JP2020153524A - Cold storage tool - Google Patents

Cold storage tool Download PDF

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Publication number
JP2020153524A
JP2020153524A JP2017133946A JP2017133946A JP2020153524A JP 2020153524 A JP2020153524 A JP 2020153524A JP 2017133946 A JP2017133946 A JP 2017133946A JP 2017133946 A JP2017133946 A JP 2017133946A JP 2020153524 A JP2020153524 A JP 2020153524A
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Japan
Prior art keywords
water
temperature
cold insulation
tool according
heat
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Japanese (ja)
Inventor
輝心 黄
Hwisim Hwang
輝心 黄
邦広 岡田
Kunihiro Okada
邦広 岡田
夕香 内海
Yuka Utsumi
夕香 内海
雅子 西橋
Masako Nishibashi
雅子 西橋
勝一 香村
Katsuichi Komura
勝一 香村
知子 加瀬
Tomoko Kase
知子 加瀬
哲 本並
Satoru Motonami
哲 本並
大祐 篠崎
Daisuke Shinozaki
大祐 篠崎
恭平 勢造
Kyohei SEZUKURI
恭平 勢造
克也 城戸
Katsuya Kido
克也 城戸
山上 真司
Shinji Yamagami
真司 山上
中野 雅行
Masayuki Nakano
雅行 中野
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Sharp Corp
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Sharp Corp
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Priority to JP2017133946A priority Critical patent/JP2020153524A/en
Priority to PCT/JP2018/025510 priority patent/WO2019009358A1/en
Publication of JP2020153524A publication Critical patent/JP2020153524A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G23/00Other table equipment
    • A47G23/02Glass or bottle holders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/18Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Packages (AREA)
  • Table Equipment (AREA)

Abstract

To manage beverages in a storage container to an appropriate temperature.SOLUTION: A cold storage tool 1 controls the temperature of the beverage in a bottle 5. The cold storage tool 1 comprises: a heat exchange unit that is filled with a heat storage material whose phase changes at a predetermined temperature, and is configured such that the heat storage material exchanges heat with the beverage; and a packaging unit 3 surrounding the bottle 5 and the heat exchange unit. The melting point of the heat storage material is 5°C or lower and higher than or equal to the freezing temperature of the beverage. Also, the packaging unit 3 comprises a side surface part formed into a cylindrical shape, and a bottom surface part that is connected to one end of the side surface part to form a closed surface, wherein a diameter D1 of the side surface part on the closed surface side is larger than a diameter D2 of the side surface part on an open end side.SELECTED DRAWING: Figure 1A

Description

本発明は、保存容器内の飲料の温度を管理する保冷用具に関する。 The present invention relates to a cold storage device that controls the temperature of a beverage in a storage container.

従来から、保温物、特に、ワイン、ビール、日本酒等のアルコール類、またはジュース、水等の飲料、或いは食品類、更には医薬品類には、それぞれに適した保存温度が存在し、保温物を所望の保管温度に、より素早く到達させ、かつ、所望の温度で長時間維持が可能な保冷用具が求められている。例えば、飲みごろ温度が求められるワイン等については、ワインボトルを冷やすために氷水を張ったワインクーラーが使用されている。 Conventionally, heat insulating materials, particularly alcohols such as wine, beer, and sake, beverages such as juice and water, foods, and pharmaceuticals have storage temperatures suitable for each, and heat insulating materials are used. There is a need for a cold insulation tool that can reach a desired storage temperature more quickly and can be maintained at a desired temperature for a long time. For example, for wines and the like that require a drinking temperature, a wine cooler filled with ice water is used to cool the wine bottle.

さらに、近年では、熱燗、常温、冷酒として飲まれてきた日本酒(アルコール飲料)に対して、冷蔵温度(5℃)以下で、かつ風味が変化しないよう凍結させない温度で飲むという新しい飲み方が提案されている。 Furthermore, in recent years, a new way of drinking sake (alcoholic beverage), which has been drunk as hot sake, room temperature, and cold sake, has been proposed to drink at a temperature below the refrigeration temperature (5 ° C) and not frozen so that the flavor does not change. Has been done.

特許文献1および特許文献2では、ワインを適温(5〜12℃の温度帯)で維持する技術が開示されている。 Patent Document 1 and Patent Document 2 disclose a technique for maintaining wine at an appropriate temperature (temperature range of 5 to 12 ° C.).

特許第4406683号明細書Japanese Patent No. 4406683 特開2003−202173号公報Japanese Unexamined Patent Publication No. 2003-20173

例えば、日本酒等のアルコール飲料を冷却する際に、一般的な家庭用冷蔵庫の「冷蔵庫」ではなく「冷凍庫」を用いることによって、アルコール飲料を5℃以下にすることができるが、アルコールの度数によっては、アルコール飲料が凍結してしまう場合がある。例えば、アルコール度数が15度の清酒の場合、−18℃で凍結してしまうことが確認されている。このため、飲料を冷却する際には、凍結温度に到達しないように温度管理をする必要がある。 For example, when cooling alcoholic beverages such as sake, the temperature of alcoholic beverages can be lowered to 5 ° C or less by using a "freezer" instead of the "refrigerator" of a general household refrigerator, but depending on the alcohol content. May freeze alcoholic beverages. For example, it has been confirmed that sake with an alcohol content of 15% freezes at -18 ° C. Therefore, when cooling the beverage, it is necessary to control the temperature so that the freezing temperature is not reached.

また、特許文献1で開示されているワインクーラーおよび特許文献2で開示されている保冷保温具は、5℃以上での保冷を目的としたものであり、冷蔵庫(5℃)から取り出した飲料の温度を、さらに下げることができない。また、保冷効果を高めるための保冷対象物を締め付ける構造を有していない。 Further, the wine cooler disclosed in Patent Document 1 and the cold insulation heat insulating device disclosed in Patent Document 2 are intended to keep cold at 5 ° C. or higher, and are used for beverages taken out from a refrigerator (5 ° C.). The temperature cannot be lowered further. In addition, it does not have a structure for tightening a cold insulation object to enhance the cold insulation effect.

本発明は、このような事情に鑑みてなされたものであり、保存容器内の飲料を適切な温度に管理することができる保冷用具を提供することを目的とする。 The present invention has been made in view of such circumstances, and an object of the present invention is to provide a cold insulation tool capable of controlling a beverage in a storage container to an appropriate temperature.

上記の目的を達成するために、本発明は、以下のような手段を講じた。すなわち、本発明の保冷用具は、保存容器内の飲料の温度を管理する保冷用具であって、予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、前記保存容器および前記熱交換部を包囲する包装部と、を備え、前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である。 In order to achieve the above object, the present invention has taken the following measures. That is, the cold insulation tool of the present invention is a cold insulation tool that controls the temperature of the beverage in the storage container, and is filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material exchanges heat with the beverage. A heat exchange unit configured to perform the heat exchange unit, a storage container, and a packaging unit surrounding the heat exchange unit are provided, and the melting point of the heat storage material is 5 ° C. or lower and higher than the freezing temperature of the beverage. ..

