WO2019000351A1 - Antistatic carpet detergent - Google Patents

Antistatic carpet detergent Download PDF

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Publication number
WO2019000351A1
WO2019000351A1 PCT/CN2017/090942 CN2017090942W WO2019000351A1 WO 2019000351 A1 WO2019000351 A1 WO 2019000351A1 CN 2017090942 W CN2017090942 W CN 2017090942W WO 2019000351 A1 WO2019000351 A1 WO 2019000351A1
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Prior art keywords
parts
sodium
polyoxyethylene ether
carpet
detergent
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PCT/CN2017/090942
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French (fr)
Chinese (zh)
Inventor
黄玉倩
Original Assignee
黄玉倩
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Publication date
Application filed by 黄玉倩 filed Critical 黄玉倩
Priority to PCT/CN2017/090942 priority Critical patent/WO2019000351A1/en
Publication of WO2019000351A1 publication Critical patent/WO2019000351A1/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/65Mixtures of anionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers

Definitions

  • the present invention relates to a laundry article, and more particularly to a novel static cleaning carpet detergent.
  • Modern detergents are complex mixtures of various ingredients, in which the surfactant is the main component of the cleaning action, and other ingredients in the detergent are either to improve and increase the cleaning performance of the surfactant, or to meet certain special needs. Or added to make the desired product form.
  • Various surfactants and various auxiliaries have their own characteristics, and these various components are mixed together, and the interaction between them will produce a more ideal washing effect.
  • the technical problem to be solved by the present invention is to provide a novel static cleaning carpet detergent.
  • the technical solution of the present invention is: a novel static cleaning carpet detergent, which is innovative in that the ratio of the weight fraction is made of the following components: 5-7 parts of oxalic acid, calcium hydrogen phosphate 2 - 6 parts, 3-6 parts of sodium lauroyl sarcosinate, 4-6 parts of tetraacetylethylenediamine, 1-4 parts of dodecyldimethylbenzylammonium bromide, 25-34 parts of deionized water; anion 13 parts of water-soluble ethylene acid copolymer, 6 parts of calcium hydrogen phosphate, 9 parts of alkylamine polyoxyethylene ether, 7 parts of fatty alcohol polyoxyethylene ether sulfate, 2 parts of cocoyl diethanolamine, sodium phosphate polymer 4 Serving, 3 parts of sodium lauroyl sarcosinate, 27 parts of urea, 5 parts of ⁇ -sulfofatty acid alkyl ester salt, 7 parts of sodium trimethylphenolate
  • the invention has the advantages of using an anionic surfactant such as a fatty alcohol polyoxyethylene ether sulfate, an ⁇ -sulfofatty acid alkyl ester salt or a sodium lauroyl sarcosinate, and a nonylphenol ethoxylate phosphate, coconut oil.
  • a nonionic surfactant such as acyl diethanolamine or hydrogenated castor oil polyoxypropylene ester, and added dodecyldimethylbenzylammonium bromide and alkylamine polyoxyethylene ether as an antistatic agent.
  • the detergent not only has strong detergency, but also has good washing effect, and can also ensure that the carpet does not generate static electricity and reduce the adsorption of dust.
  • the detergent of the invention has the advantages of convenient use and strong detergency, and can effectively maintain the static electricity on the carpet after the carpet is washed, and does not adsorb impurities.
  • the novel static elimination carpet detergent of the invention is prepared by the following components by weight fraction: 5 parts of oxalic acid, 2 parts of calcium hydrogen phosphate, 3 parts of sodium lauroyl sarcosinate, 4 parts of tetraacetylethylenediamine, bromination 1 part of dodecyldimethylbenzylammonium, 25 parts of deionized water; 13 parts of anionic water-soluble ethylene acid copolymer, 6 parts of calcium hydrogen phosphate, 9 parts of alkylamine polyoxyethylene ether, fatty alcohol polyoxyethylene 7 parts of sodium vinyl ether sulfate, 2 parts of cocoyl diethanolamine, 4 parts of sodium phosphate polymer, 3 parts of sodium lauroyl sarcosinate, 27 parts of urea, 5 parts of ⁇ -sulfofatty acid alkyl ester salt, trimethyl 7 parts of sodium phenolate, 7 parts of hydrogenated castor oil polyoxypropylene ester, 4 parts of tetraacetylethylene
  • the novel static-removing carpet detergent of the present invention is prepared by weighting the following components: 7 parts of oxalic acid, 6 parts of calcium hydrogen phosphate, 6 parts of sodium lauroyl sarcosinate, 6 parts of tetraacetylethylenediamine, bromination 4 parts of dodecyldimethylbenzylammonium, 34 parts of deionized water; 13 parts of anionic water-soluble ethylene acid copolymer, 6 parts of calcium hydrogen phosphate, 9 parts of alkylamine polyoxyethylene ether, fatty alcohol polyoxyethylene 7 parts of sodium vinyl ether sulfate, 2 parts of cocoyl diethanolamine, 4 parts of sodium phosphate polymer, 3 parts of sodium lauroyl sarcosinate, 27 parts of urea, 5 parts of ⁇ -sulfofatty acid alkyl ester salt, trimethyl 7 parts of sodium phenolate, 7 parts of hydrogenated castor oil polyoxypropylene ester, 4 parts of tetraacetyl
  • Anionic surfactants such as fatty alcohol polyoxyethylene ether sulfate, ⁇ -sulfofatty acid alkyl ester salt, sodium lauroyl sarcosinate, nonylphenol ethoxylate phosphate, cocoyl diethanolamine, and hydrazine hydride
  • a nonionic surfactant such as sesame oil polyoxypropylene ester, and adding dodecyldimethylbenzylammonium bromide and alkylamine polyoxyethylene ether as an antistatic agent, so that the prepared detergent not only detergency Strong, good washing effect, can also ensure that the carpet does not produce static electricity, reduce the adsorption of dust.
  • the detergent of the invention has the advantages of convenient use and strong detergency, and can effectively maintain the static electricity on the carpet after the carpet is washed, and does not adsorb impurities.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Disclosed is an antistatic carpet detergent, consisting of oxalic acid, calcium hydrogen phosphate, sodium lauroyl sarcosine, tetraacetylethylenediamine, dodecyl dimethylbenzylammonium bromide, and deionized water in a certain weight ratio. The detergent is convenient to use, has a strong detergency, and can effectively keep the carpet against static electricity and from adsorbing impurities after washing the carpet.

