WO2018181272A1 - Coated tool and cutting tool - Google Patents

Coated tool and cutting tool Download PDF

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Publication number
WO2018181272A1
WO2018181272A1 PCT/JP2018/012348 JP2018012348W WO2018181272A1 WO 2018181272 A1 WO2018181272 A1 WO 2018181272A1 JP 2018012348 W JP2018012348 W JP 2018012348W WO 2018181272 A1 WO2018181272 A1 WO 2018181272A1
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WO
WIPO (PCT)
Prior art keywords
coating layer
particles
phase
recess
substrate
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PCT/JP2018/012348
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French (fr)
Japanese (ja)
Inventor
忠 勝間
芳和 児玉
Original Assignee
京セラ株式会社
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Publication date
Application filed by 京セラ株式会社 filed Critical 京セラ株式会社
Priority to JP2019509865A priority Critical patent/JPWO2018181272A1/en
Publication of WO2018181272A1 publication Critical patent/WO2018181272A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23BTURNING; BORING
    • B23B27/00Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
    • B23B27/14Cutting tools of which the bits or tips or cutting inserts are of special material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides

Definitions

  • This aspect relates to a coated tool used in cutting.
  • a coated tool used for cutting such as turning and turning
  • a coated tool described in Patent Document 1 contains tungsten carbide (WC) as a hard phase component and titanium (Ti) or the like on the surface of a substrate containing 5 to 15% by mass of cobalt (Co) as a binder phase component.
  • the coating layer to be contained is formed by vapor deposition.
  • coated tools are required to have good bondability of the coating layer to the substrate and good durability of the substrate.
  • the toughness may be improved by increasing the amount of the binder phase by increasing the content of cobalt or cobalt in the substrate.
  • the content of the binder phase such as cobalt or nickel in the substrate is increased, the content of tungsten carbide is relatively decreased, so that plastic deformation is likely to occur and uneven wear is likely to proceed. Durability may be reduced.
  • a coated tool includes a base having a first phase containing a plurality of tungsten carbide particles and a second phase containing at least one of cobalt and nickel, and a coating layer positioned on the base. ing.
  • the plurality of tungsten carbide particles include a plurality of first particles in contact with the coating layer and a plurality of second particles located away from the coating layer. At least one of the plurality of first particles has a recess on the surface facing the coating layer, and the second phase is located in the recess.
  • FIG. 2 is a cross-sectional view taken along the line AA of the coated tool shown in FIG.
  • FIG. 3 is an enlarged view of the vicinity of a boundary between a substrate and a coating layer in the coating tool illustrated in FIG. 2. It is an enlarged view in area
  • the coated tool 1 of one embodiment will be described in detail with reference to the drawings.
  • each drawing referred to below shows only a main member necessary for explaining the present embodiment in a simplified manner for convenience of explanation. Therefore, the coating tool may include any component not shown in each of the referenced drawings.
  • the dimension of the member in each figure does not represent the dimension of an actual structural member, the dimension ratio of each member, etc. faithfully.
  • the coated tool 1 of this embodiment includes a base 3 and a coating layer 5.
  • the first surface 7 upper surface in FIG. 2
  • the second surface 9 side surface in FIG. 2 adjacent to the first surface 7, and the first surface 7 and the second surface 9 intersect.
  • a cutting edge 11 located on at least a part of the ridgeline.
  • the base 3 in the present embodiment has a quadrangular plate shape as shown in FIG. 1, and the first surface 7 has a quadrangular shape. Therefore, the number of the second surfaces 9 is four.
  • the shape of the substrate 3 is not limited to a square plate shape, and for example, the first surface 7 may be a triangle, a pentagon, a hexagon, or a circle.
  • substrate 3 is not limited to plate shape, For example, column shape may be sufficient.
  • the cutting edge 11 is a part used when cutting a work material in order to manufacture a cut product.
  • the cutting edge 11 may be located on the entire outer periphery of the first surface 7 of the base 3.
  • the covering tool 1 is not limited to such a configuration.
  • the cutting blade 11 may be located only on one side of the quadrangular first surface 7 or on a part of the one side.
  • the coated tool 1 according to the present embodiment includes the coating layer 5 positioned on the base 3, the cutting blade 11 itself does not necessarily need to contact the work material in the cutting process. .
  • the first surface 7 in the present embodiment has a rake face region at least partially.
  • the first region 13 along the cutting edge 11 on the first surface 7 is at least a rake surface region.
  • the second surface 9 in the present embodiment has a flank region at least partially.
  • the second region 15 along the cutting edge 11 on the second surface 9 is at least a flank region. In other words, the cutting edge 11 is located at a portion where the rake face area and the flank face area intersect.
  • the base 3 in the present embodiment contains a first phase 17 containing tungsten carbide (WC) particles, as shown in FIGS.
  • the base 3 has a second phase 19 containing at least one of cobalt (Co) and nickel (Ni).
  • the first phase 17 is a part usually called a hard phase
  • the second phase 19 is a part usually called a binder phase.
  • the second phase 19 has a function of joining the particles constituting the first phase 17 together. Further, the second phase 19 has a function of bonding the particles constituting the first phase 17 and the coating layer 5.
  • the second phase 19 in the present embodiment contains cobalt as a main component.
  • the first phase 17 may contain hard particles composed of other components such as titanium carbide (TiC) and tantalum carbide (TaC) in addition to the tungsten carbide particles.
  • TiC titanium carbide
  • TaC tantalum carbide
  • the first phase 17 in the present embodiment contains tungsten carbide as a main component even if it contains components such as titanium carbide and tantalum carbide.
  • main component means a component having the largest mass% value compared to other components. Therefore, for example, in the first phase 17, the value of mass% of tungsten carbide is the largest.
  • the covering layer 5 is located on the base 3 and covers the surface of the base 3. Note that the coating layer 5 does not need to cover the entire surface of the substrate 3, and a part of the surface of the substrate 3 may be exposed. In the present embodiment, at least the first surface 7 and the second surface 9 of the base 3 are covered with the coating layer 5.
  • the coating layer 5 is provided to improve characteristics such as wear resistance and chipping resistance of the coated tool 1 in cutting.
  • the plurality of tungsten carbide particles contained in the first phase 17 of the substrate 3 in the present embodiment are separated from the plurality of first particles 17 a located on the surface of the substrate 3 and in contact with the coating layer 5, and the coating layer 5. It has the some 2nd particle
  • the second phase 19 which is a binder phase, is located in the recess 23, the bondability of the coating layer 5 to the substrate 3 can be improved.
  • the second phase 19 positioned in the recess 23 is separated from the second phase 19 positioned between the plurality of second particles 17b positioned away from the coating layer 5.
  • the second phase 19 located in the recess 23 is surrounded by the first particles 17 a and the coating layer 5.
  • the coated tool 1 of the present embodiment can improve the bondability of the coating layer 5 to the base 3 by the second phase 19 located in the recess 23, the content ratio of the first phase 17 in the base 3 It is possible to increase. Therefore, since the content ratio of the first phase 17 is high as compared with the configuration in which the bondability is increased by simply increasing the content ratio of the second phase 19, the durability of the base body 3 can be increased.
  • the second phase 19 may be located in the recess 23, but as shown in FIG. 5, in addition to the second phase 19, third particles 17c that are tungsten carbide particles may be mixed. .
  • the size of the substrate 3 is not particularly limited.
  • the length of one side of the first surface 7 is set to about 3 to 20 mm.
  • the height from the first surface 7 to the surface (the lower surface in FIG. 2) located on the opposite side of the first surface 7 is set to about 1 to 20 mm, for example.
  • the substrate 3 in the present embodiment contains the first phase 17 and the second phase 19.
  • the content ratio of these phases is not limited to a specific value.
  • the content ratio of the first phase 17 can be set to about 60 to 95% by mass.
  • the content ratio of the first phase 17 is 60% by mass or more, since the content ratio of the first phase 17 that is a hard phase is high, the hardness of the substrate 3 is increased.
  • the toughness of the substrate 3 is enhanced because the content ratio of the second phase 19 that is the binder phase is high.
  • the sizes of the first particles 17a and the second particles 17b contained in the first phase 17 are not limited to specific values. For example, it can be set to about 0.1 to 5 ⁇ m.
  • the average particle diameter of the first particles 17a is smaller than the average particle diameter of the second particles 17b in the cross section intersecting the substrate 3 and the coating layer 5, the bondability between the substrate 3 and the coating layer 5 is high. This is because when the average particle diameter of the first particles 17a in contact with the coating layer 5 is relatively small, the number of locations where the second phase 19 and the coating layer 5 are joined increases. This is because the variation in bonding strength at the interface is small.
  • the size of the concave portion 23 located on the facing surface 21 facing the coating layer 5 in the first particle 17a is not particularly limited.
