WO2024090925A1 - Hair dye composition containing potassium alum and polyurethane-10 - Google Patents

Hair dye composition containing potassium alum and polyurethane-10 Download PDF

Info

Publication number
WO2024090925A1
WO2024090925A1 PCT/KR2023/016473 KR2023016473W WO2024090925A1 WO 2024090925 A1 WO2024090925 A1 WO 2024090925A1 KR 2023016473 W KR2023016473 W KR 2023016473W WO 2024090925 A1 WO2024090925 A1 WO 2024090925A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair dye
weight
dye composition
hair
polyurethane
Prior art date
Application number
PCT/KR2023/016473
Other languages
French (fr)
Korean (ko)
Inventor
채다은
김현나
주영아
Original Assignee
코스맥스 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 코스맥스 주식회사 filed Critical 코스맥스 주식회사
Publication of WO2024090925A1 publication Critical patent/WO2024090925A1/en

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87Polyurethanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/10Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
  • PU-10 polyurethane-10
  • hair dye The general purposes of using hair dye are 1) to restore aged gray hair to its original color, 2) to change the original hair color to a more attractive tone/shade, and 3) to restore the original color after dyeing the hair. If you want to get your hair back, use hair dye for other purposes.
  • Hair dye is a dye that penetrates the cuticle of the hair and deposits pigment molecules in the cortex.
  • the additional action of the penetrant and oxidizing agent can change the degree of discoloration and coloring of the hair.
  • the rate of fading of dye varies depending on the type, amount, and alkalinity of the dye used.
  • permanent hair dyes are known to fade in 28 to 42 days after dyeing
  • temporary hair dyes are known to fade in about 1 to 2 days. there is.
  • the faster the blue color and the relatively short dyeing time, the faster the fading rate, and the colors dyed red and yellow have problems such as not fading uniformly and progressing like a stain.
  • the present inventors completed the present invention as a result of researching a hair dye composition with excellent dyeing clarity and color uniformity.
  • the purpose of the present invention is to provide a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
  • the present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
  • One aspect of the present invention relates to a hair dye composition
  • a hair dye composition comprising potassium alum and polyurethane-10.
  • potassium alum is 0.01 to 5% by weight, 0.01 to 4% by weight, 0.01 to 3% by weight, 0.01 to 2% by weight, 0.05 to 5% by weight, 0.05 to 4% by weight, 0.05% by weight, based on the total weight of the hair dye composition.
  • potassium alum is included in the above content range, it may be possible to manufacture a hair dye with excellent color uniformity.
  • polyurethane-10 is used in an amount of 0.01 to 5% by weight, 0.01 to 4% by weight, 0.01 to 3% by weight, 0.01 to 2% by weight, 0.05 to 5% by weight, and 0.05 to 4% by weight, based on the total weight of the hair dye composition.
  • polyurethane-10 is included in the above content range, it may be possible to manufacture a hair dye with excellent dyeing clarity.
  • the weight ratio of potassium alum and polyurethane-10 is 1:10 to 10:1, 1:9 to 9:1, 1:8 to 8:1, 1:7 to 7:1, 1:6. to 6:1, 1:5 to 5:1, 1:4 to 4:1, 1:3 to 3:1, or 1:2 to 2:1, for example 1:1.
  • the hair dye composition may additionally include dye.
  • the dye is Basic Brown 16, Basic Red 76, Basic Yellow 57, Basic Brown 17, Basic Blue 99. ), Basic Orange 31, Basic Yellow 87, Basic Red 51, Basic Violet 2, HC Blue 15 and HC Blue 16. It may be one or more types selected from the group consisting of (HC Blue 16), but is not limited thereto.
  • the dye is used in an amount of 0.001 to 1% by weight, 0.001 to 0.8% by weight, 0.001 to 0.6% by weight, 0.001 to 0.4% by weight, 0.01 to 1% by weight, 0.01 to 0.8% by weight, 0.01 to 0.01% by weight, based on the total weight of the hair dye composition. It may contain 0.6% by weight, 0.01 to 0.4% by weight, 0.1 to 1% by weight, 0.1 to 0.8% by weight, 0.1 to 0.6% by weight, or 0.1 to 0.4% by weight, for example, 0.337% by weight.
  • the concentration of dye is less than 0.001% by weight relative to the total weight of the hair dye composition, the dyeing effect may be reduced, and if it exceeds 1% by weight, a problem may occur in which manufacturing efficiency is reduced due to high manufacturing costs.
  • the hair dye composition is one selected from the group consisting of Cetearyl alcohol, Stearyl alcohol, Behentrimonium chloride, and Propylene glycol. It may additionally include the above.
  • the hair dye composition contains cetearyl alcohol in an amount of 0.1 to 10% by weight, 0.1 to 8% by weight, 0.1 to 6% by weight, 0.1 to 4% by weight, 1 to 10% by weight, 1 to 1% by weight, based on the total weight of the hair dye composition. It may additionally include 8% by weight, 1 to 6% by weight, or 1 to 4% by weight, for example, 3.5% by weight.
  • cetearyl alcohol When cetearyl alcohol is included in the above content range, separation of components in the hair dye does not occur, improving stability, and making it possible to manufacture a hair dye with excellent conditioning effect and dyeing efficiency.
  • the hair dye composition contains stearyl alcohol in an amount of 0.1 to 10% by weight, 0.1 to 8% by weight, 0.1 to 6% by weight, 0.1 to 4% by weight, 1 to 10% by weight, 1 to 8% by weight, based on the total weight of the hair dye composition. It may additionally include % by weight, 1 to 6% by weight, or 1 to 4% by weight, for example, 3.5% by weight.
  • the hair dye composition contains behentrimonium chloride in an amount of 0.1 to 10% by weight, 0.1 to 8% by weight, 0.1 to 6% by weight, 0.1 to 4% by weight, 1 to 10% by weight, 1 to 1% by weight, based on the total weight of the hair dye composition. It may additionally include 8% by weight, 1 to 6% by weight, or 1 to 4% by weight, for example, 2% by weight.
  • the hair dye composition contains propylene glycol in an amount of 0.01 to 5% by weight, 0.01 to 4% by weight, 0.01 to 3% by weight, 0.01 to 2% by weight, 0.01 to 1% by weight, 0.01 to 0.01% by weight, based on the total weight of the hair dye composition. additionally comprising 0.5% by weight, 0.1 to 5% by weight, 0.1 to 4% by weight, 0.1 to 3% by weight, 0.1 to 2% by weight, 0.1 to 1% by weight, or 0.1 to 0.5% by weight, such as 0.25% by weight. It may be.
  • propylene glycol is included within the above content range, it may be possible to manufacture a hair dye with excellent dye solubility, dye penetration, and dyeing efficiency.
  • the hair dye composition includes Cocamidopropyl Betaine, Lauryl Hydroxysultaine, Lauramide MIPA, and Sodium C14-16 Olefin Sulfonate. It may additionally include one or more species selected from the group consisting of Olefin Sulfonate).
  • the hair dye composition additionally comprising one or more selected from the group consisting of cocamidopropyl betaine, lauryl hydroxysulsteine, lauramide mipha, and sodium C14-16 olefin sulfonate has a foaming effect. It may be a foam hair dye formulation.
  • the hair dye composition contains 5 to 30% by weight, 5 to 25% by weight, 5 to 20% by weight, 5 to 15% by weight, 5 to 10% by weight, and 7 to 7% of cocamidopropyl betaine based on the total weight of the hair dye composition. It may additionally include 30% by weight, 7 to 25% by weight, 7 to 20% by weight, 7 to 15% by weight, or 7 to 10% by weight, for example, 9% by weight.
  • cocamidopropyl betaine is included in the above content range, it may be possible to manufacture a hair dye with excellent foaming power, foam size, and foam sustainability.
  • the hair dye composition contains 1 to 10% by weight, 1 to 9% by weight, 1 to 8% by weight, 1 to 7% by weight, 1 to 6% by weight, based on the total weight of the hair dye composition. It may additionally include 1 to 5% by weight, 1 to 4% by weight, 1 to 3% by weight, or 1 to 2% by weight, for example, 1.8% by weight.
  • lauryl hydroxysulsteine is included in the above content range, it may be possible to manufacture a hair dye with excellent foaming power, foam size, and foam sustainability.
  • the hair dye composition contains Lauramid Mifah in an amount of 0.1 to 5% by weight, 0.1 to 4.5% by weight, 0.1 to 4% by weight, 0.1 to 3.5% by weight, 0.1 to 3% by weight, 0.1 to 10% by weight, based on the total weight of the hair dye composition. It may additionally include 2.5% by weight, 0.1 to 2% by weight, 0.1 to 1.5% by weight, or 0.1 to 1% by weight, for example, 0.5% by weight.
  • Lauramid Mifah is included in the above content range, it may be possible to manufacture a hair dye with excellent foaming power, foam size, and foam sustainability.
  • the hair dye composition contains sodium C14-16 olefin sulfonate in an amount of 0.1 to 30% by weight, 0.1 to 20% by weight, 0.1 to 10% by weight, 0.1 to 5% by weight, and 1 to 30% by weight based on the total weight of the hair dye composition. , 1 to 20% by weight, 1 to 10% by weight, 1 to 5% by weight, 2 to 30% by weight, 2 to 20% by weight, 2 to 10% by weight, 2 to 5% by weight, 3 to 30% by weight, 3 It may additionally include from 20% by weight, 3 to 10% by weight, or 3 to 5% by weight, for example, 3.5% by weight.
  • the hair dye composition may additionally include one or more selected from the group consisting of fragrances, pigments, preservatives, thickeners, moisturizers, preservatives, and solvents.
  • the hair dye composition may be formulated as any one product selected from the group consisting of shampoo, rinse, treatment, conditioning agent, hair gel, hair essence, hair oil, hair pack, and hair cream, but is limited thereto. It doesn't work.
  • the present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
  • PU-10 polyurethane-10
  • Figure 1 is a graph comparing the color uniformity of examples and comparative examples manufactured according to the manufacturing example of the present invention.
  • Figure 2 is a graph showing the clarity of dyeing of examples and comparative examples prepared according to the manufacturing example of the present invention.
  • the present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
  • the water phase raw materials purified water and behentrimonium chloride
  • the oil phase raw materials cetearyl alcohol and stearyl alcohol
  • a HOMO Mixer device After low-temperature stirring and cooling at 45°C, potassium alum and polyurethane-10 were added and mixed at 5000 rpm using a HOMO Mixer device.
  • dyes Basic Brown 16, Basic Red 51, Basic Yellow 87, and Basic Blue 99
  • propylene glycol were added and mixed at 5000 rpm using a HOMO Mixer device.
  • a preservative was added and mixed at 5000 rpm using a HOMO Mixer device.
  • degassing defoaming
  • Example 1 Potassium Alum 1.00 Polyurethane-10 1.00 Basic Brown 16 0.115 Basic Red 51 0.007 Basic Yellow 87 0.015 Basic Blue 99 0.20 Cetearyl alcohol 3.50 stearyl alcohol 3.50 behentrimonium chloride 2.00 propylene glycol 0.25 antiseptic 1.00 Purified water 87.413 Sum 100
  • the x-axis of the graph in Figure 1 represents the a* value.
  • the a* value makes red and green on one axis in the color diagram, so when it is written as +a*, it is close to red, and when it is written as -a*, it is close to green. it means.
  • the y-axis refers to the b* value.
  • the b* value makes yellow and blue on one axis in a color diagram, so when it is written as + b*, it means it is close to yellow, and when it is written as -b*, it means it is close to blue. That is, the graph in Figure 1 is data measuring the color values a* and b* of different points in the wool patch, meaning that the denser the points in the data, the better the color uniformity.
  • the product was applied to an ivory-colored wool patch measuring 5cm*5cm, washed in running water, dried, and dyed. Each dyed wool patch was divided into 9 different locations and color values (L*, a*, b*) were extracted using a colorimeter (product name: Spectrophotometer, model name: CM-2600d). The results are shown in Figure 2.
  • the x-axis of the graph in FIG. 2 means the number of measurements and the y-axis means the L* value.
  • the L* value is data measuring reflectance and represents the same brightness as human vision. It is expressed as a value from 0 to 100 and is a number. The higher the value, the brighter the brightness. In this experimental example, dyeing was performed on an ivory-colored wool patch, and the L* value means the vividness of the dyeing. In other words, the lower the L* value, the better the dyeing clarity.
  • Example 1 containing potassium alum and polyurethane-10 The average L* value of Example 1 containing potassium alum and polyurethane-10 was measured to be 22, and the average L* value of Comparative Example 1 containing only polyurethane-10 was measured to be 21, and the average L* value of Example 1 containing only potassium alum was measured to be 21.
  • the average L* value of 2 was measured to be 28, and the average L* value of Comparative Example 3, which does not contain both potassium alum and polyurethane-10, was measured to be 23.
  • the present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
  • PU-10 polyurethane-10

