WO2018147153A1 - Alcoholic beverage and production method therefor - Google Patents

Alcoholic beverage and production method therefor Download PDF

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Publication number
WO2018147153A1
WO2018147153A1 PCT/JP2018/003341 JP2018003341W WO2018147153A1 WO 2018147153 A1 WO2018147153 A1 WO 2018147153A1 JP 2018003341 W JP2018003341 W JP 2018003341W WO 2018147153 A1 WO2018147153 A1 WO 2018147153A1
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Prior art keywords
alcoholic beverage
decanal
octanal
alcohol
ppm
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PCT/JP2018/003341
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French (fr)
Japanese (ja)
Inventor
善久 田中
明大 井上
たまみ 鈴木
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アサヒビール株式会社
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Publication of WO2018147153A1 publication Critical patent/WO2018147153A1/en

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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12HPASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
    • C12H6/00Methods for increasing the alcohol content of fermented solutions or alcoholic beverages
    • C12H6/02Methods for increasing the alcohol content of fermented solutions or alcoholic beverages by distillation
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/04Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs
    • C12G3/06Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs with flavouring ingredients

Definitions

  • the present invention relates to an alcoholic beverage, in particular, an alcoholic beverage comprising a significant amount of a Japanese citrus (like) aroma component and a flavor component, that is, octanal and / or decanal, and a method for producing the same.
  • Alcoholic beverages are obtained by distilling brewed liquor, among which distilled liquor (spirits) that has been secondarily distilled with herbs (Juniper berries, coriander seeds, orange peel), etc.
  • distilled liquor spirits
  • herbs Japariper berries, coriander seeds, orange peel
  • gin is known.
  • flavor vodka etc. are known as flavor distilled liquors containing herb and fruit components.
  • Patent Document 1 Japanese Patent Laid-Open No. 2002-125653 proposes distilled liquor in which fruits and vegetables are soaked in high alcohol, which can be used as a perfume ingredient
  • Patent Document 2 Japanese Patent Laid-Open No. 2009-213410 proposes a liquor for cooking including a product obtained by soaking and extracting a ground condiment in high alcohol in order to mask unpleasant odor of livestock meat or seafood.
  • distilled liquor generally contains a high concentration of alcohol (content of more than about 20% to less than about 100%), so that some people prefer high alcohol feeling and alcohol stimulation. That is true.
  • alcohol content of more than about 20% to less than about 100%
  • many consumers avoid alcoholic beverages that exhibit a high alcohol feeling because of their high alcohol odor and alcohol irritation.
  • Patent Document 3 Japanese Patent Application Laid-Open No. 2012-249687 improves alcohol irritation by adding an oily component containing a higher fatty acid ester separated and recovered from single-type distilled liquor.
  • Patent Document 4 Japanese Patent Laid-Open No. 2016-119841 proposes adding 2,6-nonadienal or 2,4-decadienal to an alcoholic beverage as an alcohol stimulation masking agent.
  • Patent Document 5 Japanese Patent Application Laid-Open No. 2016-144418
  • Patent Document 5 Japanese Patent Application Laid-Open No. 2016-144418
  • distilled liquor contains high-concentration ethanol, so it can give a variety of flavors and flavors, so it is anxious for alcoholic beverages to be able to enjoy the new flavors and flavors of distilled spirits. It is also true that there are potential consumers.
  • the present inventors have recently focused on octanal and / or decanal as a substance that can achieve a Japanese citrus (like) aroma component and flavor component, and by containing these in significant amounts, the above-mentioned problems in the prior art can be achieved. It has been found that alcoholic beverages can be provided that are resolved in a higher dimension. Therefore, the present invention has been made based on such knowledge.
  • an alcoholic beverage Comprising octanal and / or decanal
  • the octanal content is 0.025 ppm or more in terms of pure alcohol, and / or It is possible to propose an alcoholic beverage characterized in that the content of the decanal is 0.015 ppm or more in terms of pure alcohol.
  • a method for producing an alcoholic beverage comprising: Prepare edible ethanol and octanal and / or decanal, In the edible ethanol, the octanal and / or the decanal is mixed, The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or It is possible to propose a method for producing an alcoholic beverage, comprising that the decanal content is 0.015 ppm or more in terms of pure alcohol.
  • Aspect of the present invention are as follows.
  • a method for producing an alcoholic beverage Prepare edible ethanol and octanal and / or decanal, In the edible ethanol, the octanal and / or the decanal is mixed, The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or The manufacturing method of the alcoholic drink which comprises making content of the said decanal into 0.015 ppm or more in alcohol conversion.
  • a method for producing an alcoholic beverage Prepare edible ethanol, octanal, and decanal, In the edible ethanol, the octanal and the decanal are mixed,
  • the manufacturing method of the alcoholic beverage which comprises making the total content of the said octanal and the said decanal into 0.035 ppm or more in conversion of pure alcohol.
  • alcohol in particular distilled liquor or spirits (gin, gin, etc.) can be obtained by containing octanal and / or decanal, which is a kind of citrus component or Japanese citrus (like) aroma component or flavor component, in a specific amount.
  • Vodka, etc. is reduced in bitterness and irritation, imparts sweetness and thickness, suppresses traditional aromas or flavors (eg, “pine odor”), and higher citrus (like) aroma
  • the alcoholic beverage which can provide flavor, and its manufacturing method can be provided.
  • the alcoholic beverage according to the present invention and the method for producing the same can add a Japanese citrus (like) aroma and flavor and can be maintained for a long time by containing octanal and / or decanal in a specific amount. Moreover, it becomes possible to make it easy to drink an alcoholic beverage by exhibiting the masking effect with respect to traditional aroma and flavor. Furthermore, it is possible to provide an alcoholic beverage with an enhanced aroma and flavor of Japanese citrus (like), and it becomes possible to find new alcoholic beverage lovers.
  • Japanese citrus fruits is a generic term for citrus fruits produced in Japan, including Japanese native species or native species, and Japanese species with improved quality.
  • “Wa Citrus” includes Unshu mandarin, Iyokan, Summer mandarin, Yawata, Isogo, Odor (Kabosu), Shikuwasa, Sudachi, Daidai, Hinata Natsu, Iyokan, Ponkan, Dekopon (Shiran), Kiyomi, Tankan, Summer mandarin, sweet summer, Mayer lemon, health, Setoka, Harumi, mandarin (Tangerine), Markot, Encore, Seminole, Banpeiyu, Buntan, Kara (Calamandarin), Amakusa, Sweetspring , Haruka, Natsumi, Harehime, Marihime, Golden Citrus, Kawachi Bankan (Miseikan), Red Manado, Himetsuki, Kanpei, Rei, C
  • Japanese citrus fruits include various components belonging to flavonoids, carotenoids, coumarins, terpenes, limonoids, etc., in the fruit (fruit), pericarp, shoots, stems, leaves or spines.
  • the aroma component and flavor component contained in Japanese citrus include octanal, decanal, nonanal, limonene, ⁇ -terpinene, linalool, ⁇ -terpineol, ⁇ -pinene, myrcene and the like.
  • Japanese citrus extract essential oil
  • the above main components can be obtained by a general extraction method.
  • a raw Japanese citrus fruit can be obtained by pressing, solvent extraction, fat (warm or cold permeation) adsorption method, It can be extracted by a supercritical extraction method or the like.
  • it is necessary to extract it based on the regulations of the Ministry of Health, Labor and Welfare, the Consumer Affairs Agency, etc. and the Food Sanitation Law.
  • Octanal (C 8 H 16 O) is a chain organic compound represented by the following chemical formula (1) and is a kind of aldehyde. It is a colorless or light yellow flammable liquid and has a citrus fruit scent. Obtained by hydroformylation of 1-heptene or oxidation of 1-octanol. It is abundant in essential oils of Japanese citrus fruits, etc., and these essential oils can be obtained through fractionation under reduced pressure and a purification process. In the present invention, it is used as a Japanese citrus (like) aroma component and flavor component.
  • Decanal Decanal: C 10 H 20 O
  • Decanal is an organic compound represented by the following chemical formula (2), a chain organic compound, which is a kind of aldehydes. It is a colorless or light yellow flammable liquid and has a citrus fruit scent. Although it is contained in the essential oil of grapefruit and lemongrass, it is industrially obtained from decanol. It is abundant in essential oils of Japanese citrus fruits, etc., and these essential oils can be obtained through fractionation under reduced pressure and a purification process. In the present invention, it is used as a Japanese citrus (like) aroma component and flavor component.
  • Alcoholic beverages are defined as “beverages with alcohol once or more” by the Liquor Tax Law, and are treated as food by the Food Sanitation Law and are subject to the law.
  • Alcoholic beverage includes brewed liquor, distilled liquor, other alcoholic beverages, or one or a mixture of two or more of these.
  • the “alcohol content” means the volume of ethyl alcohol contained in the original capacity at a temperature of fifteen degrees.
  • Alcohol content is a ratio of the volume concentration of ethanol to an alcoholic beverage expressed as a percentage (%).
  • the “extract” means the number of grams of non-volatile components contained in the original capacity of 100 cubic centimeters at a temperature of fifteen degrees.
  • ⁇ Brewed sake> Brewed sake is a generic name for alcoholic beverages that are made from yeast only by alcoholic fermentation and produced without distillation.
  • brewed liquors are defined as a) sake, b) fruit liquor, c) other brewed liquors.
  • liquor tax law classifies as sparkling liquors
  • beer and sparkling wine are also brewed sakes made by brewing.
  • simple fermented liquors such as wine (vinegar), cider (apple wine), horse liquor, etc.
  • ferment sugars as they are to obtain alcoholic beverages
  • saccharify starch and ferment the sugars saccharify starch and ferment the sugars.
  • double fermented liquors for obtaining liquors [for example, beer (single double fermented liquor), sake (parallel double fermented liquor)]. Since brewed liquor is only from alcoholic fermentation by yeast, the alcohol content is at most about 22%.
  • Distilled liquor is liquor made by distilling brewed liquor, and is basically an alcoholic beverage with a high alcohol content. Under the Liquor Tax Law, the following alcoholic beverages (excluding other sparkling alcoholic beverages): b) whiskey, d) brandy, e) It is defined as alcohol for raw materials, f) spirits. Distilled liquor includes those obtained by adding water to distilled alcohol or aging in a wooden barrel or the like.
  • gin raw materials: barley, rye, potatoes, herbs, etc.
  • vodka raw materials: rye, grains, sugar beet, fruits, potatoes, etc.
  • spiritus raw materials: cereals, potatoes, herbs, etc.
  • awamori raw materials: Indica rice, grains, etc.
  • shochu raw materials: rice, wheat, sweet potato, brown sugar, buckwheat, chestnut, sake lees, molasses, etc.
  • Soju "Korean shochu” raw materials: rice, potato, wheat, barley, sweet potato, tapioca, etc.
  • White liquor paichu made from cereals, and daidai dairy made from high grapes, etc.
  • mescal or tequila raw materials: dragon tongue orchid
  • whiskey raw materials: barley, rye, corn, etc.
  • brandy fruit wine is the raw material.
  • “Spirit” is liquor tax law b) liquor other than raw alcohol, b) whiskey, d) brandy, or e) liquor other than raw alcohol. belongs to.
  • “Gin” is made from cereals (barley, rye, potatoes, etc.), and is made from malt and enzyme, saccharified, fermented and distilled, with spirits such as juniper berries. A colorless and transparent liquor that has been scented by dipping grass root bark, etc., and distilled again, and has a flavor and flavor unique to the aroma component of grass root bark.
  • “Vodka” is made from cereals (rye, grains, sugar beet, fruit, potatoes, corn, wheat, barley, etc.) as raw materials, and saccharified, fermented and distilled.
  • “Rum” is a spirit made from the molasses after simmering sugarcane juice and crystallizing the sugar, followed by fermentation, distillation, and aging.
  • the content is basically expressed in ppm, that is, mg / L (mass / volume) unless otherwise specified in the present specification.
