WO2019078750A1 - Process for producing a carob bar - Google Patents

Process for producing a carob bar Download PDF

Info

Publication number
WO2019078750A1
WO2019078750A1 PCT/PT2018/050040 PT2018050040W WO2019078750A1 WO 2019078750 A1 WO2019078750 A1 WO 2019078750A1 PT 2018050040 W PT2018050040 W PT 2018050040W WO 2019078750 A1 WO2019078750 A1 WO 2019078750A1
Authority
WO
WIPO (PCT)
Prior art keywords
carob
bar
sweetener
palm
emulsifier
Prior art date
Application number
PCT/PT2018/050040
Other languages
French (fr)
Portuguese (pt)
Inventor
Maria Margarida CORTEZ VIEIRA
Vera Lúcia DA CONCEIÇÃO DUARTE ALVES
Tânia Isabel DA PALMA MATEUS
Original Assignee
Carob World Portugal, Lda.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carob World Portugal, Lda. filed Critical Carob World Portugal, Lda.
Publication of WO2019078750A1 publication Critical patent/WO2019078750A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/238Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seeds, e.g. locust bean gum or guar gum
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/34Cocoa substitutes

Definitions

  • the present invention relates to a carob tree bar process comprising 8 steps as well as 4 carob bar slices produced respectively with 9 or 7 ingredients and by the said process.
  • the carob tree (Ceratonia siliqua L.) is a tree belonging to the Leguminosae Family, essentially cultivated in the Mediterranean region, mainly Spain, Italy, Portugal and Morocco.
  • Locust bean seeds and pods are used as feedstock in industries such as food, pharmaceutical and cosmetic products.
  • Locust gum is used as a natural food thickener, a stabilizer and flavoring agent, which can normally be added to a variety of products, such as ice-cream and candy (Durazzo et al., 2014; Seczyk et al. 2016).
  • Carob has long been used as a raw material for the production of food additives.
  • carob meal Due to its sweetness and taste similar to chocolate, as well as its low price, carob meal is widely used in the Mediterranean region as a substitute for cocoa in the food industry (Durazzo, et al., 2014; Seczyk et al., 2016).
  • Carob is characterized by a high content of soluble sugars (about 40-50%, mainly sucrose), low protein content (3-4%) and lipids (0.4-0.8%) and high content of polyphenols, especially tannins (Seczyk et al., 2016).
  • Polyphenols have good biological properties, such as antioxidant activity.
  • the antioxidant activity present in the polyphenols allows to prevent against the oxidation of some biomolecules, such as DNA, proteins and lipids (Seczyk et al., 2016).
  • Carob meal is a product that contains a high content of dietary fiber, minerals (Fe, Ca, Na, K and P) and vitamins (E, D, C, niacin, folic acid and B6).
  • locust bean meal as a functional ingredient (Seczyk et al., 2016).
  • the products made from this raw material have a distinctive and unique quality in order to be able to assert themselves in the market without having to a substitute and / or substitute raw material for cocoa.
  • Locust carob production process was carefully developed according to four carob rod recipes that were previously elaborated and selected through sensorial analysis performed through a panel of tasters.
  • the result of the four recipes, produced according to the carob rod manufacturing process described in the present invention, is presented as a natural and organic nutritional product which is manufactured from the processing of natural products with low sugar content , without cocoa and their respective endogenous exciting.
  • test panel consisted of 24 testers, 9 of whom were male and 15 were female.
  • the second sensory analysis was carried out by a panel of tasters consisting of 30 tasters, of whom 10 were male and 20 were female.
  • the third sensory analysis was performed on a panel of tasters consisting of 25 tasters, of whom 6 were male and 19 were female.
  • the characteristics of the 4 carob bars are selected by the 25 tasters according to the following 10 characteristics:
  • carob rod manufacturing process and respective carob rod recipes are manufactured according to the process described in the present invention which is shown in Figure 1.
  • the carob rod manufacturing process sequentially comprises the following 9 steps:
  • Step 2 mixing the raw materials
  • Step 5 hardening the mixture
  • Step 6 shaping the product
  • Step 7 cooling the carob bar
  • Step 9 packaging and storage.
  • step I are weighed each of about 8-11 ingredients or raw materials that constitute each of the respective four recipes carob bars.
  • the mixture of vegetable fats in the following amounts:
  • the third step will occur grinding of raw materials, for 2 to 12 hours at a temperature between 30 to 70 ° C and a particle size to be obtained of the ingredients with a particle size of from 10 to 30 m.
  • the fourth step there is the conching the mixture of fat and powders obtained in the previous step, for 6 to 24 hours at a temperature between 30 to 70 ° C to obtain the desired flavor, ensuring that the product when consumed are percecionado as homogeneous and has good rheological properties.
  • hardening of the mixture is performed by means of a temperadora for 1 to 4 hours and at a temperature between 25 and 50 ° C.
  • the quenching process of the base product in palm oil and locust beans significantly affects its physical and sensory properties of the blend.
  • the process was studied and fine tuned to control the temperature, crystallization time and stirring speed.
  • the temperature of the quench varies for each type of recipe to be produced, with milk and without milk, and respectively varies between 25 and 50 ° C.
  • step 6 is carried out at the molding mass through a die which will give the shape of the carob bar.
  • step 7 the molds are cooled in a cooling tunnel for 0.2 to 1 hour, at a temperature between 5 to 18 ° C and a relative humidity of 30 to 60% relative humidity.
  • the eighth step - will be held demoulding carob bar.
  • step 9 the packaging and storage will be performed.
  • the bar packaging process plays a key role in the preservation and protection of food during transportation and distribution.
  • the packaging is effected in a flow pack that surrounds the bar with a BOPP film.
  • Locust bean bar is manufactured in accordance with the locust bean bar manufacturing process previously described.
  • the locust bean bar described in the present invention comprises the following ingredients:
  • skim milk powder 0.00-20.25% skim milk powder
  • Preferred embodiments of the present invention invention are related to the ingredients or raw materials used in each of the respective 4 carob rod recipes:
  • the carob tree bar consists of 9 to 7 ingredients:
  • Carob bar without milk and without almonds, comprises the following ingredients:
  • the carob bar, with milk and with almonds comprises the following ingredients:
  • the bar of carob, with milk and with almonds is said 4 recipes which comprises the largest number of ingredients, a total of 9.
  • the carob bar without milk and with almonds, comprises the following ingredients:
  • Carob bar, with milk and without almonds comprises the following ingredients: - 33.30-43.85% of vegetable shortening of palm;

