WO2018216461A1 - Sintered member and method for producing same - Google Patents

Sintered member and method for producing same Download PDF

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Publication number
WO2018216461A1
WO2018216461A1 PCT/JP2018/017803 JP2018017803W WO2018216461A1 WO 2018216461 A1 WO2018216461 A1 WO 2018216461A1 JP 2018017803 W JP2018017803 W JP 2018017803W WO 2018216461 A1 WO2018216461 A1 WO 2018216461A1
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WIPO (PCT)
Prior art keywords
powder
raw material
mass
green compact
sintered member
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PCT/JP2018/017803
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French (fr)
Japanese (ja)
Inventor
朝之 伊志嶺
繁樹 江頭
宗巨 野田
Original Assignee
住友電気工業株式会社
住友電工焼結合金株式会社
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Application filed by 住友電気工業株式会社, 住友電工焼結合金株式会社 filed Critical 住友電気工業株式会社
Priority to US16/615,093 priority Critical patent/US20210162499A1/en
Priority to JP2019519548A priority patent/JPWO2018216461A1/en
Publication of WO2018216461A1 publication Critical patent/WO2018216461A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/16Both compacting and sintering in successive or repeated steps
    • B22F3/162Machining, working after consolidation
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0257Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0278Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
    • C22C33/0285Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/24After-treatment of workpieces or articles
    • B22F2003/247Removing material: carving, cleaning, grinding, hobbing, honing, lapping, polishing, milling, shaving, skiving, turning the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • B22F2009/0824Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid with a specific atomising fluid
    • B22F2009/0828Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid with a specific atomising fluid with water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2201/00Treatment under specific atmosphere
    • B22F2201/02Nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/10Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/15Nickel or cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/30Low melting point metals, i.e. Zn, Pb, Sn, Cd, In, Ga
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/35Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/10Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
    • B22F5/106Tube or ring forms

Definitions

  • the present disclosure relates to a method for manufacturing a sintered member.
  • This application claims priority based on Japanese Patent Application No. 2017-105088 filed on May 26, 2017, and incorporates all the contents described in the aforementioned Japanese Patent Application.
  • a method for producing a sintered body of Patent Document 1 As a method for producing a sintered member used for automobile parts or general machine parts, a method for producing a sintered body of Patent Document 1 is known.
  • the method for manufacturing the sintered body includes a step of pressure-molding a metal powder to produce a molded body, a step of temporarily firing the molded body, a step of machining the temporary fired body, a machining step, And a step of firing.
  • the pressure during pressure molding is set to 100 MPa to 1500 MPa.
  • the method for producing a sintered member according to the present disclosure is as follows. Preparing a raw material powder containing iron-based powder; A step of pressure-molding the raw material powder to form a cylindrical or cylindrical powder compact having a relative density of 97% or more; A step of sintering the green compact.
  • the raw material powder includes at least one of a mixed powder containing pure iron powder and Ni powder, and an iron alloy powder containing Ni as an additive element, The total content of the Ni powder in the raw material powder and Ni as the additive element is 1% by mass or more.
  • FIG. 1 is a graph showing the relationship between molding pressure and molding density in Test Example 1.
  • FIG. 2 is a graph showing the relationship between molding density and tensile strength in Test Example 1.
  • a method for manufacturing a sintered member includes: Preparing a raw material powder containing iron-based powder; A step of pressure-molding the raw material powder to form a cylindrical or cylindrical powder compact having a relative density of 97% or more; A step of sintering the green compact.
  • the raw material powder includes at least one of a mixed powder containing pure iron powder and Ni powder, and an iron alloy powder containing Ni as an additive element, The total content of the Ni powder in the raw material powder and Ni as the additive element is 1% by mass or more.
  • a sintered member having high density and high strength can be manufactured. This is because the relative density of the green compact is 97% or more and the green compact shrinks due to sintering, so the relative density of the sintered member is larger than the relative density of the green compact. This is because the strength can be improved by the relative density of the sintered member being high.
  • a sintered member having a high density and a complicated shape can be easily manufactured.
  • the compacted body contains 1% by mass of Ni that lowers the machinability as a powder or 1% by mass or more as an additive element of the alloy, as compared with a sintered member or a melted material having the same composition. Easy to cut because it is soft and has low stickiness.
  • the green compact is softer than a sintered member or melted material, the relative density is very high and the strength is high to some extent.
  • the method for manufacturing a sintered member includes a step of preparing raw material powder (raw material preparation step), a step of pressing the raw material powder to form a green compact (molding step), and compacting. And a step of sintering the body (sintering step).
  • a specific raw material powder is prepared in the raw material preparation step, and a green compact that satisfies a specific relative density in the forming step is produced.
  • the raw material preparation step prepares a raw material powder including an iron-based powder having a plurality of iron-based particles.
  • the iron-based refers to pure iron or an iron alloy containing iron as a main component.
  • the raw material powder includes any one of a mixed powder containing Ni as a powder, an iron alloy powder containing Ni as an additive element, and a composite powder containing both the mixed powder and the iron alloy powder.
  • the mixed powder includes pure iron powder and Ni powder.
  • the content of the pure iron powder is, for example, 90% by mass or more, further 95% by mass or more when the raw material powder is 100% by mass.
  • the content of the Ni powder is 1% by mass or more when the raw material powder is 100% by mass. When the content of the Ni powder is 1% by mass or more, the hardenability is improved and the mechanical properties of the sintered member can be improved.
  • the content of the Ni powder is further 2% by mass or more and 10% by mass or less. This mixed powder becomes an iron-based alloy by sintering in a subsequent sintering step.
  • the mixed powder may further contain a powder of an alloying element that becomes an iron-based alloy by sintering in a subsequent sintering step.
  • the alloying element include at least one selected from Cu, Sn, Cr, Mo, Mn, and C.
  • the alloying element contributes to the improvement of the mechanical properties of the sintered member.
  • the content of Cu, Sn, Cr, Mn and Mo powders is more than 0% by mass and 5.0% by mass or less, further 0.1% by mass when the raw material powder is 100% by mass. % Or more and 2.0% by mass or less.
  • the content of the C powder is more than 0% by mass and 2.0% by mass or less, and further 0.1% by mass or more and 1.0% by mass or less when the raw material powder is 100% by mass.
  • the iron alloy powder has a plurality of iron alloy particles containing iron as a main component and Ni as an additive element.
  • the iron content is 90% by mass or more, and more preferably 95% by mass or more when the iron alloy is 100% by mass.
  • the content of Ni, when the iron alloy is 100% by mass, is 1% by mass or more, and further 2% by mass or more and 10% by mass or less.
  • the iron alloy may further contain at least one additive element selected from Cu, Sn, Cr, Mo, Mn, and C.
  • Iron alloys are allowed to contain inevitable impurities. Specific iron alloys include Fe—Ni—Mo alloy, Fe—Ni—Mo—C alloy, Fe—Ni—C alloy, Fe—Ni—Mo—Cr alloy, Fe—Ni—Mo—Mn. Alloy, Fe—Ni—Cr alloy, Fe—Ni—Cu alloy, Fe—Cu—Ni—Mo alloy, Fe—Ni—Mo—Cu—C alloy and the like.
  • the total content of Cu, Sn, Cr, Mn and Mo in the iron alloy is more than 0% by mass and 5.0% by mass or less, and further 0.1% by mass to 2.0% by mass.
  • the content of C in the iron alloy is more than 0% by mass and 2.0% by mass or less, and further 0.1% by mass to 1.0% by mass.
  • C may not be included as an additive element of the iron alloy but may be included in the raw material powder as a powder. That is, the raw material powder may contain C powder in addition to the iron alloy powder.
  • the composite powder includes both the above mixed powder and the above iron alloy powder. That is, the composite powder includes pure iron powder, Ni powder, and iron alloy powder having a plurality of iron alloy particles containing iron as a main component and Ni as an additive element.
  • the total content of pure iron and iron contained in the iron alloy in the raw material powder is 90% by mass or more, further 95% by mass or more when the total raw material powder is 100% by mass.
  • the total content of Ni contained as an additive element in the Ni powder and the iron alloy in the raw material powder is 1% by mass or more when the entire raw material powder is 100% by mass, and further 2% by mass or more and 10% by mass or less. Is mentioned.
  • the iron-based powder water atomized powder, reduced powder, gas atomized powder, carbonyl powder and the like can be used.
  • the average particle diameter of iron-type powder 20 micrometers or more and 200 micrometers or less are mentioned, for example. If the average particle diameter of the iron-based powder is within the above range, it is easy to handle and pressure forming. In particular, the fluidity of the iron-based powder can be easily ensured by setting the average particle size of the iron-based powder to 20 ⁇ m or more. By setting the average particle size of the iron-based powder to 200 ⁇ m or less, it is easy to obtain a sintered body having a dense structure.
  • the average particle diameter of the iron-based powder is further 50 ⁇ m or more and 150 ⁇ m or less.
  • the average particle size of the iron-based powder is a particle size (D50) at which the cumulative volume in the volume particle size distribution measured by a laser diffraction particle size distribution measuring device is 50%.
  • the raw material powder may contain at least one of a lubricant and an organic binder. However, it is preferable that the lubricant and the organic binder are as small as possible. As for the total content, 0.1 mass% or less is mentioned. By doing so, even if the raw material powder contains at least one of a lubricant and an organic binder, the proportion of the metal powder contained in the molded body can be increased, so that a dense compacted green body can be easily obtained. When the lubricant and the organic binder are not contained, it is not necessary to degrease the green compact in a subsequent process.