  • the alcoholic beverage comprises octanal and / or decanal.
  • the content of octanal is 0.025 ppm or more in terms of pure alcohol, preferably 0.03 ppm or more, and more preferably 0.035 ppm or more.
  • the upper limit value of the octanal content in the alcoholic beverage is the maximum value that can be contained in the alcoholic beverage in terms of pure alcohol, preferably 50 ppm or less, more preferably 2.5 ppm. It is as follows.
  • Octanal presents a Japanese citrus (like) fragrance component and a flavor component, and by adding it to an alcoholic beverage, it reduces the bitterness and pungent taste derived from alcohol, imparts sweetness and thickness, And flavor (e.g., "pine odor") can be suppressed, or Japanese citrus (like) aroma and flavor can be added in higher dimensions.
  • the effect of the present invention can be further enhanced by containing octanal in the above content.
  • the content of decanal is 0.015 ppm or more, preferably 0.02 ppm or more, more preferably 0.025 ppm or more in terms of pure alcohol.
  • the upper limit of the content of decanal in the alcoholic beverage is the maximum value that can be contained in the alcoholic beverage in terms of pure alcohol, preferably 50 ppm or less, more preferably 2.5 ppm. It is as follows.
  • Decanal presents Japanese citrus (like) fragrance and flavor components, and by adding it to alcoholic beverages, it reduces the bitterness and pungent taste derived from alcohol, imparts sweetness and thickness, And flavor (e.g., "pine odor") can be suppressed, or Japanese citrus (like) aroma and flavor can be added in higher dimensions.
  • the effect of the present invention can be further enhanced by containing octanal in the above content.
  • the alcoholic beverage comprises octanal and decanal.
  • the total content of octanal and decanal is 0.035 ppm or more, preferably 0.04 ppm or more, more preferably 0.045 ppm or more in terms of pure alcohol.
  • the upper limit of the total content of octanal and decanal in the alcoholic beverage is the maximum value that can be contained in the alcoholic beverage in terms of pure alcohol, preferably 50 ppm or less, more preferably 5 ppm or less.
  • the effects of the present invention can be synergized.
  • other aroma and flavor components unique to Japanese citrus it achieves a synergistic effect that is more than the addition of excellent Japanese citrus (like) aroma and flavor components.
  • Like) Aroma or flavor can be added.
  • the fragrance component and flavor component (Japanese flavor and flavor) derived from Japanese citrus of the Japanese native species (conventional species) As a contained alcoholic beverage, it can be proposed to the domestic and foreign markets in Japan.
  • octanal and / or decanal those extracted from a natural product or an artificial product by a method acceptable as a food additive can be used.
  • octanal and / or decanal may be synthesized by a food chemistry-acceptable technique, but only those having established food safety are preferably used.
  • the octanal and / or decanal is a substance present as a main component of an extract (for example, an edible ethanol soak) or an essential oil (extract) from a Japanese citrus, preferably a Japanese native citrus. It's okay.
  • Japanese citrus Various kinds of Japanese citrus can be used, but they are native to Japan or native species, such as Unshu mandarin, Iyokan, Summer mandarin, Yahata, Isogo, Smell orange (Kavos), Shikuwasa, Sudachi, Daidai, Hyuga summer, Iyokan, Ponkan, Deconpon, Kiyomi, Tankan, Summer orange, Sweet summer, Mayer lemon, Health, Setoka, Harumi, Tankan (Tangerine), Marcot, Encore, Seminole, Banpakuyu, Banpeiyu, Buntan, Kara (Karamandarin), Amakusa, Sweet Spring, Haruka, Nantsukai (Natsumi), Harehime, Marihime, Golden Tangerine, Kawachi Bankan (Miseikan), Red Miso, Himetsuki One or a mixture of two or more selected from the group consisting of Kanpei, Rei, Clementine, Cocktail Fruit, and Mineola
  • sweet summer and / or kabos are preferably used.
  • the skin, fruit (fruit juice), shoots, leaves, stems or spines can be used, and preferably the fruit skin and fruit (fruit juice) can be used.
  • Japanese citrus fruits are available from various producers and agricultural cooperatives in Japan.
  • the alcoholic beverage according to the present invention preferably has an alcohol content of 10 degrees (%) or more, more preferably a lower limit value of 30 degrees (%) or more and an upper limit value of about 100 degrees (%) or less.
  • the alcohol content is within the above range, the effect of adding a specific content of octanal and / or decanal can be more exhibited.
  • Alcoholic beverages can contain pigments, flavorings, sweeteners, acidulants, pH adjusters, antioxidants, preservatives, vitamins, umami ingredients, dietary fiber, stabilizers, and emulsifiers as optional ingredients. is there. These are the ones stipulated in the guidelines established by the Ministry of Health, Labor and Welfare, the Consumer Affairs Agency, and related laws and regulations (Food Sanitation Law, etc.).
  • the alcoholic beverage may be any one as long as it contains a specific content of octanal and / or decanal as an essential component, for example, edible ethanol added with a specific content of octanal and / or decanal. It may be. Preferably, it may be brewed liquor, distilled liquor and one of these mixed liquors, or a mixture of two or more of these. More preferably, it is a mixed liquor of one or two or more kinds of brewed liquor and one or more kinds of distilled liquors, and the most preferable one is one or two or more kinds of distilled liquors. In the present invention, the alcoholic beverage is distilled liquor, particularly preferably spirits or shochu.
  • “Brewed sake” is refined sake, fruit wine, or other brewed sake, and examples thereof include wine (grape), cider (apple liquor), horse milk, beer, and sake, preferably high concentrations. Wine, cider and sake are used.
  • Disistilled liquor includes, for the sake of liquor tax law, those that are included in continuous distillation, single distillation, whiskey, brandy, alcohol for raw materials, spirits, preferably continuous distillation, It is a simple distillation scent, brandy, or spirits.
  • distilled liquor generally, gin, vodka, spiritus, shochu, soju, white liquor, mescal, tequila, whiskey, brandy (armagnac, calvados, grappa, cognac, singani, pisco, etc.), cachasassa, pinga, rum, Arrack, Korn, Kirschwasser and the like can be mentioned, preferably gin, vodka, spiritus, shochu, soju, white liquor, mescal, tequila, brandy, alac, and more preferably gin, vodka, spiritus and shochu. Most preferably, gin or shochu is used.
  • One aspect of the present invention is a method of producing an alcoholic beverage, Prepare edible ethanol and octanal and / or decanal, The edible ethanol is mixed with the octanal and / or the decanal (preferably at room temperature and atmospheric pressure), The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or The manufacturing method of the alcoholic beverage which comprises making content of the said decanal into 0.015 ppm or more in conversion of alcohol is proposed.
  • Another aspect of the present invention is a method of producing an alcoholic beverage, Prepare edible ethanol, octanal, and decanal, In the edible ethanol, the octanal and the decanal are mixed,
  • the manufacturing method of the alcoholic beverage which comprises making the total content of the said octanal and the said decanal into 0.035 ppm or more in conversion of pure alcohol is proposed.
  • the method for producing an alcoholic beverage according to the present invention is produced by containing edible alcohol (ethanol) with a specific content of octanal and / or decanal as an essential component.
  • edible alcohol ethanol
  • the distilled alcohol containing octanal and / or decanal as an essential component is included in the edible alcohol (ethanol). It is. Distillation may be carried out at normal pressure or reduced pressure, but is preferably reduced pressure.
  • brewed liquor, distilled liquor and one of these mixed liquors, or a mixture of two or more of these may contain a specific content of octanal and / or decanal, or a significant amount of Japanese citrus is soaked Then, it is distilled, and the resulting Japanese citrus distilled liquor may be added to adjust the octanal and / or decanal to a specific content.
  • a specific content of octanal and / or decanal By containing a specific content of octanal and / or decanal, the original flavor and flavor of the brewed liquor and distilled liquor can be improved, and the aroma component can be reduced / suppressed.
  • the raw materials eg, octanal, decanal, edible alcohol (ethanol), Japanese citrus], content, adjustment, and the like may be the same as described in the above section [Alcoholic beverage]. .
  • a container-packed alcoholic beverage in which an alcoholic beverage is packed in a container can be proposed.
  • a container-packed alcoholic beverage maintaining the reduction of bitterness and pungent taste derived from alcohol, and maintaining sweetness and thickness, and maintaining traditional fragrance and flavor suppression, and higher citrus (like) fragrance or While maintaining the flavor, it becomes possible to provide convenience, distribution convenience, storage stability, and quality deterioration prevention of alcoholic beverages.
  • the container can be packed into containers formed in various shapes with vinyl, plastic, glass, metal, paper, wood or leather, etc., as long as the contents do not leak.
  • the container may be provided with a material (for example, a colored or functional film, a metal foil) for blocking light, heat, oxygen, ultraviolet rays, etc. inside and outside the container.
  • Example 1 Sweet summer, from which fruit juice was removed by squeezing, was soaked in 65% alcohol for two days and distilled under reduced pressure to obtain a sweet summer distilled liquor.
  • Example 2 Cabos from which juice was removed by squeezing was soaked in 65% alcohol for two days and nights, and distilled under reduced pressure to obtain Kavos distilled liquor.
  • Comparative Examples 1 to 3 Commercial distilled liquor>
  • “Seasonal Beauty” (alcohol 45%, gin, manufactured by Kyoto Distillery) was used.
  • Comparative Example 2 “WILKINSON GIN 47.5 °” (alcohol 47%, gin, manufactured by Asahi Breweries) was used.
  • Comparative Example 3 “WILKINSON GIN 37 °” (alcohol 37%, gin, manufactured by Asahi Breweries) was used.
  • Examples 1 and 2 were samples diluted 15 times with ultrapure water, and Comparative Examples 1 to 3 were samples diluted 5 times with ultrapure water. After adding 200 ⁇ L of an internal standard (10 ppm linalool-d5) to a 1 mL sample, the sample was diluted 50 times with ultrapure water. The aroma component of the diluted sample was adsorbed on Twister (40 ° C., 2 hours), subjected to GC-MS analysis, and quantified by an internal standard method.
  • an internal standard 10 ppm linalool-d5
  • ⁇ GC condition> ⁇ Equipment: Temperature rising vaporization inlet (CIS4, manufactured by Gerstel), thermal desorption unit (TDU, manufactured by Gerstel), GC System (7890B, manufactured by Agilent Technologies), Mass Selective Detector (5977, manufactured by Agilent Technologies) LTM column (1st: DB-WAX, 20 m ⁇ 0.18 mm; 0.3 ⁇ m, 2nd: DB-5, 10 m ⁇ 0.18 mm; 0.4 ⁇ m, manufactured by Agilent Technologies) TDU: 20 ° C. (1 min) ⁇ (720 ° C./min) ⁇ 250° C.
  • Table 1 shows the octanal content and decanal content in Examples and Comparative Examples.
  • Example 1 and Example 2 were high alcoholic beverages containing octanal and decanal in high significant amounts. It was understood that the distilled liquor (Comparative Example 1) did not contain any octanal or decanal.
  • Comparative Example 2 evaluation criteria
  • Ease of drinking was set to “2 points”.
  • the average score of the six panelists was calculated, and compared with Comparative Example 2, it was judged that there was an effect when there was a difference of 0.5 points or more in the average score.
  • the examples contained a specific amount of octanal and / or a specific amount of decanal in the alcoholic beverage, thereby giving the alcoholic beverage a high level of Japanese citrus (like) aroma and flavor. It was revealed that sweetness and thickness were imparted, pine odor, bitterness and irritation were reduced, and the ease of drinking was improved.

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Abstract

Provided is an alcoholic beverage that has reduced alcohol-derived bitterness and irritativeness, provides sweetness and depth, suppresses traditional aroma and flavor, or provides a novel aroma and flavor. This alcoholic beverage has an octanal content of at least 0.025 ppm in terms of pure alcohol and/or a decanal content of at least 0.015 ppm in pure alcohol terms.

