtenido del desengrasante es ámbar.  The control temperature of the process is at room temperature, not higher than 25 ° C. The color obtained from the degreaser is amber.
Es opcional la adición de colorante y esencia para determinar el aspecto final del desengrasante de acción.  The addition of dye and essence is optional to determine the final appearance of the action degreaser.
La presente invención protege además de las componentes de la formulación porcentajes de la mezcla química, su proceso de elaboración y las diluciones en que desee utilizar. The present invention protects, in addition to the components of the formulation, percentages of the chemical mixture, its manufacturing process and the dilutions in which it wishes to use.

Claims

REIVINDICACIONES El desengrasante líquido de acción múltiple es un producto innovador, ya que supera lo que ofrecen los existentes en el meneado, caracterizado poique en su formulación amplía su espectro de acción al realizar, además de las funciones específicas, las indicadas en las características señaladas en el punto 3 de las siguientes reivindicaciones: CLAIMS The multiple action liquid degreaser is an innovative product, since it exceeds what is offered by the existing ones in the shaking, characterized by its formulation in its formulation broadens its spectrum of action to perform, in addition to the specific functions, those indicated in the characteristics indicated in Item 3 of the following claims:
1. Los componentes y concentraciones de este desengrasante de acción múltiple son:  1. The components and concentrations of this multiple action degreaser are:
■ Nonil Fenol Etoxilado de 10 moles a una concentración volumétrica de 8.0 al 12.0 %.  ■ Nonyl phenol ethoxylated 10 moles at a volumetric concentration of 8.0 to 12.0%.
■ Ácido Dodecil Bencen Sulfónico a una concentración volumétrica del 4.0 al 6.0 %.  ■ Dodecyl Benzene Sulphonic Acid at a volumetric concentration of 4.0 to 6.0%.
■ 2 butoxí Etanol a una concentración volumétrica del 4.0 al 7.0 %.  ■ 2 Butoxí Ethanol at a volumetric concentration of 4.0 to 7.0%.
■ Monoetanolamina a una concentración volumétrica del 4.0 al 6.0 %.  ■ Monoethanolamine at a volumetric concentration of 4.0 to 6.0%.
■ Fonnol como conservador a una concentración volumétrica del 0.1 al 0.3 %. ■ Fonnol as a preservative at a volumetric concentration of 0.1 to 0.3%.
■ Agua como Balance al 100 %. ■ Water as 100% Balance.
■ Opcional, agregar esn de esencia y color.  ■ Optional, add esn essence and color.
2. El Método para elaborar el desengrasante de acción múltiple comprende:  2. The Method to elaborate the multiple action degreaser comprises:
• Medir los volúmenes de los diferentes componentes.  • Measure the volumes of the different components.
• Adicionar en un tanque de preparación la cantidad de agua necesaria.  • Add the amount of water needed in a preparation tank.
• Agitar a una velocidad máxima durante todo el proceso a 80 rpm.  • Shake at a maximum speed throughout the process at 80 rpm.
• Agregar el Ácido Dodecil Bencen sulfonico.  • Add Dodecyl Benzene sulfonic acid.
• Dejar en agitación de 20 a 40 minutos hasta su integración total sin la presencia de grumos. • Mezclar en otro tanque el Nonil Fenol Etoxilado de 10 moles y el 2 Butoxi Etanol a una agitación máxima de 80 rpm, durante un tiempo mínimo de S minutos. • Leave in agitation for 20 to 40 minutes until full integration without the presence of lumps. • Mix in another tank the 10 moles Ethoxylated Nonyl Phenol and the 2 Butoxy Ethanol at a maximum agitation of 80 rpm, for a minimum time of S minutes.
• Adicionar la mezcla anterior (Nonil Fenol Etoxilado de 10 moles - 2 Butoxi Etanol) al tanque que contiene el agua-Acido Dodecil Bencen Sulfónico.  • Add the above mixture (Nonyl Phenol Ethoxylated 10 moles - 2 Butoxy Ethanol) to the tank containing the water-Dodecyl Benzene Sulphonic Acid.
• Agitar durante 10 minutos.  • Stir for 10 minutes.
• Agregar la Monoetanolamina  • Add Monoethanolamine
• Continuar la agitación durante un mínimo de 10 minutos.  • Continue agitation for a minimum of 10 minutes.
• Agregar el formol.  • Add formaldehyde.
• Agitar durante 5 minutos más.  • Stir for 5 more minutes.
• En caso de utilizar esencia y color, agregar en esta etapa para definir el color final para que no se vea afectado.  • In case of using essence and color, add at this stage to define the final color so that it is not affected.
• Envasar manteniendo la agitación.  • Pack while maintaining agitation.
Consideraciones: Considerations:
■ La temperatura de control del proceso es a temperatura ambiente, no mayor a 25° C.  ■ The process control temperature is at room temperature, not higher than 25 ° C.
■ El color natural obtenido del desengrasante, sin colorante, es ámbar.  ■ The natural color obtained from the degreaser, without colorant, is amber.
■ Es opcional la adición de colorante y esencia para determinar el aspecto final del desengrasante de acción.  ■ Adding dye and essence is optional to determine the final appearance of the action degreaser.
3. Aplicaciones y características de uso:  3. Applications and characteristics of use:
Remoción de incrustaciones de aceite quemado en líneas de acero inoxidable calentado a una temperatura máxima de 75° centígrados por recirculación. Remoción de suciedad, incrustaciones de ácido, polvo, hongos, etc. de intercambiadores y componentes de aire acondicionado, sin generar vapores ácidos. Removal of incrustations of burned oil in stainless steel lines heated to a maximum temperature of 75 ° C by recirculation. Removal of dirt, incrustations of acid, dust, fungi, etc. of exchangers and air conditioning components, without generating acid vapors.
Limpieza de metales, tales como acero inoxidable, plata, oro y cobre sin dañar a éstos.  Cleaning metals, such as stainless steel, silver, gold and copper without harming them.
Remoción de sarro en superficies como mármol, porcelanato y alucobond. Remoción de grafítis sobre superficies con pintura de esmalte o vinilicas.  Removal of scale on surfaces such as marble, porcelain and alucobond. Removal of graffiti on surfaces with enamel or vinyl paint.
Remoción de marcas de plumón de tinta indeleble sobre superficies vinilicas Remoción de manchas de grasa y mugre.  Removal of indelible ink markings on vinyl surfaces Removal of grease and grime stains.
No genera vapores tóxicos agresivos en su operación o uso. It does not generate aggressive toxic vapors in its operation or use.
Figure imgf000016_0001
Figure imgf000016_0001
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0400689A (en) * 2004-02-17 2005-10-11 Oxiteno Sa Ind E Comercio Synergistic compositions of highly concentrated surfactants, alkalizers and solvents for hygiene and cleaning applications
US20060135394A1 (en) * 2004-12-20 2006-06-22 Smith Kim R Car wash composition for hard water, and methods for manufacturing and using
MX2008012711A (en) * 2006-04-28 2008-10-15 Ecolab Inc A packaged cleaning composition concentrate and a method and system for forming a cleaning composition.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0400689A (en) * 2004-02-17 2005-10-11 Oxiteno Sa Ind E Comercio Synergistic compositions of highly concentrated surfactants, alkalizers and solvents for hygiene and cleaning applications
US20060135394A1 (en) * 2004-12-20 2006-06-22 Smith Kim R Car wash composition for hard water, and methods for manufacturing and using
MX2008012711A (en) * 2006-04-28 2008-10-15 Ecolab Inc A packaged cleaning composition concentrate and a method and system for forming a cleaning composition.

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