本発明によれば、飲料を凍結させることなく十分に冷却することが可能となる。 According to the present invention, it is possible to sufficiently cool the beverage without freezing it.

本実施形態に係る保冷用具の概略を示す図である。It is a figure which shows the outline of the cold insulation tool which concerns on this embodiment. 本実施形態に係る保冷用具の側面部を展開した図である。It is a figure which developed the side surface part of the cold insulation tool which concerns on this embodiment. 本実施形態に係る保冷用具の熱交換部の概略を示す上面図である。It is a top view which shows the outline of the heat exchange part of the cold insulation tool which concerns on this embodiment. 本実施形態に係る保冷用具の熱交換部の概略を示す側面図である。It is a side view which shows the outline of the heat exchange part of the cold insulation tool which concerns on this embodiment. 各実施例および比較例で使用する保冷対象物の概略を示す図である。It is a figure which shows the outline of the cold insulation object used in each Example and comparative example. 清酒の凍結温度確認実験結果を示すグラフである。It is a graph which shows the freezing temperature confirmation experiment result of sake. 水溶性無機塩の一例として塩化ナトリウムについて、式(1)をプロットした図である。It is a figure which plotted the formula (1) about sodium chloride as an example of a water-soluble inorganic salt. 実施例1における保存容器の温度変化を示す図である。It is a figure which shows the temperature change of the storage container in Example 1. FIG. 実施例2および比較例1における各保存容器の温度変化率を示す図である。It is a figure which shows the temperature change rate of each storage container in Example 2 and Comparative Example 1. 実施例2および比較例1における各保存容器の温度変化率をまとめた図である。It is a figure which summarized the temperature change rate of each storage container in Example 2 and Comparative Example 1. 実施例1および実施例2における各保存容器の温度変化率を示す図である。It is a figure which shows the temperature change rate of each storage container in Example 1 and Example 2. FIG. 実施例1および実施例2における各保存容器の温度変化率をまとめた図である。It is a figure which summarized the temperature change rate of each storage container in Example 1 and Example 2. 実施例1および比較例2における各保存容器の温度変化率を示す図である。It is a figure which shows the temperature change rate of each storage container in Example 1 and Comparative Example 2. 実施例1および比較例2における各保存容器の温度変化率をまとめた図である。It is a figure which summarized the temperature change rate of each storage container in Example 1 and Comparative Example 2. 実施例2および比較例2における各保存容器の温度変化率をまとめた図である。It is a figure which summarized the temperature change rate of each storage container in Example 2 and Comparative Example 2.

本発明者らは、日本酒を冷やして飲むニーズが高まっている状況下で、冷やし過ぎて凍結させてしまうことによる不都合を回避するためには、飲料に応じた温度管理が必要であることに着目し、融点が5℃以下であると共に飲料の凍結温度以上である蓄熱材を用いることによって、適切な温度管理ができることを見出し、本発明に至った。 The present inventors have focused on the fact that temperature control according to a beverage is necessary in order to avoid the inconvenience caused by overcooling and freezing in a situation where the need for chilling and drinking sake is increasing. However, they have found that appropriate temperature control can be achieved by using a heat storage material having a melting point of 5 ° C. or lower and a freezing temperature of a beverage or higher, and have reached the present invention.

すなわち、本発明の保冷用具は、保存容器内の飲料の温度を管理する保冷用具であって、予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、前記保存容器および前記熱交換部を包囲する包装部と、を備え、前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である。 That is, the cold insulation tool of the present invention is a cold insulation tool that controls the temperature of the beverage in the storage container, and is filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material exchanges heat with the beverage. A heat exchange unit configured to perform the heat exchange unit, a storage container, and a packaging unit surrounding the heat exchange unit are provided, and the melting point of the heat storage material is 5 ° C. or lower and higher than the freezing temperature of the beverage. ..

これにより、本発明者らは、飲料を凍結させることなく十分に冷却することを可能とした。以下、本発明の実施形態について、図面を参照しながら具体的に説明する。 This made it possible for the present inventors to sufficiently cool the beverage without freezing it. Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings.

[保冷用具の構成]
図1Aは、本実施形態に係る保冷用具の概略を示す図である。図1Bは、本実施形態に係る保冷用具の側面部を展開した図である。熱交換部および保冷用具の閉塞面としての底面部は図示していないが、熱交換部は後述し、底面部は、包装材と同じ材料で概略円形に形成されている。図1Aおよび図1Bに示すように、本実施形態に係る保冷用具1は、2次元的な特定形状を有する包装材3が、3aと3bで重なるように巻回されることによって円筒状に形成されており、これが保冷用具1の側面部となっている。また、保冷用具1の開口端部は、円筒を斜めに切断した形状を有しており、保存容器としての瓶5を収納することによって、瓶5が着物の前身頃を合わせて、着用したような外観を形成することができる。固定ベルト7は、瓶5の首の部分を固定し、瓶5の位置を保冷用具1内部で安定させると共に、飲料を注ぐ際などに保冷用具1から瓶5が外れてしまうことを防止する。
[Composition of cold storage equipment]
FIG. 1A is a diagram showing an outline of a cold insulation tool according to the present embodiment. FIG. 1B is a developed view of a side surface portion of the cold insulation tool according to the present embodiment. The bottom surface of the heat exchange section and the cold insulation tool as the closing surface is not shown, but the heat exchange section will be described later, and the bottom surface is formed of the same material as the packaging material in a substantially circular shape. As shown in FIGS. 1A and 1B, the cold insulation tool 1 according to the present embodiment is formed into a cylindrical shape by winding a packaging material 3 having a specific two-dimensional shape so as to overlap 3a and 3b. This is the side surface of the cold insulation tool 1. Further, the open end of the cold insulation tool 1 has a shape obtained by cutting a cylinder diagonally, and by storing the bottle 5 as a storage container, it seems that the bottle 5 is worn by matching the front body of the kimono. Appearance can be formed. The fixing belt 7 fixes the neck portion of the bottle 5, stabilizes the position of the bottle 5 inside the cold insulation tool 1, and prevents the bottle 5 from coming off from the cold insulation tool 1 when pouring a beverage or the like.

