WO2018201558A1 - 一种无纺纸喷绘耗材 - Google Patents

一种无纺纸喷绘耗材 Download PDF

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Publication number
WO2018201558A1
WO2018201558A1 PCT/CN2017/088176 CN2017088176W WO2018201558A1 WO 2018201558 A1 WO2018201558 A1 WO 2018201558A1 CN 2017088176 W CN2017088176 W CN 2017088176W WO 2018201558 A1 WO2018201558 A1 WO 2018201558A1
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coating
layer
paper printing
base
printing consumable
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PCT/CN2017/088176
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English (en)
French (fr)
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周传富
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惠州艺都影像科技有限公司
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D21H27/38—Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets

Definitions

  • the utility model belongs to the field of inkjet printing technology, in particular to a nonwoven paper printing consumable material.
  • the non-woven paper wallpaper on the market is relatively high-end, breathable and sound-absorbing, less textured, less personalized, and scratch-resistant and scratch-resistant. To this end, it is necessary to develop a non-woven paper wallpaper that can adapt to personalized inkjet printing and is scratch-resistant and scratch-resistant. It is breathable, sound-absorbing and environmentally friendly, and has a high-end atmosphere, which can meet the needs of schools, hospitals, homes, industrial areas and other occasions.
  • the utility model aims to provide a non-woven paper printing consumable material, which has the characteristics of good inkjet printing effect, scratch resistance, scratch resistance and wide adaptability.
  • a nonwoven paper printing consumable comprising a substrate layer, a base coating layer, an embossed layer, a protective coating layer, an upper surface of the substrate layer being adhered to a lower surface of the base coating layer, the base coating layer The surface is bonded to the lower surface of the embossed layer, and the upper surface of the embossed layer is bonded to the lower surface of the protective coating.
  • the substrate layer has a thickness of 255 to 285 micrometers.
  • the substrate layer is a staple fiber nonwoven paper having a basis weight of 150 gsm.
  • Non-woven paper has good breathability and sound absorbing properties, and the special structure of the nonwoven paper forms the softness of the substrate.
  • the base coat layer has a thickness of 15 to 25 ⁇ m.
  • the base coating is an ink absorbing coating.
  • Different ink-absorbing coatings can be prepared for different inks, weak solvent coatings for weak solvent inks, UV coatings for UV printing, Latex coatings for Latex inks, and matte for pigment inks. Anti-coating.
  • the weak solvent coating materials are pure acrylic emulsion and silica; the UV coating materials are pure acrylic emulsion and polyurethane emulsion; the Latex coating materials are pure acrylic emulsion and calcium carbonate; the dummy coating is silica Mainly, add some emulsion and polyvinyl alcohol for bonding and film formation.
  • the base coating acts as an ink absorbing ink, and the screen prints with vivid colors and good color reproduction.
  • the embossed layer has a thickness of 3 to 5 ⁇ m.
  • the embossed layer is a layer having an appearance of a texture formed by applying a pressure of 6.5 MPa to the base coating after the base layer is coated with the base layer, and is a part of the base coating by pressure. Formed a grain.
  • the texture of the embossed layer is coarse sand, lychee or cloth.
  • the embossed layer is designed to give the wallpaper a better visual and touch effect, as well as personalization.
  • the protective coating has a thickness of 8 to 12 microns.
  • the protective coating material is a polyurethane emulsion, a curing agent and a friction-resistant hollow microsphere, and the curing agent is ⁇ -(2-aminomethylethyl)- ⁇ -(2-aminomethylethoxy)poly[oxyl ( a polymer of methyl-1,2-ethylene)] and 1-methoxy-2-propanol).
