WO2018180694A1 - Heating device and heating method - Google Patents
Heating device and heating method Download PDFInfo
- Publication number
- WO2018180694A1 WO2018180694A1 PCT/JP2018/010774 JP2018010774W WO2018180694A1 WO 2018180694 A1 WO2018180694 A1 WO 2018180694A1 JP 2018010774 W JP2018010774 W JP 2018010774W WO 2018180694 A1 WO2018180694 A1 WO 2018180694A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- burner
- fuel gas
- nozzle
- heating
- sleeve fire
- Prior art date
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23Q—IGNITION; EXTINGUISHING-DEVICES
- F23Q9/00—Pilot flame igniters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/20—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone
- F23D14/22—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/46—Details, e.g. noise reduction means
- F23D14/72—Safety devices, e.g. operative in case of failure of gas supply
- F23D14/74—Preventing flame lift-off
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23Q—IGNITION; EXTINGUISHING-DEVICES
- F23Q9/00—Pilot flame igniters
- F23Q9/02—Pilot flame igniters without interlock with main fuel supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23Q—IGNITION; EXTINGUISHING-DEVICES
- F23Q9/00—Pilot flame igniters
- F23Q9/02—Pilot flame igniters without interlock with main fuel supply
- F23Q9/04—Pilot flame igniters without interlock with main fuel supply for upright burners, e.g. gas-cooker burners
- F23Q9/045—Structurally associated with a main-burner
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23Q—IGNITION; EXTINGUISHING-DEVICES
- F23Q9/00—Pilot flame igniters
- F23Q9/08—Pilot flame igniters with interlock with main fuel supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2209/00—Safety arrangements
- F23D2209/20—Flame lift-off / stability
Definitions
- the present invention relates to a heating apparatus including a burner, and more particularly to a heating apparatus that can stably hold a flame without misfire even at a high discharge speed and can perform heating with extremely high efficiency.
- the present invention also relates to a heating method using the heating device.
- FIG. 8 is a schematic view showing an example of a premixed combustion burner conventionally used.
- combustible fuel gas 101 and air 102 are premixed in the premixed combustion burner 100 to form a mixed gas, and the mixed gas is discharged from the premixed combustion burner 100 and burned. As a result, a flame 103 is formed.
- the heat transfer amount Q from the flame to the surface of the object to be heated is proportional to the heat transfer coefficient ⁇ , and the heat transfer coefficient ⁇ is equal to the flame discharge speed V 0 .
- the heat transfer coefficient ⁇ is proportional to V 0 1/2 .
- the heat transfer coefficient ⁇ is proportional to V 0 0.58 . Therefore, in order to improve the heating efficiency by the burner, it is required to increase the discharge speed.
- Patent Document 1 a method for stabilizing the flame and suppressing the blow-off.
- the burner of Patent Document 1 it is possible to stabilize the flame and raise the flame temperature.
- the burner proposed in Patent Document 1 is not sufficient in terms of improving the discharge speed described above, and is provided with a burner that can be used stably at a higher discharge speed in order to improve heating efficiency. Development of a new heating device is required.
- the present invention has been made in view of the above circumstances, and can provide a heating apparatus that can stably hold a flame without misfire even at a high discharge speed and can perform heating with extremely high efficiency.
- the purpose is to provide.
- Another object of the present invention is to provide a heating method using the heating device.
- a heating device comprising a burner, The burner A main burner section comprising a fuel gas nozzle for discharging fuel gas and an air nozzle for discharging combustion air;
- a heating apparatus comprising: a sleeve fire burner portion that is located outside the main burner portion and burns fuel gas discharged from the main burner portion.
- the main burner section includes a pressure equalizing chamber on the upstream side of one or both of the fuel gas nozzle and the air nozzle.
- a concave portion having a bottom portion and a tapered portion gradually widening from the bottom portion toward the tip of the burner is provided at the tip of the burner,
- the main burner portion is disposed at the bottom;
- the flaming burner comprises a flaming nozzle selected from a tubular nozzle having a diameter d and a slit nozzle having a width d in the short side direction; 6.
- the heating apparatus according to any one of the above 1 to 7, further comprising a flow rate adjusting means capable of independently adjusting a flow rate in the main burner portion and a flow rate in the sleeve fire burner portion.
- the ratio of the flow rate F1 of the fuel gas discharged from the main burner portion to the flow rate F2 of the fuel gas for the sleeve fire discharged from the sleeve fire burner portion, F1: F2, is set to 70:30 to 85:15.
- Item 11 The heating method according to Item 9 or 10.
- FIG. 1 It is a schematic diagram which shows the structure of the burner in one Embodiment of this invention. It is a schematic diagram which shows the structure of the main burner part in one Embodiment of this invention. It is a schematic diagram which shows the structure of the sleeve fire burner part in one Embodiment of this invention. It is a schematic diagram which shows the structure of the sleeve fire burner part in other embodiment of this invention. It is a figure which shows the discharge speed in each burner of an Example and a comparative example. It is a figure which shows the heating power in each burner of an Example and a comparative example. It is a figure which shows the example of a measurement of the temperature distribution in the burner of the comparative example 1 and Example 1. FIG. It is a schematic diagram which shows an example of the conventional premixed combustion burner.
- the heating device of the present invention is a heating device including a burner, and the burner includes a main burner portion and a sleeve fire burner portion.
- the main burner section includes a fuel gas nozzle that discharges fuel gas and an air nozzle that discharges combustion air, and the fuel gas and air discharged from the main burner section are combusted. To form a flame for heating.
- the sleeve fire burner portion has a function for igniting the fuel gas discharged from the main burner portion.
- the sleeve fire burner portion is positioned outside the burner with respect to the main burner portion.
- the heat transfer amount Q from the flame to the surface of the object to be heated is proportional to the heat transfer coefficient ⁇ , and the heat transfer coefficient ⁇ increases as the flame discharge speed V 0 increases. Therefore, according to the heating device of the present invention, heating can be performed with extremely high efficiency by causing a flame to collide with the surface of the object to be heated at high speed. As a result, the object to be heated can be heated to a higher temperature at a higher speed.
