WO2019048272A1 - Handheld device for treating stains - Google Patents

Handheld device for treating stains Download PDF

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Publication number
WO2019048272A1
WO2019048272A1 PCT/EP2018/072971 EP2018072971W WO2019048272A1 WO 2019048272 A1 WO2019048272 A1 WO 2019048272A1 EP 2018072971 W EP2018072971 W EP 2018072971W WO 2019048272 A1 WO2019048272 A1 WO 2019048272A1
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WO
WIPO (PCT)
Prior art keywords
stain
spot
controller
treatment
handset
Prior art date
Application number
PCT/EP2018/072971
Other languages
German (de)
French (fr)
Inventor
Philipp Neumaier
Christian TILL
Original Assignee
BSH Hausgeräte GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BSH Hausgeräte GmbH filed Critical BSH Hausgeräte GmbH
Publication of WO2019048272A1 publication Critical patent/WO2019048272A1/en

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F43/00Dry-cleaning apparatus or methods using volatile solvents
    • D06F43/002Spotting apparatus
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F34/00Details of control systems for washing machines, washer-dryers or laundry dryers
    • D06F34/14Arrangements for detecting or measuring specific parameters
    • D06F34/18Condition of the laundry, e.g. nature or weight
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3563Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing solids; Preparation of samples therefor
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/359Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2103/00Parameters monitored or detected for the control of domestic laundry washing machines, washer-dryers or laundry dryers
    • D06F2103/02Characteristics of laundry or load
    • D06F2103/06Type or material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/42Detergent or additive supply
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F2105/00Systems or parameters controlled or affected by the control systems of washing machines, washer-dryers or laundry dryers
    • D06F2105/56Remaining operation time; Remaining operational cycles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F7/00Washing devices adapted to be used independently of any particular receptacle, e.g. for removable mounting on wash-tubs, bath-tubs, or the like
    • D06F7/04Washing devices adapted to be used independently of any particular receptacle, e.g. for removable mounting on wash-tubs, bath-tubs, or the like of the vibrator type
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/02Mechanical
    • G01N2201/022Casings
    • G01N2201/0221Portable; cableless; compact; hand-held

Definitions

  • the invention is in the field of stain treatment, in particular on textile materials such as e.g. Laundry.
  • textile materials such as e.g. Laundry.
  • cleaning or washing materials such as laundry, flat linen and molded articles (e.g., garments)
  • German Offenlegungsschrift DE 10 2015 006 045 A1 describes a method and a device for the after-treatment of laundry items using a sensor device and a stain removal device.
  • the sensor device may be a camera system or a sensor strip which has one or more individual sensors.
  • the stain remover seen downstream in the direction of conveyance of a laundry article to be treated may be constituted by a spray nozzle containing bleaching agents, detergents or solvents such as e.g. Alcohols, alkanes, acetates, enzymes, anionic and non-anionic surfactants or other compounds or mixtures targeted locally applied to the respective spot whose location coordinates have previously been determined by the sensor device.
  • the stain remover may provide various amounts, concentrations or compositions of cleaning or treating agents.
  • the known device is stationary and usually then arranged directly adjacent to a cleaning or washing device.
  • US Pat. No. 6,886,371 discloses a washing machine with an additional hand-operated cleaning device for the local treatment of particularly stubborn soiling with an ultrasound head.
  • a cleaning agent applied to the material area to be treated locally is brought to effect particularly effectively by oscillatory movements of the ultrasound head.
  • it is up to the user's experience and discretion to adjust the dosage and intensity of the ultrasonic waves on the one hand with regard to the (polluted) material to be treated and on the other hand with regard to the type of stain or the degree of staining.
  • An overdose involves the risk of damage to the material or the tissue.
  • US Pat. No. 6,376,444 discloses a hand-held device for stain treatment and a method practicable therewith.
  • the handset has a reservoir with a cleaning agent disposed at one end of a handle body.
  • the other end of the grip body has a transducer which applies sound waves to spots of a textile to be treated. Again, it is up to the experience and sensitivity of the user to choose the treatment intensity and treatment time so that on the one hand or the stains are sufficiently removed and on the other hand avoid damage to the treated textile area by the application of sound waves or the vibrations of the transducer is.
  • an object of the present invention is to provide a hand-held device for stain treatment on materials, such as textiles or laundry, which is particularly effective and optimized in terms of resources (energy requirements and treatment means) and at the same time reduces the risk of damage to the treated material.
  • a handheld device for treating stains on materials in accordance with the present invention includes a controller, a transducer, and a spectroscope.
  • the spectroscope is designed so that it is designed for a spectroscopic determination of the type of stained material and / or the type of spot to be treated and / or the degree of contamination.
  • the spectroscope is aimed at a defined distance (for example, predetermined by a spacer) or almost directly at the (carrier) material and / or the spot and performs a spectroscopic analysis (spectroscopy).
  • Spectroscopy is understood in a known and therefore not shown here in detail as the physical method to disperse a radiation according to certain properties, in particular according to the wavelength.
  • the intensity distribution observed here is also called the spectrum and is different substances - thus also for the composition of different spots or the type or type of the carrier material - characteristic, at least indicative.
  • the information supplied by the spectroscope and usually converted into electrical signals can be compared with reference information stored in the controller of the handheld device, for this purpose the controller can comprise an evaluation unit with a data memory. This can at least roughly determine the category or characteristic of the patch to be treated.
  • the spectrometer comprises at least one radiation source which emits radiation in a predetermined wavelength range which strikes the material or the spot to be treated. At least one radiation detector registers the radiation reflected by the material or the spot as a measurement signal (to be further processed), which is then transmitted to the controller (for example a microcomputer) and further processed therein in a manner known per se with an evaluation routine stored in the microcomputer.
  • the controller for example a microcomputer
  • calibration spectra for different materials, treatment agents and standard or standard stains can be deposited in the evaluation unit, more preferably also materials which are exposed to different amounts of at least one treatment agent or at least one standard stain.
  • the user can make a (additional) as needed calibration with known material and / or stain type and degree of contamination.
  • the handset has a transducer for treating the patch.
  • a transducer is a component which can be set into motion at comparatively high frequency, preferably in the ultrasound frequency range, and which is vibrationally supplied by a vibration generator to the sensor in a manner known per se (see, for example, US patents 6,376,444 and 6,886,371) to be treated material and / or the stain to be removed and so causes the local cleaning or stain removal or supported.
  • a particular aspect of the invention is that the controller or the Operating parameters of the transducer, in particular the amplitude and / or the frequency and / or the application time of the transducer, depending on the spectroscopic analysis, ie the determination of the nature of the stained material and / or the speckle type and / or the degree of contamination pretends, so that the user accordingly performs the cleaning process. It is preferable and convenient if the controller sets the operating parameters directly. Thus, in the case of particularly sensitive staining materials such as silk, the control can minimize the mechanical stress on the material, ie, for example, operate the transducer with a higher amplitude but a shorter application duration.
  • a preferred embodiment of the invention for handling provides that the handset has a device body, at one end of the transducer and at the other end of the spectroscope is arranged.
  • a particularly convenient stain treatment can be realized in that the handset has a storage and metering device for treatment agent.
  • treating agent is to be construed broadly and includes any preparation which is capable of inducing a treatment result on articles or materials to be treated, such as detergents or cleaning agents.
  • different treatment agents are stored in the hand-held device and / or supplied to the handset, so that according to an advantageous embodiment of the invention, the control depending on the spectroscopic analysis to be applied (it may be more than one component) treatment agent selects and / or dosed.
  • the spectroscope analyzes or determines the dissolving behavior of the stain to be treated and the control system applies different treatment agents depending on the dissolving behavior of the stain.
  • the stain to be removed can be particularly preferably analyzed and pretreated in advance, combined with a recommendation for a further treatment (for example in a subsequent wash cycle of a subsequent washing process). ses).
  • the hand-held device can be connected to a plurality of storage containers with different treatment agents or can have the storage containers integrally in which, for example, surfactants, enzymes or bleaches or mixtures and compositions of stain- and textile-differentiated cleaning agents and solvents are stored.
  • the dosage can be done manually or preferably automatically, in the simplest version continuously over the application time of the transducer.