  • the raw material powder is pressure-molded to produce a green compact with a relative density of 97% or more.
  • the relative density is further preferably 98% or more, and particularly preferably 99% or more.
  • the shape of the green compact include a shape that conforms to the final shape of the sintered member, a shape that is suitable for subsequent cutting, and specifically, a columnar shape, a cylindrical shape, and the like.
  • an appropriate molding device (mold) that can be molded into the above-mentioned shape is used. Specifically, it is preferable to use a mold capable of uniaxial pressing so as to be press-formed along the axial direction of a column or cylinder.
  • Uniaxial pressurization includes using a die having a die having openings on the top and bottom and a pair of punches fitted into the top and bottom openings.
  • the raw material powder is filled into the cavity of the die of this mold, and the raw material powder in the cavity is compressed by the upper punch and the lower punch to produce a compacted body.
  • the molding pressure (surface pressure) is 1560 MPa or more. By increasing the molding pressure, a green compact with a high relative density can be produced.
  • the molding pressure is further preferably 1660 MPa or more and 1760 MPa or more, and particularly preferably 1860 MPa or 1960 MPa or more. There is no particular upper limit on the molding pressure.
  • the molding step is preferably performed by a mold (external) lubrication method in which a lubricant is applied to the inner peripheral surface of the mold (the inner peripheral surface of the die or the pressing surface of the punch). Then, it is easy to prevent the raw material powder from sticking to the mold.
  • a lubricant for example, higher fatty acid, metal soap, fatty acid amide, higher fatty acid amide and the like can be used.
  • the metal soap include zinc stearate and lithium stearate.
  • fatty acid amides include stearic acid amide, lauric acid amide, and palmitic acid amide.
  • the higher fatty acid amide include ethylene bis stearic acid amide.
  • the relative density of the green compact to be produced is preferably 98% or more, particularly preferably 99% or more.
  • the relative density of the green compact is obtained from “ ⁇ (molding density of the green compact) / (true density of the green compact) ⁇ ⁇ 100”.
  • the compacting density of the compacted body is determined by immersing the compacted body in oil, “oil content density ⁇ ⁇ (mass of compacted body before oil impregnation) / (mass of compacted compact after oil impregnation) ⁇ ” Ask from.
  • the oil impregnation density is a value obtained by dividing the mass of the green compact after oil impregnation by the volume of the green compact.
  • the relative density of the green compact can be obtained by image analysis of the cross section of the green compact with commercially available image analysis software.
  • images of 10 or more observation fields are acquired.
  • the cross section may be an arbitrary cross section, and 10 or more cross sections may be taken as one visual field per cross section, or a plurality of visual fields may be taken per cross section.
  • the size of each visual field is 500 ⁇ m ⁇ 600 ⁇ m.
  • the image of each observation visual field is binarized to obtain the area ratio of the metal in each observation visual field, and the area ratio is regarded as the relative density of each observation visual field.
  • the average value of the relative density of all the observation visual fields is calculated
  • the green compact is sintered.
  • a sintered member in which the particles of the metal powder are brought into contact with each other is obtained.
  • the relative density of this sintered member is over 97%. Since the green compact has a relative density of 97% or more and the green compact shrinks due to sintering, the relative density of the sintered member after sintering is greater than the relative density of the green compact. is there. Since the green compact has a very high density, the amount of shrinkage of the green compact by sintering is very small, but the relative density of the sintered member exceeds the relative density of the green compact.
  • Sintering conditions can be appropriately selected according to the composition of the raw material powder.
  • sintering temperature 1100 degreeC or more and 1400 degrees C or less are mentioned, for example, Furthermore, 1200 degreeC or more and 1300 degrees C or less are mentioned.
  • sintering time 15 minutes or more and 150 minutes or less are mentioned, for example, Furthermore, 20 minutes or more and 60 minutes or less are mentioned.
  • Known conditions can be applied to the sintering conditions.
  • the sintered member manufacturing method includes a step of cutting the molded body (molded body processing step), and a step of carburizing and tempering the sintered member. It is possible to include at least one step of (heat treatment step) and a step of finishing the sintered member (finishing step).
  • the green body processing step the green body is cut after the molding step and before the sintering step.
  • the green compact is processed into a predetermined shape using a cutting tool. Since the green compact before sintering is cut, a sintered member having a high density and a complicated shape can be easily manufactured.
  • the green compact does not contain Ni, which lowers the machinability, as a powder, or contains 1% by mass or more as an additive element of the alloy. Easy to cut because it is soft and soft.
  • the green compact is softer than the sintered member or melted material, but has a relatively high relative density and a certain degree of strength. Therefore, it is easy to suppress the occurrence of chips and cracks due to cutting.
  • the green compact has only the raw material powder hardened by molding, and the metal powder particles are in mechanical contact with each other.
  • particles of the metal powder are diffusion-bonded and firmly bonded by sintering.
  • the melted material is the same size as the green compact, it is a material that is much larger and integrated than the metal particles that make up the green compact.
  • the processing speed to the compacted body using the mixed powder can be made faster than the processing speed to the compacted body using the alloy powder.
  • the maximum peripheral speed of the tool ( The cutting speed) is 350 m / min in the case of processing the alloy powder into a green compact, and 450 m / min in the case of processing the mixed powder into a green compact.
  • the maximum peripheral speed of the tool is 150 m / min in the case of processing into a molten material, and 150 m / min in the case of processing into a sintered member.
  • Examples of the cutting process include a turning process and a turning process.
  • the milling includes drilling.
  • Examples of the cutting tool include drilling, reamer, turning, milling, end mill, turning, cutting tool, and other types of cutting tips in the case of drilling.
  • a hob, a broach, a pinion cutter, or the like may be used, or a machining center that can automatically perform a plurality of types of processing may be used.
  • a volatile solution or a plastic solution in which an organic binder is dissolved may be applied or immersed on the surface of the green compact. If it does so, it is easy to suppress the crack and notch
  • the organic binder include polyethylene, polypropylene, polymethyl methacrylate, polystyrene, polyvinyl chloride, polyvinylidene chloride, polyamide, polyester, polyether, polyvinyl alcohol, vinyl acetate, paraffin, and various waxes.
  • Cutting may be performed while applying a compressive stress to the green compact in a direction that cancels the tensile stress acting on the green compact. If it does so, it will be easy to suppress a crack and a chip of a compacting object. For example, when forming a processed hole in a green compact with a broach, strong tensile stress acts near the exit of the processed hole when the broach penetrates the green compact. In this case, a plurality of green compacts may be stacked in multiple stages. It is preferable to dispose a dummy green compact or a plate material under the lowest green compact.
  • a plurality of green compacts are stacked in multiple stages, the lower surface of the green compact on the upper side is pressed against the upper surface of the lower green compact, and compressive stress acts on the lower surface. If broaching is performed from above the multi-stage stacked compacts, cracks and chips near the exit of the processed holes formed on the lower surface of the compact can be effectively prevented. Moreover, when forming a processing groove in a compacting body with a milling cutter, a strong tensile stress acts near the exit of the processing groove. In this case, it is possible to arrange a plurality of green compacts in the direction of milling and to apply a compressive stress to the portion serving as the exit of the processing groove.
  • the sintered member is carburized and tempered.
  • the mechanical properties of the sintered member particularly the hardness and toughness, are improved.
  • the finishing process In the finishing process, the surface roughness of the sintered member is reduced, and the size of the sintered member is adjusted to the design dimension. For example, the grinding
  • the sintered member manufacturing method according to the embodiment can manufacture a sintered member having high density and high strength. Further, a sintered member having a high density and a complicated shape can be easily manufactured. Therefore, the method for manufacturing a sintered member according to the embodiment is suitably used for manufacturing various general structural parts (sintered parts such as mechanical parts such as sprockets, rotors, gears, rings, flanges, pulleys, and bearings). it can.
  • the sintered member is formed by bonding a plurality of metal particles, and the relative density exceeds 97%.
  • This sintered member can be manufactured by the above-described method for manufacturing a sintered member (raw material preparation step, molding step and sintering step). Since the relative density of the molded body is 97% or more, the relative density of the sintered member that has undergone the subsequent sintering step also exceeds 97%.
  • the method for measuring the relative density is the same as the method for measuring the relative density of the green compact.
  • This sintered member has no substantial change in density within a range of 1 mm from the surface thereof. That is, the density is substantially uniform. This is because no rolling process is applied to the sintered member. Further, the stream structure in which the metal particles are stretched is not formed in the metal structure of the sintered member. This is because the sintered member is not forged.
  • Test Example 1 Sintered members were prepared and the relative density and strength of the sintered members were evaluated.
  • sample No. 1-1-No. 1-3, no. 1-101-No. 1-103 Sample No. 1-1-No. 1-3, no. 1-101-No. The sintered member 1-103 was produced through the raw material preparation step, the forming step, and the sintering step in the same manner as the above-described sintered member manufacturing method.
  • the raw material powder As the raw material powder, an iron alloy powder and a carbon powder prepared by a water atomization method were prepared.
  • the composition of the iron alloy powder is 2 mass% Ni-0.5 mass% Mo-balance Fe and inevitable impurities, and the average particle diameter (D50) is 70 ⁇ m.
