WO2019004600A1

WO2019004600A1 - Dental manicure and preparation method therefor

Info

Publication number: WO2019004600A1
Application number: PCT/KR2018/005820
Authority: WO
Inventors: 정용
Original assignee: 정용
Priority date: 2017-06-29
Filing date: 2018-05-23
Publication date: 2019-01-03
Also published as: KR101793877B1

Abstract

A dental manicure according to the present invention comprises, on the basis of the weight of the total dental manicure composition, 20-40 parts by weight of purified water, 20-30 parts by weight of ethanol, 1-20 parts by weight of shellac, 1-10 parts by weight of a rosin ester, 0.5-15 parts by weight of methacrylic acid-ethyl acrylate, 1-10 parts by weight of a silicone-based water repellent, 0.1-5 parts by weight of a surfactant, 5-20 parts by weight of titanium dioxide, 0.01-1 parts by weight of alanine, 0.1-5 parts by weight of glucose, 0.01-1 parts by weight of alliinase and 0.01-1 parts by weight of alliin.

Description

Tooth manicure and its manufacturing method

The present invention relates to a dental nail polish and a method for manufacturing the dental nail, and more particularly, it relates to a dental nail polish which is applied to a tooth and dried to show a temporary whitening effect on a tooth, The present invention relates to a tooth nail polish which can be easily detached without requiring a separate remover while having an adhesive strength, and a method for manufacturing the same.

It is known to use a whitening gel or a laser as a known tooth whitening technique to date. This conventional tooth whitening technique is used to eliminate acquired coloration, but has the disadvantage that the desired whiteness is not achieved because it can be restored to its original color except for a small number of people.

In addition, the whitening gel or laser in this tooth whitening technique is disadvantageous because it requires a skilled technician to perform the procedure, and the operation is troublesome and the operation time is long and repetitive treatment is required.

Therefore, in order to solve such a problem, recently, a coating agent for teeth, which is applied to teeth for cosmetic purposes, has been developed and used for imparting a cosmetic effect of white to teeth and glossiness.

Such a tooth dressing agent has been colored with a vinyl acetate resin colored by dispersing and processing titanium oxide. In the case of a conventional tooth dressing agent, not only the water resistance is not sufficient but also the resin film Swelling, and the coating film easily disappeared.

In order to solve such a problem, Japanese Patent Application Laid-Open No. 1999-071219 discloses an "application liquid".

The present invention improves the durability of a coating mainly composed of a ceramic or a vinyl acetate resin so that it does not fall off even after a sufficient time has elapsed after application and is applied to a tooth which is safe to the human body and has gloss and fastness A water repellent agent, in particular a silicone water repellent agent such as trimethylsiloxy silicate, is added to the tooth coating liquid to apply it to a coating mainly composed of cellulosic or vinyl acetate resin without deteriorating adhesiveness to teeth Durability, safety, and gloss that are hardly invaded by saliva are provided.

In addition to the technique of applying tooth coating solution, it can be applied to teeth and dried to show a temporary whitening effect on teeth. It is harmless to human body and is realized as a peel-off type, There is a need to develop a tooth nail polish and a method for manufacturing the tooth nail which can be easily detached without necessity.

Disclosure of the Invention The present invention has been conceived to overcome the above problems of the prior art, and it is an object of the present invention to provide a temporary whitening effect on a tooth by applying to a tooth and drying it. It is harmless to a human body and has a sufficient adhesive force, It is an object of the present invention to provide a composition for a nail polish for teeth which can be easily detached.

It is another object of the present invention to provide a constitution of an additive material and a method for producing the additive material which can exhibit water resistance together with a sufficient film property so as to realize a peel off type.

It is still another object of the present invention to provide a method for manufacturing a dental nail polish which can provide a uniform dispersibility between the respective materials and can exhibit high adhesiveness with the same.

It is a further object of the present invention to provide a pretreatment method of a cell lock which can exhibit high tackiness with high color clarity.

In order to achieve the above object, the present invention provides a tooth manicure comprising 20 to 40 parts by weight of purified water, 20 to 30 parts by weight of ethanol, 1 to 20 parts by weight of a shellac, 1 to 10 parts by weight of rosin ester, 0.5 to 15 parts by weight of methacrylic acid-ethyl acrylate, 1 to 10 parts by weight of a silicone-based water repellent, 0.1 to 5 parts by weight of a surfactant, 0.01 to 1 part by weight of alanine, 0.1 to 5 parts by weight of glucose, 0.01 to 1 part by weight of allylnase and 0.01 to 1 part by weight of allyl.