  • different treatment agents for example enzymes
  • different treatment agents can be metered and applied correspondingly with a time offset.
  • the spectroscopic analysis in the context of the invention may already be sufficient if a cursory or functional stain group is determined (for example proteins, fat, pigments) by analyzing their specific spectra and making them usable.
  • their spectra can be stored in the control as reference values as described, in order to compare the spectral distributions determined by the spectroscope with these reference values and to determine therefrom the functional speckle group.
  • data for the wavelength-dependent reflection behavior for standard contaminants are stored in the control device and / or an external server, which data can be used for the evaluation and material or spot assignment to at least one category.
  • a spectrum is generally normalized to a standard. In this way, an adjustment of a recorded spectrum with, for example, a calibration spectrum is possible; it is also possible to compare several recorded spectra with each other, for example, to track the decrease in a particular amount of a substance.
  • the user can also carry out a preliminary measurement or a determination of the (carrier) material. So, for example, In the case of an already older and graying white cotton carrier material, a substantially systematic displacement of the spectrum compared to the spectrum of a brand-new cotton carrier material results, which, however, can basically be filtered out as an offset.
  • the invention provides a handheld device for targeted stain treatment with optimized use of mechanics, treatment time and treatment agents depending on the type of textile and stains to be treated.
  • the spot-specific application of the energy consumption of the transducer is minimized, resulting in a battery-powered handset to a desirable for the user longer battery life.
  • FIG. 1 shows schematically an embodiment of a hand-held device
  • FIG. 2 shows an embodiment variant of the hand-held device from FIG. 1,
  • Figure 3 shows the treatment of a patch with the handset of Figure 1
  • Figure 4 reference spectra stain-causing media
  • FIG. 5 is a three-dimensional representation of spectral distributions of stain-forming media.
  • FIG. 1 shows a hand-held device 1 for treating a spot 2 which is located on a carrier material, for example a laundry item 3.
  • the handset 1 has a device body 4, in whose one end region 6 a spectroscope 8 is arranged.
  • the spectroscope 8 comprises a radiation source 8a, not shown in further detail, and a detector 8b, not shown in detail, which spectrally analyzes the reflected radiation 9 emanating from the spot 2 with respect to the respective wavelengths.
  • the detector generates due to the incident radiation 9 for further processing in a controller 10 of the handset 1 suitable electrical, symbolized by an arrow output signals 1 1, representing, for example, in digital form the recorded spectrum of the spot 2.
  • FIG. 1 shows a hand-held device 1 for treating a spot 2 which is located on a carrier material, for example a laundry item 3.
  • the handset 1 has a device body 4, in whose one end region 6 a spectroscope 8 is arranged.
  • the spectroscope 8 comprises a radiation
  • a transducer 15 which, in a manner known per se, has an element 18 which can be excited to vibrate by a vibration generator 17 at the tip 16.
  • the oscillation frequency which is preferably in the ultrasound range, but can also be in the audible sound range, the oscillation amplitude and / or the operating time (application time) are symbolized by arrows, variable operating parameters 19.
  • the controller 10 may - as illustrated in this embodiment - the generator 17th apply directly to these operating parameters.
  • the operating parameters may additionally or alternatively be displayed to the user on a display 20 so that the latter can execute the spot treatment in accordance with the displayed indications.
  • FIG 2 shows an embodiment of the handset 1, in which a conveying and metering device 21 (hereinafter referred to as metering device) is provided, which contained in a preferably replaceable cartridge 22 treatment agent 23 via a line 24 in the region of the tip 16 and thus of the (only shown in Figure 1) vibrating element 18 of the transducer promotes.
  • the cartridge 22 may preferably be inserted into a receptacle 28 which can be closed by a cover 26.
  • a plurality of cartridges of the same kind are introduced into a corresponding number of receptacles, wherein the metering device 21 is in selective flow communication with the respective cartridges, as indicated by a plurality of supply lines 29.
  • the metering device 21 - controlled by the controller 10 - as needed different, contained in the individual cartridges treatment means 23 - e.g. Solvents, enzymes or bleach - for each required treatment of the spot 2 ( Figure 1) select and apply.
  • the controller 10 selects the most suitable treatment agent 23 as a function of output signals 1 1 supplied by the spectroscope 8 (information about the type and optionally the intensity level of the spot 2 or of the carrier material (item 3)) and accordingly controls the metering device 21 with regard to metering , Delivery time and delivery time.
  • This control data is thereby provided or selected (for example, from a reference database stored in the controller 10) by taking appropriate spectral analyzes of typical staining media in advance, such that by comparing the spectrum of the stain 2, that stain is associated with at least one stain class or speckle type can be.
  • information about the carrier material (laundry item 3) representing output signals 1 1 can be supplied by the spectroscope by a spectral analysis of the laundry 3 takes place and the spectral values obtained are compared with stored in the controller 10 reference values of typical carrier materials.
  • the stain resolution characteristic or the dissolving behavior of the stain can be determined with the aid of the spectroscope 8 and, if necessary, also stored.
  • the referencing of the stain can serve (for example, as an egg yolk and protein existing stain).
  • the dissolution behavior of the spot to be treated can also be achieved by multiple spectroscopic analyzes during the cleaning or treatment process.
  • a design of the hand-held device is conceivable in that both the transducer and the spectroscope are arranged so that they can simultaneously treat the spot or investigate it spectroscopically.
  • the controller 10 different treatment agents - for example, a first enzyme from a first cartridge 22 ( Figure 2), which is optimized in terms of the solution of egg yolk, and then another enzyme from another cartridge 22, which is optimized in terms of the solution of protein - Apply depending on the dissolving behavior.
  • a first enzyme from a first cartridge 22 Figure 2
  • another enzyme from another cartridge 22 which is optimized in terms of the solution of protein - Apply depending on the dissolving behavior.
  • the user can preferably determine in advance the material or at least the material class of the unsupported carrier material by spectroscopically measuring a normal, that is to say imperfect, region of the material to analyze the handset.
  • the handset compares the recorded spectrum of the material as described above in connection with the spot 2 with previously recorded or stored in a database and possibly retrievable reference spectra.
  • the characteristic spectral courses of blood, cocoa, red wine, soot and sebum are shown schematically in FIG. 4 by way of example.
  • the so-called extinction (according to the absorption) in so-called standard norm variant (SNV) is plotted against the wavelength.
  • the standard standard variant is a standardization method for taking into account the measuring distance of the spectrometer; the curves would shift vertically depending on the measuring distance with essentially unchanged characteristic curve course.
  • the reference spectrum was 100% of clean cotton material (eg a T-shirt) based on reflected radiation ("referenced on clean cotton").
  • the curves were also filtered or smoothed with a suitable algorithm or filter - here the so-called Savitzky-Golay filter 3-1 1).
  • 3-1 1 means the use of a 3rd order polynomial with a sliding window that uses 5 measuring points before and 5 measuring points after the value considered for smoothing.
  • Absorption values above "0" indicate a particularly strong attenuation of the reflected light in the respective wavelength, for blood one recognizes, for example, a wave peak (maximum) of the individual measurement curves at approximately 1730 nm wavelength, while a wave trough (minimum) - ie, relatively strong reflection -
  • a wave peak maximum
  • a wave trough minimum
  • ie relatively strong reflection -
  • this reference spectrum a kind of "fingerprint" for blood and in the same way - with other striking maxima or minima spectra for the other stain - forming substances.
  • the controller assigns the specific spot currently to be treated to a spot type or spot class and accordingly sets the use of the treatment agent used or the type and duration of the operating parameters of the transducer, as described above.
  • the required control variables can be determined beforehand by appropriate tests with the respective types of stains.
  • FIG. 5 shows, in a three-dimensional representation, the relevant reference values for the spectra of typical staining materials already described in FIG. 4, namely blood, cocoa, red wine, soot and sebum, according to so-called multi-variant analysis.
  • These can be stored in the evaluation unit of the handheld device, but also externally in a storage connected via WLAN, for example, or a cloud.
  • FIG. 5 shows a 3-principal component analysis which already has stain-characteristic distributions of the three components PC (principal components), namely PC-1, PC-2 and PC 3, for most common stain-forming substances.