Description

アルコール飲料及びその製造方法Alcoholic beverage and method for producing the same
 本発明は、アルコール飲料、とりわけ、和柑橘類(様)香気成分及び風味成分、即ち、オクタナール及び/又はデカナールを有意量含んでなるアルコール飲料及びその製造方法に関する。 The present invention relates to an alcoholic beverage, in particular, an alcoholic beverage comprising a significant amount of a Japanese citrus (like) aroma component and a flavor component, that is, octanal and / or decanal, and a method for producing the same.
 アルコール飲料、とりわけ、蒸留酒は、醸造酒を蒸留することにより得られるものであり、その中でも、香草(ジュニパーベリー、コリアンダーシード、オレンジ果皮)等と伴に二次蒸留された蒸留酒(スピリッツ)としては、ジンが知られている。また、香草及び果実の成分を含有したフレーバー蒸留酒としては、フレーバーウォッカ等が知られている。 Alcoholic beverages, especially distilled liquor, are obtained by distilling brewed liquor, among which distilled liquor (spirits) that has been secondarily distilled with herbs (Juniper berries, coriander seeds, orange peel), etc. For example, gin is known. Moreover, flavor vodka etc. are known as flavor distilled liquors containing herb and fruit components.
 また、近年、特定用途のために、果物及び野菜等を浸漬した蒸留酒が提案されている。例えば、特許文献1(特開2002-125653号公報)では、香料成分に代用できる、果物及び野菜を高アルコールに浸漬した蒸留酒が提案されており、又、特許文献2(特開2009-213410号公報)では、畜肉又は魚介類の不快臭のマスキングの為に、磨砕した薬味料を高アルコールに浸漬抽出したものを包含した料理用酒類が提案されている。 In recent years, distilled liquor soaked with fruits and vegetables has been proposed for specific uses. For example, Patent Document 1 (Japanese Patent Laid-Open No. 2002-125653) proposes distilled liquor in which fruits and vegetables are soaked in high alcohol, which can be used as a perfume ingredient, and Patent Document 2 (Japanese Patent Laid-Open No. 2009-213410). No. 1) proposes a liquor for cooking including a product obtained by soaking and extracting a ground condiment in high alcohol in order to mask unpleasant odor of livestock meat or seafood.
 ところで、蒸留酒は、一般に高濃度のアルコール(約20%超過~約100%未満の含有量)を含有するものであることから、嗜好者には高アルコール感及びアルコール刺激性を好む者もいることは事実である。しかし、一般消費者は、逆に、アルコール臭気並びにアルコール刺激性が高いために、高アルコール感を呈するアルコール飲料を敬遠する者も多い。    By the way, distilled liquor generally contains a high concentration of alcohol (content of more than about 20% to less than about 100%), so that some people prefer high alcohol feeling and alcohol stimulation. That is true. However, on the contrary, many consumers avoid alcoholic beverages that exhibit a high alcohol feeling because of their high alcohol odor and alcohol irritation. *
 アルコール刺激性に対しては、特許文献3(特開2012-249587号公報)では、単式蒸留酒から分離・回収した高級脂肪酸エステルを含有する油性成分を添加することにより、アルコールの刺激感を改善し、味わい及びまろやかさを増加させた、単式・連続式混和蒸留酒が提案されている。また、特許文献4(特開2016-119841号公報)では、アルコール刺激感マスキング剤として、2,6-ノナジエナール又は2,4-デカジエナールをアルコール飲料に添加することが提案されている。他方、特許文献5(特開2016-144418号公報)では、柑橘類由来の爽快感及び新鮮感を付与するために、ジン由来のアルコールと、約10体積%の柑橘類果汁を含有した、5体積%未満の低アルコール飲料が提案されている。 For alcohol irritation, Patent Document 3 (Japanese Patent Application Laid-Open No. 2012-249687) improves alcohol irritation by adding an oily component containing a higher fatty acid ester separated and recovered from single-type distilled liquor. However, single and continuous mixed distilled spirits with increased taste and mellowness have been proposed. Patent Document 4 (Japanese Patent Laid-Open No. 2016-119841) proposes adding 2,6-nonadienal or 2,4-decadienal to an alcoholic beverage as an alcohol stimulation masking agent. On the other hand, in Patent Document 5 (Japanese Patent Application Laid-Open No. 2016-144418), in order to impart a refreshing feeling and fresh feeling derived from citrus fruits, 5% by volume containing gin-derived alcohol and about 10% by volume citrus fruit juice. Less than low alcohol drinks have been proposed.
 また、一般消費者の中には、伝統的なスピリッツに包含される香草(実)、薬草(実)の香気又は風味を嫌う者も存在する。例えば、ジンに含まれるジュニパーベリーの香気が、所謂、「松脂臭い」、又は、コリアンダーの香気が、所謂、「虫(カメムシ)臭い又は青臭い」、という嫌臭気として捉える消費者も存在する。 Also, among general consumers, there are those who dislike the aroma or flavor of herbs (fruits) and medicinal herbs (fruits) included in traditional spirits. For example, there is a consumer who regards the aroma of juniper berry contained in gin as a so-called “pine odor” or a smell of coriander that is a so-called “stink bug or blue odor”.
 その一方で、蒸留酒は高濃度のエタノールを含有することから、様々な香味及び風味を付与することができるため、新たな蒸留酒固有の香気、風味等を堪能することができるアルコール飲料を切望する潜在的な消費者が存在することも事実である。 On the other hand, distilled liquor contains high-concentration ethanol, so it can give a variety of flavors and flavors, so it is anxious for alcoholic beverages to be able to enjoy the new flavors and flavors of distilled spirits. It is also true that there are potential consumers.
 しかしながら、アルコール由来の苦味及び刺激味を低減させ、甘さ及び厚みを付与し、伝統的な香気又は風味を抑制し、或いは、新たな香気又は風味を付加したアルコール飲料は未だ十分には開発されていない。 However, alcoholic beverages that reduce the bitterness and pungent taste derived from alcohol, impart sweetness and thickness, suppress traditional fragrances or flavors, or add new fragrances or flavors are still fully developed. Not.
 よって、今尚、新たな香気成分又は風味成分を付与した、新たなアルコール飲料の提案が切望されている。 Therefore, the proposal of a new alcoholic beverage to which a new aroma component or flavor component is added is still eagerly desired.
 本発明者等は、今般、和柑橘類(様)香気成分及び風味成分を達成しうる物質として、オクタナール及び/又はデカナールに着目し、これらを有意量で含有することにより、従来技術における上記課題を高い次元において解決したアルコール飲料を提供できることを見出した。従って、本発明は、係る知見に基づいてなされたものである。 The present inventors have recently focused on octanal and / or decanal as a substance that can achieve a Japanese citrus (like) aroma component and flavor component, and by containing these in significant amounts, the above-mentioned problems in the prior art can be achieved. It has been found that alcoholic beverages can be provided that are resolved in a higher dimension. Therefore, the present invention has been made based on such knowledge.
 よって、本発明によれば、アルコール飲料であって、
 オクタナール及び/又はデカナールとを含んでなり、
 前記オクタナールの含有量が純アルコール換算で0.025ppm以上であり、及び/又は、
 前記デカナールの含有量が純アルコール換算で0.015ppm以上であることを特徴とする、アルコール飲料を提案することができる。
Thus, according to the present invention, an alcoholic beverage,
Comprising octanal and / or decanal,
The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or
It is possible to propose an alcoholic beverage characterized in that the content of the decanal is 0.015 ppm or more in terms of pure alcohol.
 別の態様によれば、アルコール飲料を製造する方法であって、
 食用エタノールと、オクタナール及び/又はデカナールとを用意し、
 前記食用エタノールに、前記オクタナール及び/又は前記デカナールを混合し、
 前記オクタナールの含有量が純アルコール換算で0.025ppm以上としてなり、及び/又は、
 前記デカナールの含有量が純アルコール換算で0.015ppm以上としてなることを含んでなる、アルコール飲料の製造方法を提案することができる。
According to another aspect, a method for producing an alcoholic beverage, comprising:
Prepare edible ethanol and octanal and / or decanal,
In the edible ethanol, the octanal and / or the decanal is mixed,
The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or
It is possible to propose a method for producing an alcoholic beverage, comprising that the decanal content is 0.015 ppm or more in terms of pure alcohol.
 〔本発明の態様〕
 本発明の態様は以下の通りである。
 〔1〕 アルコール飲料であって、
 オクタナール及び/又はデカナールを含んでなり、
 前記オクタナールの含有量が純アルコール換算で0.025ppm以上であり、及び/又は、
 前記デカナールの含有量が純アルコール換算で0.015ppm以上であることを特徴とする、アルコール飲料。
 〔2〕 アルコール飲料であって、
 オクタナール及びデカナールを含んでなり、
 前記オクタナール及び前記デカナールの合計含有量が純アルコール換算で0.035ppm以上であることを特徴とする、アルコール飲料。
 〔3〕 前記オクタナール及び/又は前記デカナールが和柑類橘から抽出されたものである、上記〔1〕又は〔2〕に記載のアルコール飲料。
 〔4〕 前記和柑橘類が、温州ミカン、伊予柑、夏ミカン、八朔、柚子、臭橙(カボス)、シークワサー、すだち、ダイダイ、日向夏、伊予柑、ぽんかん、デコポン(不知火)、清見、たんかん、夏みかん、甘夏、マイヤーレモン、げんこう、せとか、はるみ、たんかん(桶柑)、マーコット、アンコール、セミノール、晩白柚(ばんぺいゆ)、文旦(ブンタン)、カラ(カラマンダリン)、天草、スイートスプリング、はるか、南津海 (なつみ)、はれひめ、まりひめ、黄金柑、河内晩柑(美生柑)、紅まどんな、ひめのつき、甘平、麗紅、クレメンタイン、カクテルフルーツ、及びミネオラからなる群から選択される一種又は二種以上の混合物である、上記〔3〕に記載のアルコール飲料。
 〔5〕 前記和柑橘類が甘夏及び/又は臭橙(カボス)である、上記〔1〕~〔3〕の何れか一項に記載のアルコール飲料。
 〔6〕 アルコール度数が10度以上である、上記〔1〕~〔5〕の何れか一項〕に記載のアルコール飲料。
 〔7〕 前記アルコール飲料が蒸留酒である、上記〔1〕~〔6〕の何れか一項に記載のアルコール飲料。
 〔8〕 前記アルコール飲料がスピリッツ又は焼酎である、上記〔1〕~〔6〕の何れか一項に記載のアルコール飲料。
 〔9〕 前記スピリッツがジンである、上記〔8〕に記載のアルコール飲料。
 〔10〕 アルコール飲料を製造する方法であって、
 食用エタノールと、オクタナール及び/又はデカナールとを用意し、
 前記食用エタノールに、前記オクタナール及び/又は前記デカナールを混合し、
 前記オクタナールの含有量を純アルコール換算で0.025ppm以上としてなり、及び/又は、
 前記デカナールの含有量をアルコール換算で0.015ppm以上としてなることを含んでなる、アルコール飲料の製造方法。
 〔11〕 アルコール飲料を製造する方法であって、
 食用エタノールと、オクタナールと、デカナールとを用意し、
 前記食用エタノールに、前記オクタナール及び前記デカナールを混合し、
 前記オクタナール及び前記デカナールの合計含有量を純アルコール換算で0.035ppm以上としてなることを含んでなる、アルコール飲料の製造方法。
[Aspect of the Invention]
Aspects of the present invention are as follows.
[1] An alcoholic beverage,
Comprising octanal and / or decanal,
The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or
An alcoholic beverage, wherein the decanal content is 0.015 ppm or more in terms of pure alcohol.
[2] An alcoholic beverage,
Comprising octanal and decanal,
An alcoholic beverage, wherein the total content of octanal and decanal is 0.035 ppm or more in terms of pure alcohol.