Abstract

The present invention relates to an 8-step process for producing carob bars and to four recipes for carob bars produced by this process.

Description

DESCRIÇÃO  DESCRIPTION
"PROCESSO DE FABRICO DE BARRA. DE ALFARROBA" "ALFARROBA BAR MANUFACTURING PROCESS"
ÂMBITO DA INVENÇÃO SCOPE OF THE INVENTION
A presente invenção refere-se a um processo de fabrico de barra de alfarroba que compreende 8 etapas, bem como a 4 receitas de barras de alfarroba produzida respetivamente com 9 ou 7 ingredientes e através do citado processo .  The present invention relates to a carob tree bar process comprising 8 steps as well as 4 carob bar slices produced respectively with 9 or 7 ingredients and by the said process.
Alfarroba Carob
A alfarroba (Ceratonia siliqua L.) é uma árvore pertence à Família Leguminosae, essencialmente cultivada na região do Mediterrâneo, principalmente Espanha, Itália, Portugal e Marrocos .  The carob tree (Ceratonia siliqua L.) is a tree belonging to the Leguminosae Family, essentially cultivated in the Mediterranean region, mainly Spain, Italy, Portugal and Morocco.
As sementes e vagens da alfarroba são utilizadas como matéria-prima nas indústrias tais como os produtos alimentares, farmacêuticos e cosméticos. Locust bean seeds and pods are used as feedstock in industries such as food, pharmaceutical and cosmetic products.
A goma de alfarroba (LBG) é utilizada como espessante alimentar natural, um estabilizador e aromatizante, que pode ser normalmente adicionado a uma variedade de produtos, como por exemplo gelados e doces (Durazzo, et al., 2014; Seczyk et al . , 2016). Locust gum (LBG) is used as a natural food thickener, a stabilizer and flavoring agent, which can normally be added to a variety of products, such as ice-cream and candy (Durazzo et al., 2014; Seczyk et al. 2016).
A alfarroba tem sido muito utilizada como matéria-prima para a produção de aditivos alimentares. Carob has long been used as a raw material for the production of food additives.
Devido à sua doçura e sabor semelhantes ao chocolate, bem como o seu baixo preço, a farinha de alfarroba é muito utilizada na região do Mediterrâneo como substituto de cacau na indústria alimentar (Durazzo, et al., 2014; Seczyk et al . , 2016). Due to its sweetness and taste similar to chocolate, as well as its low price, carob meal is widely used in the Mediterranean region as a substitute for cocoa in the food industry (Durazzo, et al., 2014; Seczyk et al., 2016).
0 facto de a alfarroba não conter cafeína, constitui mais uma grande vantagem face ao cacau. The fact that the carob does not contain caffeine is a major advantage over cocoa.
A alfarroba é caracterizada por conter elevado teor de açúcares solúveis (cerca de 40-50%, principalmente sacarose), baixo teor de proteína (3-4%) e lipídios (0,4- 0,8%) e ainda, elevado teor de polifenóis, especialmente taninos (Seczyk et al., 2016). Carob is characterized by a high content of soluble sugars (about 40-50%, mainly sucrose), low protein content (3-4%) and lipids (0.4-0.8%) and high content of polyphenols, especially tannins (Seczyk et al., 2016).
Os polifenóis têm boas propriedades biológicas, como a atividade antioxidante. Polyphenols have good biological properties, such as antioxidant activity.
A atividade antioxidante presente nos polifenóis permite prevenir contra a oxidação de algumas biomoléculas, como o DNA, proteínas e lipídios (Seczyk et al . , 2016). The antioxidant activity present in the polyphenols allows to prevent against the oxidation of some biomolecules, such as DNA, proteins and lipids (Seczyk et al., 2016).
A farinha de alfarroba é um produto que contém um elevado teor de fibra dietética, sais minerais (Fe, Ca, Na, K e P) e vitaminas (E, D, C, niacina, ácido fólico e B6) . Carob meal is a product that contains a high content of dietary fiber, minerals (Fe, Ca, Na, K and P) and vitamins (E, D, C, niacin, folic acid and B6).
Tendo em conta o elevado valor nutritivo, existe um aumento do uso de farinha de alfarroba como um ingrediente funcional (Seczyk et al . , 2016). Given the high nutritional value, there is an increased use of locust bean meal as a functional ingredient (Seczyk et al., 2016).
Devido às qualidades da alfarroba, os produtos fabricados com essa matéria-prima apresentam qualidade distintivas e únicas para se poderem afirmarem no mercado, sem terem a necessidade de se constituírem no mercado como uma matéria-prima sucedânea e ou substituta do cacau. Due to the qualities of the carob, the products made from this raw material have a distinctive and unique quality in order to be able to assert themselves in the market without having to a substitute and / or substitute raw material for cocoa.
Desenvolvimento da barra de alfarroba Carob Bar Development
O processo de fabrico de barra de alfarroba foi criteriosamente desenvolvido de acordo com 4 receitas de barras de alfarroba que foram previamente elaboradas e selecionadas por meio de análises sensoriais, realizadas por intermédio de um painel de provadores.  Locust carob production process was carefully developed according to four carob rod recipes that were previously elaborated and selected through sensorial analysis performed through a panel of tasters.
