WO2019009358A1 - Cooling tool - Google Patents

Cooling tool Download PDF

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Publication number
WO2019009358A1
WO2019009358A1 PCT/JP2018/025510 JP2018025510W WO2019009358A1 WO 2019009358 A1 WO2019009358 A1 WO 2019009358A1 JP 2018025510 W JP2018025510 W JP 2018025510W WO 2019009358 A1 WO2019009358 A1 WO 2019009358A1
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WO
WIPO (PCT)
Prior art keywords
cold
temperature
storage
heat
water
Prior art date
Application number
PCT/JP2018/025510
Other languages
French (fr)
Japanese (ja)
Inventor
輝心 黄
邦広 岡田
夕香 内海
雅子 西橋
勝一 香村
知子 加瀬
哲 本並
大祐 篠崎
恭平 勢造
克也 城戸
山上 真司
中野 雅行
Original Assignee
シャープ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by シャープ株式会社 filed Critical シャープ株式会社
Publication of WO2019009358A1 publication Critical patent/WO2019009358A1/en

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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G23/00Other table equipment
    • A47G23/02Glass or bottle holders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Definitions

  • Some aspects of the invention relate to a cryocooler that controls the temperature of the beverage in the storage container.
  • Priority is claimed on Japanese Patent Application No. 2017-133946, filed July 7, 2017, the content of which is incorporated herein by reference.
  • cryostat that can reach the desired storage temperature more quickly and that can be maintained at the desired temperature for an extended period of time. For example, in the case of wine etc. where the temperature is required to drink, a wine cooler covered with ice water is used to cool the wine bottle.
  • Patent documents 1 and 2 disclose techniques for maintaining wine at an appropriate temperature (temperature range of 5 to 12 ° C.).
  • the wine cooler disclosed in Patent Document 1 and the cold-keeping insulation tool disclosed in Patent Document 2 are for the purpose of cold-cooling at 5 ° C. or higher, and are the beverages taken out from the refrigerator (5 ° C.) The temperature can not be lowered further. Moreover, it does not have a structure which clamps the cold storage object in order to improve the cold storage effect.
  • the one aspect of this invention is made in view of such a situation, and it aims at providing the cold-storage tool which can manage the drink in a storage container to appropriate temperature.
  • the cold-preserving tool is a cold-keeping tool for managing the temperature of the beverage in the storage container, and is filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material is the beverage And a heat exchange unit configured to exchange heat, and a packaging unit surrounding the storage container and the heat exchange unit, wherein the heat storage material has a melting point of 5 ° C. or less and the beverage is frozen It is above the temperature.
  • FIG. 6 is a view showing temperature changes of the storage container in Example 1.
  • Example 2 and Comparative Example 1 It is a figure which shows the temperature change rate of each storage container in Example 2 and Comparative Example 1. It is the figure which put together the temperature change rate of each storage container in Example 2 and Comparative Example 1. It is a figure which shows the temperature change rate of each storage container in Example 1 and Example 2.
  • FIG. It is the figure which put together the temperature change rate of each storage container in Example 1 and Example 2.
  • FIG. It is a figure which shows the temperature change rate of each storage container in Example 1 and Comparative Example 2. It is the figure which put together the temperature change rate of each storage container in Example 1 and Comparative Example 2. It is the figure which put together the temperature change rate of each storage container in Example 2 and Comparative Example 2.
  • the present inventors pay attention to the fact that the temperature control according to the beverage is necessary to avoid the inconvenience caused by freezing too much under the situation where needs for cooling and drinking sake are increasing.
  • a heat storage material having a melting point of 5 ° C. or less and a freezing temperature of the beverage, it has been found that appropriate temperature control can be performed, and the present invention has been achieved.
  • the cold-preserving tool is a cold-preserving tool for managing the temperature of the beverage in the storage container, and is filled with a heat storage material that changes its phase at a predetermined temperature;
  • a heat exchange unit configured to exchange heat with a beverage, and a packaging unit surrounding the storage container and the heat exchange unit, wherein the heat storage material has a melting point of 5 ° C. or less It is above freezing temperature.
  • FIG. 1A is a diagram showing an outline of a cold insulator according to the present embodiment.
  • FIG. 1B is a developed view of a side surface portion of the cold insulator according to the present embodiment.
  • the bottom of the heat exchange portion and the bottom surface as a closed surface of the cold storage tool is not shown, the heat exchange portion will be described later, and the bottom is formed in a substantially circular shape of the same material as the packaging material.
  • the cold-storage tool 1 which concerns on this embodiment is formed cylindrically by winding so that the packaging material 3 which has a two-dimensional specific shape may overlap by 3a and 3b. This is the side part of the cold insulator 1.
  • the open end of the cold preservation tool 1 has a shape obtained by obliquely cutting a cylinder, and by storing the bottle 5 as a storage container, the bottle 5 is worn with the front body of the kimono together. Can form an attractive appearance.
  • the fixing belt 7 fixes the neck portion of the bottle 5 and stabilizes the position of the bottle 5 inside the cooling tool 1 and prevents the bottle 5 from being detached from the cooling tool 1 when pouring a beverage or the like.
  • the diameter D1 on the bottom surface side of the side surface portion formed by the packaging material 3 is larger than the diameter D2 on the opening end side of the side surface portion.
  • the developed view of the packaging material 3 has a two-dimensional specific shape, and in the developed view, the bottom side which is lower than the paper surface is not a straight line, This is realized because the point P is formed to have an angle of 178 degrees.
  • the cold-keeping tool 1 has a so-called “taper”, the opening end of the cold-keeping tool 1 is prevented from opening when the bottle 5 is stored.
  • the cold storage tool 1 is provided with the fastener 9 which mutually locks the overlapping packaging materials 3a and 3b in the part which the packaging material 3 has overlapped.
  • the packaging material 3 comprises the side part of the cold-storage tool 1, and a side part and the bottom part which is not shown in figure comprise a packaging part.
  • the packaging material 3 by forming the packaging material 3 with a stretchable material, even when the heat storage material is melted and the volume of the heat storage material shrinks, the adhesion to the bottle 5 can be maintained.
  • FIG. 2A is a top view showing an outline of a heat exchange part of the cold preservation tool according to the present embodiment.
  • FIG. 2B is a side view showing an outline of a heat exchange part of the cold storage device according to the present embodiment.
  • the heat exchange part 20 is provided with the six thermal storage material accommodating parts 20a which accommodate the thermal storage material 22, and the five connection parts 20b which connect each thermal storage material accommodating part 20a.
  • the heat storage material 22 is frozen, it is surrounded by the packaging material 3 so as to be in close contact with the bottle 5, thereby making the bottle 5 as a storage container. Contactability is improved.
  • wearing the bottle 5 becomes slimmer, so that the number of thermal storage material accommodating part 20a and the connection part 20b which comprise the heat exchange part 20 increases.
  • six heat-storage material storage parts 20a and five connection parts 20b were shown here, it is not necessarily limited to these numbers.
  • the heat storage material storage unit 20 a has a curved surface portion 20 c at a portion in contact with the bottle 5.
  • the curved surface portion 20c is formed in a concave shape having a radius of curvature of 37 mm.
  • the adhesion to the bottle 5 can be improved.
  • the heat absorptivity from the bottle 5 is improved, and the temperature can be easily lowered.
  • the temperature rise of the drink in the bottle 5 is suppressed because the surface area of the bottle 5 which touches external air becomes small.
  • the radius of curvature is 37 mm, but this is not a limitation.
  • the radius of curvature is preferably in the range of 26.5 mm to 46.00 mm, but it may be a curvature size such as a leboworm size having a capacity six times the normal size (750 ml) of a bottle of sake or champagne good.
  • the rigidity of the curved surface portion 20c may be made higher than the rigidity of the other portions. This makes it possible to suppress deformation of the curved surface portion 20c due to volumetric expansion that occurs when the heat storage material is frozen. Further, each heat storage material storage unit 20 a of the heat exchange unit 20 may be filled with a staining solution. Thereby, even if the heat storage material leaks, it becomes possible to recognize at a glance.
  • FIG. 3 is a schematic view of a cold storage object used in each example and comparative example.
  • An object to be cooled is filled in a bottle 5 with sake (alcohol having a degree of 15 degrees, 720 ml) as a liquid to be cooled.
  • the liquid to be cooled was previously kept cold by a refrigerator (5 ° C.).
  • the ambient temperature is 23 ° C.
  • the following is a table summarizing the configurations of the cold insulators of the respective examples and comparative examples.
  • the filling height when the liquid to be cooled is filled into the storage container is 200 mm from the bottom of the storage container.
  • the temperature measurement point in each Example and the comparative example was (I) liquid center: 100 mm from the bottom, (II) liquid top: 180 mm from the bottom.
  • FIG. 4 is a graph showing the freezing temperature confirmation experiment results of sake.