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10), and has the excellent effect that hair dyed using the hair dye composition according to the present invention has excellent vividness and color uniformity.

Description

포타슘알룸 및 폴리우레탄-10을 포함하는 염모제 조성물Hair dye composition containing potassium alum and polyurethane-10
본 발명은 포타슘알룸 (Potassium alum) 및 폴리우레탄-10 (Polyurethane-10; PU-10)을 포함하는 염모제 조성물에 관한 것으로, 본 발명의 염모제 조성물을 사용하여 모발 염색 시 염색의 선명도 및 색상 균일도가 우수한 효과가 있다.The present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10). When dyeing hair using the hair dye composition of the present invention, the vividness and color uniformity of the dyeing are improved. It has excellent effects.
인류의 모발 염색 역사는 아주 오래 전 고대 이집트로부터로 알려져 있다. 당시에는 동물의 피, 뿔 및 몸 체에서 추출한 기름을 사용하여 모발에 염색을 하였으며, 그 후 헨나 (Henna), 안티모니 (Antimony), 백납 등 천연물을 이용한 염색이 그 시초라 할 수 있다. 그 후, 1863년에 파라페닐렌다이아민 (paraphenylene diamine)이 발견되어 염모제로 사용하게 된 것이 현대 염색의 시발점이 되었다. 상기 염모제들은 기본적으로 염기성이면서 물 및 공기와 접촉할 경우 쉽게 산화되어 모발의 케라틴 (keratin) 성분을 변화시킬 수 있는 것으로 알려져 있다. 1888년에는 독일의 E.에르트만이 아미노페놀 (aminophenol)계의 물질을 발견하여 염모제로 사용하기 시작하여 염모제 분야의 눈부신 발전을 이루었다.The history of human hair dyeing is known to date back to ancient Egypt. At that time, hair was dyed using oil extracted from animal blood, horns, and bodies, and later dyeing using natural products such as henna, antimony, and pewter can be said to be the beginning. Afterwards, paraphenylene diamine was discovered in 1863 and used as a hair dye, which became the starting point of modern dyeing. It is known that the hair dyes are basically basic and are easily oxidized when in contact with water and air, which can change the keratin component of the hair. In 1888, E. Ertmann of Germany discovered aminophenol-based substances and began using them as hair dyes, making remarkable progress in the field of hair dyes.
염모제를 사용하는 목적은 일반적으로 1) 노화한 흰머리를 원래의 색으로 되찾고자 할 경우, 2) 원래의 모 발색을 보다 매력적인 색조/명암으로 바꾸고자 할 경우 및 3) 모발 염색 후 원래의 색을 되찾고자 할 경우 등의 용도로 염모제를 사용한다.The general purposes of using hair dye are 1) to restore aged gray hair to its original color, 2) to change the original hair color to a more attractive tone/shade, and 3) to restore the original color after dyeing the hair. If you want to get your hair back, use hair dye for other purposes.
염모제는 색소가 모표피 (cuticle)를 침투하여 모피질 (cortex)안에 색소 분자를 침착시키는 것으로, 침투제 및 산화제의 추가작용으로 이들 모발의 탈색과 착색 정도를 변화시킬 수 있다.Hair dye is a dye that penetrates the cuticle of the hair and deposits pigment molecules in the cortex. The additional action of the penetrant and oxidizing agent can change the degree of discoloration and coloring of the hair.
한편, 사용한 염료의 종류, 양 및 알칼리도 등의 차이에 따라 염료의 퇴색속도가 달라지며, 통상 영구 염모제의 경우 염색 후 28∼42일, 일시 염모제는 1∼2일 정도가 지나면 퇴색이 되는 것으로 알려져 있다. 또한, 청색계열 및 염색시간이 상대적으로 짧은 것일수록 퇴색속도가 빠르며, 적색, 황색으로 염색한 색상은 일괄적으로 퇴색되지 않아 얼룩처럼 진행되는 등 문제점을 가지고 있다. On the other hand, the rate of fading of dye varies depending on the type, amount, and alkalinity of the dye used. In general, permanent hair dyes are known to fade in 28 to 42 days after dyeing, and temporary hair dyes are known to fade in about 1 to 2 days. there is. In addition, the faster the blue color and the relatively short dyeing time, the faster the fading rate, and the colors dyed red and yellow have problems such as not fading uniformly and progressing like a stain.
이에, 상기의 문제점들을 보완하기 위해 보다 균일하게 염료를 보다 많이 침투시킬 수 있는 염모제 조성물을 필요로 하고 있는 실정이다.Accordingly, in order to compensate for the above problems, there is a need for a hair dye composition that can penetrate more dye more uniformly.
이에 본 발명자들은 염색의 선명도 및 색상 균일도가 우수한 염모제 조성물을 연구한 결과, 본 발명을 완성하게 되었다.Accordingly, the present inventors completed the present invention as a result of researching a hair dye composition with excellent dyeing clarity and color uniformity.
본 발명의 목적은 포타슘알룸 (Potassium alum) 및 폴리우레탄-10 (Polyurethane-10; PU-10)을 포함하는 염모제 조성물을 제공하는 것이다.The purpose of the present invention is to provide a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
본 발명은 포타슘알룸 (Potassium alum) 및 폴리우레탄-10 (Polyurethane-10; PU-10)을 포함하는 염모제 조성물에 관한 것이다.The present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
이하 본 발명을 더욱 자세히 설명하고자 한다.Hereinafter, the present invention will be described in more detail.
본 발명의 일 양태는 포타슘알룸 및 폴리우레탄-10을 포함하는 염모제 조성물에 관한 것이다.One aspect of the present invention relates to a hair dye composition comprising potassium alum and polyurethane-10.
본 발명에 있어서, 포타슘알룸은 염모제 조성물 총 중량 대비 0.01 내지 5 중량%, 0.01 내지 4 중량%, 0.01 내지 3 중량%, 0.01 내지 2 중량%, 0.05 내지 5 중량%, 0.05 내지 4 중량%, 0.05 내지 3 중량%, 0.05 내지 2 중량%, 0.1 내지 5 중량%, 0.1 내지 4 중량%, 0.1 내지 3 중량%, 0.1 내지 2 중량%, 0.5 내지 5 중량%, 0.5 내지 4 중량%, 0.5 내지 3 중량%, 또는 0.5 내지 2 중량%, 예를 들어 1 중량% 포함되는 것일 수 있다.In the present invention, potassium alum is 0.01 to 5% by weight, 0.01 to 4% by weight, 0.01 to 3% by weight, 0.01 to 2% by weight, 0.05 to 5% by weight, 0.05 to 4% by weight, 0.05% by weight, based on the total weight of the hair dye composition. to 3% by weight, 0.05 to 2% by weight, 0.1 to 5% by weight, 0.1 to 4% by weight, 0.1 to 3% by weight, 0.1 to 2% by weight, 0.5 to 5% by weight, 0.5 to 4% by weight, 0.5 to 3 It may be included in % by weight, or 0.5 to 2% by weight, for example, 1% by weight.
포타슘알룸을 상기 함량 범위로 포함하는 경우 색상 균일도가 우수한 염모제의 제조가 가능해질 수 있다.If potassium alum is included in the above content range, it may be possible to manufacture a hair dye with excellent color uniformity.
본 발명에 있어서, 폴리우레탄-10은 염모제 조성물 총 중량 대비 0.01 내지 5 중량%, 0.01 내지 4 중량%, 0.01 내지 3 중량%, 0.01 내지 2 중량%, 0.05 내지 5 중량%, 0.05 내지 4 중량%, 0.05 내지 3 중량%, 0.05 내지 2 중량%, 0.1 내지 5 중량%, 0.1 내지 4 중량%, 0.1 내지 3 중량%, 0.1 내지 2 중량%, 0.5 내지 5 중량%, 0.5 내지 4 중량%, 0.5 내지 3 중량%, 또는 0.5 내지 2 중량%, 예를 들어 1 중량% 포함되는 것일 수 있다.In the present invention, polyurethane-10 is used in an amount of 0.01 to 5% by weight, 0.01 to 4% by weight, 0.01 to 3% by weight, 0.01 to 2% by weight, 0.05 to 5% by weight, and 0.05 to 4% by weight, based on the total weight of the hair dye composition. , 0.05 to 3% by weight, 0.05 to 2% by weight, 0.1 to 5% by weight, 0.1 to 4% by weight, 0.1 to 3% by weight, 0.1 to 2% by weight, 0.5 to 5% by weight, 0.5 to 4% by weight, 0.5 It may contain from 3% by weight, or 0.5 to 2% by weight, for example, 1% by weight.