  • the average particle diameter (D50) of the carbon powder is 5 ⁇ m.
  • the raw material powder was 100% by mass, the carbon powder content was 0.3% by mass, and the balance was iron alloy powder.
  • the raw material powder does not contain a lubricant and an organic binder.
  • the raw material powder was pressure-molded to produce a cylindrical compact (outer diameter: 75 mm, height: 20 mm).
  • a mold capable of uniaxial pressing was used for the production of the green compact.
  • This mold has openings on the top and bottom and forms a die having circular insertion holes that form the outer peripheral surface of the cylindrical powder compact, and both end faces of the cylindrical compact. And upper and lower punches having a circular press surface.
  • an alcohol solution of myristic acid was applied as a lubricant.
  • the molding pressure is as shown in Table 1.
  • the molding pressure in Table 1 is a numerical value obtained by converting “8 ton / cm 2 to 20 ton / cm 2 ” into “MPa” and rounding.
  • the relative density of the produced green compact was measured.
  • the relative density of the green compact was determined from “ ⁇ (molding density of the green compact) / (true density of the green compact) ⁇ ⁇ 100”.
  • the compacting density of the compacted body is determined by immersing the compacted body in oil, “oil content density ⁇ ⁇ (mass of compacted body before oil impregnation) / (mass of compacted compact after oil impregnation) ⁇ ” I asked for it.
  • the oil impregnation density is a value obtained by dividing the mass of the green compact after oil impregnation by the volume of the green compact.
  • the true density of the green compact (raw material powder) is about 7.8 g / cm 3 .
  • Table 1 shows the molding density and the relative density of the green compact of each sample. Moreover, the relationship between the shaping
  • the green compact was sintered to produce a sintered member.
  • the sintering conditions were a sintering temperature of 1150 ° C., a sintering time of 60 minutes, and a sintering atmosphere of a nitrogen atmosphere.
  • Sample No. 1-111-No. 1-117 Sample No. 1-111-No. The sintered member No. 1-117 has a sample No. 1 except that the lubricant is not applied to the mold and the raw material powder further contains a lubricant. It was produced in the same manner as 1-1. Ethylene bis stearamide was used as the lubricant, and the content of the lubricant in the raw material powder was 0.6% by mass. Sample No. 1-111-No. The relative density of the green compact of 1-117 was measured as Sample No. Measurement was performed in the same manner as in 1-1. Table 1 shows the molding density and the relative density of the green compact of each sample.
  • sample no. 1-101-No. 1-103 no. 1-111-No. It can be seen that the relative density of the green compacts of 1-117 is less than 97%. From this result, sample no. 1-101-No. 1-103, no. 1-111-No. It is considered that the relative density of each of the sintered members 1-117 is less than 97%.
  • the strength of the sintered member was evaluated by performing a tensile test and measuring the tensile strength.
  • Sample No. In the same manner as in 1-1, the sample No. Cylindrical sintered members of 2-1, 2-2, 2-101 to 2-103 were produced.
  • the molding pressure was adjusted so that the molding density (relative density) of each sample was the value shown in Table 2.
  • This cylindrical sintered member was processed into a predetermined shape and subjected to carburizing and quenching to prepare a test piece for measuring tensile strength.
  • a test piece is flat form comprised by the narrow part and the wide part formed in the both ends of a narrow part.
  • the thickness of the test piece is 4 mm and the length is 72 mm.
  • the narrow width portion is composed of a central portion and a shoulder portion having an arcuate side surface formed from the central portion to the wide width portion.
  • the central portion has a length of 32 mm, the central width is 5.7 mm, and both ends have a width of 5.96 mm.
  • the radius R of the side surface of the shoulder is 25 mm.
  • the width of the thick part is 8.7 mm.
  • the results of tensile strength (MPa) are shown in Table 2.
  • FIG. 2 shows the relationship between the molding density (g / cm 3 ) and the tensile strength (MPa).
  • the horizontal axis of the graph shown in FIG. 2 is the molding density, and the vertical axis is the tensile strength.
  • FIG. 2-1 No. 2
  • the average value of the tensile strength of 2-2 was plotted with black circles, and sample No. 2-101-No.
  • the average value of the tensile strength of 2-103 is plotted with black diamonds, and the maximum value and the minimum value of the tensile strength in these samples are indicated by error bars.
  • the tensile strength of the test piece (sintered member) 2-2 is 1700 MPa or more, further 1750 MPa or more, particularly 1800 MPa or more.
  • sample no. 2-101-No It can be seen that the tensile strength of the 2-103 test piece (sintered member) is less than 1700 MPa. Therefore, it can be understood that a sintered member having a high density and high strength can be obtained by sintering a green compact having a relative density of 97% or more.

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Abstract

Provided is a method for producing a sintered member, the method comprising: a step for preparing raw material powder containing iron-based powder; a step for pressure molding the raw material powder to form a columnar or cylindrical powder compact having a relative density of at least 97%; and a step for sintering the powder compact, wherein the raw material powder contains at least one among a mixed powder containing pure iron powder and Ni powder, and an iron alloy powder containing Ni as an additive element, and the sum content of Ni powder in the raw material powder and Ni as an additive element is at least 1 mass%.

Description

焼結部材の製造方法Method for manufacturing sintered member
 本開示は、焼結部材の製造方法に関する。本出願は2017年5月26日出願の日本特許出願第2017-105088号に基づく優先権を主張し、前記日本特許出願に記載された全ての内容を援用するものである。 The present disclosure relates to a method for manufacturing a sintered member. This application claims priority based on Japanese Patent Application No. 2017-105088 filed on May 26, 2017, and incorporates all the contents described in the aforementioned Japanese Patent Application.
 自動車用部品や一般機械の部品などに利用される焼結部材を製造する方法として、特許文献1の焼結体の製造方法が知られている。この焼結体の製造方法は、金属粉末を加圧成形して成形体を作製する工程と、成形体を仮焼成する工程と、仮焼成体を機械加工する工程と、機械加工工程後、本焼成する工程とを備える。成形体を作製する工程では、加圧成形時の圧力を100MPa~1500MPaとしている。 As a method for producing a sintered member used for automobile parts or general machine parts, a method for producing a sintered body of Patent Document 1 is known. The method for manufacturing the sintered body includes a step of pressure-molding a metal powder to produce a molded body, a step of temporarily firing the molded body, a step of machining the temporary fired body, a machining step, And a step of firing. In the step of producing a molded body, the pressure during pressure molding is set to 100 MPa to 1500 MPa.
特開2007-77468号公報JP 2007-77468 A
 本開示に係る焼結部材の製造方法は、
 鉄系粉末を含む原料粉末を準備する工程と、
 前記原料粉末を加圧成形して相対密度が97%以上の円柱状又は円筒状の圧粉成形体を成形する工程と、
 前記圧粉成形体を焼結する工程とを備え、
 前記原料粉末は、純鉄粉とNi粉末とを含む混合粉末、及び添加元素としてNiを含む鉄合金粉末の少なくとも一方を含み、
 前記原料粉末中の前記Ni粉末、及び前記添加元素としてのNiの合計含有量が1質量%以上である。
The method for producing a sintered member according to the present disclosure is as follows.
Preparing a raw material powder containing iron-based powder;
A step of pressure-molding the raw material powder to form a cylindrical or cylindrical powder compact having a relative density of 97% or more;
A step of sintering the green compact.
The raw material powder includes at least one of a mixed powder containing pure iron powder and Ni powder, and an iron alloy powder containing Ni as an additive element,
The total content of the Ni powder in the raw material powder and Ni as the additive element is 1% by mass or more.
図1は、試験例1において、成形圧力と成形密度との関係を示すグラフである。FIG. 1 is a graph showing the relationship between molding pressure and molding density in Test Example 1. 図2は、試験例1において、成形密度と引張強さとの関係を示すグラフである。FIG. 2 is a graph showing the relationship between molding density and tensile strength in Test Example 1.
 《本開示の実施形態の説明》
 最初に本開示の実施態様の内容を列記して説明する。
<< Description of Embodiments of the Present Disclosure >>
First, the contents of the embodiments of the present disclosure will be listed and described.
 (1)本開示の一態様に係る焼結部材の製造方法は、
 鉄系粉末を含む原料粉末を準備する工程と、
 前記原料粉末を加圧成形して相対密度が97%以上の円柱状又は円筒状の圧粉成形体を成形する工程と、
 前記圧粉成形体を焼結する工程とを備え、
 前記原料粉末は、純鉄粉とNi粉末とを含む混合粉末、及び添加元素としてNiを含む鉄合金粉末の少なくとも一方を含み、
 前記原料粉末中の前記Ni粉末、及び前記添加元素としてのNiの合計含有量が1質量%以上である。
(1) A method for manufacturing a sintered member according to one aspect of the present disclosure includes:
Preparing a raw material powder containing iron-based powder;
A step of pressure-molding the raw material powder to form a cylindrical or cylindrical powder compact having a relative density of 97% or more;
A step of sintering the green compact.
The raw material powder includes at least one of a mixed powder containing pure iron powder and Ni powder, and an iron alloy powder containing Ni as an additive element,
The total content of the Ni powder in the raw material powder and Ni as the additive element is 1% by mass or more.