  • the percentages of the principal components eg PC-1 (45%)
  • a cocoa stain essentially has the coefficients (components) [+4 * PC-1; -4 * PC-2; 0 * PC-3].
  • the patches consisting of different substances differ significantly, the values of which virtually define a spatial area (accumulation space of the individual recorded reference values). If the spectrum (after appropriate evaluation) of a spot or carrier material currently being analyzed by the hand-held instrument falls into one of the spatial regions, it is basically possible to reliably determine into which spot category or material category the analyzed substance falls and accordingly control the oscillating head.
  • the spatial ranges of the reference values for sebum and soot are relatively close to each other, so that an even more accurate analysis is preferably carried out here (for example using multivariate analyzes of a higher order or dimension) and / or a rough preselection by the user in the control of the handset is entered.

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The invention relates to a handheld device for treating stains, comprising a controller (10), an acoustic head (15) which is operable with at least one changeable operating parameter (19), at least the amplitude and/or the frequency and/or the application duration being changeable as operating parameters (19), and comprising a spectroscope (8) which is embodied for spectroscopic analysis of the type of stained material (3) and/or the type of stain (2) and/or the intensity of the stain (2), wherein the controller (10) of the handheld device (1) predetermines or sets the operating parameter or parameters (19) depending on the spectroscopic analysis.

Description

Handgerät zur Fleckenbehandlung  Hand-held device for stain treatment
Die Erfindung liegt auf dem Gebiet der Fleckenbehandlung insbesondere auf textilen Materialien wie z.B. Wäschestücken. Bei der Reinigung bzw. beim Waschen von Materia- lien wie Wäschestücken, Flachwäsche und Formteilen (z.B. Bekleidungsstücken) kann es vorkommen, dass nicht alle Flecken aus den verschmutzten Materialien entfernt werden können. The invention is in the field of stain treatment, in particular on textile materials such as e.g. Laundry. When cleaning or washing materials such as laundry, flat linen and molded articles (e.g., garments), it may happen that not all stains can be removed from the soiled materials.
Die Deutsche Offenlegungsschrift DE 10 2015 006 045 A1 beschreibt ein Verfahren und eine Vorrichtung zum Nachbehandeln von Wäschestücken unter Verwendung einer Sensoreinrichtung und einer Fleckentfernungseinrichtung. Bei der Sensoreinrichtung kann es sich um ein Kamerasystem oder eine Sensorleiste handeln, die einen oder mehrere einzelne Sensoren aufweist. Die in Förderrichtung eines zu behandelnden Wäschestücks gesehen nachgeordnete Fleckentfernungseinrichtung kann von einer Sprühdüse gebildet sein, die Bleichmittel, Reinigungsmittel oder Lösungsmittel wie z.B. Alkohole, Alkane, Azetate, Enzyme, anionische und nicht anionische Tenside oder andere Verbindungen oder Gemische zielgerichtet lokal auf den jeweiligen Fleck appliziert, dessen Ortskoordinaten zuvor von der Sensoreinrichtung ermittelt worden sind. Dabei kann die Fleckentfernungseinrichtung verschiedene Mengen, Konzentrationen oder Zusammensetzungen von Reini- gungs- oder Behandlungsmitteln zur Verfügung stellen. Die bekannte Vorrichtung ist ortsfest und üblicherweise prozessual unmittelbar an eine Reinigungs- bzw. Wascheinrichtung anschließend angeordnet. German Offenlegungsschrift DE 10 2015 006 045 A1 describes a method and a device for the after-treatment of laundry items using a sensor device and a stain removal device. The sensor device may be a camera system or a sensor strip which has one or more individual sensors. The stain remover seen downstream in the direction of conveyance of a laundry article to be treated may be constituted by a spray nozzle containing bleaching agents, detergents or solvents such as e.g. Alcohols, alkanes, acetates, enzymes, anionic and non-anionic surfactants or other compounds or mixtures targeted locally applied to the respective spot whose location coordinates have previously been determined by the sensor device. The stain remover may provide various amounts, concentrations or compositions of cleaning or treating agents. The known device is stationary and usually then arranged directly adjacent to a cleaning or washing device.
Aus dem US-Patent 6,886,371 ist eine Waschmaschine mit einem zusätzlichen handbe- dienbaren Reinigungsgerät zur lokalen Behandlung von besonders hartnäckigen Verschmutzungen mit einem Ultraschallkopf bekannt. Ein auf den lokal zu behandelnden Materialbereich aufgebrachtes Reinigungsmittel wird durch Schwingbewegungen des Ultraschallkopfes besonders effektiv zur Wirkung gebracht. Hierbei bleibt es allerdings der Erfahrung und dem Ermessen des Anwenders überlassen, Dosierung und Intensität der Ultraschallwellen einerseits bezüglich des zu behandelnden (verschmutzten) Materials und andererseits mit Blick auf die Fleckenart bzw. den Verschmutzungsgrad einzustellen. Eine Überdosierung birgt die Gefahr von Schädigungen des Materials bzw. des Gewebes. Aus dem US-Patent 6,376,444 sind ein Handgerät zur Fleckenbehandlung und ein mit diesem durchführbares Verfahren bekannt. Das Handgerät weist einen Vorratsbehälter mit einem Reinigungsmittel auf, der an einem Ende eines Griffkörpers angeordnet ist. Das andere Ende des Griffkörpers weist einen Schallkopf auf, der Schallwellen auf zu behan- delnde Flecken einer Textilie appliziert. Auch hier bleibt es der Erfahrung und der Sensibilität des Anwenders überlassen, die Behandlungsintensität und die Behandlungsdauer so zu wählen, dass einerseits der oder die Flecken ausreichend entfernt werden und andererseits eine Schädigung des behandelten Textilbereichs durch die Applikation der Schallwellen bzw. der Schwingungen des Schallkopfes vermieden ist. US Pat. No. 6,886,371 discloses a washing machine with an additional hand-operated cleaning device for the local treatment of particularly stubborn soiling with an ultrasound head. A cleaning agent applied to the material area to be treated locally is brought to effect particularly effectively by oscillatory movements of the ultrasound head. However, it is up to the user's experience and discretion to adjust the dosage and intensity of the ultrasonic waves on the one hand with regard to the (polluted) material to be treated and on the other hand with regard to the type of stain or the degree of staining. An overdose involves the risk of damage to the material or the tissue. US Pat. No. 6,376,444 discloses a hand-held device for stain treatment and a method practicable therewith. The handset has a reservoir with a cleaning agent disposed at one end of a handle body. The other end of the grip body has a transducer which applies sound waves to spots of a textile to be treated. Again, it is up to the experience and sensitivity of the user to choose the treatment intensity and treatment time so that on the one hand or the stains are sufficiently removed and on the other hand avoid damage to the treated textile area by the application of sound waves or the vibrations of the transducer is.
Vor diesem Hintergrund besteht eine Aufgabe der vorliegenden Erfindung in der Bereitstellung eines Handgeräts zur Fleckenbehandlung auf Materialien, beispielsweise Textilien oder Wäsche, das hinsichtlich der Ressourcen (Energiebedarf und Behandlungsmittel) besonders effektiv und optimiert arbeitet und zugleich die Gefahr von Schädigungen des behandelten Materials vermindert. Against this background, an object of the present invention is to provide a hand-held device for stain treatment on materials, such as textiles or laundry, which is particularly effective and optimized in terms of resources (energy requirements and treatment means) and at the same time reduces the risk of damage to the treated material.
Diese Aufgabe wird erfindungsgemäß gelöst durch ein Handgerät mit den Merkmalen des unabhängigen Patentanspruchs. Bevorzugte Ausführungsformen der Erfindung sind in den abhängigen Patentansprüchen aufgeführt oder ergeben sich aus der nachfolgenden Beschreibung und den Figuren der beigefügten Zeichnung, wobei einzelne dort offenbarte Elemente allein oder in Verbindungen untereinander angewendet werden können. This object is achieved by a handset with the features of the independent claim. Preferred embodiments of the invention are set forth in the dependent claims or will become apparent from the following description and the figures of the accompanying drawing, wherein individual elements disclosed therein may be applied alone or in conjunction with each other.