폴리우레탄-10을 상기 함량 범위로 포함하는 경우 염색의 선명도가 우수한 염모제의 제조가 가능해질 수 있다.If polyurethane-10 is included in the above content range, it may be possible to manufacture a hair dye with excellent dyeing clarity.
본 발명에 있어서, 포타슘알룸 및 폴리우레탄-10의 중량비는 1:10 내지 10:1, 1:9 내지 9:1, 1:8 내지 8:1, 1:7 내지 7:1, 1:6 내지 6:1, 1:5 내지 5:1, 1:4 내지 4:1, 1:3 내지 3:1, 또는 1:2 내지 2:1, 예를 들어 1:1인 것일 수 있다.In the present invention, the weight ratio of potassium alum and polyurethane-10 is 1:10 to 10:1, 1:9 to 9:1, 1:8 to 8:1, 1:7 to 7:1, 1:6. to 6:1, 1:5 to 5:1, 1:4 to 4:1, 1:3 to 3:1, or 1:2 to 2:1, for example 1:1.
포타슘알룸 및 폴리우레탄-10을 상기 중량비로 포함하는 경우 색상 균일도 및 염색의 선명도가 우수한 염모제의 제조가 가능해질 수 있다.When potassium alum and polyurethane-10 are included in the above weight ratio, it is possible to manufacture a hair dye with excellent color uniformity and dyeing clarity.
본 발명에 있어서, 염모제 조성물은 염료를 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition may additionally include dye.
본 발명에 있어서, 염료는 베이직 브라운 16 (Basic Brown 16), 베이직 레드 76 (Basic Red 76), 베이직 옐로우 57 (Basic Yellow 57), 베이직 브라운 17 (Basic Brown 17), 베이직 블루 99 (Basic Blue 99), 베이직 오렌지 31 (Basic Orange 31), 베이직 옐로우 87 (Basic Yellow 87), 베이직 레드 51 (Basic Red 51), 베이직 바이올렛 2 (Basic Violet 2), 에이치씨 블루 15 (HC Blue 15) 및 에이치씨 블루 16 (HC Blue 16)으로 이루어진 군에서 선택되는 1종 이상인 것일 수 있으나, 이에 한정되는 것은 아니다.In the present invention, the dye is Basic Brown 16, Basic Red 76, Basic Yellow 57, Basic Brown 17, Basic Blue 99. ), Basic Orange 31, Basic Yellow 87, Basic Red 51, Basic Violet 2, HC Blue 15 and HC Blue 16. It may be one or more types selected from the group consisting of (HC Blue 16), but is not limited thereto.
본 발명에 있어서, 염료는 염모제 조성물 총 중량 대비 0.001 내지 1 중량%, 0.001 내지 0.8 중량%, 0.001 내지 0.6 중량%, 0.001 내지 0.4 중량%, 0.01 내지 1 중량%, 0.01 내지 0.8 중량%, 0.01 내지 0.6 중량%, 0.01 내지 0.4 중량%, 0.1 내지 1 중량%, 0.1 내지 0.8 중량%, 0.1 내지 0.6 중량%, 또는 0.1 내지 0.4 중량%, 예를 들어 0.337 중량% 포함되는 것일 수 있다.In the present invention, the dye is used in an amount of 0.001 to 1% by weight, 0.001 to 0.8% by weight, 0.001 to 0.6% by weight, 0.001 to 0.4% by weight, 0.01 to 1% by weight, 0.01 to 0.8% by weight, 0.01 to 0.01% by weight, based on the total weight of the hair dye composition. It may contain 0.6% by weight, 0.01 to 0.4% by weight, 0.1 to 1% by weight, 0.1 to 0.8% by weight, 0.1 to 0.6% by weight, or 0.1 to 0.4% by weight, for example, 0.337% by weight.
염료의 농도가 염모제 조성물 총 중량 대비 0.001 중량% 미만이면 염색 효과가 감소할 수 있고, 1 중량%를 초과하면 높은 제조 단가로 인해 제조 효율이 감소하게 되는 문제점이 발생할 수 있다.If the concentration of dye is less than 0.001% by weight relative to the total weight of the hair dye composition, the dyeing effect may be reduced, and if it exceeds 1% by weight, a problem may occur in which manufacturing efficiency is reduced due to high manufacturing costs.
본 발명에 있어서, 염모제 조성물은 세테아릴알코올 (Cetearyl alcohol), 스테아릴알코올 (Stearyl alcohol), 베헨트라이모늄클로라이드 (Behentrimonium chloride) 및 프로필렌글라이콜 (Propylene glycol)로 이루어진 군에서 선택되는 1종 이상을 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition is one selected from the group consisting of Cetearyl alcohol, Stearyl alcohol, Behentrimonium chloride, and Propylene glycol. It may additionally include the above.
본 발명에 있어서, 염모제 조성물은 세테아릴알코올을 염모제 조성물 총 중량 대비 0.1 내지 10 중량%, 0.1 내지 8 중량%, 0.1 내지 6 중량%, 0.1 내지 4 중량%, 1 내지 10 중량%, 1 내지 8 중량%, 1 내지 6 중량%, 또는 1 내지 4 중량%, 예를 들어 3.5 중량% 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition contains cetearyl alcohol in an amount of 0.1 to 10% by weight, 0.1 to 8% by weight, 0.1 to 6% by weight, 0.1 to 4% by weight, 1 to 10% by weight, 1 to 1% by weight, based on the total weight of the hair dye composition. It may additionally include 8% by weight, 1 to 6% by weight, or 1 to 4% by weight, for example, 3.5% by weight.
세테아릴알코올을 상기 함량 범위로 포함하는 경우 염모제 내 성분 분리가 일어나지 않아 안정도가 우수해지며, 컨디셔닝 효과 및 염색 효율이 우수한 염모제의 제조가 가능해질 수 있다.When cetearyl alcohol is included in the above content range, separation of components in the hair dye does not occur, improving stability, and making it possible to manufacture a hair dye with excellent conditioning effect and dyeing efficiency.
본 발명에 있어서, 염모제 조성물은 스테아릴알코올을 염모제 조성물 총 중량 대비 0.1 내지 10 중량%, 0.1 내지 8 중량%, 0.1 내지 6 중량%, 0.1 내지 4 중량%, 1 내지 10 중량%, 1 내지 8 중량%, 1 내지 6 중량%, 또는 1 내지 4 중량%, 예를 들어 3.5 중량% 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition contains stearyl alcohol in an amount of 0.1 to 10% by weight, 0.1 to 8% by weight, 0.1 to 6% by weight, 0.1 to 4% by weight, 1 to 10% by weight, 1 to 8% by weight, based on the total weight of the hair dye composition. It may additionally include % by weight, 1 to 6% by weight, or 1 to 4% by weight, for example, 3.5% by weight.
스테아릴알코올을 상기 함량 범위로 포함하는 경우 염모제 내 성분 분리가 일어나지 않아 안정도가 우수해지며, 컨디셔닝 효과 및 염색 효율이 우수한 염모제의 제조가 가능해질 수 있다.When stearyl alcohol is included in the above content range, separation of components in the hair dye does not occur, thereby improving stability, and it may be possible to manufacture a hair dye with excellent conditioning effect and dyeing efficiency.
본 발명에 있어서, 염모제 조성물은 베헨트라이모늄클로라이드를 염모제 조성물 총 중량 대비 0.1 내지 10 중량%, 0.1 내지 8 중량%, 0.1 내지 6 중량%, 0.1 내지 4 중량%, 1 내지 10 중량%, 1 내지 8 중량%, 1 내지 6 중량%, 또는 1 내지 4 중량%, 예를 들어 2 중량% 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition contains behentrimonium chloride in an amount of 0.1 to 10% by weight, 0.1 to 8% by weight, 0.1 to 6% by weight, 0.1 to 4% by weight, 1 to 10% by weight, 1 to 1% by weight, based on the total weight of the hair dye composition. It may additionally include 8% by weight, 1 to 6% by weight, or 1 to 4% by weight, for example, 2% by weight.