 上記の構成によれば、高密度で高強度な焼結部材を製造できる。圧粉成形体の相対密度が97%以上であり焼結により圧粉成形体は収縮するため、焼結部材の相対密度は、圧粉成形体の相対密度よりも大きくなるからである。焼結部材の相対密度が高いことで強度を向上できるからである。 According to the above configuration, a sintered member having high density and high strength can be manufactured. This is because the relative density of the green compact is 97% or more and the green compact shrinks due to sintering, so the relative density of the sintered member is larger than the relative density of the green compact. This is because the strength can be improved by the relative density of the sintered member being high.
 (2)上記焼結部材の製造方法の一形態として、前記成形工程後、前記焼結工程前に、前記圧粉成形体を切削加工する工程を備えることが挙げられる。 (2) As one form of the manufacturing method of the said sintered member, providing the process of cutting the said compacting body after the said formation process and before the said sintering process is mentioned.
 上記の構成によれば、高密度で複雑形状な焼結部材を容易に製造できる。圧粉成形体は、切削加工性を低下させるNiを粉末として1質量%含んでいても合金の添加元素として1質量%以上含んでいても、同じ組成の焼結部材や溶製材に比較して軟らかくて粘りが小さいため切削加工し易い。その上、圧粉成形体は、焼結部材や溶製材に比較すると軟らかいものの、相対密度が非常に高くて強度がある程度高いため、切削加工による欠けや亀裂の発生を抑制し易い。 According to the above configuration, a sintered member having a high density and a complicated shape can be easily manufactured. The compacted body contains 1% by mass of Ni that lowers the machinability as a powder or 1% by mass or more as an additive element of the alloy, as compared with a sintered member or a melted material having the same composition. Easy to cut because it is soft and has low stickiness. In addition, although the green compact is softer than a sintered member or melted material, the relative density is very high and the strength is high to some extent.
 《本開示の実施形態の詳細》
 本開示の実施形態の詳細を、以下に説明する。
<< Details of Embodiments of the Present Disclosure >>
Details of embodiments of the present disclosure are described below.
 〔焼結部材の製造方法〕
 実施形態に係る焼結部材の製造方法は、原料粉末を準備する工程(原料準備工程)と、原料粉末を加圧成形して圧粉成形体を成形する工程(成形工程)と、圧粉成形体を焼結する工程(焼結工程)とを備える。この焼結部材の製造方法の特徴の一つは、原料準備工程で特定の原料粉末を準備し、成形工程で特定の相対密度を満たす圧粉成形体を作製することにある。以下、各工程の詳細を説明する。
[Method for producing sintered member]
The method for manufacturing a sintered member according to the embodiment includes a step of preparing raw material powder (raw material preparation step), a step of pressing the raw material powder to form a green compact (molding step), and compacting. And a step of sintering the body (sintering step). One of the features of this method for producing a sintered member is that a specific raw material powder is prepared in the raw material preparation step, and a green compact that satisfies a specific relative density in the forming step is produced. Hereinafter, details of each process will be described.
  [原料準備工程]
 原料準備工程は、鉄系粒子を複数有する鉄系粉末を含む原料粉末を準備する。鉄系とは、純鉄、又は鉄を主成分とする鉄合金のことをいう。この原料粉末は、Niを粉末として含む混合粉末、Niを添加元素として含む鉄合金粉末、混合粉末と鉄合金粉末の両方を含む複合粉末のいずれか一つを有する。
[Raw material preparation process]
The raw material preparation step prepares a raw material powder including an iron-based powder having a plurality of iron-based particles. The iron-based refers to pure iron or an iron alloy containing iron as a main component. The raw material powder includes any one of a mixed powder containing Ni as a powder, an iron alloy powder containing Ni as an additive element, and a composite powder containing both the mixed powder and the iron alloy powder.
   (混合粉末)
 混合粉末は、純鉄粉とNi粉末とを含む。純鉄粉の含有量は、原料粉末を100質量%とするとき、例えば90質量%以上、更に95質量%以上とすることが挙げられる。Ni粉末の含有量は、原料粉末を100質量%とするとき、1質量%以上が挙げられる。Ni粉末の含有量が1質量%以上であることで、焼入れ性を向上させられて焼結部材の機械的特性を向上できる。Ni粉末の含有量は、更に2質量%以上10質量%以下が挙げられる。この混合粉末は、後の焼結工程で焼結することによって鉄基合金となる。
(Mixed powder)
The mixed powder includes pure iron powder and Ni powder. The content of the pure iron powder is, for example, 90% by mass or more, further 95% by mass or more when the raw material powder is 100% by mass. The content of the Ni powder is 1% by mass or more when the raw material powder is 100% by mass. When the content of the Ni powder is 1% by mass or more, the hardenability is improved and the mechanical properties of the sintered member can be improved. The content of the Ni powder is further 2% by mass or more and 10% by mass or less. This mixed powder becomes an iron-based alloy by sintering in a subsequent sintering step.
 混合粉末は、更に、後の焼結工程で焼結することによって鉄基合金となる合金化元素の粉末を含んでいてもよい。合金化元素としては、Cu,Sn,Cr,Mo,Mn,及びCから選択される少なくとも1種が挙げられる。上記合金化元素は、焼結部材の機械的特性の向上に寄与する。上記合金化元素のうちCu,Sn,Cr,Mn及びMoの粉末の含有量は、原料粉末を100質量%とするとき、合計で0質量%超5.0質量%以下、更に0.1質量%以上2.0質量%以下が挙げられる。一方、C粉末の含有量は、原料粉末を100質量%とするとき、0質量%超2.0質量%以下、更に0.1質量%以上1.0質量%以下が挙げられる。 The mixed powder may further contain a powder of an alloying element that becomes an iron-based alloy by sintering in a subsequent sintering step. Examples of the alloying element include at least one selected from Cu, Sn, Cr, Mo, Mn, and C. The alloying element contributes to the improvement of the mechanical properties of the sintered member. Among the alloying elements, the content of Cu, Sn, Cr, Mn and Mo powders is more than 0% by mass and 5.0% by mass or less, further 0.1% by mass when the raw material powder is 100% by mass. % Or more and 2.0% by mass or less. On the other hand, the content of the C powder is more than 0% by mass and 2.0% by mass or less, and further 0.1% by mass or more and 1.0% by mass or less when the raw material powder is 100% by mass.
   (鉄合金粉末)
 鉄合金粉末は、鉄を主成分とし、添加元素としてNiを含む鉄合金粒子を複数有する。
鉄の含有量は、鉄合金を100質量%とするとき、90質量%以上、更に95質量%以上が挙げられる。Niの含有量は、鉄合金を100質量%とするとき、1質量%以上が挙げられ、更に2質量%以上10質量%以下が挙げられる。
(Iron alloy powder)
The iron alloy powder has a plurality of iron alloy particles containing iron as a main component and Ni as an additive element.
The iron content is 90% by mass or more, and more preferably 95% by mass or more when the iron alloy is 100% by mass. The content of Ni, when the iron alloy is 100% by mass, is 1% by mass or more, and further 2% by mass or more and 10% by mass or less.
 鉄合金は、更に、Cu,Sn,Cr,Mo,Mn,及びCから選択される少なくとも1種の添加元素を含んでいてもよい。鉄合金は、不可避的不純物を含むことを許容する。具体的な鉄合金は、Fe-Ni-Mo系合金、Fe-Ni-Mo-C系合金,Fe-Ni-C系合金,Fe-Ni-Mo-Cr系合金,Fe-Ni-Mo-Mn系合金,Fe-Ni-Cr系合金,Fe-Ni-Cu系合金,Fe-Cu-Ni-Mo系合金,Fe-Ni-Mo-Cu-C系合金などが挙げられる。鉄合金におけるCu,Sn,Cr,Mn及びMoの含有量は、合計で0質量%超5.0質量%以下、更に0.1質量%以上2.0質量%以下が挙げられる。鉄合金におけるCの含有量は、0質量%超2.0質量%以下、更に0.1質量%以上1.0質量%以下が挙げられる。Cは、鉄合金の添加元素として含まず、粉末として原料粉末に含まれていてもよい。即ち、原料粉末は、鉄合金粉末に加えてC粉末を含んでいてもよい。 The iron alloy may further contain at least one additive element selected from Cu, Sn, Cr, Mo, Mn, and C. Iron alloys are allowed to contain inevitable impurities. Specific iron alloys include Fe—Ni—Mo alloy, Fe—Ni—Mo—C alloy, Fe—Ni—C alloy, Fe—Ni—Mo—Cr alloy, Fe—Ni—Mo—Mn. Alloy, Fe—Ni—Cr alloy, Fe—Ni—Cu alloy, Fe—Cu—Ni—Mo alloy, Fe—Ni—Mo—Cu—C alloy and the like. The total content of Cu, Sn, Cr, Mn and Mo in the iron alloy is more than 0% by mass and 5.0% by mass or less, and further 0.1% by mass to 2.0% by mass. The content of C in the iron alloy is more than 0% by mass and 2.0% by mass or less, and further 0.1% by mass to 1.0% by mass. C may not be included as an additive element of the iron alloy but may be included in the raw material powder as a powder. That is, the raw material powder may contain C powder in addition to the iron alloy powder.