図1Aに示すように、包装材3によって形成された側面部の底面部側の径D1は、側面部の開口端側の径D2よりも大きい。これは、図1Bに示すように、包装材3の展開図が、2次元的な特定形状を有しており、展開図中、紙面に対して下側となる底辺部が、一直線ではなく、点Pを中心に178度の角度を持つように形成されていることから実現されるものである。このように、保冷用具1がいわゆる「テーパ」を有しているため、瓶5を収納した際に、保冷用具1の開口端部が開いてしまうことを防止している。 As shown in FIG. 1A, the diameter D1 on the bottom surface side of the side surface portion formed by the packaging material 3 is larger than the diameter D2 on the open end side of the side surface portion. This is because, as shown in FIG. 1B, the developed view of the packaging material 3 has a two-dimensional specific shape, and in the developed view, the bottom portion that is lower than the paper surface is not a straight line. This is realized because it is formed so as to have an angle of 178 degrees about the point P. As described above, since the cold insulation tool 1 has a so-called "taper", it is possible to prevent the open end portion of the cold insulation tool 1 from opening when the bottle 5 is stored.

また、保冷用具1は、包装材3が重なっている部分に、重なっている包装材3aおよび3bを相互に係止する留め具9が設けられている。留め具9で包装材3aおよび3bを係止することによって、後述する熱交換部20を瓶5に密着させ、冷却効果を高めることが可能となる。この点については後述する。なお、包装材3が保冷用具1の側面部を構成し、側面部と図示しない底面部とが包装部を構成する。なお、包装材3を、伸縮性素材で形成することによって、蓄熱材が融解し、蓄熱材の体積が収縮した場合であっても、瓶5への密着性を維持することが可能となる。 Further, the cold insulation tool 1 is provided with a fastener 9 for locking the overlapping packaging materials 3a and 3b to each other at a portion where the packaging materials 3 overlap. By locking the packaging materials 3a and 3b with the fastener 9, the heat exchange portion 20 described later can be brought into close contact with the bottle 5 to enhance the cooling effect. This point will be described later. The packaging material 3 constitutes a side surface portion of the cold insulation tool 1, and a side surface portion and a bottom surface portion (not shown) constitute a packaging portion. By forming the packaging material 3 with an elastic material, it is possible to maintain the adhesion to the bottle 5 even when the heat storage material melts and the volume of the heat storage material shrinks.

図2Aは、本実施形態に係る保冷用具の熱交換部の概略を示す上面図である。図2Bは、本実施形態に係る保冷用具の熱交換部の概略を示す側面図である。図2Aに示すように、熱交換部20は、蓄熱材22を収納する6つの蓄熱材収納部20aと、各蓄熱材収納部20aを連結する5つの連結部20bとを備えている。このように、蓄熱材収納部20aを複数有する構造を採ることにより、蓄熱材22が凍結した後に、包装材3によって瓶5と密着するように包囲されることで保存容器としての瓶5への接触性が向上する。なお、熱交換部20を構成する蓄熱材収納部20aと連結部20bの数が増えるほど、瓶5に装着した際の外観がスリムになる。なお、ここでは、6つの蓄熱材収納部20aと、5つの連結部20bとを示したが、これらの個数に限定されるわけではない。 FIG. 2A is a top view showing an outline of a heat exchange portion of the cold insulation tool according to the present embodiment. FIG. 2B is a side view showing an outline of a heat exchange portion of the cold insulation tool according to the present embodiment. As shown in FIG. 2A, the heat exchange section 20 includes six heat storage material storage sections 20a for storing the heat storage material 22, and five connecting sections 20b for connecting the heat storage material storage sections 20a. By adopting a structure having a plurality of heat storage material storage portions 20a in this way, after the heat storage material 22 is frozen, the heat storage material 22 is surrounded by the packaging material 3 so as to be in close contact with the bottle 5, so that the bottle 5 can be used as a storage container. Contact is improved. As the number of the heat storage material storage portions 20a and the connecting portions 20b constituting the heat exchange portion 20 increases, the appearance when attached to the bottle 5 becomes slimmer. Although the six heat storage material storage portions 20a and the five connecting portions 20b are shown here, the number is not limited to these.

また、蓄熱材収納部20aは、瓶5と接触する部分に曲面部20cを有している。曲面部20cは、曲率半径が37mmである凹状に形成されている。これにより、瓶5への密着性の向上を図ることが可能となる。その結果、瓶5からの熱吸収性が向上し、温度を下げやすくなる。また、外気に触れる瓶5の表面積が小さくなることで、瓶5内の飲料の温度上昇が抑制される。さらに、余分な出っ張りがなくなり、全体的にごつごつした状態を減少させスリム化を図ることが可能となる。なお、本実施形態では、曲率半径を37mmとしたが、これに限定されるわけではない。曲率半径の範囲としては、好ましくは26.5mm〜46.00mmであるが、日本酒の一升瓶やシャンパンの通常サイズ(750ml)の6倍の容量があるレオボワームサイズ等の曲率サイズであっても良い。なお、曲面部20cの剛性を、それ以外の部分の剛性よりも高くしても良い。これにより、蓄熱材を凍結させた時に発生する体積膨張によって、曲面部20cが変形することを抑制することが可能となる。また、熱交換部20の各蓄熱材収納部20aに、染色液が充填されていても良い。これにより、蓄熱材が漏れたとしても、一目で認識することが可能となる。 Further, the heat storage material storage portion 20a has a curved surface portion 20c at a portion in contact with the bottle 5. The curved surface portion 20c is formed in a concave shape having a radius of curvature of 37 mm. This makes it possible to improve the adhesion to the bottle 5. As a result, the heat absorption from the bottle 5 is improved, and the temperature can be easily lowered. Further, by reducing the surface area of the bottle 5 that comes into contact with the outside air, the temperature rise of the beverage in the bottle 5 is suppressed. Furthermore, extra protrusions are eliminated, and it is possible to reduce the overall rugged state and achieve slimming. In the present embodiment, the radius of curvature is 37 mm, but the present invention is not limited to this. The range of the radius of curvature is preferably 26.5 mm to 46.00 mm, but even if it is a curvature size such as a leoboworm size having a capacity 6 times the normal size (750 ml) of a bottle of sake or champagne. good. The rigidity of the curved surface portion 20c may be higher than the rigidity of the other portions. As a result, it is possible to prevent the curved surface portion 20c from being deformed due to the volume expansion generated when the heat storage material is frozen. Further, each heat storage material storage unit 20a of the heat exchange unit 20 may be filled with a dyeing liquid. As a result, even if the heat storage material leaks, it can be recognized at a glance.