- the amount of fuel gas necessary to achieve the same heating temperature can be reduced. Furthermore, since the discharge speed can be increased in the heating device of the present invention, the flame can reach a distant position. Therefore, the burner can be installed at a position away from the object to be heated, and the degree of freedom in device design is high.
- the heating device of the present invention can be used very suitably as a heating device for an iron making process for heating an iron making material.
- the heating device for the iron making process include an ignition device for a sintering machine used for producing sintered ore.
- the structure of a burner is a line burner provided with the several nozzle arranged in a linear form.
- the flame can be stably maintained even at a high discharge speed by using the above-described positional relationship for the following reason. That is, as proposed in Patent Document 1, the fuel gas nozzle and the combustion air nozzle are arranged so as to sandwich the squib burner, and the fuel gas discharge direction and the combustion air discharge direction are arranged to intersect each other. In this case, a vortex flow is generated, and the kinetic energy loss due to the flow turbulence increases, so that a high flow velocity cannot be maintained.
- the sleeve fire burner portion is located outside the burner with respect to the main burner portion, thereby suppressing the turbulence of the flow of the mainstream fuel gas and combustion air, and the high flow rate. Can be maintained. Further, if the discharge direction of the fuel gas discharged from the main burner portion and the combustion air are made parallel, the flow disturbance can be further suppressed and a higher flow rate can be maintained.
- the squib burner is arranged outside, and the combustion air nozzle is arranged outside the fuel gas nozzle, it is necessary to discharge the fuel gas toward the scabs on both sides. Is required on both sides.
- the diameter of each nozzle is reduced, so that the attenuation of the gas speed after discharge increases and the high flow rate after discharge cannot be maintained.
- a high flow rate can be maintained.
- the fuel gas is not particularly limited, and any flammable gas can be used.
- the fuel gas for example, natural gas or LPG (liquefied petroleum gas) can be generally used.
- LPG liquefied petroleum gas
- a process gas by-produced in the steelworks can be used as the fuel gas.
- the process gas it is preferable to use a process gas containing a coke oven gas.
- the process gas containing the coke oven gas for example, the coke oven gas itself (that is, a gas composed only of the coke oven gas) and M gas that is a mixture of coke oven gas and blast furnace gas are preferably used. .
- FIG. 1 is a schematic diagram of a burner 1 according to an embodiment of the present invention, and shows a structure of a cross section of the burner 1.
- the burner 1 includes a burner body 10, and a main burner portion 20 and a sleeve fire burner portion 30 provided on the burner body 10.
- a recess 40 is provided at the tip of the burner 1 (on the side where the flame is formed).
- the recess 40 includes a bottom 41 and a tapered portion 42 that gradually widens from the bottom 41 toward the tip of the burner 1. Have.
- FIG. 2 is a schematic diagram showing the structure of the main burner portion 20 in one embodiment of the present invention.
- the main burner unit 20 includes a fuel gas nozzle 21 that discharges fuel gas and an air nozzle 22 that discharges combustion air.
- One fuel gas nozzle 21 is provided at the center of the bottom 41.
- Two air nozzles 22 are provided symmetrically so as to sandwich the fuel gas nozzle 21 therebetween.
- the cross section of one burner is shown in the example shown in FIG. 2, when a wide article is heated, it is preferable to arrange a plurality of burners in the direction perpendicular to the paper surface to form a line burner.
- Fuel gas is supplied as indicated by arrow G and is discharged from the fuel gas nozzle 21.
- Combustion air is supplied as indicated by arrow A and is discharged from the air nozzle 22.
- the fuel gas is not ignited at the time of discharge, but is ignited by the sleeve fire 50 formed by the sleeve fire burner 30 as shown in FIG.
- the shape of the fuel gas nozzle 21 and the air nozzle 22 is not particularly limited, and can be any shape. However, as shown in FIG. 2, it is preferable to use a straight pipe structure that does not have a cone-like structure at the nozzle tip. If a straight tube structure nozzle is used, the discharge rate can be further improved and the heat transfer coefficient on the heated surface can be further increased. As a result, the heating efficiency can be further improved. This is because the straight pipe structure nozzle has less energy loss due to the vortex formation than the nozzle that forms the swirl flow, and the gas velocity after discharge is suppressed from being attenuated.
- the diameters of the fuel gas nozzle 21 and the air nozzle 22 are preferably determined so that the discharge flow rate in the normal use flow rate range is 50 to 80 Nm / s in order to increase the heating efficiency of the burner. Further, the discharge flow rate during maximum combustion is preferably 150 Nm / s or less. The definition of the discharge speed will be described later.
- the specific diameters of the fuel gas nozzle 21 and the air nozzle 22 are not limited, but if the diameter is 3 mm or more, attenuation of the gas velocity after being discharged from the nozzle can be further suppressed. Therefore, the diameter is preferably 3 mm or more, and more preferably 5 mm or more.
- the condition of the diameter is not particularly limited, but if the diameter is 30 mm or less, the heat load of the burner can be maintained in a more preferable range, and the life of the burner can be extended. Also, by providing a large number of small diameter nozzles having a diameter of 30 mm or less, heating can be performed more uniformly than when a small number of large diameter nozzles are provided. Therefore, the diameter is preferably 30 mm or less.
- the diameter of the fuel gas nozzle 21 and the diameter of the air nozzle 22 may be the same or different.
- the distance (nozzle pitch) L 1 between the fuel gas nozzle 21 and the air nozzle 22 is 2d NG ⁇ L 1 ⁇ 15d NA when the diameter of the fuel gas nozzle 21 is d NG and the diameter of the air nozzle 22 is d NA. It is preferable to satisfy.
- the fuel gas nozzle interval (nozzle pitch) L 2 of each burner satisfies 2d NG ⁇ L 2 ⁇ 15d NA . If the above conditions are satisfied, combustion stability is further improved, and attenuation of gas velocity can be further suppressed.
