WO2018199566A1

WO2018199566A1 - Electrochromic device

Info

Publication number: WO2018199566A1
Application number: PCT/KR2018/004666
Authority: WO
Inventors: 김용찬; 김기환; 조필성
Original assignee: 주식회사 엘지화학
Priority date: 2017-04-27
Filing date: 2018-04-23
Publication date: 2018-11-01

Abstract

The present application relates to an electrochromic device. The device comprises: an electrode layer; an electrochromic layer; and a closed ring-shaped conductive band. Such an electrochromic device changes color with superb speed and uniformity.

Description

Electrochromic device

Cross Citation with Related Applications

This application claims the benefit of priority based on Korean Patent Application No. 10-2017-0054315 dated April 27, 2017 and Korean Patent Application No. 10-2018-0045419 dated April 19, 2018. All content disclosed in the literature of the application is included as part of this specification.

Field of technology

The present application relates to an electrochromic device.

Electrochromic refers to a phenomenon in which the optical properties of an electrochromic material are changed by an electrochemical oxidation or reduction reaction, and the device using the phenomenon is called an electrochromic device. Electrochromic devices generally include a working electrode, a counter electrode, and an electrolyte, and the optical properties of each electrode may be reversibly changed by an electrochemical reaction. For example, the working electrode or the counter electrode may include a transparent conductive material and an electrochromic material, respectively, in the form of a film. When a potential is applied to the device, electrolyte ions are inserted into or detached from the electrochromic material-containing film, At the same time, as electrons move through the external circuit, the optical properties of the electrochromic material appear.

Such electrochromic devices are attracting attention as smart windows, smart mirrors, and other next-generation building window materials because they can manufacture devices with a large area at low cost and have low power consumption. However, since the insertion and / or desorption of electrolyte ions for changing the optical properties of the entire discoloration layer takes a long time, the discoloration rate is slow. In addition, even on the same plane of the electrochromic layer, the discoloration rate is different depending on the position, there is a disadvantage that the degree of discoloration is uneven.

One object of the present application is to provide an electrochromic device with improved discoloration speed.

Another object of the present application is to provide an electrochromic device having a uniform discoloration degree.

The above and other objects of the present application can all be solved by the present application described in detail below.

In one example of the present application, the present application relates to an electrochromic device. The electrochromic device of the present application may include a conductive band positioned on the electrode layer in addition to the electrode layer and the electrochromic layer positioned on the electrode layer. In the present application, the term "upper" used with respect to the position between the components is used in the meaning corresponding to "above" or "upper", and unless otherwise stated, the configuration having the position directly contact another configuration While it may mean that the case exists on it, or it may mean that there is a different configuration between them.

The electrode layer may be a transparent electrode having transparency. In the present application, the term “transparent” may mean a case where transmittance with respect to visible light is 60% or more. In addition, "visible light" may mean light in the wavelength range of 380 nm to 780 nm, specifically light of 550 nm wavelength. The upper limit of the transmittance is not particularly limited, but may be, for example, 95% or less. The light transmittance can be measured by a known haze meter.

The electrode layer may have a thickness in the range of 10 nm to 450 nm. In the present application, the term "thickness" means an average normal distance between one surface (bottom surface) of the layer to be measured and the other surface (top surface) of the layer to be measured when a virtual normal is drawn from the ground surface to the surface of the device. can do.

The electrode layer may include a transparent conductive oxide or OMO (oxide / metal / oxide) as a transparent transparent electrode material.

In one example, the transparent conductive oxide may include indium tin oxide (ITO), indium oxide (In ₂ O ₃ ), indium galium oxide (IGO), fluor doped tin oxide (FTO), aluminum doped zinc oxide (AZO), GZO (Galium doped Zinc Oxide), ATO (Antimony doped Tin Oxide), IZO (Indium doped Zinc Oxide), NTO (Niobium doped Titanium Oxide), ZnO (Zink Oxide), or CTO (Cesium Tungsten Oxide) . However, the materials listed above are not limited to the material of the transparent conductive oxide.