  • the sake (alcohol degree: 15 ° C.) was frozen when the inside temperature was ⁇ 18 ° C. From this result, the sake used in this experiment may freeze in the freezer (-18 ° C). Therefore, it is necessary to use a latent heat storage material (heat storage material) having a melting point of 5 ° C. or less and higher than ⁇ 18 ° C.
  • the latent heat storage material used in the present embodiment is preferably a latent heat storage material having a melting point of 5 ° C. or less and higher than ⁇ 18 ° C. Furthermore, the melting point of the latent heat storage material is more preferably less than 0 ° C.
  • the latent heat storage material having a temperature of less than 0 ° C. is preferably an aqueous solution of an inorganic salt, and it is more preferable that the concentration of the inorganic salt aqueous solution and the melting point satisfy the relationship of Formula (1).
  • T Melting point (° C)
  • w Concentration of inorganic salt (wt%)
  • M Molecular weight of inorganic salt (g / mol)
  • R Gas constant (J / K ⁇ mol)
  • Tf Melting point of water
  • K ⁇ H: heat of melting of water
  • n number of ions formed when one inorganic salt ionizes in aqueous solution
  • w is less than the concentration giving a eutectic of water and the water-soluble inorganic salt.
  • the latent heat storage material having a desired melting point can be designed simply by changing the concentration of the water-soluble inorganic salt.
  • Formula (1) is established with a dilute aqueous solution having a concentration less than the concentration at which w gives a eutectic with the water-soluble inorganic salt.
  • a eutectic is obtained near the concentration at which w gives a eutectic with the water-soluble inorganic salt.
  • the latent heat is high. Therefore, the cold storage temperature tends to be constant, and long-term cold storage is possible.
  • the inorganic salt sodium chloride, potassium chloride, calcium chloride, magnesium chloride, barium chloride, ammonium chloride, potassium hydrogencarbonate, sodium bicarbonate, sodium carbonate, sodium nitrate, potassium nitrate, calcium nitrate and magnesium nitrate are preferable.
  • concentration of inorganic salt is below the density
  • FIG. 5 is another diagram in which formula (1) is plotted for sodium chloride as an example of the water-soluble inorganic salt.
  • the concentration at which water and sodium chloride give a eutectic is 23.3 wt%
  • FIG. 5 is a diagram in which the region below the concentration giving a eutectic is plotted. If the temperature at which the liquid to be stored is to be stored is determined, high-precision setting of the melting point of the latent heat storage material is required. However, the concentration of inorganic salt can be calculated using FIG. It becomes possible to determine the composition ratio and material of the heat storage material.
  • the melting point of water and sodium chloride is -21 ° C
  • latent heat storage of a desired melting point is achieved by adjusting the concentration of the inorganic salt using formula (1) The material can be obtained.
  • a eutectic concentration of water and inorganic salt a eutectic having a single melting point is obtained.
  • the inorganic salt which comprises a latent heat storage material may be only 1 type among the inorganic salts mentioned above, and what mixed several inorganic salt may be used. By using a latent heat storage material having a melting point of less than 0 ° C., it is possible to cool below the freezing point that can not be realized with ice.
  • Example 1 Packaging Tapered, with fasteners 9. -The temperature for 120 minutes was measured after attaching the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5). The temperature was measured at the liquid center, outside the heat exchange unit 20 (between the packaging material and the container).
  • FIG. 6 is a view showing temperature change of the storage container in the first embodiment.
  • the temperature of the liquid core portion cooled by the refrigerator (5 ° C.) is cooled to below freezing in about 23 minutes.
  • the cryocooler of Example 1 was found to have a cooling performance of freezing below 30 minutes.
  • the temperature of the liquid center part was cooled toward the heat exchange part (cold storage material) temperature, it turned out that it did not freeze even two hours after the cooling start.
  • Temperature change rate (liquid temperature at measurement-initial liquid temperature) / initial liquid temperature ... (2)
  • the temperature change rate of 0 or more means temperature rise, and less than 0 means temperature fall.
  • Example 2 Packaging Tapered, without fasteners 9. -The temperature for 30 minutes was measured after mounting the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5). The temperature was measured at the center of the liquid and at the top of the liquid.
  • Comparative example 1 -Packaging material: No taper, no fastener 9. -The temperature for 30 minutes was measured after mounting the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5). The temperature was measured at the center of the liquid and at the top of the liquid.
  • FIG. 7A is a view showing a temperature change rate of each storage container in Example 2 and Comparative Example 1.
  • FIG. 7B is a diagram summarizing temperature change rates of the respective storage containers in Example 2 and Comparative Example 1.
  • the temperature change rate of Comparative Example 1 was 22% higher than the temperature change rate of Example 2. That is, it can be said that the temperature of the liquid upper portion is 22% higher, and the temperature is easy to rise.
  • Example 1 Packaging material: It was tapered, and there was a fastener (magic tape (registered trademark)). -The temperature for 30 minutes was measured after mounting the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5). The temperature was measured at the center of the liquid and at the top of the liquid.
  • Example 2 -Packaging material: with taper, without fastener-With respect to the storage container (bottle 5), the temperature was measured for 30 minutes after the heat exchange unit 20 and the packaging material 3 were attached. The temperature was measured at the center of the liquid and at the top of the liquid.
  • FIG. 8A is a view showing a temperature change rate of each storage container in Example 1 and Example 2.
  • FIG. 8B is a diagram summarizing temperature change rates of the respective storage containers in Example 1 and Example 2.
  • the temperature change rate of Example 1 is 8% lower than that of Example 2 in the “liquid upper portion”, and is 28% lower than that of Example 2 in the “liquid center portion”. . That is, it was found that the provision of the fastener 9 makes it possible to lower the temperature rise rate in both the liquid upper portion and the liquid center portion, and in particular, it is possible to lower the temperature rise in the liquid center portion.
  • Velcro registered trademark
  • anything may be used as long as the overlapping portion of the packaging material 3 can be locked, and the present invention is not limited to this.
  • Example 1 (Example 1, Example 2) Cover rate: 87.0%
  • the other configurations, the temperature measurement points, and the temperature measurement time are the same as those described above.
  • FIG. 9A is a view showing a temperature change rate of each storage container in Example 1 and Comparative Example 2.
  • FIG. 9B is a diagram summarizing temperature change rates of the respective storage containers in Example 1 and Comparative Example 2. As shown in FIG. 9B, the temperature change rate of the “liquid center” is 14% higher in Comparative Example 2. Further, the temperature change rate of the “liquid upper portion” is also 5% higher in Comparative Example 2. That is, it was found that the cooling performance is improved by increasing the coverage.
  • FIG. 9C is a diagram summarizing temperature change rates of the respective storage containers in Example 2 and Comparative Example 2. As shown in FIG. 9C, when the temperature change rates after 30 minutes in Example 2 and Comparative Example 2 were compared, it was found that Comparative Example 2 had higher cooling performance than Example 2. Therefore, it was found that it is possible to improve the cooling performance if at least the coverage is 79.5% or more.
  • the thermal storage material 22 in order to improve the operativity at the time of filling, it is desirable for the thermal storage material 22 to have thickening property. In this case, it can be realized by mixing the heat storage material 22 with a thickener.
  • storage containers such as bottle 5 etc. which are filled with liquid for cooling, may have a temperature display function in at least one part.
  • a temperature indicator may be applied (printed) on a storage container such as the bottle 5 or the storage container itself may be made of a material containing the temperature indicator. This makes it possible to grasp the temperature of the liquid to be cooled. Furthermore, it is more preferable to discolor or decolor the temperature indicator at 6 ° C. (or refrigeration temperature).
  • a cold-preserving tool is a cold-preserving tool for managing the temperature of a beverage in a storage container, which is filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material is A heat exchange unit configured to exchange heat with a beverage, and a packaging unit surrounding the storage container and the heat exchange unit, wherein the heat storage material has a melting point of 5 ° C. or less It is above freezing temperature.
  • the said packaging part is equipped with the side part formed in cylindrical shape, and the bottom face part couple
  • the diameter on the closed surface side of the side surface portion is larger than the diameter on the opening end side of the side surface portion.
  • the side surface portion is formed in a cylindrical shape by being wound so that a packaging material having a two-dimensional specific shape partially overlaps. There is.
  • the cold-storage tool which concerns on one form of this invention is provided in the part which the said packaging material has overlapped, and is further provided with the fastener which mutually locks the said each packaging material.
  • the heat exchange unit includes a plurality of heat storage material storage units that store the heat storage material, and a connection unit that connects the heat storage material storage units. And contact along the surface of the storage container.
  • each said thermal storage material storage part has a curved surface part which contacts the said storage container and fits the surface of the said storage container.
  • the said heat exchange part coat covers 79.5% or more with respect to the filling height of the said drink in the said storage container.
  • fusing point of the said thermal storage material is less than 0 degreeC.