[3] The alcoholic beverage according to [1] or [2] above, wherein the octanal and / or the decanal is extracted from Japanese citrus citrus.
[4] The Japanese citrus fruits are Wenzhou mandarin orange, Iyokan, Summer mandarin orange, Yahata, Isogo, Smell orange (Kabosu), Sikhwasa, Sudachi, Daidai, Hinata Natsu, Iyokan, Ponkan, Dekopon (Shiran), Kiyomi, Tankan , Summer orange, sweet summer, Mayer lemon, health, setoka, harumi, mandarin orange, marcot, encore, seminole, banbaiyu, bundan, kara (calamandarin), amakusa, sweet Spring, Haruka, Natsumi, Harehime, Marihime, Golden Citrus, Kawachi Bankan (Miseikan), Red Manado, Himetsuki, Kanpei, Rei, Clementine, Cocktail Fruit, and Mineola The alcoholic beverage according to [3] above, which is one or a mixture of two or more selected from the group consisting of:
[5] The alcoholic beverage according to any one of [1] to [3], wherein the Japanese citrus fruits are sweet summer and / or odor orange (kabosu).
[6] The alcoholic beverage according to any one of [1] to [5] above, wherein the alcohol content is 10 degrees or more.
[7] The alcoholic beverage according to any one of [1] to [6], wherein the alcoholic beverage is distilled liquor.
[8] The alcoholic beverage according to any one of [1] to [6], wherein the alcoholic beverage is spirits or shochu.
[9] The alcoholic beverage according to [8], wherein the spirit is gin.
[10] A method for producing an alcoholic beverage,
Prepare edible ethanol and octanal and / or decanal,
In the edible ethanol, the octanal and / or the decanal is mixed,
The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or
The manufacturing method of the alcoholic drink which comprises making content of the said decanal into 0.015 ppm or more in alcohol conversion.
[11] A method for producing an alcoholic beverage,
Prepare edible ethanol, octanal, and decanal,
In the edible ethanol, the octanal and the decanal are mixed,
The manufacturing method of the alcoholic beverage which comprises making the total content of the said octanal and the said decanal into 0.035 ppm or more in conversion of pure alcohol.
 本発明によれば、柑橘類の成分の一種或いは和柑橘類(様)香気成分又は風味成分である、オクタナール及び/又はデカナールを特定量で含有させることにより、アルコール、特に、蒸留酒又はスピリッツ(ジン、ウォッカ等)由来の苦味及び刺激味を低減させ、甘さ及び厚みを付与し、伝統的な香気又は風味(例えば、「松脂臭い」)を抑制し、並びに、高い次元において和柑橘類(様)香気又は風味を付与することができるアルコール飲料及びその製造方法を提供することができる。 According to the present invention, alcohol, in particular distilled liquor or spirits (gin, gin, etc.) can be obtained by containing octanal and / or decanal, which is a kind of citrus component or Japanese citrus (like) aroma component or flavor component, in a specific amount. Vodka, etc.) is reduced in bitterness and irritation, imparts sweetness and thickness, suppresses traditional aromas or flavors (eg, “pine odor”), and higher citrus (like) aroma Or the alcoholic beverage which can provide flavor, and its manufacturing method can be provided.
 その結果、本発明によるアルコール飲料及びその製造方法は、オクタナール及び/又はデカナールを特定量で含有させることにより、和柑橘類(様)香気及び風味を付与し、長期間保持することが可能となる。また、伝統的な香気及び風味に対するマスキング的な効果を発揮させることにより、アルコール飲料を飲み易くすることが可能となる。さらに、和柑橘類(様)香気及び風味を高めたアルコール飲料を提供することができ、新たなアルコール飲料嗜好者の発掘を可能とする。 As a result, the alcoholic beverage according to the present invention and the method for producing the same can add a Japanese citrus (like) aroma and flavor and can be maintained for a long time by containing octanal and / or decanal in a specific amount. Moreover, it becomes possible to make it easy to drink an alcoholic beverage by exhibiting the masking effect with respect to traditional aroma and flavor. Furthermore, it is possible to provide an alcoholic beverage with an enhanced aroma and flavor of Japanese citrus (like), and it becomes possible to find new alcoholic beverage lovers.
 〔定義〕
 (和柑橘類)
 〈種類〉
 「和柑橘類」は、日本原産種又は在来種、日本種を品質改良したものが含まれ、かつ、日本で生産される柑橘類の総称である。「和柑橘」には、温州ミカン、伊予柑、夏ミカン、八朔、柚子、臭橙(カボス)、シークワサー、すだち、ダイダイ、日向夏、伊予柑、ぽんかん、デコポン(不知火)、清見、たんかん、夏みかん、甘夏、マイヤーレモン、げんこう、せとか、はるみ、たんかん(桶柑)、マーコット、アンコール、セミノール、晩白柚(ばんぺいゆ)、文旦(ブンタン)、カラ(カラマンダリン)、天草、スイートスプリング、はるか、南津海 (なつみ)、はれひめ、まりひめ、黄金柑、河内晩柑(美生柑)、紅まどんな、ひめのつき、甘平、麗紅、クレメンタイン、カクテルフルーツ、又はミネオラ等が例示される。
[Definition]
(Japanese citrus)
<type>
“Japanese citrus fruits” is a generic term for citrus fruits produced in Japan, including Japanese native species or native species, and Japanese species with improved quality. “Wa Citrus” includes Unshu mandarin, Iyokan, Summer mandarin, Yawata, Isogo, Odor (Kabosu), Shikuwasa, Sudachi, Daidai, Hinata Natsu, Iyokan, Ponkan, Dekopon (Shiran), Kiyomi, Tankan, Summer mandarin, sweet summer, Mayer lemon, health, Setoka, Harumi, mandarin (Tangerine), Markot, Encore, Seminole, Banpeiyu, Buntan, Kara (Calamandarin), Amakusa, Sweetspring , Haruka, Natsumi, Harehime, Marihime, Golden Citrus, Kawachi Bankan (Miseikan), Red Manado, Himetsuki, Kanpei, Rei, Clementine, Cocktail Fruit, Mineola, etc. Is exemplified.
 〈主要成分〉
 和柑橘類は、その果実(果肉)、果皮、新芽、茎、葉又は棘等に、フラボノイド類、カロテノイド類、クマリン類、テルペン類、リモノイド類等に属する様々な成分を包含する。和柑橘に含まれる香気成分及び風味成分としては、オクタナール、デカナール、ノナナール、リモネン、γ-テルピネン、リナロール、α-テルピネオール、α-ピネン、ミルセン等が例示される。
<Main ingredients>
Japanese citrus fruits include various components belonging to flavonoids, carotenoids, coumarins, terpenes, limonoids, etc., in the fruit (fruit), pericarp, shoots, stems, leaves or spines. Examples of the aroma component and flavor component contained in Japanese citrus include octanal, decanal, nonanal, limonene, γ-terpinene, linalool, α-terpineol, α-pinene, myrcene and the like.
 和柑橘類のエキス(精油)並びに上記主要成分は、一般的な抽出方法によって得ることができ、例えば、原料の和柑橘類を、圧搾法、溶媒抽出法、油脂(温浸透又は冷浸透)吸着法、超臨界抽出法等によって、抽出することができる。飲食料品に使用する場合には、厚生労働省、消費者庁等所管のガイドライン及び食品衛生法等の規定に基づいて抽出することが必要である。 Japanese citrus extract (essential oil) and the above main components can be obtained by a general extraction method. For example, a raw Japanese citrus fruit can be obtained by pressing, solvent extraction, fat (warm or cold permeation) adsorption method, It can be extracted by a supercritical extraction method or the like. When used for food and drink products, it is necessary to extract it based on the regulations of the Ministry of Health, Labor and Welfare, the Consumer Affairs Agency, etc. and the Food Sanitation Law.
 (オクタナール)
 オクタナール(Octanal:C16O)は、下記化学式(1)で表される鎖状有機化合物であり、アルデヒドの一種である。無色又は淡黄色の可燃性の液体であり、柑橘類の果実香を有する。1-ヘプテンのヒドロホルミル化、または1-オクタノールの酸化により得られる。和柑橘類の精油等に多く存在し、これらの精油を減圧分留し、精製工程等を経て得ることができる。本発明にあっては、和柑橘類(様)香気成分及び風味成分として使用する。
Figure JPOXMLDOC01-appb-C000001
(Octanal)
Octanal (C 8 H 16 O) is a chain organic compound represented by the following chemical formula (1) and is a kind of aldehyde. It is a colorless or light yellow flammable liquid and has a citrus fruit scent. Obtained by hydroformylation of 1-heptene or oxidation of 1-octanol. It is abundant in essential oils of Japanese citrus fruits, etc., and these essential oils can be obtained through fractionation under reduced pressure and a purification process. In the present invention, it is used as a Japanese citrus (like) aroma component and flavor component.
Figure JPOXMLDOC01-appb-C000001
 (デカナール)
 デカナール(Decanal:C1020O)は、下記化学式(2)で表される有機化合物であり、鎖状有機化合物であり、アルデヒドの一種である。無色又は淡黄色の可燃性の液体であり、柑橘類の果実香を有する。グレープフルーツやレモングラスの精油に含まれるが、産業的にはデカノールより得られる。和柑橘類の精油等に多く存在し、これらの精油を減圧分留し、精製工程等を経て得ることができる。本発明にあっては、和柑橘類(様)香気成分及び風味成分として使用する。
Figure JPOXMLDOC01-appb-C000002
(Decanal)
Decanal (Decanal: C 10 H 20 O ) is an organic compound represented by the following chemical formula (2), a chain organic compound, which is a kind of aldehydes. It is a colorless or light yellow flammable liquid and has a citrus fruit scent. Although it is contained in the essential oil of grapefruit and lemongrass, it is industrially obtained from decanol. It is abundant in essential oils of Japanese citrus fruits, etc., and these essential oils can be obtained through fractionation under reduced pressure and a purification process. In the present invention, it is used as a Japanese citrus (like) aroma component and flavor component.
Figure JPOXMLDOC01-appb-C000002
 (アルコール飲料)
 「アルコール飲料」は、酒税法で「アルコール分一度以上の飲料」と定義されており、食品衛生法でも食品として扱われ、当該法律の適用を受けるものである。「アルコール飲料」としては、醸造酒、蒸留酒、その他の酒類、又はこれらの一種又は二種以上の混合酒が含まれる。なお、酒税法に定義されている通り、「アルコール分」とは、温度十五度の時において原容量百分中に含有するエチルアルコールの容量をいう。「アルコール度数」とは、アルコール飲料に対するエタノールの体積濃度を百分率(%)で表した割合である。また、「エキス分」とは、温度十五度の時において原容量百立方センチメートル中に含有する不揮発性成分のグラム数をいう。
(Alcoholic beverage)
“Alcoholic beverages” are defined as “beverages with alcohol once or more” by the Liquor Tax Law, and are treated as food by the Food Sanitation Law and are subject to the law. “Alcoholic beverage” includes brewed liquor, distilled liquor, other alcoholic beverages, or one or a mixture of two or more of these. As defined in the Liquor Tax Law, the “alcohol content” means the volume of ethyl alcohol contained in the original capacity at a temperature of fifteen degrees. “Alcohol content” is a ratio of the volume concentration of ethanol to an alcoholic beverage expressed as a percentage (%). The “extract” means the number of grams of non-volatile components contained in the original capacity of 100 cubic centimeters at a temperature of fifteen degrees.