Demgemäß weist ein erfindungsgemäßes Handgerät zur Behandlung von Flecken auf Materialien eine Steuerung, einen Schallkopf und ein Spektroskop auf. Das Spektroskop ist so ausgestaltet, dass es für eine spektroskopische Bestimmung der Art des fleckenbehafteten Materials und/oder der Art des zu behandelnden Flecks und/oder des Grades der Verschmutzung ausgebildet ist. Das Spektroskop wird dazu in definiertem (beispielsweise durch einen Abstandshalter vorgegebenem) Abstand oder nahezu direkt auf das (Trä- ger)Material und/oder den Fleck gerichtet und führt eine spektroskopische Analyse (Spek- troskopie) durch. Unter Spektroskopie ist in bekannter und daher hier nicht im Einzelnen dargestellter Weise die physikalische Methode zu verstehen, eine Strahlung nach bestimmten Eigenschaften, hier insbesondere nach der Wellenlänge, zu zerlegen. Die dabei zu beobachtende Intensitätsverteilung wird auch Spektrum genannt und ist für ver- schiedene Stoffe - also auch für die Zusammensetzung von verschiedenen Flecken bzw. die Art oder Gattung des Trägermaterials - charakteristisch, zumindest hinweisgebend. Accordingly, a handheld device for treating stains on materials in accordance with the present invention includes a controller, a transducer, and a spectroscope. The spectroscope is designed so that it is designed for a spectroscopic determination of the type of stained material and / or the type of spot to be treated and / or the degree of contamination. For this purpose, the spectroscope is aimed at a defined distance (for example, predetermined by a spacer) or almost directly at the (carrier) material and / or the spot and performs a spectroscopic analysis (spectroscopy). Spectroscopy is understood in a known and therefore not shown here in detail as the physical method to disperse a radiation according to certain properties, in particular according to the wavelength. The intensity distribution observed here is also called the spectrum and is different substances - thus also for the composition of different spots or the type or type of the carrier material - characteristic, at least indicative.
Die von dem Spektroskop gelieferten und üblicherweise in elektrische Signale umgesetzten Informationen können mit Referenzinformationen verglichen werden, die in der Steue- rung des Handgerätes abgelegt sind, dazu kann die Steuerung eine Auswerteeinheit mit einem Datenspeicher umfassen. Dadurch lässt sich zumindest grob die Kategorie oder Charakteristik des jeweils zu behandelnden Fleckens bestimmen. The information supplied by the spectroscope and usually converted into electrical signals can be compared with reference information stored in the controller of the handheld device, for this purpose the controller can comprise an evaluation unit with a data memory. This can at least roughly determine the category or characteristic of the patch to be treated.
Das Spektrometer umfasst mindestens eine Strahlungsquelle, die Strahlung in einem vor- gegebenen Wellenlängenbereich emittiert, die auf das Material bzw. den zu behandelnden Fleck trifft. Mindestens ein Strahlungsdetektor registriert die von dem Material bzw. dem Fleck reflektierte Strahlung als ein (weiterzuverarbeitendes) Messsignal, das dann an die Steuerung (z.B. einen Mikrocomputer) übermittelt und dort in an sich bekannter Weise mit einer im Mikrocomputer hinterlegten Auswerteroutine weiterverarbeitet wird. The spectrometer comprises at least one radiation source which emits radiation in a predetermined wavelength range which strikes the material or the spot to be treated. At least one radiation detector registers the radiation reflected by the material or the spot as a measurement signal (to be further processed), which is then transmitted to the controller (for example a microcomputer) and further processed therein in a manner known per se with an evaluation routine stored in the microcomputer.
Bevorzugt können Kalibrationsspektren für unterschiedliche Materialien, Behandlungsmittel und Standardverschmutzungen bzw. Standardflecken (z.B. Blutflecken, Weinflecken u.a.) in der Auswerteeinheit hinterlegt sein, hierbei besonders bevorzugt auch Materialien, die mit unterschiedlichen Mengen an mindestens einem Behandlungsmittel oder minde- stens einer Standardverschmutzung beaufschlagt sind. Preferably, calibration spectra for different materials, treatment agents and standard or standard stains (for example blood stains, wine stains and the like) can be deposited in the evaluation unit, more preferably also materials which are exposed to different amounts of at least one treatment agent or at least one standard stain.
Weiter bevorzugt kann der Anwender bei bekanntem Material und/oder Fleckenart und Verschmutzungsgrad eine (zusätzliche) bedarfsweise Kalibrierung vornehmen. Das Handgerät weist zur Behandlung des Fleckens einen Schallkopf auf. Unter Schallkopf ist im Rahmen der vorliegenden Erfindung ein mit vergleichsweise hoher Frequenz, vorzugsweise im Ultraschall-Frequenzbereich, in Schwingungen versetzbares Element zu verstehen, das in an sich bekannter Weise (siehe z.B. US-Patente 6,376,444 und 6,886,371 ) von einem Schwingungsgenerator gelieferte Schwingungsenergie in das zu behandelnde Material und/oder den zu entfernenden Fleck einbringt und so die lokale Reinigung bzw. Fleckenbeseitigung bewirkt bzw. unterstützt. More preferably, the user can make a (additional) as needed calibration with known material and / or stain type and degree of contamination. The handset has a transducer for treating the patch. For the purposes of the present invention, a transducer is a component which can be set into motion at comparatively high frequency, preferably in the ultrasound frequency range, and which is vibrationally supplied by a vibration generator to the sensor in a manner known per se (see, for example, US patents 6,376,444 and 6,886,371) to be treated material and / or the stain to be removed and so causes the local cleaning or stain removal or supported.
Ein besonderer Aspekt der Erfindung besteht darin, dass die Steuerung den oder die Betriebsparameter des Schallkopfes, insbesondere die Amplitude und/oder die Frequenz und/oder die Applikationsdauer des Schallkopfes, in Abhängigkeit von der spektroskopischen Analyse, also der Bestimmung der Art des flecken behafteten Materials und/oder der Fleckenart und/oder des Verschmutzungsgrades vorgibt, so dass der Anwender dementsprechend den Reinigungsvorgang ausführt. Bevorzugt und komfortabel ist es, wenn die Steuerung die Betriebsparameter unmittelbar einstellt. So kann die Steuerung bei besonders empfindlichen flecken behafteten Materialien, wie z.B. Seide, die mechanische Beanspruchung des Materials minimieren, d.h. beispielsweise den Schallkopf mit höherer Amplitude, aber geringerer Applikationsdauer betreiben. Eine für die Handhabung bevorzugte Ausgestaltung der Erfindung sieht vor, dass das Handgerät einen Gerätekörper aufweist, an dessen einem Ende der Schallkopf und an dessen anderem Ende das Spektroskop angeordnet ist. A particular aspect of the invention is that the controller or the Operating parameters of the transducer, in particular the amplitude and / or the frequency and / or the application time of the transducer, depending on the spectroscopic analysis, ie the determination of the nature of the stained material and / or the speckle type and / or the degree of contamination pretends, so that the user accordingly performs the cleaning process. It is preferable and convenient if the controller sets the operating parameters directly. Thus, in the case of particularly sensitive staining materials such as silk, the control can minimize the mechanical stress on the material, ie, for example, operate the transducer with a higher amplitude but a shorter application duration. A preferred embodiment of the invention for handling provides that the handset has a device body, at one end of the transducer and at the other end of the spectroscope is arranged.
Eine besonders komfortable Fleckenbehandlung ist dadurch realisierbar, dass das Hand- gerät eine Vorrats- und Dosiereinrichtung für Behandlungsmittel aufweist. A particularly convenient stain treatment can be realized in that the handset has a storage and metering device for treatment agent.
Der Begriff „Behandlungsmittel" ist breit auszulegen und umfasst jede Zubereitung, welche geeignet ist, ein Behandlungsergebnis an zu behandelnden Gegenständen bzw. Materialien herbeizuführen, wie z.B. Wasch- oder Reinigungsmittel. The term "treating agent" is to be construed broadly and includes any preparation which is capable of inducing a treatment result on articles or materials to be treated, such as detergents or cleaning agents.