   (複合粉末)
 複合粉末は、上述の混合粉末と上述の鉄合金粉末の両方を含む。即ち、複合粉末は、純鉄粉と、Ni粉末と、鉄を主成分とし添加元素としてNiを含む鉄合金粒子を複数有する鉄合金粉末とを含む。原料粉末中の粉純鉄及び鉄合金に含まれる鉄の合計含有量は、原料粉末全体を100質量%とするとき、90質量%以上、更に95質量%以上が挙げられる。原料粉末中のNi粉末及び鉄合金に添加元素として含まれるNiの合計含有量は、原料粉末全体を100質量%とするとき、1質量%以上が挙げられ、更に2質量%以上10質量%以下が挙げられる。
(Composite powder)
The composite powder includes both the above mixed powder and the above iron alloy powder. That is, the composite powder includes pure iron powder, Ni powder, and iron alloy powder having a plurality of iron alloy particles containing iron as a main component and Ni as an additive element. The total content of pure iron and iron contained in the iron alloy in the raw material powder is 90% by mass or more, further 95% by mass or more when the total raw material powder is 100% by mass. The total content of Ni contained as an additive element in the Ni powder and the iron alloy in the raw material powder is 1% by mass or more when the entire raw material powder is 100% by mass, and further 2% by mass or more and 10% by mass or less. Is mentioned.
 鉄系粉末は、水アトマイズ粉、還元粉、ガスアトマイズ粉、カルボニル粉などが利用できる。鉄系粉末の平均粒径は、例えば20μm以上200μm以下が挙げられる。鉄系粉末の平均粒径が上記範囲内であれば、取り扱い易く、加圧成形が行い易い。特に、鉄系粉末の平均粒径を20μm以上とすることで、鉄系粉末の流動性を確保し易い。鉄系粉末の平均粒径を200μm以下とすることで、緻密な組織の焼結体を得易い。鉄系粉末の平均粒径は、更に50μm以上150μm以下が挙げられる。鉄系粉末の平均粒径は、レーザ回折式粒度分布測定装置により測定した体積粒度分布における累積体積が50%となる粒径(D50)のことである。 As the iron-based powder, water atomized powder, reduced powder, gas atomized powder, carbonyl powder and the like can be used. As for the average particle diameter of iron-type powder, 20 micrometers or more and 200 micrometers or less are mentioned, for example. If the average particle diameter of the iron-based powder is within the above range, it is easy to handle and pressure forming. In particular, the fluidity of the iron-based powder can be easily ensured by setting the average particle size of the iron-based powder to 20 μm or more. By setting the average particle size of the iron-based powder to 200 μm or less, it is easy to obtain a sintered body having a dense structure. The average particle diameter of the iron-based powder is further 50 μm or more and 150 μm or less. The average particle size of the iron-based powder is a particle size (D50) at which the cumulative volume in the volume particle size distribution measured by a laser diffraction particle size distribution measuring device is 50%.
 原料粉末は、潤滑剤及び有機バインダーの少なくとも一方を含有してもよい。しかし、潤滑剤及び有機バインダーは、極力少ないことが好ましい。その合計含有量は、0.1質量%以下が挙げられる。そうすれば、原料粉末に潤滑剤及び有機バインダーの少なくとも一方を含有していても、成形体に含まれる金属粉末の割合を多くできるため、緻密な圧粉成形体を得易い。潤滑剤及び有機バインダーを含有しない場合、圧粉成形体を後工程で脱脂する必要がない。 The raw material powder may contain at least one of a lubricant and an organic binder. However, it is preferable that the lubricant and the organic binder are as small as possible. As for the total content, 0.1 mass% or less is mentioned. By doing so, even if the raw material powder contains at least one of a lubricant and an organic binder, the proportion of the metal powder contained in the molded body can be increased, so that a dense compacted green body can be easily obtained. When the lubricant and the organic binder are not contained, it is not necessary to degrease the green compact in a subsequent process.
  [成形工程]
 成形工程では、原料粉末を加圧成形して相対密度が97%以上の圧粉成形体を作製する。この相対密度は、更に98%以上が好ましく、特に99%以上が好ましい。圧粉成形体の形状は、焼結部材の最終形状に沿った形状や、後工程の切削加工に適した形状、具体的には円柱状や円筒状などが挙げられる。圧粉成形体の作製には、上記形状に成形できる適宜な成形装置(金型)を用いることが挙げられる。具体的には、円柱や円筒の軸方向に沿ってプレス成形するように一軸加圧が可能な金型を用いることが好ましい。一軸加圧は、上下に開口部を有するダイと、その上下の開口部に嵌め込まれる一対のパンチとを備える金型を用いることが挙げられる。この金型のダイのキャビティ内に原料粉末を充填し、キャビティ内の原料粉末を上パンチと下パンチとで圧縮することで圧粉成形体を作製する。
[Molding process]
In the forming step, the raw material powder is pressure-molded to produce a green compact with a relative density of 97% or more. The relative density is further preferably 98% or more, and particularly preferably 99% or more. Examples of the shape of the green compact include a shape that conforms to the final shape of the sintered member, a shape that is suitable for subsequent cutting, and specifically, a columnar shape, a cylindrical shape, and the like. For the production of the green compact, an appropriate molding device (mold) that can be molded into the above-mentioned shape is used. Specifically, it is preferable to use a mold capable of uniaxial pressing so as to be press-formed along the axial direction of a column or cylinder. Uniaxial pressurization includes using a die having a die having openings on the top and bottom and a pair of punches fitted into the top and bottom openings. The raw material powder is filled into the cavity of the die of this mold, and the raw material powder in the cavity is compressed by the upper punch and the lower punch to produce a compacted body.
 成形圧力(面圧)は、1560MPa以上が挙げられる。成形圧力を大きくすることで、相対密度の高い圧粉成形体を作製できる。成形圧力は、更に1660MPa以上、1760MPa以上が好ましく、特に1860MPa、1960MPa以上が好ましい。成形圧力の上限は特にない。 The molding pressure (surface pressure) is 1560 MPa or more. By increasing the molding pressure, a green compact with a high relative density can be produced. The molding pressure is further preferably 1660 MPa or more and 1760 MPa or more, and particularly preferably 1860 MPa or 1960 MPa or more. There is no particular upper limit on the molding pressure.
 成形工程は、金型の内周面(ダイの内周面やパンチの押圧面)に潤滑剤を塗布する金型(外部)潤滑法で行うことが好ましい。そうすれば、金型への原料粉末の焼き付きを防止し易い。潤滑剤は、例えば、高級脂肪酸、金属石鹸、脂肪酸アミド、高級脂肪酸アミドなどが利用できる。金属石鹸は、例えば、ステアリン酸亜鉛やステアリン酸リチウムなどが挙げられる。脂肪酸アミドは、例えば、ステアリン酸アミド、ラウリン酸アミド、パルミチン酸アミドなどが挙げられる。高級脂肪酸アミドは、例えば、エチレンビスステアリン酸アミドなどが挙げられる。 The molding step is preferably performed by a mold (external) lubrication method in which a lubricant is applied to the inner peripheral surface of the mold (the inner peripheral surface of the die or the pressing surface of the punch). Then, it is easy to prevent the raw material powder from sticking to the mold. As the lubricant, for example, higher fatty acid, metal soap, fatty acid amide, higher fatty acid amide and the like can be used. Examples of the metal soap include zinc stearate and lithium stearate. Examples of fatty acid amides include stearic acid amide, lauric acid amide, and palmitic acid amide. Examples of the higher fatty acid amide include ethylene bis stearic acid amide.
 作製する圧粉成形体の相対密度は、更に98%以上が好ましく、特に99%以上が好ましい。圧粉成形体の相対密度は、「{(圧粉成形体の成形密度)/(圧粉成形体の真密度)}×100」から求める。圧粉成形体の成形密度は、圧粉成形体を油中に浸漬させ、「含油密度×{(含油前の圧粉成形体の質量)/(含油後の圧粉成形体の質量)}」から求める。含油密度は、含油後の圧粉成形体の質量を圧粉成形体の体積で除した値である。 The relative density of the green compact to be produced is preferably 98% or more, particularly preferably 99% or more. The relative density of the green compact is obtained from “{(molding density of the green compact) / (true density of the green compact)} × 100”. The compacting density of the compacted body is determined by immersing the compacted body in oil, “oil content density × {(mass of compacted body before oil impregnation) / (mass of compacted compact after oil impregnation)}” Ask from. The oil impregnation density is a value obtained by dividing the mass of the green compact after oil impregnation by the volume of the green compact.
 また、圧粉成形体の相対密度は、圧粉成形体の断面を市販の画像解析ソフトで画像解析することで求めることができる。まず、圧粉成形体の断面において、10個以上の観察視野の画像を取得する。断面は任意の断面とし、1断面につき1視野として10個以上の断面をとってもよいし、1断面につき複数の視野をとってもよい。各視野のサイズは、500μm×600μmとする。各観察視野の画像を二値化処理して、各観察視野に占める金属の面積割合を求め、その面積割合を各観察視野の相対密度と見做す。そして、全観察視野の相対密度の平均値を求めて圧粉成形体の相対密度とする。 Further, the relative density of the green compact can be obtained by image analysis of the cross section of the green compact with commercially available image analysis software. First, in the cross section of the green compact, images of 10 or more observation fields are acquired. The cross section may be an arbitrary cross section, and 10 or more cross sections may be taken as one visual field per cross section, or a plurality of visual fields may be taken per cross section. The size of each visual field is 500 μm × 600 μm. The image of each observation visual field is binarized to obtain the area ratio of the metal in each observation visual field, and the area ratio is regarded as the relative density of each observation visual field. And the average value of the relative density of all the observation visual fields is calculated | required, and it is set as the relative density of a compacting body.