 〈醸造酒〉
 醸造酒は、原料を酵母によりアルコール発酵のみで作られ、蒸留等を行わず製造される酒類の総称である。酒税法では、醸造酒類として、イ)清酒、ロ)果実酒、ハ)その他の醸造酒と定義されている。そのほかに、酒税法では発泡性酒類として分類されているが、ビール及び発泡酒等もまた醸造によって作られる醸造酒である。醸造酒には、糖類をそのまま発酵させて酒類を得る単発酵酒〔例えば、ワイン(ブドウ酒)、シードル(リンゴ酒)、馬乳酒等〕と、でんぷんを糖化し、その糖類を発酵させて酒類を得る複発酵酒〔例えば、ビール(単行複発酵酒)、日本酒(並行複発酵酒)〕とがある。醸造酒は、酵母によるアルコール発酵のみによるものであることから、アルコール度数は高くとも約22%程度である。
<Brewed sake>
Brewed sake is a generic name for alcoholic beverages that are made from yeast only by alcoholic fermentation and produced without distillation. Under the Liquor Tax Law, brewed liquors are defined as a) sake, b) fruit liquor, c) other brewed liquors. In addition, although the liquor tax law classifies as sparkling liquors, beer and sparkling wine are also brewed sakes made by brewing. For brewed sake, simple fermented liquors (such as wine (vinegar), cider (apple wine), horse liquor, etc.)) that ferment sugars as they are to obtain alcoholic beverages, saccharify starch and ferment the sugars. There are double fermented liquors for obtaining liquors [for example, beer (single double fermented liquor), sake (parallel double fermented liquor)]. Since brewed liquor is only from alcoholic fermentation by yeast, the alcohol content is at most about 22%.
 〈蒸留酒〉
 蒸留酒は、醸造酒を蒸留して作った酒であり、基本的に、アルコール度数が高いアルコール飲料である。酒税法では、蒸留酒類として、次に掲げる酒類(その他の発泡性酒類を除く。):イ)連続式蒸留しようちゆう、ロ)単式蒸留しようちゆう、ハ)ウイスキー、ニ)ブランデー、ホ)原料用アルコール、ヘ)スピリッツと定義されている。蒸留酒には、蒸留したアルコールに加水をしたもの、或いは、木製の樽等で熟成したもの等も含まれる。
<Distilled liquor>
Distilled liquor is liquor made by distilling brewed liquor, and is basically an alcoholic beverage with a high alcohol content. Under the Liquor Tax Law, the following alcoholic beverages (excluding other sparkling alcoholic beverages): b) whiskey, d) brandy, e) It is defined as alcohol for raw materials, f) spirits. Distilled liquor includes those obtained by adding water to distilled alcohol or aging in a wooden barrel or the like.
 蒸留酒には、ジン(原料:大麦、ライ麦、ジャガイモ、香草等)、ウォッカ(原料:ライ麦、グレーン、甜菜、フルーツ、ジャガイモ等)、スピリタス(原料:穀物、ジャガイモ、香草等)、泡盛(原料:インディカ米、穀物等)、焼酎(原料:米、麦、サツマイモ、黒糖、そば、栗、酒粕、糖蜜等)、ソジュ「韓国焼酎」(原料:米、ジャガイモ、コムギ、オオムギ、サツマイモ、タピオカ等)、白酒〔穀物を原料としたパイチュ、及び高粱を原料とした茅台酒等〕、メスカル又はテキーラ(原料:竜舌蘭)、ウイスキー(原料:大麦、ライ麦、トウモロコシ等)、ブランデー〔果実酒が原料のブランデー、白ブドウが原料のアルマニャック、リンゴが原料のカルヴァドス、ブドウの搾りかすが原料のグラッパ、ブドウが原料のコニャック、ブドウが原料のシンガニ、ブドウ果汁が原料のピスコ等〕、カシャッサ又はピンガ(原料:サトウキビ)、ラム酒(原料:サトウキビ、糖蜜等)、アラック〔ジャガイモが原料のアクアビット、家畜乳又は穀物が原料のアルヒ、ブドウが原料のラク等〕、コルン(原料:小麦、ライ麦等)、キルシュヴァッサー(原料:サクランボ)等が挙げられる。 For distilled liquor, gin (raw materials: barley, rye, potatoes, herbs, etc.), vodka (raw materials: rye, grains, sugar beet, fruits, potatoes, etc.), spiritus (raw materials: cereals, potatoes, herbs, etc.), awamori (raw materials) : Indica rice, grains, etc.), shochu (raw materials: rice, wheat, sweet potato, brown sugar, buckwheat, chestnut, sake lees, molasses, etc.), Soju "Korean shochu" (raw materials: rice, potato, wheat, barley, sweet potato, tapioca, etc.) ), White liquor (paichu made from cereals, and daidai dairy made from high grapes, etc.), mescal or tequila (raw materials: dragon tongue orchid), whiskey (raw materials: barley, rye, corn, etc.), brandy (fruit wine is the raw material. Brandy, Armagnac made from white grapes, Calvados made from apples, Grappa made from grape pomace, Cognac made from grapes , Swordfish made from grapes, pisco made from grape juice, etc.), cassassa or pinga (raw materials: sugarcane), rum (raw materials: sugarcane, molasses, etc.), arak (aquabits made from potatoes, livestock milk or grains Raw materials such as alhi, grapes as raw material, etc.), colun (raw materials: wheat, rye, etc.), Kirschwasser (raw material: cherries) and the like.
 「スピリッツ」は、酒税法上、イ)連続式蒸留しようちゆう、ロ)単式蒸留しようちゆう、ハ)ウイスキー、ニ)ブランデー、又はホ)原料用アルコール以外の酒類でエキス分が二度未満のものである。
 「ジン」は、穀類(大麦、ライ麦、ジャガイモ等)を原料とし、麦芽及び酵素剤を利用して、糖化、発酵、蒸溜して得られたスピリッツに、ジュニパーベリー(杜松の実)などの草根木皮を浸すなどして、香りをつけ、再度蒸溜した無色透明の酒をいい、草根木皮の香気成分固有の香味及び風味を有する酒(スピリッツ)である。
 「ウォッカ」は、穀類(ライ麦、グレーン、甜菜、フルーツ、ジャガイモ、トウモロコシ、小麦、大麦等)を原料として、糖化、発酵、蒸溜し、得られたスピリッツを白樺炭で濾過した酒(スピリッツ)をいい、スピリッツの中でも最もクセのない香味及び風味を有し、まろやかな爽快感を特徴とするものである。
 「ラム」はサトウキビの搾り汁を煮つめて、砂糖を結晶させたあとの糖蜜を原料とし、発酵、蒸溜、熟成の工程を経てつくられる酒(スピリッツ)である。
“Spirit” is liquor tax law b) liquor other than raw alcohol, b) whiskey, d) brandy, or e) liquor other than raw alcohol. belongs to.
“Gin” is made from cereals (barley, rye, potatoes, etc.), and is made from malt and enzyme, saccharified, fermented and distilled, with spirits such as juniper berries. A colorless and transparent liquor that has been scented by dipping grass root bark, etc., and distilled again, and has a flavor and flavor unique to the aroma component of grass root bark.
“Vodka” is made from cereals (rye, grains, sugar beet, fruit, potatoes, corn, wheat, barley, etc.) as raw materials, and saccharified, fermented and distilled. It has the most savory flavor and flavor among the spirits and is characterized by a mellow refreshing feeling.
“Rum” is a spirit made from the molasses after simmering sugarcane juice and crystallizing the sugar, followed by fermentation, distillation, and aging.
 (純アルコール換算)
 「純アルコール換算」とは、アルコール飲料(1L)に含まれる特定成分(mg)の濃度(mg/L=ppm)を、このアルコール飲料のアルコール度数割合(v/v)で割って、アルコール度数100(v/v%)当たりの数値に換算したものをいう。
 例えば、特定のアルコール飲料〔アルコール度数(v/v%)が50度(%)〕に、特定の香気成分が50ppmで含まれていた場合、特定の香気成分の含有量は、純アルコール換算で、〔50ppm÷(50度÷100)〕=100ppmとなる。
(Pure alcohol equivalent)
"Pure alcohol conversion" means the alcohol content by dividing the concentration (mg / L = ppm) of the specific component (mg) contained in the alcoholic beverage (1L) by the alcohol content ratio (v / v) of this alcoholic beverage. This is a value converted to a value per 100 (v / v%).
For example, if a specific alcoholic beverage [alcohol content (v / v%) is 50 degrees (%)] contains a specific aroma component at 50 ppm, the content of the specific aroma component is calculated in terms of pure alcohol. [50 ppm ÷ (50 degrees ÷ 100)] = 100 ppm.
 (含有量)
 本発明にあっては、含有量は、本明細書において特にことわりがない限り、基本的に、ppm、即ち、mg/L(質量/体積)にて表す。
(Content)
In the present invention, the content is basically expressed in ppm, that is, mg / L (mass / volume) unless otherwise specified in the present specification.
 〔アルコール飲料〕
 アルコール飲料は、オクタナール及び/又はデカナールを含んでなる。
 (オクタナール)
 アルコール飲料中、オクタナールの含有量は、純アルコール換算で0.025ppm以上であり、好ましくは、0.03ppm以上であり、より好ましくは、0.035ppm以上である。本発明にあっては、アルコール飲料中、オクタナールの含有量の上限値は、純アルコール換算で、アルコール飲料に含有可能な最大値であり、好ましくは、50ppm以下であり、より好ましくは2.5ppm以下である。
[Alcoholic drinks]
The alcoholic beverage comprises octanal and / or decanal.
(Octanal)
In the alcoholic beverage, the content of octanal is 0.025 ppm or more in terms of pure alcohol, preferably 0.03 ppm or more, and more preferably 0.035 ppm or more. In the present invention, the upper limit value of the octanal content in the alcoholic beverage is the maximum value that can be contained in the alcoholic beverage in terms of pure alcohol, preferably 50 ppm or less, more preferably 2.5 ppm. It is as follows.
 オクタナールは、和柑橘類(様)香気成分及び風味成分を呈するものであり、アルコール飲料に含有させることにより、アルコール由来の苦味及び刺激味を低減させ、甘さ及び厚みを付与し、伝統的な香気及び風味(例えば、「松脂臭い」)を抑制し、或いは、高い次元において和柑橘類(様)香気及び風味を付加することができる。特に、オクタナールを上記含有量で含有させることにより、上記本発明の効果をさらに高めることが可能となる。 Octanal presents a Japanese citrus (like) fragrance component and a flavor component, and by adding it to an alcoholic beverage, it reduces the bitterness and pungent taste derived from alcohol, imparts sweetness and thickness, And flavor (e.g., "pine odor") can be suppressed, or Japanese citrus (like) aroma and flavor can be added in higher dimensions. In particular, the effect of the present invention can be further enhanced by containing octanal in the above content.
 (デカナール)
 アルコール飲料中、デカナールの含有量は、純アルコール換算で0.015ppm以上であり、好ましくは、0.02ppm以上であり、より好ましくは、0.025ppm以上である。本発明にあっては、アルコール飲料中、デカナールの含有量の上限値は、純アルコール換算で、アルコール飲料に含有可能な最大値であり、好ましくは、50ppm以下であり、より好ましくは2.5ppm以下である。
(Decanal)
In the alcoholic beverage, the content of decanal is 0.015 ppm or more, preferably 0.02 ppm or more, more preferably 0.025 ppm or more in terms of pure alcohol. In the present invention, the upper limit of the content of decanal in the alcoholic beverage is the maximum value that can be contained in the alcoholic beverage in terms of pure alcohol, preferably 50 ppm or less, more preferably 2.5 ppm. It is as follows.
 デカナールは、和柑橘類(様)香気成分及び風味成分を呈するものであり、アルコール飲料に含有させることにより、アルコール由来の苦味及び刺激味を低減させ、甘さ及び厚みを付与し、伝統的な香気及び風味(例えば、「松脂臭い」)を抑制し、或いは、高い次元において和柑橘類(様)香気及び風味を付加することができる。特に、オクタナールを上記含有量で含有させることにより、上記本発明の効果をさらに高めることが可能となる。 Decanal presents Japanese citrus (like) fragrance and flavor components, and by adding it to alcoholic beverages, it reduces the bitterness and pungent taste derived from alcohol, imparts sweetness and thickness, And flavor (e.g., "pine odor") can be suppressed, or Japanese citrus (like) aroma and flavor can be added in higher dimensions. In particular, the effect of the present invention can be further enhanced by containing octanal in the above content.