  • the said thermal storage material contains water and water-soluble inorganic salt, and when melting
  • the heat storage material contains water and a water-soluble inorganic salt, and the concentration by weight of the water-soluble inorganic salt is a concentration giving a eutectic of water and the water-soluble inorganic salt.
  • the said curved-surface part has rigidity higher than the rigidity of parts other than the said curved-surface part.
  • the said heat exchange part is filled with stain
  • Some aspects of the present invention can be applied to, for example, a cold insulator that can control the beverage in the storage container at an appropriate temperature.

Abstract

In order to control a beverage inside a storage container to an appropriate temperature, this cooling tool 1, which controls the temperature of a beverage inside a bottle 5, is provided with a heat exchange portion, which is filled with a heat storage material that undergoes a phase change at a predetermined temperature and which is configured such that the heat storage material exchanges heat with the beverage, and a wrapping portion 3, which surrounds the bottle 5 and the heat exchange portion, wherein the melting point of the heat storage material is equal to or less than 5°C and is equal to or greater than the freezing temperature of the beverage. Furthermore, the wrapping portion 3 comprises a side surface portion formed in a cylindrical shape and a bottom surface portion connected to one end of the side surface portion and forming a closed surface, and the diameter D1 of the closed-surface side of the side surface portion is greater than the diameter D2 of the opening-end side of the side surface portion.

Description

保冷用具Cooler
 本発明のいくつかの態様は、保存容器内の飲料の温度を管理する保冷用具に関する。
 本願は、2017年7月7日に、日本に出願された特願2017-133946に基づき優先権を主張し、その内容をここに援用する。
Some aspects of the invention relate to a cryocooler that controls the temperature of the beverage in the storage container.
Priority is claimed on Japanese Patent Application No. 2017-133946, filed July 7, 2017, the content of which is incorporated herein by reference.
 従来から、保温物、特に、ワイン、ビール、日本酒等のアルコール類、またはジュース、水等の飲料、或いは食品類、更には医薬品類には、それぞれに適した保存温度が存在し、保温物を所望の保管温度に、より素早く到達させ、かつ、所望の温度で長時間維持が可能な保冷用具が求められている。例えば、飲みごろ温度が求められるワイン等については、ワインボトルを冷やすために氷水を張ったワインクーラーが使用されている。 Conventionally, there are storage temperatures suitable for heat retaining materials, in particular, beverages such as wine, beer, alcohol such as sake, juices, water, or food products, and pharmaceuticals, respectively. There is a need for a cryostat that can reach the desired storage temperature more quickly and that can be maintained at the desired temperature for an extended period of time. For example, in the case of wine etc. where the temperature is required to drink, a wine cooler covered with ice water is used to cool the wine bottle.
 さらに、近年では、熱燗、常温、冷酒として飲まれてきた日本酒(アルコール飲料)に対して、冷蔵温度(5℃)以下で、かつ風味が変化しないよう凍結させない温度で飲むという新しい飲み方が提案されている。 Furthermore, in recent years, a new drinking method has been proposed in which, for sake (alcohol beverages) consumed as hot sake, normal temperature, and cold sake, it is a refrigerated temperature (5 ° C) or less and a temperature not frozen so that the flavor does not change. It is done.
 特許文献1および特許文献2では、ワインを適温(5~12℃の温度帯)で維持する技術が開示されている。 Patent documents 1 and 2 disclose techniques for maintaining wine at an appropriate temperature (temperature range of 5 to 12 ° C.).
特許第4406683号明細書Patent No. 4406683 specification 特開2003-202173号公報JP 2003-202173 A
 例えば、日本酒等のアルコール飲料を冷却する際に、一般的な家庭用冷蔵庫の「冷蔵庫」ではなく「冷凍庫」を用いることによって、アルコール飲料を5℃以下にすることができるが、アルコールの度数によっては、アルコール飲料が凍結してしまう場合がある。例えば、アルコール度数が15度の清酒の場合、-18℃で凍結してしまうことが確認されている。このため、飲料を冷却する際には、凍結温度に到達しないように温度管理をする必要がある。 For example, when cooling alcoholic beverages such as sake, it is possible to bring alcoholic beverages to 5 ° C or lower by using a "freezer" instead of the "refrigerator" of a common household refrigerator, but depending on the alcohol frequency May cause the alcoholic beverage to freeze. For example, in the case of sake having an alcohol content of 15 degrees, freezing at -18.degree. C. has been confirmed. For this reason, when cooling the beverage, it is necessary to control the temperature so as not to reach the freezing temperature.
 また、特許文献1で開示されているワインクーラーおよび特許文献2で開示されている保冷保温具は、5℃以上での保冷を目的としたものであり、冷蔵庫(5℃)から取り出した飲料の温度を、さらに下げることができない。また、保冷効果を高めるための保冷対象物を締め付ける構造を有していない。 In addition, the wine cooler disclosed in Patent Document 1 and the cold-keeping insulation tool disclosed in Patent Document 2 are for the purpose of cold-cooling at 5 ° C. or higher, and are the beverages taken out from the refrigerator (5 ° C.) The temperature can not be lowered further. Moreover, it does not have a structure which clamps the cold storage object in order to improve the cold storage effect.
 本発明の一つの態様は、このような事情に鑑みてなされたものであり、保存容器内の飲料を適切な温度に管理することができる保冷用具を提供することを目的とする。 The one aspect of this invention is made in view of such a situation, and it aims at providing the cold-storage tool which can manage the drink in a storage container to appropriate temperature.
 上記の目的を達成するために、本発明は、以下のような手段を講じた。すなわち、本発明の一形態である保冷用具は、保存容器内の飲料の温度を管理する保冷用具であって、予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、前記保存容器および前記熱交換部を包囲する包装部と、を備え、前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である。 In order to achieve the above object, the present invention takes the following measures. That is, the cold-preserving tool according to one aspect of the present invention is a cold-keeping tool for managing the temperature of the beverage in the storage container, and is filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material is the beverage And a heat exchange unit configured to exchange heat, and a packaging unit surrounding the storage container and the heat exchange unit, wherein the heat storage material has a melting point of 5 ° C. or less and the beverage is frozen It is above the temperature.
 本発明のいくつかの態様によれば、飲料を凍結させることなく十分に冷却することが可能となる。 According to some aspects of the invention, it is possible to sufficiently cool the beverage without freezing.
本実施形態に係る保冷用具の概略を示す図である。It is a figure which shows the outline of the cold-storage tool which concerns on this embodiment. 本実施形態に係る保冷用具の側面部を展開した図である。It is the figure which developed the side part of the cold-storage tool which concerns on this embodiment. 本実施形態に係る保冷用具の熱交換部の概略を示す上面図である。It is a top view which shows the outline of the heat exchange part of the cold-storage tool which concerns on this embodiment. 本実施形態に係る保冷用具の熱交換部の概略を示す側面図である。It is a side view which shows the outline of the heat exchange part of the cold-storage tool which concerns on this embodiment. 各実施例および比較例で使用する保冷対象物の概略を示す図である。It is a figure which shows the outline of the cold storage subject used by each Example and a comparative example. 清酒の凍結温度確認実験結果を示すグラフである。It is a graph which shows the freezing temperature confirmation experiment result of sake. 水溶性無機塩の一例として塩化ナトリウムについて、式(1)をプロットした図である。It is the figure which plotted Formula (1) about sodium chloride as an example of a water-soluble inorganic salt. 実施例1における保存容器の温度変化を示す図である。FIG. 6 is a view showing temperature changes of the storage container in Example 1. 実施例2および比較例1における各保存容器の温度変化率を示す図である。It is a figure which shows the temperature change rate of each storage container in Example 2 and Comparative Example 1. 実施例2および比較例1における各保存容器の温度変化率をまとめた図である。It is the figure which put together the temperature change rate of each storage container in Example 2 and Comparative Example 1. 実施例1および実施例2における各保存容器の温度変化率を示す図である。It is a figure which shows the temperature change rate of each storage container in Example 1 and Example 2. FIG. 実施例1および実施例2における各保存容器の温度変化率をまとめた図である。It is the figure which put together the temperature change rate of each storage container in Example 1 and Example 2. FIG. 実施例1および比較例2における各保存容器の温度変化率を示す図である。It is a figure which shows the temperature change rate of each storage container in Example 1 and Comparative Example 2. 実施例1および比較例2における各保存容器の温度変化率をまとめた図である。It is the figure which put together the temperature change rate of each storage container in Example 1 and Comparative Example 2. 実施例2および比較例2における各保存容器の温度変化率をまとめた図である。It is the figure which put together the temperature change rate of each storage container in Example 2 and Comparative Example 2.