  • the depth of the recess 23 is 1 ⁇ 2 or less of the particle size in the thickness direction of the coating layer 5 in the first particle 17a in which the recess 23 is formed, the first particle in which the recess 23 is formed.
  • the strength of 17a is difficult to decrease. Therefore, the bondability between the substrate 3 and the coating layer 5 is high while maintaining the durability of the substrate 3.
  • the substrate 3 in the present embodiment has a plurality of first particles 17a.
  • the first surface 7 has good flatness. Therefore, even when a load is applied to the plurality of first particles 17a in the direction perpendicular to the first surface 7 during the cutting process, the load is less likely to concentrate on some of the first particles 17a.
  • “on the same plane” does not require that the position is exactly on the same plane. For example, it means that there may be a variation of about 80% of the average particle diameter of the first particles 17a. This variation may be 50% or less of the average particle diameter of the first particles 17a, and may be 10% or less of the average particle diameter of the first particles 17a.
  • the first surface 7 and the second surface 9 of the base 3 are each covered with the coating layer 5. Therefore, the first particles 17 a exist on each of the first surface 7 and the second surface 9. At this time, at least one of the first particles 17 a located on the first surface 7 has a recess 23 on the facing surface 21 facing the coating layer 5, and at least one of the first particles 17 a located on the second surface 9 is covered. You may have the recessed part 23 in the opposing surface 21 which opposes the layer 5. FIG. Further, only the first particles 17 a located on the first surface 7 may have the recesses 23 on the facing surface 21 that faces the coating layer 5.
  • the first surface 7 in the present embodiment has a rake surface region and the second surface 9 has a flank region, the first surface 7 is larger than the second surface 9 during cutting. Easy to apply cutting load. Therefore, when the ratio of the first particles 17a located on the first surface 7 having the recesses 23 is higher than the ratio of the first particles 17a located on the second surface 9 having the recesses 23, particularly the first surface. When only the first particles 17 a located at 7 have the recesses 23, it is possible to improve the bondability between the base 3 and the coating layer 5 on the first surface 7 where a large cutting load is easily applied.
  • the first surface 7 is cut during the cutting process. It is difficult for the load to concentrate on the first particles 17a located at the positions. Therefore, the bondability of the coating layer 5 to the substrate 3 is further improved.
  • the surface of the second phase existing in the recess 23 is handled as the surface of the substrate 3 when measuring the ten-point average roughness.
  • the size of the recess 23 in the first particle 17a can be set, for example, such that the width of the recess 23 is about 0.05 to 0.5 ⁇ m. Further, the depth of the recess 23 can be set to about 0.03 to 0.3 ⁇ m.
  • the width of the recess 23 means the width of the opening in the direction along the first surface 7, and the depth of the recess 23 is a direction orthogonal to the depth of the recess 23. This means the width from the opening at the bottom to the bottom of the recess 23.
  • the width of the recess 23 is 0.05 ⁇ m or more, the contact area between the second phase 19 located in the recess 23 and the coating layer 5 is large.
  • grains 17a are cracked from the recessed part 23 as the width
  • the contact area of the depth direction with the 2nd phase 19 located in the recessed part 23 and the recessed part 23 becomes large as the depth of the recessed part 23 is 0.03 micrometer or more, it is the 2nd phase located in the recessed part 23. 19 and the recess 23 are highly bondable.
  • the depth of the recessed part 23 shall be 0.3 micrometer or less, it can suppress that the 1st particle
  • the number of recesses 23 per first particle 17a can be set to, for example, about 1 to 5 in a cross-sectional view.
  • the number of the recesses 23 is one or more, the amount of the second phase 19 positioned in the recesses 23 can be increased to improve the bondability between the substrate 3 and the coating layer 5.
  • the number of the recessed parts 23 is five or less, it can be avoided that the volume of the first particles 17a becomes too small. Therefore, the durability of the first particles 17a can be increased.
  • the coating layer 5 in the coated tool 1 of the present embodiment can be used, for example, to increase the wear resistance or corrosion resistance of the coated tool 1.
  • the material of the covering layer 5 include titanium carbide, nitride, oxide, carbonate, nitride oxide, carbonitride, and carbonitride.
  • aluminum oxide (Al 2 O 3 ) can be used as the material of the covering layer 5, for example.
  • the coating layer 5 may contain only one of the above materials, or may contain a plurality. Moreover, the coating layer 5 may be comprised by only one layer, and the structure by which the several layer was laminated
  • the coating layer 5 is located on the base 3 and includes a first layer 25 containing titanium carbonitride (TiCN), and a second layer 27 containing aluminum oxide located on the first layer 25. And may be provided.
  • the covering layer 5 can be positioned on the substrate 3 by using a chemical vapor deposition (CVD) method or a physical vapor deposition (PVD) method.
  • CVD chemical vapor deposition
  • PVD physical vapor deposition
  • the boundary between the above layers and regions is, for example, an electron micrograph (scanning electron microscope (SEM) photo or transmission electron microscope). It can be specified by observing a microscope (TEM: TransmissionTransElectron Microscope).
  • the elemental analysis of the coating layer 5 and the substrate 3 is evaluated by, for example, Auger analysis or SEM-EDX method using an energy dispersive X-ray spectrometer (EDX) attached to a scanning electron microscope (SEM). Can do. Moreover, confirmation of the contained component which comprises each site
  • Auger analysis or SEM-EDX method using an energy dispersive X-ray spectrometer (EDX) attached to a scanning electron microscope (SEM). Can do.
  • part can be evaluated by using X-ray diffraction (XRD) method, for example.
  • XRD X-ray diffraction
  • the second phase 19 contains cobalt as described above, but at this time, the second phase 19 may contain a component constituting the coating layer 5.
  • the second phase 19 may contain at least one of nitrogen (N) and titanium.
  • N nitrogen
  • the 2nd phase 19 contains the component which comprises the coating layer 5, the joining property of the 2nd phase 19 and the coating layer 5 is improved.
  • the content ratio of cobalt in the second phase 19 is higher than the content ratio of the components constituting the coating layer 5. Is desirable. In addition, what is necessary is just to evaluate said content ratio by the mass%.
  • the content of the component constituting the coating layer 5 in the first part is the coating in the second part.
  • the content of the component constituting the layer 5 may be larger.
  • substrate 3 can be raised, improving the adhesiveness of the coating layer 5 and the base
  • the first reason is that, in the first portion of the second phase 19, the bondability between the first phase 17 and the coating layer 5 existing in the recess 23 is enhanced.
  • the second reason is that, in the second portion of the second phase 19, the bonding properties between the adjacent first phases 17 through the second phase 19 are maintained.
  • the comparison between the content of the component constituting the coating layer 5 in the first part of the second phase 19 and the content of the component constituting the coating layer 5 in the second part of the second phase 19 is, for example,
  • the components constituting the coating layer 5 are each composed of a portion of the second phase 19 at 10 or more positions located in the recess 23 and a portion of the second phase 19 located at 10 or more locations located in the region excluding the recess 23. What is necessary is just to measure content and compare the average value in these parts.
  • the base 3 in the present embodiment has a first surface 7 and a through hole 29 that penetrates a surface located on the opposite side of the first surface 7.
  • the through hole 29 can be used for inserting a fixing member for fixing the coated tool 1 to the holder.
  • the fixing member include a screw and a clamp member.
  • a metal powder, a carbon powder, etc. are appropriately added and mixed to an inorganic powder selected from carbides, nitrides, carbonitrides, oxides, and the like that can form a hard alloy to be the base 3 by firing. Is made.
  • the mixed powder is formed into a predetermined tool shape by using a known forming method to produce a formed body. Examples of the molding method include press molding, cast molding, extrusion molding, and cold isostatic pressing.
  • the base body 3 is produced by firing the molded body in a vacuum or in a non-oxidizing atmosphere.
  • the first surface The concave portion 23 can be formed on the facing surface 21 facing the coating layer 5 in at least one of the first particles 17 a located at 7.
  • the recesses 23 can be easily formed.
  • the recesses 23 may be formed in the second phase 19 during molding, but the recesses 23 formed in the second phase 19 are almost eliminated by firing.
  • the recesses 23 may be formed in the first particles 17a by subjecting the substrate surface to grinding and polishing. First, in order to provide the recessed part 23 in the surface of the base
  • cobalt, nickel, or the like that was a part of the base body 3 enters the recess 23 formed by grinding.
  • the third particles 17 c made of tungsten carbide particles together with cobalt and nickel enter the recess 23.
  • nickel powder or cobalt powder may be rubbed against the surface of the substrate 3 so that nickel or cobalt exists in the recess 23.
  • the coating layer 5 is formed on the surface of the substrate 3 by chemical vapor deposition (CVD).