Besonders bevorzugt sind in dem Handgerät verschiedene Behandlungsmittel bevorratet und/oder dem Handgerät zuführbar, so dass nach einer vorteilhaften Ausgestaltung der Erfindung die Steuerung in Abhängigkeit von der spektroskopischen Analyse zu applizierende (es können mehrere Komponenten sein) Behandlungsmittel auswählt und/oder dosiert. Particularly preferably, different treatment agents are stored in the hand-held device and / or supplied to the handset, so that according to an advantageous embodiment of the invention, the control depending on the spectroscopic analysis to be applied (it may be more than one component) treatment agent selects and / or dosed.
Insbesondere bei empfindlichen Trägermaterialien oder besonders hartnäckigen Flecken ist es von besonderem Vorteil, die Erfindung derart auszugestalten, dass das Spektroskop das Auflöseverhalten des zu behandelnden Flecks analysiert bzw. bestimmt und die Steu- erung in Abhängigkeit des Auflöseverhaltens des Flecks verschiedene Behandlungsmittel appliziert. Dazu kann der zu entfernende Fleck besonders bevorzugt vorab analysiert und vorbehandelt werden, verbunden mit einer Empfehlung für eine weitere Behandlung (beispielsweise in einem nachfolgenden Waschgang eines anschließenden Waschprozes- ses). Das Handgerät kann mit mehreren Vorratsbehältern mit verschiedenen Behandlungsmitteln verbunden sein oder die Vorratsbehälter integral aufweisen, in denen beispielsweise Tenside, Enzyme oder Bleichmittel oder Mischungen und Kompositionen fleck- und textildifferenzierter Reinigungs- und Lösemittel bevorratet sind. Die Dosierung kann grundsätzlich manuell oder bevorzugt automatisch, in einfachster Ausführung kontinuierlich über die Applikationszeit des Schallkopfes, erfolgen. Besonders bevorzugt bei einem aus komplexen Bestandteilen bestehenden zu entfernenden Fleck können in Kenntnis des (zeitlichen) Auflöseverhaltens des Flecks verschiedene Behandlungsmittel (beispielsweise Enzyme) entsprechend zeitlich versetzt dosiert und appliziert werden. Particularly in the case of sensitive carrier materials or particularly stubborn stains, it is of particular advantage to design the invention in such a way that the spectroscope analyzes or determines the dissolving behavior of the stain to be treated and the control system applies different treatment agents depending on the dissolving behavior of the stain. For this purpose, the stain to be removed can be particularly preferably analyzed and pretreated in advance, combined with a recommendation for a further treatment (for example in a subsequent wash cycle of a subsequent washing process). ses). The hand-held device can be connected to a plurality of storage containers with different treatment agents or can have the storage containers integrally in which, for example, surfactants, enzymes or bleaches or mixtures and compositions of stain- and textile-differentiated cleaning agents and solvents are stored. The dosage can be done manually or preferably automatically, in the simplest version continuously over the application time of the transducer. With particular preference in the case of a patch consisting of complex constituents, with knowledge of the (temporal) dissolution behavior of the stain, different treatment agents (for example enzymes) can be metered and applied correspondingly with a time offset.
Dies sei am Beispiel eines Flecks aus Eidotter verdeutlicht: Hier könnten zunächst Enzyme zur besonders effektiven Auflösung des Eidotters und anschließend weitere, hinsichtlich der Auflösung der Eiweißkomponenten optimal wirkende Enzyme zugeführt werden. This is illustrated by the example of a stain of egg yolk: Here, enzymes for the particularly effective dissolution of the egg yolk and then further, with regard to the resolution of the protein components optimally acting enzymes could be supplied.
Grundsätzlich kann die spektroskopische Analyse im Rahmen der Erfindung bereits ausreichend sein, wenn eine kursorische oder funktionale Fleckengruppe ermittelt wird (beispielsweise Proteine, Fett, Pigmente), indem deren spezifische Spektren analysiert und nutzbar gemacht werden. Dazu können deren Spektren wie beschrieben in der Steuerung als Referenzwerte gespeichert sein, um die vom Spektroskop ermittelten spektralen Verteilungen mit diesen Referenzwerten zu vergleichen und daraus die funktionale Fleckengruppe zu bestimmen. Besonders vorteilhaft ist es, wenn in der Steuereinrichtung und/oder einem externen Server Daten zu dem wellenlängenabhängigen Reflexionsverhalten für Standardverschmutzungen hinterlegt sind, die für die Auswertung und Material- bzw. Fleckzuordnung zu zumindest einer Kategorie herangezogen werden können. Um eine quantitative Auswertung eines Spektrums durchführen zu können, wird ein Spektrum im Allgemeinen auf einen Standard normiert. Auf diese Weise wird ein Abgleich eines aufgenommenen Spektrums mit beispielsweise einem Kalibrationsspektrum möglich; es können auch mehrere aufgenommene Spektren miteinander abgeglichen werden, beispielsweise um die Abnahme einer bestimmten Menge einer Substanz zu verfolgen. In principle, the spectroscopic analysis in the context of the invention may already be sufficient if a cursory or functional stain group is determined (for example proteins, fat, pigments) by analyzing their specific spectra and making them usable. For this purpose, their spectra can be stored in the control as reference values as described, in order to compare the spectral distributions determined by the spectroscope with these reference values and to determine therefrom the functional speckle group. It is particularly advantageous if data for the wavelength-dependent reflection behavior for standard contaminants are stored in the control device and / or an external server, which data can be used for the evaluation and material or spot assignment to at least one category. In order to perform a quantitative evaluation of a spectrum, a spectrum is generally normalized to a standard. In this way, an adjustment of a recorded spectrum with, for example, a calibration spectrum is possible; it is also possible to compare several recorded spectra with each other, for example, to track the decrease in a particular amount of a substance.
Der Anwender kann auch eine Vorabmessung bzw. eine Bestimmung des (Träger-)Mate- rials durchführen. So würde sich z.B. bei einem schon älteren und angegrauten weißen Baumwoll-Trägermaterial eine im Wesentlichen systematische Verschiebung des Spek- trums im Vergleich zu dem Spektrum eines fabrikneuen Baumwoll-Trägermaterials ergeben, die aber quasi als Offset grundsätzlich herausfilterbar ist. The user can also carry out a preliminary measurement or a determination of the (carrier) material. So, for example, In the case of an already older and graying white cotton carrier material, a substantially systematic displacement of the spectrum compared to the spectrum of a brand-new cotton carrier material results, which, however, can basically be filtered out as an offset.
Die Erfindung stellt ein Handgerät zur gezielten Fleckenbehandlung unter optimiertem Einsatz von Mechanik, Behandlungszeit und Behandlungsmitteln in Abhängigkeit der zu behandelnden Textil- und Fleckenart bereit. Durch die fleckenspezifische Beaufschlagung wird der Energiebedarf des Schallkopfs minimiert, was bei einem batteriebetriebenen Handgerät zu einer für den Anwender wünschenswerten längeren Batteriestandzeit führt. The invention provides a handheld device for targeted stain treatment with optimized use of mechanics, treatment time and treatment agents depending on the type of textile and stains to be treated. The spot-specific application of the energy consumption of the transducer is minimized, resulting in a battery-powered handset to a desirable for the user longer battery life.
Die Erfindung wird nachfolgend anhand in der beigefügten Zeichnung dargestellter Aus- führungsbeispiele weiter erläutert. Es zeigen: The invention will be explained in more detail below with reference to exemplary embodiments illustrated in the attached drawing. Show it:
Figur 1 schematisch eine Ausgestaltung eines Handgeräts, FIG. 1 shows schematically an embodiment of a hand-held device,
Figur 2 eine Ausführungsvariante des Handgeräts aus Figur 1 ,  FIG. 2 shows an embodiment variant of the hand-held device from FIG. 1,
Figur 3 die Behandlung eines Fleckens mit dem Handgerät aus Figur 1 , Figur 4 Referenzspektren fleckenverursachender Medien und  Figure 3 shows the treatment of a patch with the handset of Figure 1, Figure 4 reference spectra stain-causing media and
Figur 5 in dreidimensionaler Darstellung spektrale Verteilungen fleckenbildender Medien.  FIG. 5 is a three-dimensional representation of spectral distributions of stain-forming media.