O resultado das 4 receitas, produzidas de acordo com o processo de fabrico da barra de alfarroba descrito na presente invenção, apresentam-se como um produto nutricional, natural e orgânico que é fabricado a partir da transformação de produtos naturais, com baixo teor de açúcar, sem cacau e os seus respetivos excitantes endógenos . The result of the four recipes, produced according to the carob rod manufacturing process described in the present invention, is presented as a natural and organic nutritional product which is manufactured from the processing of natural products with low sugar content , without cocoa and their respective endogenous exciting.
Dentro das citadas 4 receitas, 2 não têm a adição de leite, fazendo com que as mesmas possam ser consideradas vegan . Within the aforementioned 4 recipes, 2 do not have the addition of milk, causing them to be considered vegan.
Numa primeira fase da elaboração de cada uma das 4 barras, depois de identificados os ingredientes necessários, começou-se por testar diferentes receitas de barras . In a first stage of the elaboration of each one of the 4 bars, after identifying the necessary ingredients, it began by testing different bar recipes.
Para isso produziram-se algumas receitas que serviram de base para a perceção dos ingredientes e quantidades a utilizar na barra, como quantidade de alfarroba, gordura, amêndoa, leite, maltodextrina e adoçante . For this, some recipes were produced that served as a basis for the perception of the ingredients and quantities to be used in the bar, such as carob, fat, almond, milk, maltodextrin and sweetener.
Os testes realizados permitiram verificar que amêndoa deixava a barra mole, por isso optou-se por colocar amêndoa em pedaços . The tests carried out showed that Almond left the soft bar, so we chose to put almond into pieces.
Verificou-se ainda que os ingredientes necessitavam de uma moagem no mínimo de 2 horas num moinho de esferas para produzir cada uma das 4 barras com uma textura mais cremosa. It was further found that the ingredients required milling for at least 2 hours in a ball mill to produce each of the 4 bars having a creamier texture.
Após testes preliminares realizou-se o design de mistura com o objetivo de determinar as concentrações ótimas dos ingredientes para a produção das seguintes 4 receitas : After preliminary tests the mixing design was carried out in order to determine the optimal concentrations of the ingredients for the production of the following 4 recipes:
- barra de alfarroba com leite e sem amêndoas; - bar of carob with milk and without almonds;
- barra de alfarroba sem leite e sem amêndoas;- bar of carob without milk and without almonds;
- barra de alfarroba com leite e com amêndoas; e- bar of carob with milk and with almonds; and
- barra de alfarroba sem leite e com amêndoas. - bar of carob without milk and with almonds.
Para a realização do design de mistura, na primeira análise sensorial o painel de provas foi constituído por 24 provadores, dos quais 9 do sexo masculino e 15 do sexo feminino. In order to perform the mixing design, in the first sensory analysis the test panel consisted of 24 testers, 9 of whom were male and 15 were female.
A segunda análise sensorial foi realizada a um painel de provadores constituído por 30 provadores, dos quais 10 do sexo masculino e 20 do sexo feminino. The second sensory analysis was carried out by a panel of tasters consisting of 30 tasters, of whom 10 were male and 20 were female.
A terceira análise sensorial foi realizada a um painel de provadores constituído por 25 provadores, dos quais 6 do sexo masculino e 19 do sexo feminino. The third sensory analysis was performed on a panel of tasters consisting of 25 tasters, of whom 6 were male and 19 were female.
Média das respostas obtidas em cada caraterística . As características das 4 barras de alfarroba formam selecionadas pelos 25 provadores de acordo com as seguintes 10 características: Average of the answers obtained in each characteristic. The characteristics of the 4 carob bars are selected by the 25 tasters according to the following 10 characteristics:
- brilho;  - brightness;
- cor;  - color;
- aroma;  - aroma;
- dureza ao trincar;  - hardness when cracking;
- fusão na boca;  - fusion in the mouth;
- doçura;  - sweetness;
- amargor;  - bitterness;
- cremosidade;  - creaminess;
- sabor; e  - flavor; and
- sabor residual.  - residual taste.
Realizaram-se ainda diversos testes para definir as gorduras sucedâneas de manteiga de cacau e ajustar as quantidades apropriadas ao produto. A number of tests were also carried out to define the substitute fats of cocoa butter and to adjust the appropriate amounts to the product.
Estudaram-se também os processos fundamentais no desenvolvimento da barra, designadamente o processo de moagem e de temperização que permitem obter o brilho, textura e aspeto caraterísticos . We have also studied the fundamental processes in the development of the bar, namely the milling and tempering process that allow to obtain characteristic brightness, texture and appearance.
Para uma maior diversificação dos produtos estudou-se também a adição de amêndoa às barras com e sem leite, sendo este um fruto típico do Algarve (Portugal) , que também vai valorizar a barra de alfarroba. To further diversify the products, we also studied the addition of almond to the bars with and without milk, which is a typical fruit from the Algarve (Portugal), which will also value the carob tree.
