WO2019059029A1 - Woven fabric - Google Patents

Woven fabric Download PDF

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Publication number
WO2019059029A1
WO2019059029A1 PCT/JP2018/033504 JP2018033504W WO2019059029A1 WO 2019059029 A1 WO2019059029 A1 WO 2019059029A1 JP 2018033504 W JP2018033504 W JP 2018033504W WO 2019059029 A1 WO2019059029 A1 WO 2019059029A1
Authority
WO
WIPO (PCT)
Prior art keywords
yarn
woven fabric
mixed
yarns
metallic
Prior art date
Application number
PCT/JP2018/033504
Other languages
French (fr)
Japanese (ja)
Inventor
多田 秀行
勝好 藤間
Original Assignee
セーレン株式会社
理研電線株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by セーレン株式会社, 理研電線株式会社 filed Critical セーレン株式会社
Priority to KR1020207003176A priority Critical patent/KR102543050B1/en
Priority to CN201880051142.7A priority patent/CN111032937B/en
Publication of WO2019059029A1 publication Critical patent/WO2019059029A1/en

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/25Metal
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/12Threads containing metallic filaments or strips
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/38Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/449Yarns or threads with antibacterial properties
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/41Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific twist
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/44Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with specific cross-section or surface shape
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/593Stiff materials, e.g. cane or slat
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/60Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the warp or weft elements other than yarns or threads
    • D03D15/67Metal wires
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial

Definitions

  • the present invention relates to a woven fabric having antibacterial properties.
  • woven fabrics that are easy to touch the skin are required to have the property of preventing and suppressing bacterial growth.
  • a woven fabric a woven fabric in which a non-metallic yarn composed of natural fibers, synthetic fibers and the like and a metal yarn are combined has been proposed.
  • Patent Document 1 discloses a functional fabric using copper fiber yarn in whole or in part.
  • Patent Document 2 discloses a conductive fabric sewn fabric in which yarns and copper fibers, which are formed by interlacing several linear aluminum foils with a core yarn, are alternately woven at predetermined intervals.
  • Patent Document 3 discloses a woven fabric woven using a mixed yarn formed by twisting together a copper-containing wire containing at least copper and a spinnable fiber.
  • the present invention is a woven fabric comprising a mixed yarn and a first non-metallic yarn intersecting the mixed yarn, wherein the mixed yarn comprises a second non-metallic yarn and a metal yarn, and the mixed yarn and the first non-metallic yarn Ratio of diameter to yarn: mixed yarn / first non-metallic yarn is 1 or more, and the number of mixed yarns contained in a predetermined area of the woven fabric is 3 of the number of all yarns contained in the predetermined area. Relating to the woven fabric which is 5 to 30%.
  • Such a woven fabric is lightweight and has a good feel while having excellent antibacterial properties.
  • the mixed yarn may be a covering yarn obtained by winding a metal yarn around a second non-metallic yarn, or a composite yarn formed by twisting together a second non-metallic yarn and a metal yarn. This can further improve the antimicrobial properties.
  • the woven fabric of the present embodiment includes a mixed yarn and a first non-metallic yarn that intersects the mixed yarn.
  • the mixed yarn comprises a second non-metallic yarn and a metallic yarn.
  • Ratio of diameter of mixed yarn to first non-metallic yarn: mixed yarn / first non-metallic yarn is 1 or more. Further, the number of mixed yarns contained in a predetermined area of the woven fabric is 3.5 to 30% of the number of all yarns contained in the predetermined area.
  • the number of mixed yarns included in the woven fabric is in a specific range, and the ratio of the diameter of the mixed yarn to the first non-metallic yarn intersecting therewith is in a specific range In this way, a large amount of the mixed yarn can be exposed to at least one main surface of the woven fabric while reducing the content of the mixed yarn.
  • the obtained woven fabric has a good feel, is lightweight, and has excellent antibacterial properties.
  • the woven fabric is formed by weaving at least a first non-metallic yarn and a mixed yarn using a loom.
  • the mixed yarn may be contained in both the weft and the warp, may be contained only in the weft, and may be contained only in the warp.
  • one of the warp yarn and the weft yarn can be formed of only the mixed yarn.
  • the number of mixed yarns contained in a predetermined region (hereinafter, region R) of the woven fabric is 3.5 to 30% of the number of all yarns contained in the region R.
  • region R The number of mixed yarns contained in a predetermined region of the woven fabric is lightweight and flexible. It is also excellent in economics.
  • the number ratio of the mixed yarn may be 5% or more, or 7% or more.
  • the number ratio of the mixed yarn may be 25% or less, or 20% or less. All yarns include mixed yarns, first non-metallic yarns and third non-metallic yarns described below.
  • the predetermined area is an area including at least one mixed yarn when looking at one main surface of the woven fabric, for example, an area surrounded by a square having a side of 2 cm.
  • the number of yarns included in the region R can be calculated, for example, by counting the number of yarns visible from both main surfaces of the woven fabric so as not to overlap in a region surrounded by a square having a side of 2 cm. .
  • a single yarn is a unit containing one or more fibers which can be introduced as a warp or weft into a weaving machine and used for weaving.
  • fibers constituting the yarn include spun yarn and filament yarn.
  • one twisted yarn including one or more second non-metallic yarns and one or more metal yarns is one yarn.
  • the area of the mixed yarn on at least one of the main surfaces may be 5% or more, or 10% or more of the area of the woven fabric, 13 It may be% or more. Even when the area ratio of the mixed yarn is such small, high antibacterial properties can be easily obtained.
  • the area ratio of the mixed yarn is 100% or less, may be 80% or less, and may be 50% or less.
  • the area ratio of the mixed yarn can be determined by photographing the woven fabric from the normal direction of one main surface using a microscope (for example, Digital HF microscope VH-8000 manufactured by Keyence Corporation). For example, at different places, one main surface of the woven fabric is photographed at three locations, and within each photographed field of view, it contains at least one mixed yarn and is surrounded by a rectangle of 2.3 cm in length and 3.1 cm in width. Select each area. In the three selected regions, the area of the mixed yarn is divided by the area of the region to calculate the area ratio of the mixed yarn. The average value of these is taken as the area ratio of the mixed yarn.
  • a microscope for example, Digital HF microscope VH-8000 manufactured by Keyence Corporation.
  • the warp yarns of the woven fabric may include mixed yarns and non-metallic yarns (third non-metallic yarns) disposed along the mixed yarns.
  • Weft yarns may also include mixed yarns and third non-metallic yarns.
  • the mixed yarns may be equally spaced or irregularly spaced.
  • the mixed yarns are preferably arranged at equal intervals. In this case, the obtained woven fabric exhibits sufficient antibacterial performance while being flexible.
  • the density of the mixed yarn is not particularly limited.
  • the density of the mixed yarn may be constant throughout the woven fabric, or may partially change the density of the mixed yarn.
  • the ratio of the number of mixed yarn to third nonmetallic yarn may be 1: 2 to 1: 8, or may be 1: 2 to 1: 4.
  • the woven fabric is lightweight and flexible.
  • the distance between adjacent mixed yarns may be 3600 ⁇ m or less, 3000 ⁇ m or less, or 2000 ⁇ m or less. When the distance between the mixed yarns is in this range, the obtained antibacterial effect is high.
  • the distance between the mixed yarns is the width of the gap formed between the adjacent mixed yarns. The width is the length in the direction perpendicular to the longitudinal direction of the mixed yarn.
  • the thickness of the woven fabric is not particularly limited, but may be 70 to 1500 ⁇ m, 110 to 1000 ⁇ m, or 250 to 750 ⁇ m. According to this embodiment, it is possible to produce a lightweight and extremely thin woven fabric as compared to the conventional woven fabric containing metal yarn.
  • the thickness of the woven fabric can be measured, for example, using a thickness measuring instrument (PEACOCK G-6, manufactured by Ozaki Mfg. Co., Ltd.).
  • the woven fabric of this embodiment includes the first non-metallic yarn, the second non-metallic yarn and the metal yarn in the woven fabric, and the type, amount, diameter, type, arrangement, etc. of the third non-metallic yarn used as needed.
  • the method for producing the woven fabric of the present embodiment is not particularly limited, and the woven fabric can be produced by weaving with a loom in the same manner as an ordinary woven fabric.
  • a loom conventionally known looms can be used.
  • shuttle type looms rapier type looms, air jet type looms, needle type looms, water jet type looms, gripper type looms, jacquard type looms, etc.
  • shuttle type looms for example, shuttle type looms, rapier type looms, air jet type looms, needle type looms, water jet type looms, gripper type looms, jacquard type looms, etc.
  • the woven texture of the woven fabric is not particularly limited, and it is not limited, and is a three-dimensional structure such as plain weave, twilled weave, and satin weave, a deformed structure of three-dimensional weave, a special tissue such as satin weave, tangled tissue, dobby tissue, jacquard tissue, double Organization, multiple organizations, etc. can be mentioned.
  • a satin weave is preferred, and a 5-sheet satin weave is more preferred.
  • bacteria to be subjected to the antibacterial treatment of the woven fabric of the present embodiment include Staphylococcus aureus and Klebsiella pneumoniae.
  • the first non-metallic yarn is not particularly limited, and may be a yarn obtained from conventionally known fibers such as natural fibers, regenerated fibers, semi-synthetic fibers and synthetic fibers. Such fibers are substantially free of metals. These fibers may be used alone or in combination of two or more. Among them, synthetic fibers may be used because of excellent durability, and polyester fibers may be used. There are many types of polyester fibers, and it is easy to select one suitable for woven applications. Therefore, it is easy to apply the woven fabric to various uses.
  • polyester fiber is less likely to change its feel even when pre-dyed (yarn-dyed). Therefore, post-processing by which a film can be formed on the surface of a metal thread can be omitted, and the antibacterial performance by the metal thread can be sufficiently exhibited.
  • a conventionally well-known form such as a spun yarn (short fiber yarn), a multifilament yarn, and a monofilament yarn (long fiber yarn), can be mentioned.