Figur 1 zeigt ein Handgerät 1 zur Behandlung eines Flecks 2, der sich auf einem Träger- material, beispielsweise einem Wäschestück 3, befindet. Das Handgerät 1 weist einen Gerätekörper 4 auf, in dessen einem Endbereich 6 ein Spektroskop 8 angeordnet ist. Das Spektroskop 8 umfasst eine nicht näher gezeigte Strahlungsquelle 8a und einen nicht im Einzelnen dargestellten Detektor 8b, der von dem Fleck 2 ausgehende reflektierte Strahlung 9 hinsichtlich der jeweiligen Wellenlängen spektral analysiert. Der Detektor generiert aufgrund der auftreffenden Strahlung 9 zur Weiterverarbeitung in einer Steuerung 10 des Handgeräts 1 geeignete elektrische, durch einen Pfeil symbolisierte Ausgangssignale 1 1 , die beispielsweise in digitaler Form das aufgenommene Spektrum des Flecks 2 repräsentieren. In der in Figur 1 gezeigten Orientierung des Handgerätes 1 befindet sich in Richtung der Längsachse gesehen am anderen Endbereich 12 ein Schallkopf 15, der in an sich bekannter Weise an der Spitze 16 ein durch einen Schwingungsgenerator 17 zu Schwingungen anregbares Element 18 aufweist. Die Schwingungsfrequenz, die vorzugsweise im Ultraschallbereich liegt, aber auch im hörbaren Schallbereich liegen kann, die Schwingungsamplitude und/oder die Betriebsdauer (Applikationsdauer) sind durch Pfeile symbolisierte, variable Betriebsparameter 19. Die Steuerung 10 kann - wie in diesem Ausführungsbeispiel illustriert - den Generator 17 direkt mit diesen Betriebsparametern beaufschlagen. Die Betriebsparameter können zusätzlich oder alternativ dem Anwender auf einem Display 20 angezeigt werden, so dass dieser die Fleckbehandlung gemäß den angezeigten Vorgaben ausführen kann. FIG. 1 shows a hand-held device 1 for treating a spot 2 which is located on a carrier material, for example a laundry item 3. The handset 1 has a device body 4, in whose one end region 6 a spectroscope 8 is arranged. The spectroscope 8 comprises a radiation source 8a, not shown in further detail, and a detector 8b, not shown in detail, which spectrally analyzes the reflected radiation 9 emanating from the spot 2 with respect to the respective wavelengths. The detector generates due to the incident radiation 9 for further processing in a controller 10 of the handset 1 suitable electrical, symbolized by an arrow output signals 1 1, representing, for example, in digital form the recorded spectrum of the spot 2. In the orientation of the hand-held device 1 shown in FIG. 1, viewed in the direction of the longitudinal axis, at the other end region 12 is a transducer 15 which, in a manner known per se, has an element 18 which can be excited to vibrate by a vibration generator 17 at the tip 16. The oscillation frequency, which is preferably in the ultrasound range, but can also be in the audible sound range, the oscillation amplitude and / or the operating time (application time) are symbolized by arrows, variable operating parameters 19. The controller 10 may - as illustrated in this embodiment - the generator 17th apply directly to these operating parameters. The operating parameters may additionally or alternatively be displayed to the user on a display 20 so that the latter can execute the spot treatment in accordance with the displayed indications.
Figur 2 zeigt eine Ausgestaltung des Handgeräts 1 , bei der eine Förder- und Dosiereinrichtung 21 (nachfolgend nur als Dosiereinrichtung bezeichnet) vorgesehen ist, die in einer vorzugsweise auswechselbaren Patrone 22 enthaltenes Behandlungsmittel 23 über eine Leitung 24 in den Bereich der Spitze 16 und damit des (nur in Figur 1 gezeigten) schwingenden Elements 18 des Schallkopfes fördert. Die Patrone 22 kann vorzugsweise in eine von einem Deckel 26 verschließbare Aufnahme 28 eingesetzt werden. Vorzugsweise sind mehrere Patronen derselben Art in entsprechend mehrere Aufnahmen einge- bracht, wobei die Dosiereinrichtung 21 wie durch mehrere Zuleitungen 29 angedeutet mit den jeweiligen Patronen in selektiver Fließverbindung steht. Dadurch kann die Dosiereinrichtung 21 - gesteuert durch die Steuerung 10 - bedarfsweise verschiedene, in den einzelnen Patronen enthaltene Behandlungsmittel 23 - z.B. Lösungsmittel, Enzyme oder Bleichmittel - zur jeweils erforderlichen Behandlung des Flecks 2 (Figur 1 ) auswählen und applizieren. Figure 2 shows an embodiment of the handset 1, in which a conveying and metering device 21 (hereinafter referred to as metering device) is provided, which contained in a preferably replaceable cartridge 22 treatment agent 23 via a line 24 in the region of the tip 16 and thus of the (only shown in Figure 1) vibrating element 18 of the transducer promotes. The cartridge 22 may preferably be inserted into a receptacle 28 which can be closed by a cover 26. Preferably, a plurality of cartridges of the same kind are introduced into a corresponding number of receptacles, wherein the metering device 21 is in selective flow communication with the respective cartridges, as indicated by a plurality of supply lines 29. Thereby, the metering device 21 - controlled by the controller 10 - as needed different, contained in the individual cartridges treatment means 23 - e.g. Solvents, enzymes or bleach - for each required treatment of the spot 2 (Figure 1) select and apply.
In Figur 3 ist zur weiteren Verdeutlichung der Behandlung des Flecks 2 nur der Endbereich 12 des Handgeräts dargestellt; das Handgerät 1 ist also gegenüber der in Figur 1 dargestellten Situation um 180 Grad gedreht. Tropfen 34 eines Behandlungsmittels 36, das wie im Zusammenhang mit Figur 2 beschrieben aus einer entsprechenden Patrone ausgewählt und durch die Dosiereinrichtung über die Leitung 24 in den Endbereich 12 zum schwingenden Element 18 gefördert wird, werden dort auf den Fleck 2 appliziert und anschließend bzw. gleichzeitig durch den Schallkopf 15 mittels Schallwellenenergie mechanisch in Wirkung mit dem Fleck 2 gebracht. In Figure 3, only the end portion 12 of the handset is shown to further illustrate the treatment of the spot 2; the handset 1 is thus rotated 180 degrees with respect to the situation illustrated in FIG. Drops 34 of a treatment agent 36 which, as described in connection with FIG. 2, are selected from a corresponding cartridge and conveyed through the metering device via the line 24 into the end region 12 to the oscillating element 18 are applied there to the spot 2 and subsequently or simultaneously through the transducer 15 by means of sound wave energy mechanically brought into effect with the spot 2.
Dabei wählt die Steuerung 10 abhängig von vom Spektroskop 8 gelieferten Ausgangssignalen 1 1 (Informationen über die Art und gegebenenfalls den Intensitätsgrad des Flecks 2 bzw. des Trägermaterials (Wäschestück 3)) das am besten geeignete Behandlungsmittel 23 aus und steuert dementsprechend die Dosiereinrichtung 21 hinsichtlich Dosierung, Zuführungszeitpunkt und Zuführungsdauer. Diese Steuerdaten sind dadurch bereitgestellt bzw. ausgewählt (beispielsweise aus einer in der Steuerung 10 hinterlegten Referenzdatenbank), indem vorab entsprechende Spektralanalysen von typischen fleckenverursachenden Medien aufgenommen werden, so dass durch Vergleich des Spektrums des Flecks 2 dieser Fleck zumindest einer Fleckenklasse oder einer spezifizierten Fleckenart zugeordnet werden kann. Zusätzlich oder alternativ können von dem Spektroskop auch Informationen über das Trägermaterial (Wäschestück 3) repräsentierende Ausgangssignale 1 1 geliefert werden, indem eine Spektralanalyse des Wäschestücks 3 erfolgt und die dabei gewonnenen Spektralwerte mit in der Steuerung 10 abgelegten Referenzwerten von typischen Trägermaterialien verglichen werden. In this case, the controller 10 selects the most suitable treatment agent 23 as a function of output signals 1 1 supplied by the spectroscope 8 (information about the type and optionally the intensity level of the spot 2 or of the carrier material (item 3)) and accordingly controls the metering device 21 with regard to metering , Delivery time and delivery time. This control data is thereby provided or selected (for example, from a reference database stored in the controller 10) by taking appropriate spectral analyzes of typical staining media in advance, such that by comparing the spectrum of the stain 2, that stain is associated with at least one stain class or speckle type can be. Additionally or alternatively, information about the carrier material (laundry item 3) representing output signals 1 1 can be supplied by the spectroscope by a spectral analysis of the laundry 3 takes place and the spectral values obtained are compared with stored in the controller 10 reference values of typical carrier materials.
