WO2019051712A1 - Methods of manufacturing ic card circuit board substrates and ic cards - Google Patents

Methods of manufacturing ic card circuit board substrates and ic cards Download PDF

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Publication number
WO2019051712A1
WO2019051712A1 PCT/CN2017/101735 CN2017101735W WO2019051712A1 WO 2019051712 A1 WO2019051712 A1 WO 2019051712A1 CN 2017101735 W CN2017101735 W CN 2017101735W WO 2019051712 A1 WO2019051712 A1 WO 2019051712A1
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WO
WIPO (PCT)
Prior art keywords
copper
treatment tank
substrate
concentration
per litre
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Application number
PCT/CN2017/101735
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French (fr)
Inventor
Xiaoxing Wu
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Apply Card Technology Limited
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Publication date
Application filed by Apply Card Technology Limited filed Critical Apply Card Technology Limited
Priority to PCT/CN2017/101735 priority Critical patent/WO2019051712A1/en
Publication of WO2019051712A1 publication Critical patent/WO2019051712A1/en

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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/40Forming printed elements for providing electric connections to or between printed circuits
    • H05K3/42Plated through-holes or plated via connections
    • H05K3/425Plated through-holes or plated via connections characterised by the sequence of steps for plating the through-holes or via connections in relation to the conductive pattern
    • H05K3/427Plated through-holes or plated via connections characterised by the sequence of steps for plating the through-holes or via connections in relation to the conductive pattern initial plating of through-holes in metal-clad substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1646Characteristics of the product obtained
    • C23C18/165Multilayered product
    • C23C18/1653Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/42Coating with noble metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/54Contact plating, i.e. electroless electrochemical plating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/12Electroplating: Baths therefor from solutions of nickel or cobalt
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/56Electroplating: Baths therefor from solutions of alloys
    • C25D3/58Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • C23C18/38Coating with copper
    • C23C18/40Coating with copper using reducing agents
    • C23C18/405Formaldehyde
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/01Tools for processing; Objects used during processing
    • H05K2203/0104Tools for processing; Objects used during processing for patterning or coating
    • H05K2203/0126Dispenser, e.g. for solder paste, for supplying conductive paste for screen printing or for filling holes
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/04Soldering or other types of metallurgic bonding
    • H05K2203/049Wire bonding
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/24Reinforcing the conductive pattern
    • H05K3/244Finish plating of conductors, especially of copper conductors, e.g. for pads or lands
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/28Applying non-metallic protective coatings
    • H05K3/284Applying non-metallic protective coatings for encapsulating mounted components
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/303Surface mounted components, e.g. affixing before soldering, aligning means, spacing means
    • H05K3/305Affixing by adhesive