Description

[根据细则37.2由ISA制定的发明名称] 一种除静电地毯洗涤剂[Name of invention made by ISA according to Rule 37.2] A static cleaning carpet detergent 一种新型除静电地毯洗涤剂A new type of static cleaning carpet detergent
技术领域Technical field
本发明涉及一种洗涤用品,具体的说是一种新型除静电地毯洗涤剂。 The present invention relates to a laundry article, and more particularly to a novel static cleaning carpet detergent.
背景技术Background technique
现代洗涤剂是含有多种成分的复杂混合物,其中表面活性剂是起清洁作用的主要成分,洗涤剂中其他成分或是为改善和增加表面活性剂的清洗效能、或是为适应某些特殊需要、或是为制成所需而产品形式而加入的。各种表面活性剂和各种助剂都有各自的特性,这些性质各异的成分混在一起,由于他们之间相互作用便会产生更加理想的洗涤效果。目前市场上用于地毯的洗涤剂种类繁多,虽然都具有很好的洗涤效果,但是仍存在着抗静电性差的缺点,使得洗涤后的地毯仍能发生静电现象,容易吸附灰尘,无法满足市场的需求和人们的使用需求。Modern detergents are complex mixtures of various ingredients, in which the surfactant is the main component of the cleaning action, and other ingredients in the detergent are either to improve and increase the cleaning performance of the surfactant, or to meet certain special needs. Or added to make the desired product form. Various surfactants and various auxiliaries have their own characteristics, and these various components are mixed together, and the interaction between them will produce a more ideal washing effect. At present, there are many kinds of detergents for carpets on the market. Although they all have good washing effect, there are still disadvantages of poor antistatic property, so that the carpet after washing can still generate static electricity, and it is easy to adsorb dust, which cannot satisfy the market. Demand and people's needs for use.
发明内容Summary of the invention
本发明要解决的技术问题是提供一种新型除静电地毯洗涤剂。The technical problem to be solved by the present invention is to provide a novel static cleaning carpet detergent.
为解决上述技术问题,本发明的技术方案为:一种新型除静电地毯洗涤剂,其创新点在于:按重量分数配比由以下组分制成:草酸5-7份,磷酸氢钙2-6份,月桂酰肌氨酸钠3-6份,四乙酰乙二胺4-6份,溴化十二烷基二甲基苄基铵1-4份,去离子水25-34份;阴离子水溶性乙烯酸共聚物13份,磷酸氢钙6份,氧化烷基胺聚氧乙烯醚9分,脂肪醇聚氧乙烯醚硫酸钠7份,椰油酰二乙醇胺2份,磷酸钠聚合物4份,月桂酰肌氨酸钠3份,尿素27份,α-磺基脂肪酸烷基酯盐5份,三甲基苯酚钠7份,氢化蓖麻油聚氧丙烯酯7份,四乙酰乙二胺4份,壬基酚聚氧乙烯醚磷酸酯4份,溴化十二烷基二甲基苄基铵1份,去离子水25份。。In order to solve the above technical problems, the technical solution of the present invention is: a novel static cleaning carpet detergent, which is innovative in that the ratio of the weight fraction is made of the following components: 5-7 parts of oxalic acid, calcium hydrogen phosphate 2 - 6 parts, 3-6 parts of sodium lauroyl sarcosinate, 4-6 parts of tetraacetylethylenediamine, 1-4 parts of dodecyldimethylbenzylammonium bromide, 25-34 parts of deionized water; anion 13 parts of water-soluble ethylene acid copolymer, 6 parts of calcium hydrogen phosphate, 9 parts of alkylamine polyoxyethylene ether, 7 parts of fatty alcohol polyoxyethylene