  • CVD chemical vapor deposition
  • a first mixed gas is prepared by mixing hydrogen gas with 0.5 to 10% by volume titanium tetrachloride gas, 5 to 60% by volume nitrogen gas, and 0.1 to 3% by volume acetonitrile gas. To do.
  • the first mixed gas is introduced into the chamber to form a first layer 25 containing MT-titanium carbonitride.
  • a second layer 27 containing aluminum oxide is formed.
  • the second mixed gas is introduced into the chamber, and the second layer 27 is formed.
  • said manufacturing method is an example of the method of manufacturing the coating tool 1 of this embodiment. Therefore, it goes without saying that the coated tool 1 of the present embodiment is not limited to the one produced by the above manufacturing method.
  • a third layer (not shown) may be separately formed on the second layer 27.
  • the cutting tool 101 is a rod-like body that extends from a first end (upper end in FIG. 6) toward a second end (lower end in FIG. 6).
  • a holder 105 having a pocket 103 located on the side of the arm and a covering tool 1 located in the pocket 103.
  • the covering tool 1 is mounted so that at least a part of a portion used as a cutting edge on the ridge line protrudes from the tip of the holder 105.
  • the pocket 103 is a part to which the covering tool 1 is attached, and has a seating surface parallel to the lower surface of the holder 105 and a restraining side surface inclined with respect to the seating surface. Further, the pocket 103 is opened on the first end side of the holder 105.
  • the covering tool 1 is located in the pocket 103. At this time, the lower surface of the covering tool 1 may be in direct contact with the pocket 103, or a sheet may be sandwiched between the covering tool 1 and the pocket 103.
  • the covering tool 1 is mounted such that a portion used as a cutting edge on the ridge line protrudes outward from the holder 105.
  • the coated tool 1 is attached to the holder 105 with screws 107. That is, the screw 107 is inserted into the through-hole of the covering tool 1, the tip of the screw 107 is inserted into a screw hole (not shown) formed in the pocket 103, and the screw portions are screwed together, thereby covering the covering tool 1. Is mounted on the holder 105.
  • steel, cast iron or the like can be used.
  • steel having high toughness among these members it is preferable to use steel having high toughness among these members.
  • the cutting tool used for so-called turning is illustrated as the coated tool 1.
  • the turning process include an inner diameter process, an outer diameter process, and a grooving process.
  • the cutting tool is not limited to that used for turning.

Abstract

A coated tool according to one embodiment of the present invention is provided with: a substrate having a first phase including a plurality of tungsten carbide particles, and a second phase including cobalt and/or nickel; and a coating layer positioned on the substrate. The plurality of tungsten carbide particles include: a plurality of first particles which are in contact with the coating layer; and a plurality of second particles which are positioned away from the coating layer. At least one of the plurality of first particles has a recess provided to the surface facing the coating layer. The second phase is positioned in said recess.

Description

被覆工具及び切削工具Coated tool and cutting tool
 本態様は、切削加工において用いられる被覆工具に関する。 This aspect relates to a coated tool used in cutting.
 旋削加工及び転削加工のような切削加工に用いられる被覆工具としては、例えば特許文献1に記載の被覆工具が知られている。特許文献1に記載の被覆工具は、硬質相成分として炭化タングステン(WC)を含有し、結合相成分としてコバルト(Co)を5~15質量%含有する基体の表面に、チタン(Ti)などを含有する被覆層が蒸着形成された構成となっている。 As a coated tool used for cutting such as turning and turning, for example, a coated tool described in Patent Document 1 is known. The coated tool described in Patent Document 1 contains tungsten carbide (WC) as a hard phase component and titanium (Ti) or the like on the surface of a substrate containing 5 to 15% by mass of cobalt (Co) as a binder phase component. The coating layer to be contained is formed by vapor deposition.
 今般において、被覆工具には、基体に対する被覆層の接合性及び基体の耐久性の両方が良好であることが求められている。基体に対する被覆層の接合性を向上させるためには、基体におけるコバルトやコバルトの含有量を増やすことで、結合相の量を増やして靭性を向上させればよい。しかしながら、基体におけるコバルトやニッケルなどの結合相量の含有量を増やしたときには、相対的に炭化タングステンの含有量が低下するため、塑性変形が起こり易くなって偏摩耗が進行し易くなり、基体の耐久性が低下する場合がある。 In recent years, coated tools are required to have good bondability of the coating layer to the substrate and good durability of the substrate. In order to improve the bondability of the coating layer to the substrate, the toughness may be improved by increasing the amount of the binder phase by increasing the content of cobalt or cobalt in the substrate. However, when the content of the binder phase such as cobalt or nickel in the substrate is increased, the content of tungsten carbide is relatively decreased, so that plastic deformation is likely to occur and uneven wear is likely to proceed. Durability may be reduced.
特開2014-184521号公報JP 2014-184521 A
 一態様に基づく被覆工具は、複数の炭化タングステン粒子を含有する第1相、及びコバルト及びニッケルの少なくとも一方を含有する第2相を有する基体と、該基体の上に位置する被覆層とを備えている。また、前記複数の炭化タングステン粒子は、前記被覆層に接する複数の第1粒子と、前記被覆層から離れて位置する複数の第2粒子とを有する。前記複数の第1粒子の少なくとも1つが、前記被覆層との対向面に凹部を有し、該凹部に前記第2相が位置している。 A coated tool according to an aspect includes a base having a first phase containing a plurality of tungsten carbide particles and a second phase containing at least one of cobalt and nickel, and a coating layer positioned on the base. ing. The plurality of tungsten carbide particles include a plurality of first particles in contact with the coating layer and a plurality of second particles located away from the coating layer. At least one of the plurality of first particles has a recess on the surface facing the coating layer, and the second phase is located in the recess.
一実施形態の被覆工具を示す斜視図である。It is a perspective view showing a covering tool of one embodiment. 図1に示す被覆工具におけるA-A断面の断面図である。FIG. 2 is a cross-sectional view taken along the line AA of the coated tool shown in FIG. 図2に示す被覆工具における基体及び被覆層の境界付近の拡大図である。FIG. 3 is an enlarged view of the vicinity of a boundary between a substrate and a coating layer in the coating tool illustrated in FIG. 2. 図3に示す領域B1における拡大図である。It is an enlarged view in area | region B1 shown in FIG. 図4に示す領域B2における拡大図である。It is an enlarged view in area | region B2 shown in FIG. 一実施形態の切削工具を示す平面図である。It is a top view which shows the cutting tool of one Embodiment. 図6に示す領域B3における拡大図である。It is an enlarged view in area | region B3 shown in FIG.
 以下、一実施形態の被覆工具1について、図面を用いて詳細に説明する。但し、以下で参照する各図は、説明の便宜上、本実施形態を説明する上で必要な主要部材のみを簡略化して示したものである。したがって、被覆工具は、参照する各図に示されていない任意の構成部材を備え得る。また、各図中の部材の寸法は、実際の構成部材の寸法及び各部材の寸法比率等を忠実に表したものではない。 Hereinafter, the coated tool 1 of one embodiment will be described in detail with reference to the drawings. However, each drawing referred to below shows only a main member necessary for explaining the present embodiment in a simplified manner for convenience of explanation. Therefore, the coating tool may include any component not shown in each of the referenced drawings. Moreover, the dimension of the member in each figure does not represent the dimension of an actual structural member, the dimension ratio of each member, etc. faithfully.
 <被覆工具>
 本実施形態の被覆工具1は、図1及び図2に示すように、基体3及び被覆層5を備えている。本実施形態における基体3は、第1面7(図2における上面)と、第1面7と隣り合う第2面9(図2における側面)と、第1面7及び第2面9が交わる稜線の少なくとも一部に位置する切刃11とを有している。
<Coated tool>
As shown in FIGS. 1 and 2, the coated tool 1 of this embodiment includes a base 3 and a coating layer 5. In the substrate 3 in the present embodiment, the first surface 7 (upper surface in FIG. 2), the second surface 9 (side surface in FIG. 2) adjacent to the first surface 7, and the first surface 7 and the second surface 9 intersect. And a cutting edge 11 located on at least a part of the ridgeline.
 本実施形態における基体3は図1に示すように四角板形状であり、第1面7が四角形である。そのため、第2面9の数は4つとなっている。基体3の形状としては、四角板形状に限定されるものではなく、例えば第1面7が、三角形、五角形、六角形又は円形であってもよい。また、基体3は、板形状に限定されるものではなく、例えば柱形状であってもよい。 The base 3 in the present embodiment has a quadrangular plate shape as shown in FIG. 1, and the first surface 7 has a quadrangular shape. Therefore, the number of the second surfaces 9 is four. The shape of the substrate 3 is not limited to a square plate shape, and for example, the first surface 7 may be a triangle, a pentagon, a hexagon, or a circle. Moreover, the base | substrate 3 is not limited to plate shape, For example, column shape may be sufficient.
