WO2018199730A1 - "yurasus" device for the production and use of graphene - Google Patents
"yurasus" device for the production and use of graphene Download PDFInfo
- Publication number
- WO2018199730A1 WO2018199730A1 PCT/KZ2017/000009 KZ2017000009W WO2018199730A1 WO 2018199730 A1 WO2018199730 A1 WO 2018199730A1 KZ 2017000009 W KZ2017000009 W KZ 2017000009W WO 2018199730 A1 WO2018199730 A1 WO 2018199730A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- drum
- graphene
- graphite
- film
- coated
- Prior art date
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title abstract description 6
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 11
- 239000010439 graphite Substances 0.000 claims abstract description 11
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 4
- 230000001070 adhesive effect Effects 0.000 claims abstract description 4
- 239000003990 capacitor Substances 0.000 claims abstract description 3
- 239000002390 adhesive tape Substances 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000000137 annealing Methods 0.000 claims 1
- 238000003776 cleavage reaction Methods 0.000 claims 1
- 230000007423 decrease Effects 0.000 claims 1
- 230000007017 scission Effects 0.000 claims 1
- 238000004804 winding Methods 0.000 claims 1
- 239000010408 film Substances 0.000 abstract 4
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 238000004299 exfoliation Methods 0.000 abstract 1
- 239000010409 thin film Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 238000005234 chemical deposition Methods 0.000 description 2
- 238000000277 atomic layer chemical vapour deposition Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
- C01B32/19—Preparation by exfoliation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
- H01L31/0264—Inorganic materials
Definitions
- Graphene is the thinnest material, with a thickness of just one carbon atom, obtained in 2004 by A. Geim and K. Novosyolov, using an ordinary adhesive tape for sequential separation from ordinary crystalline graphite, of high quality, with further transfer to the substrate, but this the method, due to the complexity, cannot be applied in industrial technology.
- A. Geim and K. Novosyolov using an ordinary adhesive tape for sequential separation from ordinary crystalline graphite, of high quality, with further transfer to the substrate, but this the method, due to the complexity, cannot be applied in industrial technology.
- ACVD atomic chemical deposition method
- the most used method for the manufacture of film solar cells is the method of chemical deposition of graphene from the gas phase onto a Ni substrate with its subsequent dissolution after transferring the solar battery to the film.
- a device for example, for the manufacture of film solar cells, which uses the method of producing graphene, by cleaving, from a rotating graphite drum-1, on which, by milling, the cells of solar cells are made, in contact with film-2, the future solar battery, pressed by a cell drum -3, with rubber sheath-4, using springs-5.
- the film from the brake drum-b is advanced through the device-7 for applying adhesive ⁇ UV 301, on the lower side and the dryer-8 with infrared radiation-9.
- the adhesive tape splits off the graphene layer, as a result of which the pattern of solar cells is printed on the film.
- the film moves through the UV-0 camera to cure the glue, and then it is wound on the finished product-11 drum, ensuring its tension.
- applying glue to the film can be applied in advance, by analogy with adhesive tape reels. Periodically, after the release of 3 million square meters, the wear of the drum will be up to 10 mm., After which periodic milling will be required to deepen the protruding parts of the drum.
- Graphite consumption 100kg. ($ 20) At a market value of 1 sq.m. 1 million rubles graphene film, ($ 16,000), prime cost 1 sq.m. film battery, up to 3 cents! !
- This device can provide the release of integrated circuits, capacitors, batteries and monitors, on-stream, with minimal cost and unprecedented competitiveness.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Electromagnetism (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Photovoltaic Devices (AREA)
Abstract
The claimed "Yurasus" device for the production and use of graphene is based on the principle of exfoliating a thin layer of graphene from a graphite drum. This principle makes it possible to mass-produce industrial volumes of a high-quality coating, for example for thin-film solar cells, at minimal expense. A production line comprises a drum for a film substrate, and a power-driven graphite drum having solar element cells milled thereon, to which a rubber-coated driven drum is clamped on springs to produce high-quality graphene imprints. The film is unwound from the drum and is coated with 3М UV-301 adhesive by a device for application to Scotch tape, before being dried in an infrared dryer and then transferred to the graphite drum, where graphene is transferred to the film by exfoliation. After the adhesive and the coating have been cured in a device providing ultraviolet irradiation, the film is wound onto a power-driven finished product drum. Bearing in mind that graphite is thousands of times cheaper than the resulting graphene, the cost price of the graphene solar cells is no more than 3 cents per square metre. The device can be used for articles for producing integrated circuits, capacitors, storage batteries, monitors and other articles, at minimal expense.