  [焼結工程]
 焼結工程では、圧粉成形体を焼結する。この焼結により、金属粉末の粒子同士が接触して結合された焼結部材が得られる。この焼結部材の相対密度は、97%を超える。圧粉成形体の相対密度が97%以上であり焼結により圧粉成形体は収縮するため、焼結後の焼結部材の相対密度は、圧粉成形体の相対密度よりも大きくなるからである。圧粉成形体が非常に高密度であるため、焼結による圧粉成形体の収縮量は非常に小さいものの、焼結部材の相対密度は、圧粉成形体の相対密度を超える値となる。
[Sintering process]
In the sintering step, the green compact is sintered. By this sintering, a sintered member in which the particles of the metal powder are brought into contact with each other is obtained. The relative density of this sintered member is over 97%. Since the green compact has a relative density of 97% or more and the green compact shrinks due to sintering, the relative density of the sintered member after sintering is greater than the relative density of the green compact. is there. Since the green compact has a very high density, the amount of shrinkage of the green compact by sintering is very small, but the relative density of the sintered member exceeds the relative density of the green compact.
 焼結条件は、原料粉末の組成に応じて適宜選択できる。焼結温度は、例えば、1100℃以上1400℃以下が挙げられ、更に1200℃以上1300℃以下が挙げられる。焼結時間は、例えば、15分以上150分以下が挙げられ、更に20分以上60分以下が挙げられる。焼結条件は、公知の条件を適用できる。 Sintering conditions can be appropriately selected according to the composition of the raw material powder. As for sintering temperature, 1100 degreeC or more and 1400 degrees C or less are mentioned, for example, Furthermore, 1200 degreeC or more and 1300 degrees C or less are mentioned. As for sintering time, 15 minutes or more and 150 minutes or less are mentioned, for example, Furthermore, 20 minutes or more and 60 minutes or less are mentioned. Known conditions can be applied to the sintering conditions.
  [その他の工程]
 焼結部材の製造方法は、上記の原料準備工程、成型工程及び焼結工程の他にも、成形体を切削加工する工程(成形体加工工程)、焼結部材に浸炭焼入れ・焼戻しを行なう工程(熱処理工程)及び焼結部材を仕上げ加工する工程(仕上げ加工工程)の少なくとも一つの工程を備えることができる。
[Other processes]
In addition to the raw material preparation step, the molding step, and the sintering step, the sintered member manufacturing method includes a step of cutting the molded body (molded body processing step), and a step of carburizing and tempering the sintered member. It is possible to include at least one step of (heat treatment step) and a step of finishing the sintered member (finishing step).
   (成形体加工工程)
 成形体加工工程は、成形工程後、焼結工程前に、圧粉成形体を切削加工する。切削加工は、切削工具を用いて所定の形状に圧粉成形体を加工する。焼結前の圧粉成形体を切削加工するため、高密度で複雑形状な焼結部材を容易に製造できる。圧粉成形体は、切削加工性を低下させるNiを粉末として1質量%以上含んでいても合金の添加元素として1質量%以上含んでいても、同じ組成の焼結部材や溶製材に比較して軟らかくて粘りが小さいため切削加工し易い。その上、圧粉成形体は、焼結部材や溶製材に比較すると軟らかいものの、相対密度が非常に高くて強度がある程度高い。したがって、切削加工による欠けや亀裂の発生を抑制し易い。圧粉成形体は、成形により原料粉末を固めただけであり、金属粉末の粒子同士が機械的に密着している。焼結部材は、金属粉末の粒子同士が焼結により拡散結合して強固に結合している。溶製材は、圧粉成形体と同じサイズとするとき、圧粉成形体を構成する金属粒子よりも遥かに大きく一体に形成された物である。
(Molded body processing process)
In the green body processing step, the green body is cut after the molding step and before the sintering step. In the cutting process, the green compact is processed into a predetermined shape using a cutting tool. Since the green compact before sintering is cut, a sintered member having a high density and a complicated shape can be easily manufactured. The green compact does not contain Ni, which lowers the machinability, as a powder, or contains 1% by mass or more as an additive element of the alloy. Easy to cut because it is soft and soft. In addition, the green compact is softer than the sintered member or melted material, but has a relatively high relative density and a certain degree of strength. Therefore, it is easy to suppress the occurrence of chips and cracks due to cutting. The green compact has only the raw material powder hardened by molding, and the metal powder particles are in mechanical contact with each other. In the sintered member, particles of the metal powder are diffusion-bonded and firmly bonded by sintering. When the melted material is the same size as the green compact, it is a material that is much larger and integrated than the metal particles that make up the green compact.
 特に、混合粉末を用いた圧粉成形体への加工速度は、合金粉末を用いた圧粉成形体への加工速度に比較して速くできる。例えば、合金粉末を用いた圧粉成形体と混合粉末を用いた圧粉成形体とに対して、粉末ハイスで作製されたホブを用いてドライ切削加工を行った際、工具の最高周速(切削速度)は、合金粉末の圧粉成形体への加工の場合、350m/minであり、混合粉末の圧粉成形体への加工の場合、450m/minである。なお、工具の最高周速は、同様に溶製材への加工の場合、150m/minであり、焼結部材への加工の場合、150m/minである。 Especially, the processing speed to the compacted body using the mixed powder can be made faster than the processing speed to the compacted body using the alloy powder. For example, when dry cutting is performed on a powder compact using an alloy powder and a powder compact using a mixed powder using a hob made of powder HSS, the maximum peripheral speed of the tool ( The cutting speed) is 350 m / min in the case of processing the alloy powder into a green compact, and 450 m / min in the case of processing the mixed powder into a green compact. Similarly, the maximum peripheral speed of the tool is 150 m / min in the case of processing into a molten material, and 150 m / min in the case of processing into a sintered member.
 切削加工は、例えば、転削加工、旋削加工などが挙げられる。転削加工には、穴あけ加工が含まれる。切削工具には、穴あけ加工の場合、ドリルやリーマ、転削加工の場合、フライスやエンドミル、旋削加工の場合、バイトや刃先交換型切削チップなどを用いることが挙げられる。その他、ホブ、ブローチ、ピニオンカッタなどを用いてもよいし、複数種の加工を自動で行なえるマシニングセンタを用いてもよい。 Examples of the cutting process include a turning process and a turning process. The milling includes drilling. Examples of the cutting tool include drilling, reamer, turning, milling, end mill, turning, cutting tool, and other types of cutting tips in the case of drilling. In addition, a hob, a broach, a pinion cutter, or the like may be used, or a machining center that can automatically perform a plurality of types of processing may be used.
 切削加工に供する前に、圧粉成形体の表面に有機バインダーを溶かした揮発性溶液や可塑性溶液を表面に塗布または浸漬させてもよい。そうすれば、切削加工時の圧粉成形体の表層の割れや欠けを抑制し易い。有機バインダーは、例えば、ポリエチレン、ポリプロピレン、ポリメチルメタクリレート、ポリスチレン、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリアミド、ポリエステル、ポリエーテル、ポリビニルアルコール、酢酸ビニル、パラフィン、各種ワックスなどが挙げられる。 Before being subjected to cutting, a volatile solution or a plastic solution in which an organic binder is dissolved may be applied or immersed on the surface of the green compact. If it does so, it is easy to suppress the crack and notch | chip of the surface layer of the compacting body at the time of cutting. Examples of the organic binder include polyethylene, polypropylene, polymethyl methacrylate, polystyrene, polyvinyl chloride, polyvinylidene chloride, polyamide, polyester, polyether, polyvinyl alcohol, vinyl acetate, paraffin, and various waxes.
 切削加工は、圧粉成形体に作用する引張応力を打ち消す方向に、圧粉成形体に圧縮応力を付与しながら行ってもよい。そうすれば、圧粉成形体の割れや欠けを抑制し易い。例えば、ブローチで圧粉成形体に加工孔を形成する場合、ブローチが圧粉成形体を突き通すときに加工孔の出口近傍に強い引張応力が作用する。この場合、複数の圧粉成形体を多段に重ねることが挙げられる。最下段の圧粉成形体の下にはダミーの圧粉成形体や板材などを配置すると良い。複数の圧粉成形体を多段に重ねれば、上段側にある圧粉成形体の下面が、下段側の圧粉成形体の上面に押さえ付けられ、当該下面に圧縮応力が作用する。この多段に重ねられた圧粉成形体の上方からブローチ加工を行なえば、圧粉成形体の下面に形成される加工孔の出口付近の割れや欠けを効果的に防止できる。また、フライスで圧粉成形体に加工溝を形成する場合、加工溝の出口近傍に強い引張応力が作用する。その場合、フライスの進行方向に複数の圧粉成形体を並べて、加工溝の出口となる部分に圧縮応力を作用させることが挙げられる。 Cutting may be performed while applying a compressive stress to the green compact in a direction that cancels the tensile stress acting on the green compact. If it does so, it will be easy to suppress a crack and a chip of a compacting object. For example, when forming a processed hole in a green compact with a broach, strong tensile stress acts near the exit of the processed hole when the broach penetrates the green compact. In this case, a plurality of green compacts may be stacked in multiple stages. It is preferable to dispose a dummy green compact or a plate material under the lowest green compact. If a plurality of green compacts are stacked in multiple stages, the lower surface of the green compact on the upper side is pressed against the upper surface of the lower green compact, and compressive stress acts on the lower surface. If broaching is performed from above the multi-stage stacked compacts, cracks and chips near the exit of the processed holes formed on the lower surface of the compact can be effectively prevented. Moreover, when forming a processing groove in a compacting body with a milling cutter, a strong tensile stress acts near the exit of the processing groove. In this case, it is possible to arrange a plurality of green compacts in the direction of milling and to apply a compressive stress to the portion serving as the exit of the processing groove.