ether sulfate, 2 parts of cocoyl diethanolamine, sodium phosphate polymer 4 Serving, 3 parts of sodium lauroyl sarcosinate, 27 parts of urea, 5 parts of α-sulfofatty acid alkyl ester salt, 7 parts of sodium trimethylphenolate, 7 parts of hydrogenated castor oil polyoxypropylene ester, tetraacetylethylenediamine 4 parts, 4 parts of nonylphenol ethoxylate phosphate, 1 part of dodecyldimethylbenzylammonium bromide, and 25 parts of deionized water. .
本发明的优点在于:采用脂肪醇聚氧乙烯醚硫酸钠、α-磺基脂肪酸烷基酯盐、月桂酰肌氨酸钠等阴离子表面活性剂和壬基酚聚氧乙烯醚磷酸酯、椰油酰二乙醇胺、氢化蓖麻油聚氧丙烯酯等非离子表面活性剂,并加入溴化十二烷基二甲基苄基铵和氧化烷基胺聚氧乙烯醚作为抗静电剂,使制得的洗涤剂不仅去污力强,洗涤效果好,还能够保证地毯不产生静电现象,减少灰尘的吸附。The invention has the advantages of using an anionic surfactant such as a fatty alcohol polyoxyethylene ether sulfate, an α-sulfofatty acid alkyl ester salt or a sodium lauroyl sarcosinate, and a nonylphenol ethoxylate phosphate, coconut oil. a nonionic surfactant such as acyl diethanolamine or hydrogenated castor oil polyoxypropylene ester, and added dodecyldimethylbenzylammonium bromide and alkylamine polyoxyethylene ether as an antistatic agent. The detergent not only has strong detergency, but also has good washing effect, and can also ensure that the carpet does not generate static electricity and reduce the adsorption of dust.
本发明的洗涤剂使用方便,去污力强,洗涤地毯之后还能有效的保持地毯上不起静电,不吸附杂质。The detergent of the invention has the advantages of convenient use and strong detergency, and can effectively maintain the static electricity on the carpet after the carpet is washed, and does not adsorb impurities.
具体实施方式Detailed ways
下面的实施例可以使本专业的技术人员更全面地理解本发明,但并不因此将本发明限制在所述的实施例范围之中。The following examples are intended to provide a fuller understanding of the invention, and are not intended to limit the invention.
实施例1Example 1
本发明的新型除静电地毯洗涤剂按重量分数配比由以下组分制成:草酸5份,磷酸氢钙2份,月桂酰肌氨酸钠3份,四乙酰乙二胺4份,溴化十二烷基二甲基苄基铵1份,去离子水25份;阴离子水溶性乙烯酸共聚物13份,磷酸氢钙6份,氧化烷基胺聚氧乙烯醚9分,脂肪醇聚氧乙烯醚硫酸钠7份,椰油酰二乙醇胺2份,磷酸钠聚合物4份,月桂酰肌氨酸钠3份,尿素27份,α-磺基脂肪酸烷基酯盐5份,三甲基苯酚钠7份,氢化蓖麻油聚氧丙烯酯7份,四乙酰乙二胺4份,壬基酚聚氧乙烯醚磷酸酯4份,溴化十二烷基二甲基苄基铵1份,去离子水25份。The novel static elimination carpet detergent of the invention is prepared by the following components by weight fraction: 5 parts of oxalic acid, 2 parts of calcium hydrogen phosphate, 3 parts of sodium lauroyl sarcosinate, 4 parts of tetraacetylethylenediamine, bromination 1 part of dodecyldimethylbenzylammonium, 25 parts of deionized water; 13 parts of anionic water-soluble ethylene acid copolymer, 6 parts of calcium hydrogen phosphate, 9 parts of alkylamine polyoxyethylene ether, fatty alcohol polyoxyethylene 7 parts of sodium vinyl ether sulfate, 2 parts of cocoyl diethanolamine, 4 parts of sodium phosphate polymer, 3 parts of sodium lauroyl sarcosinate, 27 parts of urea, 5 parts of α-sulfofatty acid alkyl ester salt, trimethyl 7 parts of sodium phenolate, 7 parts of hydrogenated castor oil polyoxypropylene ester, 4 parts of tetraacetylethylenediamine, 4 parts of nonylphenol polyoxyethylene ether phosphate, 1 part of dodecyldimethylbenzylammonium bromide, 25 parts of deionized water.