[検証]
次に、本実施形態に係る保冷用具の効果を検証するため、以下の条件で実験を行なった。図3は、各実施例および比較例で使用する保冷対象物の概略を示す図である。冷却対象物は、瓶5に、冷却対象液体として清酒(アルコール度数15度、720ml)が充填されている。冷却対象液体(清酒)は、予め冷蔵庫(5℃)で保冷したものを使用した。環境温度は、23℃である。以下は、各実施例および比較例の保冷用具の構成をまとめた表である。

Figure 2020153524
[Verification]
Next, in order to verify the effect of the cold insulation tool according to this embodiment, an experiment was conducted under the following conditions. FIG. 3 is a diagram showing an outline of a cold insulation target used in each Example and Comparative Example. As the object to be cooled, the bottle 5 is filled with sake (alcohol content 15 degrees, 720 ml) as the liquid to be cooled. As the liquid to be cooled (sake), a liquid that had been previously cooled in a refrigerator (5 ° C.) was used. The ambient temperature is 23 ° C. The following is a table summarizing the configurations of the cold insulation tools of each Example and Comparative Example.
Figure 2020153524

冷却対象液体を保存容器に充填した時の充填高さは、保存容器の底から200mmである。また、各実施例および比較例における温度測定点は、(I)液体中心:底から100mm、(II)液体上部:底から180mmとした。 The filling height when the liquid to be cooled is filled in the storage container is 200 mm from the bottom of the storage container. The temperature measurement points in each of the Examples and Comparative Examples were (I) liquid center: 100 mm from the bottom and (II) liquid top: 180 mm from the bottom.

[凍結温度確認実験]
まず、本実施形態にて使用する保冷対象液体(清酒)の凍結温度確認実験を行なった。清酒(720ml)が充填された保存容器を庫内に静置し、庫内の温度を5時間ごとに1℃ずつ下げ、庫内の温度が何℃の時に凍結するかの実験を行なった。図4は、清酒の凍結温度確認実験結果を示すグラフである。実験の結果、図4に示すように、清酒(アルコール度数15度)は、庫内温度が−18℃の時に凍結することが分かった。この結果から、本実験で用いる清酒は、冷凍庫(−18℃)では凍結する可能性がある。そこで、融点が5℃以下であり、かつ−18℃より高い潜熱蓄熱材(蓄熱材)を用いる必要がある。
[Freezing temperature confirmation experiment]
First, an experiment was conducted to confirm the freezing temperature of the liquid (sake) to be kept cold used in this embodiment. A storage container filled with sake (720 ml) was allowed to stand in the refrigerator, the temperature inside the refrigerator was lowered by 1 ° C. every 5 hours, and an experiment was conducted to determine when the temperature inside the refrigerator would freeze. FIG. 4 is a graph showing the results of an experiment for confirming the freezing temperature of sake. As a result of the experiment, as shown in FIG. 4, it was found that sake (alcohol content 15 ° C.) freezes when the internal temperature is -18 ° C. From this result, the sake used in this experiment may be frozen in the freezer (-18 ° C). Therefore, it is necessary to use a latent heat storage material (heat storage material) having a melting point of 5 ° C. or lower and higher than -18 ° C.

[潜熱蓄熱材]
ここで、本実施形態に用いる潜熱蓄熱材について、説明する。本実施形態に用いる潜熱蓄熱材は、上述したとおり、融点が5℃以下であり、かつ−18℃より高い潜熱蓄熱材料が好ましい。さらに、潜熱蓄熱材の融点は、0℃未満であると、より好ましい。0℃未満の潜熱蓄熱材としては、無機塩の水溶液であることが好ましく、更にその無機塩水溶液の濃度と融点とが式(1)の関係性を満たすことが好ましい。

Figure 2020153524
なお、ここで、Tを融点とし、wを前記水溶性無機塩の重量パーセント濃度とし、Mを前記水溶性無機塩の分子量とし、Rを気体定数とし、Tfを水の融点とし、ΔHを水の潜熱とし、nを1つの水溶性無機塩が水溶液中で電離する数とする。さらに、前記wは、水と前記水溶性無機塩との共晶を与える濃度未満である。 [Latent heat storage material]
Here, the latent heat storage material used in the present embodiment will be described. As described above, the latent heat storage material used in the present embodiment is preferably a latent heat storage material having a melting point of 5 ° C. or lower and higher than -18 ° C. Further, the melting point of the latent heat storage material is more preferably less than 0 ° C. The latent heat storage material having a temperature of less than 0 ° C. is preferably an aqueous solution of an inorganic salt, and more preferably, the concentration of the aqueous inorganic salt solution and the melting point satisfy the relationship of the formula (1).
Figure 2020153524
Here, T is the melting point, w is the weight percent concentration of the water-soluble inorganic salt, M is the molecular weight of the water-soluble inorganic salt, R is the gas constant, Tf is the melting point of water, and ΔH is water. Let n be the number at which one water-soluble inorganic salt is ionized in an aqueous solution. Further, w is less than a concentration that gives eutectic of water and the water-soluble inorganic salt.

これにより、所望の融点をもつ潜熱蓄熱材を水溶性無機塩の濃度を変えるだけで、簡便に設計することができる。また、式(1)は前記wが前記水溶性無機塩との共晶を与える濃度未満の希薄水溶液で成り立つ。前記wが前記水溶性無機塩との共晶を与える濃度付近では、共晶が得られる。共晶状態においては、単一の融点を示し、潜熱が高くなる。そのため保冷温度が一定になり易く、長時間の保冷が可能となる。 Thereby, a latent heat storage material having a desired melting point can be easily designed only by changing the concentration of the water-soluble inorganic salt. Further, the formula (1) consists of a dilute aqueous solution having a concentration of less than w that gives eutectic with the water-soluble inorganic salt. Eutectic is obtained near the concentration at which w gives eutectic with the water-soluble inorganic salt. In the eutectic state, it exhibits a single melting point and a high latent heat. Therefore, the cold insulation temperature tends to be constant, and it is possible to keep the cold insulation for a long time.

また、無機塩としては、塩化ナトリウム、塩化カリウム、塩化カルシウム、塩化マグネシウム、塩化バリウム、塩化アンモニウム、炭酸水素カリウム、炭酸ナトリウム、硝酸ナトリウム、硝酸カリウム、硝酸カルシウム、硝酸マグネシウムが好ましい。また、無機塩の濃度は、各無機塩と水との共晶を与える濃度以下であることが好ましい。共晶を与える濃度を超える量を加えた場合には、共晶を与える濃度での融点以下にはならず、無機塩が過剰に析出するため重量当たりの潜熱が減少する。 Further, as the inorganic salt, sodium chloride, potassium chloride, calcium chloride, magnesium chloride, barium chloride, ammonium chloride, potassium hydrogen carbonate, sodium carbonate, sodium nitrate, potassium nitrate, calcium nitrate and magnesium nitrate are preferable. Further, the concentration of the inorganic salt is preferably equal to or less than the concentration that gives eutectic crystals between each inorganic salt and water. When an amount exceeding the concentration that gives eutectic is added, the temperature does not fall below the melting point at the concentration that gives eutectic, and the latent heat per weight decreases because the inorganic salt is excessively precipitated.