In addition, the dental nail polish may further comprise 0.1 to 5 parts by weight of an inorganic pigment and 1 to 15 parts by weight of an auxiliary coating agent, based on the weight of the entire dental nail varnish composition.

The auxiliary coating agent may be at least one selected from the group consisting of N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxybutane butyl methacrylate copolymer, carboxymethylcellulose, polyvinylpyrrolidone, Methyl cellulose, sodium carboxymethyl cellulose, polyvinyl alcohol, and the like.

In addition, there is provided a method for manufacturing a tooth nail polish, comprising: preparing a coating base liquid comprising 60 to 95 parts by weight of purified water and 5 to 40 parts by weight of a shellac; 3 to 30 parts by weight of rosin ester and 1 to 45 parts by weight of methacrylic acid-ethyl acrylate are mixed with 50 to 70 parts by weight of ethanol to prepare a resin base solution; Mixing the coating base solution and the resin base solution at a weight ratio of 1: 1 to 2: 1 to prepare a coating mixture solution; Adding 50 to 30 parts by weight of titanium dioxide to the weight of the coating mixture and stirring at 100 to 200 rpm for 3 to 10 minutes to prepare a dispersion; 40 to 60 parts by weight of glucose, 1 to 20 parts by weight of alanine, 1 to 20 parts by weight of alliinase and 1 to 20 parts by weight of alanine to prepare a viscous solution; Mixing the dispersion liquid and the adhesive liquid at a weight ratio of 8: 1 to 10: 1 to prepare a coating liquid; And 1 to 10 parts by weight of a silicone water repellent and 0.1 to 5 parts by weight of a surfactant based on the weight of the coating liquid to prepare a manicure composition.

The present invention provides a dental nail polish and a method of manufacturing the same,

1) A toothpaste manicure which can be applied to teeth and dried to exhibit a temporary whitening effect on teeth, and which can be detached easily without requiring a separate remover while having a sufficient adhesion to a human body and being harmless,

2) not only has a sufficient film property to realize a peel-off type, but also exhibits water resistance,

3) a method of manufacturing a dental nail polish which can provide a uniform dispersibility between the respective materials and can exhibit high adhesiveness with the same,

4) A pretreatment method of a celllock capable of exhibiting high tackiness with high color clarity was provided.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flowchart showing a basic manufacturing method of a dental nail polish of the present invention.

Figure 2 is a flow chart showing the steps of producing the coating base liquid of the present invention.

3 is a flow chart showing the step of producing the auxiliary coating liquid of the present invention.

4 is a table showing test results of the present invention.

Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. The accompanying drawings are not drawn to scale and wherein like reference numerals in the various drawings refer to like elements.

The tooth nail polish according to the present invention comprises 20 to 40 parts by weight of purified water, 20 to 30 parts by weight of ethanol, 20 to 30 parts by weight of shellac 1 1 to 10 parts by weight of rosin ester, 0.5 to 15 parts by weight of methacrylic acid-ethyl acrylate, 1 to 10 parts by weight of a silicone-based water repellent agent, 0.1 to 5 parts by weight of a surfactant, 5 to 20 parts by weight of titanium dioxide, 0.01 to 1 part by weight of alanine, 0.1 to 5 parts by weight of glucose, 0.01 to 1 part by weight of allylene and 0.01 to 1 part by weight of allyl.

At this time, a white color can be obtained through cellulosic and titanium dioxide, and the added rosin ester, methacrylic acid-ethyl acrylate, and cellar can also provide sufficient adhesion. At this time, the cellul is a kind of animal resin and exhibits sticky tackiness and at the same time shows a white color and can be used as a constituent material of a dental nail polish. In addition, it shows high safety in the body.

In addition, when the silicone-based water repellent agent is added, water repellency is exhibited, and even when applied to the tooth surface, the coating film is not easily swelled by the saliva, so that the coated nail polish composition does not easily fall off. As the silicone water repellent agent, any one selected from the group consisting of epoxy-modified silicone oil, silicone resin, methylhydrogen silicone, and trimethylsiloxy silicate may be used.