Realizou-se o estudo do tempo de prateleira da barra durante 4 meses que permitiu estimar por diferentes testes (armazenamento a temperaturas controladas de 20 °C e 30 °C com ciclos de 12h até ao aparecimento de fat bloom) que as 4 receitas de barras descritas na presente invenção poderão ter um prazo de validade de 12 meses. The study of the shelf life of the bar during 4 months allowed to be estimated by different tests (storage at controlled temperatures of 20 ° C and 30 ° C with cycles of 12h until the appearance of fat bloom) that the four bar recipes described in the present invention may have a shelf life of 12 months.
Elaboraram-se as tabelas com os valores nutricionais e as menções especiais a constar no rótulo para efeitos de marketing dos 4 produtos desenvolvidos. The tables with the nutritional values and the special indications to be included in the label for the marketing purposes of the 4 products developed were elaborated.
Foram ainda realizadas as fichas técnicas dos ingredientes ou matérias-primas e dos 4 produtos desenvolvidos . The technical sheets of the ingredients or raw materials and the 4 products developed were also made.
Pesquisaram-se empresas fornecedoras de matérias- primas alternativas, nomeadamente gorduras e todos os ingredientes utilizados. Suppliers of alternative raw materials, namely fats and all the ingredients used, were investigated.
Analisaram-se os custos das matérias-primas para a produção dos produtos desenvolvidos. The costs of the raw materials for the production of the developed products were analyzed.
BREVE DESCRIÇÃO DA FIGURA APRESENTADA BRIEF DESCRIPTION OF THE PRESENT FIGURE
A descrição que se apresenta a seguir é elaborada com referência ao desenho que é apresentado apena a titulo de referência, sem qualquer caráter limitativo, e em que:  The following description is made with reference to the drawing which is presented for reference only, without any limiting character, and in which:
Fig.l - Fluxograma do processo de fabrico de barra de alfarroba Fig. 1 - Flowchart of the carob rod manufacturing process
SÍNTESE DA INVENÇÃO SUMMARY OF THE INVENTION
0 processo de fabrico de barra de alfarroba e respetivas 4 receitas de barras de alfarroba, são fabricadas de acordo com o processo descrito na presente invenção que está representado na figura 1.  The carob rod manufacturing process and respective carob rod recipes are manufactured according to the process described in the present invention which is shown in Figure 1.
As 4 receitas de barras que possuem características sensoriais, fisico-quimicas e nutricionais únicas e foram desenvolvidas de acordo com 10 características, deram origem ao processo de fabrico de barra de alfarroba e respetivas 4 receitas das barras de alfarroba descritas na presente invenção. The 4 bar recipes that unique sensory, physicochemical and nutritional characteristics and were developed according to 10 characteristics, gave rise to the carob rod manufacturing process and respective carob rod recipes described in the present invention.
Para além da escolha criteriosa dos 8 a 11 ingredientes ou matérias-primas que constituem a composição das respetivas receitas das 4 barras, no processo de fabrico de barra de alfarroba, todos os equipamentos, temperaturas, tempos e humidades de cada uma das 6 etapas foram também alvo de uma escolha/ seleção criteriosa de forma a cada uma das 4 receitas de barras apresentem características sensoriais, fisico-quimicas e nutricionais únicas . In addition to the judicious choice of 8 to 11 ingredients or raw materials that make up the respective recipes of the four bars, in the process of carob bar production, all equipment, temperatures, times and humidities of each of the 6 steps were also selectively selected so that each of the four bar recipes has unique sensory, physico-chemical and nutritional characteristics.
Processo de fabrico de barra de alfarroba Process of carob bar production
O processo de fabrico de barra de alfarroba compreende sequencialmente as seguintes 9 etapas:  The carob rod manufacturing process sequentially comprises the following 9 steps:
Ia etapa - pesagem das matérias-primas; I to step - weighing of raw materials;
2a etapa - mistura das matérias-primas; Step 2 - mixing the raw materials;
3a etapa - moagem de matérias-primas; 3 step - grinding of raw materials;
4a etapa - conchagem da mistura; 4 the step - conching the mixture;
5a etapa - têmpera da mistura; Step 5 - hardening the mixture;
6a etapa - moldagem do produto; Step 6 - shaping the product;
7 a etapa - arrefecimento da barra de alfarroba; Step 7 - cooling the carob bar;
8a etapa - desmoldagem da barra de alfarroba; e 8 step - stripping carob bar; and
9 a etapa - embalamento e armazenagem. Step 9 - packaging and storage.
Na Ia etapa são pesados cada um dos cerca de 8 a 11 ingredientes ou matérias-primas que constituem cada uma das respetivas 4 receitas de barras de alfarroba. Na 2 a etapa vai ocorrer a mistura de gorduras vegetais, nas seguintes quantidades: In step I are weighed each of about 8-11 ingredients or raw materials that constitute each of the respective four recipes carob bars. In the second step will take place the mixture of vegetable fats in the following amounts:
33,30-43,85% de gordura vegetal de palma; e  33.30-43.85% palm vegetable fat; and