 切刃11は、切削加工物を製造するため被削材を切削する際に用いられる部位である。基体3における第1面7の外周の全体に切刃11が位置していてもよい。被覆工具1はこのような構成に限定されるものではない。例えば、四角形の第1面7における1辺のみ、或いは、上記の1辺の一部に切刃11が位置していてもよい。なお、本実施形態における被覆工具1が基体3の上に位置する被覆層5を備えていることから明らかであるように、切削加工において必ずしも切刃11自体が被削材に接触する必要はない。 The cutting edge 11 is a part used when cutting a work material in order to manufacture a cut product. The cutting edge 11 may be located on the entire outer periphery of the first surface 7 of the base 3. The covering tool 1 is not limited to such a configuration. For example, the cutting blade 11 may be located only on one side of the quadrangular first surface 7 or on a part of the one side. As apparent from the fact that the coated tool 1 according to the present embodiment includes the coating layer 5 positioned on the base 3, the cutting blade 11 itself does not necessarily need to contact the work material in the cutting process. .
 本実施形態における第1面7は、少なくとも一部にすくい面領域を有している。第1面7における切刃11に沿った第1領域13は少なくともすくい面領域である。また、本実施形態における第2面9は、少なくとも一部に逃げ面領域を有している。第2面9における切刃11に沿った第2領域15は少なくとも逃げ面領域である。言い換えれば、すくい面領域及び逃げ面領域が交差する部分に切刃11が位置している。 The first surface 7 in the present embodiment has a rake face region at least partially. The first region 13 along the cutting edge 11 on the first surface 7 is at least a rake surface region. Further, the second surface 9 in the present embodiment has a flank region at least partially. The second region 15 along the cutting edge 11 on the second surface 9 is at least a flank region. In other words, the cutting edge 11 is located at a portion where the rake face area and the flank face area intersect.
 本実施形態における基体3は、図3及び図4に示すように、炭化タングステン(WC)の粒子を含有する第1相17を含有している。また、基体3は、コバルト(Co)およびニッケル(Ni)の少なくとも一方を含有する第2相19を有している。第1相17は、硬質相と通常呼ばれる部位であり、第2相19は、結合相と通常呼ばれる部位である。第2相19は、第1相17を構成する粒子同士を接合する機能を有する。また、第2相19は、第1相17を構成する粒子と被覆層5とを接合する機能を有している。本実施形態における第2相19は、コバルトを主成分として含有している。 The base 3 in the present embodiment contains a first phase 17 containing tungsten carbide (WC) particles, as shown in FIGS. The base 3 has a second phase 19 containing at least one of cobalt (Co) and nickel (Ni). The first phase 17 is a part usually called a hard phase, and the second phase 19 is a part usually called a binder phase. The second phase 19 has a function of joining the particles constituting the first phase 17 together. Further, the second phase 19 has a function of bonding the particles constituting the first phase 17 and the coating layer 5. The second phase 19 in the present embodiment contains cobalt as a main component.
 なお、第1相17は、炭化タングステンの粒子に加えて、炭化チタン(TiC)及び炭化タンタル(TaC)などの別の成分によって構成される硬質粒子を含有していてもよい。ただし、本実施形態における第1相17は、炭化チタン及び炭化タンタルなどの成分を含有している場合であっても、炭化タングステンを主成分として含有している。 The first phase 17 may contain hard particles composed of other components such as titanium carbide (TiC) and tantalum carbide (TaC) in addition to the tungsten carbide particles. However, the first phase 17 in the present embodiment contains tungsten carbide as a main component even if it contains components such as titanium carbide and tantalum carbide.
 本実施形態において、「主成分」とは、他の成分と比較して質量%の値が最も大きい成分であることを意味している。そのため、例えば、第1相17においては、炭化タングステンの質量%の値が最も大きい。 In the present embodiment, “main component” means a component having the largest mass% value compared to other components. Therefore, for example, in the first phase 17, the value of mass% of tungsten carbide is the largest.
 被覆層5は、基体3の上に位置しており基体3の表面を覆っている。なお、被覆層5は基体3の表面の全てを覆っている必要はなく、基体3の表面の一部が露出していてもよい。本実施形態においては、基体3の少なくとも第1面7及び第2面9が被覆層5によって覆われている。被覆層5は、切削加工における被覆工具1の耐摩耗性及び耐チッピング性などの特性を向上させるために備えられている。 The covering layer 5 is located on the base 3 and covers the surface of the base 3. Note that the coating layer 5 does not need to cover the entire surface of the substrate 3, and a part of the surface of the substrate 3 may be exposed. In the present embodiment, at least the first surface 7 and the second surface 9 of the base 3 are covered with the coating layer 5. The coating layer 5 is provided to improve characteristics such as wear resistance and chipping resistance of the coated tool 1 in cutting.
 本実施形態における基体3の第1相17に含有される複数の炭化タングステンの粒子は、基体3における表面に位置して被覆層5に接する複数の第1粒子17aと、被覆層5から離れて位置する複数の第2粒子17bとを有している。 The plurality of tungsten carbide particles contained in the first phase 17 of the substrate 3 in the present embodiment are separated from the plurality of first particles 17 a located on the surface of the substrate 3 and in contact with the coating layer 5, and the coating layer 5. It has the some 2nd particle | grains 17b located.
 このとき、例えば図5に示すように、複数の第1粒子17aの少なくとも1つが被覆層5との対向面21に凹部23を有しており、この凹部23に第2相19が位置している。凹部23に結合相である第2相19が位置していることから、基体3に対する被覆層5の接合性を良好なものにできる。なお、断面視において、この凹部23に位置する第2相19は、被覆層5から離れて位置する複数の第2粒子17bの間に位置する第2相19とは離間している。言い換えると、凹部23に位置する第2相19は、第1粒子17aと被覆層5に取り囲まれている。 At this time, for example, as shown in FIG. 5, at least one of the plurality of first particles 17 a has a recess 23 on the surface 21 facing the coating layer 5, and the second phase 19 is positioned in the recess 23. Yes. Since the second phase 19, which is a binder phase, is located in the recess 23, the bondability of the coating layer 5 to the substrate 3 can be improved. In the cross-sectional view, the second phase 19 positioned in the recess 23 is separated from the second phase 19 positioned between the plurality of second particles 17b positioned away from the coating layer 5. In other words, the second phase 19 located in the recess 23 is surrounded by the first particles 17 a and the coating layer 5.
 なお、単に基体3における第2相19の含有比率を高めることによっても基体3に対する被覆層5の接合性を良好なものにできるが、第2相19の含有比率を高めれば、その分第1相17の含有比率が低くなり、基体3の耐久性が低くなる。 It should be noted that simply increasing the content ratio of the second phase 19 in the substrate 3 can also improve the bondability of the coating layer 5 to the substrate 3, but if the content ratio of the second phase 19 is increased, the first amount is increased accordingly. The content ratio of the phase 17 is reduced, and the durability of the substrate 3 is reduced.
 これに対し、本実施形態の被覆工具1は、凹部23に位置する第2相19によって基体3に対する被覆層5の接合性を良好なものにできるため、基体3における第1相17の含有比率を高めることが可能である。そのため、単に第2相19の含有比率を高めることによって接合性を高めた構成と比較して、第1相17の含有比率が高いため、基体3の耐久性を高めることができる。 On the other hand, since the coated tool 1 of the present embodiment can improve the bondability of the coating layer 5 to the base 3 by the second phase 19 located in the recess 23, the content ratio of the first phase 17 in the base 3 It is possible to increase. Therefore, since the content ratio of the first phase 17 is high as compared with the configuration in which the bondability is increased by simply increasing the content ratio of the second phase 19, the durability of the base body 3 can be increased.
 また、凹部23には第2相19のみが位置していてもよいが、図5に示すように、第2相19に加えて炭化タングステン粒子である第3粒子17cが混在していてもよい。 In addition, only the second phase 19 may be located in the recess 23, but as shown in FIG. 5, in addition to the second phase 19, third particles 17c that are tungsten carbide particles may be mixed. .
 基体3の大きさは特に限定されるものではないが、例えば、本実施形態においては、第1面7の一辺の長さが3~20mm程度に設定される。また、第1面7から第1面7の反対側に位置する面(図2における下面)までの高さは、例えば1~20mm程度に設定される。 The size of the substrate 3 is not particularly limited. For example, in this embodiment, the length of one side of the first surface 7 is set to about 3 to 20 mm. Further, the height from the first surface 7 to the surface (the lower surface in FIG. 2) located on the opposite side of the first surface 7 is set to about 1 to 20 mm, for example.