The oxide / metal / oxide (OMO) may include an upper metal oxide layer, a lower metal oxide layer, and a metal layer provided between the two layers. The upper metal oxide layer may mean a layer located relatively farther from the electrochromic layer among the layers constituting the OMO. Since the OMO having the above configuration has a lower sheet resistance than the transparent conductive oxide represented by ITO, the color change rate of the electrochromic device can be improved.

The upper and lower metal oxide layers used in the OMO include Sb, Ba, Ga, Ge, Hf, In, La, Se, Si, Ta, Se, Ti, V, Y, Zn, Zr or metal oxides of these alloys. It may include. The type of each metal oxide included in the upper and lower metal oxide layers may be the same or different.

In one example, the thickness of the upper metal oxide layer may range from 10 nm to 120 nm, or from 20 nm to 100 nm. In addition, the visible light refractive index of the upper metal oxide layer may be in the range of 1.0 to 3.0 or 1.2 to 2.8. When having a refractive index and a thickness in the above range, an appropriate level of optical properties can be imparted to the device.

In one example, the thickness of the lower metal oxide layer may range from 10 nm to 100 nm or from 20 nm to 80 nm. In addition, the visible light refractive index of the lower metal oxide layer may be in the range of 1.3 to 2.7 or 1.5 to 2.5. When having a refractive index and a thickness in the above range, an appropriate level of optical properties can be imparted to the device.

The metal layer included in the OMO may include a low resistance metal material. For example, one or more metals selected from Ag, Cu, Zn, Au, Pd, and alloys thereof may be used in the metal layer as the low resistance metal material.

In one example, the metal layer of the OMO may have a thickness in the range of 3 nm to 30 nm or in the range of 5 nm to 20 nm. In addition, the metal layer may have a visible light refractive index of 1 or less or 0.5 or less. When having a refractive index and a thickness in the above range, an appropriate level of optical properties can be imparted to the device.

The method for providing the electrode layer is not particularly limited. For example, the electrode layer can be formed using a known wet or dry coating method using the electrode material or a known lamination method.

The electrochromic layer is a layer containing an electrochromic material that can be discolored by a reversible oxidation-reduction reaction. As the electrochromic material, a known organic or inorganic material may be used.

In one example, the electrochromic layer may include a reducing color change material, that is, a material that changes color (coloration) upon reduction. More specifically, the electrochromic layer may include oxides of Ti, Nb, Mo, Ta, or W, such as WO ₃ , MoO ₃ , Nb ₂ O ₅ , Ta ₂ O _5, or TiO ₂ .

In one example, the electrochromic layer may include an oxidative color change material, that is, a material that changes color (coloring) upon oxidation. More specifically, the electrochromic layer may be an oxide of Cr, Mn, Fe, Co, Ni, Rh, or Ir, such as LiNiOx, IrO ₂ , NiO, V ₂ O ₅ , LixCoO ₂ _, Rh ₂ O ₃ or CrO ₃ . Hydroxides of Cr, Mn, Fe, Co, Ni, Rh, or Ir; And prussian blue.

Although not particularly limited, the electrochromic layer may have a thickness of 400 nm or less. More specifically, the electrochromic layer may have a thickness of 30 nm or more, 50 nm or more, 100 nm or more, or 150 nm or more, and may have a thickness of 350 nm or less or 300 nm or less.

The method for preparing the electrochromic layer is also not particularly limited. For example, the electrochromic layer may be formed by applying and sintering a coating composition including the above-described discoloring material on an electrode layer or a substrate including the electrode layer. Alternatively, the electrochromic layer including the above-mentioned material may be formed on the electrode layer or the substrate including the electrode layer through a deposition method. In addition, a method of forming an electrochromic layer separately from the electrode layer and then laminating the electrode layer and the electrochromic layer with each other may be used.

In the present application, the conductive band has a predetermined size and a predetermined thickness expressed in length, width or width. The conductive strip includes a conductive material and has a closed ring shape, that is, a form in which both ends are joined together. The specific shape of the closed ring is not particularly limited. For example, the shape of the ring visible at the top or bottom parallel to the normal to the device surface can be a circle, an ellipse, or a polymorph. In one example, the shape of the electrochromic layer visible at the top or bottom parallel to the normal direction to the device surface and the closed ring shape of the conductive strips visible in the same direction may be the same.