  • the protective coating is a scratch-resistant coating that protects the lines, scratches and scratches, and helps absorb ink during printing, allowing the product to be used for a long time.
  • the inkjet effect is good. Different inks are matched to different coatings. When printing, the base coating and the protective coating absorb ink at the same time, which can present beautiful and colorful effects.
  • scratch and scratch resistance because the protective coating formula adds scratch and scratch resistance components, can effectively prevent the scene from being scratched or scratched in public, thus ensuring the integrity of the picture, no short time Replace it inside.
  • non-woven paper printing consumables of the utility model have the characteristics of good inkjet printing effect, scratch resistance, scratch resistance, softness and easy winding.
  • Non-woven paper printing consumables can be applied to Latex ink, UV ink, weak solvent ink, pigment ink printing according to the basic coating. After printing, it can be pasted into home, hospital, school, industrial area, etc. for decoration or advertising. Can be made into frameless painting as a decorative painting, because the coating is waterproof and scratch resistant, it can save the enamel process.
  • FIG. 1 is a schematic cross-sectional structural view of a nonwoven paper printing consumable of the present invention.
  • the nonwoven paper printing consumable of the present invention comprises a base material layer 1 , a base coating layer 2 , an embossed layer 3 , a protective coating layer 4 , and an upper surface and a base coating layer of the substrate layer 1 .
  • the lower surface of the base coat layer 2 is bonded to the lower surface of the embossed layer 3, and the upper surface of the embossed layer 3 is bonded to the lower surface of the protective coat layer 4.
  • the substrate layer has a thickness of 255 to 285 micrometers, preferably 270 micrometers, and the substrate layer is a staple fiber nonwoven paper having a basis weight of 150 gsm.
  • the base coating has a thickness of 15 to 25 micrometers, preferably 20 micrometers, and the base coating is an ink-absorbing coating, which may be: a weak solvent coating adapted to a weak solvent ink, a UV coating suitable for UV printing, and a Latex ink. Latex coating, suitable for matte anti-coating of pigment inks.
  • the base coating acts as an ink absorbing ink, and the screen prints with vivid colors and good color reproduction.
  • the embossed layer has a thickness of 3 to 5 micrometers, preferably 4 micrometers, and the embossed layer is a layer having an apparent appearance formed by applying a pressure of 6.5 MPa to the base coating layer after the base layer is coated with the base coating layer. .
  • the texture of the embossed layer is coarse sand, lychee or cloth.
  • the embossed layer is designed to give the wallpaper a better visual and touch effect, as well as personalization.
  • the protective coating has a thickness of 8 to 12 microns, preferably 10 microns, and the protective coating material is a polyurethane emulsion, a curing agent, and a friction-resistant hollow microsphere.
  • the protective coating is a scratch-resistant coating that protects the lines, scratches and scratches, and helps absorb ink during printing, allowing the product to be used for a long time.
  • non-woven paper wallpaper After the non-woven paper wallpaper is printed, it can be pasted onto any wall or consumable medium that you want to decorate or advertise. It can be widely used in shopping malls, homes, public places and personalized products.
  • the non-woven paper printing consumable of the utility model has the characteristics of good inkjet printing effect, scratch resistance, scratch resistance, soft and easy winding.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)