  • monofilament yarns and multifilament yarns may be used from the viewpoint of quality, and in particular, multifilament yarns may be used from the viewpoint of texture.
  • the cross-sectional shape of the first non-metallic yarn (fiber) is also not particularly limited. It may be circular, or may be a so-called non-circular shaped cross-section yarn.
  • the diameter of the first non-metallic thread may be 24 to 644 ⁇ m, and may be 64 to 203 ⁇ m.
  • the diameter of the first non-metallic yarn is 24 ⁇ m or more, yarn breakage hardly occurs. Moreover, there is no need to increase the weave density, and the cost can be reduced.
  • the diameter of the first non-metallic yarn is 644 ⁇ m or less, the obtained woven fabric is unlikely to be coarse-hardened and the feeling is hardly impaired.
  • the diameter of the first non-metallic yarn can be determined, for example, by photographing the woven fabric from the normal direction of one of the main surfaces using a microscope as described above. For example, at different locations, one main surface of the woven fabric is photographed at three locations, and the length in the direction perpendicular to the longitudinal direction of the first non-metallic yarn in each of the photographed fields is at any three points. Measure and average these values as the diameter of the first nonmetallic thread.
  • the diameter of the mixed yarn is also the same.
  • the fineness (total fineness) of the first non-metallic yarn is 6 to 4500 dtex, and 45 to 450 dtex.
  • the fineness is a value representing the thickness of a fiber defined by JIS L 0101-1978 (Tex method), and is a value measured based on JIS L 1013-1999 B method.
  • the first non-metallic yarn may be subjected to conventionally known treatments such as water absorption, water repellency, various treatments such as deodorization, and dyeing.
  • the mixed yarn comprises a second non-metallic yarn and a metallic yarn.
  • the mixed yarn is preferably a covering yarn obtained by winding a metal yarn around a second non-metal yarn, or a composite yarn formed by twisting together a second non-metal yarn and a metal yarn.
  • two yarns are aligned and twisted to be one yarn.
  • the mixed yarn is formed by winding a metal yarn around the second non-metallic yarn.
  • One mixed yarn includes one or more second non-metallic yarns and one or more metal yarns.
  • the number of turns of the metal thread on the second non-metal thread may be 1.1 to 3 turns / cm. If the number of turns is 1.1 times / cm or more, desired antibacterial properties are easily obtained. In addition, if the number of turns is 3 times / cm or less, the mixed yarn itself is also light and excellent in economy. Furthermore, the woven fabric obtained using the mixed yarn is unlikely to be coarse and hard.
  • the mixed yarn is formed by twisting the second non-metallic yarn and the metal yarn.
  • One mixed yarn includes one or more second non-metallic yarns and one or more metal yarns.
  • the number of times of twisting of the plied yarn may be 0.5 to 20 times / cm, or may be 3 to 6 times / cm. If the number of twists is 0.5 times / cm or more, desired antibacterial properties can be easily obtained. In addition, when the number of twists is 20 times / cm or less, the mixed yarn itself is also light and excellent in economy. Furthermore, the woven fabric obtained using the mixed yarn is unlikely to be coarse and hard.
  • the direction of twisting of covering yarns and double-twisted yarns may be either Z twist or S twist.
  • the antimicrobial properties and texture of the resulting woven fabric are the same even if the direction of twist is different. Therefore, the direction of twisting may be appropriately determined in consideration of the ear wrap at the time of weaving.
  • the diameter of the mixed yarn may be 44 to 744 ⁇ m, or may be 64 to 344 ⁇ m.
  • the diameter of the mixed yarn is 44 ⁇ m or more, yarn breakage hardly occurs. Moreover, it is not necessary to increase the weave density, and it is economically excellent.
  • the diameter of the mixed yarn is 744 ⁇ m or less, the obtained woven fabric is unlikely to be coarse-hard, and the feeling is also less likely to be lost.
  • Ratio of diameter of mixed yarn to first non-metallic yarn mixed yarn / first non-metallic yarn is 1 or more. Diameter ratio: When the mixed yarn / first non-metallic yarn is 1 or more, the mixed yarn (metal yarn) exposed to the surface of the woven fabric is increased, and the antibacterial property of the obtained woven fabric is increased. Ratio: mixed yarn / first non-metallic yarn may be 1.2 or more, or 2 or more. The upper limit of the ratio: mixed yarn / first non-metallic yarn is not particularly limited, and may be 35, 20, or 10, for example.
  • Metal thread A linear metal is used as the metal thread.
  • the metal thread can be produced, for example, by drawing metal processed into a rod shape through a die having a desired diameter and stretching it under heating or at ordinary temperature.
  • metals such as copper, silver, zinc, are mentioned.
  • copper alloys in which zinc, silver, nickel and the like are singly or in combination with copper may also be mentioned.
  • metal threads containing copper as a main component (which occupies 50% by mass or more) may be used.
  • a soft copper wire (JIS C3102) for electricity, a hard copper wire, and an oxygen free copper (JIS H3100, C1020) are mentioned.
  • a hard copper wire may be used from the viewpoint of antibacterial properties and economy, and oxygen-free copper may be used from the viewpoint of antibacterial properties.
  • the metal yarn that constitutes the mixed yarn is not limited to one type, and may be two or more types.
  • the diameter of the metal thread is not particularly limited, and may be 20 to 100 ⁇ m, 30 to 50 ⁇ m, or 40 to 50 ⁇ m. When the diameter of the metal thread is 20 ⁇ m or more, thread breakage hardly occurs, and desired antibacterial properties can be obtained. When the diameter of the metal yarn is 100 ⁇ m or less, a lightweight woven fabric is easily obtained. In addition, the obtained woven fabric is unlikely to be coarse and hard.
  • the non metallic thread As a 2nd non metallic thread which constitutes mixed yarn, the non metallic thread similar to the above-mentioned 1st non metallic thread can be used, and it is chosen suitably according to the property for which textiles are required.
  • the first non-metallic yarn and the second non-metallic yarn may be the same or different.
  • the second non-metallic yarn constituting the mixed yarn is not limited to one type, and may be two or more types.
  • Ratio of diameter of metal yarn to second non-metallic yarn The metal yarn / second non-metallic yarn is not particularly limited. Ratio: metal yarn / second non-metal yarn is, for example, 0.2 or more and 1 or less.
  • the non metallic thread As a 3rd non metallic thread which may be arranged along mixed yarn, the non metallic thread similar to the above-mentioned 1st non metallic thread can be used, and it is chosen suitably according to the property required for textiles.
  • the first non-metallic yarn and the third non-metallic yarn may be the same or different.
  • the second non-metallic yarn and the third non-metallic yarn may be the same or different.
  • the third non-metallic yarn may be of one type or of two or more types.
  • Ratio of diameter of mixed yarn and third non-metallic yarn mixed yarn / third non-metallic yarn is not particularly limited.
  • Mated yarn B A hard copper wire (metal thread, 40 ⁇ m in diameter) made of oxygen-free copper on polyester yarn (second nonmetal thread, 124 ⁇ m in diameter, fineness of 167 dtex / 48f), S twisting direction, 2.5 times of twisting times It covered as / cm and produced mixed yarn B (diameter 164 micrometers).
  • Mated yarn C A hard copper wire (metal thread, 50 ⁇ m in diameter) made of oxygen-free copper on polyester yarn (second nonmetal thread, 124 ⁇ m in diameter, fineness of 167 dtex / 48f), S twisting direction, 2.5 times of twisting times It covered as / cm and produced mixed yarn C (diameter 174 micrometers).
  • Example 1 ⁇ Production of woven fabric> Weaving the prepared mixed yarn A, polyester yarn A (first non-metallic yarn, diameter 72 ⁇ m, fineness 56 dtex / 25 f), and polyester yarn B (third non-metallic yarn 174 m in diameter, fineness 330 dtex / 288 f) A plain weave woven fabric was made. As shown in Table 1, the warp yarn is polyester yarn A. The weft yarn is polyester yarn B and mixed yarn A. In the weft yarn, the ratio of the number of mixed yarn A to polyester yarn B is 1: 2.
  • the number of mixed yarns A contained in a predetermined region R (a region surrounded by a square of 2 cm on a side) of the woven fabric is 11.9% of the total number of warps and wefts contained in the region R,
  • the yarns A were arranged at equal intervals.
  • the distance between adjacent mixed yarns A was 1154 ⁇ m.
  • the area of the mixed yarn A was 15.6% of the area of the woven fabric on both sides of the woven fabric.
  • the thickness of the woven fabric was 293 ⁇ m.
  • test cloth (0.40 g ⁇ 0.05 g) was cut out from the produced woven fabric and evaluated in accordance with JIS L1902-2015 (bacterial fluid absorption method).
  • Staphylococcus aureus (Staphylococcus aureus NBRC 12732) was used as a test species, and 100% cotton white cloth was used as a standard cloth.
  • the test bacteria solution was inoculated on a test cloth and a standard cloth, and the measurement value of the number of viable bacteria immediately after inoculation of the test bacteria solution and after 18 hours of culture was obtained. Then, the bacteriostatic activity value S and the bactericidal activity value L were calculated based on the following formula.
  • Example 2 A woven fabric was produced in the same manner as in Example 1 except that the ratio of the number of mixed yarn A to polyester yarn B in the weft was changed to 1: 4.
  • the number of mixed yarns A contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was set to 7.1% of the total number of warp yarns and wefts contained in the region R.
  • the distance between adjacent mixed yarns A was 1865 ⁇ m.
  • the area of the mixed yarn A was 16.6% of the area of the woven fabric on both sides of the woven fabric.
  • the thickness of the woven fabric was 279 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • Example 3 A woven fabric was produced in the same manner as in Example 1 except that the ratio of the number of mixed yarn A to polyester yarn B in the weft was changed to 1: 6.
  • the number of mixed yarns A included in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was made to be 5.1% of the total number of warps and wefts included in the region R.