 本発明者らは、日本酒を冷やして飲むニーズが高まっている状況下で、冷やし過ぎて凍結させてしまうことによる不都合を回避するためには、飲料に応じた温度管理が必要であることに着目し、融点が5℃以下であると共に飲料の凍結温度以上である蓄熱材を用いることによって、適切な温度管理ができることを見出し、本発明に至った。 The present inventors pay attention to the fact that the temperature control according to the beverage is necessary to avoid the inconvenience caused by freezing too much under the situation where needs for cooling and drinking sake are increasing. By using a heat storage material having a melting point of 5 ° C. or less and a freezing temperature of the beverage, it has been found that appropriate temperature control can be performed, and the present invention has been achieved.
 すなわち、本発明のいくつかの態様の保冷用具は、保存容器内の飲料の温度を管理する保冷用具であって、予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、前記保存容器および前記熱交換部を包囲する包装部と、を備え、前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である。 That is, the cold-preserving tool according to some aspects of the present invention is a cold-preserving tool for managing the temperature of the beverage in the storage container, and is filled with a heat storage material that changes its phase at a predetermined temperature; A heat exchange unit configured to exchange heat with a beverage, and a packaging unit surrounding the storage container and the heat exchange unit, wherein the heat storage material has a melting point of 5 ° C. or less It is above freezing temperature.
 これにより、本発明者らは、飲料を凍結させることなく十分に冷却することを可能とした。以下、本発明の実施形態について、図面を参照しながら具体的に説明する。 This enabled the inventors to sufficiently cool the beverage without freezing it. Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings.
 [保冷用具の構成]
 図1Aは、本実施形態に係る保冷用具の概略を示す図である。図1Bは、本実施形態に係る保冷用具の側面部を展開した図である。熱交換部および保冷用具の閉塞面としての底面部は図示していないが、熱交換部は後述し、底面部は、包装材と同じ材料で概略円形に形成されている。図1Aおよび図1Bに示すように、本実施形態に係る保冷用具1は、2次元的な特定形状を有する包装材3が、3aと3bで重なるように巻回されることによって円筒状に形成されており、これが保冷用具1の側面部となっている。また、保冷用具1の開口端部は、円筒を斜めに切断した形状を有しており、保存容器としての瓶5を収納することによって、瓶5が着物の前身頃を合わせて、着用したような外観を形成することができる。固定ベルト7は、瓶5の首の部分を固定し、瓶5の位置を保冷用具1内部で安定させると共に、飲料を注ぐ際などに保冷用具1から瓶5が外れてしまうことを防止する。
[Composition of cold insulation tool]
FIG. 1A is a diagram showing an outline of a cold insulator according to the present embodiment. FIG. 1B is a developed view of a side surface portion of the cold insulator according to the present embodiment. Although the bottom of the heat exchange portion and the bottom surface as a closed surface of the cold storage tool is not shown, the heat exchange portion will be described later, and the bottom is formed in a substantially circular shape of the same material as the packaging material. As shown to FIG. 1A and FIG. 1B, the cold-storage tool 1 which concerns on this embodiment is formed cylindrically by winding so that the packaging material 3 which has a two-dimensional specific shape may overlap by 3a and 3b. This is the side part of the cold insulator 1. In addition, the open end of the cold preservation tool 1 has a shape obtained by obliquely cutting a cylinder, and by storing the bottle 5 as a storage container, the bottle 5 is worn with the front body of the kimono together. Can form an attractive appearance. The fixing belt 7 fixes the neck portion of the bottle 5 and stabilizes the position of the bottle 5 inside the cooling tool 1 and prevents the bottle 5 from being detached from the cooling tool 1 when pouring a beverage or the like.
 図1Aに示すように、包装材3によって形成された側面部の底面部側の径D1は、側面部の開口端側の径D2よりも大きい。これは、図1Bに示すように、包装材3の展開図が、2次元的な特定形状を有しており、展開図中、紙面に対して下側となる底辺部が、一直線ではなく、点Pを中心に178度の角度を持つように形成されていることから実現されるものである。このように、保冷用具1がいわゆる「テーパ」を有しているため、瓶5を収納した際に、保冷用具1の開口端部が開いてしまうことを防止している。 As shown in FIG. 1A, the diameter D1 on the bottom surface side of the side surface portion formed by the packaging material 3 is larger than the diameter D2 on the opening end side of the side surface portion. This is because, as shown in FIG. 1B, the developed view of the packaging material 3 has a two-dimensional specific shape, and in the developed view, the bottom side which is lower than the paper surface is not a straight line, This is realized because the point P is formed to have an angle of 178 degrees. Thus, since the cold-keeping tool 1 has a so-called “taper”, the opening end of the cold-keeping tool 1 is prevented from opening when the bottle 5 is stored.
 また、保冷用具1は、包装材3が重なっている部分に、重なっている包装材3aおよび3bを相互に係止する留め具9が設けられている。留め具9で包装材3aおよび3bを係止することによって、後述する熱交換部20を瓶5に密着させ、冷却効果を高めることが可能となる。この点については後述する。なお、包装材3が保冷用具1の側面部を構成し、側面部と図示しない底面部とが包装部を構成する。なお、包装材3を、伸縮性素材で形成することによって、蓄熱材が融解し、蓄熱材の体積が収縮した場合であっても、瓶5への密着性を維持することが可能となる。 Moreover, the cold storage tool 1 is provided with the fastener 9 which mutually locks the overlapping packaging materials 3a and 3b in the part which the packaging material 3 has overlapped. By locking the packaging materials 3a and 3b with the fasteners 9, the heat exchange unit 20 to be described later can be closely attached to the bottle 5, and the cooling effect can be enhanced. This point will be described later. In addition, the packaging material 3 comprises the side part of the cold-storage tool 1, and a side part and the bottom part which is not shown in figure comprise a packaging part. In addition, by forming the packaging material 3 with a stretchable material, even when the heat storage material is melted and the volume of the heat storage material shrinks, the adhesion to the bottle 5 can be maintained.
 図2Aは、本実施形態に係る保冷用具の熱交換部の概略を示す上面図である。図2Bは、本実施形態に係る保冷用具の熱交換部の概略を示す側面図である。図2Aに示すように、熱交換部20は、蓄熱材22を収納する6つの蓄熱材収納部20aと、各蓄熱材収納部20aを連結する5つの連結部20bとを備えている。このように、蓄熱材収納部20aを複数有する構造を採ることにより、蓄熱材22が凍結した後に、包装材3によって瓶5と密着するように包囲されることで保存容器としての瓶5への接触性が向上する。なお、熱交換部20を構成する蓄熱材収納部20aと連結部20bの数が増えるほど、瓶5に装着した際の外観がスリムになる。なお、ここでは、6つの蓄熱材収納部20aと、5つの連結部20bとを示したが、これらの個数に限定されるわけではない。 FIG. 2A is a top view showing an outline of a heat exchange part of the cold preservation tool according to the present embodiment. FIG. 2B is a side view showing an outline of a heat exchange part of the cold storage device according to the present embodiment. As shown to FIG. 2A, the heat exchange part 20 is provided with the six thermal storage material accommodating parts 20a which accommodate the thermal storage material 22, and the five connection parts 20b which connect each thermal storage material accommodating part 20a. Thus, by adopting a structure having a plurality of heat storage material storage portions 20a, after the heat storage material 22 is frozen, it is surrounded by the packaging material 3 so as to be in close contact with the bottle 5, thereby making the bottle 5 as a storage container. Contactability is improved. In addition, the appearance at the time of mounting | wearing the bottle 5 becomes slimmer, so that the number of thermal storage material accommodating part 20a and the connection part 20b which comprise the heat exchange part 20 increases. In addition, although six heat-storage material storage parts 20a and five connection parts 20b were shown here, it is not necessarily limited to these numbers.
 また、蓄熱材収納部20aは、瓶5と接触する部分に曲面部20cを有している。曲面部20cは、曲率半径が37mmである凹状に形成されている。これにより、瓶5への密着性の向上を図ることが可能となる。その結果、瓶5からの熱吸収性が向上し、温度を下げやすくなる。また、外気に触れる瓶5の表面積が小さくなることで、瓶5内の飲料の温度上昇が抑制される。さらに、余分な出っ張りがなくなり、全体的にごつごつした状態を減少させスリム化を図ることが可能となる。なお、本実施形態では、曲率半径を37mmとしたが、これに限定されるわけではない。曲率半径の範囲としては、好ましくは26.5mm~46.00mmであるが、日本酒の一升瓶やシャンパンの通常サイズ(750ml)の6倍の容量があるレオボワームサイズ等の曲率サイズであっても良い。なお、曲面部20cの剛性を、それ以外の部分の剛性よりも高くしても良い。これにより、蓄熱材を凍結させた時に発生する体積膨張によって、曲面部20cが変形することを抑制することが可能となる。また、熱交換部20の各蓄熱材収納部20aに、染色液が充填されていても良い。これにより、蓄熱材が漏れたとしても、一目で認識することが可能となる。 Further, the heat storage material storage unit 20 a has a curved surface portion 20 c at a portion in contact with the bottle 5. The curved surface portion 20c is formed in a concave shape having a radius of curvature of 37 mm. As a result, the adhesion to the bottle 5 can be improved. As a result, the heat absorptivity from the bottle 5 is improved, and the temperature can be easily lowered. Moreover, the temperature rise of the drink in the bottle 5 is suppressed because the surface area of the bottle 5 which touches external air becomes small. Furthermore, there is no extra protrusion, and it becomes possible to reduce the overall rough condition and to achieve slimming. In the present embodiment, the radius of curvature is 37 mm, but this is not a limitation. The radius of curvature is preferably in the range of 26.5 mm to 46.00 mm, but it may be a curvature size such as a leboworm size having a capacity six times the normal size (750 ml) of a bottle of sake or champagne good. The rigidity of the curved surface portion 20c may be made higher than the rigidity of the other portions. This makes it possible to suppress deformation of the curved surface portion 20c due to volumetric expansion that occurs when the heat storage material is frozen. Further, each heat storage material storage unit 20 a of the heat exchange unit 20 may be filled with a staining solution. Thereby, even if the heat storage material leaks, it becomes possible to recognize at a glance.