 (オクタナール及び/又はデカナール)
 好ましい態様では、アルコール飲料は、オクタナール及びデカナールを含んでなる。
 アルコール飲料中、オクタナール及びデカナールの合計含有量が純アルコール換算で0.035ppm以上であり、好ましくは、0.04ppm以上であり、より好ましくは、0.045ppm以上である。本発明にあっては、アルコール飲料中、オクタナール及びデカナールの合計含有量の上限値は、純アルコール換算で、アルコール飲料に含有可能な最大値であり、好ましくは、50ppm以下であり、より好ましくは5ppm以下である。
(Octanal and / or decanal)
In a preferred embodiment, the alcoholic beverage comprises octanal and decanal.
In the alcoholic beverage, the total content of octanal and decanal is 0.035 ppm or more, preferably 0.04 ppm or more, more preferably 0.045 ppm or more in terms of pure alcohol. In the present invention, the upper limit of the total content of octanal and decanal in the alcoholic beverage is the maximum value that can be contained in the alcoholic beverage in terms of pure alcohol, preferably 50 ppm or less, more preferably 5 ppm or less.
 オクタナールとデカナールとを混合して含有することにより、上記本発明の効果を相乗することが可能となる。また、他の和柑橘類固有の香気成分及び風味成分と相俟って、優れた和柑橘類(様)香気成分及び風味成分の加算以上の相乗効果を達成し、さらには、高い次元において和柑橘類(様)香気又は風味を付加することができる。 By mixing and containing octanal and decanal, the effects of the present invention can be synergized. In addition, in combination with other aroma and flavor components unique to Japanese citrus, it achieves a synergistic effect that is more than the addition of excellent Japanese citrus (like) aroma and flavor components. Like) Aroma or flavor can be added.
 また、蒸留酒、例えば、ジン、ウォッカ等のスピリッツは、欧米諸国で伝統的に製造されたものであり、日本人等の東洋人には、蒸留酒に包含される香草の香気成分が嗜好に合致しないことがある。しかし、和柑橘類(様)香気成分及び風味成分を呈するオクタナール及び/又はデカナールを含有することにより、これら伝統的な香気成分を緩和することができる。 In addition, spirits such as gin and vodka are traditionally produced in Western countries, and the fragrance components of the herbs included in distilled liquor are preferred by orientals such as Japanese. May not match. However, the inclusion of octanal and / or decanal presenting Japanese citrus (like) fragrance components and flavor components can alleviate these traditional fragrance components.
 さらに、オクタナール及び/又はデカナールは、和柑橘類(様)香気成分及び風味成分を呈することから、日本原産種(在来種)の和柑橘類由来の香気成分及び風味成分(和の香味及び風味)を含有したアルコール飲料として、日本国内及び外国市場に提案することが可能となる。 Furthermore, since octanal and / or decanal presents a Japanese citrus (like) fragrance component and a flavor component, the fragrance component and flavor component (Japanese flavor and flavor) derived from Japanese citrus of the Japanese native species (conventional species) As a contained alcoholic beverage, it can be proposed to the domestic and foreign markets in Japan.
 オクタナール及び/又はデカナールは、天然物又は人工物から食品添加物として許容される方法で抽出されたものを使用することができる。また、オクタナール及び/又はデカナールは、食品化学的に許容される手法によって合成されたものであってよいが、食品安全性が確立したもののみを好ましくは使用する。好ましくは、オクタナール及び/又はデカナールは、和柑橘類、好ましくは日本在来種の和柑橘類からの抽出物(例えば、食用エタノール浸漬物)又は精油(エキス)の主要成分として存在している物であってよい。 As the octanal and / or decanal, those extracted from a natural product or an artificial product by a method acceptable as a food additive can be used. In addition, octanal and / or decanal may be synthesized by a food chemistry-acceptable technique, but only those having established food safety are preferably used. Preferably, the octanal and / or decanal is a substance present as a main component of an extract (for example, an edible ethanol soak) or an essential oil (extract) from a Japanese citrus, preferably a Japanese native citrus. It's okay.
 (和柑橘類)
 和柑橘類は、様々なものが使用できるが、日本原産種又は在来種である、温州ミカン、伊予柑、夏ミカン、八朔、柚子、臭橙(カボス)、シークワサー、すだち、ダイダイ、日向夏、伊予柑、ぽんかん、デコポン(不知火)、清見、たんかん、夏みかん、甘夏、マイヤーレモン、げんこう、せとか、はるみ、たんかん(桶柑)、マーコット、アンコール、セミノール、晩白柚(ばんぺいゆ)、文旦(ブンタン)、カラ(カラマンダリン)、天草、スイートスプリング、はるか、南津海 (なつみ)、はれひめ、まりひめ、黄金柑、河内晩柑(美生柑)、紅まどんな、ひめのつき、甘平、麗紅、クレメンタイン、カクテルフルーツ、及びミネオラからなる群から選択される一種又は二種以上の混合物を使用することができる。これらの中でも、好ましくは、甘夏及び/又はカボスを使用する。
 また、和柑橘類は、その果皮、果実(果汁)、新芽、葉、茎又は棘を使用することができ、好ましくは、果皮、果実(果汁)を用いることができる。
 和柑橘類は、日本国内の様々な生産者、農業協同組合等から入手可能である。
(Japanese citrus)
Various kinds of Japanese citrus can be used, but they are native to Japan or native species, such as Unshu mandarin, Iyokan, Summer mandarin, Yahata, Isogo, Smell orange (Kavos), Shikuwasa, Sudachi, Daidai, Hyuga summer, Iyokan, Ponkan, Deconpon, Kiyomi, Tankan, Summer orange, Sweet summer, Mayer lemon, Health, Setoka, Harumi, Tankan (Tangerine), Marcot, Encore, Seminole, Banpakuyu, Banpeiyu, Buntan, Kara (Karamandarin), Amakusa, Sweet Spring, Haruka, Nantsukai (Natsumi), Harehime, Marihime, Golden Tangerine, Kawachi Bankan (Miseikan), Red Miso, Himetsuki One or a mixture of two or more selected from the group consisting of Kanpei, Rei, Clementine, Cocktail Fruit, and Mineola can be used. Of these, sweet summer and / or kabos are preferably used.
For Japanese citrus fruits, the skin, fruit (fruit juice), shoots, leaves, stems or spines can be used, and preferably the fruit skin and fruit (fruit juice) can be used.
Japanese citrus fruits are available from various producers and agricultural cooperatives in Japan.
 (アルコール含有量)
 本発明によるアルコール飲料は、好ましくは、アルコール度数が10度(%)以上、より好ましくは下限値が30度(%)以上であり、上限値が約100度(%)以下であるものである。アルコール度数が上記範囲内にあることにより、特定含有量のオクタナール及び/又はデカナールを添加することによる効果をより発揮させることが可能となる。
(Alcohol content)
The alcoholic beverage according to the present invention preferably has an alcohol content of 10 degrees (%) or more, more preferably a lower limit value of 30 degrees (%) or more and an upper limit value of about 100 degrees (%) or less. . When the alcohol content is within the above range, the effect of adding a specific content of octanal and / or decanal can be more exhibited.
 (任意成分)
 アルコール飲料は、任意成分として、色素、香料、甘味料、酸味料、pH調整剤、酸化防止剤、保存料、ビタミン類、旨み成分、食物繊維、安定化剤、乳化剤を含有することが可能である。これらは、厚生労働省、消費者庁等において定められたガイドライン及び関連法規(食品衛生法等)に規定されたものを用いる。
(Optional component)
Alcoholic beverages can contain pigments, flavorings, sweeteners, acidulants, pH adjusters, antioxidants, preservatives, vitamins, umami ingredients, dietary fiber, stabilizers, and emulsifiers as optional ingredients. is there. These are the ones stipulated in the guidelines established by the Ministry of Health, Labor and Welfare, the Consumer Affairs Agency, and related laws and regulations (Food Sanitation Law, etc.).
 (アルコール飲料)
 アルコール飲料は、特定含有量のオクタナール及び/又はデカナールを必須成分として包含するものであれば、いずれのものであってよく、例えば、食用エタノールに特定含有量のオクタナール及び/又はデカナールを添加したものであってよい。好ましくは、醸造酒、蒸留酒及びこれらの混合酒の一種、或いはこれらの二種以上の混合酒としてもよい。より好ましくは、一種又は二種以上の醸造酒と、一種又は二種以上の蒸留酒との混合酒であり、最も好ましいものは、一種又は二種以上の蒸留酒である。本発明にあっては、アルコール飲料は、蒸留酒、特に好ましくはスピリッツまたは焼酎である。
(Alcoholic beverage)
The alcoholic beverage may be any one as long as it contains a specific content of octanal and / or decanal as an essential component, for example, edible ethanol added with a specific content of octanal and / or decanal. It may be. Preferably, it may be brewed liquor, distilled liquor and one of these mixed liquors, or a mixture of two or more of these. More preferably, it is a mixed liquor of one or two or more kinds of brewed liquor and one or more kinds of distilled liquors, and the most preferable one is one or two or more kinds of distilled liquors. In the present invention, the alcoholic beverage is distilled liquor, particularly preferably spirits or shochu.
 〈醸造酒〉
 「醸造酒」は、清酒、果実酒、又はその他の醸造酒であり、例えば、ワイン(ブドウ酒)、シードル(リンゴ酒)、馬乳酒、ビール、日本酒が挙げられ、好ましくは、高濃度のワイン、シードル、日本酒が使用される。
<Brewed sake>
“Brewed sake” is refined sake, fruit wine, or other brewed sake, and examples thereof include wine (grape), cider (apple liquor), horse milk, beer, and sake, preferably high concentrations. Wine, cider and sake are used.
 〈蒸留酒〉
 「蒸留酒」は、酒税法上、連続式蒸留しようちゆう、単式蒸留しようちゆう、ウイスキー、ブランデー、原料用アルコール、スピリッツに含まれるものが挙げられ、好ましくは、連続式蒸留しようちゆう、単式蒸留しようちゆう、ブランデー、又はスピリッツである。「蒸留酒」としては、一般に、ジン、ウォッカ、スピリタス、焼酎、ソジュ、白酒、メスカル、テキーラ、ウイスキー、ブランデー(アルマニャック、カルヴァドス、グラッパ、コニャック、シンガニ、ピスコ等)、カシャッサ、ピンガ、ラム酒、アラック、コルン、キルシュヴァッサー等が挙げられ、好ましくは、ジン、ウォッカ、スピリタス、焼酎、ソジュ、白酒、メスカル、テキーラ、ブランデー、アラックが挙げられ、より好ましくは、ジン、ウォッカ、スピリタス、焼酎であり、最も好ましくはジン又は焼酎が挙げられる。
<Distilled liquor>
“Distilled liquor” includes, for the sake of liquor tax law, those that are included in continuous distillation, single distillation, whiskey, brandy, alcohol for raw materials, spirits, preferably continuous distillation, It is a simple distillation scent, brandy, or spirits. As "distilled liquor", generally, gin, vodka, spiritus, shochu, soju, white liquor, mescal, tequila, whiskey, brandy (armagnac, calvados, grappa, cognac, singani, pisco, etc.), cachasassa, pinga, rum, Arrack, Korn, Kirschwasser and the like can be mentioned, preferably gin, vodka, spiritus, shochu, soju, white liquor, mescal, tequila, brandy, alac, and more preferably gin, vodka, spiritus and shochu. Most preferably, gin or shochu is used.