Für besonders hartnäckige oder komplexe Flecken kann mit Hilfe des Spektroskops 8 die Fleckauflösecharakteristik bzw. das Auflöseverhalten des Flecks bestimmt und bedarfsweise auch gespeichert werden. Dazu kann beispielsweise die Referenzierung des Flecks (beispielsweise als aus Eigelb und Eiweiß bestehender Fleck) dienen. Das Auflöseverhalten des zu behandelnden Flecks kann aber auch durch mehrfache spektroskopische Analysen während des Reinigungs- bzw. Behandlungsprozesses erfolgen. Dazu ist eine Gestaltung des Handgeräts dahingehend denkbar, dass sowohl der Schallkopf als auch das Spektroskop so angeordnet sind, dass sie gleichzeitig den Fleck behandeln bzw. spektroskopisch untersuchen können. Dabei kann die Steuerung 10 verschiedene Behandlungsmittel - beispielsweise ein erstes Enzym aus einer ersten Patrone 22 (Figur 2), das hinsichtlich der Lösung von Eigelb optimiert ist, und anschließend ein anderes Enzym aus einer anderen Patrone 22, das hinsichtlich der Lösung von Eiweiß optimiert ist - in Abhängigkeit des Auflöseverhaltens applizieren. For particularly stubborn or complex stains, the stain resolution characteristic or the dissolving behavior of the stain can be determined with the aid of the spectroscope 8 and, if necessary, also stored. For this purpose, for example, the referencing of the stain can serve (for example, as an egg yolk and protein existing stain). The dissolution behavior of the spot to be treated can also be achieved by multiple spectroscopic analyzes during the cleaning or treatment process. For this purpose, a design of the hand-held device is conceivable in that both the transducer and the spectroscope are arranged so that they can simultaneously treat the spot or investigate it spectroscopically. In this case, the controller 10 different treatment agents - for example, a first enzyme from a first cartridge 22 (Figure 2), which is optimized in terms of the solution of egg yolk, and then another enzyme from another cartridge 22, which is optimized in terms of the solution of protein - Apply depending on the dissolving behavior.
Der Nutzer kann in der zuvor beschriebenen Weise bevorzugt vorab das Material oder zumindest die Materialklasse des - unbeschmutzten - Trägermaterials bestimmen, indem er einen normalen, das heißt unbefleckten Bereich des Materials spektroskopisch von dem Handgerät analysieren lässt. In diesem Fall vergleicht das Handgerät das aufgenommene Spektrum des Materials wie vorstehend im Zusammenhang mit dem Fleck 2 beschrieben mit zuvor aufgenommenen oder in einer Datenbank gespeicherten und ggf. abrufbaren Referenzspektren. Zur weiteren Verdeutlichung der beschriebenen Referenzierung typischer fleckbildender Stoffe sind in Figur 4 schematisch beispielhaft die charakteristischen spektralen Verläufe von Blut, Kakao, Rotwein, Ruß und Sebum gezeigt. In dem Diagramm ist die so genannte Extinktion (entsprechend der Absorption) in so genannter Standard Norm Variante (SNV) über der Wellenlänge aufgetragen. Die Standard Norm Variante ist eine Normierungsme- thode zur Berücksichtigung des Messabstands des Spektrometers; die Kurven würden sich in Abhängigkeit vom Messabstand bei im Wesentlichen unverändertem charakteristischen Kurvenverlauf vertikal verschieben. Im vorliegenden Beispiel wurde als Referenzspektrum 100% von sauberem Bauwollmaterial (z.B. einem T-Shirt) reflektierte Strahlung zugrunde gelegt („referenced on clean cotton). Die Kurven wurden zudem mit einem geeigneten Algorithmus oder Filter - hier dem sog. Savitzky-Golay-Filter 3-1 1 ) gefiltert bzw. damit geglättet. 3-1 1 bedeutet hierbei die Verwendung eines Polynoms 3. Grades mit einem gleitenden Fenster, das zur Glättung 5 Messpunkte vor und 5 Messpunkte nach dem betrachteten Wert heranzieht. Absorptionswerte über„0" bezeichnen eine besonders starke Dämpfung des reflektierten Lichts in der jeweiligen Wellenlänge, für Blut erkennt man z.B. ein Wellenberg (Maximum) der einzelnen Messkurven bei etwa 1730 nm Wellenlänge, während ein Wellental (Minimum) - d.h. also relativ starke Reflexion - bei Licht der Wellenlänge 1650 nm zu beobachten ist. So erhält man mit diesem Referenzspektrum quasi einen„Fingerabdruck" für Blut und in entsprechender Weise - mit anderen markanten Maxima bzw. Minima - Spektren für die anderen fleckbildenden Stoffe. Aufgrund der charakteristischen Verläufe ordnet die Steuerung den konkreten aktuell zu behandelnden Fleck einer Fleckart oder Fleckklasse zu und stellt demgemäß wie zuvor beschrieben den Einsatz des jeweils verwendeten Behandlungsmittels bzw. die Art und Dauer der Betriebsparameter des Schallkopfes ein. Die dafür erforderlichen Ansteuerungsgrößen können zuvor durch entsprechende Versuche mit den jeweiligen Fleckenarten ermittelt werden. In the manner described above, the user can preferably determine in advance the material or at least the material class of the unsupported carrier material by spectroscopically measuring a normal, that is to say imperfect, region of the material to analyze the handset. In this case, the handset compares the recorded spectrum of the material as described above in connection with the spot 2 with previously recorded or stored in a database and possibly retrievable reference spectra. To further illustrate the described referencing of typical stain-forming substances, the characteristic spectral courses of blood, cocoa, red wine, soot and sebum are shown schematically in FIG. 4 by way of example. In the diagram, the so-called extinction (according to the absorption) in so-called standard norm variant (SNV) is plotted against the wavelength. The standard standard variant is a standardization method for taking into account the measuring distance of the spectrometer; the curves would shift vertically depending on the measuring distance with essentially unchanged characteristic curve course. In the present example the reference spectrum was 100% of clean cotton material (eg a T-shirt) based on reflected radiation ("referenced on clean cotton"). The curves were also filtered or smoothed with a suitable algorithm or filter - here the so-called Savitzky-Golay filter 3-1 1). In this case, 3-1 1 means the use of a 3rd order polynomial with a sliding window that uses 5 measuring points before and 5 measuring points after the value considered for smoothing. Absorption values above "0" indicate a particularly strong attenuation of the reflected light in the respective wavelength, for blood one recognizes, for example, a wave peak (maximum) of the individual measurement curves at approximately 1730 nm wavelength, while a wave trough (minimum) - ie, relatively strong reflection - In the case of light with a wavelength of 1650 nm, one obtains with this reference spectrum a kind of "fingerprint" for blood and in the same way - with other striking maxima or minima spectra for the other stain - forming substances. Due to the characteristic courses, the controller assigns the specific spot currently to be treated to a spot type or spot class and accordingly sets the use of the treatment agent used or the type and duration of the operating parameters of the transducer, as described above. The required control variables can be determined beforehand by appropriate tests with the respective types of stains.