In addition to this, the dental nail polish composition of the present invention includes alanine, glucose, alginase, and aline, which are proteins and saccharides that can be extracted from garlic, And at the same time, it is expected to improve the adhesiveness through alliinase and alginine. In addition, antiseptic properties can be expected because it contains many active ingredients of garlic.

In addition, a surfactant is added. The surfactant is added to obtain a more uniform mixture by increasing the dispersibility among the materials contained in the nail polish composition for a tooth, and there is no limitation on the kind thereof, but preferably, polysorbate 80 .

Such a tooth nail polish can be applied to the tooth surface after application of a separate adhesive, or can be applied to the tooth surface without using an adhesive to perform its function. In order to improve adhesiveness, a material capable of acting as a primer or an adhesive is applied to the surface of the tooth and then the tooth nail polish is applied to the top surface of the tooth. At this time, as the primer and adhesive, there are used alanine, glucose, Natural primer and glue containing the active ingredient extracted from garlic, including algin, may be used.

Such a tooth nail polish is preferably applied to the tooth surface to form a dense film, so that it is not easily swollen. However, it may be gradually melted or disappear naturally over time, or it may be removed by brushing or the like.

Further, in order to more conveniently remove the tooth nail polish of the present invention, the tooth nail polish of the present invention may be manufactured as a peel-off type. In case of discontinuing use, the tooth nail polish formed on the tooth surface To be removed through a nail or the like so as to be neatly removed.

To this end, the toothpaste nail polish may further comprise 0.1 to 5 parts by weight of an inorganic pigment and 1 to 15 parts by weight of an auxiliary coating agent, based on the weight of the entire tooth nail polish composition, wherein the auxiliary coating agent has a strength and a water resistance So that the film can be maintained firmly and can be dropped neatly when removed. In addition, it is possible to obtain a higher color through the addition of an inorganic pigment, and various colors can be realized because there is no limitation on the kind of the inorganic pigment.

At this time, the auxiliary coating agent is preferably N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxybutane butyl methacrylate copolymer, carboxymethylcellulose, polyvinylpyrrolidone, Methyl cellulose, sodium carboxymethyl cellulose, and polyvinyl alcohol may be used, and the above-described materials may be used in combination as an auxiliary coating agent.

Such an auxiliary coating agent may be added in a range of 15 parts by weight with respect to the weight of the composition of the entire tooth nail polish, or may be applied to the teeth by applying the auxiliary nail polish composition to the upper surface thereof. have.

A method of manufacturing the dental nail polish of the present invention will be described with reference to the drawings.

1 is a flowchart showing a basic manufacturing method of a tooth nail polish of the present invention.

1, a method of manufacturing a tooth nail polish according to the present invention includes the steps of: (S100) preparing a coating base liquid; (S200) preparing a resin base liquid; S300); (S600); and a step (S700) of manufacturing a nail polish composition (S700). The method for producing a nail polish composition according to the present invention comprises the steps of: . Each step will be described in detail as follows.

코팅 베이스액을 제조하는 단계(S100)A step (S100) of preparing a coating base liquid

First, a process for producing a coating base liquid comprising 60 to 95 parts by weight of purified water and 5 to 40 parts by weight of a cellar is carried out. As described above, since cellul, which is a kind of animal resin, exhibits hydrophilicity, it is easily dispersed in purified water. This cell-lock is mixed with purified water to prepare a coating base liquid to be the base of the nail polish composition.

수지 베이스액을 제조하는 단계(S200)The step of manufacturing the resin base liquid (S200)

Next, the resin base solution is prepared by mixing 3 to 30 parts by weight of rosin ester and 1 to 45 parts by weight of methacrylic acid-ethyl acrylate with 50 to 70 parts by weight of ethanol. Rosin ester and methacrylic acid-ethyl acrylate function as an adhesive material for easily adhering to tooth surfaces and are dissolved in an ethanol solvent to form a resin base solution.

코팅 혼합액을 제조하는 단계(S300)A step (S300) of preparing a coating mixture solution

When the preparation of the coating base liquid and the resin base liquid is completed, the coating base liquid and the resin base liquid are mixed at a weight ratio of 1: 1 to 2: 1 to prepare a coating mixture liquid. This is a step of mixing a coating base liquid to give a white hue on the tooth surface and a resin base liquid to exhibit water repellency and adhesion, wherein the mixing weight ratio is 1: 1 to 2: 1, preferably 1.5: 1 To 2: 1 by weight.