 本実施形態における基体3は、第1相17及び第2相19を含有している。これらの相の含有比率は特定の値に限定されるものではない。例えば、第1相17の含有比率は、60~95質量%程度に設定することができる。第1相17の含有比率が60質量%以上である場合には、硬質相である第1相17の含有比率が高いため基体3の硬度が高められる。また、第1相17の含有比率が95質量%以下である場合には、結合相である第2相19の含有比率が高いため基体3の靭性が高められる。 The substrate 3 in the present embodiment contains the first phase 17 and the second phase 19. The content ratio of these phases is not limited to a specific value. For example, the content ratio of the first phase 17 can be set to about 60 to 95% by mass. When the content ratio of the first phase 17 is 60% by mass or more, since the content ratio of the first phase 17 that is a hard phase is high, the hardness of the substrate 3 is increased. In addition, when the content ratio of the first phase 17 is 95% by mass or less, the toughness of the substrate 3 is enhanced because the content ratio of the second phase 19 that is the binder phase is high.
 第1相17に含有される第1粒子17a及び第2粒子17bの大きさは、特定の値に限定されるものではない。例えば、0.1~5μm程度に設定することができる。基体3及び被覆層5と交差する断面において、第1粒子17aの平均粒径が、第2粒子17bの平均粒径よりも小さい場合には、基体3及び被覆層5の接合性が高い。これは、被覆層5に接する第1粒子17aの平均粒径が相対的に小さい場合には、第2相19及び被覆層5が接合する箇所の数が増えるため、基体3及び被覆層5の界面における接合強度のばらつきが小さいからである。 The sizes of the first particles 17a and the second particles 17b contained in the first phase 17 are not limited to specific values. For example, it can be set to about 0.1 to 5 μm. When the average particle diameter of the first particles 17a is smaller than the average particle diameter of the second particles 17b in the cross section intersecting the substrate 3 and the coating layer 5, the bondability between the substrate 3 and the coating layer 5 is high. This is because when the average particle diameter of the first particles 17a in contact with the coating layer 5 is relatively small, the number of locations where the second phase 19 and the coating layer 5 are joined increases. This is because the variation in bonding strength at the interface is small.
 第1粒子17aにおける被覆層5に対向する対向面21に位置する凹部23の大きさは、特に限定されない。凹部23の深さが、凹部23が形成された第1粒子17aにおける被覆層5の厚み方向での粒径に対して1/2以下である場合には、凹部23が形成された第1粒子17aの強度が低下しにくい。そのため、基体3の耐久性を維持しつつ基体3及び被覆層5の接合性が高い。 The size of the concave portion 23 located on the facing surface 21 facing the coating layer 5 in the first particle 17a is not particularly limited. When the depth of the recess 23 is ½ or less of the particle size in the thickness direction of the coating layer 5 in the first particle 17a in which the recess 23 is formed, the first particle in which the recess 23 is formed. The strength of 17a is difficult to decrease. Therefore, the bondability between the substrate 3 and the coating layer 5 is high while maintaining the durability of the substrate 3.
 本実施形態における基体3は複数の第1粒子17aを有している。これらの複数の第1粒子17aのうち基体3の第1面7に位置する粒子のそれぞれにおける被覆層5に対向する対向面21が、同一平面上に位置している場合には、第1面7の平坦性が良好になる。そのため、切削加工時に上記の複数の第1粒子17aに対して第1面7に直交する方向に負荷が加わったとしても、この負荷が一部の第1粒子17aに集中しにくい。 The substrate 3 in the present embodiment has a plurality of first particles 17a. When the opposing surface 21 facing the coating layer 5 in each of the particles positioned on the first surface 7 of the substrate 3 among the plurality of first particles 17a is positioned on the same plane, the first surface 7 has good flatness. Therefore, even when a load is applied to the plurality of first particles 17a in the direction perpendicular to the first surface 7 during the cutting process, the load is less likely to concentrate on some of the first particles 17a.
 これにより、被覆層5が基体3から剥離するおそれが小さくなり、被覆層5の基体3に対する接合性が良好になる。なお、上記の「同一平面上」とは、厳密に同一平面上に位置することを要求するものではない。例えば、第1粒子17aの平均粒径の80%程度のばらつきがあってもよいことを意味している。このばらつきは、第1粒子17aの平均粒径の50%以下としてもよく、さらに第1粒子17aの平均粒径の10%以下としてもよい。 Thereby, the possibility that the coating layer 5 is peeled off from the substrate 3 is reduced, and the bonding property of the coating layer 5 to the substrate 3 is improved. Note that “on the same plane” does not require that the position is exactly on the same plane. For example, it means that there may be a variation of about 80% of the average particle diameter of the first particles 17a. This variation may be 50% or less of the average particle diameter of the first particles 17a, and may be 10% or less of the average particle diameter of the first particles 17a.
 また、図5に示すように、被覆層5の一部が凹部23に向かって突出している場合においては、被覆層5に対して第1面7に平行な方向に力が加わった際に上記の突出する部分が凹部23に受け止められるため、被覆層5の剥離に対する物理的な抑止力となる。 Further, as shown in FIG. 5, when a part of the coating layer 5 protrudes toward the recess 23, the force is applied to the coating layer 5 in a direction parallel to the first surface 7. Since the protruding portion is received by the concave portion 23, it becomes a physical deterrent against peeling of the coating layer 5.
 本実施形態の被覆工具1においては、基体3における第1面7及び第2面9がそれぞれ被覆層5によって覆われている。そのため、第1面7及び第2面9のそれぞれに第1粒子17aが存在している。このとき、第1面7に位置する第1粒子17aの少なくとも1つが被覆層5に対向する対向面21に凹部23を有するとともに、第2面9に位置する第1粒子17aの少なくとも1つが被覆層5に対向する対向面21に凹部23を有していてもよい。また、第1面7に位置する第1粒子17aのみが被覆層5に対向する対向面21に凹部23を有していてもよい。 In the coated tool 1 of the present embodiment, the first surface 7 and the second surface 9 of the base 3 are each covered with the coating layer 5. Therefore, the first particles 17 a exist on each of the first surface 7 and the second surface 9. At this time, at least one of the first particles 17 a located on the first surface 7 has a recess 23 on the facing surface 21 facing the coating layer 5, and at least one of the first particles 17 a located on the second surface 9 is covered. You may have the recessed part 23 in the opposing surface 21 which opposes the layer 5. FIG. Further, only the first particles 17 a located on the first surface 7 may have the recesses 23 on the facing surface 21 that faces the coating layer 5.
 本実施形態における第1面7がすくい面領域を有するとともに、第2面9が逃げ面領域を有していることから、第2面9と比較して第1面7には切削加工時に大きな切削負荷が加わり易い。そのため、第1面7に位置する第1粒子17aにおける凹部23を有するものの比率が、第2面9に位置する第1粒子17aにおける凹部23を有するものの比率よりも高い場合、特に、第1面7に位置する第1粒子17aのみが凹部23を有している場合には、大きな切削負荷が加わり易い第1面7における基体3と被覆層5の接合性を高めることができる。 Since the first surface 7 in the present embodiment has a rake surface region and the second surface 9 has a flank region, the first surface 7 is larger than the second surface 9 during cutting. Easy to apply cutting load. Therefore, when the ratio of the first particles 17a located on the first surface 7 having the recesses 23 is higher than the ratio of the first particles 17a located on the second surface 9 having the recesses 23, particularly the first surface. When only the first particles 17 a located at 7 have the recesses 23, it is possible to improve the bondability between the base 3 and the coating layer 5 on the first surface 7 where a large cutting load is easily applied.
 このとき、基体3及び被覆層5と交差する断面において、第1面7の十点平均粗さが、第2面9の十点平均粗さよりも小さい場合には、切削加工時に第1面7に位置する第1粒子17aに負荷が集中しにくい。そのため、被覆層5の基体3に対する接合性がさらに良好になる。なお、基体3及び被覆層5と交差する断面において、十点平均粗さを測定する際には、凹部23に存在する第2相の表面は、基体3の表面として取り扱う。 At this time, if the ten-point average roughness of the first surface 7 is smaller than the ten-point average roughness of the second surface 9 in the cross section intersecting the base 3 and the coating layer 5, the first surface 7 is cut during the cutting process. It is difficult for the load to concentrate on the first particles 17a located at the positions. Therefore, the bondability of the coating layer 5 to the substrate 3 is further improved. In the cross section intersecting with the substrate 3 and the coating layer 5, the surface of the second phase existing in the recess 23 is handled as the surface of the substrate 3 when measuring the ten-point average roughness.