The conductive strip may be in direct physical contact with the electrochromic layer. As in some embodiments of the present application described below, the conductive bands in contact with the electrochromic layer form an equipotential section in the electrochromic layer, thereby improving the electrochromic speed and contributing to the uniform discoloration of the electrochromic layer. .

In one example, the conductive strip can contact the electrochromic layer, surrounding the side of the electrochromic layer. In this application, the "side surface of a layer" can mean the surface other than the upper surface and lower surface which mutually oppose in the thickness direction of the layer demonstrated above. Specifically, the conductive strip may extend along the side of the electrochromic layer in physical contact with the side of the electrochromic layer, and may have a closed ring shape in which both ends are joined to each other. That is, the conductive strip may exist in a state surrounding the side of the electrochromic layer. When a voltage is applied to the device, the conductive band in physical contact with the electrochromic layer in the above manner contributes to widening the equipotential section of the electrochromic layer. For example, in the case where the electrochromic layer seen in the upper part of the normal direction to the surface of the element is rectangular, the conductive band surrounds the electrochromic layer in contact with the four side edges of the electrochromic layer, so that the equipotential section by the conductive band is It can be formed evenly up to the center of the electrochromic layer. On the other hand, when the conductive band is not formed, or when the conductive band is formed only on a part of the side surface of the electrochromic layer, the expansion of the equipotential section, the uniformity of the degree of discoloration, and the improvement of the discoloration speed cannot be expected.

As described above, when the conductive strip has a closed ring shape surrounding the side of the electrochromic layer, the electrode layer may have an area equal to or greater than the sum of the areas of the conductive strip and the area of the electrochromic layer. In the present application, unless otherwise defined, the term "area" means an area, for example, an orthographic area, which is visible when the device is viewed from above or below in a direction parallel to the normal direction of the surface thereof. Can be. Therefore, the increase or decrease of the actual area due to the unevenness and the like of the structure to be compared with the area is not considered. 1 schematically illustrates the area relationship between an electrode layer, an electrochromic layer and a conductive strip, according to an example of the present application. As shown in FIG. 1, the area S1 of the electrode layer may be the same size as the sum of the area S2 of the electrochromic layer and the area S3 of the conductive strip. In this case, the shapes of the conductive strip and the electrochromic layer observed in the upper or lower part of the direction parallel to the normal direction of the element surface may be the same in quadrilateral.

In one example, when the conductive strip has a closed ring shape surrounding (or wrapping) the side of the electrochromic layer, each of the electrochromic layer and the conductive strip may directly contact the same side of the electrode layer.

In one example, the conductive strip may have a thickness of at least an electrochromic layer. Specifically, when the conductive strip and the electrochromic layer are positioned on the electrode layer while directly contacting the same side of the electrode layer, respectively, the normal length from the lower surface to the upper surface of the conductive strip may be the same as or larger than that of the electrochromic layer. have.

The method of forming the conductive strip so as to surround the side of the electrochromic layer and satisfy the area relationship described in FIG. 1 is not particularly limited. For example, after forming the electrochromic layer on the electrode layer, the edge of the electrochromic layer is etched so that the area of the electrochromic layer is smaller than the area of the electrode layer, and the electrochromic layer is etched to surround the side of the electrochromic layer. A conductive strip can be formed on the marked part. Alternatively, even without etching, an electrochromic layer having a smaller size than the electrode layer may be formed on the electrode layer, and a conductive strip may be formed to surround the side surface of the electrochromic layer. In addition, the conductive strip may be attached to a predetermined portion in the form of a tape having an adhesive surface, or may be formed by applying a conductive composition to the predetermined portion and then sintering or drying the conductive strip.

In another example, the conductive strip may be located on the upper or lower surface of the electrochromic layer. More specifically, the conductive band may be in direct contact with the electrode layer and the electrochromic layer while being positioned between the electrode layer and the electrochromic layer, or may be directly in contact with the electrochromic layer while being located on the opposite side of one side of the electrochromic layer facing the electrode layer. have.