분산액을 제조하는 단계(S400)The step of preparing the dispersion (S400)

When the preparation of the coating liquid mixture is completed, 50 to 30 parts by weight of titanium dioxide is added to the coating liquid mixture in order to improve the film strength of the nail polish composition and to obtain a clear white color, and the mixture is stirred at 100 to 200 rpm for 3 to 10 minutes To prepare a dispersion. At this time, the titanium dioxide is preferably in the form of micro-particles, and preferably has a particle size of 200 탆 or less.

접착액을 제조하는 단계Step of producing adhesive liquid

When the preparation of the dispersion liquid is completed, a process for producing a viscous liquid of a natural adhesive component containing an active ingredient of garlic is carried out in order to improve the adhesiveness and the preservability of the tooth nail polish of the present invention. To this end, To 60 parts by weight of an aniline, 1 to 20 parts by weight of an alanine, 1 to 20 parts by weight of an alanine, and 1 to 20 parts by weight of an alyne. It is needless to say that the extraction process for extracting the active ingredient from garlic may be preceded for extracting glucose, alanine, alanase, and alanine.

도포액을 제조하는 단계(S600)The step of preparing the coating liquid (S600)

When the preparation of the adhesive liquid is completed, the adhesive liquid of 1 to 10 parts by weight based on the weight of the dispersion liquid is added to the dispersion to prepare a coating liquid. In this case, not only the preservative can be improved by adding the adhesive liquid to the dispersion, but also the adhesiveness of the film can be increased by performing functions as a natural adhesive including proteins and saccharides.

매니큐어 조성물을 제조하는 단계(S700)The step of manufacturing the manicure composition (S700)

Finally, a process for preparing a manicure composition is performed by adding 1 to 10 parts by weight of a silicone-based water repellent agent and 0.1 to 5 parts by weight of a surfactant to the weight of the coating liquid as an additive. As described above, any one selected from the group consisting of epoxy-modified silicone oil, silicone resin, methylhydrogen silicone, and trimethylsiloxy silicate may be used as the silicone water repellent agent, and polysorbate 80 is preferably used as the surfactant .

The dental nail polish manufactured through such a method has a effect of temporarily applying a whitening effect to the tooth to be applied to teeth and showing a whitening effect on teeth, and is not only harmless to human body but also exhibits sufficient adhesive force and water repellency,

In addition, in the method of manufacturing a dental nail polish of the present invention, further processing can be further performed for realizing a higher color rendering power or peel-off property. Then,

2 is a flowchart showing a step (S100) of producing the coating base liquid of the present invention.

Referring to FIG. 2, a description will be made of a step (S100) of preparing a coating base liquid including pretreatment of a cell lock to obtain a higher white color in the tooth nail polish of the present invention. The step of producing S100 includes a step of discoloring the cell rock S110, a step S120 of producing a cell rock mixture, a step S400 of producing an arginine mixed dispersion S130, a step of adjusting the dissolved oxygen concentration S140). In addition, a step of adding a preservative (S150) and a step of adding an acidity adjusting agent (S160) may be further included. Each step will be described in more detail as follows.

셀락을 탈색 처리하는 단계(S110)The step of decolorizing the cell (S110)

First, a step of decolorizing the cellulat, which is an animal resin, is performed. In this case, since there is no limitation on the decoloring treatment method, it is needless to say that various methods such as a decoloring treatment using a bleaching agent or a decoloring treatment using a heating method can be used. At this time, the decolorized cell lacquer appears to be light white or white. The decolorizing process of the cell can be repeatedly carried out until sufficient white / white color is obtained.

셀락 혼합액을 제조하는 단계(S120)The step (S120) of preparing the cell-

Next, a process of preparing a cellock mixture is carried out by dispersing 5 to 40 parts by weight of the decolorized cellrakes in 60 to 95 parts by weight of purified water at 50 to 60 ° C. This is a process of dispersing the cell rock into purified water, and since the cell rock exhibits hydrophilicity, it can be easily mixed with purified water to easily prepare a cellock mixture.