Definitions

  • This invention relates to methods of manufacturing integrated circuit (IC) card circuit board substrates and manufacturing IC cards (or so called “smart cards” ) and in particular such methods suitable for, but not limited to, manufacturing contact IC card circuit board substrates and contact IC cards.
  • IC integrated circuit
  • Contact IC cards were devised in the 1990’s and have since been undergoing development. For contact IC cards, at least a major surface of an IC module of the IC card with a read/write interface is exposed to the outside environment. Contact IC card does not carry power source. When in use, the read/write interface of the contact IC card is in direct physical contact with a read/write head of a computer terminal or processor, whereby data may be written into or read from the IC module in the contact IC card.
  • the signals transmitted by the read/write head consist of two parts, namely a first part being an electric power signal which provides the electric power for the IC module, and a second part being combined data signals directing the IC module to carry out changing and storing of data, and to provide feedback to the read/write head.
  • SIM subscriber identity module
  • subscriber identification module a module that specifies the access control, transport, social security, identity certification, and electronic wallets.
  • a method of manufacturing an integrated circuit (IC) card circuit board substrate including (a) providing a substrate with two opposite major surfaces both covered by a layer of copper, (b) forming at least two holes through said substrate, each said hole being of a diameter of no more than 0.50 mm, (c) depositing a layer of copper on an interior surface of each of said two holes, said layer of copper covering at least part of each of said major surfaces of said substrate, (d) forming an electric circuit on at least one of said major surfaces of said substrate, and (e) depositing at least a layer of nickel and a layer of gold on said layer of copper.
  • IC integrated circuit
  • a method of forming an integrated circuit (IC) card including steps (a) providing a substrate with two opposite major surfaces both covered by a layer of copper, (b) forming at least two holes through said substrate, each said hole being of a diameter of no more than 0.50 mm, (c) depositing a layer of copper on an interior surface of each of said two holes, said layer of copper covering at least part of each of said major surfaces of said substrate, (d) forming an electric circuit on at least one of said major surfaces of said substrate, and (e) depositing at least a layer of nickel and a layer of gold on said layer of copper, (l) fixedly securing an IC module with said substrate, and (m) electrically connecting said IC module with said electric circuit on said at least one of said major surfaces of said substrate.
  • Figs. 1 to 6 show a method according to an embodiment of the present invention to manufacture an integrated circuit (IC) card circuit board substrate
  • Fig. 7 shows a schematic diagram of an IC card formed by flip flop bonding on an IC card circuit board substrate manufactured according to an embodiment of the present invention
  • Figs. 8 to 10 show a method of forming the IC card of Fig. 7;
  • Fig. 11 shows a schematic diagram of an IC card formed by wire bonding on an IC card circuit board substrate manufactured according to an embodiment of the present invention.
  • Figs. 12 to 16 show a method of forming the IC card of Fig. 11.
  • Fig. 1 shows an FR4 sheet 10 from which a substrate 12 (which is here also called “flexible circuit board” (FCB) ) is cut out. Both opposite major surfaces 13 of the FR4 sheet 10 (and thus of the FCB 12) are covered by copper. As shown in Fig. 2, pairs of holes 14 are formed through the FCB 12, e.g. by drilling or punching. Fig. 3 shows that, after drilling or punching, the cylindrical interior surface 16 of the holes 14 is not covered by an electrically conductive material, e.g. copper, and thus the two opposite major surfaces 13 of the PCB 12 are not electrically connected with each other..
  • FCB flexible circuit board
  • the FCB 12 is then placed in a treatment tank for electroplating an electrically conductive material, e.g. copper, onto the cylindrical interior surface 16 of the holes 14.
  • the electroplating process is carried out at a temperature of 0 °C to 75 °C for 2 hours.