 第1粒子17aにおける凹部23の大きさは例えば、凹部23の幅を0.05~0.5μm程度に設定できる。また、凹部23の深さを0.03~0.3μm程度に設定できる。ここで、凹部23の幅とは第1面7に沿った方向での開口部の幅を意味しており、凹部23の深さとは、凹部23の深さとは第1面7に直交する方向での開口部から凹部23の底までの幅を意味している。凹部23の幅が0.05μm以上であると、凹部23に位置する第2相19と被覆層5との接触面積が大きい。また、凹部23の幅が0.5μm以下であると、凹部23を起点として第1粒子17aが割れてしまうことを抑制できる。また、凹部23の深さが0.03μm以上であると、凹部23に位置する第2相19と、凹部23との深さ方向の接触面積が大きくなるため、凹部23に位置する第2相19と、凹部23との接合性が高い。また、凹部23の深さを0.3μm以下とすると、第1粒子17aが割れてしまうことを抑制できる。 The size of the recess 23 in the first particle 17a can be set, for example, such that the width of the recess 23 is about 0.05 to 0.5 μm. Further, the depth of the recess 23 can be set to about 0.03 to 0.3 μm. Here, the width of the recess 23 means the width of the opening in the direction along the first surface 7, and the depth of the recess 23 is a direction orthogonal to the depth of the recess 23. This means the width from the opening at the bottom to the bottom of the recess 23. When the width of the recess 23 is 0.05 μm or more, the contact area between the second phase 19 located in the recess 23 and the coating layer 5 is large. Moreover, it can suppress that the 1st particle | grains 17a are cracked from the recessed part 23 as the width | variety of the recessed part 23 is 0.5 micrometer or less. Moreover, since the contact area of the depth direction with the 2nd phase 19 located in the recessed part 23 and the recessed part 23 becomes large as the depth of the recessed part 23 is 0.03 micrometer or more, it is the 2nd phase located in the recessed part 23. 19 and the recess 23 are highly bondable. Moreover, when the depth of the recessed part 23 shall be 0.3 micrometer or less, it can suppress that the 1st particle | grains 17a break.
 第1粒子17a1つあたりの凹部23の数は、断面視において、例えば1~5個程度に設定できる。凹部23の数が1つ以上である場合には、凹部23に位置する第2相19の量を増やして基体3及び被覆層5の接合性を高めることができる。また、凹部23の数が5つ以下である場合には第1粒子17aの体積が小さくなり過ぎることが避けられる。そのため、第1粒子17aの耐久性を高めることができる。 The number of recesses 23 per first particle 17a can be set to, for example, about 1 to 5 in a cross-sectional view. When the number of the recesses 23 is one or more, the amount of the second phase 19 positioned in the recesses 23 can be increased to improve the bondability between the substrate 3 and the coating layer 5. Moreover, when the number of the recessed parts 23 is five or less, it can be avoided that the volume of the first particles 17a becomes too small. Therefore, the durability of the first particles 17a can be increased.
 本実施形態の被覆工具1における被覆層5は、例えば、被覆工具1の耐摩耗性或いは耐腐食性を高める為に用いることが可能である。被覆層5の材質としては、例えば、チタンの炭化物、窒化物、酸化物、炭酸化物、窒酸化物、炭窒化物及び炭窒酸化物などが挙げられる。また、被覆層5の材質として、例えば、酸化アルミニウム(Al)を用いることも可能である。被覆層5は、上記の材質のうち1つのみを含有していてもよく、複数を含有していてもよい。また、被覆層5は、1つのみの層によって構成されていてもよく、複数の層が積層された構成であってもよい。 The coating layer 5 in the coated tool 1 of the present embodiment can be used, for example, to increase the wear resistance or corrosion resistance of the coated tool 1. Examples of the material of the covering layer 5 include titanium carbide, nitride, oxide, carbonate, nitride oxide, carbonitride, and carbonitride. Further, as the material of the covering layer 5, for example, aluminum oxide (Al 2 O 3 ) can be used. The coating layer 5 may contain only one of the above materials, or may contain a plurality. Moreover, the coating layer 5 may be comprised by only one layer, and the structure by which the several layer was laminated | stacked may be sufficient.
 例えば、被覆層5が、基体3の上に位置して炭窒化チタン(TiCN)を含有する第1層25と、この第1層25の上に位置して酸化アルミニウムを含有する第2層27とを備えていてもよい。被覆層5は、化学蒸着(CVD)法又は物理蒸着(PVD)法を用いることによって、基体3の上に位置させることが可能である。 For example, the coating layer 5 is located on the base 3 and includes a first layer 25 containing titanium carbonitride (TiCN), and a second layer 27 containing aluminum oxide located on the first layer 25. And may be provided. The covering layer 5 can be positioned on the substrate 3 by using a chemical vapor deposition (CVD) method or a physical vapor deposition (PVD) method.
 なお、被覆層5が複数の層が積層された構成である場合には、上記の層及び領域の境界は、例えば、電子顕微鏡写真(走査型電子顕微鏡(SEM:Scanning Electron Microscope)写真又は透過電子顕微鏡(TEM:Transmission Electron Microscope)写真)を観察することにより、特定することが可能である。 In the case where the coating layer 5 has a configuration in which a plurality of layers are laminated, the boundary between the above layers and regions is, for example, an electron micrograph (scanning electron microscope (SEM) photo or transmission electron microscope). It can be specified by observing a microscope (TEM: TransmissionTransElectron Microscope).
 また、被覆層5及び基体3を構成する元素分析は、例えばオージェ分析又は走査型電子顕微鏡(SEM)に付属するエネルギー分散型X線分光器(EDX)を用いたSEM-EDX法によって評価することができる。また、各部位を構成する含有成分の確認は、例えばX線回折(XRD)法を用いることで評価できる。 The elemental analysis of the coating layer 5 and the substrate 3 is evaluated by, for example, Auger analysis or SEM-EDX method using an energy dispersive X-ray spectrometer (EDX) attached to a scanning electron microscope (SEM). Can do. Moreover, confirmation of the contained component which comprises each site | part can be evaluated by using X-ray diffraction (XRD) method, for example.
 また、第2相19は、上記の通りコバルトを含有しているが、このとき、被覆層5を構成する成分を含有していてもよい。例えば、被覆層5が窒化チタンを含有している場合には、第2相19が窒素(N)及びチタンの少なくとも一方を含有していてもよい。第2相19が被覆層5を構成する成分を含有している場合には、第2相19及び被覆層5の接合性が高められる。 Further, the second phase 19 contains cobalt as described above, but at this time, the second phase 19 may contain a component constituting the coating layer 5. For example, when the coating layer 5 contains titanium nitride, the second phase 19 may contain at least one of nitrogen (N) and titanium. When the 2nd phase 19 contains the component which comprises the coating layer 5, the joining property of the 2nd phase 19 and the coating layer 5 is improved.
 このとき、第2相19を介して隣り合う第1相17同士の接合性を高めるためには、第2相19におけるコバルトの含有比率が被覆層5を構成する成分の含有比率よりも高いことが望ましい。なお、上記の含有比率は質量%によって評価すればよい。 At this time, in order to improve the bondability between the first phases 17 adjacent via the second phase 19, the content ratio of cobalt in the second phase 19 is higher than the content ratio of the components constituting the coating layer 5. Is desirable. In addition, what is necessary is just to evaluate said content ratio by the mass%.
 特に、第2相19のうち、凹部23内を第1部位、凹部23外を第2部位としたときに、第1部位における被覆層5を構成する成分の含有量が、第2部位における被覆層5を構成する成分の含有量よりも多くてもよい。このような構成を有する場合には、以下の理由により、被覆層5及び基体3の接合性を高めつつ基体3の強度を高めることができる。第1の理由は、第2相19のうち第1部位において、この凹部23に存在する第1相17及び被覆層5の接合性が高められることである。また、第2の理由は、第2相19のうち第2部位では、第2相19を介して隣り合う第1相17同士の接合性が維持されることである。 Particularly, in the second phase 19, when the inside of the recess 23 is the first part and the outside of the recess 23 is the second part, the content of the component constituting the coating layer 5 in the first part is the coating in the second part. The content of the component constituting the layer 5 may be larger. When it has such a structure, the intensity | strength of the base | substrate 3 can be raised, improving the adhesiveness of the coating layer 5 and the base | substrate 3 for the following reasons. The first reason is that, in the first portion of the second phase 19, the bondability between the first phase 17 and the coating layer 5 existing in the recess 23 is enhanced. The second reason is that, in the second portion of the second phase 19, the bonding properties between the adjacent first phases 17 through the second phase 19 are maintained.