As described above, when the conductive strip is located on the upper or lower surface of the electrochromic layer, the electrochromic layer may have an area equal to or larger than the sum of the area of the conductive strip and the inner area of the closed ring of the conductive strip. For example, as shown in FIG. 2, the area S4 of the electrochromic layer may be equal to or larger than the sum of the area of the conductive band S5 and the area S6 inside the ring. In one example, the shape of the conductive strip and the electrochromic layer observed at the top or the bottom in a direction parallel to the normal direction of the device surface may be quadrilateral. In addition, although not particularly limited, in the case described above, the electrochromic layer may have an area of the electrode layer or less.

As described above, the method for providing the conductive strip on the upper or lower surface of the electrochromic layer is not particularly limited. For example, a conductive layer may be formed by forming a conductive layer on the upper or lower surface of the electrochromic layer using a known coating method and etching the conductive layer to have a closed ring shape. Alternatively, a conductive strip in the form of a tape can be used to provide a conductive strip on the upper or lower surface of the electrochromic layer.

As described above, when the conductive strip is located on the upper or lower surface of the electrochromic layer and satisfies a specific area relationship, the electrochromic device may further include a wiring unit (not shown) electrically connected to the conductive strip. The wiring portion may be used to connect the electrode layer and the conductive strip.

In one example, the conductive strip may include a metal as a conductive material. The type of metal is not particularly limited, and for example, nickel (Ni), aluminum (Al), silver (Ag), copper (Cu), zinc (Zn), gold (Au), palladium (Pd), platinum ( Pt) or alloys thereof can be used for the conductive strips.

In one example, the resistance value of the conductive strip may be 10% or less of the electrode layer resistance value. If the above relationship is satisfied, the discoloration speed of the device can be further improved.

Although not particularly limited, the conductive strip may have a width or width of 100 nm or less. Specifically, the conductive band may have a width of 70 nm or less, 50 nm or less, 30 nm or less, 20 nm or less, or 15 nm or less, and may have a thickness of 1 nm or more, 3 nm or more, or 5 nm or more. .

Although not particularly limited, the conductive strip may have a thickness of 1,200 nm or less. More specifically, it may have a thickness of 1,100 nm or less, 900 nm or less, 700 nm or less, or 500 nm or less, and have a thickness of 100 nm or more, 200 nm or more, 300 nm or more, 400 nm or more or 500 nm or more. Can be.

The electrochromic device may include an electrolyte layer on one surface opposite to one surface of the electrochromic layer facing the electrode layer. In an example related to this, the electrochromic device may sequentially include an electrode layer, a conductive strip, an electrochromic layer, and an electrolyte layer, or may sequentially include an electrode layer, an electrochromic layer, a conductive strip, and an electrolyte layer. In another example, the electrochromic device may include an electrode layer, an electrochromic layer, and an electrolyte layer sequentially, such that a conductive band surrounding the side of the electrochromic layer is positioned between the electrode layer and the electrolyte layer like the electrochromic layer. have.

The electrolyte layer may be configured to provide electrolyte ions involved in the electrochromic reaction. Electrolyte ions are monovalent cations inserted into the conductive laminate, and may be, for example, H ⁺ , Li ⁺ , Na ⁺ , K ⁺ , Rb ⁺ , or Cs ⁺ .

In one example, the electrolyte layer may include a gel polymer electrolyte. Gel polymer electrolytes have ionic conductivity but no electrical conductivity. Therefore, as will be described below, in the case where the second conductive band is further present on one surface of the counter electrode layer, the gel polymer present between the two conductive bands can prevent the device from shorting. In addition, the gel polymer electrolyte may also serve as a buffer for a step, that is, a thickness difference that may exist between the electrochromic layer and the conductive band.

In one example, the gel polymer electrolyte may comprise a polymer. Examples of the polymer that can be used include, for example, polyvinylidene fluoride (PVdF), polyacrylonitrile (PAN), polymethyl methacrylate (PMMA), and polyvinyl chloride (polyvinyl chloride). chloride, PVC), polyethylene oxide (PEO), polypropylene oxide (PPO), poly (vinylidene fluoride-hexafluoro propylene) (Poly (vinylidene fluoride-hexafluoro propylene), PVdF- HFP), polyvinyl acetate (Polyvinyl acetate, PVAc), polyoxyethylene (Polyoxyethylene, POE), polyamideimide (Polyamideimide, PAI) and the like.