베헨트라이모늄클로라이드을 상기 함량 범위로 포함하는 경우 염모제 내 성분 분리가 일어나지 않아 안정도가 우수해지며, 컨디셔닝 효과 및 염색 효율이 우수한 염모제의 제조가 가능해질 수 있다.When behentrimonium chloride is included in the above content range, separation of components in the hair dye does not occur, thereby improving stability, and it may be possible to manufacture a hair dye with excellent conditioning effect and dyeing efficiency.
본 발명에 있어서, 염모제 조성물은 프로필렌글라이콜을 염모제 조성물 총 중량 대비 0.01 내지 5 중량%, 0.01 내지 4 중량%, 0.01 내지 3 중량%, 0.01 내지 2 중량%, 0.01 내지 1 중량%, 0.01 내지 0.5 중량%, 0.1 내지 5 중량%, 0.1 내지 4 중량%, 0.1 내지 3 중량%, 0.1 내지 2 중량%, 0.1 내지 1 중량%, 또는 0.1 내지 0.5 중량%, 예를 들어 0.25 중량% 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition contains propylene glycol in an amount of 0.01 to 5% by weight, 0.01 to 4% by weight, 0.01 to 3% by weight, 0.01 to 2% by weight, 0.01 to 1% by weight, 0.01 to 0.01% by weight, based on the total weight of the hair dye composition. additionally comprising 0.5% by weight, 0.1 to 5% by weight, 0.1 to 4% by weight, 0.1 to 3% by weight, 0.1 to 2% by weight, 0.1 to 1% by weight, or 0.1 to 0.5% by weight, such as 0.25% by weight. It may be.
프로필렌글라이콜을 상기 함량 범위로 포함하는 경우 염료의 용해도, 염료의 침투력 및 염색 효율이 우수한 염모제의 제조가 가능해질 수 있다.When propylene glycol is included within the above content range, it may be possible to manufacture a hair dye with excellent dye solubility, dye penetration, and dyeing efficiency.
본 발명에 있어서, 염모제 조성물은 코카미도프로필베타인 (Cocamidopropyl Betaine), 라우릴하이드록시설테인 (Lauryl Hydroxysultaine), 라우라마이드미파 (Lauramide MIPA) 및 소듐C14-16올레핀설포네이트 (Sodium C14-16 Olefin Sulfonate)로 이루어진 군에서 선택되는 1종 이상을 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition includes Cocamidopropyl Betaine, Lauryl Hydroxysultaine, Lauramide MIPA, and Sodium C14-16 Olefin Sulfonate. It may additionally include one or more species selected from the group consisting of Olefin Sulfonate).
본 발명에 있어서, 코카미도프로필베타인, 라우릴하이드록시설테인, 라우라마이드미파 및 소듐C14-16올레핀설포네이트로 이루어진 군에서 선택되는 1종 이상을 추가적으로 포함하는 염모제 조성물은 거품이 발생하는 거품염모제의 제형일 수 있다.In the present invention, the hair dye composition additionally comprising one or more selected from the group consisting of cocamidopropyl betaine, lauryl hydroxysulsteine, lauramide mipha, and sodium C14-16 olefin sulfonate has a foaming effect. It may be a foam hair dye formulation.
본 발명에 있어서, 염모제 조성물은 코카미도프로필베타인을 염모제 조성물 총 중량 대비 5 내지 30 중량%, 5 내지 25 중량%, 5 내지 20 중량%, 5 내지 15 중량%, 5 내지 10 중량%, 7 내지 30 중량%, 7 내지 25 중량%, 7 내지 20 중량%, 7 내지 15 중량%, 또는 7 내지 10 중량%, 예를 들어 9 중량% 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition contains 5 to 30% by weight, 5 to 25% by weight, 5 to 20% by weight, 5 to 15% by weight, 5 to 10% by weight, and 7 to 7% of cocamidopropyl betaine based on the total weight of the hair dye composition. It may additionally include 30% by weight, 7 to 25% by weight, 7 to 20% by weight, 7 to 15% by weight, or 7 to 10% by weight, for example, 9% by weight.
코카미도프로필베타인을 상기 함량 범위로 포함하는 경우 거품력의 양, 거품의 크기 및 거품의 지속력이 우수한 염모제의 제조가 가능해질 수 있다.If cocamidopropyl betaine is included in the above content range, it may be possible to manufacture a hair dye with excellent foaming power, foam size, and foam sustainability.
본 발명에 있어서, 염모제 조성물은 라우릴하이드록시설테인을 염모제 조성물 총 중량 대비 1 내지 10 중량%, 1 내지 9 중량%, 1 내지 8 중량%, 1 내지 7 중량%, 1 내지 6 중량%, 1 내지 5 중량%, 1 내지 4 중량%, 1 내지 3 중량%, 또는 1 내지 2 중량%, 예를 들어 1.8 중량% 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition contains 1 to 10% by weight, 1 to 9% by weight, 1 to 8% by weight, 1 to 7% by weight, 1 to 6% by weight, based on the total weight of the hair dye composition. It may additionally include 1 to 5% by weight, 1 to 4% by weight, 1 to 3% by weight, or 1 to 2% by weight, for example, 1.8% by weight.
라우릴하이드록시설테인을 상기 함량 범위로 포함하는 경우 거품력의 양, 거품의 크기 및 거품의 지속력이 우수한 염모제의 제조가 가능해질 수 있다.If lauryl hydroxysulsteine is included in the above content range, it may be possible to manufacture a hair dye with excellent foaming power, foam size, and foam sustainability.
본 발명에 있어서, 염모제 조성물은 라우라마이드미파를 염모제 조성물 총 중량 대비 0.1 내지 5 중량%, 0.1 내지 4.5 중량%, 0.1 내지 4 중량%, 0.1 내지 3.5 중량%, 0.1 내지 3 중량%, 0.1 내지 2.5 중량%, 0.1 내지 2 중량%, 0.1 내지 1.5 중량%, 또는 0.1 내지 1 중량%, 예를 들어 0.5 중량% 추가적으로 포함하는 것일 수 있다. In the present invention, the hair dye composition contains Lauramid Mifah in an amount of 0.1 to 5% by weight, 0.1 to 4.5% by weight, 0.1 to 4% by weight, 0.1 to 3.5% by weight, 0.1 to 3% by weight, 0.1 to 10% by weight, based on the total weight of the hair dye composition. It may additionally include 2.5% by weight, 0.1 to 2% by weight, 0.1 to 1.5% by weight, or 0.1 to 1% by weight, for example, 0.5% by weight.
라우라마이드미파를 상기 함량 범위로 포함하는 경우 거품력의 양, 거품의 크기 및 거품의 지속력이 우수한 염모제의 제조가 가능해질 수 있다.If Lauramid Mifah is included in the above content range, it may be possible to manufacture a hair dye with excellent foaming power, foam size, and foam sustainability.
본 발명에 있어서, 염모제 조성물은 소듐C14-16올레핀설포네이트를 염모제 조성물 총 중량 대비 0.1 내지 30 중량%, 0.1 내지 20 중량%, 0.1 내지 10 중량%, 0.1 내지 5 중량%, 1 내지 30 중량%, 1 내지 20 중량%, 1 내지 10 중량%, 1 내지 5 중량%, 2 내지 30 중량%, 2 내지 20 중량%, 2 내지 10 중량%, 2 내지 5 중량%, 3 내지 30 중량%, 3 내지 20 중량%, 3 내지 10 중량%, 또는 3 내지 5 중량%, 예를 들어 3.5 중량% 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition contains sodium C14-16 olefin sulfonate in an amount of 0.1 to 30% by weight, 0.1 to 20% by weight, 0.1 to 10% by weight, 0.1 to 5% by weight, and 1 to 30% by weight based on the total weight of the hair dye composition. , 1 to 20% by weight, 1 to 10% by weight, 1 to 5% by weight, 2 to 30% by weight, 2 to 20% by weight, 2 to 10% by weight, 2 to 5% by weight, 3 to 30% by weight, 3 It may additionally include from 20% by weight, 3 to 10% by weight, or 3 to 5% by weight, for example, 3.5% by weight.
소듐C14-16올레핀설포네이트를 상기 함량 범위로 포함하는 경우 거품력의 양, 거품의 크기 및 거품의 지속력이 우수한 염모제의 제조가 가능해질 수 있다.When sodium C14-16 olefin sulfonate is included in the above content range, it is possible to manufacture a hair dye with excellent foaming power, foam size, and foam sustainability.