아르기닌 혼합 분산액을 제조하는 단계(S400)(S130)Arginine mixed dispersion (S400) (S130)

Thereafter, the cellulite mixture is mixed with 1 to 5 parts by weight of L-arginine per the weight of the cellulous mixture, and stirred for 5 to 60 minutes to prepare an arginine mixed dispersion. At this time, L-arginine is an amino acid showing basicity, and functions to increase the acid resistance of the coating film formed from the composition containing the cell rock to suppress the swelling of the coating film and to increase the acid resistance to various acidic materials which can be contacted in the oral environment.

용존 산소 농도를 조절하는 단계(S140)Adjusting the dissolved oxygen concentration (S140)

When the arginine mixed dispersion is prepared, the arginine mixed dispersion is bubbled with nitrogen gas to adjust the dissolved oxygen concentration to 0.1 to 3 mg / L. This is to prevent the oxidation of the arginine mixed dispersion prepared by replacing the oxygen gas contained in the arginine mixed dispersion with nitrogen gas, that is, the coating base solution as a final product, thereby increasing the preservation. The dissolved oxygen concentration is preferably 0.1 To 2 mg / L.

방부제를 첨가하는 단계(S150)Adding the preservative (S150)

In addition, in order to further increase the preservability of the arginine mixed dispersion of the present invention, the addition of the preservative in an amount of 0.1 to 5 parts by weight based on the weight of the arginine mixed dispersion may be further performed. At this time, there is no particular limitation on the preservative, but sodium citrate may be preferably used as a preservative to enhance safety in the human body.

산도조절제를 첨가하는 단계(S160)The step of adding acid controlling agent (S160)

Finally, the acidity of the arginine mixed dispersion may be adjusted by adding an acidity controlling agent to enhance water-solubilization efficiency and improve water resistance and acid resistance. Preferably, the pH of the arginine mixed dispersion is adjusted to 6.0 to 7.5, A modifier is added. At this time, since there is no limitation on the kind of the acidity adjusting agent, various weakly basic or weakly acidic substances which can satisfy the above-mentioned pH range and show safety to the human body can be used as the acidity adjusting agent.

The step (S100) of preparing the coating base liquid containing such steps not only makes it possible for the cell lock to exhibit clear whiteness / whiteness of color, but also exhibits water resistance and acid resistance in the nail polish composition of the present invention including cellul And has an effect of enhancing anticorrosion.

As another constitution, in the description of the above-described manicure composition, it is possible to add a constitution of an auxiliary auxiliary agent for realizing the peel-off type. However, in order to realize a method for manufacturing a tooth manicure comprising such auxiliary auxiliary agent in the composition (S300) of preparing the coating mixture, and preparing an auxiliary coating fluid before the coating mixture is prepared (S300). In the step of forming the coating mixture (S300) and the step of forming the dispersion (S400) , It may further include the step of adding an auxiliary coating liquid to the coating mixture liquid. Here, each step will be described in more detail as follows.

The step of preparing the auxiliary coating liquid comprises the steps of mixing 40 to 70 parts by weight of ethanol, 10 to 30 parts by weight of N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxybutane butyl methacrylate copolymer 5 to 20 parts by weight of polyvinylpyrrolidone, and 3 to 15 parts by weight of carboxymethylcellulose, wherein the active ingredient of the auxiliary coating liquid is N-methacryloyloxyethyl-N , N-dimethylammonium -? - N-methylcarboxybutane butyl methacrylate copolymer is added. The material serves to impart water resistance to the dispersing agent at the same time, thereby enhancing the water resistance of the coating and allowing the above-mentioned materials to be more mixed. In addition, the strength of the film can be increased by increasing the adhesiveness through addition of polyvinylpyrrolidone, carboxymethylcellulose, etc., and the peel-off property can be realized through this.

Therefore, when the preparation of the auxiliary coating liquid is completed, the auxiliary coating liquid contained between the step (S300) of preparing the coating mixture and the step (S400) of preparing the dispersion, 10 to 30 parts by weight of the auxiliary coating liquid based on the weight of the mixed liquid may be added to the coating mixture to add the peel-off property.

Hereinafter, the step of manufacturing the auxiliary coating liquid will be described in detail.

3 is a flow chart showing the steps of producing the auxiliary coating liquid of the present invention.

