WO2018205496A1 - Formulation de colorant qui ne se décolore pas facilement - Google Patents

Formulation de colorant qui ne se décolore pas facilement Download PDF

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Publication number
WO2018205496A1
WO2018205496A1 PCT/CN2017/105338 CN2017105338W WO2018205496A1 WO 2018205496 A1 WO2018205496 A1 WO 2018205496A1 CN 2017105338 W CN2017105338 W CN 2017105338W WO 2018205496 A1 WO2018205496 A1 WO 2018205496A1
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WO
WIPO (PCT)
Prior art keywords
parts
agent
dye formulation
dye
fluorescent agent
Prior art date
Application number
PCT/CN2017/105338
Other languages
English (en)
Chinese (zh)
Inventor
刘春燕
Original Assignee
南通薇星纺织科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by 南通薇星纺织科技有限公司 filed Critical 南通薇星纺织科技有限公司
Publication of WO2018205496A1 publication Critical patent/WO2018205496A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5228—Polyalkenyl alcohols, e.g. PVA
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/627—Sulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/647—Nitrogen-containing carboxylic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D06P1/67366—Phosphates or polyphosphates

Definitions

  • the invention relates to the field of home textile printing and dyeing technology, in particular to a dye formulation which is not easy to fade.
  • Textile dyes are dyes used in textile dyeing and are often classified into natural dyes and synthetic dyes.
  • the existing textile dyes are usually prepared by artificial proportioning according to different needs, and the existing dye-dyed fabrics have poor colorability and insufficient color fastness, and fade and fade after repeated cleaning. The phenomenon.
  • the dye formulation consisting of parts by weight of natural plant dye 20-40 parts; 2-5 parts of fatty alcohol sodium sulfate; 5-10 parts of polyvinyl alcohol; sodium propionate 3-6 parts; methyl acrylate 5-8 parts; acrylic resin 1-3 parts; glacial acetic acid 3-6 parts; fluorescer 2-5 parts; inorganic antibacterial agent 5-10 parts; anionic antistatic agent 0.5-2 parts Deionized water 50-70 parts.
  • the natural plant dye is one of valerian, comfrey, sorghum, indigo, and scutellaria.
  • the fluorescent agent is one of a fluorescent agent BC, a fluorescent agent EBF, a fluorescent agent R, a fluorescent agent AD, and a fluorescent agent ER.
  • the inorganic antibacterial agent is one of zinc oxide, copper oxide, ammonium dihydrogen phosphate, and lithium carbonate.
  • the anionic antistatic agent is an alkali metal salt of an alkylsulfonic acid, a phosphoric acid or a dithiocarbamic acid.
  • the dye formulation consists of parts by weight of the following components: natural vegetable dye 30 parts; fatty alcohol sodium sulfate 3 parts; polyvinyl alcohol 7 parts; sodium propionate 4 parts; methyl acrylate 6 parts; 2 parts of resin; 4 parts of glacial acetic acid; 3 parts of fluorescent agent; 6 parts of inorganic antibacterial agent; 1 part of anionic antistatic agent; 60 parts of deionized water.
  • the dye formulation of the present invention contains a fluorescent agent, so that the cloth emits fluorescence in a dark environment, and the visual effect is good.
  • the anionic antistatic agent is added to the dye formulation of the invention, thereby rapidly conducting static electricity, and the antistatic property of the dye of the invention can be improved, so that the printed fabric can quickly conduct static electricity and has excellent antistatic property.
  • the inorganic antibacterial agent is added to the dye formulation of the invention to prevent the growth and reproduction of bacteria, and effectively improve the antibacterial property of the printed fabric.
  • a dye formulation that is not easily faded consisting of parts by weight of natural plant dye 20 parts; 2 parts of fatty alcohol sodium sulfate; 5 parts of polyvinyl alcohol; 3 parts of sodium propionate; 1 part; acrylic resin 1 part; glacial acetic acid 3 parts; 2 parts of fluorescent agent; 5 parts of inorganic antibacterial agent; 0.5 part of anionic antistatic agent; 50 parts of deionized water.
  • the natural plant dye is valerian.
  • the fluorescent agent is a fluorescent agent BC.
  • the inorganic antibacterial agent is zinc oxide.
  • the anionic antistatic agent is an alkali metal salt of an alkylsulfonic acid.