 [検証]
 次に、本実施形態に係る保冷用具の効果を検証するため、以下の条件で実験を行なった。図3は、各実施例および比較例で使用する保冷対象物の概略を示す図である。冷却対象物は、瓶5に、冷却対象液体として清酒(アルコール度数15度、720ml)が充填されている。冷却対象液体(清酒)は、予め冷蔵庫(5℃)で保冷したものを使用した。環境温度は、23℃である。以下は、各実施例および比較例の保冷用具の構成をまとめた表である。
Figure JPOXMLDOC01-appb-T000002
[Verify]
Next, in order to verify the effect of the cold insulator according to the present embodiment, an experiment was performed under the following conditions. FIG. 3 is a schematic view of a cold storage object used in each example and comparative example. An object to be cooled is filled in a bottle 5 with sake (alcohol having a degree of 15 degrees, 720 ml) as a liquid to be cooled. The liquid to be cooled (sake) was previously kept cold by a refrigerator (5 ° C.). The ambient temperature is 23 ° C. The following is a table summarizing the configurations of the cold insulators of the respective examples and comparative examples.
Figure JPOXMLDOC01-appb-T000002
 冷却対象液体を保存容器に充填した時の充填高さは、保存容器の底から200mmである。また、各実施例および比較例における温度測定点は、(I)液体中心:底から100mm、(II)液体上部:底から180mmとした。 The filling height when the liquid to be cooled is filled into the storage container is 200 mm from the bottom of the storage container. Moreover, the temperature measurement point in each Example and the comparative example was (I) liquid center: 100 mm from the bottom, (II) liquid top: 180 mm from the bottom.
 [凍結温度確認実験]
 まず、本実施形態にて使用する保冷対象液体(清酒)の凍結温度確認実験を行なった。清酒(720ml)が充填された保存容器を庫内に静置し、庫内の温度を5時間ごとに1℃ずつ下げ、庫内の温度が何℃の時に凍結するかの実験を行なった。図4は、清酒の凍結温度確認実験結果を示すグラフである。実験の結果、図4に示すように、清酒(アルコール度数15度)は、庫内温度が-18℃の時に凍結することが分かった。この結果から、本実験で用いる清酒は、冷凍庫(-18℃)では凍結する可能性がある。そこで、融点が5℃以下であり、かつ-18℃より高い潜熱蓄熱材(蓄熱材)を用いる必要がある。
[Freezing temperature confirmation experiment]
First, a freezing temperature confirmation experiment of a liquid to be stored (sake) used in the present embodiment was performed. A storage container filled with sake (720 ml) was allowed to stand in a refrigerator, the temperature in the refrigerator was lowered by 1 ° C. every five hours, and experiments were conducted to determine the temperature at which the refrigerator freezes. FIG. 4 is a graph showing the freezing temperature confirmation experiment results of sake. As a result of the experiment, as shown in FIG. 4, it was found that the sake (alcohol degree: 15 ° C.) was frozen when the inside temperature was −18 ° C. From this result, the sake used in this experiment may freeze in the freezer (-18 ° C). Therefore, it is necessary to use a latent heat storage material (heat storage material) having a melting point of 5 ° C. or less and higher than −18 ° C.
 [潜熱蓄熱材]
 ここで、本実施形態に用いる潜熱蓄熱材について、説明する。本実施形態に用いる潜熱蓄熱材は、上述したとおり、融点が5℃以下であり、かつ-18℃より高い潜熱蓄熱材料が好ましい。さらに、潜熱蓄熱材の融点は、0℃未満であると、より好ましい。0℃未満の潜熱蓄熱材としては、無機塩の水溶液であることが好ましく、更にその無機塩水溶液の濃度と融点とが式(1)の関係性を満たすことが好ましい。
Figure JPOXMLDOC01-appb-M000003
(T:融点(℃)
 w:無機塩の含有濃度 (wt%)
 M:無機塩の分子量(g/mol)
 R:気体定数(J/K・mol)
 Tf:水の融点(K)
 ΔH:水の融解潜熱(J/g)
 n:1つの無機塩が水溶液中で電離する際に生成するイオンの数)
 ここで、前記wは、水と前記水溶性無機塩との共晶を与える濃度未満である。
[Latent heat storage material]
Here, the latent heat storage material used in the present embodiment will be described. As described above, the latent heat storage material used in the present embodiment is preferably a latent heat storage material having a melting point of 5 ° C. or less and higher than −18 ° C. Furthermore, the melting point of the latent heat storage material is more preferably less than 0 ° C. The latent heat storage material having a temperature of less than 0 ° C. is preferably an aqueous solution of an inorganic salt, and it is more preferable that the concentration of the inorganic salt aqueous solution and the melting point satisfy the relationship of Formula (1).
Figure JPOXMLDOC01-appb-M000003
(T: Melting point (° C)
w: Concentration of inorganic salt (wt%)
M: Molecular weight of inorganic salt (g / mol)
R: Gas constant (J / K · mol)
Tf: Melting point of water (K)
ΔH: heat of melting of water (J / g)
n: number of ions formed when one inorganic salt ionizes in aqueous solution)
Here, w is less than the concentration giving a eutectic of water and the water-soluble inorganic salt.
 これにより、所望の融点をもつ潜熱蓄熱材を水溶性無機塩の濃度を変えるだけで、簡便に設計することができる。また、式(1)は前記wが前記水溶性無機塩との共晶を与える濃度未満の希薄水溶液で成り立つ。前記wが前記水溶性無機塩との共晶を与える濃度付近では、共晶が得られる。共晶状態においては、単一の融点を示し、潜熱が高くなる。そのため保冷温度が一定になり易く、長時間の保冷が可能となる。 Thus, the latent heat storage material having a desired melting point can be designed simply by changing the concentration of the water-soluble inorganic salt. In addition, Formula (1) is established with a dilute aqueous solution having a concentration less than the concentration at which w gives a eutectic with the water-soluble inorganic salt. A eutectic is obtained near the concentration at which w gives a eutectic with the water-soluble inorganic salt. In the eutectic state, a single melting point is exhibited, and the latent heat is high. Therefore, the cold storage temperature tends to be constant, and long-term cold storage is possible.
 また、無機塩としては、塩化ナトリウム、塩化カリウム、塩化カルシウム、塩化マグネシウム、塩化バリウム、塩化アンモニウム、炭酸水素カリウム、炭酸ナトリウム、硝酸ナトリウム、硝酸カリウム、硝酸カルシウム、硝酸マグネシウムが好ましい。また、無機塩の濃度は、各無機塩と水との共晶を与える濃度以下であることが好ましい。共晶を与える濃度を超える量を加えた場合には、共晶を与える濃度での融点以下にはならず、無機塩が過剰に析出するため重量当たりの潜熱が減少する。 Further, as the inorganic salt, sodium chloride, potassium chloride, calcium chloride, magnesium chloride, barium chloride, ammonium chloride, potassium hydrogencarbonate, sodium bicarbonate, sodium carbonate, sodium nitrate, potassium nitrate, calcium nitrate and magnesium nitrate are preferable. Moreover, it is preferable that the density | concentration of inorganic salt is below the density | concentration which gives the eutectic of each inorganic salt and water. When an amount exceeding the concentration giving the eutectic is added, the temperature does not fall below the melting point at the concentration giving the eutectic and the latent heat per weight decreases because the inorganic salt precipitates excessively.