   (熱処理工程)
 熱処理工程では、焼結部材に浸炭焼入れ・焼戻しを行なう。そうして、焼結部材の機械的特性、特に硬度及び靭性を向上させる。
(Heat treatment process)
In the heat treatment step, the sintered member is carburized and tempered. Thus, the mechanical properties of the sintered member, particularly the hardness and toughness, are improved.
   (仕上げ加工工程)
 仕上げ加工工程は、焼結部材の表面粗さを小さくすると共に、焼結部材の寸法を設計寸法に合わせる。例えば、焼結部材の表面への研磨加工などが挙げられる。
(Finishing process)
In the finishing process, the surface roughness of the sintered member is reduced, and the size of the sintered member is adjusted to the design dimension. For example, the grinding | polishing process etc. to the surface of a sintered member are mentioned.
  [用途]
 実施形態に係る焼結部材の製造方法は、高密度で高強度な焼結部材を製造できる。また、高密度で複雑な形状の焼結部材を容易に製造できる。よって、実施形態に係る焼結部材の製造方法は、各種の一般構造用部品(スプロケット、ローター、ギア、リング、フランジ、プーリー、軸受けなどの機械部品などの焼結部品)の製造に好適に利用できる。
[Usage]
The sintered member manufacturing method according to the embodiment can manufacture a sintered member having high density and high strength. Further, a sintered member having a high density and a complicated shape can be easily manufactured. Therefore, the method for manufacturing a sintered member according to the embodiment is suitably used for manufacturing various general structural parts (sintered parts such as mechanical parts such as sprockets, rotors, gears, rings, flanges, pulleys, and bearings). it can.
 〔焼結部材〕
 焼結部材は、複数の金属粒子同士が結合されてなり、相対密度が97%を超える。この焼結部材は、上述の焼結部材の製造方法(原料準備工程、成型工程及び焼結工程)により製造することができる。成形体の相対密度が97%以上であるため、その後の焼結工程を経た焼結部材の相対密度も97%を超える。この相対密度の測定方法は、圧粉成形体の相対密度の測定方法と同じである。この焼結部材は、その表面から1mmの範囲で実質的な密度の変化がない。つまり、密度が実質的に均一である。焼結部材に対して転造加工を施していないからである。また、焼結部材の金属組織は、金属粒子が引き伸ばされた流線状の組織が形成されていない。焼結部材に対して鍛造加工を施していないからである。
(Sintered member)
The sintered member is formed by bonding a plurality of metal particles, and the relative density exceeds 97%. This sintered member can be manufactured by the above-described method for manufacturing a sintered member (raw material preparation step, molding step and sintering step). Since the relative density of the molded body is 97% or more, the relative density of the sintered member that has undergone the subsequent sintering step also exceeds 97%. The method for measuring the relative density is the same as the method for measuring the relative density of the green compact. This sintered member has no substantial change in density within a range of 1 mm from the surface thereof. That is, the density is substantially uniform. This is because no rolling process is applied to the sintered member. Further, the stream structure in which the metal particles are stretched is not formed in the metal structure of the sintered member. This is because the sintered member is not forged.
 《試験例1》
 焼結部材を作製し、焼結部材の相対密度と強度とを評価した。
<< Test Example 1 >>
Sintered members were prepared and the relative density and strength of the sintered members were evaluated.
 〔試料No.1-1~No.1-3、No.1-101~No.1-103〕
 試料No.1-1~No.1-3、No.1-101~No.1-103の焼結部材は、上述の焼結部材の製造方法と同様にして、原料準備工程と成形工程及び焼結工程とを経て作製した。
[Sample No. 1-1-No. 1-3, no. 1-101-No. 1-103]
Sample No. 1-1-No. 1-3, no. 1-101-No. The sintered member 1-103 was produced through the raw material preparation step, the forming step, and the sintering step in the same manner as the above-described sintered member manufacturing method.
  [原料準備工程]
 原料粉末には、水アトマイズ法により作製した鉄合金粉末と炭素粉末とを用意した。鉄合金粉末の組成は、2質量%Ni-0.5質量%Mo-残部Fe及び不可避的不純物であり、その平均粒径(D50)は、70μmである。炭素粉末の平均粒径(D50)は、5μmである。原料粉末を100質量%とするとき、炭素粉末の含有量を0.3質量%とし、残部を鉄合金粉末とした。原料粉末は、潤滑剤と有機バインダーとを含有していない。
[Raw material preparation process]
As the raw material powder, an iron alloy powder and a carbon powder prepared by a water atomization method were prepared. The composition of the iron alloy powder is 2 mass% Ni-0.5 mass% Mo-balance Fe and inevitable impurities, and the average particle diameter (D50) is 70 μm. The average particle diameter (D50) of the carbon powder is 5 μm. When the raw material powder was 100% by mass, the carbon powder content was 0.3% by mass, and the balance was iron alloy powder. The raw material powder does not contain a lubricant and an organic binder.
  [成形工程]
 原料粉末を加圧成形して円柱状(外径:75mm、高さ:20mm)の圧粉成形体を作製した。この圧粉成形体の作製には、一軸加圧が可能な金型を用いた。この金型は、上下に開口部を有し、円柱状の圧粉成形体の外周面を形成する円形状の挿通孔が形成されたダイと、円柱状の圧粉成形体の両端面を形成する円形状のプレス面を有する上下のパンチとを備える。ダイの内周面には、潤滑剤としてミリスチン酸のアルコール溶液を塗布した。
成形圧力は、表1に示す通りである。表1の成形圧力は、「8ton/cm~20ton/cm」を「MPa」に換算して丸めた数値である。
[Molding process]
The raw material powder was pressure-molded to produce a cylindrical compact (outer diameter: 75 mm, height: 20 mm). A mold capable of uniaxial pressing was used for the production of the green compact. This mold has openings on the top and bottom and forms a die having circular insertion holes that form the outer peripheral surface of the cylindrical powder compact, and both end faces of the cylindrical compact. And upper and lower punches having a circular press surface. On the inner peripheral surface of the die, an alcohol solution of myristic acid was applied as a lubricant.
The molding pressure is as shown in Table 1. The molding pressure in Table 1 is a numerical value obtained by converting “8 ton / cm 2 to 20 ton / cm 2 ” into “MPa” and rounding.
 作製した圧粉成形体の相対密度を測定した。圧粉成形体の相対密度は、「{(圧粉成形体の成形密度)/(圧粉成形体の真密度)}×100」から求めた。圧粉成形体の成形密度は、圧粉成形体を油中に浸漬させ、「含油密度×{(含油前の圧粉成形体の質量)/(含油後の圧粉成形体の質量)}」から求めた。含油密度は、含油後の圧粉成形体の質量を圧粉成形体の体積で除した値である。圧粉成形体(原料粉末)の真密度は約7.8g/cmである。各試料の圧粉成形体の成形密度及び相対密度を表1に示す。また、各試料の圧粉成形体の成形圧力(MPa)と成形密度(g/cm)との関係を図1に示す。図1に示すグラフの横軸は成形圧力(MPa)とし、縦軸は成形密度(g/cm)としている。図1には、試料No.1-1~No.1-3の結果を黒丸でプロットし、試料No.1-101~No.1-103の結果を黒菱形でプロットしている。 The relative density of the produced green compact was measured. The relative density of the green compact was determined from “{(molding density of the green compact) / (true density of the green compact)} × 100”. The compacting density of the compacted body is determined by immersing the compacted body in oil, “oil content density × {(mass of compacted body before oil impregnation) / (mass of compacted compact after oil impregnation)}” I asked for it. The oil impregnation density is a value obtained by dividing the mass of the green compact after oil impregnation by the volume of the green compact. The true density of the green compact (raw material powder) is about 7.8 g / cm 3 . Table 1 shows the molding density and the relative density of the green compact of each sample. Moreover, the relationship between the shaping | molding pressure (MPa) of the compacting body of each sample and a shaping | molding density (g / cm < 3 >) is shown in FIG. The horizontal axis of the graph shown in FIG. 1 is the molding pressure (MPa), and the vertical axis is the molding density (g / cm 3 ). In FIG. 1-1-No. The results of 1-3 are plotted with black circles. 1-101-No. The results of 1-103 are plotted with black diamonds.
  [焼結工程]
 圧粉成形体を焼結して焼結部材を作製した。焼結条件は、焼結温度を1150℃、焼結時間を60分、焼結雰囲気を窒素雰囲気とした。
[Sintering process]
The green compact was sintered to produce a sintered member. The sintering conditions were a sintering temperature of 1150 ° C., a sintering time of 60 minutes, and a sintering atmosphere of a nitrogen atmosphere.