1,20-5,00% de gordura vegetal de coco.  1.20-5.00% coconut fat.
Simultaneamente na já referida 2a etapa, também vai ocorrer a pré-mistura de pós, nas seguintes quantidades : Simultaneously in the said second step, it will also occur to the premix powder of the following quantities:
10,00-35,00% de alfarroba; e  10.00-35.00% carob; and
0,01-0,04% de edulcorante;  0.01-0.04% sweetener;
30, 65-45, 60%de fibra alimentar do tipo maltodextrina; 0,00-20,25% de leite magro em pó;  30, 65-45, 60% maltodextrin-like dietary fiber; 0.00-20.25% skim milk powder;
0,18-0,50% de emulsionante;  0.18-0.50% emulsifier;
0,26-0,50% de lecitina de soja; e  0.26-0.50% soy lecithin; and
0,00-15,00% de pedaços de amêndoa torrada com pele.  0.00-15.00% pieces of toasted almonds with skin.
Estas citadas gorduras e pós são misturadas no moinho durante a 3a etapa. These aforementioned powders and fats are mixed in the mill during the third step.
Na 3a etapa vai ocorrer a moagem das matérias- primas, durante 2 a 12 horas, a uma temperatura entre 30 a 70°c e até ser obtida uma granulometria dos ingredientes com um tamanho das partículas entre 10 a 30 m. In the third step will occur grinding of raw materials, for 2 to 12 hours at a temperature between 30 to 70 ° C and a particle size to be obtained of the ingredients with a particle size of from 10 to 30 m.
Na 4a etapa, ocorre a conchagem da mistura de gorduras e pós obtida na etapa anterior, durante 6 a 24 horas e a uma temperatura entre 30 a 70 °C para obter o sabor desejado, garantindo que o produto quando consumido seja percecionado como homogéneo e tenha boas propriedades reológicas . In the fourth step, there is the conching the mixture of fat and powders obtained in the previous step, for 6 to 24 hours at a temperature between 30 to 70 ° C to obtain the desired flavor, ensuring that the product when consumed are percecionado as homogeneous and has good rheological properties.
De seguida na 5a, a têmpera da mistura é realizada por meio de uma temperadora, durante 1 a 4 horas e a uma temperatura entre 25 a 50 °C. Then in the 5th, hardening of the mixture is performed by means of a temperadora for 1 to 4 hours and at a temperature between 25 and 50 ° C.
O processo de têmpera do produto de base em óleo de palma e alfarroba, afeta significativamente as suas propriedades físicas e sensoriais da mistura. The quenching process of the base product in palm oil and locust beans significantly affects its physical and sensory properties of the blend.
0 processo foi estudado e afinado para controlar a temperatura, tempo de cristalização e velocidade de agitação . The process was studied and fine tuned to control the temperature, crystallization time and stirring speed.
A temperatura da têmpera varia para cada tipo de receita a produzir, com leite e sem leite, e respetivamente varia entre os 25 e os 50°C. The temperature of the quench varies for each type of recipe to be produced, with milk and without milk, and respectively varies between 25 and 50 ° C.
Na 6a etapa é realizada a moldagem da massa através de um molde que irá originar a forma da barra de alfarroba . In the step 6 is carried out at the molding mass through a die which will give the shape of the carob bar.
Após a moldagem, na 7 a etapa ocorre o arrefecimento dos moldes, num túnel de arrefecimento, durante 0,2 a 1 hora, a uma temperatura entre 5 a 18°C e com uma humidade relativa entre 30 a 60% de humidade relativa . After molding, in step 7, the molds are cooled in a cooling tunnel for 0.2 to 1 hour, at a temperature between 5 to 18 ° C and a relative humidity of 30 to 60% relative humidity.
Na penúltima etapa - a 8a etapa - irá ser realizada a desmoldagem da barra de alfarroba. In the penultimate stage - the eighth step - will be held demoulding carob bar.
Na 9a etapa, e última, vai ser realizado o embalamento e armazenagem. In step 9, and lastly, the packaging and storage will be performed.
O processo de embalamento das barras tem um papel fundamental na conservação e proteção do alimento durante o transporte e distribuição. 0 embalamento é efetuado numa flow pack que envolve a barra com um filme BOPP. The bar packaging process plays a key role in the preservation and protection of food during transportation and distribution. The packaging is effected in a flow pack that surrounds the bar with a BOPP film.
De seguida, numa encartonadora, que coloca a barra numa caixa de cartão, que permite manter as propriedades organoléticas, características nutricionais e prolongar o seu tempo de vida útil. Then, in a cartoner, which places the bar in a carton, which allows to maintain the organoleptic properties, nutritional characteristics and prolong its life time.
Estes processos e métodos de produção e embalagem foram estudados e permitem a melhor eficiência, afinação dos produtos e respetiva conservação. These processes and methods of production and packaging have been studied and allow the best efficiency, product tuning and its conservation.
Barra de alfarroba Carob bar
A barra de alfarroba é fabricada de acordo com o processo de fabrico de barra de alfarroba anteriormente descrito .  Locust bean bar is manufactured in accordance with the locust bean bar manufacturing process previously described.