본 발명에 있어서, 염모제 조성물은 향료, 색소, 방부제, 점증제, 보습제, 보존제 및 용제로 이루어진 군으로부터 선택되는 1종 이상을 추가적으로 포함하는 것일 수 있다.In the present invention, the hair dye composition may additionally include one or more selected from the group consisting of fragrances, pigments, preservatives, thickeners, moisturizers, preservatives, and solvents.
본 발명에 있어서, 염모제 조성물은 샴푸, 린스, 트리트먼트, 컨디셔닝제, 헤어젤, 헤어에센스, 헤어오일, 헤어팩 및 헤어크림으로 이루어진 군에서 선택되는 어느 하나의 제품으로 제형화될 수 있으나, 이에 한정되는 것은 아니다.In the present invention, the hair dye composition may be formulated as any one product selected from the group consisting of shampoo, rinse, treatment, conditioning agent, hair gel, hair essence, hair oil, hair pack, and hair cream, but is limited thereto. It doesn't work.
본 발명은 포타슘알룸 (Potassium alum) 및 폴리우레탄-10 (Polyurethane-10; PU-10)을 포함하는 염모제 조성물에 관한 것으로, 본 발명의 염모제 조성물을 사용하여 모발 염색 시 염색의 선명도 및 색상 균일도가 우수한 효과가 있다.The present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10). When dyeing hair using the hair dye composition of the present invention, the vividness and color uniformity of the dyeing are improved. It has excellent effects.
도 1은 본 발명의 제조예에 따라 제조된 실시예 및 비교예의 색상 균일도를 비교한 그래프이다.Figure 1 is a graph comparing the color uniformity of examples and comparative examples manufactured according to the manufacturing example of the present invention.
도 2는 본 발명의 제조예에 따라 제조된 실시예 및 비교예의 염색의 선명도를 나타낸 그래프이다.Figure 2 is a graph showing the clarity of dyeing of examples and comparative examples prepared according to the manufacturing example of the present invention.
본 발명은 포타슘알룸 (Potassium alum) 및 폴리우레탄-10 (Polyurethane-10; PU-10)을 포함하는 염모제 조성물에 관한 것이다.The present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10).
이하, 본 발명을 구체적으로 설명하기 위해 제조예 및 실험예를 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 제조예 및 실험예는 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상술하는 제조예 및 실험예에 한정되는 것으로 해석되어서는 안 된다. 본 발명의 제조예 및 실험예는 당 업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되는 것이다.Hereinafter, the present invention will be described in detail with reference to manufacturing examples and experimental examples. However, the manufacturing examples and experimental examples according to the present invention may be modified into various other forms, and the scope of the present invention should not be construed as being limited to the manufacturing examples and experimental examples detailed below. Preparation examples and experimental examples of the present invention are provided to more completely explain the present invention to those with average knowledge in the art.
제조예 1. 염모제 조성물의 제조Preparation Example 1. Preparation of hair dye composition
하기 표 1 및 2의 조성에 따라 실시예 및 비교예의 염모제 조성물을 제조하였다.Hair dye compositions of Examples and Comparative Examples were prepared according to the compositions in Tables 1 and 2 below.
구체적으로, 수상부 원료 (정제수 및 베헨트라이모늄클로라이드)와 유상부 원료 (세테아릴알코올 및 스테아릴알코올)를 각각 별도로 75 ℃에서 용해시키고, HOMO Mixer 장치를 이용하여 5000 rpm으로 혼합하였다. 그 다음 45 ℃에서 저온 교반 냉각을 한 후, 포타슘알룸과 폴리우레탄-10을 투입하고 HOMO Mixer 장치를 이용하여 5000 rpm으로 혼합하였다. 그 다음 염료 (Basic Brown 16, Basic Red 51, Basic Yellow 87 및 Basic Blue 99)와 프로필렌글라이콜을 투입하고 HOMO Mixer 장치를 이용하여 5000 rpm으로 혼합하였다. 그 다음 방부제를 투입하고 HOMO Mixer 장치를 이용하여 5000 rpm으로 혼합하였다. 그 다음 30 ℃에서 저온 교반 냉각을 한 후 진공펌프를 사용해 탈기 (탈포)를 진행하였다.Specifically, the water phase raw materials (purified water and behentrimonium chloride) and the oil phase raw materials (cetearyl alcohol and stearyl alcohol) were dissolved separately at 75°C and mixed at 5000 rpm using a HOMO Mixer device. Next, after low-temperature stirring and cooling at 45°C, potassium alum and polyurethane-10 were added and mixed at 5000 rpm using a HOMO Mixer device. Next, dyes (Basic Brown 16, Basic Red 51, Basic Yellow 87, and Basic Blue 99) and propylene glycol were added and mixed at 5000 rpm using a HOMO Mixer device. Next, a preservative was added and mixed at 5000 rpm using a HOMO Mixer device. Then, after low-temperature stirring and cooling at 30°C, degassing (defoaming) was performed using a vacuum pump.
성분명 (중량%)Ingredient name (% by weight) 실시예 1Example 1
포타슘알룸Potassium Alum 1.001.00
폴리우레탄-10Polyurethane-10 1.001.00
Basic Brown 16Basic Brown 16 0.1150.115
Basic Red 51Basic Red 51 0.0070.007
Basic Yellow 87Basic Yellow 87 0.0150.015
Basic Blue 99Basic Blue 99 0.200.20
세테아릴알코올Cetearyl alcohol 3.503.50
스테아릴알코올stearyl alcohol 3.503.50
베헨트라이모늄클로라이드behentrimonium chloride 2.002.00
프로필렌글라이콜propylene glycol 0.250.25
방부제antiseptic 1.001.00
정제수Purified water 87.41387.413
합계Sum 100100
성분명 (중량%)Ingredient name (% by weight) 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3
포타슘알룸Potassium Alum -- 1.001.00 --
폴리우레탄-10Polyurethane-10 1.001.00 -- --
Basic Brown 16Basic Brown 16 0.1150.115 0.1150.115 0.1150.115
Basic Red 51Basic Red 51 0.0070.007 0.0070.007 0.0070.007
Basic Yellow 87Basic Yellow 87 0.0150.015 0.0150.015 0.0150.015
Basic Blue 99Basic Blue 99 0.200.20 0.200.20 0.200.20
세테아릴알코올Cetearyl alcohol 3.503.50 3.503.50 3.503.50
스테아릴알코올stearyl alcohol 3.503.50 3.503.50 3.503.50
베헨트라이모늄클로라이드behentrimonium chloride 2.002.00 2.002.00 2.002.00
프로필렌글라이콜propylene glycol 0.250.25 0.250.25 0.250.25
방부제antiseptic 1.001.00 1.001.00 1.001.00
정제수Purified water 88.41388.413 88.41388.413 89.41389.413
합계Sum 100100 100100 100100
실험예 1: 염모제 조성물의 색상 균일도 비교Experimental Example 1: Comparison of color uniformity of hair dye compositions
상기 제조예 1에 따라 제조된 실시예 및 비교예의 색상 균일도를 비교하였다. The color uniformity of the examples and comparative examples prepared according to Preparation Example 1 was compared.
구체적으로, 5cm*5cm크기의 아이보리 색상의 Wool 패치에 제품을 도포하고 흐르는 물에 씻어낸 후 건조 진행하여 염색을 진행하였다. 염색된 Wool 패치 각각은 서로 다른 9곳으로 나누어 측색기 (제품명: Spectrophotometer, 모델명: CM-2600d)로 색상값 (L*, a*, b*)을 추출하였다. 그 결과를 도 1에 나타냈다.Specifically, the product was applied to an ivory-colored wool patch measuring 5cm*5cm, washed in running water, dried, and dyed. Each dyed wool patch was divided into 9 different locations and color values (L*, a*, b*) were extracted using a colorimeter (product name: Spectrophotometer, model name: CM-2600d). The results are shown in Figure 1.