- the main burner portion 20 is provided with a pressure equalizing chamber 23 on the upstream side of each of the fuel gas nozzle 21 and the air nozzle 22, and fuel gas or air passes on the opposite side (upstream side) of the nozzle of the pressure equalizing chamber 23.
- a perforated plate 24 provided with holes is provided. If the pressure equalizing chamber 23 is provided in this way, the gas can be discharged more uniformly, so that the flame can be further stabilized and the discharge speed can be further increased.
- the pressure equalizing chamber 23 can be provided only on the upstream side of one of the fuel gas nozzle 21 and the air nozzle 22, but it is preferable to provide the pressure equalizing chamber 23 on both as shown in FIG.
- the pressure equalizing chamber is a structure provided on the upstream side of the nozzle in order to mitigate the influence of fluctuations in gas supply pressure.
- the pressure equalization chamber includes a plate (throttle plate) provided on the upstream side of the nozzle and having one or more openings, and a space between the throttle plate and the nozzle. Is provided.
- the upstream side of the diaphragm plate and the space are connected only by the opening of the diaphragm plate.
- the total area of the openings provided in the diaphragm plate is smaller than the cross-sectional area of the space in a plane perpendicular to the discharge direction of the nozzle.
- the total area of the nozzle openings is also smaller than the cross-sectional area of the space in a plane perpendicular to the nozzle ejection direction.
- the sleeve fire burner portion has a function of igniting the fuel gas discharged from the main burner portion and burning the fuel gas.
- the ignition of the fuel gas discharged from the main burner portion is performed by a flame (sleeve fire) formed by the sleeve fire burner portion.
- the sleeve fire burner section normally includes a sleeve fire fuel gas outlet and a sleeve fire air outlet for forming a sleeve fire.
- a sleeve fire is formed by burning the fuel gas for the sleeve fire using the air for the sleeve fire.
- “sleeve fire fuel gas” may be simply referred to as “fuel gas”
- sleeve fire air” may be simply referred to as “air”.
- the heating device of the present invention includes the sleeve fire burner for burning the fuel gas discharged from the main burner outside the main burner as described above, the fuel gas from the main burner The flame can be stably maintained even under conditions where the discharge speed is high. Therefore, the burner of the present invention has a combustion chamber structure for stably maintaining a flame on the front side of the main burner, that is, a structure protruding toward the front of the burner so as to surround the main burner and the sleeve fire burner. There is also an advantage that it is not necessary.
- the flame of the main burner is maintained in the space portion in front of the gas discharge direction from the main burner.
- a combustion chamber structure for stably maintaining a flame or a cone-shaped structure composed of a refractory is provided on the front side of the main burner, and the flame is maintained inside or on the surface thereof.
- the intersection of the gas discharge direction of the main burner portion and the gas discharge direction of the sleeve fire burner portion is the outside of the space portion in front of the gas discharge direction of the burner or the recess of the burner ( It is preferably located outside the burner.
- FIG. 3 is a schematic diagram showing the structure of the sleeve fire burner 30 in one embodiment of the present invention.
- the sleeve fire burner 30 is composed of a surface combustion burner.
- a porous plate 31 is provided at the tip of the surface combustion burner, and fuel gas for sleeve fire and air for sleeve fire are supplied to the porous plate 31 as indicated by arrows G and A, respectively.
- an accompanying flow accompanying the air flow is formed near the tip of the burner 1, particularly in the recess 40.
- the flow rate of the gas discharged from the main burner portion is 50 m / s
- the flow rate of the accompanying flow is as high as 20 to 30 m / s, so the sleeve fire 50 formed by the sleeve fire burner portion 30 is unstable. There is a risk of becoming.
- the surface combustion burner since the ignition point exists on the surface or inside of the porous plate, the sleeve fire can be stably held without being affected by the accompanying flow.
- the porous plate 31 is not particularly limited, and a plate-like member made of an arbitrary porous body can be used.
- the porous body can be made of, for example, one or more materials selected from the group consisting of metals, alloys, and ceramics.
- a metal mesh a laminate of metal fibers
- the surface of the porous plate 31 is preferably disposed on the same plane as the surface of the tapered portion 42.
- the main burner portion 20 and the sleeve fire burner portion 30 have a discharge axis (discharge direction) of the main burner portion 20 and a discharge axis (discharge direction) of the sleeve fire burner portion 30. It is preferable that they are arranged so as to intersect on the extension line. More specifically, it is preferable that the angle ⁇ formed by the bottom portion 41 and the tapered portion 42 constituting the recess 40 is 20 ° or more.
- the angle ⁇ is less than 20 °, the flame of the sleeve fire burner part is difficult to reach the gas flow discharged from the main burner part, and misfire is likely to occur.
- the ⁇ is more preferably 30 ° or more.
- the upper limit of the ⁇ is not particularly limited, but is usually preferably 80 ° or less, and more preferably 60 ° or less.
- the distance between the main burner portion and the sleeve fire burner portion is determined so that the flame of the sleeve fire burner portion (sleeve fire 50) reaches the discharge flow from the main burner portion.
- the effective flame length of the sleeve fire burner is F
- the distance that the flame of the sleeve fire burner reaches in the direction parallel to the surface of the bottom 41 is F ⁇ sin ⁇ .
- the distance between the main burner portion and the sleeve fire burner portion may be determined so that the distance from the center position of the sleeve fire burner portion is F ⁇ sin ⁇ or less in the direction parallel to the surface of the bottom portion 41.
- the effective flame length of the sleeve burner portion is 100 mm
- the center of the main burner portion and the sleeve flame The distance at the center of the burner may be 75 mm or less.
- the distance between the center of the main burner portion and the center of the sleeve burner portion is 60 to 110 mm.
- the effective flame length can be determined as the length from the combustion surface or the taper surface of the region that is equal to or higher than the gas ignition temperature based on the measurement result of the flame temperature.