A nível dos ingredientes ou matérias-primas a barra de alfarroba descrita na presente invenção compreende os seguintes ingredientes: At the level of the ingredients or raw materials the locust bean bar described in the present invention comprises the following ingredients:
33,30-43,85% de gordura vegetal de palma;  33.30-43.85% palm vegetable fat;
1,20-5,00% de gordura vegetal de coco;  1.20-5.00% coconut fat;
10,00-35,00% de alfarroba;  10.00-35.00% carob;
0,01-0,04% de edulcorante;  0.01-0.04% sweetener;
30,65-45,60% de fibra alimentar do tipo maltodextrina;  30.65-45.60% maltodextrin dietary fiber;
0,00-20,25% de leite magro em pó;  0.00-20.25% skim milk powder;
0,18-0,50% de emulsionante;  0.18-0.50% emulsifier;
0,26-0,50% de lecitina de soja; e  0.26-0.50% soy lecithin; and
0,00-15,00% de pedaços de amêndoa torrada com pele.  0.00-15.00% pieces of toasted almonds with skin.
Formas de realização preferencial da presente invenção Preferred embodiments of the present invention
As formas de realização preferencial da presente invenção estão relacionadas com os ingredientes ou matérias-primas utilizadas em cada uma das respetivas 4 receitas de barras de alfarroba: Preferred embodiments of the present invention invention are related to the ingredients or raw materials used in each of the respective 4 carob rod recipes:
- barra de alfarroba com leite e com amêndoas;  - bar of carob with milk and with almonds;
- barra de alfarroba sem leite e sem amêndoas;  - bar of carob without milk and without almonds;
- barra de alfarroba com leite e sem amêndoas; e  - bar of carob with milk and without almonds; and
- barra de alfarroba sem leite e com amêndoas.  - bar of carob without milk and with almonds.
A barra de alfarroba compreende entre 9 a 7 ingredientes : The carob tree bar consists of 9 to 7 ingredients:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30, 65-45, 60%de fibra alimentar do tipo maltodextrina; - 30, 65-45, 60% maltodextrin type food fiber;
- 0,00-20,25% de leite magro em pó; - 0.00-20.25% skimmed milk powder;
- 0,18-0,50% de emulsionante;  - 0.18-0.50% emulsifier;
- 0,26-0,50% de lecitina de soja; e  - 0.26-0.50% soy lecithin; and
- 0,00-15,00% de pedaços de amêndoa torrada com pele.  - 0.00-15.00% pieces of toasted almonds with skin.
Conforme se pode verificar as grandes diferenças entre as 4 citadas receitas barra de alfarroba, é com ou sem leite e com ou sem amêndoas. As can be seen the great differences between the 4 mentioned carob bar recipes, it is with or without milk and with or without almonds.
A barra de alfarroba, sem leite e sem amêndoas compreende os seguintes ingredientes: Carob bar, without milk and without almonds, comprises the following ingredients:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30, 65-45, 60%de fibra alimentar do tipo maltodextrina; - 30, 65-45, 60% maltodextrin type food fiber;
- 0,18-0,50% de emulsionante; e - 0.18-0.50% emulsifier; and
- 0,26-0,50% de lecitina de soja. A barra de alfarroba, sem leite e sem amêndoas é das referidas 4 receitas a que compreende o menor número de ingredientes, num total de 7. - 0.26-0.50% soy lecithin. The bar of carob, without milk and without almonds is said 4 recipes which comprises the fewest ingredients, a total of 7.
A barra de alfarroba, com leite e com amêndoas compreende os seguintes ingredientes: The carob bar, with milk and with almonds comprises the following ingredients:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30, 65-45, 60%de fibra alimentar do tipo maltodextrina; - 30, 65-45, 60% maltodextrin type food fiber;
- 5,00-20,25% de leite magro em pó; - 5,00-20,25% of skim milk powder;
- 0,18-0,50% de emulsionante;  - 0.18-0.50% emulsifier;
- 0,26-0,50% de lecitina de soja; e  - 0.26-0.50% soy lecithin; and
- 0,00-15,00% de pedaços de amêndoa torrada com pele.  - 0.00-15.00% pieces of toasted almonds with skin.
A barra de alfarroba, com leite e com amêndoas é das referidas 4 receitas a que compreende o maior número de ingredientes, num total de 9. The bar of carob, with milk and with almonds is said 4 recipes which comprises the largest number of ingredients, a total of 9.
A barra de alfarroba, sem leite e com amêndoas compreende os seguintes ingredientes: The carob bar, without milk and with almonds, comprises the following ingredients:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30, 65-45, 60%de fibra alimentar do tipo maltodextrina; - 30, 65-45, 60% maltodextrin type food fiber;
- 0,18-0,50% de emulsionante; - 0.18-0.50% emulsifier;
- 0,26-0,50% de lecitina de soja; e  - 0.26-0.50% soy lecithin; and
- 5,00-15,00% de pedaços de amêndoa torrada com pele.  - 5,00-15,00% pieces of toasted almonds with skin.
A barra de alfarroba, com leite e sem amêndoas compreende os seguintes ingredientes: - 33,30-43,85% de gordura vegetal de palma; Carob bar, with milk and without almonds comprises the following ingredients: - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30, 65-45, 60%de fibra alimentar do tipo maltodextrina; - 30, 65-45, 60% maltodextrin type food fiber;
- 5,00-20,25% de leite magro em pó; - 5,00-20,25% of skim milk powder;
- 0,18-0,50% de emulsionante; e  - 0.18-0.50% emulsifier; and
- 0,26-0,50% de lecitina de soja.  - 0.26-0.50% soy lecithin.
A presente invenção deve apenas ser limitada pelo espirito das reivindicações que se seguem. The present invention should only be limited by the spirit of the following claims.
Faro, 6 de Setembro de 2017 Faro, September 6, 2017