 図5は、水溶性無機塩の一例として塩化ナトリウムについて、式(1)をプロットし他図である。なお、水と塩化ナトリウムが共晶を与える濃度は23.3wt%であり、図5は、共晶を与える濃度未満の領域をプロットした図である。保冷対象液体の保冷すべき温度が定まっている場合に、潜熱蓄熱材の融点の高精度な設定が求められるが、図5を用いれば、無機塩の濃度を算出することができ、簡便に潜熱蓄熱材の組成比や材料を決定することが可能となる。また、水と塩化ナトリウムが共晶の融点は-21℃だが、共晶の融点以上であっても、式(1)を用いて無機塩の濃度を調整することで、所望の融点の潜熱蓄熱材を得ることができる。また水と無機塩の共晶濃度付近では、単一の融点を有する共晶が得られる。なお、潜熱蓄熱材を構成する無機塩は、前述した無機塩の内、1種類のみでも良いし、複数の無機塩を混合させたものでも良い。なお、融点が0℃未満の潜熱蓄熱材を用いることによって、氷では実現できない氷点下への冷却が可能となる。 FIG. 5 is another diagram in which formula (1) is plotted for sodium chloride as an example of the water-soluble inorganic salt. The concentration at which water and sodium chloride give a eutectic is 23.3 wt%, and FIG. 5 is a diagram in which the region below the concentration giving a eutectic is plotted. If the temperature at which the liquid to be stored is to be stored is determined, high-precision setting of the melting point of the latent heat storage material is required. However, the concentration of inorganic salt can be calculated using FIG. It becomes possible to determine the composition ratio and material of the heat storage material. Moreover, although the melting point of water and sodium chloride is -21 ° C, even if it is higher than the melting point of the eutectic, latent heat storage of a desired melting point is achieved by adjusting the concentration of the inorganic salt using formula (1) The material can be obtained. Also, near the eutectic concentration of water and inorganic salt, a eutectic having a single melting point is obtained. In addition, the inorganic salt which comprises a latent heat storage material may be only 1 type among the inorganic salts mentioned above, and what mixed several inorganic salt may be used. By using a latent heat storage material having a melting point of less than 0 ° C., it is possible to cool below the freezing point that can not be realized with ice.
 次に、上記の融点を有する潜熱蓄熱材を用いて保冷用具の構成による性能の違いを検証した。 Next, using the latent heat storage material having the above melting point, the difference in performance depending on the configuration of the cold insulator was verified.
 [1.冷却性能/実施例1]
 (実施例1)
 ・包装材:テーパあり、留め具9あり、とした。
 ・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、120分間の温度を測定した。
 温度測定箇所は、液体中心部、熱交換部20の外側(包装材と容器との間)とした。
[1. Cooling performance / Example 1]
Example 1
Packaging: Tapered, with fasteners 9.
-The temperature for 120 minutes was measured after attaching the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5).
The temperature was measured at the liquid center, outside the heat exchange unit 20 (between the packaging material and the container).
 図6は、実施例1における保存容器の温度変化を示す図である。図6に示すように、冷蔵庫(5℃)で保冷された液体中心部の温度は、約23分で氷点下まで冷却されている。実施例1の保冷用具は、30分以内に氷点下にする冷却性能を有することが分かった。また、液体中心部の温度は、熱交換部(蓄冷材)温度に向かって冷却されるが、冷却開始から2時間後も凍結はしていないことが分かった。 FIG. 6 is a view showing temperature change of the storage container in the first embodiment. As shown in FIG. 6, the temperature of the liquid core portion cooled by the refrigerator (5 ° C.) is cooled to below freezing in about 23 minutes. The cryocooler of Example 1 was found to have a cooling performance of freezing below 30 minutes. Moreover, although the temperature of the liquid center part was cooled toward the heat exchange part (cold storage material) temperature, it turned out that it did not freeze even two hours after the cooling start.
 [2.テーパの有無の効果/実施例2と比較例1の比較]
 次に、テーパの有無の効果について、実施例2および比較例1を用いて検証した。比較方法は、以下に示す式(2)により算出される温度変化を用いて、正規化した値での比較を行なった。これは、冷蔵庫から取り出した時の温度が異なるためである。
[2. Effect of presence / absence of taper / comparison of Example 2 and Comparative Example 1]
Next, the effect of the presence or absence of the taper was verified using Example 2 and Comparative Example 1. The comparison method performed the comparison with the normalized value using the temperature change calculated by Formula (2) shown below. This is because the temperature when taken out from the refrigerator is different.
 温度変化率=(測定時液体温度-初期液体温度)/初期液体温度・・・(2)
 ここで、温度変化率が0以上は温度上昇、0未満は温度低下を意味する。
Temperature change rate = (liquid temperature at measurement-initial liquid temperature) / initial liquid temperature ... (2)
Here, the temperature change rate of 0 or more means temperature rise, and less than 0 means temperature fall.
 (実施例2)
 ・包装材:テーパあり、留め具9なし、とした。
 ・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
 温度測定箇所は、液体中心部、液体上部とした。
 (比較例1)
 ・包装材:テーパなし、留め具9なしとした。
 ・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
 温度測定箇所は、液体中心部、液体上部とした。
(Example 2)
Packaging: Tapered, without fasteners 9.
-The temperature for 30 minutes was measured after mounting the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5).
The temperature was measured at the center of the liquid and at the top of the liquid.
(Comparative example 1)
-Packaging material: No taper, no fastener 9.
-The temperature for 30 minutes was measured after mounting the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5).
The temperature was measured at the center of the liquid and at the top of the liquid.
 図7Aは、実施例2および比較例1における各保存容器の温度変化率を示す図である。図7Bは、実施例2および比較例1における各保存容器の温度変化率をまとめた図である。30分後の温度変化比率について、「液体中心部」については、ほぼ差が見られなかった。すなわち、比較例1が3%のみ低く、これは温度低下率が3%高いということとなり、冷却されたこととなる。一方、「液体上部」については、比較例1の温度変化率が実施例2の温度変化率よりも22%高かった。つまり、液体上部は、温度上昇率が22%高く、温度が上がり易いといえる。 FIG. 7A is a view showing a temperature change rate of each storage container in Example 2 and Comparative Example 1. FIG. 7B is a diagram summarizing temperature change rates of the respective storage containers in Example 2 and Comparative Example 1. About the temperature change ratio after 30 minutes, about "liquid center", almost no difference was seen. That is, Comparative Example 1 is low by only 3%, which means that the temperature decrease rate is high by 3%, which means that it was cooled. On the other hand, regarding the “liquid upper portion”, the temperature change rate of Comparative Example 1 was 22% higher than the temperature change rate of Example 2. That is, it can be said that the temperature of the liquid upper portion is 22% higher, and the temperature is easy to rise.
 以上の結果、テーパを設けることで、液体中心部においては冷却効果が得られ、液体上部においては、温度上昇を抑制する効果が得られ、特に、液体上部の温度上昇率を抑制することが可能となることが分かった。 As a result of the above, by providing the taper, a cooling effect can be obtained at the liquid center, and an effect of suppressing the temperature rise can be obtained at the liquid top, and in particular, the temperature rise rate of the liquid top can be suppressed. It turned out that it became.
 [3.留め具の有無の効果/実施例1と実施例2の比較]
 次に、留め具9の有無の効果について、実施例1および実施例2を用いて検証した。比較方法は、テーパの有無の効果の比較方法と同様の方法で比較を行なった。
[3. Effect of presence / absence of fastener / Comparison of Example 1 and Example 2]
Next, the effect of the presence or absence of the fastener 9 was verified using Example 1 and Example 2. The comparison method compared in the method similar to the comparison method of the effect of the presence or absence of a taper.
 (実施例1)
 ・包装材:テーパあり、留め具(マジックテープ(登録商標))あり、とした。
 ・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
 温度測定箇所は、液体中心部、液体上部とした。
 (実施例2)
 ・包装材:テーパあり、留め具なし、とした
 ・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
 温度測定箇所は、液体中心部、液体上部とした。
Example 1
-Packaging material: It was tapered, and there was a fastener (magic tape (registered trademark)).
-The temperature for 30 minutes was measured after mounting the heat exchange part 20 and the packaging material 3 with respect to the storage container (bottle 5).
The temperature was measured at the center of the liquid and at the top of the liquid.
(Example 2)
-Packaging material: with taper, without fastener-With respect to the storage container (bottle 5), the temperature was measured for 30 minutes after the heat exchange unit 20 and the packaging material 3 were attached.
The temperature was measured at the center of the liquid and at the top of the liquid.