  • the treatment tank contains sodium hydroxide at a concentration of 12 grams per litre, formaldehyde at a concentration of 5 grams per litre, copper ions at a concentration of 2 grams per litre, and plastic palladium at a concentration of 5 grams per litre.
  • a layer of copper is then formed on the cylindrical interior surfaces 16 of the holes 14 and on each opposite major surface 13 of the FCB 12, as shown in Fig. 4. The two opposite major surfaces 13 of the PCB 12 are thus electrically connected with each other.
  • An electric circuit is then formed on the major surfaces 13 of the FCB 12.
  • a circuit pattern is first formed on the major surfaces 13 of the FCB 12.
  • a photo-resist material is applied on the major surfaces 13 of the FCB 12 to form pre-determined circuit patterns.
  • Copper is then electroplated on the major surface 13 of the FCB 12 by placing the FCB 12 in a treatment tank for electroplating.
  • the treatment tank contains tin brightener at a concentration of 20 millilitres per litre, copper brightener at a concentration of 5 millilitres per litre, sulfuric acid at a concentration of 180 grams per litre, copper sulfate at a concentration of 70 grams per litre, chloride ions at a concentration of 50 parts per million (PPM) , electroplating tin at a concentration of 30 grams per litre, and tin (II) sulfate at a concentration of 30 grams per litre, and electroplating is carried out at a temperature of 0 °C to 45 °C for 2 hours. Excessive copper is then removed by an etching solution containing copper chloride and aqueous chloride, such that the remaining copper on the major surfaces 13 of the FCB 12 forms the electric circuit, as shown in Fig. 5.
  • a layer of nickel (Ni) 15 is then deposited on the layer of copper on the upper and lower surfaces 13 and the interior surface 16 of the holes 14 of the FCB 12 and a layer of gold (Au) 17 is deposited on the layer of nickel 15 by treating the FCB 12 by electroless nickel immersion gold (ENIG) in a treatment tank containing a gold plating bath solution at a concentration of 100 millitres per litre, potassium gold cyanide at a concentration of 0.8 grams per litre, nickel ions at a concentration of 4.6 grams per litre and palladium ions at a concentration of 3 grams per litre for 2 hours and at a temperature of 0 °C to 95 °C, to form an integrated circuit (IC) card circuit board substrate 18.
  • ENIG is a type of surface plating, and the layer of immersion gold protects the layer of nickel from oxidation.
  • the two opposite major surfaces are electrically connected with each other via the holes 14.
  • the method of manufacturing the integrated circuit (IC) card circuit board substrate 18 according to the present invention is relatively simple and does not require the use of solder or laser for causing the holes to be electrically conductive, thus lowering the production cost.
  • Fig. 7 shows a schematic diagram of an IC card 20 (such as a SIM card) formed by flip flop bonding on the IC card circuit board substrate (FCB) 18.
  • Figs. 8 to 10 show a method of forming the IC card 20 by the flip flop bonding method.
  • An integrated circuit (IC) module 22 (also called a “chip” or a “wafer” ) is picked up by a first pick tool 24.
  • the first pick tool 24 then rotates and passes the IC module 22 to a second pick tool 26.
  • the second pick 26 then rotates and places the IC module 22 on the substrate 18.
  • An adhesive 28 is then applied on the IC module 22 and the substrate 18 to secure the IC module 22 to the substrate 18.
  • Two electrically conductive wires e.g.
  • the IC card 20 is formed. UV plastic is then added and subsequently treated for encapsulating the IC module 22, for water-proof and dust-proof purposes.
  • Fig. 11 shows a schematic diagram of an IC card 30 (such as a SIM card) formed by wire bonding on the IC card circuit board substrate 18 manufactured according to an embodiment of the present invention.
  • Figs. 12 to 16 show a method of forming the IC card 30 by the wire bonding method.
  • An adhesive 32 is provided at the location on the substrate (FCB) 18 for subsequently fixedly receiving an IC module.
  • a tool 34 picks up an integrated circuit (IC) module 22 (also called a “chip” or a “wafer” ) and places the IC module 22 on the adhesive 32 on the FCB 18.
  • Two electrically conductive wires 36 e.g. gold wires
  • are then bonded e.g.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing Of Printed Wiring (AREA)