3, step S810 of producing a resin mixture, step S820 of producing a cellulose solution, step S830 of forming an auxiliary coating liquid, . Here, each step will be described in more detail as follows.

수지 혼합물을 제조하는 단계(S810)The resin mixture is prepared (S810)

First, 60 to 90 parts by weight of N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxybutane butyl methacrylate copolymer and 10 to 30 parts by weight of polyvinylpyrrolidone are mixed to prepare a resin The process of preparing the mixture is carried out. This is a process of mixing two materials of a resin material first, and is a process of mixing two materials of a resin material in a non-dried state, that is, a mixture of a liquid polyvinylpyrrolidone and N- methacryloyloxyethyl-N, N-dimethylammonium- Butyl methacrylate copolymer is mixed. Or N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxy betaine methacrylate copolymer prepared in powder form as a dry state may be mixed with polyvinylpyrrolidone in powder form Of course it is.

셀룰로오스 용액을 제조하는 단계(S820)The step of preparing the cellulose solution (S820)

Next, 5 to 25 parts by weight of carboxymethylcellulose is dispersed in 65 to 95 parts by weight of ethanol to prepare a cellulose solution. This is a process of dissolving carboxymethylcellulose in ethanol as a solvent, and the step (S820) of preparing a cellulose solution at this time may preferably be carried out at a temperature range of 10 to 50 ° C.

보조 피막액을 형성하는 단계(S830)Forming the auxiliary coating liquid (S830)

Finally, the cellulose solution and the resin mixture are mixed at a weight ratio of 2: 1 to 3: 1 and stirred for 3 to 15 minutes through a stirrer to form an auxiliary coating liquid. The auxiliary coating liquid thus prepared functions as the above-described auxiliary coating agent. At this time, preferably, the cellulose mixture is added dropwise at a rate of 10 to 50 ml / min while stirring the resin mixture, And prevents the solute from aggregating in the solution.

The tooth nail polish manufactured as described above is applied to teeth and dried to show a temporary whitening effect on the teeth. It is harmless to human body and is realized as a peel-off type so that it has a sufficient adhesive force and does not require a separate remover It can easily be removed.

Experiments were performed to compare the functions of the tooth nail polish manufactured through the method of manufacturing the tooth nail polish of the present invention with the commercially available tooth surface whitening application agent.

After giving a sample of a tooth (a small tooth) to one test performer, a tooth nail polish (example) manufactured according to the manufacturing method of the tooth manicure of the present invention (an example) and a commercially available liquid type tooth surface whitening agent ), Respectively. And then, the ease of use, the uniformity of the film applied on the teeth, the whitening effect, and the ease of removal were evaluated on a 5 - point scale.

4 is a table showing test results of the present invention.

As can be seen from the table shown in FIG. 4, the dental nail polish (Example) manufactured through the method of manufacturing the dental nail polish of the present invention exhibited more uniformity on the tooth surface than the commercially available tooth surface whitening agent (control) , The whitening effect is excellent, and at the same time, it is easily removed as a peel-off type, so that it is easy to use and can be easily removed.

As described above, the construction and operation of the dental manicure according to the present invention and the manufacturing method thereof are described in the above description and drawings, however, the present invention is not limited to the above description and drawings, And various changes and modifications may be made without departing from the technical spirit of the present invention.

Claims

As a tooth manicure,

With respect to the weight of the entire tooth nail polish composition,

20 to 40 parts by weight of purified water, 20 to 30 parts by weight of ethanol, 1 to 20 parts by weight of shellac, 1 to 10 parts by weight of rosin ester and 0.5 to 15 parts by weight of methacrylic acid-ethyl acrylate, 1 to 10 parts by weight of a silicone-based water repellent, 0.1 to 5 parts by weight of a surfactant, 5 to 20 parts by weight of titanium dioxide, 0.01 to 1 part by weight of alanine, 0.1 to 5 parts by weight of glucose, And 0.01 to 1 part by weight of allyl.
The method according to claim 1,

The toothpaste nail polish includes:

Further comprising 0.1 to 5 parts by weight of an inorganic pigment and 1 to 15 parts by weight of an auxiliary coating agent, based on the weight of the entire tooth nail polish composition.
3. The method of claim 2,