 図8Aは、実施例1および実施例2における各保存容器の温度変化率を示す図である。図8Bは、実施例1および実施例2における各保存容器の温度変化率をまとめた図である。図8Bに示すように、実施例1の温度変化率は、「液体上部」において実施例2よりも8%低下しており、「液体中心部」において実施例2よりも28%低下している。つまり、留め具9を設けることにより、液体上部、液体中心部ともに温度上昇率を低下させることが可能となり、特に、液体中心部の温度上昇を低下させることが可能となることが分かった。なお、本実施形態では、留め具9として、マジックテープ(登録商標)を用いたが、包装材3の重なった部分を係止することができれば、何でも良く、これに限定されるわけではない。 FIG. 8A is a view showing a temperature change rate of each storage container in Example 1 and Example 2. FIG. 8B is a diagram summarizing temperature change rates of the respective storage containers in Example 1 and Example 2. As shown in FIG. 8B, the temperature change rate of Example 1 is 8% lower than that of Example 2 in the “liquid upper portion”, and is 28% lower than that of Example 2 in the “liquid center portion”. . That is, it was found that the provision of the fastener 9 makes it possible to lower the temperature rise rate in both the liquid upper portion and the liquid center portion, and in particular, it is possible to lower the temperature rise in the liquid center portion. Although Velcro (registered trademark) is used as the fastener 9 in the present embodiment, anything may be used as long as the overlapping portion of the packaging material 3 can be locked, and the present invention is not limited to this.
 [4.被覆率の効果/実施例1、実施例2と比較例2の比較]
 次に、被覆率の効果について、実施例1、実施例2および比較例2を用いて検証した。すなわち、熱交換部20が、瓶5における飲料の充填高さに対して、どのくらいを被覆するかに応じて比較を行なった。被覆率以外のその他の構成、温度測定箇所、温度測定時間は、上記各検証と同様である。
[4. Effect of Coverage Ratio / Comparison of Example 1, Example 2 and Comparative Example 2]
Next, the effect of the coverage was verified using Example 1, Example 2 and Comparative Example 2. That is, the heat exchange unit 20 compares the filling height of the beverage in the bottle 5 according to how much it covers. The configuration other than the coverage, the temperature measurement point, and the temperature measurement time are the same as those in the above-described respective verifications.
 (実施例1、実施例2)
 被覆率:87.0%
 その他の構成、温度測定箇所、温度測定時間は、前述と同様である。
(Example 1, Example 2)
Cover rate: 87.0%
The other configurations, the temperature measurement points, and the temperature measurement time are the same as those described above.
 (比較例2)
 被覆率:79.5%
 その他の構成、温度測定箇所、温度測定時間は、前述と同様である。
(Comparative example 2)
Coverage rate: 79.5%
The other configurations, the temperature measurement points, and the temperature measurement time are the same as those described above.
 図9Aは、実施例1および比較例2における各保存容器の温度変化率を示す図である。図9Bは、実施例1および比較例2における各保存容器の温度変化率をまとめた図である。図9Bに示すように、「液体中心部」の温度変化率は、比較例2が14%高い。また、「液体上部」の温度変化率についても、比較例2が5%高い。つまり、被覆率を上げることにより冷却性能は向上することが分かった。 FIG. 9A is a view showing a temperature change rate of each storage container in Example 1 and Comparative Example 2. FIG. 9B is a diagram summarizing temperature change rates of the respective storage containers in Example 1 and Comparative Example 2. As shown in FIG. 9B, the temperature change rate of the “liquid center” is 14% higher in Comparative Example 2. Further, the temperature change rate of the “liquid upper portion” is also 5% higher in Comparative Example 2. That is, it was found that the cooling performance is improved by increasing the coverage.
 図9Cは、実施例2および比較例2における各保存容器の温度変化率をまとめた図である。図9Cに示すように、実施例2および比較例2において、30分後の温度変化率を比較すると、比較例2の方が実施例2よりも冷却性能が高いことが分かった。したがって、少なくとも被覆率が79.5%以上であれば、冷却性能を向上させることが可能であることが分かった。 FIG. 9C is a diagram summarizing temperature change rates of the respective storage containers in Example 2 and Comparative Example 2. As shown in FIG. 9C, when the temperature change rates after 30 minutes in Example 2 and Comparative Example 2 were compared, it was found that Comparative Example 2 had higher cooling performance than Example 2. Therefore, it was found that it is possible to improve the cooling performance if at least the coverage is 79.5% or more.
 なお、蓄熱材22は、熱交換部20の製造工程上、充填時の操作性を向上させるために増粘性を有していることが望ましい。この場合、蓄熱材22に増粘剤を混入させることで実現可能である。 In addition, in the manufacturing process of the heat exchange part 20, in order to improve the operativity at the time of filling, it is desirable for the thermal storage material 22 to have thickening property. In this case, it can be realized by mixing the heat storage material 22 with a thickener.
 また、冷却対象液体を充填する瓶5等の保存容器は、少なくとも一部に温度表示機能を有していても良い。この温度表示機能は、例えば、示温材を瓶5等の保存容器に塗布(印字)しても良いし、保存容器自体が示温材を含有する素材で作られたものでも良い。これにより、冷却対象液体の温度を把握することが可能となる。さらに、上記示温材は、6℃(または、冷蔵温度)で変色または消色するほうが好ましい。これは、冷蔵室で保冷した飲料物をさらに冷却することを前提とした場合、保存容器が冷蔵温度帯になったかどうかが分かることで、保冷用具を装着するタイミングが分かり、使用者が保冷用具の本来の性能を発揮する適切なタイミングを知ることが可能となるためである。 Moreover, storage containers, such as bottle 5 etc. which are filled with liquid for cooling, may have a temperature display function in at least one part. For this temperature display function, for example, a temperature indicator may be applied (printed) on a storage container such as the bottle 5 or the storage container itself may be made of a material containing the temperature indicator. This makes it possible to grasp the temperature of the liquid to be cooled. Furthermore, it is more preferable to discolor or decolor the temperature indicator at 6 ° C. (or refrigeration temperature). This is based on the premise that the beverage kept cold in the refrigerator compartment is further cooled, it can be understood whether the storage container is in the cold storage temperature zone, the timing for wearing the cooling implement can be known, and the user can use the cold insulator This makes it possible to know the appropriate timing for achieving the original performance of
 また、本発明は、以下の態様を採ることも可能である。 Furthermore, the present invention can also adopt the following aspects.
 (A)本発明の一形態に係る保冷用具は、保存容器内の飲料の温度を管理する保冷用具であって、予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、前記保存容器および前記熱交換部を包囲する包装部と、を備え、前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である。 (A) A cold-preserving tool according to an aspect of the present invention is a cold-preserving tool for managing the temperature of a beverage in a storage container, which is filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material is A heat exchange unit configured to exchange heat with a beverage, and a packaging unit surrounding the storage container and the heat exchange unit, wherein the heat storage material has a melting point of 5 ° C. or less It is above freezing temperature.
 (B)また、本発明の一形態に係る保冷用具において、前記包装部は、円筒状に形成された側面部と、前記側面部の一端と結合し閉塞面を形成する底面部と、を備え、前記側面部の前記閉塞面側の径は、前記側面部の開口端側の径よりも大きい。 (B) Moreover, in the cold-storage tool which concerns on one form of this invention, the said packaging part is equipped with the side part formed in cylindrical shape, and the bottom face part couple | bonded with one end of the said side part and forming a closed surface. The diameter on the closed surface side of the side surface portion is larger than the diameter on the opening end side of the side surface portion.
 (C)また、本発明の一形態に係る保冷用具において、前記側面部は、2次元的な特定形状を有する包装材が一部で重なるように巻回されることによって円筒状に形成されている。 (C) In the cooling tool according to one aspect of the present invention, the side surface portion is formed in a cylindrical shape by being wound so that a packaging material having a two-dimensional specific shape partially overlaps. There is.
 (D)また、本発明の一形態に係る保冷用具は、前記包装材が重なっている部分に設けられ、前記各包装材を相互に係止する留め具をさらに備える。 (D) Moreover, the cold-storage tool which concerns on one form of this invention is provided in the part which the said packaging material has overlapped, and is further provided with the fastener which mutually locks the said each packaging material.
 (E)また、本発明の一形態に係る保冷用具において、前記熱交換部は、前記蓄熱材を収納する複数の蓄熱材収納部と、前記各蓄熱材収納部を連結する連結部と、を備え、前記保存容器の表面に沿って接触する。 (E) In the cold preservation tool according to one aspect of the present invention, the heat exchange unit includes a plurality of heat storage material storage units that store the heat storage material, and a connection unit that connects the heat storage material storage units. And contact along the surface of the storage container.
 (F)また、本発明の一形態に係る保冷用具において、前記各蓄熱材収納部は、前記保存容器と接触し前記保存容器の表面に適合する曲面部を有する。 (F) Moreover, in the cold preservation tool which concerns on one form of this invention, each said thermal storage material storage part has a curved surface part which contacts the said storage container and fits the surface of the said storage container.
 (G)また、本発明の一形態に係る保冷用具において、前記熱交換部は、前記保存容器内の前記飲料の充填高さに対して、79.5%以上を被覆する。 (G) Moreover, in the cold preservation tool which concerns on one form of this invention, the said heat exchange part coat | covers 79.5% or more with respect to the filling height of the said drink in the said storage container.