Abstract

A method of manufacturing an integrated circuit (IC) card circuit board substrate (18) is disclosed as including steps (a) providing a substrate (12) with two opposite major surfaces (13) both covered by a layer of copper, (b) forming at least two holes (14) through the substrate, each said hole being of a diameter of no more than 0.50 mm, (c) depositing a layer of copper on an interior surface (16) of each of the two holes, the layer of copper covering at least part of each of the major surfaces of the substrate, (d) forming an electric circuit on at least one of the major surfaces of the substrate, and (e) depositing at least a layer of nickel (15) and a layer of gold (17) on the layer of copper

Description

Methods of Manufacturing IC Card Circuit Board Substrates and IC Cards
This invention relates to methods of manufacturing integrated circuit (IC) card circuit board substrates and manufacturing IC cards (or so called “smart cards” ) and in particular such methods suitable for, but not limited to, manufacturing contact IC card circuit board substrates and contact IC cards.
Background of the Invention
Contact IC cards were devised in the 1990’s and have since been undergoing development. For contact IC cards, at least a major surface of an IC module of the IC card with a read/write interface is exposed to the outside environment. Contact IC card does not carry power source. When in use, the read/write interface of the contact IC card is in direct physical contact with a read/write head of a computer terminal or processor, whereby data may be written into or read from the IC module in the contact IC card. The signals transmitted by the read/write head consist of two parts, namely a first part being an electric power signal which provides the electric power for the IC module, and a second part being combined data signals directing the IC module to carry out changing and storing of data, and to provide feedback to the read/write head.
With the development of communications technology, contact IC cards have been used as finance IC cards, SIM (which stands for “subscriber identity module” or “subscriber identification module” ) cards, in GSM and CDMA mobile phone communications technology, and in such daily areas as access control, transport, social security, identity certification, and electronic wallets.
The existing methods of manufacturing contact IC card circuit board substrates are rather complicated. In addition, after manufacture of the substrates, it is still necessary to arrange for the holes provided on the contact IC card circuit board substrates to be electrically conducting by laser, or alternatively by adding solder. Such increases the production cost and adversely affects competitiveness in the market.
It is thus an object of the present invention to provide a method of manufacturing IC card circuit board substrates and a method of manufacturing IC cards in which the aforesaid shortcomings are mitigated or at least to provide a useful alternative to the trade and  public.
Summary of the Invention
According to a first aspect of the present invention, there is provided a method of manufacturing an integrated circuit (IC) card circuit board substrate, including (a) providing a substrate with two opposite major surfaces both covered by a layer of copper, (b) forming at least two holes through said substrate, each said hole being of a diameter of no more than 0.50 mm, (c) depositing a layer of copper on an interior surface of each of said two holes, said layer of copper covering at least part of each of said major surfaces of said substrate, (d) forming an electric circuit on at least one of said major surfaces of said substrate, and (e) depositing at least a layer of nickel and a layer of gold on said layer of copper.