Abstract

一种无纺纸喷绘耗材，包括基材层（1）、基础涂层（2）、压纹层（3）、保护涂层（4），所述基材层（1）的上表面与基础涂层（2）的下表面贴合，所述基础涂层（2）的上表面与压纹层（3）的下表面贴合，所述压纹层（3）的上表面与保护涂层（4）的下表面贴合。所述无纺纸喷绘耗材具有喷绘效果好、抗刮抗划伤、柔软易收卷的特点，可根据不同的基础涂层来适应于Latex墨水、UV墨水、弱溶剂墨水、颜料墨水打印，打印后可以粘贴到家庭、医院、学校、工业区等用来做装饰或者广告，也可以做成无框画作为装饰画，由于涂层防水耐刮，可省却裱膜工序。

Description

一种无纺纸喷绘耗材 技术领域
本实用新型属于喷绘技术领域，具体涉及一种无纺纸喷绘耗材。
背景技术
国内的墙纸大部分是在纸基上淋膜一层PVC之后进行压纹和印刷图案，此种墙纸由于PVC不够环保，使用受到限制，印刷图案需要一定的量，这样客户就很难实现个性化定制图案，对于生产厂家来说则会造成很多的库存和积压资金。市场上的无纺纸墙纸相对高端，透气吸音，较少有纹路，且较少个性化图案，也不具备耐刮耐划伤的性能。为此需要开发出一种能够适应个性化喷绘且能够耐刮耐划伤的无纺纸墙纸，透气吸音环保，高端大气，能满足学校、医院、家庭、工业区等不同场合的需求。
市场上的喷绘耗材种类繁多，市场越来越喜欢布类和纸类的产品，因为给人很好的手感和质感，并且易收卷、不易打折。布类产品的价格普遍偏高。而市场上的无纺纸喷绘材料大多没有保护层，极易被外界刮擦所破坏。为此需要设计出适应各种墨水打印，耐刮擦且表观呈现特定纹路的打印耗材，满足客户打印效果的同时给耗材提供长久的保护。
发明内容
本实用新型的目的是提供一种无纺纸喷绘耗材，具有喷绘效果好、耐刮耐划伤和适应性广的特点。
为达到上述目的，本实用新型采用以下技术方案：
一种无纺纸喷绘耗材，包括基材层、基础涂层、压纹层、保护涂层，所述基材层的上表面与基础涂层的下表面贴合，所述基础涂层的上表面与压纹层的下表面贴合，所述压纹层的上表面与保护涂层的下表面贴合。
进一步地，所述基材层的厚度为255～285微米。
进一步地，所述基材层为克重150gsm的短纤维无纺纸。
无纺纸具有透气性好、可吸音的性能，无纺纸的特殊构造形成了基材的柔软性。
进一步地，所述基础涂层的厚度为15～25微米。
进一步地，所述基础涂层为吸墨涂层。
为适应不同墨水可以分别调配出不同的吸墨涂层，有适应弱溶剂墨水的弱溶剂涂层，有适应UV打印的UV涂层，有适应Latex墨水的Latex涂层，有适应颜料墨水的哑防涂层。
弱溶剂涂层的材料是纯丙乳液和二氧化硅；UV涂层的材料是纯丙乳液和聚氨酯乳液；Latex涂层的材料是纯丙乳液和碳酸钙；哑防涂层以二氧化硅为主，加入一些乳液和聚乙烯醇进行粘结和成膜。
基础涂层起到吸墨的作用，画面打印时呈现出鲜艳的色彩以及很好的色彩还原性。
进一步地，所述压纹层的厚度为3～5微米。
进一步地，所述压纹层是在基材层涂布完基础涂层后，向基础涂层施加6.5MPa的压力而形成的具有纹路表观的一层，是通过压力使得基础涂层的一部分形成了纹路。
进一步地，所述压纹层的纹路是粗砂纹、荔枝纹或布纹。
压纹层是为了给墙纸更好的视觉效果和触摸效果，同时也体现出个性化。
进一步地，所述保护涂层的厚度为8～12微米。
保护涂层的材料是聚氨酯乳液、固化剂和耐摩擦中空微球，固化剂为α-(2-氨基甲基乙基)-ω-(2-氨基甲基乙氧基)聚[氧基(甲基-1,2-亚乙基)]的聚合物和1-甲氧基-2-丙醇)。
保护涂层为抗刮涂层，起到保护纹路、抗刮耐划伤的作用，并能帮助喷绘时吸墨，从而使得产品能够长久使用。
本实用新型具有以下有益效果：
1、喷绘效果好，针对不同的墨水匹配不同的涂层，打印时基础涂层和保护涂层同时吸墨，能够呈现画面精美、色彩鲜艳的效果。
2、耐刮抗划伤，由于保护涂层配方里增加了耐刮抗划伤的组分，能够有效防止公共场合画面被刮花或者划伤的情况产生，从而保证画面的完整，不用短时间内进行更换。
3、柔软，无纺纸的材质和本身内部的蓬松结构形成柔软的手感，卷起来不易起拱打折，透气性好，不易发霉。
4、适应性广，由于可个性化打印，性价比高，可在家居、学校、医院、商业楼、工业区可以进行装饰或者广告，也适应个性化打印装饰。由于表面耐刮擦，画面不会受到影响，可长时间实用，也能抗一般的液体如咖啡、茶水、番茄酱等的污染，轻轻擦拭调污染物即可还原画面。