- FIG. 4 is a schematic view showing an example of the structure of the sledge fire burner portion in another embodiment of the present invention.
- the sleeve fire burner 30 includes a tubular nozzle having a diameter d as the sleeve fire nozzle 32.
- the sleeve fire nozzle 32 includes an outer pipe and an inner pipe provided coaxially. As shown by an arrow G, the sleeve fire fuel gas is supplied to the inner pipe. It is discharged from the tip of the inner tube. On the other hand, as shown by the arrow A, the sleeve fire air is supplied to the outer pipe, and the sleeve fire air is discharged from the tip of the outer pipe.
- the tip of the sleeve fire nozzle 32 is provided at a position deeper than d from the surface of the tapered portion 42 as shown in FIG. In other words, the distance from the surface of the taper portion 42 to the tip of the sleeve nozzle 32 is d or more.
- the fuel gas for sleeve fire discharged from the sleeve fire nozzle 32 is ignited in the space 33, and the flame (sleeve) is formed so as to extend beyond the surface of the tapered portion 42.
- the tip of the sleeve fire nozzle 32 is set to a position recessed toward the inside of the burner body 10, the effect of the accompanying flow described above can be suppressed and the sleeve fire can be stabilized without using a surface combustion burner. It becomes possible to hold. Even when the sleeve fire burner portion 30 includes a slit nozzle having a width d in the short side direction as the sleeve fire nozzle 32, the tip of the sleeve fire nozzle 32 is similarly recessed at least d from the surface of the tapered portion 42. It is preferable to provide it.
- the distance from the surface of the tapered portion 42 to the tip of the sleeve fire nozzle 32 is preferably 2d or more.
- the distance from the surface of the tapered portion 42 to the tip of the sleeve fire nozzle 32 is preferably 15 d or less, and more preferably 4 d or less.
- the heating device of the present invention it is possible to stably hold a flame without misfire even at a high discharge speed, and it is possible to perform heating with extremely high efficiency.
- the discharge speed at the time of use is not particularly limited and may be any speed as long as the flame can be held.
- the fuel gas and air discharged from the main burner section The discharge speed of each is preferably 50 Nm / s or more, more preferably 60 Nm / s or more, and still more preferably 65 Nm / s or more.
- an extremely high discharge speed cannot be realized by a conventional burner.
- discharge speed gas flow rate per unit time of a single nozzle / nozzle cross-sectional area.
- the cross-sectional area of the nozzle outlet portion is considered as the nozzle cross-sectional area.
- the fuel discharged from the burner with a cross-sectional area at the outlet of the cone portion By dividing the total flow rate of the sum of gas and air, the burner discharge speed can be determined.
- the fuel gas discharge speed and the combustion air discharge speed be approximately equal.
- the ratio of the discharge speed of the fuel gas to the discharge speed of the combustion air is preferably 0.8 to 1.2.
- the discharge flow rate ratio in the nozzle hole portion in front of the cone is preferably 0.8 to 1.2.
- the heating device includes a flow rate adjusting unit that can independently adjust the fuel gas flow rate in the main burner portion and the fuel gas flow rate in the stagfire burner portion.
- the combustion air amount can be determined by multiplying the fuel gas flow rate by the theoretical amount of fuel gas and the air ratio.
- the heating device includes a flow rate adjusting unit that can independently adjust the flow rate of the combustion air in the main burner portion and the flow rate of the combustion air in the sleeve fire burner portion.
- a flow rate adjusting valve or the like can be used as the flow rate adjusting means.
- the flow rate of the fuel gas in the sleeve fire burner is 15% or more.
- the ratio of the flow rate F1 of the fuel gas discharged from the main burner portion to the flow rate F2 of the fuel gas for sleeve fire discharged from the sleeve fire burner portion, F1: F2 is 85:15 or less (F1 / F2 ⁇ 85/15).
- the flow rate of the fuel gas in the sleeve fire burner portion is 30% or less, in other words, F1: F2 is 70:30 or more (F1 / F2 ⁇ 70/30).
- Table 1 shows the dimensions of the nozzle and the cross-sectional area of the discharge part. Further, the ratio of the flow rate of the fuel gas in the main burner portion and the flow rate of the fuel gas in the sleeve fire burner portion in Comparative Example 2 and Example 1 (fuel gas flow rate ratio) is shown in Table 1 together.
- Comparative Example 1 a slit-shaped nozzle having the cross-sectional shape shown in FIG. 8 and having a nozzle width of 10 mm and a length of 1 m was used.
- Comparative Example 2 60 nozzles set in a straight line between 1 m in the burner width direction were used as shown in FIG. Since the burner described in Patent Document 1 includes two fuel gas nozzles per burner, the number of fuel gas nozzles is 120.
- 50 nozzle sets of the nozzles of FIGS. 1 and 2 according to the present invention were linearly arranged in the burner width direction 1 m, that is, 50 fuel gas nozzles were installed. When 50 sets of nozzles were arranged in the burner of Comparative Example 2, the flame was unstable, so 60 sets of nozzles were installed to stabilize the flame.
- the experiment was conducted in an experimental combustion furnace having a combustion space size of 1.4 m ⁇ 1.4 m ⁇ 0.4 m.
- the flow rate of the fuel gas and the combustion air was increased so that the flow rate ratio was constant, and the critical discharge flow rate at which the flame could be held without the flame blowing out was measured.
- M gas mixed gas of coke oven gas and blast furnace gas
- the main components of the M gas were H 2 : 26.5%, CO: 17.6%, CH 4 : 9.1%, and N 2 : 30.9%.
- Comparative Example 1 when the flow velocity (discharge speed) in the nozzle straight pipe portion exceeded 30 Nm / s, the flame could not be held and blowing out occurred.
- the flow rate of the straight pipe portion is 3 Nm / s when converted to the flow velocity at the tip of the cone portion.
- Comparative Example 2 when the flow velocity (discharge speed) in the nozzle straight pipe portion exceeded 40 Nm / s, the flame could not be held and blowing out occurred.