According to a second aspect of the present invention, there is provided a method of forming an integrated circuit (IC) card, including steps (a) providing a substrate with two opposite major surfaces both covered by a layer of copper, (b) forming at least two holes through said substrate, each said hole being of a diameter of no more than 0.50 mm, (c) depositing a layer of copper on an interior surface of each of said two holes, said layer of copper covering at least part of each of said major surfaces of said substrate, (d) forming an electric circuit on at least one of said major surfaces of said substrate, and (e) depositing at least a layer of nickel and a layer of gold on said layer of copper, (l) fixedly securing an IC module with said substrate, and (m) electrically connecting said IC module with said electric circuit on said at least one of said major surfaces of said substrate.
Brief Description of the Drawings
Embodiments of the present invention will now be described, by way of examples only, with reference to the accompanying drawings, in which:
Figs. 1 to 6 show a method according to an embodiment of the present invention to manufacture an integrated circuit (IC) card circuit board substrate,
Fig. 7 shows a schematic diagram of an IC card formed by flip flop bonding on an IC card circuit board substrate manufactured according to an embodiment of the present invention;
Figs. 8 to 10 show a method of forming the IC card of Fig. 7;
Fig. 11 shows a schematic diagram of an IC card formed by wire bonding on an IC card circuit board substrate manufactured according to an embodiment of the present invention;  and
Figs. 12 to 16 show a method of forming the IC card of Fig. 11.
Detailed Description of the Embodiments
Fig. 1 shows an FR4 sheet 10 from which a substrate 12 (which is here also called “flexible circuit board” (FCB) ) is cut out. Both opposite major surfaces 13 of the FR4 sheet 10 (and thus of the FCB 12) are covered by copper. As shown in Fig. 2, pairs of holes 14 are formed through the FCB 12, e.g. by drilling or punching. Fig. 3 shows that, after drilling or punching, the cylindrical interior surface 16 of the holes 14 is not covered by an electrically conductive material, e.g. copper, and thus the two opposite major surfaces 13 of the PCB 12 are not electrically connected with each other..
The FCB 12 is then placed in a treatment tank for electroplating an electrically conductive material, e.g. copper, onto the cylindrical interior surface 16 of the holes 14. The electroplating process is carried out at a temperature of 0 ℃ to 75 ℃ for 2 hours. The treatment tank contains sodium hydroxide at a concentration of 12 grams per litre, formaldehyde at a concentration of 5 grams per litre, copper ions at a concentration of 2 grams per litre, and plastic palladium at a concentration of 5 grams per litre. A layer of copper is then formed on the cylindrical interior surfaces 16 of the holes 14 and on each opposite major surface 13 of the FCB 12, as shown in Fig. 4. The two opposite major surfaces 13 of the PCB 12 are thus electrically connected with each other.
An electric circuit is then formed on the major surfaces 13 of the FCB 12. A circuit pattern is first formed on the major surfaces 13 of the FCB 12. In particular, by using film exposure principle, a photo-resist material is applied on the major surfaces 13 of the FCB 12 to form pre-determined circuit patterns. Copper is then electroplated on the major surface 13 of the FCB 12 by placing the FCB 12 in a treatment tank for electroplating. The treatment tank contains tin brightener at a concentration of 20 millilitres per litre, copper brightener at a concentration of 5 millilitres per litre, sulfuric acid at a concentration of 180 grams per litre, copper sulfate at a concentration of 70 grams per litre, chloride ions at a concentration of 50 parts per million (PPM) , electroplating tin at a concentration of 30 grams per litre, and tin (II) sulfate at a concentration of 30 grams per litre, and electroplating is carried out at a temperature of 0 ℃ to 45 ℃ for 2 hours. Excessive copper is then removed  by an etching solution containing copper chloride and aqueous chloride, such that the remaining copper on the major surfaces 13 of the FCB 12 forms the electric circuit, as shown in Fig. 5.