Claims

- 1 - REIVINDICAÇÕES In the first aspect,
1. Processo de fabrico de barra de alfarroba caracterizado por compreender sequencialmente 9 etapas : Ia etapa Process for the production of carob tree bar comprising sequentially comprising 9 steps: I to step
pesagem das matérias-primas  weighing of raw materials
2 a etapa 2 a step
mistura de gorduras, de  mixture of fats,
- 33,30-43,85% de gordura vegetal de palma; e  - 33.30-43.85% of vegetable shortening of palm; and
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
num moinho, durante 0,25 a 1 hora e a uma temperatura ente 30 e 70°C;  in a mill, for 0.25 to 1 hour and at a temperature between 30 and 70 ° C;
e and
pré-mistura de pós, de  pre-mix of powders,
- 10,00-35,00% de alfarroba; e  - 10.00-35.00% carob; and
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30,65-45,60% de fibra alimentar do tipo maltodextrina;  - 30.65-45.60% maltodextrin dietary fiber;
- 0,00-20,25% de leite magro em pó;  - 0.00-20.25% skimmed milk powder;
- 0,18-0,50% de emulsionante;  - 0.18-0.50% emulsifier;
- 0,26-0,50% de lecitina de soja; e  - 0.26-0.50% soy lecithin; and
- 0,00-15,00% de pedaços de amêndoa torrada com pele; num moinho, durante 0,25 a 1 hora e a uma temperatura entre 30 a 70°C;  - 0.00-15.00% pieces of toasted almonds with skin; in a mill, for from 0.25 to 1 hour and at a temperature between 30 and 70 ° C;
3a etapa 3 a step
mistura de gorduras e de pós, num moinho durante 2 a 12 horas, a uma temperatura entre 30 a 70aC e até ser obtida uma granulometria com um tamanho das partículas entre 10 a 30μπι; mixing fat and powders, in a mill for 2 to 12 hours at a temperature between 30 C and 70 to be obtained to a particle size with a particle size between 10 and 30μπι;
4a etapa 4 a step
conchagem da mistura de gorduras e de pós obtida na etapa anterior durante 6 a 24 horas e a uma temperatura - 2 - entre 30 a 70°C the mixture of fats and powders obtained in the previous step for 6 to 24 hours and at a temperature - between 30 and 70 ° C
5a etapa 5 a step
têmpera da mistura de gorduras e de pós, obtidas nas 2 etapas antecedentes, na temperadora, durante 1 a 4 horas e a uma temperatura entre 25 a 50 °C  quenching of the mixture of fats and powders obtained in the foregoing 2 stages in the temperadora for 1 to 4 hours and at a temperature between 25 to 50 ° C
6a etapa Step 6
moldagem da mistura de gorduras e de pós através de um molde  molding the mixture of fats and powders through a mold
7a etapa Step 7
arrefecimento da barra de alfarroba, num túnel de arrefecimento durante 0,10 a 0,50 horas, a uma temperatura entre 5 a 18°c e com uma humidade relativa entre 30 a 60% de humidade relativa  cooling the carob rod in a cooling tunnel for 0.10 to 0.50 hours, at a temperature between 5 to 18 ° C and with a relative humidity between 30 to 60% relative humidity
8a etapa Step 8
desmoldagem da barra de alfarroba  carob bar demoulding
9a etapa Step 9
embalamento e armazenagem.  packaging and storage.
2. Barra de alfarroba, fabricada de acordo com o processo de fabrico de barra de alfarroba descrito na reivindicação anterior caracterizado por a barra de alfarroba compreender: Carob rod, made according to the carob rod manufacturing process described in the preceding claim, characterized in that the carob rod comprises:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30, 65-45, 60%de fibra alimentar do tipo maltodextrina; - 30, 65-45, 60% maltodextrin type food fiber;
- 0,00-20,25% de leite magro em pó; - 0.00-20.25% skimmed milk powder;
- 0,18-0,50% de emulsionante;  - 0.18-0.50% emulsifier;
- 0,26-0,50% de lecitina de soja; e  - 0.26-0.50% soy lecithin; and
- 0,00-15,00% de pedaços de amêndoa torrada com pele.  - 0.00-15.00% pieces of toasted almonds with skin.
3. Barra de alfarroba de acordo com a - 3 - reivindicação anterior caracterizado por a barra de alfarroba compreender: 3. Carob bar according to Characterized in that the locust bean bar comprises:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30,65-45,60% fibra alimentar do tipo maltodextrina; - 30.65-45.60% maltodextrin type food fiber;
- 5,00-20,25% de leite magro em pó; - 5,00-20,25% of skim milk powder;
- 0,18-0,50% de emulsionante; e  - 0.18-0.50% emulsifier; and
- 0,26-0,50% de lecitina de soja.  - 0.26-0.50% soy lecithin.
4. Barra de alfarroba de acordo com a reivindicação n.°2 caracterizado por a barra de alfarroba compreender : Carob bar according to claim 2, characterized in that the locust bean bar comprises:
-33,30-43,85% de gordura vegetal de palma;  -33.30-43.85% of vegetable shortening of palm;
-1,20-5,00% de gordura vegetal de coco;  -1.20-5.00% coconut fat;
-10,00-35,00% de alfarroba;  -10.00-35.00% carob;
-0,01-0,04% de edulcorante;  -0.01-0.04% sweetener;
-30,65-45,60% fibra alimentar do tipo maltodextrina; -0,18-0,50% de emulsionante; e  -30.65-45.60% maltodextrin type food fiber; -0.18-0.50% emulsifier; and
-0,26-0,50% de lecitina de soja.  -0.26-0.50% soy lecithin.
5. Barra de alfarroba de acordo com a reivindicação n.°2, caracterizado por barra de alfarroba compreender : Carob bar according to claim 2, characterized in that carob rod comprises:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30,65-45,60% fibra alimentar do tipo maltodextrina; - 30.65-45.60% maltodextrin type food fiber;
- 5,00-20,25% de leite magro em pó; - 5,00-20,25% of skim milk powder;
- 0,18-0,50% de emulsionante;  - 0.18-0.50% emulsifier;
- 0,26-0,50% de lecitina de soja; e - 4 - - 0.26-0.50% soy lecithin; and - 4 -
- 5,00-15,00% de pedaços de amêndoa torrada com pele. - 5,00-15,00% pieces of toasted almonds with skin.
6. Barra de alfarroba acordo com a reivindicação n.° 2, caracterizado por barra de alfarroba, compreender : Carob bar according to claim 2, characterized by carob rod, comprising:
- 33,30-43,85% de gordura vegetal de palma;  - 33.30-43.85% of vegetable shortening of palm;
- 1,20-5,00% de gordura vegetal de coco;  - 1.20-5.00% coconut fat;
- 10,00-35,00% de alfarroba;  - 10.00-35.00% carob;
- 0,01-0,04% de edulcorante;  - 0.01-0.04% sweetener;
- 30,65-45,60% fibra alimentar do tipo maltodextrina; - 30.65-45.60% maltodextrin type food fiber;
- 0,18-0,50% de emulsionante; - 0.18-0.50% emulsifier;
- 0,26-0,50% de lecitina de soja; e  - 0.26-0.50% soy lecithin; and
- 5,00-15,00% de pedaços de amêndoa torrada com pele. Faro, 16 de Outubro de 2017  - 5,00-15,00% pieces of toasted almonds with skin. Faro, October 16, 2017
PCT/PT2018/050040 2017-10-16 2018-10-16 Process for producing a carob bar WO2019078750A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PT11035317A PT110353A (en) 2017-10-16 2017-10-16 ALFARROBA BAR MANUFACTURING PROCESS.
PT110353 2017-10-16