- Example 1 the flame was stable even under conditions where the discharge speed exceeded 40 Nm / s. When the discharge speed exceeded 100 Nm / s, the flame became unstable and blow-off occurred at 120 Nm / s.
- the heating apparatus of the present invention can perform stable combustion even at a discharge flow rate significantly higher than that of a conventional burner.
- use near the blow-off limit flow rate may increase the risk of blow-off due to fluctuations in the operation of the supply system, etc.
- the flow rate be reduced.
- FIG. 5 also shows an example of the actual normal use flow rate.
- FIG. 6 shows the heating power of the burner in each example and comparative example when the fuel gas flow rate and the air ratio are the same. In Example 1, it turns out that a heating power is improving significantly compared with the comparative example 1 and the comparative example 2.
- Comparative Example 1 combustion is performed inside the cone in front of the burner, and combustion of many fuel gases is completed before reaching the object to be heated.
- Example 1 the fuel gas discharged from the main burner is ignited by the flame of the sleeve fire burner in the vicinity of the middle of the burner and the object to be heated, and starts to burn, and a lot of fuel gas is discharged near the object to be heated. Fuel gas is burning.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Pre-Mixing And Non-Premixing Gas Burner (AREA)
- Gas Burners (AREA)
Abstract
Description
前記バーナが、
燃料ガスを吐出する燃料ガスノズルと燃焼用空気を吐出する空気ノズルとを備える主バーナ部と、
前記主バーナ部よりも外側に位置し、前記主バーナ部から吐出される燃料ガスを燃焼させるための袖火バーナ部とを備える、加熱装置。 1. A heating device comprising a burner,
The burner
A main burner section comprising a fuel gas nozzle for discharging fuel gas and an air nozzle for discharging combustion air;
A heating apparatus, comprising: a sleeve fire burner portion that is located outside the main burner portion and burns fuel gas discharged from the main burner portion.
前記主バーナ部が前記底部に配置されており、
前記袖火バーナ部が前記テーパー部に配置されている、上記1~3のいずれか一項に記載の加熱装置。 4). A concave portion having a bottom portion and a tapered portion gradually widening from the bottom portion toward the tip of the burner is provided at the tip of the burner,
The main burner portion is disposed at the bottom;
The heating apparatus according to any one of
前記袖火ノズルの先端が、前記テーパー部の表面からd以上15d以下奥まった位置に設けられている、上記4または5に記載の加熱装置。 7). The flaming burner comprises a flaming nozzle selected from a tubular nozzle having a diameter d and a slit nozzle having a width d in the short side direction;
6. The heating apparatus according to 4 or 5 above, wherein a tip of the flaming nozzle is provided at a position deeper than d and not more than 15d from the surface of the tapered portion.
上記燃料ガスとしては特に限定されることなく、可燃性ガスであれば任意のものを用いることができる。前記燃料ガスとしては、例えば、一般には天然ガスやLPG(liquefied petroleum gas)が使用可能である。上記加熱装置を製鉄所において使用する場合には、製鉄所で副生するプロセスガスを前記燃料ガスとして用いることもできる。前記プロセスガスとしては、コークス炉ガスを含有するプロセスガスを用いることが好ましい。前記コークス炉ガスを含有するプロセスガスとしては、例えば、コークス炉ガス自体(すなわち、コークス炉ガスのみからなるガス)、およびコークス炉ガスと高炉ガスを混合したガスであるMガスが好適に用いられる。 [Fuel gas]
The fuel gas is not particularly limited, and any flammable gas can be used. As the fuel gas, for example, natural gas or LPG (liquefied petroleum gas) can be generally used. When the heating device is used in a steelworks, a process gas by-produced in the steelworks can be used as the fuel gas. As the process gas, it is preferable to use a process gas containing a coke oven gas. As the process gas containing the coke oven gas, for example, the coke oven gas itself (that is, a gas composed only of the coke oven gas) and M gas that is a mixture of coke oven gas and blast furnace gas are preferably used. .
図2は、本発明の一実施形態における主バーナ部20の構造を示す模式図である。主バーナ部20は、燃料ガスを吐出する燃料ガスノズル21と、燃焼用空気を吐出する空気ノズル22とを備えている。燃料ガスノズル21は、底部41の中央に1つ設けられている。空気ノズル22は、燃料ガスノズル21を挟むように左右対称に2つ設けられている。なお、図2に示した例では1つのバーナの断面を示しているが、幅のある物品を加熱する場合には複数のバーナを紙面垂直方向に配列してラインバーナとすることが好ましい。 [Main burner section]
FIG. 2 is a schematic diagram showing the structure of the
主バーナ部20には、燃料ガスノズル21および空気ノズル22それぞれの上流側に均圧室23が設けられており、均圧室23のノズルと反対側(上流側)には燃料ガスまたは空気が通るための孔が設けたれた有孔板24が設置されている。このように均圧室23を設ければガスをより均一に吐出できるため、火炎をさらに安定化し、吐出速度をさらに上げることが可能となる。なお、燃料ガスノズル21および空気ノズル22のいずれか一方の上流側にのみ均圧室23を設けることもできるが、図2に示したように両方に設けることが好ましい。ここで、均圧室とは、ガスの供給圧の変動による影響を緩和するために、ノズルの上流側に設けられる構造である。前記均圧室は、図2に例示したように、ノズルの上流側に設置された、1または2以上の開口を備える板(絞り板)と、前記絞り板と前記ノズルとの間の空間とを備える。そして、前記絞り板の上流側と前記空間とは、前記絞り板の開口のみで繋がっている。前記絞り板に設けられた開口の合計面積は、前記空間の、前記ノズルの吐出方向と垂直な面における断面積よりも小さい。さらに、前記ノズルの開口の合計面積も、前記空間の、前記ノズルの吐出方向と垂直な面における断面積よりも小さい。 [Equal pressure chamber]
The
上述したように、袖火バーナ部は、主バーナ部から吐出される燃料ガスに着火し、該燃料ガスを燃焼させる機能を有している。主バーナ部から吐出される燃料ガスの着火は、袖火バーナ部によって形成される炎(袖火)によって行われる。したがって、袖火バーナ部は、通常、袖火を形成するための、袖火用燃料ガス出口と袖火用空気出口を備えている。前記袖火用空気を用いて前記袖火用燃料ガスを燃焼させることにより袖火が形成される。なお、以下の説明において、「袖火用燃料ガス」を単に「燃料ガス」、「袖火用空気」を単に「空気」と呼ぶ場合がある。 [Sleeve Burner]
As described above, the sleeve fire burner portion has a function of igniting the fuel gas discharged from the main burner portion and burning the fuel gas. The ignition of the fuel gas discharged from the main burner portion is performed by a flame (sleeve fire) formed by the sleeve fire burner portion. Therefore, the sleeve fire burner section normally includes a sleeve fire fuel gas outlet and a sleeve fire air outlet for forming a sleeve fire. A sleeve fire is formed by burning the fuel gas for the sleeve fire using the air for the sleeve fire. In the following description, “sleeve fire fuel gas” may be simply referred to as “fuel gas”, and “sleeve fire air” may be simply referred to as “air”.