  • the distance between adjacent mixed yarns A was 2649 ⁇ m.
  • the area of the mixed yarn A was 6.2% of the area of the woven fabric on both sides of the woven fabric.
  • the thickness of the woven fabric was 274 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • Example 4 A woven fabric was produced in the same manner as in Example 1 except that the ratio of the number of mixed yarn A to polyester yarn B in the weft was changed to 1: 8.
  • the number of mixed yarns A contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was set to be 3.9% of the total number of warps and wefts contained in the region R.
  • the distance between adjacent mixed yarns A was 3424 ⁇ m.
  • the area of the mixed yarn A was 7.4% of the area of the woven fabric on both sides of the woven fabric.
  • the thickness of the woven fabric was 267 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • Example 5 A woven fabric was produced in the same manner as in Example 1 except that the mixed yarn A was changed to the mixed yarn B.
  • the number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on a side) of the woven fabric was 11.9% of the total number of warps and wefts contained in the region R.
  • the distance between adjacent mixed yarns B was 1121.9 ⁇ m.
  • the area of the mixed yarn B was 15.1% of the area of the woven fabric on both sides of the woven fabric. There was a gap between adjacent mixed yarn B and polyester yarn B.
  • the thickness of the woven fabric was 305 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • Example 6 A woven fabric was produced in the same manner as in Example 2 except that mixed yarn A was changed to mixed yarn B.
  • the number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was 7.1% of the total number of warps and wefts contained in the region R.
  • the distance between adjacent mixed yarns B was 1640.6 ⁇ m.
  • the area of the mixed yarn B was 16.3% of the area of the woven fabric on both sides of the woven fabric.
  • the thickness of the woven fabric was 291 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • Example 7 A woven fabric was produced in the same manner as in Example 3, except that the mixed yarn A was changed to the mixed yarn B.
  • the number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was made to be 5.1% of the total number of warps and wefts contained in the region R.
  • the distance between adjacent mixed yarns B was 3430.4 ⁇ m.
  • the area of the mixed yarn B was 6.4% of the area of the woven fabric on both sides of the woven fabric.
  • the thickness of the woven fabric was 284 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • Example 8 A woven fabric was produced in the same manner as in Example 4 except that mixed yarn A was changed to mixed yarn B.
  • the number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was made to be 3.9% of the total number of warps and wefts contained in the region R.
  • the distance between adjacent mixed yarns B was 3579.8 ⁇ m.
  • the area of the mixed yarn B was 7.2% of the area of the woven fabric on both sides of the woven fabric.
  • the thickness of the woven fabric was 278 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • Example 9 Weaving mixed yarn C, polyester yarn C (first nonmetal yarn, diameter 124 ⁇ m, fineness 167 dtex / 48f), and polyester yarn D (third nonmetal yarn, diameter 124 ⁇ m, fineness 167 dtex / 48f), and satin A woven woven fabric was made. As shown in Table 1, warp yarns were mixed yarn C and polyester yarn C, weft yarns were polyester yarn D, and the ratio of the number of mixed yarn C to polyester yarn C in the warp yarns was 1: 4.
  • the number of mixed yarns C contained in a predetermined region R (a region surrounded by a square of 5 cm on a side) of the woven fabric is 14.2% of the total number of warps and wefts contained in the region R,
  • the yarns C were arranged at equal intervals on the warp yarns.
  • the weave density (design density) was 150 / 2.54 cm and 60 // 2.54 cm.
  • the mixed yarns C were arranged to be in contact with each other (interval: 0 ⁇ m), and the area of the mixed yarn C occupied 100% of the area of the main surfaces.
  • the area of the mixed yarn C was 7.1% of the area of the main surface.
  • the thickness of the woven fabric was 275 ⁇ m.
  • the evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
  • the obtained woven fabric was washed 5 times, and the antibacterial property and the feeling to Staphylococcus aureus and Klebsiella pneumonia were evaluated for the woven fabric before laundering and the woven fabric after laundering.
  • the washing method was according to the washing method (standard washing method) of the SEK mark textile product specified by the Fiber Evaluation Technology Council.
  • the antibacterial property was evaluated in the same manner as the antibacterial property test of (1), and Staphylococcus aureus (Staphylococcus aureus NBRC 12732) and Klebsiella pneumoniae NBRC 13277 were used as test bacterial species.
  • the evaluation results are shown in Table 3.
  • the woven fabrics obtained in Examples 1 to 9 are thin. Furthermore, it can be seen from Table 2 and Table 3 that these woven fabrics exhibit high antibacterial properties and are also excellent in terms of feel. Further, as can be seen from Example 9, the woven fabric according to the present embodiment does not have reduced antimicrobial properties even by washing.
  • the woven fabric of the present invention includes sheets, pillow covers, linen products such as towels, pajamas, white coats, aprons, hats, uniforms, various clothing articles such as uniforms, seat sheets such as car seats, chairs, strollers and the like It can be widely used for seat covers, bags, shoes, curtains, tents, sleeping bags, place mats, interior seats for refrigerators and the like.

Abstract

This woven fabric includes: a mixed yarn; and a first nonmetal yarn that intersects the mixed yarn, wherein the mixed yarn includes a second nonmetal yarn and a metal yarn, the diameter ratio of the mixed yarn to the first nonmetal yarn (mixed yarn/first nonmetal yarn) is 1 or higher, and the number of mixed yarns included in a prescribed region of the woven fabric is 3.5-30% of the number of all yarns included in the prescribed region. The mixed yarn can be a covering yarn formed by winding the metal yarn on the second nonmetal yarn or a twisted yarn formed by twisting the second nonmetal yarn and the metal yarn together.

Description

織布Woven cloth
 本発明は、抗菌性を有する織布に関する。 The present invention relates to a woven fabric having antibacterial properties.
 近年、肌に触れやすい織布には、細菌の増殖を阻止および抑制する性質が求められている。このような織布として、天然繊維や合成繊維などから構成される非金属糸と金属糸とを組み合わせた織布が提案されている。 In recent years, woven fabrics that are easy to touch the skin are required to have the property of preventing and suppressing bacterial growth. As such a woven fabric, a woven fabric in which a non-metallic yarn composed of natural fibers, synthetic fibers and the like and a metal yarn are combined has been proposed.
 特許文献1には、全部または一部に銅繊維糸を用いた機能性生地が開示されている。特許文献2には、数条の線状アルミニウム箔を芯糸に交絡させて形成した撚り糸と銅繊維とを、所定の間隔に交互に織り込んだ導電性繊維縫製生地が開示されている。特許文献3には、少なくとも銅を含む銅含有線と可紡性繊維とが撚り合わされて形成された混合糸を用いて織られた織布が開示されている。 Patent Document 1 discloses a functional fabric using copper fiber yarn in whole or in part. Patent Document 2 discloses a conductive fabric sewn fabric in which yarns and copper fibers, which are formed by interlacing several linear aluminum foils with a core yarn, are alternately woven at predetermined intervals. Patent Document 3 discloses a woven fabric woven using a mixed yarn formed by twisting together a copper-containing wire containing at least copper and a spinnable fiber.
特開2004-149945号公報JP 2004-149945 A 特開2005-206987号公報JP 2005-206987 A 特開2012-153994号公報JP, 2012-153994, A
 抗菌性を高めるためには、金属糸の線径を大きくしたり、非金属糸に対する金属糸の撚り回数を多くした混合糸を使用したりするなどして、金属糸の割合を大きくすればよい。しかし、この方法では、抗菌性が高くなる一方で、生地が粗硬になり風合が劣る。 In order to enhance the antibacterial property, it is sufficient to increase the ratio of metal yarns by, for example, increasing the wire diameter of metal yarns or using a mixed yarn in which the number of times of twisting of metal yarns to nonmetal yarns is increased. . However, in this method, while the antibacterial property is high, the dough becomes coarse and hard to feel.
 また、近年、抗菌性に優れ、軽量な織布の開発が望まれている。軽量化のために金属糸と非金属糸とを含む混合糸を細くすると、抗菌性が低下したり、混合糸中の非金属糸が湾曲して外観が不良になったりするなどの問題があった。 Moreover, in recent years, development of lightweight and excellent in antibacterial properties is desired. When the mixed yarn containing metal yarns and nonmetal yarns is made thinner for weight reduction, there are problems such as deterioration of antibacterial property and curving of nonmetal yarn in the mixed yarn and appearance defect The
 本発明は、混合糸と、混合糸と交わる第1非金属糸と、を含む織布であって、混合糸が、第2非金属糸と金属糸とを含み、混合糸と第1非金属糸との直径の比:混合糸/第1非金属糸が1以上であり、織布の所定の領域に含まれる混合糸の本数が、上記所定の領域に含まれるすべての糸の本数の3.5~30%である織布に関する。
 このような織布は、優れた抗菌性を備えながら、軽量で風合がよい。
The present invention is a woven fabric comprising a mixed yarn and a first non-metallic yarn intersecting the mixed yarn, wherein the mixed yarn comprises a second non-metallic yarn and a metal yarn, and the mixed yarn and the first non-metallic yarn Ratio of diameter to yarn: mixed yarn / first non-metallic yarn is 1 or more, and the number of mixed yarns contained in a predetermined area of the woven fabric is 3 of the number of all yarns contained in the predetermined area. Relating to the woven fabric which is 5 to 30%.
Such a woven fabric is lightweight and has a good feel while having excellent antibacterial properties.
 混合糸は、第2非金属糸に金属糸を巻き付けたカバリング糸、あるいは、第2非金属糸および金属糸を撚り合わせて形成される合撚糸であってもよい。これにより、抗菌性をさらに向上させることができる。 The mixed yarn may be a covering yarn obtained by winding a metal yarn around a second non-metallic yarn, or a composite yarn formed by twisting together a second non-metallic yarn and a metal yarn. This can further improve the antimicrobial properties.
 本発明によれば、抗菌性に優れ、かつ、風合がよく、軽量な織布を得ることができる。 According to the present invention, it is possible to obtain a lightweight woven fabric which is excellent in antibacterial properties and has a good feeling.