도 1의 그래프의 x축은 a* 값을 의미하는 것으로서, a* 값은 색상 다이어그램에서 빨간색과 초록색을 한 축으로 만들어 +a*로 표기되면 빨간색에 가깝고 -a*로 표기되면 초록색에 가깝다는 것을 의미한다. y축은 b* 값을 의미하는 것으로서, b* 값은 색상 다이어그램에서 노랑색과 파랑색을 한 축으로 만들어 + b*로 표기되면 노랑색에 가깝고 -b*로 표기되면 파랑색에 가깝다는 것을 의미한다. 즉, 도 1의 그래프는 wool 패치에 서로 다른 지점의 색상값 a* 및 b*를 측정한 데이터로, 데이터의 점이 조밀할수록 색상 균일도가 우수함을 의미한다.The x-axis of the graph in Figure 1 represents the a* value. The a* value makes red and green on one axis in the color diagram, so when it is written as +a*, it is close to red, and when it is written as -a*, it is close to green. it means. The y-axis refers to the b* value. The b* value makes yellow and blue on one axis in a color diagram, so when it is written as + b*, it means it is close to yellow, and when it is written as -b*, it means it is close to blue. That is, the graph in Figure 1 is data measuring the color values a* and b* of different points in the wool patch, meaning that the denser the points in the data, the better the color uniformity.
도 1의 결과로, 포타슘알룸 및 폴리우레탄-10을 포함하는 염모제 조성물 (실시예 1)의 경우 폴리우레탄-10만을 포함하는 염모제 조성물 (비교예 1)에 비하여 색상 균일도가 우수함을 확인하였다.As a result of Figure 1, it was confirmed that the hair dye composition containing potassium alum and polyurethane-10 (Example 1) had superior color uniformity compared to the hair dye composition containing only polyurethane-10 (Comparative Example 1).
실험예 2: 염모제 조성물의 염색의 선명도 비교Experimental Example 2: Comparison of dyeing clarity of hair dye compositions
상기 제조예 1에 따라 제조된 실시예 및 비교예의 염색의 선명도를 측정하여 염색의 선명도를 비교하였다. The clarity of dyeing of the examples and comparative examples prepared according to Preparation Example 1 was measured and compared.
구체적으로, 5cm*5cm크기의 아이보리 색상의 Wool 패치에 제품을 도포하고 흐르는 물에 씻어낸 후 건조 진행하여 염색을 진행하였다. 염색된 Wool 패치 각각은 서로 다른 9곳으로 나누어 측색기 (제품명: Spectrophotometer, 모델명: CM-2600d)로 색상값 (L*, a*, b*)을 추출하였다. 그 결과를 도 2에 나타냈다.Specifically, the product was applied to an ivory-colored wool patch measuring 5cm*5cm, washed in running water, dried, and dyed. Each dyed wool patch was divided into 9 different locations and color values (L*, a*, b*) were extracted using a colorimeter (product name: Spectrophotometer, model name: CM-2600d). The results are shown in Figure 2.
도 2의 그래프의 x축은 측정 횟수를 의미하고 y축은 L* 값을 의미하는 것으로서, L* 값은 반사율을 측정한 데이터로 인간의 시각과 같은 명도를 나타내며 0~100까지의 값으로 표시되며 숫자가 높을수록 밝기가 밝음을 의미한다. 본 실험예는 아이보리 색상의 Wool 패치에 염색을 진행한 것으로, L* 값은 즉 염색의 선명도를 의미한다. 다시 말해, L* 값이 낮을수록 염색의 선명도가 우수함을 의미한다.The x-axis of the graph in FIG. 2 means the number of measurements and the y-axis means the L* value. The L* value is data measuring reflectance and represents the same brightness as human vision. It is expressed as a value from 0 to 100 and is a number. The higher the value, the brighter the brightness. In this experimental example, dyeing was performed on an ivory-colored wool patch, and the L* value means the vividness of the dyeing. In other words, the lower the L* value, the better the dyeing clarity.
포타슘알룸 및 폴리우레탄-10을 포함하는 실시예 1의 L* 평균값은 22로 측정되었고, 폴리우레탄-10만을 포함하는 비교예 1의 L* 평균값은 21로 측정되었고, 포타슘알룸만을 포함하는 비교예 2의 L* 평균값은 28로 측정되었고, 포타슘알룸 및 폴리우레탄-10을 모두 포함하지 않는 비교예 3의 L* 평균값은 23으로 측정되었다.The average L* value of Example 1 containing potassium alum and polyurethane-10 was measured to be 22, and the average L* value of Comparative Example 1 containing only polyurethane-10 was measured to be 21, and the average L* value of Example 1 containing only potassium alum was measured to be 21. The average L* value of 2 was measured to be 28, and the average L* value of Comparative Example 3, which does not contain both potassium alum and polyurethane-10, was measured to be 23.
도 2의 결과로, 포타슘알룸 및 폴리우레탄-10을 포함하는 염모제 조성물 (실시예 1)의 경우 포타슘알룸만을 포함하는 염모제 조성물 (비교예 2)에 비하여 색상이 진하여 염색의 선명도가 우수함을 확인하였다.As a result of Figure 2, it was confirmed that the color of the hair dye composition containing potassium alum and polyurethane-10 (Example 1) was darker than that of the hair dye composition containing only potassium alum (Comparative Example 2), and the clarity of dyeing was excellent. did.
즉, 도 1 및 도 2의 결과를 통해 포타슘알룸 또는 폴리우레탄-10을 단독으로 포함하는 염모제 조성물의 경우 염색의 선명도 및 색상 균일도 두 가지의 효과를 모두 충족시키기 어려운 반면, 포타슘알룸 및 폴리우레탄-10을 모두 포함하는 염모제 조성물의 경우 염색의 선명도 및 색상 균일도 모두 일정 수준 이상의 우수한 효과를 가지는 상호보완적 효과를 확인하였다.That is, through the results of Figures 1 and 2, it is difficult to satisfy both the effects of dyeing clarity and color uniformity in the case of a hair dye composition containing potassium alum or polyurethane-10 alone, whereas potassium alum and polyurethane-10 are difficult to achieve. In the case of a hair dye composition containing all 10, a complementary effect was confirmed, with excellent effects above a certain level in both dyeing clarity and color uniformity.
전술한 본 발명의 설명은 예시를 위한 것이며, 본 발명이 속하는 기술분야의 통상의 지식을 가진 자는 본 발명의 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 쉽게 변형이 가능하다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다.The description of the present invention described above is for illustrative purposes, and those skilled in the art will understand that the present invention can be easily modified into other specific forms without changing the technical idea or essential features of the present invention. will be. Therefore, the embodiments described above should be understood in all respects as illustrative and not restrictive.
본 발명은 포타슘알룸 (Potassium alum) 및 폴리우레탄-10 (Polyurethane-10; PU-10)을 포함하는 염모제 조성물에 관한 것으로, 본 발명의 염모제 조성물을 사용하여 모발 염색 시 염색의 선명도 및 색상 균일도가 우수한 효과가 있다.The present invention relates to a hair dye composition containing potassium alum and polyurethane-10 (PU-10). When dyeing hair using the hair dye composition of the present invention, the vividness and color uniformity of the dyeing are improved. It has excellent effects.