 〔試料No.1-111~No.1-117〕
 試料No.1-111~No.1-117の焼結部材は、金型には潤滑剤を塗布しない点と、原料粉末が更に潤滑剤を含む点とを除き、試料No.1-1と同様にして作製した。潤滑剤にはエチレンビスステアリン酸アミドを用い、原料粉末における潤滑剤の含有量は0.6質量%とした。試料No.1-111~No.1-117の圧粉成形体の相対密度を、試料No.1-1と同様にして測定した。各試料の圧粉成形体の成形密度及び相対密度を表1に示す。また、各試料の圧粉成形体の成形圧力(MPa)と成形密度(g/cm)との関係を図1に示す。試料No.1-111~No.1-117の結果を白四角でプロットしている。
[Sample No. 1-111-No. 1-117]
Sample No. 1-111-No. The sintered member No. 1-117 has a sample No. 1 except that the lubricant is not applied to the mold and the raw material powder further contains a lubricant. It was produced in the same manner as 1-1. Ethylene bis stearamide was used as the lubricant, and the content of the lubricant in the raw material powder was 0.6% by mass. Sample No. 1-111-No. The relative density of the green compact of 1-117 was measured as Sample No. Measurement was performed in the same manner as in 1-1. Table 1 shows the molding density and the relative density of the green compact of each sample. Moreover, the relationship between the shaping | molding pressure (MPa) of the compacting body of each sample and a shaping | molding density (g / cm < 3 >) is shown in FIG. Sample No. 1-111-No. The results of 1-117 are plotted with white squares.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1及び図1に示すように、試料No.1-1~No.1-3の圧粉成形体の相対密度はいずれも、97%(成形密度≒7.57g/cm)以上であることが分かる。この結果から、試料No.1-1~No.1-3の焼結部材の相対密度はいずれも、97%(成形密度≒7.57g/cm)を超える値となると考えられる。 As shown in Table 1 and FIG. 1-1-No. It can be seen that the relative density of each of the 1-3 compacts is 97% (molding density≈7.57 g / cm 3 ) or more. From this result, sample no. 1-1-No. It is considered that the relative density of each of the 1-3 sintered members exceeds 97% (molding density≈7.57 g / cm 3 ).
 これに対して、試料No.1-101~No.1-103、No.1-111~No.1-117の圧粉成形体の相対密度はいずれも、97%未満であることが分かる。この結果から、試料No.1-101~No.1-103、No.1-111~No.1-117の焼結部材の相対密度はいずれも、97%未満となると考えられる。 In contrast, sample no. 1-101-No. 1-103, no. 1-111-No. It can be seen that the relative density of the green compacts of 1-117 is less than 97%. From this result, sample no. 1-101-No. 1-103, no. 1-111-No. It is considered that the relative density of each of the sintered members 1-117 is less than 97%.
 〔強度の評価〕
 焼結部材の強度は、引張試験を行なって引張強さを測定することで評価した。試料No.1-1と同様にして、試料No.2-1,2-2,2-101~2-103の円柱状の焼結部材を作製した。ここでは、各試料の成形密度(相対密度)が表2の値となるように成形圧力を調整した。この円柱状の焼結部材を所定の形状に加工して浸炭焼き入れを行って、引張強さの測定用の試験片を作製した。試験片は、細幅部と、細幅部の両端に形成される太幅部で構成される平板状である。試験片の厚みは4mmで、長さは72mmである。細幅部は、中央部と、中央部から太幅部に掛けて形成される円弧状の側面を有する肩部とで構成される。中央部の長さは32mm、中央の幅は5.7mm、両端の幅は5.96mmである。肩部の側面の半径Rは25mmである。太幅部の幅は、8.7mmである。
この試験片に対して、汎用の引張試験機を用いて引張試験を行った。
[Evaluation of strength]
The strength of the sintered member was evaluated by performing a tensile test and measuring the tensile strength. Sample No. In the same manner as in 1-1, the sample No. Cylindrical sintered members of 2-1, 2-2, 2-101 to 2-103 were produced. Here, the molding pressure was adjusted so that the molding density (relative density) of each sample was the value shown in Table 2. This cylindrical sintered member was processed into a predetermined shape and subjected to carburizing and quenching to prepare a test piece for measuring tensile strength. A test piece is flat form comprised by the narrow part and the wide part formed in the both ends of a narrow part. The thickness of the test piece is 4 mm and the length is 72 mm. The narrow width portion is composed of a central portion and a shoulder portion having an arcuate side surface formed from the central portion to the wide width portion. The central portion has a length of 32 mm, the central width is 5.7 mm, and both ends have a width of 5.96 mm. The radius R of the side surface of the shoulder is 25 mm. The width of the thick part is 8.7 mm.
A tensile test was performed on the test piece using a general-purpose tensile tester.
 引張強さ(MPa)の結果を表2に示す。表2に示す引張強さ(MPa)は評価数n=5の平均値である。また、成形密度(g/cm)と引張強さ(MPa)との関係を図2に示す。図2に示すグラフの横軸は成形密度とし、縦軸は引張強さとしている。図2には、試料No.2-1,No.2-2の引張強さの平均値を黒丸でプロットし、試料No.2-101~No.2-103の引張強さの平均値を黒菱形でプロットし、これらの試料における引張強さの最大値と最小値とをエラーバーで示している。 The results of tensile strength (MPa) are shown in Table 2. The tensile strength (MPa) shown in Table 2 is an average value of the evaluation number n = 5. FIG. 2 shows the relationship between the molding density (g / cm 3 ) and the tensile strength (MPa). The horizontal axis of the graph shown in FIG. 2 is the molding density, and the vertical axis is the tensile strength. In FIG. 2-1, No. 2 The average value of the tensile strength of 2-2 was plotted with black circles, and sample No. 2-101-No. The average value of the tensile strength of 2-103 is plotted with black diamonds, and the maximum value and the minimum value of the tensile strength in these samples are indicated by error bars.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 表2及び図2に示すように、試料No.2-1、No.2-2の試験片(焼結部材)の引張強さは、1700MPa以上、更には1750MPa以上、特に1800MPa以上であることが分かる。これに対して、試料No.2-101~No.2-103の試験片(焼結部材)の引張強さは、1700MPa未満であることが分かる。従って、相対密度が97%以上の圧粉成形体を焼結することで、高密度で高強度な焼結部材が得られることが分かる。 As shown in Table 2 and FIG. 2-1. It can be seen that the tensile strength of the test piece (sintered member) 2-2 is 1700 MPa or more, further 1750 MPa or more, particularly 1800 MPa or more. In contrast, sample no. 2-101-No. It can be seen that the tensile strength of the 2-103 test piece (sintered member) is less than 1700 MPa. Therefore, it can be understood that a sintered member having a high density and high strength can be obtained by sintering a green compact having a relative density of 97% or more.
 なお、自動車用のトランスミッションギアなど非常に負荷のかかる構造部品に使用される一般的なクロムモリブデン鋼(SCM415)を、試料No.1-1などと同様に引張強さを測定したところ、その引張強さは1372MPaであった。即ち、試料No.2-1、No.2-2の焼結部材の引張強さは非常に高いことが分かる。 Note that a common chromium-molybdenum steel (SCM415) used for structural parts that are extremely loaded such as transmission gears for automobiles is used as a sample No. When the tensile strength was measured in the same manner as in 1-1, the tensile strength was 1372 MPa. That is, sample no. 2-1. It can be seen that the tensile strength of the sintered member 2-2 is very high.
 今回開示された実施の形態はすべての点で例示であって、どのような面からも制限的なものではないと理解されるべきである。本発明の範囲は上記した説明ではなく、請求の範囲によって規定され、請求の範囲と均等の意味および範囲内でのすべての変更が含まれることが意図される。 It should be understood that the embodiment disclosed herein is illustrative in all respects and is not restrictive in any way. The scope of the present invention is defined by the scope of the claims, rather than the description above, and is intended to include any modifications within the scope and meaning equivalent to the scope of the claims.

Claims (2)

  1.  鉄系粉末を含む原料粉末を準備する工程と、
     前記原料粉末を加圧成形して相対密度が97%以上の円柱状又は円筒状の圧粉成形体を成形する工程と、
     前記圧粉成形体を焼結する工程とを備え、
     前記原料粉末は、純鉄粉とNi粉末とを含む混合粉末、及び添加元素としてNiを含む鉄合金粉末の少なくとも一方を含み、
     前記原料粉末中の前記Ni粉末、及び前記添加元素としてのNiの合計含有量が1質量%以上である焼結部材の製造方法。
    Preparing a raw material powder containing iron-based powder;
    A step of pressure-molding the raw material powder to form a cylindrical or cylindrical powder compact having a relative density of 97% or more;
    A step of sintering the green compact.
    The raw material powder includes at least one of a mixed powder containing pure iron powder and Ni powder, and an iron alloy powder containing Ni as an additive element,
    The manufacturing method of the sintered member whose total content of the said Ni powder in the said raw material powder and Ni as said additional element is 1 mass% or more.
  2.  前記成形する工程後、前記焼結する工程前に、前記圧粉成形体を切削加工する工程を備える請求項1に記載の焼結部材の製造方法。 The method for producing a sintered member according to claim 1, further comprising a step of cutting the green compact after the step of forming and before the step of sintering.
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