 本実施形態の織布は、混合糸と、混合糸と交わる第1非金属糸とを含む。混合糸は、第2非金属糸と、金属糸とを含む。混合糸と第1非金属糸との直径の比:混合糸/第1非金属糸は1以上である。さらに、織布の所定の領域に含まれる混合糸の本数は、上記所定の領域に含まれるすべての糸の本数の3.5~30%である。 The woven fabric of the present embodiment includes a mixed yarn and a first non-metallic yarn that intersects the mixed yarn. The mixed yarn comprises a second non-metallic yarn and a metallic yarn. Ratio of diameter of mixed yarn to first non-metallic yarn: mixed yarn / first non-metallic yarn is 1 or more. Further, the number of mixed yarns contained in a predetermined area of the woven fabric is 3.5 to 30% of the number of all yarns contained in the predetermined area.
 本発明の実施形態に係る織布によれば、織布に含まれる混合糸の本数を特定の範囲にするとともに、混合糸とこれと交わる第1非金属糸との直径の比を特定の範囲にすることにより、混合糸の含有量を少なくしながら、織布の少なくとも一方の主面に多く露出させることができる。よって、得られる織布は、風合がよく、軽量であるとともに、優れた抗菌性を有する。 According to the woven fabric according to the embodiment of the present invention, the number of mixed yarns included in the woven fabric is in a specific range, and the ratio of the diameter of the mixed yarn to the first non-metallic yarn intersecting therewith is in a specific range In this way, a large amount of the mixed yarn can be exposed to at least one main surface of the woven fabric while reducing the content of the mixed yarn. Thus, the obtained woven fabric has a good feel, is lightweight, and has excellent antibacterial properties.
[織布]
 織布は、織機を用いて、少なくとも第1非金属糸および混合糸を織り込むことにより形成される。混合糸は、緯糸および経糸の両方に含まれていてもよく、緯糸のみに含まれていてもよく、経糸のみに含まれていてもよい。また、経糸および緯糸の一方を、混合糸のみで形成することもできる。
[Woven cloth]
The woven fabric is formed by weaving at least a first non-metallic yarn and a mixed yarn using a loom. The mixed yarn may be contained in both the weft and the warp, may be contained only in the weft, and may be contained only in the warp. In addition, one of the warp yarn and the weft yarn can be formed of only the mixed yarn.
 織布の所定の領域(以下、領域R)に含まれる混合糸の本数は、当該領域Rに含まれるすべての糸の本数の3.5~30%とする。混合糸の本数が上記範囲のとき、織布は軽量であり、柔軟である。また経済性にも優れる。混合糸の本数割合は、5%以上であってもよく、7%以上であってもよい。混合糸の本数割合は、25%以下であってもよく、20%以下であってもよい。すべての糸には、混合糸、第1非金属糸および後述する第3非金属糸が含まれる。 The number of mixed yarns contained in a predetermined region (hereinafter, region R) of the woven fabric is 3.5 to 30% of the number of all yarns contained in the region R. When the number of mixed yarns is in the above range, the woven fabric is lightweight and flexible. It is also excellent in economics. The number ratio of the mixed yarn may be 5% or more, or 7% or more. The number ratio of the mixed yarn may be 25% or less, or 20% or less. All yarns include mixed yarns, first non-metallic yarns and third non-metallic yarns described below.
 所定の領域とは、織布の一方の主面を見たとき、少なくとも1本の混合糸が含まれており、例えば一辺が2cmの正方形によって囲まれた領域である。領域Rに含まれる糸の本数は、例えば、一辺が2cmの正方形によって囲まれた領域において、織布の両方の主面から見える糸の本数を、重複しないように数えることで算出することができる。 The predetermined area is an area including at least one mixed yarn when looking at one main surface of the woven fabric, for example, an area surrounded by a square having a side of 2 cm. The number of yarns included in the region R can be calculated, for example, by counting the number of yarns visible from both main surfaces of the woven fabric so as not to overlap in a region surrounded by a square having a side of 2 cm. .
 ここで、1本の糸とは、単独で、経糸または緯糸として織機に導入されて製織に用いられ得る、1以上の繊維を含む単位である。糸を構成する繊維としては、紡績糸やフィラメント糸などが挙げられる。ただし、混合糸の場合、1本以上の第2非金属糸と1本以上の金属糸とを含む1本の撚糸が、1本の糸である。 Here, a single yarn is a unit containing one or more fibers which can be introduced as a warp or weft into a weaving machine and used for weaving. Examples of fibers constituting the yarn include spun yarn and filament yarn. However, in the case of mixed yarn, one twisted yarn including one or more second non-metallic yarns and one or more metal yarns is one yarn.
 織布を主面の法線方向から見たとき、少なくとも一方の主面における混合糸の面積は、織布の面積の5%以上であってもよく、10%以上であってもよく、13%以上であってもよい。混合糸の面積割合がこのように小さい場合であっても、高い抗菌性が得られやすくなる。混合糸の面積割合は、100%以下であり、80%以下であってもよく、50%以下であってもよい。 When the woven fabric is viewed in the normal direction of the main surface, the area of the mixed yarn on at least one of the main surfaces may be 5% or more, or 10% or more of the area of the woven fabric, 13 It may be% or more. Even when the area ratio of the mixed yarn is such small, high antibacterial properties can be easily obtained. The area ratio of the mixed yarn is 100% or less, may be 80% or less, and may be 50% or less.
 混合糸の面積割合は、マイクロスコープ(例えば、キーエンス株式会社製、デジタルHFマイクロスコープVH-8000)を用いて、織布を一方の主面の法線方向から撮影することにより求められる。例えば、場所を変えて、織布の一方の主面を3箇所撮影し、撮影された各視野内から、混合糸を少なくとも1本含み、タテ2.3cm、ヨコ3.1cmの長方形によって囲まれた領域をそれぞれ選出する。選出された3つの領域において、混合糸の面積を当該領域の面積で除して、混合糸の面積割合を算出する。これらの平均値を混合糸の面積割合とする。 The area ratio of the mixed yarn can be determined by photographing the woven fabric from the normal direction of one main surface using a microscope (for example, Digital HF microscope VH-8000 manufactured by Keyence Corporation). For example, at different places, one main surface of the woven fabric is photographed at three locations, and within each photographed field of view, it contains at least one mixed yarn and is surrounded by a rectangle of 2.3 cm in length and 3.1 cm in width. Select each area. In the three selected regions, the area of the mixed yarn is divided by the area of the region to calculate the area ratio of the mixed yarn. The average value of these is taken as the area ratio of the mixed yarn.
 織布の経糸は、混合糸および混合糸に沿って配置される非金属糸(第3非金属糸)を含んでもよい。緯糸も同様に、混合糸および第3非金属糸を含んでもよい。経糸および/または緯糸が、混合糸と第3非金属糸とを含む場合、混合糸は、等間隔に配置されてもよいし、変則的な間隔で配置されてもよい。なかでも、混合糸は、等間隔で配置されることが好ましい。この場合、得られる織布は、柔軟でありながら、十分な抗菌性能を発揮する。 The warp yarns of the woven fabric may include mixed yarns and non-metallic yarns (third non-metallic yarns) disposed along the mixed yarns. Weft yarns may also include mixed yarns and third non-metallic yarns. When the warp yarns and / or weft yarns include the mixed yarn and the third non-metallic yarn, the mixed yarns may be equally spaced or irregularly spaced. Above all, the mixed yarns are preferably arranged at equal intervals. In this case, the obtained woven fabric exhibits sufficient antibacterial performance while being flexible.
 上記の場合、混合糸の密度は特に制限されない。混合糸の密度は、織布全体にわたって一定であってもよいし、部分的に混合糸の密度を変化させてもよい。なかでも、混合糸は、「第3非金属糸8本に対して混合糸1本」以上の割合で、均等に配置されることが好ましい。これは、例えば、混合糸が緯糸に含まれる場合、混合糸の本数に対して、緯糸を構成する第3非金属糸の本数が、8倍以下であることを意味する。混合糸と第3非金属糸との本数の比は、1:2~1:8であってもよく、1:2~1:4であってもよい。混合糸と第3非金属糸との本数の比が上記範囲であるとき、織布は軽量であり、柔軟である。 In the above case, the density of the mixed yarn is not particularly limited. The density of the mixed yarn may be constant throughout the woven fabric, or may partially change the density of the mixed yarn. Among them, it is preferable that the mixed yarns be uniformly disposed at a ratio of “one mixed yarn to eight third non-metallic yarns” or more. This means that, for example, when the mixed yarn is included in the weft, the number of third non-metallic yarns constituting the weft is eight or less times the number of mixed yarn. The ratio of the number of mixed yarn to third nonmetallic yarn may be 1: 2 to 1: 8, or may be 1: 2 to 1: 4. When the ratio of the number of mixed yarn to the number of third nonmetallic yarns is in the above range, the woven fabric is lightweight and flexible.
 隣り合う混合糸同士の間隔は、3600μm以下であってもよく、3000μm以下であってもよく、2000μm以下であってもよい。混合糸同士の間隔がこの範囲のとき、得られる抗菌効果が高くなる。混合糸同士の間隔とは、隣り合う混合糸の間に形成される隙間の幅である。幅とは、混合糸の長手方向に垂直な方向における長さである。 The distance between adjacent mixed yarns may be 3600 μm or less, 3000 μm or less, or 2000 μm or less. When the distance between the mixed yarns is in this range, the obtained antibacterial effect is high. The distance between the mixed yarns is the width of the gap formed between the adjacent mixed yarns. The width is the length in the direction perpendicular to the longitudinal direction of the mixed yarn.