As shown in Fig. 6, a layer of nickel (Ni) 15 is then deposited on the layer of copper on the upper and lower surfaces 13 and the interior surface 16 of the holes 14 of the FCB 12 and a layer of gold (Au) 17 is deposited on the layer of nickel 15 by treating the FCB 12 by electroless nickel immersion gold (ENIG) in a treatment tank containing a gold plating bath solution at a concentration of 100 millitres per litre, potassium gold cyanide at a concentration of 0.8 grams per litre, nickel ions at a concentration of 4.6 grams per litre and palladium ions at a concentration of 3 grams per litre for 2 hours and at a temperature of 0 ℃ to 95 ℃, to form an integrated circuit (IC) card circuit board substrate 18. ENIG is a type of surface plating, and the layer of immersion gold protects the layer of nickel from oxidation. In the IC card circuit board substrate 18, the two opposite major surfaces are electrically connected with each other via the holes 14.
The method of manufacturing the integrated circuit (IC) card circuit board substrate 18 according to the present invention is relatively simple and does not require the use of solder or laser for causing the holes to be electrically conductive, thus lowering the production cost.
Fig. 7 shows a schematic diagram of an IC card 20 (such as a SIM card) formed by flip flop bonding on the IC card circuit board substrate (FCB) 18. Figs. 8 to 10 show a method of forming the IC card 20 by the flip flop bonding method. An integrated circuit (IC) module 22 (also called a “chip” or a “wafer” ) is picked up by a first pick tool 24. The first pick tool 24 then rotates and passes the IC module 22 to a second pick tool 26. The second pick 26 then rotates and places the IC module 22 on the substrate 18. An adhesive 28 is then applied on the IC module 22 and the substrate 18 to secure the IC module 22 to the substrate 18. Two electrically conductive wires (e.g. gold wires) are then bonded (e.g. by ultrasonic bonding) to the contact points on the IC module 22 and the contact points on the substrate 18 to electrically connect the IC module 22 with the electric circuit on the substrate 18. The IC card 20 is formed. UV plastic is then added and subsequently treated for encapsulating the IC module 22, for water-proof and dust-proof purposes.
Fig. 11 shows a schematic diagram of an IC card 30 (such as a SIM card) formed by wire bonding on the IC card circuit board substrate 18 manufactured according to an embodiment of the present invention. Figs. 12 to 16 show a method of forming the IC card 30 by the wire bonding method. An adhesive 32 is provided at the location on the substrate (FCB) 18 for subsequently fixedly receiving an IC module. A tool 34 picks up an integrated circuit (IC) module 22 (also called a “chip” or a “wafer” ) and places the IC module 22 on the adhesive 32 on the FCB 18. Two electrically conductive wires 36 (e.g. gold wires) are then bonded (e.g. by ultrasonic bonding) to the contact points on the IC module 22 and the contact points on the substrate 18 to electrically connect the IC module 22 with the electric circuit on the substrate 18. An electrically conductive adhesive 38 is then applied to further secure the connection between the electrically conductive wires 36 and the FCB 12. The IC card 30 is formed. UV plastic 40 is then added and subsequently treated for encapsulating the IC module 22, for water-proof and dust-proof purposes.
It should be understood that the above only illustrates examples whereby the present invention may be carried out, and that various modifications and/or alterations may be made thereto without departing from the spirit of the invention.
It should also be understood that certain features of the invention, which are, for clarity, described in the context of separate embodiments, may be provided in combination in a single embodiment. Conversely, various features of the invention which are, for brevity, described in the context of a single embodiment, may also be provided separately or in any appropriate sub-combinations.