实施例2Example 2
本发明的新型除静电地毯洗涤剂按重量分数配比由以下组分制成:草酸7份,磷酸氢钙6份,月桂酰肌氨酸钠6份,四乙酰乙二胺6份,溴化十二烷基二甲基苄基铵4份,去离子水34份;阴离子水溶性乙烯酸共聚物13份,磷酸氢钙6份,氧化烷基胺聚氧乙烯醚9分,脂肪醇聚氧乙烯醚硫酸钠7份,椰油酰二乙醇胺2份,磷酸钠聚合物4份,月桂酰肌氨酸钠3份,尿素27份,α-磺基脂肪酸烷基酯盐5份,三甲基苯酚钠7份,氢化蓖麻油聚氧丙烯酯7份,四乙酰乙二胺4份,壬基酚聚氧乙烯醚磷酸酯4份,溴化十二烷基二甲基苄基铵1份,去离子水25份。The novel static-removing carpet detergent of the present invention is prepared by weighting the following components: 7 parts of oxalic acid, 6 parts of calcium hydrogen phosphate, 6 parts of sodium lauroyl sarcosinate, 6 parts of tetraacetylethylenediamine, bromination 4 parts of dodecyldimethylbenzylammonium, 34 parts of deionized water; 13 parts of anionic water-soluble ethylene acid copolymer, 6 parts of calcium hydrogen phosphate, 9 parts of alkylamine polyoxyethylene ether, fatty alcohol polyoxyethylene 7 parts of sodium vinyl ether sulfate, 2 parts of cocoyl diethanolamine, 4 parts of sodium phosphate polymer, 3 parts of sodium lauroyl sarcosinate, 27 parts of urea, 5 parts of α-sulfofatty acid alkyl ester salt, trimethyl 7 parts of sodium phenolate, 7 parts of hydrogenated castor oil polyoxypropylene ester, 4 parts of tetraacetylethylenediamine, 4 parts of nonylphenol polyoxyethylene ether phosphate, 1 part of dodecyldimethylbenzylammonium bromide, 25 parts of deionized water.
采用脂肪醇聚氧乙烯醚硫酸钠、α-磺基脂肪酸烷基酯盐、月桂酰肌氨酸钠等阴离子表面活性剂和壬基酚聚氧乙烯醚磷酸酯、椰油酰二乙醇胺、氢化蓖麻油聚氧丙烯酯等非离子表面活性剂,并加入溴化十二烷基二甲基苄基铵和氧化烷基胺聚氧乙烯醚作为抗静电剂,使制得的洗涤剂不仅去污力强,洗涤效果好,还能够保证地毯不产生静电现象,减少灰尘的吸附。Anionic surfactants such as fatty alcohol polyoxyethylene ether sulfate, α-sulfofatty acid alkyl ester salt, sodium lauroyl sarcosinate, nonylphenol ethoxylate phosphate, cocoyl diethanolamine, and hydrazine hydride A nonionic surfactant such as sesame oil polyoxypropylene ester, and adding dodecyldimethylbenzylammonium bromide and alkylamine polyoxyethylene ether as an antistatic agent, so that the prepared detergent not only detergency Strong, good washing effect, can also ensure that the carpet does not produce static electricity, reduce the adsorption of dust.
本发明的洗涤剂使用方便,去污力强,洗涤地毯之后还能有效的保持地毯上不起静电,不吸附杂质。The detergent of the invention has the advantages of convenient use and strong detergency, and can effectively maintain the static electricity on the carpet after the carpet is washed, and does not adsorb impurities.