 織布の厚さは、特に限定されないが、70~1500μmであってもよく、110~1000μmであってもよく、250~750μmであってもよい。本実施形態によれば、従来の金属糸を含有する織布に比べて、軽量で極薄の織布を作製することが可能となる。なお、織布の厚さは、例えば、厚み測定器(株式会社尾崎製作所製、PEACOCK G-6)を用いて測定することができる。 The thickness of the woven fabric is not particularly limited, but may be 70 to 1500 μm, 110 to 1000 μm, or 250 to 750 μm. According to this embodiment, it is possible to produce a lightweight and extremely thin woven fabric as compared to the conventional woven fabric containing metal yarn. The thickness of the woven fabric can be measured, for example, using a thickness measuring instrument (PEACOCK G-6, manufactured by Ozaki Mfg. Co., Ltd.).
 本実施形態の織布は、織布中の第1非金属糸、第2非金属糸および金属糸、さらに必要に応じて用いられる第3非金属糸の種類、量、直径、種類、配置などの設計の自由度が高く、所望の用途、抗菌性などに応じた様々な織布を得ることができる。 The woven fabric of this embodiment includes the first non-metallic yarn, the second non-metallic yarn and the metal yarn in the woven fabric, and the type, amount, diameter, type, arrangement, etc. of the third non-metallic yarn used as needed. There is a high degree of freedom in designing, and various woven fabrics can be obtained according to the desired application, antibacterial properties and the like.
 本実施形態の織布の作製方法は特に限定されるものでなく、通常の織物と同様に織機で織ることにより作製することができる。織機としては、従来公知の織機を用いることができ、例えば、シャトル式織機、レピア式織機、エアージェット式織機、ニードル式織機、ウォータージェット式織機、グリッパー式織機、ジャカード式織機などを用いることができる。 The method for producing the woven fabric of the present embodiment is not particularly limited, and the woven fabric can be produced by weaving with a loom in the same manner as an ordinary woven fabric. As the loom, conventionally known looms can be used. For example, shuttle type looms, rapier type looms, air jet type looms, needle type looms, water jet type looms, gripper type looms, jacquard type looms, etc. Can.
 織布の織物組織は、特に限定されるものでなく、平織、綾織、朱子織といった三原組織、三原組織の変形組織、梨地織などの特別組織、からみ組織、ドビー組織、ジャカード組織、二重組織、多重組織などが挙げられる。なかでも風合の観点から、朱子織が好ましく、さらには5枚朱子織が好ましい。 The woven texture of the woven fabric is not particularly limited, and it is not limited, and is a three-dimensional structure such as plain weave, twilled weave, and satin weave, a deformed structure of three-dimensional weave, a special tissue such as satin weave, tangled tissue, dobby tissue, jacquard tissue, double Organization, multiple organizations, etc. can be mentioned. Among them, from the viewpoint of feeling, a satin weave is preferred, and a 5-sheet satin weave is more preferred.
 本実施形態の織布の抗菌の対象となる菌としては、黄色ブドウ球菌、肺炎桿菌などが挙げられる。 Examples of bacteria to be subjected to the antibacterial treatment of the woven fabric of the present embodiment include Staphylococcus aureus and Klebsiella pneumoniae.
(第1非金属糸)
 第1非金属糸としては、特に限定されるものでなく、天然繊維、再生繊維、半合成繊維、合成繊維などの従来公知の繊維から得られる糸を挙げることができる。このような繊維は、実質的に金属を含有しない。これらの繊維は、単独で用いてもよく、2種以上組み合わせて用いてもよい。なかでも、耐久性に優れるという理由から、合成繊維であってもよく、特にポリエステル繊維であってもよい。ポリエステル繊維は種類が多く、織布の用途に適したものを選択しやすい。そのため、織布を様々な用途に適用し易い。また、ポリエステル繊維から形成される糸を含む織布は、染色、撥水加工、撥油加工、抗菌加工、防臭加工、難燃加工、UVカット加工などの後加工も施しやすい。さらに、ポリエステル繊維は、先染め(糸染め)しても風合が変わりにくい。そのため、金属糸表面に皮膜が形成され得る後加工を省略することができて、金属糸による抗菌性能が十分に発揮されやすくなる。
(First non-metallic thread)
The first non-metallic yarn is not particularly limited, and may be a yarn obtained from conventionally known fibers such as natural fibers, regenerated fibers, semi-synthetic fibers and synthetic fibers. Such fibers are substantially free of metals. These fibers may be used alone or in combination of two or more. Among them, synthetic fibers may be used because of excellent durability, and polyester fibers may be used. There are many types of polyester fibers, and it is easy to select one suitable for woven applications. Therefore, it is easy to apply the woven fabric to various uses. In addition, woven fabrics including yarns formed of polyester fibers are easily subjected to post-processing such as dyeing, water-repellent processing, oil-repellent processing, antibacterial processing, deodorizing processing, flame-retardant processing, UV cutting processing, and the like. Furthermore, polyester fiber is less likely to change its feel even when pre-dyed (yarn-dyed). Therefore, post-processing by which a film can be formed on the surface of a metal thread can be omitted, and the antibacterial performance by the metal thread can be sufficiently exhibited.
 第1非金属糸の形態としては、特に限定されるものでなく、紡績糸(短繊維糸)、マルチフィラメント糸およびモノフィラメント糸(長繊維糸)など、従来公知の形態を挙げることができる。なかでも、品位の観点から、モノフィラメント糸およびマルチフィラメント糸であってもよく、特に風合の観点から、マルチフィラメント糸であってもよい。また、第1非金属糸(繊維)の断面形状も特に限定されない。円形であってもよいし、円形以外のいわゆる異形断面糸であってもよい。 It does not specifically limit as a form of a 1st non metallic thread, A conventionally well-known form, such as a spun yarn (short fiber yarn), a multifilament yarn, and a monofilament yarn (long fiber yarn), can be mentioned. Among them, monofilament yarns and multifilament yarns may be used from the viewpoint of quality, and in particular, multifilament yarns may be used from the viewpoint of texture. Moreover, the cross-sectional shape of the first non-metallic yarn (fiber) is also not particularly limited. It may be circular, or may be a so-called non-circular shaped cross-section yarn.
 第1非金属糸の直径は、24~644μmであってもよく、64~203μmであってもよい。第1非金属糸の直径が24μm以上であると、糸切れが発生しにくい。また、織密度を高くする必要がなく、コストが抑えられる。第1非金属糸の直径が644μm以下であると、得られる織布が粗硬になりにくく、風合が損なわれにくい。 The diameter of the first non-metallic thread may be 24 to 644 μm, and may be 64 to 203 μm. When the diameter of the first non-metallic yarn is 24 μm or more, yarn breakage hardly occurs. Moreover, there is no need to increase the weave density, and the cost can be reduced. When the diameter of the first non-metallic yarn is 644 μm or less, the obtained woven fabric is unlikely to be coarse-hardened and the feeling is hardly impaired.
 第1非金属糸の直径は、例えば、上記のようにマイクロスコープを用いて、織布を一方の主面の法線方向から撮影することにより求められる。例えば、場所を変えて、織布の一方の主面を3箇所撮影し、撮影された各視野内における第1非金属糸の長手方向に垂直な方向の長さを、それぞれ任意の3点で測定し、これらの平均値を第1非金属糸の直径とする。混合糸の直径も同様である。 The diameter of the first non-metallic yarn can be determined, for example, by photographing the woven fabric from the normal direction of one of the main surfaces using a microscope as described above. For example, at different locations, one main surface of the woven fabric is photographed at three locations, and the length in the direction perpendicular to the longitudinal direction of the first non-metallic yarn in each of the photographed fields is at any three points. Measure and average these values as the diameter of the first nonmetallic thread. The diameter of the mixed yarn is also the same.
 上記の場合、第1非金属糸の繊度(総繊度)は、6~4500dtexであり、45~450dtexである。繊度は、JIS L 0101-1978(テックス方式)により規定される繊維の太さを表す値であり、JIS L 1013-1999 B法に基づいて測定した値である。 In the above case, the fineness (total fineness) of the first non-metallic yarn is 6 to 4500 dtex, and 45 to 450 dtex. The fineness is a value representing the thickness of a fiber defined by JIS L 0101-1978 (Tex method), and is a value measured based on JIS L 1013-1999 B method.
 第1非金属糸には、吸水、撥水、消臭などの各種加工、染色などの従来公知の処理を施してもよい。 The first non-metallic yarn may be subjected to conventionally known treatments such as water absorption, water repellency, various treatments such as deodorization, and dyeing.
(混合糸)
 混合糸は、第2非金属糸と、金属糸とを含む。具体的には、混合糸は、第2非金属糸に金属糸を巻き付けたカバリング糸、または第2非金属糸および金属糸を撚り合わせて形成される合撚糸であることが好ましい。なお、本明細書において、2本の糸を引き揃えるとともに撚りをかけて、1本の糸にすることを合撚するという。
(Mixed yarn)
The mixed yarn comprises a second non-metallic yarn and a metallic yarn. Specifically, the mixed yarn is preferably a covering yarn obtained by winding a metal yarn around a second non-metal yarn, or a composite yarn formed by twisting together a second non-metal yarn and a metal yarn. In the present specification, two yarns are aligned and twisted to be one yarn.
 混合糸がカバリング糸である場合、混合糸は、第2非金属糸のまわりに金属糸が巻き付けられることにより形成される。1本の混合糸には、1本以上の第2非金属糸、および、1本以上の金属糸が含まれる。金属糸の第2非金属糸への巻き回数は、1.1~3回/cmであってもよい。巻き回数が1.1回/cm以上であると、所望の抗菌性が得られやすい。また、巻き回数が3回/cm以下であれば、混合糸自体も軽量となり、経済性にも優れる。さらに、混合糸を用いて得られる織布が粗硬になりにくい。 When the mixed yarn is a covering yarn, the mixed yarn is formed by winding a metal yarn around the second non-metallic yarn. One mixed yarn includes one or more second non-metallic yarns and one or more metal yarns. The number of turns of the metal thread on the second non-metal thread may be 1.1 to 3 turns / cm. If the number of turns is 1.1 times / cm or more, desired antibacterial properties are easily obtained. In addition, if the number of turns is 3 times / cm or less, the mixed yarn itself is also light and excellent in economy. Furthermore, the woven fabric obtained using the mixed yarn is unlikely to be coarse and hard.