In one example, the electrolyte layer may comprise a metal salt compound capable of providing monovalent cations to the electrochromic layer or the ion storage layer described below. For example, the electrolyte layer may be LiPF ₆ , LiAsF ₆ , LiCF ₃ SO ₃ , LiN (CF ₃ SO ₂ ) ₂ , LiBF ₄ , LiSbF ₆ , LiN (C ₂ F ₅ SO ₂ ) ₂ , LiAlO ₄ , LiAlCl ₄ , LiCo ₀ _. ₂ Ni ₀ _. ₅₆ Mn ₀ _. Lithium salt compounds such as ₂₇ O ₂ , LiCoO ₂ , LiSO ₃ CF ₃ or LiClO ₄ , or sodium salt compounds such as NaClO ₄ may be included.

In another example, the electrolyte layer may further include a carbonate compound as a solvent. Since a carbonate type compound has high dielectric constant, ionic conductivity can be improved. As a non-limiting example, a solvent such as propylene carbonate (PC), ethylene carbonate (EC), dimethyl carbonate (DMC), diethyl carbonate (DEC), or ethylmethyl carbonate (EMC) may be used as the carbonate-based compound.

In one example, when the conductive strip is present surrounding the side of the electrochromic layer, the area of the electrolyte layer may have an area equal to or larger than the sum of the area of the conductive strip and the area of the electrochromic layer. Through the above configuration, short can be prevented.

In another example, when the conductive band is located on the upper or lower surface of the electrochromic layer, the area of the electrolyte layer may have an area equal to or larger than the sum of the area of the conductive band and the inner area of the ring of the conductive band. have. Through the above configuration, short can be prevented.

In another example, the area of the electrolyte layer may be different from or the same as the area of the electrode layer described above. In addition, the area of the electrolyte layer may be different from or the same as that of the counter electrode layer described below.

Although not particularly limited, the light transmittance of the electrolyte layer may range from 60% to 95%, and the thickness may range from 10 μm to 300 μm.

The electrochromic device may further include a counter electrode layer on one surface opposite to one surface of the electrolyte layer facing the electrochromic layer. The structure and other characteristics of the counter electrode layer are the same as those described in connection with the electrode layer.

The electrochromic device of the present application may further include an ion storage layer. The ion storage layer refers to a layer formed to balance the charge balance with the electrochromic layer during the reversible oxidation / reduction reaction for discoloration of the electrochromic material. The ion storage layer may be located on one surface of the counter electrode layer. More specifically, the ion storage layer may be located between the counter electrode layer and the electrolyte layer.

The ion storage layer may include an electrochromic material having a color development characteristic different from that of the electrochromic material used in the electrochromic layer. For example, when the electrochromic layer includes a reducing electrochromic material, the ion storage layer may include an oxidative electrochromic material. The reverse is also possible.

Although not particularly limited, the ion storage layer may have a thickness of 400 nm or less. More specifically, the ion storage layer may have a thickness of 30 nm or more, 50 nm or more, 100 nm or more, or 150 nm or more, and may have a thickness of 350 nm or less or 300 nm or less.

In one example, the electrochromic device of the present application may further include a second conductive band. In this case, the two conductive bands included in the electrochromic device of the present application may be referred to as first and second conductive bands, respectively. The configuration or characteristic of the second conductive strip itself, or the relationship with the adjacent layer, may be the same as that of the conductive strip described above. In this case, the description of the electrochromic layer may be applied to the ion storage layer, and the description of the electrode layer may be applied to the counter electrode layer.

In one example, the second conductive band may be in direct physical contact with the ion storage layer.

In another example, the second conductive band may contact the ion storage layer while surrounding the side of the ion storage layer. In this case, the counter electrode layer may have an area equal to or larger than the sum of the area of the second conductive band and the area of the ion storage layer. In this case, each of the ion storage layer and the second conductive band may directly contact the same surface of the counter electrode layer. In addition, the second conductive band may have a thickness greater than or equal to the ion storage layer.