上述したように、本発明の加熱装置によれば、高い吐出速度においても失火することなく安定して火炎を保持することが可能であり、極めて高い効率で加熱を行うことができる。なお、使用時の吐出速度は特に限定されず、火炎が保持できる範囲内であれば任意の速度とすることができるが、加熱効率の観点からは、主バーナ部から吐出される燃料ガスと空気のそれぞれの吐出速度を50Nm/s以上とすることが好ましく、60Nm/s以上とすることがより好ましく、65Nm/s以上とすることがさらに好ましい。このように極めて高い吐出速度は従来のバーナでは実現できなかったものである。 [Discharge speed]
As described above, according to the heating device of the present invention, it is possible to stably hold a flame without misfire even at a high discharge speed, and it is possible to perform heating with extremely high efficiency. In addition, the discharge speed at the time of use is not particularly limited and may be any speed as long as the flame can be held. From the viewpoint of heating efficiency, the fuel gas and air discharged from the main burner section The discharge speed of each is preferably 50 Nm / s or more, more preferably 60 Nm / s or more, and still more preferably 65 Nm / s or more. Thus, an extremely high discharge speed cannot be realized by a conventional burner.
主バーナ部における燃料ガス流量と袖火バーナ部における燃料ガス流量の比率(以下、「燃料ガス流量比」ともいう)は、火炎の安定性および加熱能力に大きく影響する。そのため、加熱装置は、主バーナ部における燃料ガス流量と袖火バーナ部における燃料ガス流量を、それぞれ独立に調整可能な流量調整手段を備えることが好ましい。また、燃焼用空気量は、燃料ガス流量に、燃料ガスの理論空気量と空気比を乗じて決定することができる。加熱装置は、主バーナ部における燃焼用空気の流量と袖火バーナ部における燃焼用空気の流量を、それぞれ独立に調整可能な流量調整手段を備えることが好ましい。前記流量調整手段としては、流量調整弁などを用いることができる。 [Fuel gas flow ratio]
The ratio of the fuel gas flow rate in the main burner portion and the fuel gas flow rate in the sleeve fire burner portion (hereinafter also referred to as “fuel gas flow rate ratio”) greatly affects the flame stability and the heating capacity. Therefore, it is preferable that the heating device includes a flow rate adjusting unit that can independently adjust the fuel gas flow rate in the main burner portion and the fuel gas flow rate in the stagfire burner portion. The combustion air amount can be determined by multiplying the fuel gas flow rate by the theoretical amount of fuel gas and the air ratio. It is preferable that the heating device includes a flow rate adjusting unit that can independently adjust the flow rate of the combustion air in the main burner portion and the flow rate of the combustion air in the sleeve fire burner portion. As the flow rate adjusting means, a flow rate adjusting valve or the like can be used.
(比較例1)図8に示した従来の一般的な予混合燃焼バーナ
(比較例2)特許文献1の図1に示したバーナ
(実施例1)図1~3に示した構造のバーナ In order to confirm the influence of the burner structure on the flame stability, the following three types of burners were used to evaluate the critical discharge speed at which the flame can be held without blowing out.
(Comparative Example 1) Conventional general premixed combustion burner shown in FIG. 8 (Comparative Example 2) Burner shown in FIG. 1 of Patent Document 1 (Example 1) Burner having the structure shown in FIGS.
10 バーナ本体
20 主バーナ部
21 燃料ガスノズル
22 空気ノズル
23 均圧室
30 袖火バーナ部
31 多孔質板
33 空間
40 凹部
41 底部
42 テーパー部
50 袖火
60 火炎
DESCRIPTION OF
Claims (11)
- バーナを備える加熱装置であって、
前記バーナが、
燃料ガスを吐出する燃料ガスノズルと燃焼用空気を吐出する空気ノズルとを備える主バーナ部と、
前記主バーナ部よりも外側に位置し、前記主バーナ部から吐出される燃料ガスを燃焼させるための袖火バーナ部とを備える、加熱装置。 A heating device comprising a burner,
The burner
A main burner section comprising a fuel gas nozzle for discharging fuel gas and an air nozzle for discharging combustion air;
A heating apparatus, comprising: a sleeve fire burner portion that is located outside the main burner portion and burns fuel gas discharged from the main burner portion. - 前記主バーナ部が、前記燃料ガスノズルおよび前記空気ノズルの一方または両方の上流側に均圧室を備える、請求項1に記載の加熱装置。 The heating apparatus according to claim 1, wherein the main burner section includes a pressure equalizing chamber on the upstream side of one or both of the fuel gas nozzle and the air nozzle.
- 前記燃料ガスノズルおよび前記空気ノズルが直管構造である、請求項1または2に記載の加熱装置。 The heating apparatus according to claim 1 or 2, wherein the fuel gas nozzle and the air nozzle have a straight pipe structure.