In entsprechender Weise sind hier nicht näher gezeigte Referenzspektren für (Trä- ger)Materialien wie z.B. Seide, Baumwolle usw. aufgenommen und gespeichert, so dass der Anwender durch spektroskopische Untersuchung eine Zuordnung des Trägermaterials zu einer Materialklasse erhält und damit die Intensität, Dauer usw. der Schwingkopfapplikation und Behandlung bestimmt wird. Figur 5 zeigt in dreidimensionaler Darstellung die einschlägigen Referenzwerte für die schon in Figur 4 beschriebenen Spektren typischer fleckenbildender Materialien, nämlich Blut, Kakao, Rotwein, Ruß und Sebum, nach sogenannter Multivarianter Analyse. Diese können in der Auswerteeinheit des Handgeräts, aber auch extern in einem z.B. über WLAN verbundenen Speicher oder einer Cloud abgelegt sein. In a corresponding manner, reference spectra (not shown here) for ger) materials such as silk, cotton, etc. recorded and stored, so that the user receives a classification of the carrier material to a class of material by spectroscopic examination and thus the intensity, duration, etc. of the oscillating head application and treatment is determined. FIG. 5 shows, in a three-dimensional representation, the relevant reference values for the spectra of typical staining materials already described in FIG. 4, namely blood, cocoa, red wine, soot and sebum, according to so-called multi-variant analysis. These can be stored in the evaluation unit of the handheld device, but also externally in a storage connected via WLAN, for example, or a cloud.
Figur 5 zeigt eine 3-Hauptcomponentenanalyse, die bereits für die meisten gängigen fleckbildenden Stoffe fleckcharakteristische Verteilungen der drei Komponenten PC (Principal Components), nämlich PC-1 , PC-2 und PC 3, aufweist. Die prozentualen Angaben der Principal Components (z.B. PC-1 (45%)) bedeuten die Variation des Spektrums und damit die Gewichtung. So weist beispielsweise ein Kakaofleck im Wesentlichen die Koeffizienten (Komponenten) [+4*PC-1 ; -4*PC-2; 0*PC-3] auf. FIG. 5 shows a 3-principal component analysis which already has stain-characteristic distributions of the three components PC (principal components), namely PC-1, PC-2 and PC 3, for most common stain-forming substances. The percentages of the principal components (eg PC-1 (45%)) mean the variation of the spectrum and thus the weighting. For example, a cocoa stain essentially has the coefficients (components) [+4 * PC-1; -4 * PC-2; 0 * PC-3].
Bereits in den dargestellten drei Dimensionen unterscheiden sich die aus verschiedenen Stoffen bestehenden Flecken signifikant, deren Werte quasi einen Raumbereich (Ansammlungsraum der einzelnen aufgenommenen Referenzwerte) definieren. Fällt das Spektrum (nach entsprechender Auswertung) eines aktuell mit dem Handgerät analysierten Flecks bzw. Trägermaterials in einen der Raumbereiche, lässt sich grundsätzlich zuverlässig bestimmen, in welche Fleckkategorie bzw. Materialkategorie der analysierte Stoff fällt und demgemäß der Schwingkopf ansteuern. Man erkennt in Figur 5 allerdings auch, dass die Raumbereiche der Referenzwerte für Sebum und Ruß relativ dicht beieinander bzw. ineinander liegen, so dass hier bevorzugt eine noch genauere Analyse durchgeführt wird (beispielsweise unter Verwendung von multivarianten Analysen höherer Ordnung oder Dimension) und/oder eine grobe Vorauswahl durch den Anwender in die Steuerung des Handgeräts eingebbar ist. BezugszeichenAlready in the illustrated three dimensions, the patches consisting of different substances differ significantly, the values of which virtually define a spatial area (accumulation space of the individual recorded reference values). If the spectrum (after appropriate evaluation) of a spot or carrier material currently being analyzed by the hand-held instrument falls into one of the spatial regions, it is basically possible to reliably determine into which spot category or material category the analyzed substance falls and accordingly control the oscillating head. However, it can also be seen in FIG. 5 that the spatial ranges of the reference values for sebum and soot are relatively close to each other, so that an even more accurate analysis is preferably carried out here (for example using multivariate analyzes of a higher order or dimension) and / or a rough preselection by the user in the control of the handset is entered. reference numeral
1 Handgerät 1 handset
2 Fleck  2 stain
3 Wäschestück  3 pieces of laundry
4 Gerätekörper  4 device body
6 Endbereich  6 end area
8 Spektroskop  8 spectroscope
8a Strahlungsquelle  8a radiation source
8b Detektor  8b detector
9 Strahlung  9 radiation
10 Steuerung  10 control
1 1 Ausgangssignale  1 1 output signals
12 Endbereich  12 end area
15 Schallkopf  15 transducer
16 Spitze  16 tip
17 Generator  17 generator
18 Element  18 element
19 Betriebsparameter  19 operating parameters
20 Display  20 display
21 Förder-/Dosiereinrichtung  21 conveying / metering device
22 Patrone  22 cartridge
23 Behandlungsmittel  23 treatment agents
24 Leitung  24 line
24 Display  24 display
26 Deckel  26 lids
28 Aufnahme  28 recording
30 Zuleitung  30 supply line
34 Tropfen  34 drops
36 Behandlungsmittel  36 treatment agents
PC-1 Komponente (Principal Component) PC-1 component (Principal Component)
PC-2 Komponente (Principal Component)PC-2 component (Principal Component)
PC-3 Komponente (Principal Component) PC-3 component (Principal Component)

Claims

Patentansprüche claims
1 . Handgerät zur Fleckenbehandlung mit 1 . Hand-held device for stain treatment
- einer Steuerung (10),  a controller (10),
- einem Schallkopf (15), der mit wenigstens einem veränderbaren Betriebsparameter (19) betreibbar ist, wobei als Betriebsparameter (19) zumindest die Amplitude und/oder die Frequenz und/oder die Applikationsdauer veränderbar sind, und a transducer (15) which can be operated with at least one variable operating parameter (19), wherein at least the amplitude and / or the frequency and / or the application duration can be changed as the operating parameter (19), and
- einem Spektroskop (8), das für eine spektroskopische Analyse der Art des fleckenbehafteten Materials (3) und/oder der Art und des Flecks (2) und/oder des Intensitätsgrads des Flecks (2) ausgebildet ist, a spectroscope (8) designed for a spectroscopic analysis of the nature of the stained material (3) and / or the nature and spot (2) and / or the intensity of the stain (2),
- wobei die Steuerung (10) des Handgeräts (1 ) den oder die Betriebsparameter (19) in Abhängigkeit von der spektroskopischen Analyse vorgibt oder einstellt.  - Wherein the controller (10) of the handset (1) presets or sets the operating parameters (19) in dependence on the spectroscopic analysis.
2. Handgerät nach Anspruch 1 , 2. Hand device according to claim 1,
- wobei das Handgerät (1 ) einen Gerätekörper (4) aufweist, an dessen einem Endbereich (12) der Schallkopf (15) und an dessen anderem Endbereich (6) das Spektroskop (8) angeordnet sind.  - The handset (1) has a device body (4), at one end region (12) of the transducer (15) and at the other end region (6), the spectroscope (8) are arranged.
3. Handgerät nach Anspruch 1 oder 2, 3. Hand tool according to claim 1 or 2,
- wobei das Handgerät (1 ) eine Vorrats- und Dosiereinrichtung (21 ) für Behandlungsmittel (23) aufweist.  - Wherein the handset (1) has a storage and metering device (21) for treatment agent (23).
4. Handgerät nach Anspruch 3, 4. Hand device according to claim 3,
- wobei die Steuerung (10) in Abhängigkeit von der spektroskopischen Analyse zu applizierendes Behandlungsmittel (23) auswählt und/oder dosiert.  - The controller (10) depending on the spectroscopic analysis to be applied treatment agent (23) selects and / or metered.
5. Handgerät nach wenigstens einem der vorangehenden Ansprüche, 5. Hand device according to at least one of the preceding claims,
wobei das Spektroskop (8) das Auflöseverhalten des zu behandelnden Flecks (2) bestimmt und  wherein the spectroscope (8) determines the dissolution behavior of the spot to be treated (2) and
die Steuerung (10) mehrere verschiedene Behandlungsmittel (23) in Abhängigkeit des Auflöseverhaltens des Flecks (2) appliziert.  the controller (10) applied a plurality of different treatment agents (23) as a function of the dissolving behavior of the spot (2).
PCT/EP2018/072971 2017-09-08 2018-08-27 Handheld device for treating stains WO2019048272A1 (en)

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