Description
УСТРОЙСТВО «YURASUS» ПО ПОЛУЧЕНИЮ И ИСПОЛЬЗОВАНИЮ ГРАФЕНА YURASUS DEVICE FOR RECEIVING AND USING GRAPHENE
Графен- самый тонкий материал, толщиной всего в один атом углерода, полученный в 2004 г. А. Геймом и К.Новосёловым, используя обычную ленту-скотч для последовательного отделению от обычного кристаллического графита, высокого качества, с дальнейшим переносом на подложку, но этот метод, в связи с трудоёмкостью, не может быть применён в промышленной технологии. Есть способ атомно-химического осаждения (ALCVD), но это высокотемпературный процесс, и не применим для пластиковых подложек. Graphene is the thinnest material, with a thickness of just one carbon atom, obtained in 2004 by A. Geim and K. Novosyolov, using an ordinary adhesive tape for sequential separation from ordinary crystalline graphite, of high quality, with further transfer to the substrate, but this the method, due to the complexity, cannot be applied in industrial technology. There is an atomic chemical deposition method (ALCVD), but this is a high-temperature process, and is not applicable for plastic substrates.
Наиболее используемым методом, для изготовления плёночных солнечных батарей, является метод химического осаждения графена из газовой фазы на Ni-подложку с её последующи растворением, после переноса на плёнку солнечной батареи. The most used method for the manufacture of film solar cells is the method of chemical deposition of graphene from the gas phase onto a Ni substrate with its subsequent dissolution after transferring the solar battery to the film.
Естественно это многоэтапный процесс, требующий больших затрат времени и рабочей силы, при переносе, возможны образования складок и сдвигов, которые приводят к деформации структуры графена, и не может считаться технологичным, для промышленного использования, Naturally, this is a multi-stage process that requires a lot of time and labor, during the transfer, the formation of folds and shears are possible, which lead to deformation of the structure of graphene, and cannot be considered technological, for industrial use,
Предлагается устройство, например для изготовления плёночных солнечных батарей, которое использует метод получение графена, отщеплением, от вращающегося графитового барабана-1, на котором, методом фрезерования, выполнены ячейки солнечных элементов, при соприкосновении с плёнкой-2, будущей солнечной батареи, прижимаемой сотелитным барабаном-3, с резиновой оболочкой-4, с помощью пружин-5. Плёнка с подторможенного барабана-б продвигается через устройство-7 для нанесения клея ЗМ UV 301, на нижнюю сторону и сушилку-8 с инфракрасным облучением-9. A device is proposed, for example, for the manufacture of film solar cells, which uses the method of producing graphene, by cleaving, from a rotating graphite drum-1, on which, by milling, the cells of solar cells are made, in contact with film-2, the future solar battery, pressed by a cell drum -3, with rubber sheath-4, using springs-5. The film from the brake drum-b is advanced through the device-7 for applying adhesive ЗМ UV 301, on the lower side and the dryer-8 with infrared radiation-9.
При продвижение плёнки между барабанами, клейкая лента отщепляет слой графена, в результате чего на плёнке отпечатывается рисунок солнечных элементов. Для закрепления отпечатка плёнка продвигается через камеру ультрафиолетового облучения- 0, для отверждения клея, после чего наматывается на барабан готовой продукции-11, обеспечивающий ее натяжение. Для упрощения производства нанесение клея на плёнку, может наносится заранее, по аналогии с бобинами скотча. Периодически, после выпуска 3-х миллионов кв.м., износ барабана составит до 10 мм., после чего потребуется периодическое фрезерование для углубление выступающих частей барабана. Расход графита- 100кг. ($20) При рыночной стоимости 1 кв.м. графеновой плёнки в 1 миллион рублей, ($16000 ), себестоимость 1 кв.м. плёночной батареи, составит до 3-х центов! !Данное устройство может обеспечить выпуск интегральных схем, конденсаторов, аккумуляторов и мониторов, на потоке, с минимальными затратами и небывалой конкурентоспособностью.