 なお、第2相19のうち第1部位における被覆層5を構成する成分の含有量と、第2相19のうち第2部位における被覆層5を構成する成分の含有量との比較は、例えば、第2相19のうち凹部23に位置する10箇所以上における部分と、第2相19のうち凹部23を除く領域に位置する10箇所以上における部分とで、それぞれ被覆層5を構成する成分の含有量を測定し、これらの部分での平均値を比較すればよい。 The comparison between the content of the component constituting the coating layer 5 in the first part of the second phase 19 and the content of the component constituting the coating layer 5 in the second part of the second phase 19 is, for example, The components constituting the coating layer 5 are each composed of a portion of the second phase 19 at 10 or more positions located in the recess 23 and a portion of the second phase 19 located at 10 or more locations located in the region excluding the recess 23. What is necessary is just to measure content and compare the average value in these parts.
 本実施形態における基体3は、第1面7及び第1面7の反対側に位置する面を貫通する貫通孔29を有している。貫通孔29は、被覆工具1をホルダに固定するための固定部材を挿入するために用いることができる。固定部材としては、例えばネジ及びクランプ部材が挙げられる。 The base 3 in the present embodiment has a first surface 7 and a through hole 29 that penetrates a surface located on the opposite side of the first surface 7. The through hole 29 can be used for inserting a fixing member for fixing the coated tool 1 to the holder. Examples of the fixing member include a screw and a clamp member.
 <製造方法>
 次に、本実施形態に係る被覆工具1の製造方法について説明する。
<Manufacturing method>
Next, the manufacturing method of the coated tool 1 which concerns on this embodiment is demonstrated.
 まず、基体3となる硬質合金を焼成によって形成しうる炭化物、窒化物、炭窒化物及び酸化物などから選択される無機物粉末に、金属粉末、カーボン粉末などを適宜添加及び混合して、混合粉末を作製する。次に、この混合粉末を公知の成形方法を用いて所定の工具形状に成形することによって成形体を作製する。成形方法としては、例えば、プレス成形、鋳込成形、押出成形及び冷間静水圧プレス成形などが挙げられる。上記の成形体を、真空中又は非酸化性雰囲気中にて焼成することによって基体3を作製する。 First, a metal powder, a carbon powder, etc. are appropriately added and mixed to an inorganic powder selected from carbides, nitrides, carbonitrides, oxides, and the like that can form a hard alloy to be the base 3 by firing. Is made. Next, the mixed powder is formed into a predetermined tool shape by using a known forming method to produce a formed body. Examples of the molding method include press molding, cast molding, extrusion molding, and cold isostatic pressing. The base body 3 is produced by firing the molded body in a vacuum or in a non-oxidizing atmosphere.
 このとき、例えば、基体3を成形するための金型のうち、第1面7に当接する部分の表面粗さを第2面9に当接する部分の表面粗さよりも大きくすることによって第1面7に位置する第1粒子17aの少なくとも1つにおける被覆層5に対向する対向面21に凹部23を形成することができる。この金型の表面に、例えば、ダイヤモンドの被覆膜を設けておくと、凹部23を形成しやすい。なお、第1粒子17aに加えて第2相19にも成形時に凹部23が形成される場合があるが、第2相19に形成される凹部23は焼成によってほぼ無くなる。 At this time, for example, by making the surface roughness of the portion that contacts the first surface 7 out of the mold for molding the base 3 larger than the surface roughness of the portion that contacts the second surface 9, the first surface The concave portion 23 can be formed on the facing surface 21 facing the coating layer 5 in at least one of the first particles 17 a located at 7. For example, if a diamond coating film is provided on the surface of the mold, the recesses 23 can be easily formed. In addition to the first particles 17a, the recesses 23 may be formed in the second phase 19 during molding, but the recesses 23 formed in the second phase 19 are almost eliminated by firing.
 さらに、基体表面に対して、研削加工と研磨加工を施すことで、第1粒子17aに凹部23を形成してもよい。まず、焼成後の基体3の表面に凹部23を設けるために研削加工を施す。そのままでは、基体3の表面が荒くなりすぎるために、さらに研磨加工を施し、第1粒子の表面にある、凹部23を残しつつ、傷の一部を除去する。 Furthermore, the recesses 23 may be formed in the first particles 17a by subjecting the substrate surface to grinding and polishing. First, in order to provide the recessed part 23 in the surface of the base | substrate 3 after baking, it grinds. As it is, since the surface of the substrate 3 becomes too rough, further polishing is performed to remove a part of the scratch while leaving the recess 23 on the surface of the first particle.
 その際に、研削加工によって形成された凹部23に、基体3の一部であったコバルトやニッケルなどが入り込む。また、研磨の条件によっては、凹部23にコバルトやニッケルととともに炭化タングステン粒子からなる第3粒子17cが凹部23に入り込む。あるいは、ニッケル粉末やコバルト粉末を基体3の表面に擦りつけて、凹部23の中にニッケルやコバルトが存在するようにしてもよい。 At that time, cobalt, nickel, or the like that was a part of the base body 3 enters the recess 23 formed by grinding. Depending on the polishing conditions, the third particles 17 c made of tungsten carbide particles together with cobalt and nickel enter the recess 23. Alternatively, nickel powder or cobalt powder may be rubbed against the surface of the substrate 3 so that nickel or cobalt exists in the recess 23.
 次に、基体3の表面に化学気相蒸着(CVD)法によって被覆層5を成膜する。この工程では、まず、基体3を加熱する。この加熱により、凹部23と、凹部23の中に存在する第2相19との接合力が高くなる。 Next, the coating layer 5 is formed on the surface of the substrate 3 by chemical vapor deposition (CVD). In this step, first, the substrate 3 is heated. By this heating, the bonding force between the recess 23 and the second phase 19 existing in the recess 23 is increased.
 まず、炭窒化チタンを含有する第1層25を成膜する。水素ガスに、0.5~10体積%の四塩化チタンガスと、5~60体積%の窒素ガスと、0.1~3体積%のアセトニトリルガスとを混合して、第1混合ガスを作製する。第1混合ガスをチャンバ内に導入し、MT-炭窒化チタンを含有する第1層25を成膜する。 First, a first layer 25 containing titanium carbonitride is formed. A first mixed gas is prepared by mixing hydrogen gas with 0.5 to 10% by volume titanium tetrachloride gas, 5 to 60% by volume nitrogen gas, and 0.1 to 3% by volume acetonitrile gas. To do. The first mixed gas is introduced into the chamber to form a first layer 25 containing MT-titanium carbonitride.
 次に、酸化アルミニウムを含有する第2層27を成膜する。成膜温度を950℃~1100℃、ガス圧を5kPa~20kPaとし、反応ガスの組成が、水素ガスに、5体積%~15体積%の三塩化アルミニウム(AlCl)ガスと、0.5体積%~2.5体積%の塩化水素(HCl)ガスと、0.5体積%~5.0体積%の二酸化炭素ガスと、0体積%~1体積%の硫化水素(HS)ガスとを混合して、第2混合ガスを作製する。第2混合ガスをチャンバ内に導入し、第2層27を成膜する。 Next, a second layer 27 containing aluminum oxide is formed. The film forming temperature 950 ° C.-1100 ° C., a gas pressure of 5 kPa - 20 kPa, the composition of the reaction gas, hydrogen gas, 5% to 15% by volume of aluminum trichloride (AlCl 3) gas, 0.5 volume % To 2.5% by volume hydrogen chloride (HCl) gas, 0.5% to 5.0% by volume carbon dioxide gas, 0% to 1% by volume hydrogen sulfide (H 2 S) gas, Are mixed to produce a second mixed gas. The second mixed gas is introduced into the chamber, and the second layer 27 is formed.
 その後、必要に応じて、成膜した被覆層5の表面における切刃11に相当する部分を研磨加工する。このような研磨加工を行った場合には、被覆層5における切刃11に相当する部分への被削材の溶着が抑制され易くなるため、さらに耐欠損性に優れた被覆工具1となる。 Thereafter, if necessary, a portion corresponding to the cutting edge 11 on the surface of the formed coating layer 5 is polished. When such a polishing process is performed, the welding of the work material to the portion corresponding to the cutting edge 11 in the coating layer 5 is easily suppressed, so that the coated tool 1 is further excellent in fracture resistance.
 なお、上記の製造方法は、本実施形態の被覆工具1を製造する方法の一例である。したがって、本実施形態の被覆工具1は、上記の製造方法によって作製されたものに限定されないことは言うまでもない。例えば、第2層27の上に別途第3層(不図示)を成膜してもよい。 In addition, said manufacturing method is an example of the method of manufacturing the coating tool 1 of this embodiment. Therefore, it goes without saying that the coated tool 1 of the present embodiment is not limited to the one produced by the above manufacturing method. For example, a third layer (not shown) may be separately formed on the second layer 27.
 <切削工具>
 次に、一実施形態の切削工具101について図面を用いて説明する。
<Cutting tools>
Next, a cutting tool 101 according to an embodiment will be described with reference to the drawings.