図5は、水溶性無機塩の一例として塩化ナトリウムについて、式(1)をプロットし他図である。なお、水と塩化ナトリウムが共晶を与える濃度は23.3wt%であり、図5は、共晶を与える濃度未満の領域をプロットした図である。保冷対象液体の保冷すべき温度が定まっている場合に、潜熱蓄熱材の融点の高精度な設定が求められるが、図5を用いれば、無機塩の濃度を算出することができ、簡便に潜熱蓄熱材の組成比や材料を決定することが可能となる。また、水と塩化ナトリウムが共晶の融点は−21℃だが、共晶の融点以上であっても、式(1)を用いて無機塩の濃度を調整することで、所望の融点の潜熱蓄熱材を得ることができる。また水と無機塩の共晶濃度付近では、単一の融点を有する共晶が得られる。なお、潜熱蓄熱材を構成する無機塩は、前述した無機塩の内、1種類のみでも良いし、複数の無機塩を混合させたものでも良い。なお、融点が0℃未満の潜熱蓄熱材を用いることによって、氷では実現できない氷点下への冷却が可能となる。 FIG. 5 is another diagram in which the formula (1) is plotted for sodium chloride as an example of a water-soluble inorganic salt. The concentration at which water and sodium chloride give eutectic is 23.3 wt%, and FIG. 5 is a plot of regions below the concentration at which eutectic is given. When the temperature at which the liquid to be kept cold should be kept cold is determined, it is required to set the melting point of the latent heat storage material with high accuracy. However, if FIG. 5 is used, the concentration of the inorganic salt can be calculated and the latent heat can be easily calculated. It is possible to determine the composition ratio and material of the heat storage material. The melting point of the eutectic of water and sodium chloride is -21 ° C, but even if it is above the melting point of the eutectic, latent heat storage at the desired melting point can be achieved by adjusting the concentration of the inorganic salt using the formula (1). The material can be obtained. Further, near the eutectic concentration of water and the inorganic salt, a eutectic having a single melting point can be obtained. The inorganic salt constituting the latent heat storage material may be only one type among the above-mentioned inorganic salts, or may be a mixture of a plurality of inorganic salts. By using a latent heat storage material having a melting point of less than 0 ° C., cooling below the freezing point, which cannot be achieved with ice, becomes possible.

次に、上記の融点を有する潜熱蓄熱材を用いて保冷用具の構成による性能の違いを検証した。 Next, using the latent heat storage material having the above melting point, the difference in performance depending on the configuration of the cold insulation tool was verified.

[1.冷却性能/実施例1]
(実施例1)
・包装材:テーパあり、留め具9あり、とした。
・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、120分間の温度を測定した。
温度測定箇所は、液体中心部、熱交換部20の外側(包装材と容器との間)とした。
[1. Cooling performance / Example 1]
(Example 1)
-Packaging material: There is a taper and there are 9 fasteners.
-The temperature was measured for 120 minutes after the heat exchange section 20 and the packaging material 3 were attached to the storage container (bottle 5).
The temperature measurement points were the center of the liquid and the outside of the heat exchange section 20 (between the packaging material and the container).

図6は、実施例1における保存容器の温度変化を示す図である。図6に示すように、冷蔵庫(5℃)で保冷された液体中心部の温度は、約23分で氷点下まで冷却されている。実施例1の保冷用具は、30分以内に氷点下にする冷却性能を有することが分かった。また、液体中心部の温度は、熱交換部(蓄冷材)温度に向かって冷却されるが、冷却開始から2時間後も凍結はしていないことが分かった。 FIG. 6 is a diagram showing a temperature change of the storage container in Example 1. As shown in FIG. 6, the temperature of the center of the liquid kept cold in the refrigerator (5 ° C.) is cooled to below freezing in about 23 minutes. It was found that the cold insulation tool of Example 1 had a cooling performance to bring the temperature below freezing within 30 minutes. Further, it was found that the temperature of the central part of the liquid was cooled toward the temperature of the heat exchange part (cold storage material), but was not frozen even 2 hours after the start of cooling.

[2.テーパの有無の効果/実施例2と比較例1の比較]
次に、テーパの有無の効果について、実施例2および比較例1を用いて検証した。比較方法は、以下に示す式(2)により算出される温度変化を用いて、正規化した値での比較を行なった。これは、冷蔵庫から取り出した時の温度が異なるためである。
[2. Effect of presence / absence of taper / Comparison between Example 2 and Comparative Example 1]
Next, the effect of the presence or absence of taper was verified using Example 2 and Comparative Example 1. As a comparison method, a comparison was performed using normalized values using the temperature change calculated by the following equation (2). This is because the temperature when taken out from the refrigerator is different.

温度変化率=(測定時液体温度−初期液体温度)/初期液体温度・・・(2)
ここで、温度変化率が0以上は温度上昇、0未満は温度低下を意味する。
Temperature change rate = (liquid temperature at the time of measurement-initial liquid temperature) / initial liquid temperature ... (2)
Here, a temperature change rate of 0 or more means a temperature rise, and a temperature change rate of less than 0 means a temperature decrease.

(実施例2)
・包装材:テーパあり、留め具9なし、とした。
・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
温度測定箇所は、液体中心部、液体上部とした。
(比較例1)
・包装材:テーパなし、留め具9なしとした。
・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
温度測定箇所は、液体中心部、液体上部とした。
(Example 2)
-Packaging material: with taper and without fastener 9.
-After attaching the heat exchange unit 20 and the packaging material 3 to the storage container (bottle 5), the temperature was measured for 30 minutes.
The temperature measurement points were the central part of the liquid and the upper part of the liquid.
(Comparative Example 1)
-Packaging material: No taper, no fastener 9.
-After attaching the heat exchange unit 20 and the packaging material 3 to the storage container (bottle 5), the temperature was measured for 30 minutes.
The temperature measurement points were the central part of the liquid and the upper part of the liquid.

図7Aは、実施例2および比較例1における各保存容器の温度変化率を示す図である。図7Bは、実施例2および比較例1における各保存容器の温度変化率をまとめた図である。30分後の温度変化比率について、「液体中心部」については、ほぼ差が見られなかった。すなわち、比較例1が3%のみ低く、これは温度低下率が3%高いということとなり、冷却されたこととなる。一方、「液体上部」については、比較例1の温度変化率が実施例2の温度変化率よりも22%高かった。つまり、液体上部は、温度上昇率が22%高く、温度が上がり易いといえる。 FIG. 7A is a diagram showing the temperature change rate of each storage container in Example 2 and Comparative Example 1. FIG. 7B is a diagram summarizing the temperature change rate of each storage container in Example 2 and Comparative Example 1. Regarding the temperature change ratio after 30 minutes, there was almost no difference in the "liquid center". That is, Comparative Example 1 was only 3% lower, which means that the temperature decrease rate was 3% higher, which means that it was cooled. On the other hand, for the "upper part of the liquid", the temperature change rate of Comparative Example 1 was 22% higher than that of Example 2. That is, it can be said that the temperature rise rate of the upper part of the liquid is 22% higher and the temperature rises easily.