 混合糸が合撚糸である場合、混合糸は、第2非金属糸および金属糸を撚り合わせて形成される。1本の混合糸には、1本以上の第2非金属糸、および、1本以上の金属糸が含まれる。合撚糸の撚り回数は、0.5~20回/cmであってもよく、3~6回/cmであってもよい。撚り回数が0.5回/cm以上であると、所望の抗菌性が得られやすい。また、撚り回数が20回/cm以下であると、混合糸自体も軽量となり、経済性にも優れる。さらに、混合糸を用いて得られる織布が粗硬になりにくい。 When the mixed yarn is a plied yarn, the mixed yarn is formed by twisting the second non-metallic yarn and the metal yarn. One mixed yarn includes one or more second non-metallic yarns and one or more metal yarns. The number of times of twisting of the plied yarn may be 0.5 to 20 times / cm, or may be 3 to 6 times / cm. If the number of twists is 0.5 times / cm or more, desired antibacterial properties can be easily obtained. In addition, when the number of twists is 20 times / cm or less, the mixed yarn itself is also light and excellent in economy. Furthermore, the woven fabric obtained using the mixed yarn is unlikely to be coarse and hard.
 カバリング糸および合撚糸の撚りの方向は、Z撚りおよびS撚りのいずれであってもよい。撚りの方向が異なっていても、得られる織布の抗菌性および風合は同じである。そのため、撚りの方向は、製織の際の耳巻きを考慮して適宜決定されればよい。 The direction of twisting of covering yarns and double-twisted yarns may be either Z twist or S twist. The antimicrobial properties and texture of the resulting woven fabric are the same even if the direction of twist is different. Therefore, the direction of twisting may be appropriately determined in consideration of the ear wrap at the time of weaving.
 混合糸の直径は、44~744μmであってもよく、64~344μmであってもよい。混合糸の直径が44μm以上であると、糸切れが発生しにくい。また、織密度を高くする必要がなく、経済的にも優れる。混合糸の直径が744μm以下であると、得られる織布が粗硬になりにくく、風合も損なわれにくい。 The diameter of the mixed yarn may be 44 to 744 μm, or may be 64 to 344 μm. When the diameter of the mixed yarn is 44 μm or more, yarn breakage hardly occurs. Moreover, it is not necessary to increase the weave density, and it is economically excellent. When the diameter of the mixed yarn is 744 μm or less, the obtained woven fabric is unlikely to be coarse-hard, and the feeling is also less likely to be lost.
 混合糸と第1非金属糸との直径の比:混合糸/第1非金属糸は1以上である。直径の比:混合糸/第1非金属糸が1以上であると、織布の表面に露出する混合糸(金属糸)が多くなるため、得られる織布の抗菌性が高くなる。比:混合糸/第1非金属糸は、1.2以上であってもよく、2以上であってもよい。比:混合糸/第1非金属糸の上限は特に限定されないが、例えば、35であってもよいし、20であってもよいし、10であってもよい。 Ratio of diameter of mixed yarn to first non-metallic yarn: mixed yarn / first non-metallic yarn is 1 or more. Diameter ratio: When the mixed yarn / first non-metallic yarn is 1 or more, the mixed yarn (metal yarn) exposed to the surface of the woven fabric is increased, and the antibacterial property of the obtained woven fabric is increased. Ratio: mixed yarn / first non-metallic yarn may be 1.2 or more, or 2 or more. The upper limit of the ratio: mixed yarn / first non-metallic yarn is not particularly limited, and may be 35, 20, or 10, for example.
(金属糸)
 金属糸としては、線状の金属が用いられる。
 金属糸は、例えば、棒状に加工された金属を、所望の直径を有するダイスに通して、加熱下または常温で伸長させることにより作製することができる。金属糸の材質としては、銅、銀、亜鉛などの金属が挙げられる。また、銅に、亜鉛や銀、ニッケルなどを、単独または複数組み合わせた銅合金も挙げられる。なかでも抗菌性の観点から、銅を主成分(50質量%以上を占める)とする金属糸であってもよい。銅を主成分とする金属糸としては、電気用軟銅線(JIS C3102)、硬銅線、無酸素銅(JIS H3100、C1020)が挙げられる。なかでも、抗菌性および経済性の観点から硬銅線であってもよく、抗菌性の観点から無酸素銅であってもよい。混合糸を構成する金属糸は、1種に限定されず、2種以上であってもよい。
(Metal thread)
A linear metal is used as the metal thread.
The metal thread can be produced, for example, by drawing metal processed into a rod shape through a die having a desired diameter and stretching it under heating or at ordinary temperature. As a material of a metal thread, metals, such as copper, silver, zinc, are mentioned. In addition, copper alloys in which zinc, silver, nickel and the like are singly or in combination with copper may also be mentioned. Among them, from the viewpoint of antibacterial properties, metal threads containing copper as a main component (which occupies 50% by mass or more) may be used. As a metal thread which has copper as a main component, a soft copper wire (JIS C3102) for electricity, a hard copper wire, and an oxygen free copper (JIS H3100, C1020) are mentioned. Among them, a hard copper wire may be used from the viewpoint of antibacterial properties and economy, and oxygen-free copper may be used from the viewpoint of antibacterial properties. The metal yarn that constitutes the mixed yarn is not limited to one type, and may be two or more types.
 金属糸の直径は、特に限定されるものでなく、20~100μmであってもよく、30~50μmであってもよく、40~50μmであってもよい。金属糸の直径が20μm以上であると、糸切れが発生しにくく、所望の抗菌性を得ることができる。金属糸の直径が100μm以下であると、軽量の織布が得られやすい。また、得られる織布が粗硬になりにくい。 The diameter of the metal thread is not particularly limited, and may be 20 to 100 μm, 30 to 50 μm, or 40 to 50 μm. When the diameter of the metal thread is 20 μm or more, thread breakage hardly occurs, and desired antibacterial properties can be obtained. When the diameter of the metal yarn is 100 μm or less, a lightweight woven fabric is easily obtained. In addition, the obtained woven fabric is unlikely to be coarse and hard.
(第2非金属糸)
 混合糸を構成する第2非金属糸としては、上記第1非金属糸と同様の非金属糸を用いることができ、織布に要求される性質に応じて適宜選択される。第1非金属糸と第2非金属糸とは、同じであってもよく、異なっていてもよい。
 また、混合糸を構成する第2非金属糸は、1種に限定されず、2種以上であってもよい。
(Second non-metallic thread)
As a 2nd non metallic thread which constitutes mixed yarn, the non metallic thread similar to the above-mentioned 1st non metallic thread can be used, and it is chosen suitably according to the property for which textiles are required. The first non-metallic yarn and the second non-metallic yarn may be the same or different.
In addition, the second non-metallic yarn constituting the mixed yarn is not limited to one type, and may be two or more types.
 金属糸と第2非金属糸との直径の比:金属糸/第2非金属糸は、特に限定されない。比:金属糸/第2非金属糸は、例えば、0.2以上、1以下である。 Ratio of diameter of metal yarn to second non-metallic yarn: The metal yarn / second non-metallic yarn is not particularly limited. Ratio: metal yarn / second non-metal yarn is, for example, 0.2 or more and 1 or less.
(第3非金属糸)
 混合糸に沿って配置され得る第3非金属糸としては、上記第1非金属糸と同様の非金属糸を用いることができ、織布に要求される性質に応じて適宜選択される。第1非金属糸と第3非金属糸とは、同じであってもよく、異なっていてもよい。第2非金属糸と第3非金属糸とは、同じであってもよく、異なっていてもよい。第3非金属糸は、1種であってもよく、2種以上であってもよい。
(Third non-metallic thread)
As a 3rd non metallic thread which may be arranged along mixed yarn, the non metallic thread similar to the above-mentioned 1st non metallic thread can be used, and it is chosen suitably according to the property required for textiles. The first non-metallic yarn and the third non-metallic yarn may be the same or different. The second non-metallic yarn and the third non-metallic yarn may be the same or different. The third non-metallic yarn may be of one type or of two or more types.
 混合糸と第3非金属糸との直径の比:混合糸/第3非金属糸は、特に限定されない。比:混合糸/第3非金属糸は、例えば、0.05以上、35以下であり、0.5以上、5以下であってもよく、0.7以上、2以下であってもよい。 Ratio of diameter of mixed yarn and third non-metallic yarn: mixed yarn / third non-metallic yarn is not particularly limited. Ratio: mixed yarn / third non-metallic yarn is, for example, 0.05 or more and 35 or less, may be 0.5 or more and 5 or less, and may be 0.7 or more and 2 or less.
 以下、実施例により本発明をさらに詳しく説明するが、本発明はこれらの例に限定されるものではない。 Hereinafter, the present invention will be described in more detail by way of examples, but the present invention is not limited to these examples.
<混合糸の作製>
(混合糸A)
 ポリエステル糸(第2非金属糸、直径124μm、繊度167dtex/48f)に、無酸素銅から作製した軟銅線(金属糸、直径40μm)を、撚り方向をS撚り、撚り回数を2.5回/cmとしてカバリングし、混合糸A(直径164μm)を作製した。
<Preparation of mixed yarn>
(Mixed yarn A)
A soft copper wire (metal thread, 40 μm in diameter) made of oxygen-free copper was used as a polyester yarn (second nonmetal thread, 124 μm in diameter, fineness of 167 dtex / 48f) with S twisting direction and 2.5 twisting times Covering as cm, mixed yarn A (diameter: 164 μm) was produced.