- 前記バーナの先端に、底部と、該底部から該バーナの先端に向かって漸次拡幅するテーパー部とを有する凹部が設けられており、
前記主バーナ部が前記底部に配置されており、
前記袖火バーナ部が前記テーパー部に配置されている、請求項1~3のいずれか一項に記載の加熱装置。 A concave portion having a bottom portion and a tapered portion gradually widening from the bottom portion toward the tip of the burner is provided at the tip of the burner,
The main burner portion is disposed at the bottom;
The heating apparatus according to any one of claims 1 to 3, wherein the sleeve fire burner portion is disposed in the tapered portion. - 前記底部および前記テーパー部のなす角度θが20°以上である、請求項4に記載の加熱装置。 The heating device according to claim 4, wherein an angle θ formed by the bottom portion and the tapered portion is 20 ° or more.
- 前記袖火バーナ部が面燃焼バーナである、請求項1~5のいずれか一項に記載の加熱装置。 The heating apparatus according to any one of claims 1 to 5, wherein the sleeve fire burner is a surface combustion burner.
- 前記袖火バーナ部が、直径dの管形ノズルおよび短辺方向の幅dのスリットノズルから選択される袖火ノズルを備え、
前記袖火ノズルの先端が、前記テーパー部の表面からd以上15d以下奥まった位置に設けられている、請求項4または5に記載の加熱装置。 The flaming burner comprises a flaming nozzle selected from a tubular nozzle having a diameter d and a slit nozzle having a width d in the short side direction;
6. The heating device according to claim 4, wherein a tip of the sleeve fire nozzle is provided at a position recessed from d to 15 d from the surface of the tapered portion. - 前記主バーナ部における流量と前記袖火バーナ部における流量とを独立して調整可能な流量調整手段を備える、請求項1~7のいずれか一項に記載の加熱装置。 The heating apparatus according to any one of claims 1 to 7, further comprising a flow rate adjusting means capable of independently adjusting a flow rate in the main burner portion and a flow rate in the sleeve fire burner portion.
- 請求項1~8のいずれか一項に記載の加熱装置を用いて加熱する、加熱方法。 A heating method of heating using the heating device according to any one of claims 1 to 8.
- 前記主バーナ部から吐出される燃料ガスと燃焼用空気のそれぞれの吐出速度が50Nm/s以上である、請求項9に記載の加熱方法。 The heating method according to claim 9, wherein the discharge speeds of the fuel gas and the combustion air discharged from the main burner part are 50 Nm / s or more.
- 前記主バーナ部から吐出される燃料ガスの流量F1と前記袖火バーナ部から吐出される袖火用燃料ガスの流量F2の比、F1:F2を、70:30~85:15とする、請求項9または10に記載の加熱方法。 The ratio of the flow rate F1 of the fuel gas discharged from the main burner portion to the flow rate F2 of the fuel gas for the sleeve fire discharged from the sleeve fire burner portion, F1: F2, is set to 70:30 to 85:15. Item 11. The heating method according to Item 9 or 10.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019509343A JP6690779B2 (en) | 2017-03-27 | 2018-03-19 | Heating device and heating method |
EP18778121.6A EP3604925B1 (en) | 2017-03-27 | 2018-03-19 | Heating device and heating method |
KR1020197025717A KR102273957B1 (en) | 2017-03-27 | 2018-03-19 | Heating device and heating method |
CN201880013141.3A CN110325794B (en) | 2017-03-27 | 2018-03-19 | Heating device and heating method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017-061583 | 2017-03-27 | ||
JP2017061583 | 2017-03-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2018180694A1 true WO2018180694A1 (en) | 2018-10-04 |
Family
ID=63675710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2018/010774 WO2018180694A1 (en) | 2017-03-27 | 2018-03-19 | Heating device and heating method |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP3604925B1 (en) |
JP (1) | JP6690779B2 (en) |
KR (1) | KR102273957B1 (en) |
CN (1) | CN110325794B (en) |
TW (1) | TWI670457B (en) |
WO (1) | WO2018180694A1 (en) |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3302596A (en) * | 1966-01-21 | 1967-02-07 | Little Inc A | Combustion device |
JPS5218234A (en) * | 1975-07-31 | 1977-02-10 | Exxon Research Engineering Co | Multi stages air burner |
JPH06159613A (en) * | 1992-11-24 | 1994-06-07 | Nippon Furnace Kogyo Kaisha Ltd | Low nox combustion method and burner used for the same |
JPH08145315A (en) * | 1994-07-18 | 1996-06-07 | Toyota Motor Corp | Low nox burner |
JP2008249280A (en) * | 2007-03-30 | 2008-10-16 | Toho Gas Co Ltd | Gas burner |
JP2013194991A (en) | 2012-03-19 | 2013-09-30 | Jfe Steel Corp | Burner for sintering machine ignition furnace |
JP2014201809A (en) * | 2013-04-08 | 2014-10-27 | 新日鉄住金エンジニアリング株式会社 | Combustion device and operation method thereof, and rotary hearth furnace |
JP2015004483A (en) * | 2013-06-21 | 2015-01-08 | 日本ファーネス株式会社 | Fuel two-stage combustion type burner device, and fuel two-stage combustion method |
JP2016191533A (en) * | 2015-03-31 | 2016-11-10 | 大陽日酸株式会社 | Burner flame forming method |
JP2017036901A (en) * | 2015-08-13 | 2017-02-16 | 中外炉工業株式会社 | Industrial furnace and ignition method of industrial furnace |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2822864A (en) * | 1953-09-28 | 1958-02-11 | Babcock & Wilcox Co | Combination fluid fuel burner |
JPS54115645U (en) * | 1978-02-02 | 1979-08-14 | ||
JPS56158716U (en) * | 1980-04-25 | 1981-11-26 | ||
JPS58124U (en) * | 1981-06-20 | 1983-01-05 | 大阪瓦斯株式会社 | Radiant tube burner |