以上の結果、テーパを設けることで、液体中心部においては冷却効果が得られ、液体上部においては、温度上昇を抑制する効果が得られ、特に、液体上部の温度上昇率を抑制することが可能となることが分かった。 As a result of the above, by providing the taper, a cooling effect can be obtained in the central part of the liquid, an effect of suppressing the temperature rise can be obtained in the upper part of the liquid, and in particular, the temperature rise rate of the upper part of the liquid can be suppressed. It turned out to be.

[3.留め具の有無の効果/実施例1と実施例2の比較]
次に、留め具9の有無の効果について、実施例1および実施例2を用いて検証した。比較方法は、テーパの有無の効果の比較方法と同様の方法で比較を行なった。
[3. Effect of presence / absence of fastener / Comparison of Example 1 and Example 2]
Next, the effect of the presence or absence of the fastener 9 was verified using Example 1 and Example 2. The comparison method was the same as the method for comparing the effects of the presence or absence of taper.

(実施例1)
・包装材:テーパあり、留め具(マジックテープ(登録商標))あり、とした。
・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
温度測定箇所は、液体中心部、液体上部とした。
(実施例2)
・包装材:テーパあり、留め具なし、とした
・保存容器(瓶5)に対して、熱交換部20および包装材3を装着後、30分間の温度を測定した。
温度測定箇所は、液体中心部、液体上部とした。
(Example 1)
-Packaging material: Tapered and fasteners (magic tape (registered trademark)).
-After attaching the heat exchange unit 20 and the packaging material 3 to the storage container (bottle 5), the temperature was measured for 30 minutes.
The temperature measurement points were the central part of the liquid and the upper part of the liquid.
(Example 2)
-Packaging material: Tapered, without fasteners-The temperature was measured for 30 minutes after the heat exchange section 20 and the packaging material 3 were attached to the storage container (bottle 5).
The temperature measurement points were the central part of the liquid and the upper part of the liquid.

図8Aは、実施例1および実施例2における各保存容器の温度変化率を示す図である。図8Bは、実施例1および実施例2における各保存容器の温度変化率をまとめた図である。図8Bに示すように、実施例1の温度変化率は、「液体上部」において実施例2よりも8%低下しており、「液体中心部」において実施例2よりも28%低下している。つまり、留め具9を設けることにより、液体上部、液体中心部ともに温度上昇率を低下させることが可能となり、特に、液体中心部の温度上昇を低下させることが可能となることが分かった。なお、本実施形態では、留め具9として、マジックテープ(登録商標)を用いたが、包装材3の重なった部分を係止することができれば、何でも良く、これに限定されるわけではない。 FIG. 8A is a diagram showing the temperature change rate of each storage container in Example 1 and Example 2. FIG. 8B is a diagram summarizing the temperature change rate of each storage container in Example 1 and Example 2. As shown in FIG. 8B, the temperature change rate of Example 1 is 8% lower than that of Example 2 in the “upper part of the liquid” and 28% lower than that of Example 2 in the “center part of the liquid”. .. That is, it was found that by providing the fastener 9, it is possible to reduce the temperature rise rate in both the upper part of the liquid and the central part of the liquid, and in particular, it is possible to reduce the temperature rise in the central part of the liquid. In the present embodiment, the velcro (registered trademark) is used as the fastener 9, but anything is acceptable as long as the overlapping portion of the packaging material 3 can be locked, and the present invention is not limited to this.

[4.被覆率の効果/実施例1、実施例2と比較例2の比較]
次に、被覆率の効果について、実施例1、実施例2および比較例2を用いて検証した。すなわち、熱交換部20が、瓶5における飲料の充填高さに対して、どのくらいを被覆するかに応じて比較を行なった。被覆率以外のその他の構成、温度測定箇所、温度測定時間は、上記各検証と同様である。
[4. Effect of coverage / Comparison of Example 1, Example 2 and Comparative Example 2]
Next, the effect of the coverage was verified using Example 1, Example 2, and Comparative Example 2. That is, a comparison was made according to how much the heat exchange unit 20 covers the filling height of the beverage in the bottle 5. Other configurations other than the coverage, temperature measurement location, and temperature measurement time are the same as in each of the above verifications.

(実施例1、実施例2)
被覆率:87.0%
その他の構成、温度測定箇所、温度測定時間は、前述と同様である。
(Example 1, Example 2)
Coverage: 87.0%
Other configurations, temperature measurement points, and temperature measurement times are the same as described above.

(比較例2)
被覆率:79.5%
その他の構成、温度測定箇所、温度測定時間は、前述と同様である。
(Comparative Example 2)
Coverage: 79.5%
Other configurations, temperature measurement points, and temperature measurement times are the same as described above.

図9Aは、実施例1および比較例2における各保存容器の温度変化率を示す図である。図9Bは、実施例1および比較例2における各保存容器の温度変化率をまとめた図である。図9Bに示すように、「液体中心部」の温度変化率は、比較例2が14%高い。また、「液体上部」の温度変化率についても、比較例2が5%高い。つまり、被覆率を上げることにより冷却性能は向上することが分かった。 FIG. 9A is a diagram showing the temperature change rate of each storage container in Example 1 and Comparative Example 2. FIG. 9B is a diagram summarizing the temperature change rate of each storage container in Example 1 and Comparative Example 2. As shown in FIG. 9B, the temperature change rate of the “liquid center” is 14% higher in Comparative Example 2. Further, the temperature change rate of the “upper part of the liquid” is also 5% higher in Comparative Example 2. That is, it was found that the cooling performance is improved by increasing the coverage.

図9Cは、実施例2および比較例2における各保存容器の温度変化率をまとめた図である。図9Cに示すように、実施例2および比較例2において、30分後の温度変化率を比較すると、比較例2の方が実施例2よりも冷却性能が高いことが分かった。したがって、少なくとも被覆率が79.5%以上であれば、冷却性能を向上させることが可能であることが分かった。 FIG. 9C is a diagram summarizing the temperature change rate of each storage container in Example 2 and Comparative Example 2. As shown in FIG. 9C, when the temperature change rates after 30 minutes were compared in Example 2 and Comparative Example 2, it was found that Comparative Example 2 had higher cooling performance than Example 2. Therefore, it was found that the cooling performance can be improved if the coverage is at least 79.5% or more.