In another example, the second conductive band may be located on the upper or lower surface of the ion storage layer. More specifically, the second conductive band may be directly contacted with the counter electrode layer and the ion storage layer while being positioned between the counter electrode layer and the ion storage layer. Alternatively, the ion storage layer may be directly in contact with the ion storage layer while being positioned on the opposite side of one surface of the ion storage layer facing the counter electrode layer, that is, between the electrolyte layer and the ion storage layer. As described above, when the second conductive band is located on the upper or lower surface of the ion storage layer, the ion storage layer is equal to or larger than the sum of the area of the second conductive band and the inner area of the closed ring of the second conductive band. It may have an area. In addition, although not particularly limited, in the above case, the ion storage layer may have an area of the counter electrode layer or less.

In another example, as described above, when the second conductive band is located on the upper or lower surface of the ion storage layer and satisfies a specific area relationship, the electrochromic device further includes a wiring part electrically connected to the second conductive band. can do. The wiring portion may be used to connect the counter electrode layer and the second conductive strip.

In another example, when the second conductive band exists around the side of the ion storage layer, the area of the electrolyte layer is equal to or larger than the sum of the area of the second conductive band and the area of the ion storage layer. Can have

In another example, when the second conductive band is located on the upper or lower surface of the ion storage layer, the area of the electrolyte layer is equal to or equal to the sum of the area of the second conductive band and the ring inner area of the second conductive band. It can have a larger area.

In one example, the electrochromic device may further include a light transmissive substrate. The light transmissive substrate may be located on the outer side of the device, specifically, on the outer side of the electrode layer and / or the counter electrode layer.

The light transmissive substrate may be, for example, a substrate having a visible light transmittance of about 60% to 95%. If the transmittance | permeability of the said range is satisfied, the kind of base material used will not be restrict | limited in particular. For example glass or polymer resins can be used. More specifically, a polyester film such as polycarbonate (PC), polyethylene (phthalene naphthalate) (PEN) or polyethylene (ethylene terephthalate) (PET), an acrylic film such as poly (methyl methacrylate) (PMMA), or polyethylene (PE) Or a polyolefin film such as PP (polypropylene) may be used, but is not limited thereto.

The electrochromic device may further include a power source. The manner of electrically connecting the power source to the device is not particularly limited and may be appropriately made by those skilled in the art. The electrochromic device may apply a predetermined voltage necessary for electrochromic.

According to an example of the present application, an electrochromic device having improved electrochromic speed and uniformity of color change can be provided.

1 schematically illustrates the area relationship of an electrode layer, an electrochromic layer, and a conductive strip, according to an example of the present application.

2 schematically illustrates the area relationship between the electrochromic layer and the conductive strip according to an example of the present application.

3 is a graph relating to driving characteristics of an embodiment device according to an example of the present application.

4 is a graph relating to driving characteristics of a comparative example element.

Hereinafter, the present application will be described in detail through examples. However, the protection scope of the present application is not limited by the examples described below.

<전기변색 시간의 측정 방법><Measuring method of electrochromic time>

Permeability: measured using oceanoptics. Specifically, at three points (B1, B2, B3 when decoloring; C1, C2, C3 when discoloring), the change in transmittance with time is measured. Each was measured.

실시예Example

Preparation of First Laminate : Using an evaporation method, an ITO (thickness: 100 nm) layer and a WO ₃ layer (thickness: 350 nm) were sequentially formed on a 150 nm thick PET substrate. The planar area of the ITO layer and the WO ₃ layer was such that the quadrilaterals were of the same size (width X length: 10 cm × 7 cm).

100 ppm of an electrolytic solution containing LiClO ₄ (1M), propylene carbonate (PC) and a potentiostat device were prepared, and a voltage of −1 V was applied for 50 seconds to allow Li ⁺ to be added to the WO ₃ layer. Inserted and colored WO ₃ layer.

Thereafter, all four edges of the WO ₃ layer were etched. The width of each edge removed by etching was 10 nm. Thereafter, a 10 nm wide nickel tape was attached to all four edges etched with WO ₃ . The thickness of the nickel tape used was 1,000 nm.