(混合糸B)
 ポリエステル糸(第2非金属糸、直径124μm、繊度167dtex/48f)に、無酸素銅から作製した硬銅線(金属糸、直径40μm)を、撚り方向をS撚り、撚り回数を2.5回/cmとしてカバリングし、混合糸B(直径164μm)を作製した。
(Mixed yarn B)
A hard copper wire (metal thread, 40 μm in diameter) made of oxygen-free copper on polyester yarn (second nonmetal thread, 124 μm in diameter, fineness of 167 dtex / 48f), S twisting direction, 2.5 times of twisting times It covered as / cm and produced mixed yarn B (diameter 164 micrometers).
(混合糸C)
 ポリエステル糸(第2非金属糸、直径124μm、繊度167dtex/48f)に、無酸素銅から作製した硬銅線(金属糸、直径50μm)を、撚り方向をS撚り、撚り回数を2.5回/cmとしてカバリングし、混合糸C(直径174μm)を作製した。
(Mixed yarn C)
A hard copper wire (metal thread, 50 μm in diameter) made of oxygen-free copper on polyester yarn (second nonmetal thread, 124 μm in diameter, fineness of 167 dtex / 48f), S twisting direction, 2.5 times of twisting times It covered as / cm and produced mixed yarn C (diameter 174 micrometers).
[実施例1]
<織布の作製>
 作製した混合糸Aと、ポリエステル糸A(第1非金属糸、直径72μm、繊度56dtex/25f)と、ポリエステル糸B(第3非金属糸、直径174μm、繊度330dtex/288f)とを、製織し、平織の織布を作製した。表1に示すように、経糸はポリエステル糸Aである。緯糸はポリエステル糸Bおよび混合糸Aであり、緯糸中、混合糸Aとポリエステル糸Bとの本数の比は、1:2とした。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Aの本数は、領域Rに含まれる経糸および緯糸の合計本数の11.9%となるようにし、混合糸Aは、等間隔になるよう配置した。
 得られた織布において、隣り合う混合糸A同士の間隔は、1154μmであった。また、織布を主面の法線方向から見たとき、織布両面において、混合糸Aの面積は、織布の面積の15.6%であった。隣り合う混合糸Aとポリエステル糸Bとの間には隙間が空いていた。織布の厚さは293μmであった。
Example 1
<Production of woven fabric>
Weaving the prepared mixed yarn A, polyester yarn A (first non-metallic yarn, diameter 72 μm, fineness 56 dtex / 25 f), and polyester yarn B (third non-metallic yarn 174 m in diameter, fineness 330 dtex / 288 f) A plain weave woven fabric was made. As shown in Table 1, the warp yarn is polyester yarn A. The weft yarn is polyester yarn B and mixed yarn A. In the weft yarn, the ratio of the number of mixed yarn A to polyester yarn B is 1: 2. The number of mixed yarns A contained in a predetermined region R (a region surrounded by a square of 2 cm on a side) of the woven fabric is 11.9% of the total number of warps and wefts contained in the region R, The yarns A were arranged at equal intervals.
In the obtained woven fabric, the distance between adjacent mixed yarns A was 1154 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn A was 15.6% of the area of the woven fabric on both sides of the woven fabric. There was a gap between adjacent mixed yarn A and polyester yarn B. The thickness of the woven fabric was 293 μm.
<織布の評価>
 得られた織布について、以下の評価を行った。結果を表2に示す。
<Evaluation of woven fabric>
The following evaluation was performed about the obtained woven fabric. The results are shown in Table 2.
(1)抗菌性
 作製した織布から試験布(0.40g±0.05g)を切り出して、JIS L1902-2015(菌液吸収法)に準拠して評価した。試験菌種として黄色ブドウ球菌(Staphylococcus aureus NBRC 12732)を、標準布として綿100%の白布を用いた。試験布および標準布に試験菌液を接種し、試験菌液接種直後および18時間培養後の生菌数の測定値を求めた。その後、下記式に基づいて静菌活性値Sおよび殺菌活性値Lを算出した。静菌活性値が2.2以上、殺菌活性値が0を超えていれば、抗菌性に優れていると判断した。
 S=(Mb-Ma)-(Mc-Mo)
 L=Ma-Mc
  S :静菌活性値
  L :殺菌活性値
  Ma:標準布の試験菌液接種直後の生菌数の対数値
  Mb:標準布の18時間培養後の生菌数の対数値
  Mo:試験布の試験菌液接種直後の生菌数の対数値
  Mc:試験布の18時間培養後の生菌数の対数値
(1) Antibacterial Property A test cloth (0.40 g ± 0.05 g) was cut out from the produced woven fabric and evaluated in accordance with JIS L1902-2015 (bacterial fluid absorption method). Staphylococcus aureus (Staphylococcus aureus NBRC 12732) was used as a test species, and 100% cotton white cloth was used as a standard cloth. The test bacteria solution was inoculated on a test cloth and a standard cloth, and the measurement value of the number of viable bacteria immediately after inoculation of the test bacteria solution and after 18 hours of culture was obtained. Then, the bacteriostatic activity value S and the bactericidal activity value L were calculated based on the following formula. When the bacteriostatic activity value was 2.2 or more and the bactericidal activity value exceeded 0, it was judged that the antibacterial property was excellent.
S = (Mb-Ma)-(Mc-Mo)
L = Ma-Mc
S: bacteriostatic activity L: bactericidal activity Ma: logarithm of viable count immediately after inoculation of test fabric with standard cloth Mb: logarithm of viable count after 18 hours incubation of standard cloth Mo: examination of test cloth Logarithmic value of viable cell count immediately after inoculation of bacterial solution Mc: Logarithmic value of viable cell count after 18 hours incubation of the test cloth
(2)風合
 織布に触れ、以下の基準に従って判定した。
 (判定)
  最良:柔らかい。
  良:やや粗硬な部分があるが、問題のない程度である。
  不良:全体的に粗硬である。また金属糸の断線が認められる。
(2) Touch The woven fabric was touched and judged in accordance with the following criteria.
(Judgement)
Best: Soft.
Good: There is a somewhat rough and hard part, but there is no problem.
Poor: Overall coarse and hard. Also, disconnection of the metal thread is observed.
[実施例2]
 緯糸中の混合糸Aとポリエステル糸Bとの本数の比を1:4に変更した以外は、実施例1と同様にして、織布を作製した。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Aの本数は、領域Rに含まれる経糸および緯糸の合計本数の7.1%となるようにした。
 得られた織布において、隣り合う混合糸A同士の間隔は、1865μmであった。織布を主面の法線方向から見たとき、織布両面において、混合糸Aの面積は、織布の面積の16.6%であった。織布の厚さは279μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
Example 2
A woven fabric was produced in the same manner as in Example 1 except that the ratio of the number of mixed yarn A to polyester yarn B in the weft was changed to 1: 4. The number of mixed yarns A contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was set to 7.1% of the total number of warp yarns and wefts contained in the region R.
In the obtained woven fabric, the distance between adjacent mixed yarns A was 1865 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn A was 16.6% of the area of the woven fabric on both sides of the woven fabric. The thickness of the woven fabric was 279 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
[実施例3]
 緯糸中の混合糸Aとポリエステル糸Bとの本数の比を1:6に変更した以外は、実施例1と同様にして、織布を作製した。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Aの本数は、領域Rに含まれる経糸および緯糸の合計本数の5.1%となるようにした。
 得られた織布において、隣り合う混合糸A同士の間隔は、2649μmであった。織布を主面の法線方向から見たとき、織布両面において、混合糸Aの面積は、織布の面積の6.2%であった。隣り合う混合糸Aとポリエステル糸Bとの間には隙間が空いていた。織布の厚さは274μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
[Example 3]
A woven fabric was produced in the same manner as in Example 1 except that the ratio of the number of mixed yarn A to polyester yarn B in the weft was changed to 1: 6. The number of mixed yarns A included in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was made to be 5.1% of the total number of warps and wefts included in the region R.
In the obtained woven fabric, the distance between adjacent mixed yarns A was 2649 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn A was 6.2% of the area of the woven fabric on both sides of the woven fabric. There was a gap between adjacent mixed yarn A and polyester yarn B. The thickness of the woven fabric was 274 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
[実施例4]
 緯糸中の混合糸Aとポリエステル糸Bとの本数の比を1:8に変更した以外は、実施例1と同様にして、織布を作製した。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Aの本数は、領域Rに含まれる経糸および緯糸の合計本数の3.9%となるようにした。
 得られた織布において、隣り合う混合糸A同士の間隔は、3424μmであった。織布を主面の法線方向から見たとき、織布両面において、混合糸Aの面積は、織布の面積の7.4%であった。織布の厚さは267μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
Example 4
A woven fabric was produced in the same manner as in Example 1 except that the ratio of the number of mixed yarn A to polyester yarn B in the weft was changed to 1: 8. The number of mixed yarns A contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was set to be 3.9% of the total number of warps and wefts contained in the region R.
In the obtained woven fabric, the distance between adjacent mixed yarns A was 3424 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn A was 7.4% of the area of the woven fabric on both sides of the woven fabric. The thickness of the woven fabric was 267 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
[実施例5]
 混合糸Aを、混合糸Bに変更した以外は、実施例1と同様にして織布を作製した。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Bの本数は、領域Rに含まれる経糸および緯糸の合計本数の11.9%となるようにした。
 得られた織布において、隣り合う混合糸B同士の間隔は、1121.9μmであった。織布を主面の法線方向から見たとき、織布両面において、混合糸Bの面積は、織布の面積の15.1%であった。隣り合う混合糸Bとポリエステル糸Bとの間には隙間が空いていた。織布の厚さは305μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
[Example 5]
A woven fabric was produced in the same manner as in Example 1 except that the mixed yarn A was changed to the mixed yarn B. The number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on a side) of the woven fabric was 11.9% of the total number of warps and wefts contained in the region R.