なお、蓄熱材22は、熱交換部20の製造工程上、充填時の操作性を向上させるために増粘性を有していることが望ましい。この場合、蓄熱材22に増粘剤を混入させることで実現可能である。 It is desirable that the heat storage material 22 has a thickening property in order to improve the operability at the time of filling in the manufacturing process of the heat exchange unit 20. In this case, it can be realized by mixing a thickener into the heat storage material 22.

また、冷却対象液体を充填する瓶5等の保存容器は、少なくとも一部に温度表示機能を有していても良い。この温度表示機能は、例えば、示温材を瓶5等の保存容器に塗布(印字)しても良いし、保存容器自体が示温材を含有する素材で作られたものでも良い。これにより、冷却対象液体の温度を把握することが可能となる。さらに、上記示温材は、6℃(または、冷蔵温度)で変色または消色するほうが好ましい。これは、冷蔵室で保冷した飲料物をさらに冷却することを前提とした場合、保存容器が冷蔵温度帯になったかどうかが分かることで、保冷用具を装着するタイミングが分かり、使用者が保冷用具の本来の性能を発揮する適切なタイミングを知ることが可能となるためである。 Further, the storage container such as the bottle 5 filled with the liquid to be cooled may have a temperature display function at least in part. For this temperature display function, for example, the temperature indicating material may be applied (printed) to a storage container such as a bottle 5, or the storage container itself may be made of a material containing the temperature indicating material. This makes it possible to grasp the temperature of the liquid to be cooled. Further, it is preferable that the temperature indicating material is discolored or decolorized at 6 ° C. (or refrigerating temperature). This is based on the assumption that the beverage that has been kept cold in the refrigerating room will be further cooled, and by knowing whether or not the storage container has reached the refrigerating temperature range, the timing of installing the cold storage device can be known, and the user can know the cold storage device. This is because it is possible to know the appropriate timing for demonstrating the original performance of.

また、本発明は、以下の態様を採ることも可能である。 The present invention can also take the following aspects.

(A)本発明の一形態に係る保冷用具は、保存容器内の飲料の温度を管理する保冷用具であって、予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、前記保存容器および前記熱交換部を包囲する包装部と、を備え、前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である。 (A) The cold storage tool according to one embodiment of the present invention is a cold storage tool that controls the temperature of a beverage in a storage container, and is filled with a heat storage material that changes phase at a predetermined temperature, and the heat storage material is the said. A heat exchange unit configured to exchange heat with a beverage, a storage container, and a packaging unit surrounding the heat exchange unit are provided, and the heat storage material has a melting point of 5 ° C. or lower and the beverage has a melting point of 5 ° C. or lower. It is above the freezing temperature.

(B)また、本発明の一形態に係る保冷用具において、前記包装部は、円筒状に形成された側面部と、前記側面部の一端と結合し閉塞面を形成する底面部と、を備え、前記側面部の前記閉塞面側の径は、前記側面部の開口端側の径よりも大きい。 (B) Further, in the cold insulation tool according to one embodiment of the present invention, the packaging portion includes a side surface portion formed in a cylindrical shape and a bottom surface portion that is combined with one end of the side surface portion to form a closed surface. The diameter of the side surface portion on the closed surface side is larger than the diameter of the side surface portion on the opening end side.

(C)また、本発明の一形態に係る保冷用具において、前記側面部は、2次元的な特定形状を有する包装材が一部で重なるように巻回されることによって円筒状に形成されている。 (C) Further, in the cold insulation tool according to one embodiment of the present invention, the side surface portion is formed into a cylindrical shape by being wound so as to partially overlap packaging materials having a specific two-dimensional shape. There is.

(D)また、本発明の一形態に係る保冷用具は、前記包装材が重なっている部分に設けられ、前記各包装材を相互に係止する留め具をさらに備える。 (D) Further, the cold insulation tool according to one embodiment of the present invention is provided at a portion where the packaging materials overlap, and further includes a fastener for locking the packaging materials to each other.

(E)また、本発明の一形態に係る保冷用具において、前記熱交換部は、前記蓄熱材を収納する複数の蓄熱材収納部と、前記各蓄熱材収納部を連結する連結部と、を備え、前記保存容器の表面に沿って接触する。 (E) Further, in the cold insulation tool according to one embodiment of the present invention, the heat exchange unit includes a plurality of heat storage material storage units for storing the heat storage material and a connecting portion for connecting the heat storage material storage units. Provided and contacted along the surface of the storage container.

(F)また、本発明の一形態に係る保冷用具において、前記各蓄熱材収納部は、前記保存容器と接触し前記保存容器の表面に適合する曲面部を有する。 (F) Further, in the cold insulation tool according to one embodiment of the present invention, each of the heat storage material storage portions has a curved surface portion that comes into contact with the storage container and conforms to the surface of the storage container.

(G)また、本発明の一形態に係る保冷用具において、前記熱交換部は、前記保存容器内の前記飲料の充填高さに対して、79.5%以上を被覆する。 (G) Further, in the cold insulation tool according to one embodiment of the present invention, the heat exchange section covers 79.5% or more of the filling height of the beverage in the storage container.

(H)また、本発明の一形態に係る保冷用具において、前記蓄熱材の融点は、0℃未満である。 (H) Further, in the cold insulation tool according to one embodiment of the present invention, the melting point of the heat storage material is less than 0 ° C.

(I)また、本発明の一形態に係る保冷用具において、前記蓄熱材は、水および水溶性無機塩を含み、融点をTとし、前記水溶性無機塩の重量パーセント濃度をwとし、前記水溶性無機塩の分子量をMとし、気体定数をRとし、水の融点をTfとし、ΔHを水の潜熱とし、1つの水溶性無機塩が水溶液中で電離する数をnとし、前記wを水と前記水溶性無機塩との共晶を与える濃度未満であるとしたときに、次式を満たす。

Figure 2020153524
(I) Further, in the cold insulation tool according to one embodiment of the present invention, the heat storage material contains water and a water-soluble inorganic salt, has a melting point of T, and has a weight percent concentration of the water-soluble inorganic salt as w. The molecular weight of the sex inorganic salt is M, the gas constant is R, the melting point of water is Tf, ΔH is the latent heat of water, the number of ionizing one water-soluble inorganic salt in an aqueous solution is n, and w is water. When the concentration is less than the concentration that gives eutectic with the water-soluble inorganic salt, the following equation is satisfied.
Figure 2020153524

(J)また、前記蓄熱材は、水および水溶性無機塩を含み、前記水溶性無機塩の重量パーセント濃度が、水と前記水溶性無機塩との共晶を与える濃度である。 (J) Further, the heat storage material contains water and a water-soluble inorganic salt, and the weight percent concentration of the water-soluble inorganic salt is a concentration that gives eutectic crystals of water and the water-soluble inorganic salt.

(K)また、本発明の一形態に係る保冷用具において、前記包装材は、伸縮性素材で形成された。 (K) Further, in the cold insulation tool according to one embodiment of the present invention, the packaging material is formed of an elastic material.