Preparation of Second Laminate : Using an evaporation method, an ITO (thickness: 100 nm) layer and a Prussian blue (PB) layer (thickness: 350 nm) were sequentially formed on a 150 nm thick PET substrate. The planar width of the ITO layer and the PB layer was such that a quadrilateral of the same size (width × length: 10 cm × 7 cm) was obtained.

Similarly, all four edges of the PB layer were etched. The width of each edge removed by etching was 10 nm. Thereafter, a 10 nm wide nickel tape was attached to all four edges etched with PB. The thickness of the nickel tape used was 1,000 nm.

Fabrication of the device: WO ₃ layer of the first laminate and PB layer of the second laminate face each other via a gel polymer electrolyte (GPE) layer having an area size of 10 cm × 7 cm and a thickness of 50 μm. Each laminate was bonded to each other, and a device (ITO / WO ₃ / GPE / PB / ITO) was manufactured.

The change in the amount of charge of the device over time was observed while repeatedly applying a bleaching voltage and a coloring voltage to the device manufactured from the above at regular intervals. The bleaching and coloring voltages per cycle were ± 1.2 V each, applied for 50 seconds each. A predetermined cycle was driven for stabilization, and the change in desorption time with voltage application was observed. The result is shown in FIG. 3.

비교예Comparative example

When fabricating the first and second laminates, devices were fabricated in the same manner, except that only one rim of each of the WO ₃ layer and the PB layer was etched and a nickel tape was attached to only one etched edge. The measurement result of discoloration time is shown in FIG.

Claims

An electrode layer; An electrochromic layer positioned on the electrode layer; And a conductive band positioned on the electrode layer and having a closed ring shape.
The electrochromic device of claim 1, wherein the conductive band is in contact with the electrochromic layer.
The electrochromic device of claim 2, wherein the conductive band surrounds a side surface of the electrochromic layer.
The electrochromic device of claim 3, wherein the electrode layer has an area equal to or greater than the sum of an area of the conductive band and an area of the electrochromic layer.
The electrochromic device of claim 4, wherein each of the electrochromic layer and the conductive strip is in contact with the same surface of the electrode layer.
The electrochromic device of claim 5, wherein the conductive band has a thickness greater than or equal to the electrochromic layer.
The electrochromic device of claim 2, wherein the conductive band is positioned between the electrode layer and the electrochromic layer or on an opposite side of one surface of the electrochromic layer facing the electrode layer.
The electrochromic device of claim 7, wherein the electrochromic layer has an area equal to or greater than the sum of an area of the conductive band and an inner area of the closed ring of the conductive band.
The electrochromic device of claim 2, further comprising an electrolyte layer on one surface opposite to one surface of the electrochromic layer facing the electrode layer.
The electrochromic device of claim 9, wherein the electrolyte layer comprises a gel polymer electrolyte.
The electrochromic device of claim 1, further comprising a counter electrode layer on a surface opposite to one surface of the electrolyte layer facing the electrochromic layer.
The electrochromic device of claim 11, further comprising an ion storage layer between the counter electrode layer and the electrolyte layer.
The electrochromic device of claim 12, further comprising a second conductive band in contact with the ion storage layer and having a closed ring shape.
The electrochromic device of claim 13, wherein the second conductive band surrounds a side surface of the ion storage layer.
The electrochromic device of claim 14, wherein the counter electrode layer has an area equal to or greater than the sum of the area of the second conductive band and the area of the ion storage layer.
The electrochromic device of claim 15, wherein each of the ion storage layer and the second conductive band contacts the same surface of the counter electrode layer.
The electrochromic device of claim 16, wherein the second conductive band has a thickness greater than or equal to the thickness of the ion storage layer.
The electrochromic device of claim 13, wherein the second conductive band is positioned between the counter electrode layer and the ion storage layer or on an opposite side of one surface of the ion storage layer facing the counter electrode layer.
19. The electrochromic device of claim 18, wherein the ion storage layer has an area equal to or greater than the sum of the area of the second conductive band and the area of the closed ring of the second conductive band.
The said electroconductive strip and a 2nd electroconductive strip of Claim 1 or 13 are nickel (Ni), aluminum (Al), silver (Ag), copper (Cu), zinc (Zn), and gold. Electrochromic device comprising (Au), palladium (Pd), platinum (Pt) or alloys thereof.