Publications (1)

Publication Number Publication Date
WO2019078750A1 true WO2019078750A1 (en) 2019-04-25

Family

ID=64500423

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/PT2018/050040 WO2019078750A1 (en) 2017-10-16 2018-10-16 Process for producing a carob bar

Country Status (2)

Country Link
PT (1) PT110353A (en)
WO (1) WO2019078750A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023285547A1 (en) * 2021-07-14 2023-01-19 Nxfoods Gmbh Flavor composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1958522A2 (en) * 2005-11-30 2008-08-20 La Morella Nuts, S.A. Functional food having positive effects in the prevention of cardiovascular diseases
WO2016022082A1 (en) * 2014-08-06 2016-02-11 Gökaltay Nükhet Hayriye Nutrient food composition
CA2996385A1 (en) * 2015-08-21 2017-03-02 Luiz CARMINE GIUNTI DE OLIVEIRA Formulation of chocolate with carob and low caffeine and theobromine content, no added sugar, dairy free, gluten free, soy free, and with or without fibers
EP3175716A1 (en) * 2015-12-04 2017-06-07 Emilia Rosario Rotulo Montiani Food bars comprising carob powder
WO2017096448A1 (en) * 2015-12-07 2017-06-15 Oliveira Luiz Carmine Giunti De Optimised alternative chocolate formulation made from carob beam, milk-free, with or without added sugar, gluten-free, soy-free and with or without fibres

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1958522A2 (en) * 2005-11-30 2008-08-20 La Morella Nuts, S.A. Functional food having positive effects in the prevention of cardiovascular diseases
WO2016022082A1 (en) * 2014-08-06 2016-02-11 Gökaltay Nükhet Hayriye Nutrient food composition
CA2996385A1 (en) * 2015-08-21 2017-03-02 Luiz CARMINE GIUNTI DE OLIVEIRA Formulation of chocolate with carob and low caffeine and theobromine content, no added sugar, dairy free, gluten free, soy free, and with or without fibers
EP3175716A1 (en) * 2015-12-04 2017-06-07 Emilia Rosario Rotulo Montiani Food bars comprising carob powder
WO2017096448A1 (en) * 2015-12-07 2017-06-15 Oliveira Luiz Carmine Giunti De Optimised alternative chocolate formulation made from carob beam, milk-free, with or without added sugar, gluten-free, soy-free and with or without fibres

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ANONYMOUS: "carob and Cashew Nut Bar", GNPD, MINTEL, 1 May 2014 (2014-05-01), XP002766830 *
ANONYMOUS: "Carob and Raisins Bar", GNPD, MINTEL, 1 April 2013 (2013-04-01), XP002766832 *
DATABASE GNPD [online] MINTEL; 15 September 2017 (2017-09-15), ANONYMOUS: "Carob Bar", XP055549324, retrieved from www.gnpd.com Database accession no. 5093119 *
DATABASE GNPD [online] MINTEL; 9 September 2016 (2016-09-09), ANONYMOUS: "Organic Carob Bar", XP055549318, retrieved from www.gnpd.com Database accession no. 4276487 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023285547A1 (en) * 2021-07-14 2023-01-19 Nxfoods Gmbh Flavor composition

Also Published As

Publication number Publication date
PT110353A (en) 2019-04-16

Similar Documents

Publication Publication Date Title
KR102339379B1 (en) Sweet food product made from dry fruit
KR20120064215A (en) Herbal cookie and method of manufacturing the same
CN104642707A (en) Ice-cream and preparation method thereof
KR20140115087A (en) Smoothie cube ice cream and manufacturing method thereof
JP2014209925A (en) Fiber-rich gelato composition with low carbohydrate content and high protein content, and manufacturing method thereof
RU2294109C1 (en) Method for cover production
WO2019078750A1 (en) Process for producing a carob bar
KR20170092956A (en) Chocolate containing extract of aronia and black raspberry and manufacturing method thereof
RU2555445C1 (en) Marshmallow production method
US20070286934A1 (en) Frozen confections and method of manufacturing same
WO2019078749A1 (en) Process for producing a carob cream spread
RU2410893C2 (en) Three-layered candies production method
Kot et al. Study of the properties of vegan ice cream based on almond drink
Bochkarev et al. Development and research candies with increased biological value with protein-fat composite
RU2323583C1 (en) Composition for praline production
KR101787578B1 (en) Icecream comprising green tea, rubus coreanus, blueberry, acaberry, bamboo leaf and mulberries leaf and manufacturing method thereof
RU2800603C1 (en) Chocolate manufacturing method
KR20160057691A (en) Vegetable ice cream comprising cocoa butter and coconut oil and method of preparing the same
CA2691400A1 (en) Frozen confections and method of manufacturing same
ES1223824U (en) FOOD PRODUCT BASED ON COCOA WITHOUT ADDED SUGARS OR SWEETENERS (Machine-translation by Google Translate, not legally binding)
RU2163449C1 (en) Sweets
RU2763051C1 (en) Method for making lollipop
RU2521505C1 (en) Confectionery goods
Das et al. Chemistry and Different Aspects of Ice Cream
RU2757598C1 (en) Frozen dessert product

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18811079

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 18811079

Country of ref document: EP

Kind code of ref document: A1