In the auxiliary coating agent,

N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxybutane butyl methacrylate copolymer, carboxymethylcellulose, polyvinylpyrrolidone, hydroxypropylmethylcellulose, sodium carboxymethylcellulose , And polyvinyl alcohol. &Lt; RTI ID = 0.0 > 15. < / RTI >
A method for manufacturing a tooth nail polish,

60 to 95 parts by weight of purified water and 5 to 40 parts by weight of a shellac;

3 to 30 parts by weight of rosin ester and 1 to 45 parts by weight of methacrylic acid-ethyl acrylate are mixed with 50 to 70 parts by weight of ethanol to prepare a resin base solution;

Mixing the coating base solution and the resin base solution at a weight ratio of 1: 1 to 2: 1 to prepare a coating mixture solution;

Adding 50 to 30 parts by weight of titanium dioxide to the weight of the coating mixture and stirring at 100 to 200 rpm for 3 to 10 minutes to prepare a dispersion;

Preparing adhesive liquid by mixing 40 to 60 parts by weight of glucose, 1 to 20 parts by weight of alanine, 1 to 20 parts by weight of alliinase and 1 to 20 parts by weight of alanine;

Adding 1 to 10 parts by weight of the adhesive liquid to the dispersion to the dispersion to prepare a coating liquid;

Adding a silicone water repellent agent and a surfactant in an amount of 1 to 10 parts by weight based on the weight of the coating liquid to a manicure composition.
5. The method of claim 4,

The surfactant,

Wherein the polysorbate 80 is polysorbate 80.
5. The method of claim 4,

The silicone-based water-

An epoxy-modified silicone oil, a silicone resin, a methylhydrogen silicone, and a trimethylsiloxy silicic acid.
5. The method of claim 4,

Wherein the step of preparing the coating base liquid comprises:

Discoloring treatment of the cell,

Dispersing 5 to 40 parts by weight of the decolorized cellrakes in 60 to 95 parts by weight of purified water at 50 to 60 ° C to prepare a cellock mixture,

1 to 5 parts by weight of L-arginine is mixed with the cellock mixture solution in an amount of 1 to 5 parts by weight based on the weight of the cellulous mixture, and the mixture is stirred for 5 to 60 minutes to prepare an arginine mixed dispersion,

Further comprising the step of bubbling nitrogen gas into the arginine mixed dispersion to adjust the dissolved oxygen concentration to 0.1 to 3 mg / L.
8. The method of claim 7,

After the step of bubbling nitrogen gas into the arginine mixed dispersion,

Adding 0.1 to 5 parts by weight of a preservative based on the weight of the arginine mixed dispersion,

Further comprising the step of adding an acidity controlling agent so that the pH of the arginine mixed dispersion becomes 6.0 to 7.5.
9. The method of claim 8,

The preservative,

Characterized in that it is sodium citrate.
5. The method of claim 4,

Before the step of preparing the coating mixture,

40 to 70 parts by weight of ethanol and 10 to 30 parts by weight of a copolymer of N-methacryloyloxyethyl-N and N-dimethylammonium-α-N-methylcarboxybutane butyl methacrylate and polyvinylpyrrolidone 5 to 20 parts by weight and carboxymethylcellulose in an amount of 3 to 15 parts by weight,

Between the step of preparing the coating mixture and the step of producing the dispersion,

And further adding 10 to 30 parts by weight of the auxiliary coating liquid to the coating mixture, based on the weight of the coating mixture.
11. The method of claim 10,

Wherein the step of preparing the auxiliary coating liquid comprises:

60 to 90 parts by weight of N-methacryloyloxyethyl-N, N-dimethylammonium-α-N-methylcarboxybutane butyl methacrylate copolymer and 10 to 30 parts by weight of polyvinylpyrrolidone are mixed to obtain a resin Preparing a mixture,

Dispersing 5 to 25 parts by weight of carboxymethyl cellulose in 65 to 95 parts by weight of ethanol to prepare a cellulose solution,

Further comprising the step of mixing the cellulose solution and the resin mixture at a weight ratio of 2: 1 to 3: 1 and stirring the mixture for 3 to 15 minutes through a stirrer to form an auxiliary coating liquid. &Lt; / RTI >
12. The method of claim 11,

Wherein forming the auxiliary coating liquid comprises:

And the cellulose solution is dropped uniformly at a rate of 10 to 50 ml / min while the resin mixture is stirred.