JPS5899607A (en) * | 1981-12-07 | 1983-06-14 | Matsushita Electric Ind Co Ltd | Burner |
JPS5899607U (en) * | 1981-12-28 | 1983-07-06 | 東芝機械株式会社 | Measuring device |
AU644350B2 (en) * | 1988-09-02 | 1993-12-09 | American Combustion, Incorporated | Method and apparatus for generating highly luminous flame |
JP2739884B2 (en) * | 1991-12-20 | 1998-04-15 | 東京瓦斯株式会社 | Burner with low nitrogen oxide generation |
JP2849977B2 (en) * | 1994-03-30 | 1999-01-27 | 矢崎総業株式会社 | Gas burner |
JP4018809B2 (en) * | 1998-06-10 | 2007-12-05 | 株式会社Nfkホールディングス | Additional combustion method using gas turbine exhaust gas and additional burner using this additional combustion method |
US20070037106A1 (en) * | 2005-08-12 | 2007-02-15 | Kobayashi William T | Method and apparatus to promote non-stationary flame |
US20070231761A1 (en) * | 2006-04-03 | 2007-10-04 | Lee Rosen | Integration of oxy-fuel and air-fuel combustion |
JP4963621B2 (en) * | 2007-03-30 | 2012-06-27 | オリンピア工業株式会社 | Low NOx gas burner |
CN101520178A (en) * | 2009-04-07 | 2009-09-02 | 湖南吉祥石化科技股份有限公司 | High-tenacity mixing low pollution combustor discharging acid gas |
JP6102009B2 (en) * | 2015-02-27 | 2017-03-29 | 大陽日酸株式会社 | GAS FUEL BURNER AND HEATING METHOD USING GAS FUEL BURNER |
WO2017048638A1 (en) * | 2015-09-14 | 2017-03-23 | Clearsign Combustion Corporation | Partially transitioned flame start-up of a perforated flame holder |
CN106152136B (en) * | 2016-08-26 | 2018-11-16 | 佛山市科皓燃烧设备制造有限公司 | The ultralow NOx fuel dilution technology heat-accumulating burner of combustion gas injection |
-
2018
- 2018-03-19 WO PCT/JP2018/010774 patent/WO2018180694A1/en unknown
- 2018-03-19 EP EP18778121.6A patent/EP3604925B1/en active Active
- 2018-03-19 CN CN201880013141.3A patent/CN110325794B/en active Active
- 2018-03-19 JP JP2019509343A patent/JP6690779B2/en active Active
- 2018-03-19 KR KR1020197025717A patent/KR102273957B1/en active IP Right Grant
- 2018-03-26 TW TW107110302A patent/TWI670457B/en active
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3302596A (en) * | 1966-01-21 | 1967-02-07 | Little Inc A | Combustion device |
JPS5218234A (en) * | 1975-07-31 | 1977-02-10 | Exxon Research Engineering Co | Multi stages air burner |
JPH06159613A (en) * | 1992-11-24 | 1994-06-07 | Nippon Furnace Kogyo Kaisha Ltd | Low nox combustion method and burner used for the same |
JPH08145315A (en) * | 1994-07-18 | 1996-06-07 | Toyota Motor Corp | Low nox burner |
JP2008249280A (en) * | 2007-03-30 | 2008-10-16 | Toho Gas Co Ltd | Gas burner |
JP2013194991A (en) | 2012-03-19 | 2013-09-30 | Jfe Steel Corp | Burner for sintering machine ignition furnace |
JP2014201809A (en) * | 2013-04-08 | 2014-10-27 | 新日鉄住金エンジニアリング株式会社 | Combustion device and operation method thereof, and rotary hearth furnace |
JP2015004483A (en) * | 2013-06-21 | 2015-01-08 | 日本ファーネス株式会社 | Fuel two-stage combustion type burner device, and fuel two-stage combustion method |
JP2016191533A (en) * | 2015-03-31 | 2016-11-10 | 大陽日酸株式会社 | Burner flame forming method |
JP2017036901A (en) * | 2015-08-13 | 2017-02-16 | 中外炉工業株式会社 | Industrial furnace and ignition method of industrial furnace |
Non-Patent Citations (1)
Title |
---|
See also references of EP3604925A4 |
Also Published As
Publication number | Publication date |
---|---|
CN110325794B (en) | 2021-07-20 |
JP6690779B2 (en) | 2020-04-28 |
EP3604925B1 (en) | 2022-05-11 |
JPWO2018180694A1 (en) | 2019-11-21 |
TW201839342A (en) | 2018-11-01 |
TWI670457B (en) | 2019-09-01 |
KR102273957B1 (en) | 2021-07-06 |
CN110325794A (en) | 2019-10-11 |
EP3604925A1 (en) | 2020-02-05 |
EP3604925A4 (en) | 2020-04-01 |
KR20190113899A (en) | 2019-10-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US10760784B2 (en) | Burner including a perforated flame holder spaced away from a fuel nozzle | |
EP2886956B1 (en) | Solid-fuel burner | |
JP5320517B1 (en) | Combustion apparatus, operating method thereof, and rotary hearth type heating furnace | |
JP6043393B2 (en) | Burner flame formation method | |
WO2018180694A1 (en) | Heating device and heating method | |
JP6458919B1 (en) | Method for producing sintered ore | |
KR101595678B1 (en) | Tubular flame burner | |
EP2653566B1 (en) | Top-firing hot blast stove | |
CN104482538A (en) | Burner for radiant tube | |
JP6825601B2 (en) | Heating device and heating method | |
JP7091386B2 (en) | Oxygen burner | |
JP6206290B2 (en) | Multiple tubular flame burner | |
JP2019168205A (en) | Burner and heating method | |
JP2001099407A (en) | Gas combustion burner | |
CZ293781B6 (en) | Burner head |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 18778121 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2019509343 Country of ref document: JP Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 20197025717 Country of ref document: KR Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2018778121 Country of ref document: EP Effective date: 20191028 |