When the film moves between the reels, the adhesive tape splits off the graphene layer, as a result of which the pattern of solar cells is printed on the film. To fix the fingerprint, the film moves through the UV-0 camera to cure the glue, and then it is wound on the finished product-11 drum, ensuring its tension. To simplify production, applying glue to the film can be applied in advance, by analogy with adhesive tape reels. Periodically, after the release of 3 million square meters, the wear of the drum will be up to 10 mm., After which periodic milling will be required to deepen the protruding parts of the drum. Graphite consumption - 100kg. ($ 20) At a market value of 1 sq.m. 1 million rubles graphene film, ($ 16,000), prime cost 1 sq.m. film battery, up to 3 cents! ! This device can provide the release of integrated circuits, capacitors, batteries and monitors, on-stream, with minimal cost and unprecedented competitiveness.
Claims
1. Отщепление, например для солнечных батарей, происходит непосредственно на подложку, покрытую клеем, например ЗМ UV- 301, при контакте с графитовым барабаном с отфрезерованным рисунком, в виде ячеек солнечных элементов, при обжатии пружинами с фрикционным барабаном, покрытым, например, резиной, с дальнейшим отверждением клея ультрафиолетовым облучением, перед намоткой, с усилием, на барабан готовой продукции, причём нанесение клея может быть нанесено, как. перед контактом с графитовым барабаном, так и заранее, по аналогии с бобиной скотча. 1. Cleavage, for example for solar panels, occurs directly on a substrate coated with glue, for example ZM UV-301, in contact with a graphite drum with a milled pattern, in the form of cells of solar cells, when pressed with springs with a friction drum coated, for example, with rubber , with further curing of the adhesive by ultraviolet irradiation, before winding, with effort, on the drum of the finished product, and the application of glue can be applied as. before contact with a graphite drum, and in advance, by analogy with an adhesive tape reel.
2. Графитовый барабан по п.1, выполненный по ширине подложки, отфрезерован из расчёта совпадения конфигурации ячеек, при непрерывном вращении, а при убывании материала, при отщеплении, фрезерование (углубление) повторяется. 2. The graphite drum according to claim 1, made across the width of the substrate, is milled based on the coincidence of the configuration of the cells during continuous rotation, and when the material decreases, when cleaving, milling (recess) is repeated.
3. Устройство, по п.-1 может применяться для создания интегральных схем, конденсаторов, аккумуляторов и других устройств, с использованием графена, в промышленных объёмах с минимальными затратами.
3. The device according to p. 1 can be used to create integrated circuits, capacitors, batteries and other devices using graphene in industrial volumes at minimal cost.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/KZ2017/000009 WO2018199730A1 (en) | 2017-04-24 | 2017-04-24 | "yurasus" device for the production and use of graphene |
| EA201900397A EA201900397A1 (en) | 2017-04-24 | 2017-04-24 | "YURASUS" DEVICE FOR RECEIVING AND USING GRAPHENE |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/KZ2017/000009 WO2018199730A1 (en) | 2017-04-24 | 2017-04-24 | "yurasus" device for the production and use of graphene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2018199730A1 true WO2018199730A1 (en) | 2018-11-01 |
Family
ID=63918535
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/KZ2017/000009 WO2018199730A1 (en) | 2017-04-24 | 2017-04-24 | "yurasus" device for the production and use of graphene |
Country Status (2)
| Country | Link |
|---|---|
| EA (1) | EA201900397A1 (en) |
| WO (1) | WO2018199730A1 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140295150A1 (en) * | 2013-03-28 | 2014-10-02 | Nokia Corporation | Method and apparatus for joining together multiple functional layers of a flexible display |
| US20150344312A1 (en) * | 2014-06-03 | 2015-12-03 | Est Co., Ltd. | Method of manufacturing graphene and conductor |
-
2017
- 2017-04-24 WO PCT/KZ2017/000009 patent/WO2018199730A1/en active Application Filing
- 2017-04-24 EA EA201900397A patent/EA201900397A1/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140295150A1 (en) * | 2013-03-28 | 2014-10-02 | Nokia Corporation | Method and apparatus for joining together multiple functional layers of a flexible display |
| US20150344312A1 (en) * | 2014-06-03 | 2015-12-03 | Est Co., Ltd. | Method of manufacturing graphene and conductor |
Also Published As
| Publication number | Publication date |
|---|---|
| EA201900397A1 (en) | 2020-03-06 |
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