Claims (16)

  1. 포타슘알룸 (Potassium alum) 및 폴리우레탄-10 (Polyurethane-10; PU-10)을 포함하는 염모제 조성물.A hair dye composition containing potassium alum and polyurethane-10 (PU-10).
  2. 제1항에 있어서, 상기 포타슘알룸은 염모제 조성물 총 중량 대비 0.01 내지 5 중량% 포함되는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the potassium alum is contained in an amount of 0.01 to 5% by weight based on the total weight of the hair dye composition.
  3. 제1항에 있어서, 상기 폴리우레탄-10은 염모제 조성물 총 중량 대비 0.01 내지 5 중량% 포함되는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the polyurethane-10 is contained in an amount of 0.01 to 5% by weight based on the total weight of the hair dye composition.
  4. 제1항에 있어서, 상기 포타슘알룸 및 폴리우레탄-10의 중량비는 1:10 내지 10:1인 것을 특징으로 하는, 염모제 조성물.The hair dye composition according to claim 1, wherein the weight ratio of potassium alum and polyurethane-10 is 1:10 to 10:1.
  5. 제1항에 있어서, 상기 염모제 조성물은 염료를 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains a dye.
  6. 제5항에 있어서, 상기 염료는 염모제 조성물 총 중량 대비 0.001 내지 1 중량% 포함되는 것인, 염모제 조성물.The hair dye composition according to claim 5, wherein the dye is contained in an amount of 0.001 to 1% by weight based on the total weight of the hair dye composition.
  7. 제1항에 있어서, 상기 염모제 조성물은 세테아릴알코올 (Cetearyl alcohol), 스테아릴알코올 (Stearyl alcohol), 베헨트라이모늄클로라이드 (Behentrimonium chloride) 및 프로필렌글라이콜 (Propylene glycol)로 이루어진 군에서 선택되는 1종 이상을 추가적으로 포함하는 것인, 염모제 조성물.The method of claim 1, wherein the hair dye composition is selected from the group consisting of Cetearyl alcohol, Stearyl alcohol, Behentrimonium chloride, and Propylene glycol. A hair dye composition that additionally includes one or more types.
  8. 제1항에 있어서, 상기 염모제 조성물은 세테아릴알코올을 염모제 조성물 총 중량 대비 0.1내지 10 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 0.1 to 10% by weight of cetearyl alcohol based on the total weight of the hair dye composition.
  9. 제1항에 있어서, 상기 염모제 조성물은 스테아릴알코올을 염모제 조성물 총 중량 대비 0.1 내지 10 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 0.1 to 10% by weight of stearyl alcohol based on the total weight of the hair dye composition.
  10. 제1항에 있어서, 상기 염모제 조성물은 베헨트라이모늄클로라이드를 염모제 조성물 총 중량 대비 0.1 내지 10 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 0.1 to 10% by weight of behentrimonium chloride based on the total weight of the hair dye composition.
  11. 제1항에 있어서, 상기 염모제 조성물은 프로필렌글라이콜을 염모제 조성물 총 중량 대비 0.01 내지 5 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 0.01 to 5% by weight of propylene glycol based on the total weight of the hair dye composition.
  12. 제1항에 있어서, 상기 염모제 조성물은 코카미도프로필베타인 (Cocamidopropyl Betaine), 라우릴하이드록시설테인 (Lauryl Hydroxysultaine), 라우라마이드미파 (Lauramide MIPA) 및 소듐C14-16올레핀설포네이트 (Sodium C14-16 Olefin Sulfonate)로 이루어진 군에서 선택되는 1종 이상을 추가적으로 포함하는 것인, 염모제 조성물.The method of claim 1, wherein the hair dye composition includes Cocamidopropyl Betaine, Lauryl Hydroxysultaine, Lauramide MIPA, and Sodium C14-16 Olefin Sulfonate. A hair dye composition that additionally includes at least one selected from the group consisting of -16 Olefin Sulfonate.
  13. 제1항에 있어서, 상기 염모제 조성물은 코카미도프로필베타인을 염모제 조성물 총 중량 대비 5 내지 30 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 5 to 30% by weight of cocamidopropyl betaine based on the total weight of the hair dye composition.
  14. 제1항에 있어서, 상기 염모제 조성물은 라우릴하이드록시설테인을 염모제 조성물 총 중량 대비 1 내지 10 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 1 to 10% by weight of lauryl hydroxysulfate based on the total weight of the hair dye composition.
  15. 제1항에 있어서, 상기 염모제 조성물은 라우라마이드미파를 염모제 조성물 총 중량 대비 0.1 내지 5 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 0.1 to 5% by weight of Lauramid Mifah based on the total weight of the hair dye composition.
  16. 제1항에 있어서, 상기 염모제 조성물은 소듐C14-16올레핀설포네이트를 염모제 조성물 총 중량 대비 0.1 내지 30 중량% 추가적으로 포함하는 것인, 염모제 조성물.The hair dye composition according to claim 1, wherein the hair dye composition additionally contains 0.1 to 30% by weight of sodium C14-16 olefin sulfonate based on the total weight of the hair dye composition.
PCT/KR2023/016473 2022-10-25 2023-10-23 Hair dye composition containing potassium alum and polyurethane-10 WO2024090925A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2022-0138595 2022-10-25
KR1020220138595A KR20240059685A (en) 2022-10-25 2022-10-25 Hair dye composition comprising potassium alum and polyurethane-10