  • a dye formulation which is not easily faded, and the dye formulation is composed of parts by weight of natural plant dye 30 parts; 3 parts of fatty alcohol sodium sulfate; 7 parts of polyvinyl alcohol; 4 parts of sodium propionate; 6 parts of ester; 2 parts of acrylic resin; 4 parts of glacial acetic acid; 3 parts of fluorescent agent; 6 parts of inorganic antibacterial agent; 1 part of anionic antistatic agent; 60 parts of deionized water.
  • the natural vegetable dye is comfrey.
  • the fluorescent agent is a fluorescent agent EBF.
  • the inorganic antibacterial agent is copper oxide.
  • the anionic antistatic agent is an alkali metal salt of phosphoric acid.
  • a non-fading dye formulation consisting of parts by weight of natural plant dyes 35 parts; 4 parts of fatty alcohol sodium sulfate; 8 parts of polyvinyl alcohol; 5 parts of sodium propionate; 2 parts; 2 parts of acrylic resin; 5 parts of glacial acetic acid; 4 parts of fluorescent agent; 8 parts of inorganic antibacterial agent; 1.5 parts of anionic antistatic agent; 65 parts of deionized water.
  • the natural vegetable dye is Susie.
  • the fluorescent agent is a fluorescent agent R.
  • the inorganic antibacterial agent is ammonium dihydrogen phosphate.
  • the anionic antistatic agent is an alkali metal salt of a dithiocarbamic acid.
  • a dye formulation that is not easily faded consisting of parts by weight of natural plant dye 20 parts; 2 parts of fatty alcohol sodium sulfate; 5 parts of polyvinyl alcohol; 3 parts of sodium propionate; 1 part; acrylic resin 1 part; glacial acetic acid 3 parts; 2 parts of fluorescent agent; 5 parts of inorganic antibacterial agent; 0.5 part of anionic antistatic agent; 50 parts of deionized water.
  • the natural plant dye is indigo.
  • the fluorescent agent is a fluorescent agent AD.
  • the inorganic antibacterial agent is lithium carbonate.
  • the anionic antistatic agent is an alkali metal salt of a dithiocarbamic acid.
  • a dye formulation which is not easily faded, and the dye formulation is composed of parts by weight of natural plant dye 30 parts; 3 parts of fatty alcohol sodium sulfate; 7 parts of polyvinyl alcohol; 4 parts of sodium propionate; 6 parts of ester; 2 parts of acrylic resin; 4 parts of glacial acetic acid; 3 parts of fluorescent agent; 6 parts of inorganic antibacterial agent; 1 part of anionic antistatic agent; 60 parts of deionized water.
  • the natural plant dye is scutellaria.
  • the fluorescent agent is a fluorescent agent ER.
  • the inorganic antibacterial agent is zinc oxide.
  • the anionic antistatic agent is an alkali metal salt of phosphoric acid.
  • the pigments of the respective formulations of Examples 1-5 make the fabric dyed by the dye less fading, so that the fabric dyed with the dye formulation has excellent coloring property and color fastness.
  • the dye formulation contains a fluorescent agent that causes the fabric to fluoresce in a dark environment with good visual effects.
  • An anionic antistatic agent is added to the dye formulation, thereby rapidly conducting static electricity, and the antistatic property of the dye of the present invention can be improved, thereby enabling the printed fabric to rapidly conduct static electricity and having excellent antistatic properties.
  • An inorganic antibacterial agent is added to the dye formulation to prevent the growth and reproduction of bacteria, and effectively improve the antibacterial properties of the printed fabric.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Coloring (AREA)

Abstract

La présente invention concerne une formulation de colorant qui ne se décolore pas facilement et est constituée des composants suivants en parties en poids : de 20 à 40 parties d'un colorant végétal naturel ; de 2 à 5 parties de sulfate d'alcool aliphatique de sodium ; de 5 à 10 parties d'alcool polyvinylique ; de 3 à 6 parties de propionate de sodium ; de 5 à 8 parties d'acrylate de méthyle ; de 1 à 3 parties d'une résine acrylique ; de 3 à 6 parties d'acide acétique glacial ; de 2 à 5 parties d'un agent fluorescent ; de 5 à 10 parties d'un agent antibactérien inorganique ; de 0,5 à 2 parties d'un agent antistatique à ions négatifs ; et de 50 à 70 parties d'eau déionisée. La formulation de colorant est remplie d'une résine acrylique de telle sorte que le tissu coloré ne se décolore pas facilement, et la formulation de colorant contient un agent fluorescent de telle sorte que le tissu soit fluorescent dans un environnement sombre et présente un bon effet visuel.
PCT/CN2017/105338 2017-05-09 2017-10-09 Formulation de colorant qui ne se décolore pas facilement WO2018205496A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710320244.1A CN106978736A (zh) 2017-05-09 2017-05-09 一种不易褪色的染料配方
CN201710320244.1 2017-05-09