Claims (1)

  1. 一种新型除静电地毯洗涤剂,其特征在于:按重量分数配比由以下组分制成:草酸5-7份,磷酸氢钙2-6份,月桂酰肌氨酸钠3-6份,四乙酰乙二胺4-6份,溴化十二烷基二甲基苄基铵1-4份,去离子水25-34份;阴离子水溶性乙烯酸共聚物13份,磷酸氢钙6份,氧化烷基胺聚氧乙烯醚9分,脂肪醇聚氧乙烯醚硫酸钠7份,椰油酰二乙醇胺2份,磷酸钠聚合物4份,月桂酰肌氨酸钠3份,尿素27份,α-磺基脂肪酸烷基酯盐5份,三甲基苯酚钠7份,氢化蓖麻油聚氧丙烯酯7份,四乙酰乙二胺4份,壬基酚聚氧乙烯醚磷酸酯4份,溴化十二烷基二甲基苄基铵1份,去离子水25份。A novel static cleaning carpet detergent characterized in that the proportion by weight is made up of the following components: 5-7 parts of oxalic acid, 2-6 parts of calcium hydrogen phosphate, and 3-6 parts of sodium lauroyl sarcosinate. 4-6 parts of tetraacetylethylenediamine, 1-4 parts of dodecyldimethylbenzylammonium bromide, 25-34 parts of deionized water; 13 parts of anionic water-soluble ethylene acid copolymer, 6 parts of calcium hydrogen phosphate , oxidized alkylamine polyoxyethylene ether 9 points, fatty alcohol polyoxyethylene ether sulfate 7 parts, cocoyl diethanolamine 2 parts, sodium phosphate polymer 4 parts, sodium lauroyl sarcosinate 3 parts, urea 27 parts 5 parts of α-sulfofatty acid alkyl ester salt, 7 parts of sodium trimethylphenolate, 7 parts of hydrogenated castor oil polyoxypropylene ester, 4 parts of tetraacetylethylenediamine, 4 parts of nonylphenol polyoxyethylene ether phosphate 1 part of dodecyldimethylbenzylammonium bromide and 25 parts of deionized water.
PCT/CN2017/090942 2017-06-29 2017-06-29 Antistatic carpet detergent WO2019000351A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876477A (en) * 2012-09-07 2013-01-16 南通华豪巨电子科技有限公司 Antistatic cleaning agent for carpet
CN103060109A (en) * 2013-02-01 2013-04-24 施维华 Low-foam cleaning agent for cleaning polypropylene carpet
CN104178365A (en) * 2013-05-22 2014-12-03 江苏天恒纳米科技有限公司 Electrostatic-eliminating carpet-washing agent
CN106244348A (en) * 2016-08-08 2016-12-21 合肥永佳新材料科技有限公司 A kind of carpet Anti-static detergent and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876477A (en) * 2012-09-07 2013-01-16 南通华豪巨电子科技有限公司 Antistatic cleaning agent for carpet
CN103060109A (en) * 2013-02-01 2013-04-24 施维华 Low-foam cleaning agent for cleaning polypropylene carpet
CN104178365A (en) * 2013-05-22 2014-12-03 江苏天恒纳米科技有限公司 Electrostatic-eliminating carpet-washing agent
CN106244348A (en) * 2016-08-08 2016-12-21 合肥永佳新材料科技有限公司 A kind of carpet Anti-static detergent and preparation method thereof

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