Claims (36)

  1. A method of manufacturing an integrated circuit (IC) card circuit board substrate, including:
    (a) providing a substrate with two opposite major surfaces both covered by a layer of copper,
    (b) forming at least two holes through said substrate, each said hole being of a diameter of no more than 0.50 mm,
    (c) depositing a layer of copper on an interior surface of each of said two holes, said layer of copper covering at least part of each of said major surfaces of said substrate,
    (d) forming an electric circuit on at least one of said major surfaces of said substrate, and
    (e) depositing at least a layer of nickel and a layer of gold on said layer of copper.
  2. A method according to any of Claim 1, wherein said at least two holes are formed by drilling and/or punching.
  3. A method according to Claim 1 or 2, wherein said substrate is a flexible circuit board.
  4. A method according to any of the preceding claims, wherein said step (c) is carried out at a temperature of 0 ℃ to 75 ℃.
  5. A method according to any of the preceding claims, wherein said step (c) is carried out for substantially 2 hours.
  6. A method according to any of the preceding claims, wherein said step (c) is carried out in a first treatment tank containing at least sodium hydroxide, formaldehyde, copper ions and plastic palladium.
  7. A method according to Claim 6, wherein said first treatment tank contains copper ions at a concentration of substantially 2 grams per litre.
  8. A method according to Claim 6 or 7, wherein said first treatment tank contains sodium  hydroxide at a concentration of substantially 12 grams per litre.
  9. A method according to any one of Claims 6 to 8, wherein first treatment tank contains formaldehyde at a concentration of substantially 5 grams per litre.
  10. A method according to any one of Claims 6 to 9, wherein first treatment tank contains plastic palladium at a concentration of substantially 5 grams per litre.
  11. A method according to any of the preceding claims, wherein said step (d) includes a step (f) of forming a circuit pattern on said at least one of said major surfaces of said substrate, and a step (g) of depositing copper on said circuit pattern to form said electric circuit.
  12. A method according to Claim 11, wherein said step (g) includes a step (h) of electroplating copper on said at least one of said major surfaces of said substrate and a step (i) of removing unwanted copper from said at least one of said major surfaces of said substrate whereby the remaining copper on said at least one of said major surfaces of said substrate forms said electric circuit.
  13. A method according to Claim 12, wherein said step (h) is carried out in a second treatment tank containing at least tin brightener, copper brightener, sulfuric acid, copper sulfate, chloride ions, electroplating tin, and tin (II) sulfate.
  14. A method according to Claim 13, wherein said second treatment tank contains tin brightener at a concentration of substantially 20 millilitres per litre.
  15. A method according to Claim 13 or 14, wherein said second treatment tank contains sulfuric acid at a concentration of substantially 180 grams per litre.
  16. A method according to any one of Claims 13 to 15, wherein said second treatment tank contains copper brightener at a concentration of substantially 5 millilitres per litre.
  17. A method according to any one of Claims 13 to 16, wherein said second treatment tank contains copper sulfate at a concentration of substantially 70 grams per litre.
  18. A method according to any one of Claims 13 to 17, wherein said second treatment tank contains chloride ions at a concentration of substantially 50 parts per million (PPM) .
  19. A method according to any one of Claims 13 to 18, wherein said second treatment tank contains electroplating tin at a concentration of substantially 30 grams per litre.
  20. A method according to any one of Claims 13 to 19, wherein said second treatment tank contains tin (II) sulfate at a concentration of substantially 30 grams per litre.
  21. A method according to any one of Claims 12 to 20, wherein said step (g) is carried out at a temperature of 0 ℃ to 45 ℃.
  22. A method according to any one of Claims 12 to 21, wherein said step (i) is carried out by using an etching solution including at least copper chloride and aqueous ammonia.
  23. A method according to any one of Claims 12 to 22, wherein said step (g) is carried out for substantially 2 hours.
  24. A method according to any of the preceding claims, wherein said step (e) is carried out in a third treatment tank containing at least a gold plating bath solution, potassium gold cyanide, palladium ions and nickel ions.
  25. A method according to Claim 24, wherein said third treatment tank contains gold plating bath solution at a concentration of substantially 100 millitres per litre.
  26. A method according to Claim 24 or 25, wherein said third treatment tank contains potassium gold cyanide at a concentration of substantially 0.8 grams per litre.
  27. A method according to any one of Claims 24 to 26, wherein said third treatment tank contains palladium ions at a concentration of substantially 3 grams per litre.
  28. A method according to any one of Claims 24 to 27, wherein said third treatment tank  contains nickel ions at a concentration of substantially 4.6 grams per litre.
  29. A method according to any of the preceding claims, wherein said step (e) is carried out for substantially 2 hours.
  30. A method according to any of the preceding claims, wherein said step (e) is carried out at a temperature of 0 ℃ to 95 ℃.
  31. A method according to any of the preceding claims, wherein, in said step (e) , said layer of nickel is deposited on said layer of copper and said layer of gold is deposited on said layer of nickel.
  32. A method according to any of the preceding claims, wherein said step (e) is carried out by electroless nickel immersion gold.
  33. A method of forming an integrated circuit (IC) card, including steps:
    (k) manufacturing an integrated circuit (IC) card circuit board substrate according to Claim 1,
    (l) fixedly securing an IC module with said substrate, and
    (m) electrically connecting said IC module with said electric circuit on said at least one of said major surfaces of said substrate.
  34. A method according to Claim 33, wherein said step (l) is carried out by flip flop bonding.
  35. A method according to Claim 33, wherein said step (l) is carried out by wire bonding.
  36. A method according to any one of Claims 33 to 35 wherein said IC card is a SIM card.
PCT/CN2017/101735 2017-09-14 2017-09-14 Methods of manufacturing ic card circuit board substrates and ic cards WO2019051712A1 (en)

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EP3892759A1 (en) * 2020-04-06 2021-10-13 Linxens Holding Tape for electrical circuits with rose-gold contact pads and method for manufacturing such a tape

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EP3892759A1 (en) * 2020-04-06 2021-10-13 Linxens Holding Tape for electrical circuits with rose-gold contact pads and method for manufacturing such a tape

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