Publications (1)

Publication Number Publication Date
WO2018205496A1 true WO2018205496A1 (fr) 2018-11-15

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Application Number Title Priority Date Filing Date
PCT/CN2017/105338 WO2018205496A1 (fr) 2017-05-09 2017-10-09 Formulation de colorant qui ne se décolore pas facilement

Country Status (2)

Country Link
CN (1) CN106978736A (fr)
WO (1) WO2018205496A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106978736A (zh) * 2017-05-09 2017-07-25 南通薇星纺织科技有限公司 一种不易褪色的染料配方
CN109137563A (zh) * 2018-07-20 2019-01-04 启东市新利来制衣有限公司 一种不易掉色的活性染料配方
CN109706725A (zh) * 2018-12-17 2019-05-03 桐乡盛利得纺织有限公司 一种耐腐蚀布料用染料配方
CN112281517A (zh) * 2020-11-06 2021-01-29 福建省联丰盛漂染植绒有限公司 一种快速排汗的超细纤维面料的染整工艺
CN113417152A (zh) * 2021-06-30 2021-09-21 嘉兴市腾旺染整有限公司 一种染整配方及搅拌设备

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WO2003008510A1 (fr) * 2001-07-19 2003-01-30 Clariant Gmbh Dispersions pigmentaires basees sur l'eau et sur l'acrylate
WO2007077045A1 (fr) * 2006-01-03 2007-07-12 Evonik Degussa Gmbh Preparations pigmentaires universelles
CN101161924A (zh) * 2006-10-13 2008-04-16 江门市科恒实业有限责任公司 靛蓝还原染色增深剂
CN101215745A (zh) * 2008-01-04 2008-07-09 临邑澳泰纺织有限公司 羊毛牛仔面料的加工方法
CN103046399A (zh) * 2012-12-17 2013-04-17 常州大学 一种天然染料转移印花色浆及其制备方法和印花方法
CN106436363A (zh) * 2016-09-21 2017-02-22 东莞市联洲知识产权运营管理有限公司 一种基于纳米微球和黑色素的天然染料及其制备方法
CN106978736A (zh) * 2017-05-09 2017-07-25 南通薇星纺织科技有限公司 一种不易褪色的染料配方

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110009021A1 (en) * 2009-04-16 2011-01-13 Schoots Harrie P Colorfastness and finishing compounds
CN104404790A (zh) * 2014-12-15 2015-03-11 蒋瑾 一种不易掉色的染料配方
CN106283719A (zh) * 2016-07-18 2017-01-04 南通富之岛寝具发展有限公司 一种荧光抗菌染料

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003008510A1 (fr) * 2001-07-19 2003-01-30 Clariant Gmbh Dispersions pigmentaires basees sur l'eau et sur l'acrylate
WO2007077045A1 (fr) * 2006-01-03 2007-07-12 Evonik Degussa Gmbh Preparations pigmentaires universelles
CN101161924A (zh) * 2006-10-13 2008-04-16 江门市科恒实业有限责任公司 靛蓝还原染色增深剂
CN101215745A (zh) * 2008-01-04 2008-07-09 临邑澳泰纺织有限公司 羊毛牛仔面料的加工方法
CN103046399A (zh) * 2012-12-17 2013-04-17 常州大学 一种天然染料转移印花色浆及其制备方法和印花方法
CN106436363A (zh) * 2016-09-21 2017-02-22 东莞市联洲知识产权运营管理有限公司 一种基于纳米微球和黑色素的天然染料及其制备方法
CN106978736A (zh) * 2017-05-09 2017-07-25 南通薇星纺织科技有限公司 一种不易褪色的染料配方

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