综上所述，本实用新型的无纺纸喷绘耗材具有喷绘效果好、抗刮抗划伤、柔软易收卷的特点。无纺纸喷绘耗材可根据基础涂层不同来适应于Latex墨水、UV墨水、弱溶剂墨水、颜料墨水打印，打印后可以粘贴到家庭、医院、学校、工业区等用来做装饰或者广告，也可以做成无框画作为装饰画，由于涂层防水耐刮，可省却裱膜工序。
附图说明
图1为本实用新型无纺纸喷绘耗材的剖面结构示意图。
具体实施方式
下面结合附图和具体实施方式对本实用新型作进一步详细的说明。
如图1所示，本实用新型的无纺纸喷绘耗材，包括基材层1、基础涂层2、压纹层3、保护涂层4，所述基材层1的上表面与基础涂层2的下表面贴合，所述基础涂层2的上表面与压纹层3的下表面贴合，所述压纹层3的上表面与保护涂层4的下表面贴合。
其中，基材层的厚度为255～285微米，优选270微米，基材层为克重150gsm的短纤维无纺纸。
基础涂层的厚度为15～25微米，优选20微米，基础涂层为吸墨涂层，根据需要可以是：适应弱溶剂墨水的弱溶剂涂层，适应UV打印的UV涂层，适应Latex墨水的Latex涂层，适应颜料墨水的哑防涂层。
基础涂层起到吸墨的作用，画面打印时呈现出鲜艳的色彩以及很好的色彩还原性。
压纹层的厚度为3～5微米，优选4微米，压纹层是在基材层涂布完基础涂层后，向基础涂层施加6.5MPa的压力而形成的具有纹路表观的一层。
压纹层的纹路是粗砂纹、荔枝纹或布纹。
压纹层是为了给墙纸更好的视觉效果和触摸效果，同时也体现出个性化。
保护涂层的厚度为8～12微米，优选10微米，保护涂层的材料是聚氨酯乳液、固化剂和耐摩擦中空微球。
保护涂层为抗刮涂层，起到保护纹路、抗刮耐划伤的作用，并能帮助喷绘时吸墨，从而使得产品能够长久使用。
无纺纸墙纸喷绘之后，可粘贴到任意想装饰或者广告的墙面、耗材介质上，可广泛用于商场、家居、公共场所和个性化定制产品中。
本实用新型的无纺纸喷绘耗材具有喷绘效果好、抗刮抗划伤、柔软易收卷的特点。
上述实施例和说明书中描述的只是说明本实用新型的原理和最佳实施例，在不脱离本实用新型精神和范围的前提下，本实用新型还会有各种变化和改进，这些变化和改进都落入要求保护的本实用新型范围内。

Claims (10)

  1. 一种无纺纸喷绘耗材，其特征在于，所述无纺纸喷绘耗材包括基材层、基础涂层、压纹层、保护涂层，所述基材层的上表面与基础涂层的下表面贴合，所述基础涂层的上表面与压纹层的下表面贴合，所述压纹层的上表面与保护涂层的下表面贴合。
  2. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述基材层的厚度为255～285微米。
  3. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述基材层为克重150gsm的短纤维无纺纸。
  4. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述基础涂层的厚度为15～25微米。
  5. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述基础涂层为吸墨涂层。
  6. 根据权利要求5所述的无纺纸喷绘耗材，其特征在于，所述吸墨涂层为弱溶剂涂层、UV涂层、Latex涂层或哑防涂层。
  7. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述压纹层的厚度为3～5微米。
  8. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述压纹层是向基础涂层施加6.5MPa的压力而形成。
  9. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述压纹层的纹路是粗砂纹、荔枝纹或布纹。
  10. 根据权利要求1所述的无纺纸喷绘耗材，其特征在于，所述保护涂层的厚度为8～12微米。
PCT/CN2017/088176 2017-05-05 2017-06-14 一种无纺纸喷绘耗材 WO2018201558A1 (zh)

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