 〔アルコール飲料の製造方法〕
 本発明の一の態様は、アルコール飲料を製造する方法であって、
 食用エタノールと、オクタナール及び/又はデカナールとを用意し、
 前記食用エタノールに、前記オクタナール及び/又は前記デカナールを混合し(好ましくは、常温、大気圧下)、
 前記オクタナールの含有量を純アルコール換算で0.025ppm以上としてなり、及び/又は、
 前記デカナールの含有量をアルコール換算で0.015ppm以上としてなることを含んでなる、アルコール飲料の製造方法を提案する。
[Method for producing alcoholic beverage]
One aspect of the present invention is a method of producing an alcoholic beverage,
Prepare edible ethanol and octanal and / or decanal,
The edible ethanol is mixed with the octanal and / or the decanal (preferably at room temperature and atmospheric pressure),
The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or
The manufacturing method of the alcoholic beverage which comprises making content of the said decanal into 0.015 ppm or more in conversion of alcohol is proposed.
 本発明の別の態様は、アルコール飲料を製造する方法であって、
 食用エタノールと、オクタナールと、デカナールとを用意し、
 前記食用エタノールに、前記オクタナール及び前記デカナールを混合し、
 前記オクタナール及び前記デカナールの合計含有量を純アルコール換算で0.035ppm以上としてなることを含んでなる、アルコール飲料の製造方法を提案する。
Another aspect of the present invention is a method of producing an alcoholic beverage,
Prepare edible ethanol, octanal, and decanal,
In the edible ethanol, the octanal and the decanal are mixed,
The manufacturing method of the alcoholic beverage which comprises making the total content of the said octanal and the said decanal into 0.035 ppm or more in conversion of pure alcohol is proposed.
 具体的には、本発明によるアルコール飲料の製造方法は、食用アルコール(エタノール)に、特定含有量のオクタナール及び/又はデカナールを必須成分として含有させることによって製造するものである。また、食用アルコール(エタノール)に、有意量の和柑橘類を浸漬した後に蒸留して、オクタナール及び/又はデカナールを必須成分として包含した蒸留酒を、食用アルコール(エタノール)に含有させることによって製造するものである。蒸留は常圧で行ってもよいし減圧で行ってもよいが、好ましくは減圧である。 Specifically, the method for producing an alcoholic beverage according to the present invention is produced by containing edible alcohol (ethanol) with a specific content of octanal and / or decanal as an essential component. In addition, by immersing a significant amount of Japanese citrus fruits in edible alcohol (ethanol) and then distilling them, the distilled alcohol containing octanal and / or decanal as an essential component is included in the edible alcohol (ethanol). It is. Distillation may be carried out at normal pressure or reduced pressure, but is preferably reduced pressure.
 例えば、醸造酒、蒸留酒及びこれらの混合酒の一種、或いはこれらの二種以上の混合酒に、特定含有量のオクタナール及び/又はデカナールを含有させてもよいし、有意量の和柑橘類を浸漬した後に蒸留し、得られた和柑橘類の蒸留酒を添加して、オクタナール及び/又はデカナールを特定含有量となるように調整したものであってよい。特定含有量のオクタナール及び/又はデカナールを含有させることにより、これら醸造酒、蒸留酒本来の香味及び風味を向上させる一方で、香気成分を低減・抑制することも可能となる。 For example, brewed liquor, distilled liquor and one of these mixed liquors, or a mixture of two or more of these may contain a specific content of octanal and / or decanal, or a significant amount of Japanese citrus is soaked Then, it is distilled, and the resulting Japanese citrus distilled liquor may be added to adjust the octanal and / or decanal to a specific content. By containing a specific content of octanal and / or decanal, the original flavor and flavor of the brewed liquor and distilled liquor can be improved, and the aroma component can be reduced / suppressed.
 アルコール飲料を製造する方法において、原料〔例えば、オクタナール、デカナール、食用アルコール(エタノール)、和柑橘類〕、含有量、調整等は、上記〔アルコール飲料〕の項で説明したのと同様であってよい。 In the method for producing an alcoholic beverage, the raw materials [eg, octanal, decanal, edible alcohol (ethanol), Japanese citrus], content, adjustment, and the like may be the same as described in the above section [Alcoholic beverage]. .
 〔容器詰めアルコール飲料〕
 別の好ましい態様によれば、アルコール飲料を容器に詰めた容器詰アルコール飲料を提案することができる。容器詰アルコール飲料とすることにより、アルコール由来の苦味及び刺激味低減維持と、甘味及び厚み付与を保持し、伝統的な香気及び風味の抑制維持、並びに、高い次元において和柑橘類(様)香気又は風味を保持し続けると伴に、アルコール飲料の提供利便性、流通利便性、保存性、品質劣化防止を図ることが可能となる。
[Contained alcoholic beverages]
According to another preferable aspect, a container-packed alcoholic beverage in which an alcoholic beverage is packed in a container can be proposed. By making a container-packed alcoholic beverage, maintaining the reduction of bitterness and pungent taste derived from alcohol, and maintaining sweetness and thickness, and maintaining traditional fragrance and flavor suppression, and higher citrus (like) fragrance or While maintaining the flavor, it becomes possible to provide convenience, distribution convenience, storage stability, and quality deterioration prevention of alcoholic beverages.
 容器は、内容物が漏洩しない材料であれば、ビニール、プラスチック、ガラス、金属、紙、木又は皮等で、様々な形状で形成された容器に詰めることができる。より好ましい態様によれば、容器の内外に、光、熱、酸素、紫外線等を遮断するための素材(たとえば、着色又は機能性フィルム、金属箔)を備えたものであってよい。 The container can be packed into containers formed in various shapes with vinyl, plastic, glass, metal, paper, wood or leather, etc., as long as the contents do not leak. According to a more preferred aspect, the container may be provided with a material (for example, a colored or functional film, a metal foil) for blocking light, heat, oxygen, ultraviolet rays, etc. inside and outside the container.
 以下の実施例により、本発明の内容を更に具体的に説明するが、本発明の範囲は下記実施例に限定して解釈されるものではない。また、以下の実施例は、本発明の実施態様の一例を示すものであるが、これら実施例により当業者は本発明の全ての範囲について容易に実施することができること当然に理解するものである。 The contents of the present invention will be described more specifically with reference to the following examples, but the scope of the present invention should not be construed as being limited to the following examples. In addition, the following examples show examples of embodiments of the present invention. However, it should be understood that those skilled in the art can easily implement the entire scope of the present invention by using these examples. .
 〔評価試験1:オクタナール及びデカナールの定性定量〕
 下記実施例1及び実施例2、比較例1~3のアルコール飲料について、オクタナールおよびデカナールの定量を行った。
[Evaluation test 1: Qualitative determination of octanal and decanal]
Octalal and decanal were quantified for the alcoholic beverages of Examples 1 and 2 and Comparative Examples 1 to 3 below.
 (アルコール飲料の調製)
 〈実施例1〉
 搾汁により果汁を取り除いた甘夏を65%アルコールに二昼夜浸漬し、減圧蒸留することで、甘夏の蒸留酒を得た。
(Preparation of alcoholic beverages)
<Example 1>
Sweet summer, from which fruit juice was removed by squeezing, was soaked in 65% alcohol for two days and distilled under reduced pressure to obtain a sweet summer distilled liquor.
 〈実施例2〉
 搾汁により果汁を取り除いたカボスを65%アルコールに二昼夜浸漬し、減圧蒸留することで、カボスの蒸留酒を得た。
<Example 2>
Cabos from which juice was removed by squeezing was soaked in 65% alcohol for two days and nights, and distilled under reduced pressure to obtain Kavos distilled liquor.
 〈比較例1~3:市販蒸留酒〉
 比較例1は、「季の美」(アルコール45%、ジン、京都蒸留所社製)を用いた。
 比較例2は、「WILKINSON GIN 47.5°」(アルコール47%、ジン、アサヒビール社製)を用いた。
 比較例3は、「WILKINSON GIN 37°」(アルコール37%、ジン、アサヒビール社製)を用いた。
<Comparative Examples 1 to 3: Commercial distilled liquor>
In Comparative Example 1, “Seasonal Beauty” (alcohol 45%, gin, manufactured by Kyoto Distillery) was used.
In Comparative Example 2, “WILKINSON GIN 47.5 °” (alcohol 47%, gin, manufactured by Asahi Breweries) was used.
In Comparative Example 3, “WILKINSON GIN 37 °” (alcohol 37%, gin, manufactured by Asahi Breweries) was used.
 (定性定量方法)
 実施例1及び2は超純水で15倍希釈したもの、比較例1~3は超純水で5倍希釈したものをそれぞれ試料とした。1mLの試料に200μLの内部標準(10ppm リナロール-d5)を添加した後に、超純水で50倍希釈した。希釈した試料の香気成分をTwisterに吸着(40℃、2時間)させ、GC-MS分析を行い、内部標準法により定量を行った。
(Qualitative quantification method)
Examples 1 and 2 were samples diluted 15 times with ultrapure water, and Comparative Examples 1 to 3 were samples diluted 5 times with ultrapure water. After adding 200 μL of an internal standard (10 ppm linalool-d5) to a 1 mL sample, the sample was diluted 50 times with ultrapure water. The aroma component of the diluted sample was adsorbed on Twister (40 ° C., 2 hours), subjected to GC-MS analysis, and quantified by an internal standard method.
 〈GC条件〉
 ・装置:昇温気化型注入口(CIS4,Gerstel社製)、加熱脱着ユニット(TDU,Gerstel社製)、GC Systerm(7890B、Agilent Technologies社製)、Mass Selective Detector(5977、Agilent Technologies社製)
 ・LTMカラム(1st:DB-WAX,20m×0.18mm;0.3μm、2nd:DB-5,10m×0.18mm;0.4μm,Agilent Technologies社製) 
 ・TDU:20℃(1min)-(720℃/min)-250℃(3min)
 ・CIS4:-50℃(1.5min)-(12℃/sec)-240℃(45min)
 ・スプリット比:30:1
 ・注入口圧:508.28kPa
 ・ベント圧:314.11kPa
 ・1stカラム温度:40℃(3min)-(5℃/min)-180℃(0min)
 ・2ndカラム温度:40℃(31min)-(5℃/min)-180℃(0min)
 ・MSD:SCAN mode,m/z 29-230,20Hz,EI
 ・定量イオン:リナロール-d5(m/z 98)、オクタナール(m/z 110)、デカナール(m/z 112)                                                                       
<GC condition>
・ Equipment: Temperature rising vaporization inlet (CIS4, manufactured by Gerstel), thermal desorption unit (TDU, manufactured by Gerstel), GC System (7890B, manufactured by Agilent Technologies), Mass Selective Detector (5977, manufactured by Agilent Technologies)
LTM column (1st: DB-WAX, 20 m × 0.18 mm; 0.3 μm, 2nd: DB-5, 10 m × 0.18 mm; 0.4 μm, manufactured by Agilent Technologies)
TDU: 20 ° C. (1 min) − (720 ° C./min)−250° C. (3 min)
CIS4: -50 ° C (1.5min)-(12 ° C / sec) -240 ° C (45min)
-Split ratio: 30: 1
・ Inlet pressure: 508.28 kPa
・ Vent pressure: 314.11kPa
1st column temperature: 40 ° C. (3 min) − (5 ° C./min)−180° C. (0 min)
2nd column temperature: 40 ° C. (31 min) − (5 ° C./min)−180° C. (0 min)
・ MSD: SCAN mode, m / z 29-230, 20Hz, EI
Quantitative ions: linalool-d5 (m / z 98), octanal (m / z 110), decanal (m / z 112)
 (定性定量結果)
 実施例と比較例における、オクタナール含有量と、デカナール含有量を下記表1に記載した。                                                        
(Qualitative quantitative results)
Table 1 below shows the octanal content and decanal content in Examples and Comparative Examples.