In the obtained woven fabric, the distance between adjacent mixed yarns B was 1121.9 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn B was 15.1% of the area of the woven fabric on both sides of the woven fabric. There was a gap between adjacent mixed yarn B and polyester yarn B. The thickness of the woven fabric was 305 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
[実施例6]
 混合糸Aを、混合糸Bに変更した以外は、実施例2と同様にして織布を作製した。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Bの本数は、領域Rに含まれる経糸および緯糸の合計本数の7.1%となるようにした。
 得られた織布において、隣り合う混合糸B同士の間隔は、1640.6μmであった。織布を主面の法線方向から見たとき、織布両面において、混合糸Bの面積は、織布の面積の16.3%であった。織布の厚さは291μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
[Example 6]
A woven fabric was produced in the same manner as in Example 2 except that mixed yarn A was changed to mixed yarn B. The number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was 7.1% of the total number of warps and wefts contained in the region R.
In the obtained woven fabric, the distance between adjacent mixed yarns B was 1640.6 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn B was 16.3% of the area of the woven fabric on both sides of the woven fabric. The thickness of the woven fabric was 291 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
[実施例7]
 混合糸Aを、混合糸Bに変更した以外は、実施例3と同様にして織布を作製した。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Bの本数は、領域Rに含まれる経糸および緯糸の合計本数の5.1%となるようにした。
 得られた織布において、隣り合う混合糸B同士の間隔は、3430.4μmであった。織布を主面の法線方向から見たとき、織布両面において、混合糸Bの面積は、織布の面積の6.4%であった。隣り合う混合糸Bとポリエステル糸Bとの間には隙間が空いていた。織布の厚さは284μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
[Example 7]
A woven fabric was produced in the same manner as in Example 3, except that the mixed yarn A was changed to the mixed yarn B. The number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was made to be 5.1% of the total number of warps and wefts contained in the region R.
In the obtained woven fabric, the distance between adjacent mixed yarns B was 3430.4 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn B was 6.4% of the area of the woven fabric on both sides of the woven fabric. There was a gap between adjacent mixed yarn B and polyester yarn B. The thickness of the woven fabric was 284 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
[実施例8]
 混合糸Aを、混合糸Bに変更した以外は、実施例4と同様にして織布を作製した。織布の所定の領域R(一辺2cmの正方形によって囲まれた領域)に含まれる混合糸Bの本数は、領域Rに含まれる経糸および緯糸の合計本数の3.9%となるようにした。
 得られた織布において、隣り合う混合糸B同士の間隔は、3579.8μmであった。織布を主面の法線方向から見たとき、織布両面において、混合糸Bの面積は、織布の面積の7.2%であった。織布の厚さは278μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
[Example 8]
A woven fabric was produced in the same manner as in Example 4 except that mixed yarn A was changed to mixed yarn B. The number of mixed yarns B contained in a predetermined region R (a region surrounded by a square of 2 cm on one side) of the woven fabric was made to be 3.9% of the total number of warps and wefts contained in the region R.
In the obtained woven fabric, the distance between adjacent mixed yarns B was 3579.8 μm. When the woven fabric was viewed in the normal direction of the main surface, the area of the mixed yarn B was 7.2% of the area of the woven fabric on both sides of the woven fabric. The thickness of the woven fabric was 278 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
[実施例9]
 混合糸Cと、ポリエステル糸C(第1非金属糸、直径124μm、繊度167dtex/48f)と、ポリエステル糸D(第3非金属糸、直径124μm、繊度167dtex/48f)とを、製織し、サテン織の織布を作製した。表1に示すように、経糸は混合糸Cおよびポリエステル糸C、緯糸はポリエステル糸Dとし、経糸中、混合糸Cと、ポリエステル糸Cとの本数の比は、1:4とした。織布の所定の領域R(一辺5cmの正方形によって囲まれた領域)に含まれる混合糸Cの本数は、領域Rに含まれる経糸および緯糸の合計本数の14.2%となるようにし、混合糸Cは、経糸に等間隔になるよう配置した。織密度(設計密度)は、経150本/2.54cm、緯60本/2.54cmであった。
 得られた織布の一方の主面において、混合糸C同士は接触するように配置されており(間隔0μm)、混合糸Cの面積は、当該主面の面積の100%を占めていた。他方の主面において、混合糸Cの面積は、当該主面の面積の7.1%であった。織布の厚さは275μmであった。
 (1)抗菌性および(2)風合の評価結果を、表2に示す。
[Example 9]
Weaving mixed yarn C, polyester yarn C (first nonmetal yarn, diameter 124 μm, fineness 167 dtex / 48f), and polyester yarn D (third nonmetal yarn, diameter 124 μm, fineness 167 dtex / 48f), and satin A woven woven fabric was made. As shown in Table 1, warp yarns were mixed yarn C and polyester yarn C, weft yarns were polyester yarn D, and the ratio of the number of mixed yarn C to polyester yarn C in the warp yarns was 1: 4. The number of mixed yarns C contained in a predetermined region R (a region surrounded by a square of 5 cm on a side) of the woven fabric is 14.2% of the total number of warps and wefts contained in the region R, The yarns C were arranged at equal intervals on the warp yarns. The weave density (design density) was 150 / 2.54 cm and 60 // 2.54 cm.
In one main surface of the obtained woven fabric, the mixed yarns C were arranged to be in contact with each other (interval: 0 μm), and the area of the mixed yarn C occupied 100% of the area of the main surfaces. In the other main surface, the area of the mixed yarn C was 7.1% of the area of the main surface. The thickness of the woven fabric was 275 μm.
The evaluation results of (1) antibacterial properties and (2) hand feeling are shown in Table 2.
 別途、得られた織布を5回洗濯し、洗濯前の織布、洗濯後の織布のそれぞれについて、黄色ブドウ球菌および肺炎桿菌に対する抗菌性および風合を評価した。洗濯方法は、繊維評価技術協議会規定のSEKマーク繊維製品の洗濯方法(標準洗濯法)に従った。なお、抗菌性の評価は、(1)の抗菌性試験と同様に行い、試験菌種として黄色ブドウ球菌(Staphylococcus aureus NBRC 12732)および肺炎桿菌(Klebsiella pneumoniae NBRC 13277)を用いた。評価結果を表3に示す。 Separately, the obtained woven fabric was washed 5 times, and the antibacterial property and the feeling to Staphylococcus aureus and Klebsiella pneumonia were evaluated for the woven fabric before laundering and the woven fabric after laundering. The washing method was according to the washing method (standard washing method) of the SEK mark textile product specified by the Fiber Evaluation Technology Council. The antibacterial property was evaluated in the same manner as the antibacterial property test of (1), and Staphylococcus aureus (Staphylococcus aureus NBRC 12732) and Klebsiella pneumoniae NBRC 13277 were used as test bacterial species. The evaluation results are shown in Table 3.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 実施例1~実施例9で得られる織布は薄い。さらに、表2および表3より、これら織布は高い抗菌性を示すとともに、風合の点でも優れることがわかる。また、実施例9からわかるように、本実施形態にかかる織布は、洗濯によっても抗菌性は低下しない。 The woven fabrics obtained in Examples 1 to 9 are thin. Furthermore, it can be seen from Table 2 and Table 3 that these woven fabrics exhibit high antibacterial properties and are also excellent in terms of feel. Further, as can be seen from Example 9, the woven fabric according to the present embodiment does not have reduced antimicrobial properties even by washing.
 これらのことから、金属糸を含む織布においては、混合糸と第1非金属糸との直径の比、および織布に含まれる混合糸の本数を限定することにより、優れた抗菌性および風合を両立することが可能になることが明らかとなった。 From these facts, in the woven fabric containing the metal yarn, excellent antibacterial property and wind resistance can be obtained by limiting the ratio of the diameter of the mixed yarn to the first non-metallic yarn and the number of mixed yarns contained in the woven fabric. It became clear that it was possible to make the case compatible.
 本発明によれば、抗菌性および風合に優れた織布が得られる。また、金属糸を含むにもかかわらず、織布を薄くすることも可能である。そのため、本発明の織布は、シーツ、枕カバー、タオルなどのリネン品、パジャマ、白衣、エプロン、帽子、ユニフォーム、制服などの各種衣料品、カーシート、椅子、ベビーカーなどの座席用シートおよびそのシートカバー、鞄、靴、カーテン、テント、寝袋、ランチョンマット、冷蔵庫内用シートなどに広く用いることができる。 According to the present invention, a woven fabric having excellent antibacterial properties and feeling can be obtained. It is also possible to thin the fabric despite the inclusion of metal yarns. Therefore, the woven fabric of the present invention includes sheets, pillow covers, linen products such as towels, pajamas, white coats, aprons, hats, uniforms, various clothing articles such as uniforms, seat sheets such as car seats, chairs, strollers and the like It can be widely used for seat covers, bags, shoes, curtains, tents, sleeping bags, place mats, interior seats for refrigerators and the like.

Claims (2)

  1.  混合糸と、前記混合糸と交わる第1非金属糸と、を含む織布であって、
     前記混合糸が、第2非金属糸と金属糸とを含み、
     前記混合糸と前記第1非金属糸との直径の比:混合糸/第1非金属糸が1以上であり、
     前記織布の所定の領域に含まれる前記混合糸の本数が、前記所定の領域に含まれるすべての糸の本数の3.5~30%である、織布。
    A woven fabric comprising a mixed yarn and a first non-metallic yarn intersecting with the mixed yarn,
    The mixed yarn comprises a second non-metallic yarn and a metallic yarn,
    The ratio of the diameter of the mixed yarn to the first non-metallic yarn: mixed yarn / first non-metallic yarn is 1 or more,
    A woven fabric, wherein the number of the mixed yarns contained in a predetermined area of the woven fabric is 3.5 to 30% of the number of all the yarns contained in the predetermined area.
  2.  前記混合糸が、前記第2非金属糸に前記金属糸を巻き付けたカバリング糸、あるいは、前記第2非金属糸および前記金属糸を撚り合わせて形成される合撚糸である、請求項1に記載の織布。 The covering yarn according to claim 1, wherein the mixed yarn is a covering yarn obtained by winding the metal yarn around the second non-metallic yarn, or a composite yarn formed by twisting the second non-metallic yarn and the metal yarn. Woven fabric.
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