(L)また、本発明の一形態に係る保冷用具において、前記曲面部は、剛性が前記曲面部以外の部分の剛性よりも高い。 (L) Further, in the cold insulation tool according to one embodiment of the present invention, the rigidity of the curved surface portion is higher than the rigidity of the portion other than the curved surface portion.

(M)また、本発明の一形態に係る保冷用具において、前記熱交換部には染色液が充填されている。 (M) Further, in the cold insulation tool according to one embodiment of the present invention, the heat exchange portion is filled with a dyeing solution.

以上説明したように、本実施形態によれば、飲料を凍結させることなく十分に冷却することが可能となる。 As described above, according to the present embodiment, it is possible to sufficiently cool the beverage without freezing it.

1 保冷用具
3、3a、3b 包装材
5 瓶
7 固定ベルト
9 留め具
20 熱交換部
20a 蓄熱材収納部
20b 連結部
20c 曲面部
22 蓄熱材
1 Cold insulation tool 3, 3a, 3b Packaging material 5 Bottle 7 Fixing belt 9 Fastener 20 Heat exchange part 20a Heat storage material storage part 20b Connecting part 20c Curved surface part 22 Heat storage material

Claims (13)

保存容器内の飲料の温度を管理する保冷用具であって、
予め定められた温度で相変化する蓄熱材が充填され、前記蓄熱材が前記飲料と熱交換を行なうように構成された熱交換部と、
前記保存容器および前記熱交換部を包囲する包装部と、を備え、
前記蓄熱材の融点は、5℃以下であると共に前記飲料の凍結温度以上である保冷用具。
A cold storage device that controls the temperature of beverages in a storage container.
A heat exchange unit filled with a heat storage material that changes its phase at a predetermined temperature so that the heat storage material exchanges heat with the beverage.
The storage container and the packaging part surrounding the heat exchange part are provided.
A cold insulation tool having a melting point of 5 ° C. or lower and a freezing temperature or higher of the beverage.
前記包装部は、円筒状に形成された側面部と、
前記側面部の一端と結合し閉塞面を形成する底面部と、を備え、
前記側面部の前記閉塞面側の径は、前記側面部の開口端側の径よりも大きい請求項1記載の保冷用具。
The packaging portion includes a side portion formed in a cylindrical shape and a side portion.
A bottom surface portion that is coupled to one end of the side surface portion to form a closed surface is provided.
The cold insulation tool according to claim 1, wherein the diameter of the side surface portion on the closed surface side is larger than the diameter on the opening end side of the side surface portion.
前記側面部は、2次元的な特定形状を有する包装材が一部で重なるように巻回されることによって円筒状に形成された請求項2記載の保冷用具。 The cold insulation tool according to claim 2, wherein the side surface portion is formed into a cylindrical shape by being wound so as to partially overlap packaging materials having a specific two-dimensional shape. 前記包装材が重なっている部分に設けられ、前記各包装材を相互に係止する留め具をさらに備える請求項3記載の保冷用具。 The cold insulation tool according to claim 3, further comprising a fastener that is provided at a portion where the packaging materials overlap and that locks the packaging materials to each other. 前記熱交換部は、
前記蓄熱材を収納する複数の蓄熱材収納部と、
前記各蓄熱材収納部を連結する連結部と、を備え、
前記保存容器の表面に沿って接触する請求項1から請求項4のいずれかに記載の保冷用具。
The heat exchange unit
A plurality of heat storage material storage units for storing the heat storage material, and
A connecting portion for connecting each of the heat storage material storage portions is provided.
The cold insulation tool according to any one of claims 1 to 4, which comes into contact with the surface of the storage container.
前記各蓄熱材収納部は、前記保存容器と接触し前記保存容器の表面に適合する曲面部を有する請求項5記載の保冷用具。 The cold storage tool according to claim 5, wherein each of the heat storage material storage portions has a curved surface portion that comes into contact with the storage container and conforms to the surface of the storage container. 前記熱交換部は、前記保存容器内の前記飲料の充填高さに対して、79.5%以上を被覆する請求項1から請求項6のいずれかに記載の保冷用具。 The cold storage tool according to any one of claims 1 to 6, wherein the heat exchange unit covers 79.5% or more of the filling height of the beverage in the storage container. 前記蓄熱材の融点は、0℃未満である請求項1から請求項7のいずれかに記載の保冷用具。 The cold storage tool according to any one of claims 1 to 7, wherein the melting point of the heat storage material is less than 0 ° C. 前記蓄熱材は、水および水溶性無機塩を含み、
融点をTとし、
前記水溶性無機塩の重量パーセント濃度をwとし、
前記水溶性無機塩の分子量をMとし、
気体定数をRとし、
水の融点をTfとし、
ΔHを水の潜熱とし、
1つの水溶性無機塩が水溶液中で電離する数をnとし、
前記wを水と前記水溶性無機塩との共晶を与える濃度未満であるとしたときに、次式を満たす請求項1から請求項8のいずれかに記載の保冷用具。
Figure 2020153524
The heat storage material contains water and a water-soluble inorganic salt, and contains water.
Let T be the melting point
Let w be the weight percent concentration of the water-soluble inorganic salt.
Let M be the molecular weight of the water-soluble inorganic salt.
Let R be the gas constant
Let Tf be the melting point of water
Let ΔH be the latent heat of water
Let n be the number of one water-soluble inorganic salt ionized in the aqueous solution.
The cold insulation tool according to any one of claims 1 to 8, which satisfies the following formula, assuming that w is less than a concentration that gives eutectic of water and the water-soluble inorganic salt.
Figure 2020153524
前記蓄熱材は、水および水溶性無機塩を含み、
前記水溶性無機塩の重量パーセント濃度が、水と前記水溶性無機塩との共晶を与える濃度である請求項1から請求項8の何れかに記載の保冷用具。
The heat storage material contains water and a water-soluble inorganic salt, and contains water.
The cold insulation tool according to any one of claims 1 to 8, wherein the weight percent concentration of the water-soluble inorganic salt is a concentration that gives eutectic crystals of water and the water-soluble inorganic salt.
前記包装材は、伸縮性素材で形成された請求項3または請求項4記載の保冷用具。 The cold insulation tool according to claim 3 or 4, wherein the packaging material is made of an elastic material. 前記曲面部は、剛性が前記曲面部以外の部分の剛性よりも高い請求項6記載の保冷用具。 The cold insulation tool according to claim 6, wherein the curved surface portion has a rigidity higher than that of a portion other than the curved surface portion. 前記熱交換部には染色液が充填されている請求項1から請求項12のいずれかに記載の保冷用具。 The cold insulation tool according to any one of claims 1 to 12, wherein the heat exchange unit is filled with a dyeing solution.
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