 本実施形態の切削工具101は、図6及び図7に示すように、第1端(図6における上端)から第2端(図6における下端)に向かって延びる棒状体であり、第1端の側に位置するポケット103を有するホルダ105と、ポケット103に位置する上記の被覆工具1とを備えている。本実施形態の切削工具101においては、稜線における切刃として用いられる部分の少なくとも一部がホルダ105の先端から突出するように被覆工具1が装着されている。 As shown in FIGS. 6 and 7, the cutting tool 101 according to the present embodiment is a rod-like body that extends from a first end (upper end in FIG. 6) toward a second end (lower end in FIG. 6). A holder 105 having a pocket 103 located on the side of the arm and a covering tool 1 located in the pocket 103. In the cutting tool 101 of this embodiment, the covering tool 1 is mounted so that at least a part of a portion used as a cutting edge on the ridge line protrudes from the tip of the holder 105.
 ポケット103は、被覆工具1が装着される部分であり、ホルダ105の下面に対して平行な着座面と、着座面に対して傾斜する拘束側面とを有している。また、ポケット103は、ホルダ105の第1端側において開口している。 The pocket 103 is a part to which the covering tool 1 is attached, and has a seating surface parallel to the lower surface of the holder 105 and a restraining side surface inclined with respect to the seating surface. Further, the pocket 103 is opened on the first end side of the holder 105.
 ポケット103には被覆工具1が位置している。このとき、被覆工具1の下面がポケット103に直接に接していてもよく、また、被覆工具1とポケット103との間にシートを挟んでいてもよい。 The covering tool 1 is located in the pocket 103. At this time, the lower surface of the covering tool 1 may be in direct contact with the pocket 103, or a sheet may be sandwiched between the covering tool 1 and the pocket 103.
 被覆工具1は、稜線における切刃として用いられる部分がホルダ105から外方に突出するように装着される。本実施形態においては、被覆工具1は、ネジ107によって、ホルダ105に装着されている。すなわち、被覆工具1の貫通孔にネジ107を挿入し、このネジ107の先端をポケット103に形成されたネジ孔(不図示)に挿入してネジ部同士を螺合させることによって、被覆工具1がホルダ105に装着されている。 The covering tool 1 is mounted such that a portion used as a cutting edge on the ridge line protrudes outward from the holder 105. In the present embodiment, the coated tool 1 is attached to the holder 105 with screws 107. That is, the screw 107 is inserted into the through-hole of the covering tool 1, the tip of the screw 107 is inserted into a screw hole (not shown) formed in the pocket 103, and the screw portions are screwed together, thereby covering the covering tool 1. Is mounted on the holder 105.
 ホルダ105としては、鋼、鋳鉄などを用いることができる。特に、これらの部材の中で靱性の高い鋼を用いることが好ましい。 As the holder 105, steel, cast iron or the like can be used. In particular, it is preferable to use steel having high toughness among these members.
 本実施形態においては、被覆工具1としていわゆる旋削加工に用いられる切削工具を例示している。旋削加工としては、例えば、内径加工、外径加工及び溝入れ加工が挙げられる。なお、切削工具としては旋削加工に用いられるものに限定されない。例えば、転削加工に用いられる切削工具に上記の実施形態の被覆工具1を用いてもよい。 In this embodiment, the cutting tool used for so-called turning is illustrated as the coated tool 1. Examples of the turning process include an inner diameter process, an outer diameter process, and a grooving process. The cutting tool is not limited to that used for turning. For example, you may use the covering tool 1 of said embodiment for the cutting tool used for a rolling process.
  1・・・被覆工具(切削工具)
  3・・・基体
  5・・・被覆層
  7・・・第1面
  9・・・第2面
 11・・・切刃
 13・・・第1領域
 15・・・第2領域
 17・・・第1相
 17a・・第1粒子
 17b・・第2粒子
 17c・・第3粒子
 19・・・第2相
 21・・・対向面
 23・・・凹部
 25・・・第1層
 27・・・第2層
 29・・・貫通孔
101・・・切削工具
103・・・ポケット
105・・・ホルダ
107・・・固定ネジ
1 ... Coated tool (cutting tool)
DESCRIPTION OF SYMBOLS 3 ... Base | substrate 5 ... Covering layer 7 ... 1st surface 9 ... 2nd surface 11 ... Cutting blade 13 ... 1st area | region 15 ... 2nd area | region 17 ... 1st 1 phase 17a ·· 1st particle 17b · · 2nd particle 17c · · 3rd particle 19 · · · second phase 21 · · · opposing surface 23 · · · concave portion 25 · · · first layer 27 · · · first 2 layers 29 ... through hole 101 ... cutting tool 103 ... pocket 105 ... holder 107 ... fixing screw

Claims (10)

  1.  複数の炭化タングステン粒子を含有する第1相及びコバルト及びニッケルの少なくとも一方を含有する第2相を有する基体と、該基体の上に位置する被覆層とを備えた被覆工具であって、
     前記複数の炭化タングステン粒子は、前記被覆層に接する複数の第1粒子と、前記被覆層から離れて位置する複数の第2粒子とを有し、
     前記複数の第1粒子の少なくとも1つが、前記被覆層との対向面に凹部を有し、該凹部に前記第2相が位置していることを特徴とする被覆工具。
    A coated tool comprising a substrate having a first phase containing a plurality of tungsten carbide particles and a second phase containing at least one of cobalt and nickel, and a coating layer positioned on the substrate,
    The plurality of tungsten carbide particles have a plurality of first particles in contact with the coating layer, and a plurality of second particles positioned away from the coating layer,
    A coated tool, wherein at least one of the plurality of first particles has a recess on a surface facing the coating layer, and the second phase is located in the recess.
  2.  前記凹部は、さらに炭化タングステン粒子からなる第3粒子を有する、請求項1に記載の被覆工具。 The coated tool according to claim 1, wherein the concave portion further includes third particles made of tungsten carbide particles.
  3.  前記基体及び前記被覆層と交差する断面において、前記複数の第1粒子の平均粒径が、前記複数の第2粒子の平均粒径よりも小さいことを特徴とする請求項1又は2に記載の被覆工具。 3. The average particle diameter of the plurality of first particles is smaller than the average particle diameter of the plurality of second particles in a cross section intersecting the base and the coating layer. Coated tool.
  4.  前記複数の第1粒子のそれぞれにおける前記対向面が、同一面上に位置していることを特徴とする請求項1~3いずれか1つに記載の被覆工具。 The coated tool according to any one of claims 1 to 3, wherein the facing surfaces of each of the plurality of first particles are located on the same surface.
  5.  前記被覆層の一部が、前記凹部に向かって突出していることを特徴とする請求項1~4のいずれか1つに記載の被覆工具。 The covering tool according to any one of claims 1 to 4, wherein a part of the covering layer protrudes toward the concave portion.
  6.  前記第2相は、前記被覆層を構成する成分を含有していることを特徴とする請求項1~5のいずれか1つに記載の被覆工具。 The coated tool according to any one of claims 1 to 5, wherein the second phase contains a component constituting the coating layer.
  7.  前記第2相のうち、前記凹部内を第1部位、前記凹部外を第2部位としたとき、
     前記第1部位における前記被覆層を構成する成分の含有量は、前記第2部位における前記被覆層を構成する成分の含有量よりも多いことを特徴とする請求項6に記載の被覆工具。
    Of the second phase, when the inside of the recess is a first part and the outside of the recess is a second part,
    The coating tool according to claim 6, wherein the content of the component constituting the coating layer in the first part is larger than the content of the component constituting the coating layer in the second part.
  8.  前記基体は、すくい面領域を有する第1面と、逃げ面領域を有する第2面とを有し、
     前記凹部は、前記第1面のみに位置していることを特徴とする請求項1~7のいずれか1つに記載の被覆工具。
    The base body has a first surface having a rake face area and a second face having a flank face area;
    The coated tool according to any one of claims 1 to 7, wherein the concave portion is located only on the first surface.
  9.  前記基体及び前記被覆層と交差する断面において、前記第1面の十点平均粗さが、前記第2面の十点平均粗さよりも小さいことを特徴とする請求項8に記載の被覆工具。 The coated tool according to claim 8, wherein a ten-point average roughness of the first surface is smaller than a ten-point average roughness of the second surface in a cross section intersecting the base and the coating layer.
  10.  第1端から第2端に向かって伸びる棒状であり、前記第1端の側に位置するポケットを有するホルダと、
     前記ポケット内に位置する、請求項1~9のいずれか1つに記載の被覆工具とを有する切削工具。
    A holder having a pocket extending from the first end toward the second end and having a pocket located on the first end side;
    A cutting tool having a coated tool according to any one of claims 1 to 9 located in the pocket.
PCT/JP2018/012348 2017-03-29 2018-03-27 Coated tool and cutting tool WO2018181272A1 (en)

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