Publications (1)

Publication Number Publication Date
WO2024090925A1 true WO2024090925A1 (en) 2024-05-02

Family

ID=90831250

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2023/016473 WO2024090925A1 (en) 2022-10-25 2023-10-23 Hair dye composition containing potassium alum and polyurethane-10

Country Status (2)

Country Link
KR (1) KR20240059685A (en)
WO (1) WO2024090925A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101493483B1 (en) * 2012-02-13 2015-02-16 주식회사 세화 피앤씨 Hair and scalp protective composition for hair dyeing
JP2018135298A (en) * 2017-02-22 2018-08-30 日本精化株式会社 Cosmetic composition
US20190091118A1 (en) * 2014-12-17 2019-03-28 Henkel Ag & Co. Kgaa Agent for treating dyed hair
CN109689019A (en) * 2016-09-16 2019-04-26 株式会社资生堂 Composition and product
KR20210105937A (en) * 2018-12-20 2021-08-27 엘브이엠에이취 러쉐르쉐 How to dye or make up your eyebrows

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101493483B1 (en) * 2012-02-13 2015-02-16 주식회사 세화 피앤씨 Hair and scalp protective composition for hair dyeing
US20190091118A1 (en) * 2014-12-17 2019-03-28 Henkel Ag & Co. Kgaa Agent for treating dyed hair
CN109689019A (en) * 2016-09-16 2019-04-26 株式会社资生堂 Composition and product
JP2018135298A (en) * 2017-02-22 2018-08-30 日本精化株式会社 Cosmetic composition
KR20210105937A (en) * 2018-12-20 2021-08-27 엘브이엠에이취 러쉐르쉐 How to dye or make up your eyebrows

Also Published As

Publication number Publication date
KR20240059685A (en) 2024-05-08

Similar Documents

Publication Publication Date Title
EP0957893B1 (en) Composition for simultaneously lightening and coloring hair
CN1117265A (en) Cationic dyes for keratin-containing fibres
JP2003520220A (en) Composition for bleaching and coloring hair in one step, and method of using same
EP0359465B1 (en) Novel dyeing system
WO2023096054A1 (en) Hair dye composition
EP0335403A2 (en) Hair-dyeing composition
WO2021215629A1 (en) Foam type semi-permanent hair dyeing composition
WO2024090925A1 (en) Hair dye composition containing potassium alum and polyurethane-10
WO2017057868A1 (en) Moldable hair care composition
WO2023177084A1 (en) Phase-change hair dye composition
WO2017082526A1 (en) Agent for forming tooth whitening coating film and method for forming tooth whitening coating film
WO2023132669A1 (en) Method for manufacturing skin-care cosmetic composition
KR20020023121A (en) Acidic hairdye composition
EP0879591A1 (en) Ascorbic and isoascorbic acids to remove or adjust oxidative color in hair
DE3929173A1 (en) METHOD FOR COLORING HAIR WITH DIRECT COLORS
JP2004535409A (en) Semi-permanent hair dyeing system using vat dye
US3619102A (en) Dyeing keratinic fibers with aqueous solutions of direct dyes and organic solvents
WO2024049223A1 (en) Composition for dyeing and cleansing hair
DE60029185T2 (en) hair dye
KR20220050324A (en) Method for dyeing hair using mixture of polymer having amine group and natural dye
JPS62164612A (en) Hair dye
US3822112A (en) Dyeing live human hair with an aqueous solution of a direct dye,2-phenoxy-ethanol and ethyl glycol acetate
WO2023282376A1 (en) Hair-coloring composition containing polyphenols
WO2013147418A1 (en) Method for preserving natural flowers with gradation coloring and a liquid composition used therefor
DE1667874A1 (en) Hair dyes