 〔評価試験1:結果〕
 実施例1及び実施例2(本発明)は、高い有意量においてオクタナール及びデカナールを包含した高アルコール飲料であったことが理解された。蒸留酒(比較例1)は、オクタナール及びデカナールを全く包含されていなかったことが理解された。
[Evaluation Test 1: Results]
It was understood that Example 1 and Example 2 (invention) were high alcoholic beverages containing octanal and decanal in high significant amounts. It was understood that the distilled liquor (Comparative Example 1) did not contain any octanal or decanal.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 〔評価試験2:官能評価試験〕
 (アルコール飲料の調製)
 下記表2、3に記載した通り、オクタナール含有量と、デカナール含有量を調製した実施例及び比較例を調製した。
 実施例3~8及び比較例4は、比較例2にオクタナール又はデカナールを表2の濃度になるように添加したものを用いた。
 実施例9は、比較例2に実施例1で製造した甘夏の蒸留酒及び水を表2の濃度になるように添加したものを用いた。
 実施例10は、比較例2に実施例2で製造したカボスの蒸留酒及び水を表2の濃度になるように添加したものを用いた。
 実施例11~12は、比較例3にオクタナール又はデカナールを表3の濃度になるように添加したものを用いた。
[Evaluation Test 2: Sensory Evaluation Test]
(Preparation of alcoholic beverages)
As described in Tables 2 and 3 below, Examples and Comparative Examples in which the octanal content and decanal content were prepared were prepared.
In Examples 3 to 8 and Comparative Example 4, those obtained by adding octanal or decanal to Comparative Example 2 so as to have the concentrations shown in Table 2 were used.
In Example 9, the one obtained by adding the sweet summer distilled liquor and water produced in Example 1 to Comparative Example 2 so as to have the concentrations shown in Table 2 was used.
In Example 10, the Kabos distilled liquor produced in Example 2 and water were added to Comparative Example 2 so as to have the concentrations shown in Table 2.
Examples 11 to 12 used Comparative Example 3 in which octanal or decanal was added to the concentration shown in Table 3.
 (官能評価手法)
 本出願人会社内の品質管理試験を通った食品官能評価能力のある6名(20歳から65歳までの男女)のパネルにより、実施例及び比較例のアルコール飲料を以下の基準で評価し、その平均値を得て、その結果を、下記表2及び表3に記載した。
(Sensory evaluation method)
By the panel of 6 people (men and women from 20 to 65 years old) who have food sensory evaluation ability that passed the quality control test in the applicant company, alcoholic beverages of Examples and Comparative Examples were evaluated according to the following criteria, The average value was obtained and the results are shown in Tables 2 and 3 below.
 〔評価基準〕
 (1) 松脂臭、苦味、刺激、甘さ、厚みの評価基準は以下の通りであった。また、「飲みやすさ」は大変飲みやすいを「5点」、大変飲みにくいを「1点」とし、5段階評価で行った。
  評価点 1:感じられない。
  評価点 2:弱い。
  評価点 3:やや弱い。
  評価点 4:やや強い。
  評価点 5:強い。
〔Evaluation criteria〕
(1) The evaluation criteria of pine odor, bitterness, irritation, sweetness, and thickness were as follows. In addition, “easy to drink” was evaluated according to a five-step evaluation, with “5 points” being very easy to drink and “1 point” being very difficult to drink.
Evaluation point 1: It is not felt.
Evaluation point 2: weak.
Evaluation point 3: Slightly weak.
Evaluation point 4: Slightly strong.
Evaluation point 5: Strong.
 (2) 実施例3~10及び比較例4は、比較例2との比較官能を行った。比較例2(評価基準)の評点はパネル間での評価判定の下、松脂臭「5点」、苦味「5点」、刺激「5点」、爽快感「2点」、厚み「2点」、飲みやすさ「2点」とした。
 パネル6名の平均点を算出し、比較例2と比較して、平均点が0.5点以上差があった際に効果があると判断した。
(2) Examples 3 to 10 and Comparative Example 4 were subjected to a comparative sensory function with Comparative Example 2. The scores of Comparative Example 2 (evaluation criteria) are as follows: pine odor “5 points”, bitterness “5 points”, irritation “5 points”, refreshment “2 points”, thickness “2 points” Ease of drinking was set to “2 points”.
The average score of the six panelists was calculated, and compared with Comparative Example 2, it was judged that there was an effect when there was a difference of 0.5 points or more in the average score.
 (3) 実施例11及び12は、比較例3との比較官能を行った。なお、比較例3(評価基準)の評点はパネル間での評価判定の下、松脂臭「4点」、苦味「4点」、刺激「4点」、爽快感「2点」、厚み「2点」、飲みやすさ「2点」とした。パネル6名の平均点を算出し、比較例3と比較して、平均点が0.5点以上差があった際に効果があると判断した。 (3) In Examples 11 and 12, comparative sensation with Comparative Example 3 was performed. In addition, the score of Comparative Example 3 (evaluation criteria) was pine odor “4 points”, bitterness “4 points”, irritation “4 points”, exhilaration “2 points”, and thickness “2” after evaluation between panels. "Point" and ease of drinking "2 points". The average score of the six panelists was calculated, and compared with Comparative Example 3, it was judged that the average score was effective when there was a difference of 0.5 points or more.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
 〔評価試験2:結果〕
 実施例3~10は、比較例2と比較して、甘さや厚みが付与されたことで、松脂臭、苦味、刺激が低減され、飲みやすさが改善されていることがわかった。
 実施例11及び12は、比較例3と比較して、甘さや厚みが付与されたことで、松脂臭、苦味、刺激が低減され、飲みやすさが改善されていることがわかった。
 比較例2~4は、松脂臭、苦味、刺激が強く、甘さ、厚みが弱いことから、飲みにくいものであった。
[Evaluation Test 2: Results]
In Examples 3 to 10, it was found that compared to Comparative Example 2, sweetness and thickness were imparted, so that pine odor, bitterness and irritation were reduced, and ease of drinking was improved.
In Examples 11 and 12, it was found that sweetness and thickness were imparted as compared with Comparative Example 3, so that rosin odor, bitterness and irritation were reduced, and ease of drinking was improved.
Comparative Examples 2 to 4 were difficult to drink due to strong pine odor, bitterness, irritation, sweetness, and low thickness.
 〔総合評価〕
 実施例は、比較例との対比において、特定量のオクタナール及び/又は特定量のデカナールを、アルコール飲料に含有させることで、アルコール飲料に、和柑橘類(様)香気及び風味を高いレベルで付与し、甘さや厚みを付与し、松脂臭、苦味、刺激を低減され、飲みやすさを改善することが明らかとなった。
〔Comprehensive evaluation〕
In contrast to the comparative example, the examples contained a specific amount of octanal and / or a specific amount of decanal in the alcoholic beverage, thereby giving the alcoholic beverage a high level of Japanese citrus (like) aroma and flavor. It was revealed that sweetness and thickness were imparted, pine odor, bitterness and irritation were reduced, and the ease of drinking was improved.

Claims (11)

  1.  アルコール飲料であって、
     オクタナール及び/又はデカナールを含んでなり、
     前記オクタナールの含有量が純アルコール換算で0.025ppm以上であり、及び/又は、
     前記デカナールの含有量が純アルコール換算で0.015ppm以上であることを特徴とする、アルコール飲料。
    An alcoholic beverage,
    Comprising octanal and / or decanal,
    The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or
    An alcoholic beverage, wherein the decanal content is 0.015 ppm or more in terms of pure alcohol.
  2.  アルコール飲料であって、
     オクタナール及びデカナールを含んでなり、
     前記オクタナール及び前記デカナールの合計含有量が純アルコール換算で0.035ppm以上であることを特徴とする、アルコール飲料。
    An alcoholic beverage,
    Comprising octanal and decanal,
    An alcoholic beverage, wherein the total content of octanal and decanal is 0.035 ppm or more in terms of pure alcohol.
  3.  前記オクタナール及び/又は前記デカナールが和柑橘類から抽出されたものである、請求項1又は2に記載のアルコール飲料。 The alcoholic beverage according to claim 1 or 2, wherein the octanal and / or the decanal is extracted from Japanese citrus.
  4.  前記和柑橘類が、温州ミカン、伊予柑、夏ミカン、八朔、柚子、臭橙(カボス)、シークワサー、すだち、ダイダイ、日向夏、ぽんかん、デコポン(不知火)、清見、夏みかん、甘夏、マイヤーレモン、げんこう、せとか、はるみ、たんかん(桶柑)、マーコット、アンコール、セミノール、晩白柚(ばんぺいゆ)、文旦(ブンタン)、カラ(カラマンダリン)、天草、スイートスプリング、はるか、南津海 (なつみ)、はれひめ、まりひめ、黄金柑、河内晩柑(美生柑)、紅まどんな、ひめのつき、甘平、麗紅、クレメンタイン、カクテルフルーツ、及びミネオラからなる群から選択される一種又は二種以上の混合物である、請求項3に記載のアルコール飲料。 The Japanese citrus fruits are Unshu mandarin, Iyokan, Summer mandarin, Yawata, Yuzu, Smell orange (Kavos), Sikhwasa, Sudachi, Daidai, Natsu Hinata, Ponkan, Dekopon (Shiran), Kiyomi, Summer mandarin, Sweet summer, Meyer lemon , Health, Setoka, Harumi, Tankan (Tangerine), Markot, Angkor, Seminole, Banpeiyu, Buntan, Kara (Karamandarin), Amakusa, Sweet Spring, Haruka, Natsumi ), Harehime, Marihime, Golden Tangerine, Kawachi Bankan (Miseikan), Beni-Mado, Himetsuki, Ganpei, Rei, Clementine, Cocktail Fruit, and Mineola Or the alcoholic beverage of Claim 3 which is a mixture of 2 or more types.
  5.  前記和柑橘類が甘夏及び/又は臭橙(カボス)である、請求項3に記載のアルコール飲料。 The alcoholic beverage according to claim 3, wherein the Japanese citrus fruits are sweet summer and / or odor orange (kabosu).
  6.  アルコール度数が10度以上である、請求項1又は2に記載のアルコール飲料。 The alcoholic beverage according to claim 1 or 2, wherein the alcohol content is 10 ° C or more.
  7.  前記アルコール飲料が蒸留酒である、請求項1又は2に記載のアルコール飲料。 The alcoholic beverage according to claim 1 or 2, wherein the alcoholic beverage is distilled liquor.
  8.  前記アルコール飲料がスピリッツ又は焼酎である、請求項1又は2に記載のアルコール飲料。 The alcoholic beverage according to claim 1 or 2, wherein the alcoholic beverage is spirits or shochu.
  9.  前記スピリッツがジンである、請求項8に記載のアルコール飲料。 The alcoholic beverage according to claim 8, wherein the spirit is gin.
  10.  アルコール飲料を製造する方法であって、
     食用エタノールと、オクタナール及び/又はデカナールとを用意し、
     前記食用エタノールに、前記オクタナール及び/又は前記デカナールを混合し、
     前記オクタナールの含有量を純アルコール換算で0.025ppm以上としてなり、及び/又は、
     前記デカナールの含有量をアルコール換算で0.015ppm以上としてなることを含んでなる、アルコール飲料の製造方法。
    A method for producing an alcoholic beverage, comprising:
    Prepare edible ethanol and octanal and / or decanal,
    In the edible ethanol, the octanal and / or the decanal is mixed,
    The octanal content is 0.025 ppm or more in terms of pure alcohol, and / or
    The manufacturing method of the alcoholic drink which comprises making content of the said decanal into 0.015 ppm or more in alcohol conversion.
  11.  アルコール飲料を製造する方法であって、
     食用エタノールと、オクタナールと、デカナールとを用意し、
     前記食用エタノールに、前記オクタナール及び前記デカナールを混合し、
     前記オクタナール及び前記デカナールの合計含有量を純アルコール換算で0.035ppm以上としてなることを含んでなる、アルコール飲料の製造方法。
    A method for producing an alcoholic beverage, comprising:
    Prepare edible ethanol, octanal, and decanal,
    In the edible ethanol, the octanal and the decanal are mixed,
    The manufacturing method of the alcoholic beverage which comprises making the total content of the said octanal and the said decanal into 0.035 ppm or more in conversion of pure alcohol.
PCT/JP2018/003341 2017-02-10 2018-02-01 Alcoholic beverage and production method therefor WO2018147153A1 (en)

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