 (H)また、本発明の一形態に係る保冷用具において、前記蓄熱材の融点は、0℃未満である。 (H) Moreover, in the cold-storage tool which concerns on one form of this invention, melting | fusing point of the said thermal storage material is less than 0 degreeC.
 (I)また、本発明の一形態に係る保冷用具において、前記蓄熱材は、水および水溶性無機塩を含み、融点をTとしたときに、上記(1)式を満たす。 (I) Moreover, in the cold-storage tool which concerns on one form of this invention, the said thermal storage material contains water and water-soluble inorganic salt, and when melting | fusing point is set to T, the said (1) Formula is satisfy | filled.
 (J)また、前記蓄熱材は、水および水溶性無機塩を含み、前記水溶性無機塩の重量パーセント濃度が、水と前記水溶性無機塩との共晶を与える濃度である。 (J) Further, the heat storage material contains water and a water-soluble inorganic salt, and the concentration by weight of the water-soluble inorganic salt is a concentration giving a eutectic of water and the water-soluble inorganic salt.
 (K)また、本発明の一形態に係る保冷用具において、前記包装材は、伸縮性素材で形成された。 (K) Moreover, the cold-packing tool which concerns on one form of this invention WHEREIN: The said packaging material was formed with the elastic raw material.
 (L)また、本発明の一形態に係る保冷用具において、前記曲面部は、剛性が前記曲面部以外の部分の剛性よりも高い。 (L) Moreover, in the cold preservation tool which concerns on one form of this invention, the said curved-surface part has rigidity higher than the rigidity of parts other than the said curved-surface part.
 (M)また、本発明の一形態に係る保冷用具において、前記熱交換部には染色液が充填されている。 (M) Moreover, in the cold-storage tool which concerns on one form of this invention, the said heat exchange part is filled with stain | dye liquid.
 以上説明したように、本実施形態によれば、飲料を凍結させることなく十分に冷却することが可能となる。 As described above, according to the present embodiment, it is possible to sufficiently cool the beverage without freezing it.
 本発明のいくつかの態様は、保存容器内の飲料を適切な温度に管理することができる保冷用具などに適用できる。

 
Some aspects of the present invention can be applied to, for example, a cold insulator that can control the beverage in the storage container at an appropriate temperature.

Claims (13)

  1.  保存容器内の飲料の温度を管理する保冷用具であって、
     予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、
     前記保存容器および前記熱交換部を包囲する包装部と、を備え、
     前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である保冷用具。
    A cooling tool for controlling the temperature of the beverage in the storage container,
    A heat exchange section filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material is configured to exchange heat with the beverage;
    And a packaging unit surrounding the storage container and the heat exchange unit,
    The cold storage tool, wherein the heat storage material has a melting point of 5 ° C. or less and a freezing temperature of the beverage.
  2.  前記包装部は、円筒状に形成された側面部と、
     前記側面部の一端と結合し閉塞面を形成する底面部と、を備え、
     前記側面部の前記閉塞面側の径は、前記側面部の開口端側の径よりも大きい請求項1記載の保冷用具。
    The packaging portion has a cylindrical side surface portion,
    A bottom portion coupled with one end of the side portion to form a closed surface;
    The cold preservation tool according to claim 1, wherein a diameter of the side surface on the closed surface side is larger than a diameter of the open end side of the side surface.
  3.  前記側面部は、2次元的な特定形状を有する包装材が一部で重なるように巻回されることによって円筒状に形成された請求項2記載の保冷用具。 The said side part is cylindrically formed by winding so that the packaging material which has a two-dimensional specific shape may overlap in part.
  4.  前記包装材が重なっている部分に設けられ、前記各包装材を相互に係止する留め具をさらに備える請求項3記載の保冷用具。 The cold-preserving device according to claim 3, further comprising a fastener provided at an overlapping portion of the wrapping material and locking the wrapping materials to each other.
  5.  前記熱交換部は、
     前記蓄熱材を収納する複数の蓄熱材収納部と、
     前記各蓄熱材収納部を連結する連結部と、を備え、
     前記保存容器の表面に沿って接触する請求項1から請求項4のいずれか一項に記載の保冷用具。
    The heat exchange unit is
    A plurality of heat storage material storage sections for storing the heat storage material;
    A connecting portion connecting the heat storage material storage portions;
    The cooling tool according to any one of claims 1 to 4, contacting along the surface of the storage container.
  6.  前記各蓄熱材収納部は、前記保存容器と接触し前記保存容器の表面に適合する曲面部を有する請求項5記載の保冷用具。 The cold storage tool according to claim 5, wherein each of the heat storage material storage portions has a curved surface portion that is in contact with the storage container and that fits on the surface of the storage container.
  7.  前記熱交換部は、前記保存容器内の前記飲料の充填高さに対して、79.5%以上を被覆する請求項1から請求項6のいずれか一項に記載の保冷用具。 The cold storage device according to any one of claims 1 to 6, wherein the heat exchange portion covers 79.5% or more of the filling height of the beverage in the storage container.
  8.  前記蓄熱材の融点は、0℃未満である請求項1から請求項7のいずれか一項に記載の保冷用具。 The cold storage tool according to any one of claims 1 to 7, wherein the melting point of the heat storage material is less than 0 ° C.
  9.  前記蓄熱材は、水および水溶性無機塩を含み、
     融点をTとし、
     前記wを水と前記水溶性無機塩との共晶を与える濃度未満であるとしたときに、次式を満たす請求項1から請求項8のいずれか一項に記載の保冷用具。
    Figure JPOXMLDOC01-appb-M000001
    (T:融点(℃)
    w:無機塩の含有濃度 (wt%)
    M:無機塩の分子量(g/mol)
     R:気体定数(J/K・mol)
     Tf:水の融点(K)
     ΔH:水の融解潜熱(J/g)
     n:1つの無機塩が水溶液中で電離する際に生成するイオンの数)
    The heat storage material contains water and a water-soluble inorganic salt,
    Let the melting point be T,
    The cold-storing tool according to any one of claims 1 to 8, wherein the following equation is satisfied when w is less than a concentration that gives a eutectic of water and the water-soluble inorganic salt.
    Figure JPOXMLDOC01-appb-M000001
    (T: Melting point (° C)
    w: Concentration of inorganic salt (wt%)
    M: Molecular weight of inorganic salt (g / mol)
    R: Gas constant (J / K · mol)
    Tf: Melting point of water (K)
    ΔH: heat of melting of water (J / g)
    n: number of ions formed when one inorganic salt ionizes in aqueous solution)
  10.  前記蓄熱材は、水および水溶性無機塩を含み、
     前記水溶性無機塩の重量パーセント濃度が、水と前記水溶性無機塩との共晶を与える濃度である請求項1から請求項8のいずれか一項に記載の保冷用具。
    The heat storage material contains water and a water-soluble inorganic salt,
    The cooling tool according to any one of claims 1 to 8, wherein a weight percent concentration of the water soluble inorganic salt is a concentration giving a eutectic of water and the water soluble inorganic salt.
  11.  前記包装材は、伸縮性素材で形成された請求項3または請求項4記載の保冷用具。 The cooling material according to claim 3 or 4, wherein the packaging material is formed of a stretchable material.
  12.  前記曲面部は、剛性が前記曲面部以外の部分の剛性よりも高い請求項6記載の保冷用具。 The cold tool according to claim 6, wherein the curved surface portion has a rigidity higher than the rigidity of a portion other than the curved surface portion.
  13.  前記熱交換部には染色液が充填されている請求項1から請求項12のいずれか一項に記載の保冷用具。 The cold storage device according to any one of claims 1 to 12, wherein the heat exchange part is filled with a staining solution.
PCT/JP2018/025510 2017-07-07 2018-07-05 Cooling tool WO2019009358A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5188877A (en) * 1991-03-07 1993-02-23 Magaro Steven B Thermal device
JP2002113032A (en) * 2000-10-10 2002-04-16 Hakugen:Kk Warmer
JP2013236615A (en) * 2012-11-26 2013-11-28 Shima System:Kk Processing method for beverage or seasoning
WO2016002597A1 (en) * 2014-06-30 2016-01-07 シャープ株式会社 Cooling member
JP2016211750A (en) * 2015-04-28 2016-12-15 シャープ株式会社 Heat storage pack and heat exchange unit

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5188877A (en) * 1991-03-07 1993-02-23 Magaro Steven B Thermal device
JP2002113032A (en) * 2000-10-10 2002-04-16 Hakugen:Kk Warmer
JP2013236615A (en) * 2012-11-26 2013-11-28 Shima System:Kk Processing method for beverage or seasoning
WO2016002597A1 (en) * 2014-06-30 2016-01-07 シャープ株式会社 Cooling member
JP2016211750A (en) * 2015-04-28 2016-12-15 シャープ株式会社 Heat storage pack and heat exchange unit

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